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USGS1985

Electrical geophysical investigations of massive sulfide deposits and their host rocks, West Shasta copper-zinc district

The West Shasta copper-zinc district, Shasta County, California, contains many volcanogenic sulfide deposits within Middle Devonian rhyolites that have not been highly metamorphosed. The district was selected by the U.S. Geological Survey for intensive geological, geochemical, and geophysical study under the Development of Assessment Techniques (DAT) project because accessible exposures have been created by erosion and mining. This report describes the geophysical methods applied to characterize the electrical properties of selected West Shasta massive sulfide deposits and their host rocks, at both small (less than 25 ft) and large (greater than 25 ft) scales. The electrical techniques used galvanic (spectral induced polarization--SIP) and induction (very low frequency--VLF, slingram, and time domain electro-magnetics--TDEM) methods.In situ spectral induced polarization measurements were carried out to determine whether or not conductive anomalies in the district could be differentiated by their polarization signatures. The sulfide, in situ, induced polarization-phase spectral signatures (the induced polarization effect as a function of frequency) have much less character and lack the distinctive shape reported for other massive sulfide deposits; however, they do have some identifiable massive sulfide traits, such as low resistivity and variable polarizability. The nondescript sulfide spectral signature is attributed to the poor development of polarization processes due to a high percentage of resistive, nonpolarizable gangue minerals, lack of pore space, and limited electrolytic fluids. Large-scale spectral induced polarization measurements over the Hornet orebody have a greater polarization than the in situ measurements. This observation, in addition to the fact that much of the Hornet sulfide body has been removed by previous mining activity, suggests that the dominant polarization processes occur at the ground-water-sulfide interface.Combined use of induction techniques, which have different depths of penetration, were used to locate conductive anomalies and determine their shape and depth. All the induction surveys over the Hornet orebody detected the conductive tabular-shaped massive pyritic sulfide deposit hosted in resistive rhyolite. Shallow penetrating induction methods near the Keystone mine detected a conductive fault zone where a block of shale has been downfaulted into volcanic rock. Integrated interpretation of deeper penetrating induction data over this conductive fault zone indicates that parts of the shale are also conductive, demonstrating that the integrated use of several induction methods provides better conductor definition than a single method.

Economic Geology↗

USGS1999

Geology of the Barite Hill gold-silver deposit in the southern Carolina slate belt

Barite Hill is a stratiform gold-silver deposit associated with base metal sulfides and barite in greenschist facies rocks. The deposit, southernmost of four recently mined gold deposits in the Carolina slate belt, is located in the Lincolnton-McCormick district of Georgia and South Carolina, which includes several known gold-silver and base metal deposits in a Kuroko-type geological setting along with deposits of kyanite and manganese. Approximately 1,835,000 g of gold was produced mainly from oxidized ores in the Main and Rainsford pits from 1990 until their closing in 1994. Ore is hosted by sericitically altered felsic metavolcanic and metasedimentary rocks of the Late Proterozoic Persimmon Fork Formation. The deposit is stratigraphically below an overturned contact between upper and lower pyroclastic units, which overlie the Lincolnton metarhyolite, an intrusive unit. Gold-silver-rich zones in the Main pit are partly coincident with lenses of siliceous barite rock, but not confined to them, and occur more commonly in pyrite-quartz-altered fragmental rock. The Main pit ore is stratigraphically overlain by a zone of base metal and barite enrichment, which is, in turn, overlain by a talc-tremolite alteration zone locally. Siliceous barite zones are absent in the Rainsford pit, and gold-silver minerals are associated with silicified rocks and chert. The Barite Hill deposit is interpreted to be the result of Kuroko-type, volcanogenic, base metal sulfide mineralization, followed by gold-silver mineralization under epithermal conditions with the following stages of evolution: (1) massive sulfides, barite, and fine-grained siliceous exhalites were deposited during Late Proterozoic to Cambrian submarine volcanism, which was related to plate convergence and subduction in a microcontinental or island-arc setting distant from the North American continental plate; (2) Au-Ag-Te and base and precious metal Te-Se-Bi minerals were deposited either during waning stages of hydrothermal activity in a failed massive sulfide system or in a separate event; (3) sulfides and silica-barite rock recrystallized during regional deformation and greenschist facies metamorphism related to the Middle to Late Ordovician collision of the Carolina terrane with the North American continental plate; (4) quartz, barite, and gold were remobilized and formed veins that cut across cleavage; (5) orebodies were offset along high-angle faults; and (6) during weathering, base metal sulfides and barite dissolved and reprecipitated as supergene euhedral barite crystals that line ferric iron oxide-hydroxide gossans.

Economic Geology↗

USGS2022

The Coles Hill uranium deposit, Virginia, USA: Geology, geochemistry, geochronology, and genetic model

The Coles Hill uranium deposit with an indicated resource of about 130 million lbs. of U 3 O 8 is the largest unmined uranium deposit in the United States. The deposit is hosted in the Taconian (approximately 480 – 450 Ma) Martinsville igneous complex, which consists of the Ordovician Leatherwood Granite (granodiorite) and Silurian Rich Acres Formation (diorite). The host rock was metamorphosed to orthogneiss during the Alleghanian orogeny (approximately 325 – 260 Ma) when it also underwent dextral strike-slip movement along the Brookneal shear zone. During the Triassic, extensional tectonics led to the development of the Dan River Basin that lies east of Coles Hill. The mineralized zone is hosted in brittle structures in the footwall of the Triassic Chatham fault that forms the western edge of the basin. Within brittle fracture zones, uranium silicate and uranium-bearing fluorapatite with traces of brannerite form veins and breccia fill with chlorite, quartz, calcite, titanium oxide, pyrite, and calcite. Uranium silicates also coat and replace primary titanite, zircon, ilmenite, and sulfides. Sodium metasomatism preceded and accompanied uranium mineralization, pervasively altering host rock, and forming albite from primary feldspar, depositing limpid albite rims on feldspar, altering titanite to titanium oxide and calcite and forming riebeckite. Various geothermometers suggest temperatures of less than approximately ~200°C during mineralization. In situ U-Pb analyses of titanite, Ti-oxide, and apatite, and Rb/Sr and U/Pb isotope-systematics of whole rock samples resolve the timing of geologic processes affecting Coles Hill. The host Leatherwood granite containing primary euhedral titanite is dated at 450 – 445 Ma, in agreement with previously obtained ages from zircon in the Martinsville igneous complex. A regional metamorphic event at 330 – 310 Ma formed anhedral titanite and some apatite, re-equilibrated whole rock Rb/Sr and U-Pb isotopes and is interpreted to have coincided with movement along the Brookneal shear zone. During shearing and metamorphism primary refractory uranium-bearing minerals including titanite, zircon, and uranothorite were recrystallized and uranium was liberated and incorporated locally into hematite, clay, and other fine-grained minerals. Uranium mineralization was accompanied by a metasomatic episode between 250 and 200 Ma that reset the Rb-Sr and U-Pb isotope systems, forming titanite and apatite that are associated and in places intimately intergrown with uranium silicate dating mineralization. This event coincides with rifting that formed the Dan River Basin and was a precursor to the breakup of Pangea. Based on the close spatial and temporal association of uranium with apatite, we conclude that uranium was carried as a uranyl-phosphate complex. The release of calcium during sodium metasomatic alteration of primary calcic feldspar and titanite in the host rock initiated successive reactions in which uranium and phosphate in mineralizing fluids combined with calcium to form U-enriched fluorapatite. Excess uranium was locally reduced by coupled redox reactions involving ferrous iron and sulfide minerals in the host rock, forming uranium silicates. Based on the deposit mineralogy, oxygen isotope geochemistry and trace element characteristics of uranium silicate and gangue minerals the primary mineralizing fluids likely included connate and/or meteoric water sourced from the local Dan River Basin. High heat flow related to Mesozoic rifting may have driven these (P-Na-F-rich) brines through local aquifers and into basin margin faults, transporting uranium from the basin or mobilizing uranium from previously formed U-minerals in the Brookneal shear zone, or from U-enriched older basement rock.

