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Uranium-series age estimates and paleoclimatic significance of Pleistocene tufas from the Lahontan basin, California and Nevada

An extended chronology of Lahontan basin lake levels based on uranium-series age estimates correlates with the global ice-volume record. Lake highstands occur at or shortly after times of maximum ice-sheet size. Moderate size lakes occur when the global ice volume is about 80% of its maximum. The data indicate that lake levels rise and fall relative to the proximity of the mean position of the jetstream. When the continental ice sheet is above some threshold size or shape, it appears that the large-scale circulation and climatic conditions are right for producing lakes of moderate to large size within the Lahontan basin. ?? 1988.

Quaternary Research

UDATE1: A computer program for the calculation of uranium-series isotopic ages

UDATE1 is a FORTRAN-77 program with an interface for an Apple Macintosh computer that calculates isotope activities from measured count rates to date geologic materials by uranium-series disequilibria. Dates on pure samples can be determined directly by the accumulation of 230Th from 234U and of 231Pa from 235U. Dates for samples contaminated by clays containing abundant natural thorium can be corrected by the program using various mixing models. Input to the program and file management are made simple and user friendly by a series of Macintosh modal dialog boxes. ?? 1991.

Computers & Geosciences

Leaching of molybdenum and arsenic from uranium ore and mill tailings

A sequential, selective extraction procedure was used to assess the effects of sulfuric acid milling on the geochemical associations of molybdenum and arsenic in a uranium ore blend, and the tailings derived therefrom. The milling process removed about 21% of the molybdenum and 53% of the arsenic initially present in the ore. While about one-half of the molybdenum in the ore was water soluble, only about 14% existed in this form in the tailings. The major portion of the extractable molybdenum in the tailings appears to be associated with hydrous oxides of iron, and with alkaline earth sulfate precipitates. In contrast with the pattern seen for molybdenum, the partitioning of arsenic into the various extractable fractions differs little between the ore and the tailings.

Hydrometallurgy

Leaching of 226Ra from components of uranium mill tailings

A sequential extraction procedure was used to characterize the geochemical forms of 226 Ra retained by mixtures of quartz sand and a variety of fine-grained rock and mineral species. These mixtures had previously been exposed to the sulfuric acid milling liquor of a simulated acid-leach uranium milling circuit. For most test cases, the major fraction of the 226 Ra was extracted with 1 mol/1 NH 4 Cl and was deemed to be exchangeable. However, 226 Ra retained by the barite-containing mixture was resistant to both 1 mol/1 NH 4 Cl and 1 mol/HCHCl extraction.

Hydrometallurgy

Uranium-series isochron dating at El Castillo Cave (Cantabria, Spain): The "Acheulean"/"Mousterian" question

A massive flowstone layer, Level 23, near the base of the stratigraphic sequence in El Castillo Cave (Cantabria, Spain), is dated by the uranium-series isochron method to 89+11/−10 ka bp. The flowstone separates cultural layers traditionally labelled “Mousterian” (above) and “Acheulean” (below). The date reported here, in association with other recent age determinations for “Mousterian” and “Acheulean” artifact assemblages in Western Europe, calls into question the temporal significance of these archaeological designations. In addition, it further underlies the importance of the Castillo cultural sequence and allows tentative discussion of changing rates of sedimentation in the vestibule of the cave, where some 18 m of cultural and geological deposits were laid down during the course of the Upper Pleistocene.

