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Hydrologic reconnaissance of Hansel Valley and northern Rozel Flat, Box Elder County, Utah

This report is the ninth in a series by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights, which describes the water resources of the western basins of Utah (see fig. 1). Its purpose is to present available hydrologic data for Hansel Valley, to provide an evaluation of the potential water-resource development of the valley, and to identify needed studies that would improve understanding of the valley's water supply. Hydrologic data from the northern part of adjacent Rozel Flat were collected to aid in evaluation of southern Hansel Valley, and these data also are included in this report.

Utah

Reconnaissance examination of the biology, chemistry, and physical characteristics of selected streams in California and Nevada

This report contains hydrological data from several California and Nevada streams. Emphasis is placed upon water-quality data, but stream discharge at the time of making the water-quality measurements also is given. The purpose of the report is to provide personnel of the U.S. Bureau of Land Management with baseline hydrological data from the selected streams and one well. The streams, the stream sites selected for sampling, and the parameters measured, were chosen in consultation with U.S. Bureau of Land Management personnel.

California, Nevada

A water-budget analysis of Medina and Diversion Lakes and the Medina/Diversion Lake system, with estimated recharge to Edwards aquifer, San Antonio area, Texas

In January 2001, the U.S. Geological Survey—in cooperation with the Edwards Aquifer Authority—began a study to refine and, if possible, extend previously derived (1995–96) relations between the stage in Medina Lake and recharge to the Edwards aquifer to include the effects of reservoir stages below 1,018 feet and greater than 1,046 feet above National Geodetic Vertical Datum of 1929. The principal objective of this present (2001–02) study was to estimate ground-water outflow (seepage) from Medina Lake, Diversion Lake, and from the Medina/Diversion Lake system through the calculation of water budgets representing steady-state conditions over as wide a range as possible in the stages of Medina and Diversion Lakes. The water budgets were compiled for selected periods during which time the water-budget components were inferred to be relatively stable and the influence of precipitation, stormwater runoff, and changes in storage were presumably minimal. Water budgets for the Medina/Diversion Lake system were compiled for 127 water-budget periods ranging from 8 to 78 days from daily hydrologic data collected during March 1955–September 1964, October 1995–September 1996, and February 2001–June 2002. Budgets for Medina and Diversion Lakes were compiled for 14 periods ranging from 8 to 23 days from daily hydrologic data collected only during October 1995–September 1996 and April 2001–June 2002. Linear equations were developed to relate the stage in Medina Lake to ground-water outflow from Medina Lake, Diversion Lake, and the Medina/Diversion Lake system. The computed mean rates of outflow from Medina Lake ranged from about 18 to 182 acre-feet per day between stages of 1,019 and 1,064 feet above National Geodetic Vertical Datum of 1929. The computed rates of outflow from Diversion Lake ranged from about -85 to 52 acre-feet per day. The rates of outflow from the entire lake system ranged from about 5 to 178 acre-feet per day between Medina Lake stages of 963 to 1,064 feet. It is assumed that all outflow from the lake system enters the ground-water system as recharge to the Edwards aquifer. During the time that the stage in Medina Lake was greater than about 1,040 feet, Diversion Lake gained more water than it lost to the ground-water system and the rate of ground-water outflow from Medina Lake increased sharply while its stage was between about 1,043 and 1,045 feet. The observed outflow from Diversion Lake during this time decreased sharply to the extent that a net gain resulted—indicating that a substantial amount of the additional outflow from Medina Lake returned to Diversion Lake. When the stage in Medina Lake is at the spillway elevation of 1,064 feet, Diversion Lake appears to gain as much as 40 percent of the concurrent ground-water outflow from Medina Lake. An indication of water moving from the lake system into the ground-water system and back to the surface-water system was observed in the most downstream reach of the Medina River, between Diversion Lake and the Medina River near Riomedina. During conditions of no flow over Diversion Dam, this reach of the Medina River gained from about 32 to 94 acre-feet per day, with the gain increasing with increasing stage in Diversion Lake. The average of the monthly recharge to the Edwards aquifer from the Medina/Diversion Lake system—as estimated by the present study for the October 1995–September 2002 period—is 3,083 acre-feet, or about 56 percent of recharge computed for this period with a previously used (Lowry) method. The present study’s estimates of recharge for months with rising-lake stage conditions are about 44 percent of those computed with the previously used method, compared to about 60 percent for months with steady or falling-stage conditions. For stages greater than 1,045 feet, the present study estimated recharge to be about 52 percent of that computed with the previously used method, compared to about 64 percent at stages below 1,045 feet.