Virginia↗

USGS1959

Geology and uranium-vanadium deposits of the slick rock district, San Miguel and Dolores counties, Colorado

Sedimentary rocks known in the Slick Rock district in southwestern Colorado range in age from Devonian (?) to Cretaceous, and aggregate about 13,000 feet in maximum thickness. Important uranium-vanadium production has come from deposits in the Salt Wash member of the Morrison formation of Late Jurassic age. The sedimentary rocks are gently folded in the Dolores and Glade anticlines and the Disappointment syncline, and are cut by the Dolores fault zone in the north part of the district and by the Glade fault zone in the south part of the district . Principal fracture sets are oriented approximately parallel to the major faults. Detrital hematite, magnetite, and ilmenite in rocks of the Morrison formation not affected by epigenetic alteration contain appreciable amounts of several of the elements found in the ore deposits . Epigenetic alteration processes have bleached large volumes of rock and largely destroyed these minerals. Such alteration is spatially associated with the Dolores fault zone. Most of the known ore deposits are in the north part of the Slick Rock district in a belt called the Dolores ore zone. The zone lies along the Dolores fault zone but is wider than the fault zone. All known deposits are associated with abundant carbonaceous plant material. Uranium-vanadium deposits in the district are chiefly tabular to lenticular and are roughly parallel to the sedimentary bedding. Some ore bodies, however, are narrow, elongate, and curve sharply across bedding; these bodies have been called "rolls" by the miners. Mineral zoning is evident in some roll bodies; carbonates, goethite (altered from pyrite), selenides, and sulfides are commonly found in concentric layers at the concave edge of rolls. This zoning, and the relationship of roll ore bodies to sedimentary structures and lithology, suggest that ore was deposited at an interface between two solutions, possibly cool connate water and a warmer ore solution. On a district scale, copper and lead are distinctly most abundant in the ore deposits within and immediately adjacent to the Dolores fault zone, and less abundant in deposits toward the edge of the zone. Uranium-vanadium deposits in the district occur only in sandstone that is considered to be epigenetically altered, and the most extensive epigenetic changes have occurred close to ore bodies. It is concluded that ground water, heated and set into circulation near the end of Cretaceous time by igneous intrusions in the La Sal and other centers on the Colorado Plateau, picked up elements from sedimentary rocks where they had been faulted and fractured, and deposited the elements at solution interfaces where accumulations of carbonaceous material provided favorable chemical conditions for precipitation.

Colorado, Utah↗

USGS1946

The quartz crystal deposits of western Arkansas

Extensive geological investigations of domestic deposits of quartz crystals were undertaken by the Geological Survey of the United States Department of the Interior in the fall of 1942 in response to the urgent demand for crystals for war purposes. The work was continued throughout 1943 and took survey geologists into some 20 states in which over 1,400 deposits or reports of deposits were examined. Of the numerous highly varied occurrences of quartz examined, only the deposits in western Arkansas, in the Piedmont and Blue Ridge provinces of Virginia, North Carolina and Georgia and the placer quartz of Mokelumne Hill, California, were of sufficient promise to warrant detailed work. Production in 1943 from these areas totaled slightly less than 4 tons of oscillator quartz, over 85 per cent of which came from Arkansas.The Arkansas deposits occur throughout the thick, deformed Paleozoic shales, sandstones, and cherts exposed along the central belt of the Ouachita Mountains. Steeply dipping fractures closely related to the major folds control the deposition of most quartz.Clear quartz is confined largely to the terminal parts of primary crystals, which have developed without disturbance or interference, are commonly elongate parallel to their C axes and are bounded by relatively simple forms. Deposition of silica during and subsequent to the fracturing of crystals resulted in the formation of complex crystals which are characterized by extensive optical twinning and lineage structures, and commonly are bounded by aggregates of the simpler crystal forms. The principal defects in all types of crystals are twinning, smokiness, cavities, solid inclusions and fractures.The Arkansas quartz deposits include veins, sheeted zones and stock-works. They are largely cavity fillings, apparently deposited by rising, attenuated, hydrothermal solutions, at relatively low temperatures and pressures. Minerals associated with the quartz, which constitutes 90 per cent or more of the cavity fillings, include dickite and carbonaceous material, calcite, adularia, and chlorite. The constituents of the cavity fillings could have been derived principally from magmatic sources or more probably from underlying rocks, with small additions from the rocks enclosing the cavities. The complex vein fabrics apparently resulting from intermittent regional deformation during the deposition of the quartz, and certain structural relations of the deposits, indicate that they were formed in the final stages of the Ouachita orogeny, probably in mid-Pennsylvanian time.

Arkansas↗

USGS1994

Geology and geochemistry of Summitville, Colorado: An epithermal acid sulfate deposit in a volcanic dome