Journal of Archaeological Science

Radioactive springs geochemical data related to uranium exploration

Radioactive mineral springs and wells at 33 localities in the States of Colorado, Utah, Arizona and New Mexico in the United States were sampled and studied to obtain geochemical data which might be used for U exploration. The major source of radioactivity at mineral spring sites is 226 Ra. Minor amounts of 228 Ra, 238 U and 232 Th are also present. Ra is presumed to have been selectively removed from possibly quite deep uranium-mineralized rock by hydrothermal solutions and is either precipitated at the surface or added to fresh surface water. In this way, the source rocks influence the geochemistry of the spring waters and precipitates. Characteristics of the spring waters at or near the surface are also affected by variations in total dissolved solids, alkalinity, temperature and co-precipitation. Spring precipitates, both hard and soft, consist of four major types: (1) calcite travertine; (2) iron- and arsenic-rich precipitates; (3) manganese- and barium-rich precipitates; and (4) barite, in some instances accompanied by S, Ra and U, if present in the spring water, are co-precipitated with the barite, Mn-Ba and Fe-As precipitates. Using parameters based on U and Ra concentrations in waters and precipitates springsite areas are tentatively rated for favourability as potential uraniferous areas.

Journal of Geochemical Exploration

Uranium-series nuclides in the Golden fault, Colorado, U.S.A.: Dating latest fault displacement and measuring recent uptake of radionuclides by fault-zone materials

Concentrations and isotopic ratios of U, Th and Ra were measured in a fault zone near Golden, Colorado where major displacement occurred between about 190 and 615 ka. Faulting created new surfaces for leaching and provided the pathways for U-rich ground water. Uranium and 230 Th, the latter produced by the decay of dissolved 234 U, are adsorbed by fault gouge, hematite-stained sand and brecciated sand- and claystones. The observed U enrichment is as much as six times baseline value and the simultaneous enrichment of 230 Th is estimated at about ninefold relative to 238 U. The adsorption of radionuclides chemically analogous to Th, such as Pu (IV) and Np, and 237 Np decay products, on fault-zone materials would contribute to the immobilization of high-level radioactive waste in the vicinity of a repository in the event of leakage from engineered barriers into fractured rock-mass.

Colorado

The Uranium-trend dating method: Principles and application for southern California marine terrace deposits

Uranium-trend dating is an open-system method for age estimation of Quaternary sediments, using disequilibrium in the 238U234U230Th decay series. The technique has been applied to alluvium, colluvium, loess, till, and marine sediments. In this study we tested the U-trend dating method on calcareous marine terrace deposits from the Palos Verdes Hills and San Nicolas Island, California. Independent age estimates indicate that terraces in these areas range from ???80 ka to greater than 1.0 Ma. Two low terraces on San Nicolas Island yielded U-trend plots that have a clustered array of points and the ages of these deposits are indeterminate or highly suspect. Middle Pleistocene terraces and one early Pleistocene terrace on San Nicolas Island and all terraces on the Palos Verdes Hills gave reasonably linear U-trend plots and estimated ages that are stratigraphically consistent and in agreement with independent age estimates. We conclude that many marine terrace deposits are suitable for U-trend dating, but U-trend plots must be carefully evaluated and U-trend ages should be consistent with independent geologic control. ?? 1989.

Quaternary International

Potential effects of alpha-recoil on uranium-series dating of calcrete

Evaluation of paleosol ages in the vicinity of Yucca Mountain, Nevada, at the time the site of a proposed high-level nuclear waste repository, is important for fault-displacement hazard assessment. Uranium-series isotope data were obtained for surface and subsurface calcrete samples from trenches and boreholes in Midway Valley, Nevada, adjacent to Yucca Mountain. 230 Th/U ages of 33 surface samples range from 1.3 to 423 thousand years (ka) and the back-calculated 234 U/ 238 U initial activity ratios (AR) are relatively constant with a mean value of 1.54 ± 0.15 (1σ), which is consistent with the closed-system behavior. Subsurface calcrete samples are too old to be dated by the 230 Th/U method. U-Pb data for post-pedogenic botryoidal opal from a subsurface calcrete sample show that these subsurface calcrete samples are older than ~ 1.65 million years (Ma), old enough to have attained secular equilibrium had their U-Th systems remained closed. However, subsurface calcrete samples show U-series disequilibrium indicating open-system behavior of 238 U daughter isotopes, in contrast with the surface calcrete, where open-system behavior is not evident. Data for 21 subsurface calcrete samples yielded calculable 234 U/ 238 U model ages ranging from 130 to 1875 ka (assuming an initial AR of 1.54 ± 0.15, the mean value calculated for the surface calcrete samples). A simple model describing continuous α-recoil loss predicts that the 234 U/ 238 U and 230 Th/ 238 U ARs reach steady-state values ~ 2 Ma after calcrete formation. Potential effects of open-system behavior on 230 Th/U ages and initial 234 U/ 238 U ARs for younger surface calcrete were estimated using data for old subsurface calcrete samples with the 234 U loss and assuming that the total time of water-rock interaction is the only difference between these soils. The difference between the conventional closed-system and open-system ages may exceed errors of the calculated conventional ages for samples older than ~ 250 ka, but is negligible for younger soils.