Texas

Geohydrology, aqueous geochemistry, and thermal regime of the Soda Lakes and Upsal Hogback geothermal systems, Churchill County, Nevada

A flow-routing model of the upper Schoharie Creek basin, New York, was developed and used to simulate high flows at the inlet of the Blenheim-Gilboa Reservoir. The flows from Schoharie Creek at Prattsville, the primary source of flow data in the basin, and tributary flows from the six minor basins downstream, are combined and routed along the 9.7 mile reach of the Schoharie Creek between Prattsville and the reservoir inlet. Data from five historic floods were used for model calibration and four for verification. The accuracy of the model as measured by the difference between simulated and observed total flow volumes, is within 14 percent. Results indicate that inflows to the Blenheim-Gilboa Reservoir can be predicted approximately 2 hours in advance. One of the historical floods was chosen for additional model testing to assess a hypothetical real-time model application. Total flow-volume errors ranged from 30.2 percent to -9.2 percent. Alternative methods of obtaining hydrologic data for model input are presented for use in the event that standard forms of hydrologic data are unavailable. (USGS)

Water-Resources Investigations Report

Suspended- and bedload-sediment transport in the Snake and Clearwater rivers in the vicinity of Lewiston, Idaho, August 1976 through July 1978

Impoundment of water in the Snake River and Clearwater River arms behind Lower Granite Dam (see cover map) began in June 1975. At this time, Lower Granite Reservoir and Lock facilities, constructed by the USACE (U.S. Army Corps of Engineers), Walla Walla District, became operational. Construction and operation of this facility necessitated collection of hydrologic data that did not exist prior to construction. The USACE requested the USGS (U.S. Geological Survey) to collect hydraulic- and channel-geometry data and describe sediment-transport characteristics, beginning in the spring of 1972. This report summarizes information collected during August 1976 through July 1978 and is the fifth in a series of reports designed to release hydrologic data on a timely basis. Although some of the data were collected during the late summer and fall periods (August through December) of 1976 and 1977, most were collected during the spring runoff periods of 1977 and 1978. Therefore, for convenience, data contained in this report will be referred to as the 1977-78 data. Because this is primarily a basic-data report, no interpretation of the data is provided. This report presents tables of selected data collected and computations compiled since the 1976 report (Seitz, 1976). Most of the tabular data are also presented on graphs. Some of the graphs show plots of data since 1972~ others show plots of only the 1977-78 data. Relatively minor amounts of bedload were transported during the 1977 drought period. Therefore, regular scheduled sampling of the bedload was impractical. Only two bedload samples were collected from the Clearwater River in 1977. The resultant data are included in tables 10, 12, and 14, and figure 6. All bedload data in this report should be considered tentative, pending completion of sampler-calibration studies and possible adjustment of the data to correct for sampler efficiency. An analysis of the middle Snake River streamflow record was made during 1977. The streamflow rating for the Snake River near Anatone, Washington, gage was found to be in error at high stages. The streamflow record for water years 1974 and 1975 was revised and published with 1976 water-year data (Water Resources Data for Idaho, Water Year 1976). The revised Snake River near Anatone streamflow rating was used to recompute the sediment-discharge rating curve (fig. 3). This study program is funded by the USACE through a cooperative agreement with the USGS. All field work, laboratory analysis, and compilation of data are being conducted by the USGS. Data collection is scheduled to terminate at the end of the 1979 runoff season. A reanalysis of all data collected since the start of the program will correct all provisional records since 1972, including the 1974, 1975, and 1976 years for the Snake River near Anatone station.

Idaho

Water-quality characteristics of streams in the Treyburn Development area of Falls Lake watershed, North Carolina, 1988-93

Treyburn is a 5,400 acre planned, mixed-use community located in the Falls Lake watershed in the upper Neuse River Basin of North Carolina. From February 1988 through 1993, hydrologic-data were collected at 17 study sites in or near the Treyburn development to compare the effects of varying types of land-use development on the water-quality of streams flowing in or near the development. The collected hydrologic data included measurements of streamflow and concentrations of major dissolved constituents, nutrients, minor elements, and organic compounds. Streamflow in the study basin was approximately 40 percent lower in 1992 and 40 percent higher in 1993 than the long-term annual mean of the long-term discharge records at Flat River in Bahama. Calcium and bicarbonate were the predominant cation and anion at all study sites except one. Mean total nitrogen and phosphorus concentrations at sites in the Treyburn development ranged from 0.5 to 0.8 and 0.03 to 0.10 milligrams per liter, respectively. Total aluminum, iron, and manganese were the metals most frequently detected in the 200 organic compunds analyzed. Dichloro- difluoromethane and methylene chloride were detected most often.