Geologic studies during recent open-pit mining at Summitville, Colorado, have provided new information on an epithermal acid sulfate Au-Ag-Cu deposit formed in a volcanic dome. Geologic mapping, geochemical studies of whole-rock samples from blast holes, and geologic and geochemical traverse studies refine the details of the evolution of the Summitville deposit. Six distinct events followed emplacement of the quartz latite volcanic dome and define the development of the Summitville deposit: (1) an early stage of acid sulfate alteration, (2) subsequent Cu sulfide and gold mineralization, (3) widespread hydrothermal brecciation, (4) volumetrically minor, base metal sulfide-bearing barite veining, (5) volumetrically minor, kaolinite matrix brecciation, and finally, (6) supergene oxidation. Events 1 and 2 were the most important for the formation of the Summitville deposit. Acid sulfate altered rock is primarily found in the quartz latite volcanic dome rock and consists of vuggy silica (central), quartz-alunite, quartz-kaolinite, argillic, and propylitic (distal) zones. Ore deposition (event 2) of enargite, luzonite, covellite, pyrite, native sulfur, marcasite, and minor sphalerite, native gold, + or - barite and galena overprinted the acid sulfate altered rocks. Events 3, 4, and 5 are geologically important but rarely formed units large enough to be considered mineable ore by open-pit mining. The final supergene oxidation event affected much of the near-surface portion of the deposit and leached copper and sulfide minerals forming oxide zones. Near-surface oxide zones contain the highest Au grades and decrease progressively with depth.Fractures were important fbr localizing both the acid sulfate altered rock and ore deposition at Summitville. Such fracture control is apparent despite a lack of distinct throughgoing open-space quartz veins; instead, laterally and vertically extensive ore zones are identified by their highly silicified character that can be traced laterally for up to 500 m and vertically up to 200 m. Ore zones strike parallel to regional faults related to rifting and basin and range development, suggesting that hydrothermal fluids followed preexisting fractures. Ore zones follow two northwest trends, a N 30 degrees W + or - 20 degrees trend, and a N 60 degrees W trend. Most fractures and faults in the open pit dip steeply from 65 degrees to vertical. Ore zones intersect near the center of the deposit to form a large zone approximately 150 by 400 m. Ore zones form a rough radial pattern located near the center of the deposit and a discontinuous arcuate feature on the northern side. This radial pattern, arcuate feature, and the intersection of ore zones near the center of the deposit are probably related to the intrusion of a porphyry below the deposit. The overall low Au-grade, high-tonnage character of the Summitville deposit is related to low permeability in the quartz latite volcanic dome rock and absence of well-developed open-space hydrothermal veins.Gold analyses of development drill holes and blast hole samples, in conjunction with geologic mapping in the open pit, indicate that vuggy silica, quartz-alunite, and quartz-kaolinite altered rock constitute most of the Au ore. Vuggy silica averaged 2.4 ppm Au, quartz-alunite averaged 1.2 ppm Au, and quartz-kaolinite averaged 0.86 ppm Au during open-pit mining. Grades for argillically altered rock were usually below the ore cutoff of 0.34 ppm Au. Propylitically altered rock rarely contained detectable Au concentrations (0.03 ppm Au) and constituted only waste rock. Although volumetrically minor, event 4 base metal sulfide-bearing barite veins and event 5 kaolinite matrix breccias contained high Au grades (up to about 800 ppm Au), producing approximately 5 to 15 percent of the total Au mined in the deposit.Geochemical studies of samples collected across traverses of altered and mineralized ore zones indicate that Te, Bi, and Pb are characteristic trace elements, in addition to Au, Ag, Cu, and As that are typical of acid sulfate mineral deposits. Anomalous Te is associated with Cu sulfides and gold in vuggy silica zones. Anomalous Bi and Pb concentrations correlate most consistently with quartz-alunite zones. Thallium is also anomalous at Summitville. Highest concentrations of Tl are found in argillic rock, whereas silicified zones are depleted in it. The anomalous Tl in distal zones is similar to observations in some porphyry Cu systems. Pronounced lateral zonation of Ag/Au ratios is present in the deposit. The Ag/Au ratios vary from about 2:1 near the center of the orebody to greater than 20:1 on the periphery.The Summitville deposit is located in the midlevel portion of a mineralized volcanic dome, with a porphyry system at depth, and a hot springs environment at the surface. Drill holes through the volcanic dome intersected a quartz monzonite porphyry approximately 600 m below the surface that is altered to sericite and pyrite similar to some porphyry deposits. Laterally extensive cristobalite and opal replacing quartz latite are found southwest of the deposit and represent a hot-spring environment. Bedded siliceous sinter, some of which contains plant debris, overlies the cristobalite and opal at some localities. These deposits may represent surface vents for the fluids responsible for acid sulfate alteration or mineralization of the volcanic dome.

Economic Geology↗

USGS2004

Nature of hydrothermal fluids at the shale-hosted Red Dog Zn-Pb-Ag deposits, Brooks Range, Alaska

The Red Dog Zn-Pb-Ag district in the western Brooks Range, northern Alaska, contains numerous shale-hosted Zn-Pb sulfide and barite deposits in organic-rich siliceous mudstone and shale, chert, and carbonate rocks of the Carboniferous Kuna Formation. The giant Red Dog shale-hosted deposits consist of a cluster of four orebodies (Main, Qanaiyaq, Aqqaluk, and Paalaaq) that lie within distinct thrust panels that offset a single ore deposit during the Mesozoic Brookian orogeny. These Zn-Pb-Ag-barite orebodies contain one of the world's largest reserves and resources of zinc. Fluid inclusions in samples of vein sphalerite, which accounts for about 20 percent of the ore in the Main deposit, and quartz that composes the bulk of the extensive silicification in the ore deposit, were studied by microthermometry, Raman spectrometry, and ion chromatography. The study of fluid inclusions in the vein sphalerite was limited by the intense postore deformation of the ore deposits. However, four primary aqueous fluid inclusion assemblages in vein sphalerite yield temperatures of homogenization of 115° to 120°C, 123° to 127°C, 110° to 120°C and 175° to 180°C. More abundant final-melting temperatures indicate that the fluid inclusions in sphalerite have salinities of about 14 to 19 wt percent NaCl equiv. The fluid inclusion electrolyte data show that the ore fluid responsible for the vein sphalerite derived its salinity from the evaporation of seawater. Considering the salinity of the fluid inclusions together with the electrolyte data, it is possible that the evaporative brine was initially about 30 wt percent saline fluid and that it mixed with a more dilute fluid somewhere along its flow path. The temperature, salinity, and electrolyte composition of vein sphalerite in the Red Dog deposits are remarkably similar to those characteristics in sphalerite veins near the Century zinc deposit, Australia. Together, these data compose the majority of information on the temperature and composition of sphalerite in deposits of this type. On the basis of data describing fluid inclusions in sphalerite and the geologic setting of the ore deposits, a "reflux brine" model is suggested for the Red Dog deposits. In this model, brines were produced in evaporative environments in supratidal carbonate facies of the Lisburne Group less than 100 km from the Red Dog deposits. These reflux brines may have infiltrated the underlying rocks of Endicott Group or fractured metasedimentary basement rocks. In the absence of a local heat source at the Red Dog deposits, the temperature of the ore fluids (~100° to <200°C) requires that the fluids circulated at depths between ~ 2.4 and 7.4 km. In the Red Dog area, the metalliferous fluids ascended into the organic-rich rocks of the Kuna Formation, probably along zones of active extensional faults or breaches in the shale aquitards overlying the aquifers in the Endicott Group. Fluid inclusions were also studied in the abundant quartz that constitutes the majority of the silica rock in the ore deposits. This postore quartz extensively replaced barite and was traditionally thought to be part of the main ore event. Primary fluid inclusion assemblages contain two-phase aqueous inclusions, single-phase inclusions of dense methane, or both. Primary assemblages that contain single-phase, dense-methane inclusions together with two-phase aqueous inclusions yield consistent homogenization temperatures that provide unequivocal evidence for the coeval trapping of immiscible gas and aqueous fluids. The densities of the methane inclusions, together with the temperature of homogenization of coexisting aqueous fluid inclusions, show that these fluid inclusions were trapped between pressures of 800 and 3,400 bars and temperatures between 187° and 214°C. The pressures obtained provide unequivocal evidence that the quartz formed after ore deposition in the Carboniferous because such high fluid pressures could only have been produced from thrust loading during the Mesozoic Brookian orogeny. The observed large variation in pressure is best explained by transient fluid pressures from hydrostatic to lithostatic conditions during thrust loading. The 3,400 bars pressure corresponds with about 12 km of lithostatic burial, whereas the lower pressures (800 bars) correspond with about 8 km of hydrostatic pressure. Because of their low salinity (0-5 wt % NaCl equiv) the electrolyte compositions of the quartz fluid inclusions do not constrain their origin.