Chemical Geology

Uranium isotopes and dissolved organic carbon in loess permafrost: Modeling the age of ancient ice

The residence time of ice in permafrost is an indicator of past climate history, and of the resilience and vulnerability of high-latitude ecosystems to global change. Development of geochemical indicators of ground-ice residence times in permafrost will advance understanding of the circumstances and evidence of permafrost formation, preservation, and thaw in response to climate warming and other disturbance. We used uranium isotopes to evaluate the residence time of segregated ground ice from ice-rich loess permafrost cores in central Alaska. Activity ratios of 234 U vs. 238 U ( 234 U/ 238 U) in water from thawed core sections ranged between 1.163 and 1.904 due to contact of ice and associated liquid water with mineral surfaces over time. Measured ( 234 U/ 238 U) values in ground ice showed an overall increase with depth in a series of five neighboring cores up to 21 m deep. This is consistent with increasing residence time of ice with depth as a result of accumulation of loess over time, as well as characteristic ice morphologies, high segregated ice content, and wedge ice, all of which support an interpretation of syngenetic permafrost formation associated with loess deposition. At the same time, stratigraphic evidence indicates some past sediment redistribution and possibly shallow thaw among cores, with local mixing of aged thaw waters. Using measures of surface area and a leaching experiment to determine U distribution, a geometric model of ( 234 U/ 238 U) evolution suggests mean ages of up to ∼200 ky BP in the deepest core, with estimated uncertainties of up to an order of magnitude. Evidence of secondary coatings on loess grains with elevated ( 234 U/ 238 U) values and U concentrations suggests that refinement of the geometric model to account for weathering processes is needed to reduce uncertainty. We suggest that in this area of deep ice-rich loess permafrost, ice bodies have been preserved from the last glacial period (10–100 ky BP), despite subsequent fluctuations in climate, fire disturbance and vegetation. Radiocarbon ( 14 C) analysis of dissolved organic carbon (DOC) in thaw waters supports ages greater than ∼40 ky BP below 10 m. DOC concentrations in thaw waters increased with depth to maxima of >1000 ppm, despite little change in ice content or cryostructures. These relations suggest time-dependent production of old DOC that will be released upon permafrost thaw at a rate that is mediated by sediment transport, among other factors.

Alaska

Statistical analysis of soil geochemical data to identify pathfinders associated with mineral deposits: An example from the Coles Hill uranium deposit, Virginia, USA

Soil geochemical anomalies can be used to identify pathfinders in exploration for ore deposits. In this study, compositional data analysis is used with multivariate statistical methods to analyse soil geochemical data collected from the Coles Hill uranium deposit, Virginia, USA, to identify pathfinders associated with this deposit. Elemental compositions and relationships were compared between the collected Coles Hill soil and reference soil samples extracted from a regional subset of a national-scale geochemical survey. Results show that pathfinders for the Coles Hill deposit include light rare earth elements (La and Ce), which, when normalised by their Al content, are correlated with U/Al, and elevated Th/Al values, which are not correlated with U/Al, supporting decoupling of U from Th during soil generation. These results can be used in genetic and weathering models of the Coles Hill deposit, and can also be applied to future prospecting for similar U deposits in the eastern United States, and in regions with similar geological/climatic conditions.