North Carolina

South Cascade Glacier, Washington; hydrologic and meteorological data, 1957-67

Historic hydrologic and meteorological data are compiled for South Cascade Glacier, Washington, USA, a site selected by the U.S. Geological Survey for long-term study of the response of a glacier to climate change and its effect on water resources. The data consist of stream discharge and meteorological data, including precipitation, air temperature, and instantaneous weather observations, all at various locations in the glacier basin. Data span the years 1957-67 and are presented in tables, with annual time-series graphs shown for most data.

Open-File Report

Discussion of “Annual floods and the partial duration flood series”

The writer is interested in finding from this paper a similar idea which he had in mind when engaging in a statistical study of hydrologic data, a part of the Highway Drainage Research Project being carried out in the Department of Civil Engineering, the University of Illinois. However, a complete presentation of the study will be reserved for future publications, and only fragments of thought are discussed here. In treating hydrologic data for the study of their frequency of recurrence, two phases of study are generally met. One is the frequency of recurrence for the observed distributions, and the other is the corresponding frequency of recurrence for the theoretical distributions of best‐fit. The former is usually required for the purpose of plotting observed data, and hence is called the “plotting positions,” a term used by Foster [1934, p. 1217]. The latter is treated by the mathematical theory of probability, and generally serves as a theoretical interpretation of the observed phenomena.

Eos, Transactions, American Geophysical Union

Hydrogeologic framework and groundwater/surface-water interactions of the South Fork Nooksack River Basin, northwestern Washington

A hydrogeologic framework of the South Fork (SF) Nooksack River Basin in northwestern Washington was developed and hydrologic data were collected to characterize the groundwater-flow system and its interaction with surface‑water features. In addition to domestic, agricultural, and commercial uses of groundwater within the SF Nooksack River Basin, groundwater has the potential to provide ecological benefits by maintaining late-summer streamflows and buffering stream temperatures. Cold-water refugia, created and maintained in part by groundwater, have been identified by water-resource managers as key elements to restore the health and viability of threatened salmonids in the SF Nooksack River. The SF Nooksack River drains a 183-square mile area of the North Cascades and the Puget Lowland underlain by unconsolidated glacial and alluvial sediments deposited over older sedimentary, metamorphic, and igneous bedrock. The primary aquifer that interacts with the SF Nooksack River was mapped within unconsolidated glacial outwash and alluvial sediment. The lower extent of this unit is bounded by bedrock and fine-grained, poorly sorted unconsolidated glaciomarine and glaciolacustrine sediments. In places, these deposits overlie and confine an aquifer within older glacial sediments. The extent and thickness of the hydrogeologic units were assembled from mapped geologic units and lithostratigraphic logs of field-inventoried wells. Generalized groundwater-flow directions within the surficial aquifer were interpreted from groundwater levels measured in August 2012; and groundwater seepage gains and losses to the SF Nooksack River were calculated from synoptic streamflow measurements made in the SF Nooksack River and its tributaries in September 2012. A subset of the field-inventoried wells was measured at a monthly interval to determine seasonal fluctuations in groundwater levels during water year 2013. Taken together, these data provide the foundation for a future groundwater-flow model of the SF Nooksack River Basin that may be used to investigate the potential effects of future climate change, land use, and groundwater pumping on water resources in the study area. Site-specific hydrologic data, including time series of longitudinal temperature profiles measured with a fiber-optic distributed temperature sensor and continuous monitoring of stream stage and water levels measured in wells in adjacent wetlands and aquifers, also were measured to characterize the interaction among the SF Nooksack River, surficial aquifers, and riparian wetlands.