Alaska↗

USGS1959

Ground-water provinces of India

This paper gives a general resume of ground-water utilization and development and describes the occurrence of water in eight ground-water provinces of India. The paper is based in part on observations of the writer during 1951-55 and in part on earlier work of the Geological Survey of India. Ground water has been utilized extensively in India since before the beginning of the Christian era. Currently (1956) ground water is an important source of supply for domestic, stock, municipal, and industrial needs throughout the Republic and is widely used for irrigation in the Peninsular and Ganges-Brahmaputra regions west of longitude 85°. Dug, bored, and drilled wells are the principal means by which ground water is developed, although locally infiltration tunnels or improved springs are used. Methods of lifting or pumping water from wells include the hand line and bucket, the hand-lift pump, the counterpoised sweep, bullocks, and "mote," the water wheel, horizontal and vertical centrifugal pumps, and deep-well turbine pumps. The most common device for lifting water for irrigation is still the time-honored bullock and "mote" (leather bag). However, in modern India there is increasing use of mechanical pumps. With respect to the occurrence of ground water, India can be divided into eight provinces, lying in three major regions, (1) the Peninsular region, (2) the Ganges-Brahmaputra region, and (3) the Himalayan region. The Peninsular region contains six ground-water provinces. Precambrian igneous, metamorphic, and indurated sedimentary rocks and early Tertiary volcanic rocks in three of these provinces yield many small supplies of water, which generally is of good quality but locally is brackish or salty. Cretaceous water-bearing sandstones in another province are moderately productive and in places are developed for large water supplies. Late Tertiary and Quaternary water-bearing sands and gravels in two other provinces sustain many small water supplies and several large water supplies-particularly in the coastal areas of southern India. The Ganges-Brahmaputra region is a single ground-water province in which many tens of thousands of small water supplies and several thousand large supplies are obtained from water-bearing sands and gravels in late Tertiary and Quaternary alluvium. This province constitutes a vast groundwater reservoir, which is the most productive in India. The Himalayan region also is considered as a single province, in which ground water occurs in a series of narrow valleys filled with moderately to highly permeable Quaternary alluvium. These alluvial valleys transmit large quantities of water to the ground-water reservoir in the Ganges-Brahmaputra region.

Economic Geology↗

USGS1952

Geology of the Iron King Mine, Yavapai county, Arizona

The Iron King mine is about 2,000 feet west-northwest of the intersection of the 112 15 west meridian and the 34 30 north parallel in the Humboldt region in central Yavapai County , Arizona . The mine is approximately in the geographical center of the Humboldt region. Precambrian rocks form the bedrock. Late Cenozoic unconsolidated river wash and valley fill with some interbedded basalt locally mantle the Precambrian rocks, especially in the north-central part of the region. The Precambrian rocks consist of two metamorphosed volcanic formations and intrusive rocks that range in composition from quartz porphyry to gabbro. The volcanic formations originally were flows, volcanic breccias, and tuffaceous sedimentary rocks. Dynamothermal metamorphism of these rocks formed textures, structures, and mineral assemblages characteristic of low-grade ;riietamorphic rocks, but sufficient relict textures and structures remain to permit delineation of formations on the bases of their original nature. All the Precambrian rocks are foliated, except those in the interior parts of the larger intrusive masses. This foliation has two major trends, (1) north to N 20° W, and (2) N 20° E. The northeast-trending foliation is younger and locally is superimposed on the north- to northwest-trending foliation. The Precambrian rocks strike north to northwest and dip steeply, chiefly westward. Duplication of stratigraphic units and determination of tops suggest two major northeast-trending folds, which probably plunge southward. The northeast-trending foliation appears to bear an axial-plane relationship to these folds. Some masses of igneous rock probably were intruded during development of foliation. The Iron King deposit supports the only active mine in the Humboldt region. It consists of 12 steeply plunging echelon veins arranged along the footwall of a sheared and altered zone in the metamorphosed andesitic tuffaceous sedimentary rocks. Narrow zones of more intense shear probably localized the veins. Solutions first introduced quartz, pyrite, ankerite, and sericite, forming a sporadically mineralized zone (in the hanging wall of the deposit) and probably veins in the Iron King fracture system. Intra-mineralization shear strongly brecciated these early minerals and formed the structures that localized and distributed the ore minerals in the veins. After this deformation, sphalerite, galena, chalcopyrite, tennantite, arsenopyrite, pyrite, quartz, and ankerite were deposited; the last three minerals may have formed through solution and the redeposition of earlier minerals. Formation of sericite either accompanied or followed the deposition of ore-forming minerals. Silver is related closely in distribution to copper and probably is in the tennantite. Gold occurs chiefly in the pyrite. Banding, mimetic after foliation and planes developed by shearing, is pronounced in much of the vein material. Mineral zoning, generally similar in each vein, is a characteristic of the deposit. High-angle reverse faults of about 100 feet in maximum vertical separation offset the veins. These faults are nearly parallel to the veins in strike and dip.

Arizona↗

USGS1992

Hydrothermal ore-forming processes in the light of studies in rock- buffered systems: II. Some general geologic applications

The experimental metal solubilities for rock-buffered hydrothermal systems, reported by Hemley et al. (1992), provide important insights into the acquisition, transport, and deposition of metals in real hydrothermal systems that produced base metal ore deposits. Water-rock reactions that determine pH, together with total chloride and changes in temperature and fluid pressure, play significant roles in controlling the solubility of metals and determining where metals are fixed to form ore deposits.Hydrothermal systems circulate fluids and heat, and the transport path of a hydrothermal fluid is likely to lie somewhere between an adiabatic (no heat loss to adjacent rocks) and a geothermal (complete thermal equilibrium with adjacent rock) path. The transport path of the hydrothermal fluids emanating from, or circulating near, deep-seated crystallizing plutons can be approximated by a quasi-adiabatic pressure-temperature path. In such a quasi-adiabatic setting, the pressure effect on rock-buffered metal solubilities is significant and allows metal transport over long distances because the trend of decreasing metal solubility with decreasing temperature is compensated by the trend of increasing metal solubility with decreasing pressure. The high-temperature portion of a quasi-adiabatic hydrothermal system will tend to leach metals from the rock and fix K and Na in feldspars. The source of the extracted metals may be late-stage magmatic melt, trace metals distributed in the lattice of silicate minerals destroyed during rock metasomatism, and/or small amounts of base metal sulfides disseminated throughout a given rock.Deposition of metals in hydrothermal systems occurs where changes such as cooling, pH increase due to rock alteration, boiling, or fluid mixing cause the aqueous metal concentration to exceed saturation. Relative metal transport concentrations, the availability of sulfur, the disposition of the saturation surfaces relative to each other, and the interplay of these variables through time are the major factors controlling the pattern of metal deposition (and nondeposition).Metal zoning results from deposition occurring at successive saturation surfaces. Zoning is not a reflection simply of relative solubility but of the manner of intersection of transport concentration paths with those surfaces. The experimental results are consistent with the typical outward zonation of Cu-Zn-Pb observed in porphyry coppers, Butte-type base metal vein deposits, skarns, and massive sulfides. Implications to mineralization patterns in Mississippi Valley-type, sedimentary Cu, and other low-temperature deposits are also of interest, with due recognition of the greater uncertainty regarding speciation and attainment of equilibrium in those environments. In such deposits, a probable outward zoning of Cu-Zn-Pb-Fe is suggested from the results.Saturation surfaces will tend to migrate outward and inward in prograde and retrograde time, respectively, controlled by either temperature or chemical variables. This, in turn, gives rise to zone migration and, where one zone encroaches on another, the appropriate apparent paragenetic relations. Such textural implications are incorrect, however, unless viewed within the context of the overall mineralization process. Additional controls bearing on metal precipitation sequence and coprecipitation, the presence or absence of zoning, reversals in zoning, sulfidation state, and timing relations between alteration and metallization are implicit in the results and are discussed.