Virginia

Effects of grazing on leaf area index, fractional cover and evapotranspiration by a desert phreatophyte community at a former uranium mill site on the Colorado Plateau

This study employed ground and remote sensing methods to monitor the effects of grazing on leaf area index (LAI), fractional cover (f c ) and evapotranspiration (ET) of a desert phreatophyte community over an 11 year period at a former uranium mill site on the Colorado Plateau, U.S. Nitrate, ammonium and sulfate are migrating away from the mill site in a shallow alluvial aquifer. The phreatophyte community, consisting of Atriplex canescens (ATCA) and Sarcobatus vermiculatus (SAVE) shrubs, intercepts groundwater and could potentially slow the movement of the contaminant plume through evapotranspiration (ET). However, the site has been heavily grazed by livestock, reducing plant cover and LAI. We used livestock exclosures and revegetation plots to determine the effects of grazing on LAI, f c and ET, then projected the findings over the whole site using multi-platform remote sensing methods. We show that ET is approximately equal to annual precipitation at the site, but when ATCA and SAVE are protected from grazing they can develop high f c and LAI values, and ET can exceed annual precipitation, with the excess coming from groundwater discharge. Therefore, control of grazing could be an effective method to slow migration of contaminants at this and similar sites in the western U.S.

Colorado Plateau

Natural and anthropogenic processes affecting radon releases during mining and early stage reclamation activities, Pinenut uranium mine, Arizona, USA

Radon (Rnair) was monitored in open air in publicly accessible areas surrounding the Pinenut uranium (U) mine during mining and reclamation activities in 2015–16 to address concerns about mining related effects to areas surrounding Grand Canyon National Park (GCNP) in Arizona, USA. During July 2015, Rnair concentrations associated with the ore storage pile monitoring site were larger than those at the mine vent monitoring site and likely resulted from the relatively large amount of ore stored on site during this period. Higher wind velocities at the ore pile monitoring site generally resulted in lower Rnair concentrations; however, wind velocity did not appear to be an important factor in controlling Rnair concentrations at the mine vent monitoring site. Physical disturbances of the ore pile by heavy equipment did not coincide with elevated Rnair concentrations at the ore storage pile or mine vent monitoring sites. The relative size of the ore storage pile showed a positive trend with the daily mean Rnair concentration measured at the ore pile monitoring site. Principal component analysis (PCA) was applied to the ore pile and mine vent multivariate data sets for simultaneous comparison of all measured variables during 230 days of the study period. A significant positive coefficient for Rnair was associated with a significant negative coefficient for wind speed for principal component (PC) 2ore pile. Significant, positive PC2mine vent coefficients included Rnair, wind direction, and relative ore pile size indicating that Rnair variations at the mine vent monitoring site may be affected by Rn sourced from the ore pile. The ore pile is located about 200 m south of the mine vent Rn monitor with the prevalent wind direction coming from the south. All data generated during the field study and laboratory verification tests were published by Naftz et al. (2018) and are available online at:

Journal of Environmental Radioactivity

Evolving radon diffusion through earthen barriers at uranium waste disposal sites

Field measurements of Rn-222 fluxes from the tops and bottoms of compacted clay radon barriers were used to calculate effective Rn diffusion coefficients (D Rn ) at four uranium waste disposal sites in the western United States to assess cover performance after more than 20 years of service. Values of D Rn ranged from 7.4 × 10 −7 to 6.0 × 10 −9 m 2 /s, averaging 1.42 × 10 −7 . Water saturation (S W ) from soil cores indicated that there was relatively little control of D Rn by S W , especially at higher moisture levels, in contrast to estimates from most steady-state diffusion models. This is attributed to preferential pathways intrinsic to construction of the barriers or to natural process that have developed over time including desiccation cracks, root channels, and insect burrows in the engineered earthen barriers. A modification to some models in which fast and slow pathway D Rn values are partitioned appears to give a good representation of the data; 4% of the fast pathway was needed to fit the data regression. For locations with high S w and highest D Rn (and fluxes) at each site, the proportion of fast pathway ranged from 1.7% to 34%, but for many locations with lower fluxes, little if any fast pathway was needed.