Washington

U. S. Geological Survey Federal-State Cooperative Water-Resources Program Fiscal Year 1993

The Federal-State Cooperative Program is a part- nership between the U.S. Geological Survey and State and local agencies. It provides a balanced approach to the study and resolution of water- related problems and to acquiring hydrologic data. The principal program objectives are to: (1) collect, on a systematic basis, data needed for the continuing determination and evaluation of the quantity, quality, and use of the Nation's water resources, and (2) appraise the availa- bility and the physical, chemical, and biological characteristics of surface and ground water through analytical and interpretive investi- gations. During fiscal year 1993, hydrologic data collection, interpretive investigations, and research were conducted by Geological Survey personnel in offices in every State, Puerto Rico, and in several territories in cooperation with about 1,100 local, State, and regional agencies. In fiscal year 1993, Federal funding of $63.5 million was matched by cooperating agencies, which also provided almost $23 million unmatched for a total program of about $150 million. This amounted to nearly 40 percent of the total funds for Geological Survey water- resources activities. This report presents examples of current (1993) investigations. It also provides updated information on Cooperative Program investigations related to agricultural activities.

Open-File Report

Strategies for ensuring global consistency/comparability of water-quality data

In the past 20 years the water quality of the United States has improved remarkably-the waters are safer for drinking, swimming, and fishing. However, despite many accomplishments, it is still difficult to answer such basic questions as: 'How clean is the water?' and 'How is it changing over time?' These same questions exist on a global scale as well. In order to focus water-data issues in the United States, a national Intergovernmental Task Force on Monitoring Water Quality (ITFM) was initiated for public and private organizations, whereby key elements involved in data collection, analysis, storage, and management could be made consistent and comparable. The ITFM recommended and its members are implementing a nationwide strategy to improve water-quality monitoring, assessment, and reporting activities. The intent of this paper is to suggest that a voluntary effort be initiated to ensure the comparability and utility of hydrological data on a global basis. Consistent, long-term data sets that are comparable are necessary in order to formulate ideas regarding regional and global trends in water quantity and quality. The author recommends that a voluntary effort similar to the ITFM effort be utilized. The strategy proposed would involve voluntary representation from countries and international organizations (e.g. World Health Organization) involved in drinking-water assessments and/or ambient water-quality monitoring. Voluntary partnerships such as this will improve curability to reduce health risks and achieve a better return on public and private investments in monitoring, environmental protection, and natural resource management, and result in a collaborative process that will save millions of dollars.In this work it is suggested that a voluntary effort be initiated to ensure the comparability and utility of hydrological data on a global basis. The strategy proposed would involve voluntary representation from countries and international organizations involved in drinking-water assessments and/or ambient water-quality monitoring.

Conference Paper

Hydrogeology of the Lake Tahoe Basin, California and Nevada

Ground water in the Lake Tahoe basin is the primary source of domestic and municipal water supply and an important source of inflow to Lake Tahoe. Over the past 30-40 years, Federal, State, and local agencies, and research institutions have collected hydrologic data to quantify the ground-water resources in the Lake Tahoe basin. These data are dispersed among the various agencies and institutions that collected the data and generally are not available in a format suitable for basin-wide assessments. To successfully and efficiently manage the ground-water resources throughout the Lake Tahoe basin, the U.S. Geological Survey (USGS) in cooperation with the U.S. Forest Service (USFS) compiled and evaluated the pertinent geologic, geophysical, and hydrologic data, and built a geodatabase incorporating the consolidated and standardized data for the Lake Tahoe basin that is relevant for examining the extent and characteristics of the hydrogeologic units that comprise the aquifers.

California, Nevada

Ground-water hydrology and water quality of the Southern High Plains Aquifer, Cannon Air Force Base, Curry County, New Mexico, 1994-2005

In cooperation with the U.S. Air Force, the U.S. Geological Survey has collected hydrologic data about the Southern High Plains aquifer at Cannon Air Force Base in east-central New Mexico since 1994. Under the guidance of the State of New Mexico, ground-water quality of the aquifer has been analyzed as part of annual monitoring at regulated sites at the base. This report provides a summary and interpretation of all available hydrologic data collected by the U.S. Geological Survey for Cannon Air Force Base environmental managers for the regulated sites of Landfill 5 and the Sewage Lagoons between 1994 and 2005.