Economic Geology↗

USGS2009

Ultra-deep oxidation and exotic copper formation at the late pliocene boyongan and bayugo porphyry copper-gold deposits, surigao, philippines: Geology, mineralogy, paleoaltimetry, and their implications for Geologic, physiographic, and tectonic controls

The Boyongan and Bayugo porphyry copper-gold deposits are part of an emerging belt of intrusion-centered gold-rich deposits in the Surigao district of northeast Mindanao, Philippines. Exhumation and weathering of these Late Pliocene-age deposits has led to the development of the world's deepest known porphyry oxidation profile at Boyongan (600 m), and yet only a modest (30-70 m) oxidation profile at adjacent Bayugo. Debris flows, volcanic rocks, and fluviolacustrine sediments accumulating in the actively extending Mainit graben subsequently covered the deposits and preserved the supergene profiles. At Boyongan and Bayugo, there is a vertical transition from shallower supergene copper oxide minerals (malachite + azurite + cuprite) to deeper sulfide-stable assemblages (chalcocite ?? hypogene sulfides). This transition provides a time-integrated proxy for the position of the water table at the base of the saturated zone during supergene oxidation. Contours of the elevation of the paleopotentiometric surface based on this min- eralogical transition show that the thickest portions of the unsaturated zone coincided with a silt-sand matrix diatreme breccia complex at Boyongan. Within the breccia complex, the thickness of the unsaturated zone approached 600 in, whereas outside the breccia complex (e.g., at Bayugo), the thickness averaged 50 m. Contours of the paleopotentiometric surface suggest that during weathering, groundwater flowed into the breccia complex from the north, south, and east, and exited along a high permeability zone to the west. The high relief (>550 m) on the elevation of the paleopotentiometric surface is consistent with an environment of high topographic relief, and the outflow zone to the west of the breccia complex probably reflects proximity to a steep scarp intersecting the western breccia complex margin. Stable isotope paleoaltimetry has enabled estimation of the elevation of the land surface, which further constrains the physiographic setting during supergene oxidation. Isotopic measurements of oxygen in supergene kaolinite from Boyongan suggest that local paleometeoric water involved in weathering had a ??180 composition of approximately -5.7 per mil. At the latitude of the southern Philippines, this value corresponds to Pleistocene rain water condensing at elevations between 750 and 1,050 m above contemporary sea level, providing a maximum estimate for the surface elevation during weathering of the porphyry systems. Physiographic reconstuctions suggest that the deep oxidation profile at Boyongan formed in an environment of high topographic relief immediately east of a prominent (>550 m) escarpment. The high permeability contrast between the breccia complex and the surrounding wall rocks, coupled with the proximity of the breccia complex to the escarpment, led to a depressed groundwater table and a vertically extensive unsaturated zone in the immediate vicinity of Boyongan. This thick vadose zone and the low hypogene pyrite/copper sulfide ratios (0.6) at Boyongan promoted in situ oxidation of copper sulfides with only modest (<200 m) supergene remobilization of copper. In contrast, higher hypogene pyrite/chalcopyrite ratios (2.3) at Bayugo led to greater acid production during weathering and more complete leaching of copper above the base of oxidation. This process promoted significant (600 m) lateral dispersion of copper down the paleohydraulic gradient into the diatreme breccia comple, ultimately leading to the formation of an exotic copper deposit. ?? 2009 Society of Economices Geologists, Inc.

Economic Geology↗

USGS2003

Geology and geochemistry of the Reocín zinc-lead deposit, Basque-Cantabrian Basin, Northern Spain

The Reocín Zn-Pb deposit , 30 km southwest of Santander, Spain , occurs within Lower Cretaceous dolomitized Urgonian limestones on the southern flank of the Santillana syncline. The Reocín deposit is one of the largest known strata-bound, carbonate-hosted, zinc - lead deposits in Europe. The total metal endowment of the deposit , including past production and remaining reserves, is 62 Mt of ore grading 8.7 percent Zn and 1.0 percent Pb. The epigenetic mineralization consists of sphalerite and galena, with lesser marcasite and trace pyrite with dolomite as gangue. Microprobe analyses of different generations of dolomite revealed nonstoichiometric compositions with various amounts of iron (up to 14 mol % of FeCO 3 ). Replacement of host dolomite, open-space filling of fractures, and cementation of breccias derived from dissolution collapse are the principal types of ore occurrence. Detailed cross-section mapping indicates a stratigraphic and structural control on the deposit . A stratiform morphology is present in the western part of the orebody (Capa Sur), whereas mineralization in the eastern part is highly discordant but strata bound (Barrendera). Stratigraphic studies demonstrate that synsedimentary tectonic activity, related to the rifting of the North Atlantic (Bay of Biscay), was responsible for variation in sedimentation, presence of unconformities (including paleokarsts), local platform emergence and dolomitization along the N60 fault trend. In the Reocín area, two stages of dolomitization are recognized. The first stage is a pervasive dolomitization of the limestone country rocks that was controlled by faulting and locally affected the upper part of the Aptian and the complete Albian sequence. The second dolomitization event occurred after erosion and was controlled by karstic cavities. This later dolomitization was accompanied by ore deposition and, locally, filling of dolomite sands and clastic sediments in karstic cavities. The circulation of hydrothermal fluids responsible for sulfide deposition and the infilling of karst cavities were broadly contemporaneous, indicating a post-Albian age. Vitrinite reflectance data are consistent with previously measured fluid inclusion temperatures and indicate temperatures of ore deposition that were less than 100°C. Carbon and oxygen isotopic data from samples of regional limestone, host-rock dolostone and ore-stage dolomite suggest an early hydrothermal alteration of limestone to dolostone. This initial dolomitization was followed by a second period of dolomite formation produced by the mixing of basinal metal-rich fluids with local modified seawater. Both dolomitization events occurred under similar conditions from fluids exhibiting characteristics of basinal brines. The δ 34 S values of sulfides are between -1.8 and +8.5 per mil, which is consistent with thermochemical sulfate reduction involving organic matter as the main source of reduced sulfur. Galena lead isotope compositions are among the most radiogenic values reported for Zn-Pb occurrences in Europe, and they are distinct from values reported for galena from other Basque - Cantabrian deposits. This suggests that a significant part of the lead was scavenged from the local underlying Asturian sediments. The stratigraphic and structural setting, timing of epigenetic mineralization, mineralogy, and isotopic geochemistry of sulfide and gangue minerals of the Reocín deposit are consistent with the features of most of Mississippi Valley-type ore deposits.

northern Spain↗

USGS2002

SHRIMP U-Pb and 40Ar/39Ar age constraints for relating plutonism and mineralization in the Boulder batholith region, Montana