Journal of Environmental Radioactivity

Natural uranium and strontium isotope tracers of water sources and surface water-groundwater interactions in arid wetlands: Pahranagat Valley, Nevada, USA

Near-surface physical and chemical process can strongly affect dissolved-ion concentrations and stable isotope compositions of water in wetland settings, especially under arid climate conditions. In contrast, heavy radiogenic isotopes of strontium ( 87 Sr/ 86 Sr) and uranium ( 234 U/ 238 U) remain largely unaffected and can be used to help identify unique signatures from different sources and quantify end-member mixing that would otherwise be difficult to determine. The utility of combined Sr and U isotopes are demonstrated in this study of wetland habitats on the Pahranagat National Wildlife Refuge, which depend on supply from large-volume springs north of the Refuge, and from small-volume springs and seeps within the Refuge. Water budgets from these sources have not been quantified previously. Evaporation, transpiration, seasonally variable surface flow, and water management practices complicate the use of conventional methods for determining source contributions and mixing relations. In contrast, 87 Sr/ 86 Sr and 234 U/ 238 U remain unfractionated under these conditions, and compositions at a given site remain constant. Differences in Sr- and U-isotopic signatures between individual sites can be related by simple two- or three-component mixing models. Results indicate that surface flow constituting the Refuge’s irrigation source consists of a 65:25:10 mixture of water from two distinct regionally sourced carbonate aquifer springs, and groundwater from locally sourced volcanic aquifers. Within the Refuge, contributions from the irrigation source and local groundwater are readily determined and depend on proximity to those sources as well as water management practices.

Nevada

An exploration of open-system uranium-series history of marine terrace corals, Perachora Peninsula, Greece and San Nicolas Island, California, USA

Emergent marine terraces record past periods of relatively high sea level and are common on uplifting coasts worldwide. Such landforms are extensive around the Gulf of Corinth area of Greece and along the coast of California, USA. In the Gulf of Corinth region, marine terraces record Quaternary uplift due to ongoing basin extension on the northern side of the Africa-Eurasia-Aegean Sea plate boundary. Although dating of terrace fossils has been extensive in the Perachora Peninsula part of this region, some apparent ages are much older (∼190 ka to ∼150 ka) and some are much younger (∼91 ka to ∼69 ka) than expected for a marine terrace that has long been hypothesized to be of last-interglacial (∼120 ka) age. New uranium-series analyses of terrace corals from two previously studied localities are reported here. As with previous work, the new results show that these corals have behaved as open systems, with back-calculated, initial 234 U/ 238 U values higher than those found in modern seawater. New and previously published U-series analyses of last-interglacial corals from San Nicolas Island, California (USA) illustrate the possible mechanisms of open-system behavior, which include both “early” alpha-recoil-derived additions of 230 Th and 234 U, and “continuing” alpha-recoil-derived additions of these nuclides. Many corals from the Perachora Peninsula appear to have experienced the “continuing” alpha-recoil-derived open-system history, which explains the apparent older ages, and permits an interpretation that all analyzed corals likely date to the last interglacial period, ∼120 ka. If the estimated age of ∼120 ka reported here is correct, this age, along with considerations of glacial isostatic adjustment (GIA) modeling of past sea level, indicates that the southern side of the Perachora Peninsula has experienced uplift rates ranging from ∼0.23 m/kyr to ∼0.57 m/kyr, increasing to the southeast, in agreement with previous work. Interpretation of the geomorphology of the northern side of the peninsula has been controversial for more than four decades. The “stepped” topography has been interpreted as either a series of successively higher and older marine terraces, as on the southern side, or a marine terrace of one age that has been displaced by a series of shore-parallel, northward-dipping normal faults. In the second interpretation, topographic steps in the landscape are interpreted to be fault scarps, not ancient sea cliffs. Interpretation of the open-system U-series ages indicates that marine deposits at elevations of ∼22 m and ∼44 m are both likely ∼120 ka, supporting the scenario that steps in the landscape are likely fault scarps, not sea cliffs. Using the new U-series ages of ∼120 ka, along with GIA-modeled paleo-sea level confirms another previous study that uplift rates on the northern side of the peninsula are at least as high as 0.39–0.46 m/kyr.