New Mexico

Characterization and simulation of ground-water flow in the Kansas River Valley at Fort Riley, Kansas, 1990-98

Hydrologic data and a ground-water flow model were used to characterize ground-water flow in the Kansas River alluvial aquifer at Fort Riley in northeast Kansas. The ground-water flow model was developed as a tool to project ground-water flow and potential contaminant-transport paths in the alluvial aquifer on the basis of past hydrologic conditions. The model also was used to estimate historical and hypothetical ground-water flow paths with respect to a private- and several public-supply wells. The ground-water flow model area extends from the Smoky Hill and Republican Rivers downstream to about 2.5 miles downstream from the city of Ogden. The Kansas River Valley has low relief and, except for the area within the Fort Riley Military Reservation, is used primarily for crop production. Sedimentary deposits in the Kansas River Valley, formed after the ancestral Kansas River eroded into bedrock, primarily are alluvial sediment deposited by the river during Quaternary time. The alluvial sediment consists of as much as about 75 feet of poorly sorted, coarse-to-fine sand, silt, and clay, 55 feet of which can be saturated with ground water. The alluvial aquifer is unconfined and is bounded on the sides and bottom by Permian-age shale and limestone bedrock. Hydrologic data indicate that ground water in the Kansas River Valley generally flows in a downstream direction, but flow direction can be quite variable near the Kansas River due to changes in river stage. Ground-water-level changes caused by infiltration of precipitation are difficult to detect because they are masked by larger changes caused by fluctuation in Kansas River stage. Ratios of strontium isotopes Sr87 and Sr86 in water collected from wells in the Camp Funston Area indicate that the ground water along the northern valley wall originates, in part, from upland areas north of the river valley. Water from Threemile Creek, which flows out of the uplands north of the river valley, had Sr87:Sr86 ratios similar to those in ground water from wells in the northern Camp Funston Area. In addition, comparison of observed water levels from wells CF90-06, CF97-101, and CF97-401 in the Camp Funston Area and ground-water levels simulated for these wells using floodwave-response analysis indicates that ground-water inflow from bedrock is a hydraulic stress that, in addition to the changing stage in the Kansas River, acts on the aquifer. This hydraulic stress seems to be located near the northern valley wall because the effect of this stress is greater for well CF97-101, which is the well closest to the valley wall. Ground-water flow was simulated using a modular, three-dimensional, finite-difference ground-water flow model (MODFLOW). Particle tracking, used to visualize ground-water flow paths in the alluvial aquifer, was accomplished using MODPATH. Forward-in-time particle tracking indicated that, in general, particles released near the Kansas River followed much more variable paths than particles released near the valley wall. Although particle tracking does not simulate solute transport, this increased path variability indicates that, near the river, ground-water contaminants could follow many possible paths towards the river, whereas more distant from the river, ground-water contaminants likely would follow a narrower corridor. Particle tracks in the Camp Funston Area indicate that, for the 1990-98 simulation period, contaminants from the ground-water study sites in the Camp Funston Area would be unlikely to move into the vicinity of Ogden's supply wells. Backward-in-time particle tracking indicated that the flow-path and recharge areas for model cells corresponding to Ogden's supply wells lie near the northern valley wall and extend into the northern Camp Funston Area. The flow-path and recharge areas for model cells corresponding to Morris County Rural Water District wells lie within Clarks Creek Valley and probably extend outside the model area. Three hypothetical simulations, i

Water-Resources Investigations Report

Using hydrogeomorphic criteria to classify wetlands on Mt. Desert Island, Maine – Approach, classification system, and examples

A wetland classification system was designed for Mt. Desert Island, Maine, to help categorize the large number of wetlands (over 1,200 mapped units) as an aid to understanding their hydrologic functions. The classification system, developed by the U.S. Geological Survey (USGS), in cooperation with the National Park Service, uses a modified hydrogeomorphic (HGM) approach, and assigns categories based on position in the landscape, soils and surficial geologic setting, and source of water. A dichotomous key was developed to determine a preliminary HGM classification of wetlands on the island. This key is designed for use with USGS topographic maps and 1:24,000 geographic information system (GIS) coverages as an aid to the classification, but may also be used with field data. Hydrologic data collected from a wetland monitoring study were used to determine whether the preliminary classification of individual wetlands using the HGM approach yielded classes that were consistent with actual hydroperiod data. Preliminary HGM classifications of the 20 wetlands in the monitoring study were consistent with the field hydroperiod data. The modified HGM classification approach appears robust, although the method apparently works somewhat better with undisturbed wetlands than with disturbed wetlands. This wetland classification system could be applied to other hydrogeologically similar areas of northern New England.