The composite Boulder batholith, Montana, hosts a variety of mineral deposit types, including important silver-rich polymetallic quartz vein districts in the northern part of the batholith and the giant Butte porphyry copper-molybdenum pre-Main Stage system and crosscutting copper-rich Main Stage vein system in the southern part of the batholith. Previous dating studies have identified ambiguous relationships among igneous and mineralizing events. Mineralizing hydrothermal fluids for these types of deposits and magma for quartz porphyry dikes at Butte have all been considered to be late-stage differentiates of the Boulder batholith. However, previous dating studies indicated that the Boulder batholith plutons cooled from about 78 to 72 Ma, whereas copper-rich Main Stage veins at Butte were dated at about 61 Ma. Recent efforts to date the porphyry copper-molybdenum pre-Main Stage deposits at Butte resulted in conflicting estimates of both 64 and 76 Ma for the mineralizing events. Silver-rich polymetallic quartz vein deposits elsewhere in the batholith have not been dated previously. To resolve this controversy, we used the U.S. Geological Survey, Stanford, SHRIMP RG ion microprobe to date single-age domains within zircons from plutonic rock samples and 40 Ar/ 39 Ar geochronology to date white mica, biotite, and K-feldspar from mineral deposits. U-Pb zircon ages are Rader Creek Granodiorite, 80.4 ± 1.2 Ma; Unionville Granodiorite, 78.2 ± 0.8 Ma; Pulpit Rock granite, 76.5 ± 0.8 Ma; Butte Granite, 74.5 ± 0.9 Ma; altered Steward-type quartz porphyry dike (I-15 roadcut), 66.5 ± 1.0 Ma; altered Steward-type quartz porphyry dike (Continental pit), 65.7 ± 0.9 Ma; and quartz monzodiorite of Boulder Baldy (Big Belt Mountains), 66.2 ± 0.9 Ma. Zircons from Rader Creek Granodiorite and quartz porphyry dike samples contain Archean inheritance. The 40 Ar/ 39 Ar ages are muscovite, silver-rich polymetallic quartz vein (Basin district), 74.4 ± 0.3 Ma; muscovite, silver-rich polymetallic quartz vein (Boulder district), 74.4 ± 1.2 Ma; muscovite, early dark micaceous vein (Continental pit), 63.6 ± 0.2 Ma; biotite, early dark micaceous vein (Continental pit), 63.6 ± 0.2 Ma; potassium feldspar, early dark micaceous vein (Continental pit), 63 to 59 Ma; and biotite, biotite breccia dike (Continental pit), 63.6 ± 0.2 Ma. Outlying silver-rich polymetallic quartz veins of the Basin and Boulder mining districts probably are directly related to the 74.5 Ma Butte Granite, whereas Steward-type east-west quartz porphyry dikes and Butte pre-Main Stage deposits are parts of a 66 to 64 Ma magmatic-mineralization system unrelated to emplacement of the Boulder batholith. The age of the crosscutting Main Stage veins may be about 61 Ma as originally reported but can only be bracketed as younger than the 64 Ma pre-Main Stage mineralization and older than the about 50 Ma Eocene Lowland Creek intrusions. The 66 Ma age for the quartz monzodiorite of Boulder Baldy and consideration of previous dating studies in the region indicate that small ca. 66 Ma plutonic systems may be common in the Boulder batholith region and especially to the east. The approximately 64 Ma porphyry copper systems at Butte and gold mineralization at Miller Mountain are indicative of regionally important mineralizing systems of this age in the Boulder batholith region. Resolution of the age and probable magmatic source of the Butte pre-Main Stage porphyry copper-molybdenum system and of the silver-rich polymetallic quartz vein systems in the northern part of the Boulder batholith documents that these deposits formed from two discrete periods of hydrothermal mineralization related to two discrete magmatic events.

Montana↗

USGS1986

The Schwarzwalder uranium deposit, III: Alteration, vein mineralization, light stable isotopes, and genesis of the deposit

The Schwartzwalder uranium deposit formed at 69.3 + or - 1.1 m.y. in a complex fracture system during the inception of Laramide uplift of the Front Range in Colorado. Geologic and isotopic evidence demonstrates that the ore-forming fluids were in chemical equilibrium with the Proterozoic metavolcanic and metasedimentary host-rock terrane at depth and that the metals, sulfur, and carbonate deposited in the fractures were derived from the metamorphic rocks. The data are not consistent with chemical contributions from an unrecognized magma or from the overlying Phanerozoic sedimentary rocks. The protoliths for the metamorphic rocks were submarine volcanic rocks and related volcanogenic exhalative iron-formations and chert. Water trapped along the basement faults and in the regolith between the basement and the overlying Paleozoic sedimentary rocks interacted with the metavolcanic rocks to produce isotopically heavy fluids containing high concentrations of dissolved metals and carbonate. Calculated delta 18 O values for this fluid range from 4.3 to 8.2 per mil, indicating a low water/rock ratio in the source terrane.Two stages of alteration and three stages of vein mineralization are recorded in the Schwartzwalder deposit. At the onset of Laramide faulting, fluids migrated along the fracture systems to zones of low hydraulic potential. These fluids contained CO 2 and had a metastably large K/Na ratio; they altered the gneissic wall rocks to a carbonate-sericite assemblage, adding K (super +) and CO 2 and removing SiO 2 with little or no change in volume. As the fractures continued to open, CO 2 was evolved from the fluids, increasing the pH and superimposing a hematite-adularia alteration assemblage on the earlier alteration.The veins record three stages of mineralization, the second of which generated the high-grade uranium veins. Evidence for the stage I sulfide-carbonate mineralization is poorly preserved, but isotopic and temperature data from this stage are consistent with a trend in fluid composition culminating in stage II pitchblende deposition. Sudden, large movements along the faults caused episodic evolution of CO 2 from the fluid. This loss of CO 2 decreased the solubilities of carbonates and adularia and the stabilities of sulfur species in solution. Uranyl carbonate complexes dissociated and sulfur species in solution likely reduced the uranyl ions to produce stage II pitchblende. Carbonate, adularia, and sulfides dominated the vein mineralogy after deposition of pitchblende. Progressively lower delta 18 O values in vein carbonates suggest the mixing of cooler, less evolved, perhaps meteoric, waters during the later stages of mineralization. However, the fluid pressure remained high, as indicated by explosion breccias and inward collapse features which formed as fault movements produced sudden decreases in the confining pressure. Only the stage III carbonate-iron disulfide assemblage in the major postore segment of the Illinois fault may be the product of meteoric water alone.