California

Assessing nonpoint-source uranium pollution in an irrigated stream-aquifer system

Uranium (U) in rocks and soils of arid and semi-arid environments can be mobilized by irrigation and fertilization, posing environmental and health risks. Elevated U, along with selenium (Se) and nitrate (NO 3 ) co-constituents, necessitates careful monitoring and management. We developed a distributed-parameter numerical model to assess U pollution in an irrigated stream-aquifer system, applying it to a 552 km 2 region in Colorado's Lower Arkansas River Valley (LARV) over 14 years. A MODFLOW model, describing groundwater and stream flow, was coupled with an RT3D-OTIS model to portray reactive U transport. Calibration using the PESTPP-iES iterative ensemble smoother (iES) software indicated good agreement with observed U concentrations. The model revealed substantial and variable U levels across the LARV, highlighting potential hotspots and possible contributing factors, such as geological composition of the bedrock and near-surface shale and aquifer sediments derived from them, irrigation practices, and riparian landscape. U levels exceed the chronic standard (85th percentile = 30 μg/L, set by the US Environmental Protection Agency), which is the permissible regulatory threshold, in groundwater across 44 % of the region and along the river by an average factor of 2.9. Simulated average U concentrations in the non-riparian aquifer and river are 124 μg/L and 60 μg/L, respectively, compared with 112 μg/L and 62 μg/L for measured values. The average 85th percentile U concentration is 222 μg/L in the aquifer and 82 μg/L in the river. Average simulated U mass loading to the river is 0.17 kg/day per km, compared to an estimated 0.23 kg/day per km. Findings provide a baseline for comparing future simulated outcomes of alternative best management practices (BMPs) for U pollution mitigation and offer a methodology applicable to other irrigated regions.

Colorado

A procedure for quantitation of total oxidized uranium for bioremediation studies

A procedure was developed for the quantitation of complexed U(VI) during studies on U(VI) bioremediation. These studies typically involve conversion of soluble or complexed U(VI) (oxidized) to U(IV) (the reduced form which is much less soluble). Since U(VI) freely exchanges between material adsorbed to the solid phase and the dissolved phase, uranium bioremediation experiments require a mass balance of U in both its soluble and adsorbed forms as well as in the reduced sediment bound phase. We set out to optimize a procedure for extraction and quantitation of sediment bound U(VI). Various extractant volumes to sediment ratios were tested and it was found that between 1:1 to 8:1 ratios (v/w) there was a steady increase in U(VI) recovered, but no change with further increases in v/w ratio. Various strengths of NaHCO 3 , Na-EDTA, and Na-citrate were used to evaluate complexed U(VI) recovery, while the efficiency of a single versus repeated extraction steps was compared with synthesized uranyl-phosphate and uranyl-hydroxide. Total recovery with 1 M NaHCO 3 was 95.7% and 97.9% from uranyl-phosphate and uranyl-hydroxide, respectively, compared to 80.7% and 89.9% using 450 mM NaHCO 3 . Performing the procedure once yielded an efficiency of 81.1% and 92.3% for uranyl-phosphate and uranyl-hydroxide, respectively, as compared to three times. All other extractants yielded 7.9–82.0% in both experiments.

Journal of Microbiological Methods