Maine

Summary and conclusions

Executive Summary Chromium concentrations in rock and aquifer material in Hinkley and Water Valleys in the Mojave Desert, 80 miles northeast of Los Angeles, California, are generally low compared to the average chromium concentration of 185 milligrams per kilogram (mg/kg) in the average bulk continental crust. Chromium concentrations in felsic, coarse-textured “Mojave-type” deposits, composed of Mojave River stream (alluvium) and lake-margin (beach) deposits sourced from the Mojave River, are as low as 5 mg/kg, with a median concentration of 23 mg/kg in aquifer materials adjacent to the screened intervals of sampled wells. The most abundant chromium-containing mineral within aquifer materials in Hinkley and Water Valleys is magnetite. Magnetite is resistant to weathering, and about 90 percent of chromium remains within unweathered mineral grains. However, chromium-containing hornblende diorite and basalt are present in surrounding uplands, and chromium-containing actinolite is present within some aquifer materials. Although geologic abundance of chromium is clearly important, hexavalent chromium, Cr(VI), concentrations in alkaline oxic groundwater are related to additional factors. Hexavalent chromium concentrations in groundwater are influenced by a combination of processes including (1) mineralogy and the weathering rates of chromium-containing minerals; (2) texture of aquifer deposits; (3) accumulation of chromium weathered from minerals within surface coatings on mineral grains; (4) oxidation of accumulated Cr(III) to Cr(VI) in the presence of manganese oxides (Mn oxides), including the abundance and oxidation states of those Mn oxides; (5) pH-dependent desorption of chromium from coatings on the surfaces of mineral grains into groundwater during appropriate aqueous geochemical conditions; and (6) age (time since recharge) of groundwater. The pH of groundwater increases with groundwater age (time since recharge) as a result of silicate weathering, and desorption of Cr(VI) from aquifer deposits increases with increasing pH as long as groundwater remains oxic. In the absence of the detailed geologic, geochemical, and hydrologic data collected as part of this study, pH-dependent sorption, evaluated as the Cr(VI) occurrence probability at the measured pH, is an effective indicator of natural or anthropogenic Cr(VI). The Pacific Gas and Electric Company (PG&E) Hinkley compressor station is used to compress natural gas as it is transported through a pipeline from Texas to California. Between 1952 and 1964, cooling water containing Cr(VI) was discharged to unlined ponds and released into groundwater in unconsolidated aquifers. The extent of groundwater containing evidence of at least some anthropogenic Cr(VI) was 5.5 square miles (mi 2 ) and was estimated using a summative scale incorporating geologic, geochemical, and hydrologic data collected from more than 100 wells between March 2015 and November 2017. The summative-scale Cr(VI) plume extent is larger than the 2.2 mi 2 extent of the October–December 2015 (Q4 2015) regulatory Cr(VI) plume but is smaller than the 8.3 mi 2 maximum mapped extent of Cr(VI) greater than the interim regulatory Cr(VI) background concentration of 3.1 micrograms per liter (μg/L). The summative-scale Cr(VI) plume is within felsic, low-chromium aquifer material deposited by the Mojave River described as Mojave-type deposits and is within the area covered by the PG&E monitoring well network. Background Cr(VI) concentrations were calculated using the computer program ProUCL 5.1 as the upper 95-percent tolerance limit, UTL 95 , using data from wells outside the summative-scale Cr(VI) plume extent collected between April 2017 and March 2018. The overall UTL 95 for undifferentiated, unconsolidated deposits in the eastern and western subareas and the northern subarea upgradient of the Mount General fault in Hinkley Valley was 3.8 μg/L; this value is similar to the overall UTL 95 value of 3.9 μg/L calculated for Mojave-type deposits in Hinkley and Water Valleys, and is similar to the maximum Cr(VI) concentration of older groundwater in contact with Mojave-type deposits of 3.6 μg/L. In most cases the overall UTL 95 value may be an acceptable