Economic Geology↗

USGS1994

Fluid chemistry evolution and mineral deposition in the main-stage Creede epithermal system

This paper presents results of chemical speciation and reaction path calculations that model fluid chemistry evolution and ore deposition in the main-stage Creede, Colorado, epithermal system. An extensive geologic, mineralogic, and geochemical framework for mineralization has been developed by many researchers for the central and southern district vein systems (OH and P veins; central and southern Amethyst and Bulldog Mountain vein systems) and is used to constrain and guide the modeling presented in this paper. Previous studies have shown that the central base metal sulfide-rich and southern barite- and silver-rich Creede ores were deposited by hydrothermal brines with temperatures as high as 285 degrees C and salinities as high as 13 wt percent NaCl equiv. Fluid inclusion studies indicate that mixing with dilute steam-heated ground waters was the dominant ore deposition mechanism, although boiling did occur during some stages. Speciation calculations confirm that the hydrothermal fluids, due to their high salinities, were relatively acidic (pH near 5.5) and transported significant quantities of base metals (i.e., up to 10-2 m total concentrations of Zn) as chloride complexes. Reaction path calculations show that strong north-south mineralogical variations in main-stage mineralization are best accounted for by variable boiling of the hydrothermal brines, followed by lateral mixing of the brines with overlying dilute, steam-heated ground waters. The extent of boiling prior to mixing was a function of the temperature and gas contents of the hydrothermal fluids as they first entered the district ore zones from depth, and of the thickness of the steam-heated ground-water column overlying the hydrothermal fluids. The calculations indicate that limited amounts of boiling (during stages when the overlying ground-water column was relatively thick) produced a chlorite-pyrite-hematite-sphalerite-galena-chalcopyrite + or - adularia assemblage in the central district vein systems (OH and P veins; central Amethyst and Bulldog Mountain vein systems). More extensive boiling (during a stage in which the ground-water table apparently dropped considerably) deposited quartz, fluorite, adularia, and hematite with only minor sulfides in the central district veins. Boiling ceased when the saturation pressure of the hydrothermal fluids dropped below hydrostatic pressures generated by the overlying ground-water column. Following boiling, lateral mixing with overlying steam-heated ground waters initially produced sphalerite- and galena-rich assemblages in the central district vein systems. With continued mixing to the south, the hydrothermal fluids deposited abundant barite, subordinate sphalerite, galena, and quartz, and lesser native silver, acanthite, and sulfosalts in the district's southern vein systems (southern Amethyst, southern Bulldog Mountain vein systems).Modeling results for Creede and other epithermal fluid compositions show that epithermal ore grades, mineral assemblages, and mineral zoning patterns are strongly influenced by shallow hydrologic processes such as boiling and fluid mixing. As a result, epithermal mineral assemblages and zoning patterns can be used to reconstruct the paleohydrology of the hydrothermal systems from which they were deposited, and thus provide useful tools for epithermal ore exploration.

Economic Geology↗

USGS1993

Geology and genesis of the Baid Al Jimalah tungsten deposit, Kingdom of Saudi Arabia

The Baid al Jimalah tungsten deposit in Saudi Arabia (lat 25 degrees 09'N, long 42 degrees 41'E) consists predominantly of swarms of steeply dipping, subparallel, tungsten-bearing quartz veins and of less abundant, smaller stockwork veins. It is spatially, temporally, and genetically associated with a 569 Ma, highly differentiated, porphyritic, two-feldspar granite that intrudes Late Proterozoic immature sandstones.Paragenetic data from crosscutting veins demonstrate unambiguously a single cycle of magma intrusion and hydrothermal mineralization. Hypogene mineralization can be divided into three periods: (1) early quartz-molybdenite stockwork veining, (2) wolframite- and scheelite-bearing, greisen-bordered veining, and (3) late, quartz-carbonate-fluorite veining. The first two of these three periods can be further divided into several stages that are transitional to each other. The greisen-bordered veins, in particular, show replacement of earlier mineral assemblages by later ones. Precious and base metal veins at Baid al Jimalah East, approximately 1.5 km east of the Baid al Jimalah tungsten deposit, are genetically related to the tungsten deposit and probably formed contemporaneously with the greisenized tungsten-bearing veins.Fluid inclusion and oxygen isotope data indicate that the Baid al Jimalah deposit formed over a temperature range of 120 degrees to 550 degrees C, from low salinity magmatic and metamorphic fluids, and at a depth of about 4.2 km. Early stockwork veins (period 1) formed at low magmatic temperatures (ca. 550 degrees C) from magma-derived (delta 18 O = 9.6-9.7ppm), low-salinity (1-2 wt % NaCl equiv) fluid. This hydrothermal fluid was generally low density and CO 2 rich. All other veins were formed from regionally derived fluid in equilibrium with metamorphic rocks (delta 18 O = 7.9 + or - 1.0ppm at the site of deposition). This fluid probably scavenged most of the period 2 ore-mineral components from a postulated granite batholith whose existence is indicated by a 6-mGal gravity low centered on the deposit. The greisen-bordered tungsten veins (period 2) formed from fluids in the liquid state at temperatures mostly between 380 degrees and 440 degrees C with salinities between 4.5 and 10.9 wt percent NaCl equiv. Late, barren veins (period 3) formed from liquids with salinities between 0.0 and 3.5 wt percent NaCl equiv at temperatures as low as 120 degrees C. The veins at Baid al Jimalah East formed from liquids with salinities between 0 and 4.2 wt percent NaCl equiv at temperatures mostly between about 340 degrees and 390 degrees C. Important volatile constituents in some hydrothermal fluids were CO 2 and CH 4 , in addition to H 2 O and HF. The delta 18 O data on mineral separates of fresh and altered Bald al Jimalah granite, and whole-rock delta 18 O data on country-rock samples as far as 16 km from the deposit, indicate that the rocks in the Bald al Jimalah area were pervasively infiltrated by a fluid with relatively high delta 18 O values. Interaction and exchange of the country rocks with this delta 18 O fluid led to an increase in the delta 18 O values of volcanic rocks of the Jurdhawiyah Group but to a decrease in the delta 18 O values of the high value delta 18 O Murdama Group sandstones, resulting in a hydrothermal anomaly exceeding 100 km 2 in area. This fluid had an estimated delta 18 O value of about 6 to 8 per mil, essentially identical to that of the metamorphic water calculated from the vein quartz, thus strongly supporting the conclusion that all of the mineral deposits at Baid al Jimalah (except for the early-stage quartz-molybdenite veins), as well as the 12-km 2 geochemical anomaly surrounding the deposit, were from the same metamorphic fluid.Bald al Jimalah is similar in character and origin to Phanerozoic tungsten-tin greisen deposits throughout the world, especially the Hemerdon deposit in Devon, England. It is also analogous to Climax-type molybdenum deposits, which contain virtually identical mineral assemblages, but with the relative proportions of molybdenum and tungsten mineralization reversed, primarily owing to differences in oxygen fugacity. This similarity in mineralization styles and fluid histories indicates that metallogenic processes in granite-related deposits in the late Precambrian were similar to those seen in the Phanerozoic.

Economic Geology↗

USGS2003

Geologic setting and genesis of the Mule Canyon low-sulfidation epithermal gold-silver deposit, north-central Nevada