Cr(VI) background value near the Cr(VI) plume margin; however, UTL 95 values for the various subareas in Hinkley and Water Valleys provide greater resolution of Cr(VI) background that may be important for some purposes. The UTL 95 values for undifferentiated, unconsolidated deposits in the eastern, western, and northern subareas upgradient of the Mount General fault were 2.8, 3.8, and 4.8 μg/L, respectively. The UTL 95 value of 2.8 μg/L for wells screened in undifferentiated, unconsolidated deposits in the eastern subarea is important for plume management because the Hinkley compressor station and most of the summative-scale Cr(VI) plume are within the eastern subarea. A UTL 95 value of 2.3 μg/L was calculated for Mojave-type deposits downgradient from the Hinkley compressor station. This value represents Cr(VI) concentrations that may have been present in that part of the aquifer had Cr(VI) not been released from the Hinkley compressor station, and it reflects coarser textured deposits in this area and the proximity of those deposits to recharge areas along the Mojave River that results in younger (post-1952), less alkaline groundwater than in wells farther downgradient. This value may be a suitable metric for Cr(VI) cleanup goals within the Cr(VI) plume after regulatory updates. A separate UTL 95 value of 5.8 μg/L was calculated for mudflat/playa deposits and older groundwater near Mount General in the eastern subarea. The UTL 95 values calculated for undifferentiated, unconsolidated deposits in the northern subarea downgradient from the Mount General fault and in Water Valley, including lacustrine (lake) deposits and material eroded from basalt and Miocene deposits, were 9.0 and 6.4 μg/L, respectively. Hexavalent chromium concentrations in more than 70 domestic wells sampled between January 27 and 31, 2016, ranged from less than the study reporting level of 0.1–4.0 μg/L, with a median concentration of 1.2 μg/L. Hexavalent chromium concentrations in water from domestic wells did not exceed UTL 95 values within subareas where the wells were located. Water from 47 percent of domestic wells sampled between January 27 and 31, 2016, had arsenic, uranium, or nitrate concentrations above a maximum contaminant level. Anthropogenic Cr(VI) within groundwater downgradient from the Hinkley compressor station is treated by PG&E using bioremediation by adding ethanol as a reductant within a volume of aquifer known as the in situ reactive zone (IRZ). Laboratory microcosm studies showed that Cr(VI) is rapidly reduced to Cr(III) with additions of ethanol. Reduced Cr(III) is sorbed and is sequestered into crystalline iron and manganese oxides on the surfaces of mineral grains within the microcosms during a period of several months. Trivalent chromium was reoxidized back to Cr(VI) within 2 weeks of return to oxic (oxygen present) conditions within the microcosms. As much as 10 percent of added Cr was oxidized to Cr(VI) in microcosms prepared using recent Mojave River aquifer material, and as much as 20 percent of added Cr was oxidized to Cr(VI) in microcosms prepared using older Mojave River aquifer material. Less Cr(VI) (less than 3 percent of Cr added before reduction) was released to the aqueous phase, and this release occurred following longer time periods of oxygen exposure. Sequestration of chromium with manganese oxides during reduction facilitates reoxidation of Cr(III) to Cr(VI) under oxic conditions. Future maintenance of anoxic (oxygen absent) conditions would ensure continued sequestration of chromium as Cr(III) within IRZ treated portions of the Cr(VI) plume. Although Cr(VI) within the summative-scale Cr(VI) plume may have an anthropogenic history associated with releases from the Hinkley compressor station, Cr(VI) concentrations less than the UTL 95 values for the various subareas may not require regulatory attention. The regulatory Cr(VI) plume can be updated using the UTL 95 values calculated as part of this study. The updated regulatory Cr(VI) plume extent would lie within the summative-scale Cr(VI) plume extent. The authority to establish regulatory Cr(VI) background values, clean-up goals, and future site management practices resides with the Lahontan Regional Water Quality Control Board.