The Mule Canyon mine exploited shallow, low - sulfidation , epithermal Au-Ag deposits that lie near the west side of the Northern Nevada rift in northern Lander County, Nevada . Mule Canyon consists of six small deposits that contained premining reserves of about 8.2 Mt at an average grade of 3.81 g Au/tonne. It is an uncommon mafic end member of low - sulfidation Au-Ag deposits associated with tholeiitic bimodal basalt-rhyolite magmatism. The ore is hosted by a basalt-andesite eruptive center that formed between about 16.4 to 15.8 Ma during early mafic eruptions related to regionally extensive bimodal magmatism. Hydrothermal alteration and Au-Ag ores formed at about 15.6 Ma and were tightly controlled by north -northwest- to north -striking high-angle fault and breccia zones developed during rifting, emplacement of mafic dikes, and eruption of mafic lava flows. Hydrothermal alteration assemblages are zoned outward from fluid conduits in the sequence silica-adularia, adularia-smectite, smectite (intermediate argillic), and smectite-carbonate (propylitic). All alteration types contain abundant pyrite and/or marcasite ± arsenopyrite. Field relations indicate that silica-adularia alteration is superimposed on argillic and propylitic alteration. Little or no steam-heated acid-sulfate alteration is present, probably the result of a near-surface water table during hydrothermal alteration and ore deposition. Two distinct ore types are present at Mule Canyon : early replacement and later open-space filling. Replacement ores consist of disseminated and vesicle-filling pyrite, marcasite, and arsenopyrite in argillically altered or weakly silicified rocks. Ore minerals consist of Au-bearing arsenopyrite and arsenian pyrite overgrowths on earlier-formed pyrite and marcasite. Open-space filling ores include narrow stockwork quartz-adularia veins, banded and crustiform opaline and chalcedonic silica-adularia veins, silica-adularia cemented breccias, and sparse carbonate-pyrite and/or marcasite veins. Ore minerals consist mostly of electrum and Ag sulfide and selenide minerals, with minor to major amounts of pyrite, marcasite, and arsenopyrite, and local stibnite. Both types of ores have similar geochemical signatures, characterized by high Au, Ag, As, Sb, and Se contents, locally high Hg, Mo, Tl, and W contents, and low Cu, Pb, and Zn contents. Stable isotope data indicate that ore fluids consisted dominantly of meteoric water that evolved by deep circulation through Paleozoic sedimentary rocks at low water/rock ratios (about 1) and high temperatures (>200°C). Calculated isotopic compositions of ore fluids are δ 18 O H2O = -3 to -7 per mil, δD H2O = -107 to -124 per mil, δ 13 C CO2 = 0 to -6 per mil, and δ 34 S H2S = -3 to +8 per mil. The ore fluids obtained much of their H 2 S and CO 2 and probably scavenged ore metals and trace elements from the Paleozoic sedimentary rocks. Some H 2 S and CO 2 may have been derived from degassing Miocene magmas. Mule Canyon formed at shallow depths, probably about 100 m below the paleosurface. Ore fluids were dilute, nearly neutral in pH, reduced, H 2 S-rich, and CO 2 -bearing. Peak temperatures in ore zones reached 230° to 265°C at nearly lithostatic pressures when some crystalline quartz ± adularia precipitated, but most ore formed at temperatures <200°C at near hydrostatic pressures and was accompanied by precipitation of opaline and chalcedonic silica ± adularia ± calcite and dolomite. Deposition of gold in As-rich overgrowths on pyrite and/or marcasite in disseminated ores occurred owing to decreasing H 2 S in the ore fluids resulting from sulfidation reactions. Later electrum and Ag selenide precipitation in open spaces occurred owing to boiling, loss of H 2 S to the vapor phase, and cooling. Mule Canyon is similar to most other low - sulfidation Au-Ag deposits associated with Miocene tholeiitic bimodal basalt-rhyolite magmatism in the Great Basin, such as Sleeper, Midas, and Buckhorn. Major differences at Mule Canyon are the high Fe sulfide contents of some ores and altered wall rocks, the paucity of silicification, and the presence of only narrow and discontinuous gold -bearing siliceous veins. These differences primarily are due to the mafic composition of the host rocks. Mule Canyon differs from low - sulfidation deposits associated with subduction-related calc-alkaline porphyry intrusions, such as the Comstock lode, in that a much smaller proportion of water, salts, and metals was derived from crystallizing magmas.

Nevada↗

USGS2003

Applied geochemistry, geology and mineralogy of the northernmost Carlin trend, Nevada

Investigations in the northernmost Carlin trend were undertaken to advance understanding of the geochemical signatures and genesis of precious metal deposits in the trend . Two fundamental geologic relationships near the trend significantly affect regional geochemical distributions: a remarkably intact lower Paleozoic stratigraphic sequence of siliceous rocks in the upper plate of the middle Paleozoic Roberts Mountains thrust, and the widespread repetition of rocks high in the upper plate during late Paleozoic thrusting that thickens the cover above mineralized rock in the lower plate. A compilation of previously published chemical analyses of 440 stream sediment samples and 115 rocks from two 7 1/2-minute quadrangles, as well as new chemical analyses of approximately 1,000 drill core samples in a 1,514 m (4,970 ft) hole through the Rodeo Creek deposit were used to construct three-dimensional element distribution models that highlight metal zonation in the mineralized systems. The Rodeo Creek deposit comprises deep Ag base-metal ± Au-mineralized rock below the Roberts Mountains thrust and contains an unusually high Ag/Au ratio greater than 30. Stacked geochemical halos related to the deposit are confined to the lower plate of the Roberts Mountains thrust and include two horizons of Hg, Cu, and Zn anomalies-as much as 180 m above the deposit-that mostly result from mercurian sphalerite. Extremely subtle indications of mineralization in the upper plate of the Roberts Mountains thrust above the deposit include arsenopyrite overgrowths on small pyrite crystals in 50- to 75-μm-wide clay-carbonate veinlets that lack alteration halos, arsenical rims on small disseminated crystal of recrystallized diagenetic pyrite, and partial replacement of diagenetic pyrite by tennantite. Some of these minerals contain anomalously high Au. However, these As-(Au)-bearing rocks most likely represent another locus of largely untested mineralized rock rather than distal halos related to either the Rodeo Creek or the nearby Dee and Storm gold deposits. Application of micromineralogic techniques helped to identify mineral assemblages that are specific to mineralization and provided an empirical foundation for interpretations of geochemical halos in the Carlin trend . District-scale geochemical patterns of several elements in stream sediments and surface rocks coincide with the northernmost Carlin trend and can be used to explore for Carlin -type deposits. Concentrations of elevated As and Sb in stream sediments (as much as 54 ppm As) have northwest-elongate lobate patterns that clearly outline the trend across a width of approximately 4 km. Arsenic contents of exposed rocks (as much as 90 ppm As) strongly correlate with As contents of derivative stream sediments, and rock contents of Sb show a somewhat lesser but nonetheless strong and similar correspondence. Factor analysis of stream-sediment data shows that those factor scores that are correlated with As, Sb, Au, and Pb also are high along the trend and suggest that mineralized rocks may be present. Although As was not detected by scanning electron microscope-energy dispersive spectrometer (SEM-EDS) studies in heavy mineral concentrates of high-As stream sediments in the Carlin trend , X-ray absorption near-edge spectra (XANES) of selected light fractions of stream sediment samples indicate that Al-bearing phases, such as gibbsite, amorphous Al oxyhydroxides, or aluminosilicate clay minerals host most of the As(V). The best fit, visually and in terms of the lowest residual, was obtained by a model compound of As(V) sorbed to gibbsite. Thus, most As in stream sediments derived from altered rock within the Carlin trend apparently is contained in light fractions. The geochemical character of young, unconsolidated, postmineral deposits that cover mineralized rocks on the Carlin trend partly results from mineralized sources along the trend . Concentration of As in the Miocene Carlin Formation shows an exceptionally well developed progressive increase to about 30 ppm As as altered rock surrounding the trend is approached. Mineralized and/or altered rock fragments probably have been shed directly into the sedimentary basin of the Carlin Formation, and migration of As, now fixed as As(V), also may have occurred in the supergene environment after material was recycled out of the Carlin Formation and into present-day gulleys.

Nevada↗