California

Investigations by the U.S. Geological Survey of soil and moisture conservation on public domain lands, 1941-1964

The passage of the Taylor Grazing Act in 1934 marked the end of an era in the land policies in the United States in that disposal of the public lands by homesteading was terminated except under rigidly prescribed procedures, and the remaining public lands covering about 175 million acres in the western conterminous states were brought under regulatory authority for grazing use. In 1934 the lands were mostly in a severe state of deterioration as a result of overgrazing and drought. In addition to reducing numbers of livestock using the lands, successive programs of conservation practices were established of which the Soil and Moisture Conservation Program of the Department of the Interior is of particular interest here. The services of the Geological Survey, in an investigational and advisory capacity were enlisted in this program. The work of the Geological Survey has consisted of the collection of hydrologic data, investigations of range-water supplies to facilitate management and provide information for design of structures and land-treatment measures. Appraisal of the effects of treatment practices has also been an important activity. Conservation on the public domain involves mainly growing vegetation for forage and reducing erosion. The two elements are intimately related--accomplishment in one is usually reflected by an improvement in the other. Erosion is a serious problem on most of the public domain, but particularly in the Colorado River and Rio Grande basins where, despite low annual water yields, the public domain and similar lands on the Indian reservations contribute the major part of the sediment measured at the downstream gaging stations. In parts of the Missouri River basin also, erosion is obviously very active but the sediment yield contributed by the public domain cannot be as readily isolated. The reasons for the erosion are generally evident--the erodibility of the rock and soils and the sparsity of vegetation as a result of low precipitation, unfavorable soils, or past land use. How much is due to the land use is still controversial, resulting in many questions relative to planning corrective measures. The problem facing the early administrators of the Taylor Grazing Act to bring about proper use and conservation of the public domain was a difficult one because of the lack of records on actual grazing use in animal-unit months of the qualified allottees and the lack of data on treatment practices in an arid area. Reduction of grazing was imperative in some localities, but generally, it could not be brought about as rapidly as it should have been. Numbers of animal units in the grazing districts were reduced from about 3.6 million in 1941 to about 3.2 million in 1964, whereas the areas included in districts was increased about 3 percent. Reductions are still being made in certain areas where deterioration is evident. One of the earliest activities connected with management of the range was the development of water supplies to facilitate the distribution of grazing. The investigations needed for such development formed a large part of the early work in the Soil and Moisture program of the Geological Survey and has continued to be a major activity to the present time. Most of the work has involved investigations of sites for wells but has included also the investigation of proposed spring developments and collection of hydrologic data for use in reservoir design. Well-site investigations have been of two general types: (1) the investigation of a site selected by the land administration agency, and (2) an areal investigation covering entire grazing districts or units thereof. In each type of investigation, a study is made of the geology and the recharge conditions. Reports are prepared giving estimates of the depth of drilling required, the depth to water, the yield, and the quality of the water, together with other information on drilling conditions and developing. Springs are a significant so

Open-File Report

Biodegradation of chlorinated ethenes at a karst site in middle Tennessee

This report presents results of field and laboratory investigations examining the biodegradation of chlorinated ethenes in a karst aquifer contaminated with trichloroethylene (TCE). The study site, located in Middle Tennessee, was selected because of the presence of TCE degradation byproducts in the karst aquifer and available site hydrologic and chlorinated-ethene information. Additional chemical, biological, and hydrologic data were gathered to evaluate whether the occurrence of TCE degradation byproducts in the karst aquifer was the result of biodegradation within the aquifer or simply transport into the aquifer. Geochemical analysis established that sulfate-reducing conditions, essential for reductive dechlorination of chlorinated solvents, existed in parts of the contaminated karst aquifer. Other areas of the aquifer fluctuated between anaerobic and aerobic conditions and contained compounds associated with cometabolism, such as ethane, methane, ammonia, and dissolved oxygen. A large, diverse bacteria population inhabits the contaminated aquifer. Bacteria known to biodegrade TCE and other chlorinated solvents, such as sulfate-reducers, methanotrophs, and ammonia-oxidizers, were identified from karst-aquifer water using the RNA-hybridization technique. Results from microcosms using raw karst-aquifer water found that aerobic cometabolism and anaerobic reductive-dechlorination degradation processes were possible when appropriate conditions were established in the microcosms. These chemical and biological results provide circumstantial evidence that several biodegradation processes are active in the aquifer. Additional site hydrologic information was developed to determine if appropriate conditions persist long enough in the karst aquifer for these biodegradation processes to be significant. Continuous monitoring devices placed in four wells during the spring of 1998 indicated that pH, specific conductance, dissolved oxygen, and oxidation-reduction potentials changed very little in areas isolated from active ground-water flow paths. These stable areas in the karst aquifer had geochemical conditions and bacteria conducive to reductive dechlorination of chlorinated ethenes. Other areas of the karst aquifer were associated with active ground-water flow paths and fluctuated between anaerobic and aerobic conditions in response to rain events. Associated with this dynamic environment were bacteria and geochemical conditions conducive to cometabolism. In summary, multiple lines of evidence developed from chemical, biological, and hydrologic data demonstrate that a variety of biodegradation processes are active in this karst aquifer.

Tennessee