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Suspended-sediment concentrations, bedload, particle sizes, surrogate measurements, and annual sediment loads for selected sites in the lower Minnesota River Basin, water years 2011 through 2016

Accurate measurements of fluvial sediment are important for assessing stream ecological health, calculating flood levels, computing sediment budgets, and managing and protecting water resources. Sediment-enriched rivers in Minnesota are a concern among Federal, State, and local governments because turbidity and sediment-laden waters are the leading impairments and affect more than 6,000 miles of rivers in Minnesota. The suspended sediment in the lower Minnesota River is deleterious, contributing about 75 to 90 percent of the suspended sediment being deposited into Lake Pepin. The Saint Paul District of the U.S. Army Corps of Engineers and the Lower Minnesota River Watershed District collaborate to maintain a navigation channel on the lower 14.7 miles of the Minnesota River through scheduled dredging operations. The Minnesota Pollution Control Agency has adopted a sediment-reduction strategy to reduce sediment in the Minnesota River by 90 percent by 2040. The U.S. Geological Survey, in cooperation with the U.S. Army Corps of Engineers, the Minnesota Pollution Control Agency, and the Lower Minnesota River Watershed District, collected suspended-sediment, bedload, and particle-size samples at five sites in the lower Minnesota River Basin during water years 2011 through 2014 and surrogate measurements of acoustic backscatter at one of these sites on the lower Minnesota River during water years 2012 through 2016 to quantify sediment loads and improve understanding of sediment-transport relations. Annual sediment loads were computed for calendar years 2011 through 2014. Data collected from water years 2011 through 2014 indicated that two tributaries, Le Sueur River and High Island Creek, had the highest sediment yield and concentrations of suspended sediment. These tributaries also had greater stream gradients than the sites on the Minnesota River. Suspended fines were greater than suspended sand at all sites in the study area. The range of median particle sizes matched the range for stream gradients from greatest to smallest. Bedload ranged from 3 to 20 percent of the total load at the Le Sueur River, Minnesota River at Mankato, and High Island Creek and was less than 1 percent of the total load at the Minnesota River near Jordan and at Fort Snelling State Park. The reach of the Minnesota River between Mankato and Jordan is a major source of sediment, with the sediment yield at Jordan being two and a half times greater than at Mankato. Between Jordan and Fort Snelling, the sediment yield decreases substantially, which indicates that the Minnesota River in this reach is a sink for sediment. Surrogate measurements (acoustic backscatter) collected with suspended-sediment concentration data from water years 2012 through 2016 from the Minnesota River at Fort Snelling State Park indicated strong relations between the acoustic backscatter and suspended-sediment concentrations. These results point to the dynamic nature of sediment aggradation, degradation, and transport in the Minnesota River Basin. The analyses described in this report will improve the understanding of sediment-transport relations and sediment budgets in the Minnesota River Basin.

Minnesota

Monitoring avian productivity and survivorship (MAPS) 5-year summary, Naval Outlying Landing Field, Imperial Beach, southwestern San Diego County, California, 2009-13

During 2009–13, a Monitoring Avian Productivity and Survivorship (MAPS) banding station was operated at the Naval Outlying Landing Field (NOLF), Imperial Beach, in southwestern San Diego County, California. The station was established as part of a long-term monitoring program of Neotropical migratory bird populations on NOLF and helps Naval Base Coronado (NOLF is a component) meet the goals and objectives of Department of Defense Partners in Flight program and the Birds and Migratory Birds Management Strategies of the Naval Base Coronado Integrated Natural Resources Management Plan. During 2009–13, captures averaged 644 ±155 per year. Fifty-seven species were captured, of which 44 are Neotropical migratory species and 33 breed at the MAPS station. Twenty-two sensitive species were detected, including Least Bell’s Vireo ( Vireo bellii pusillus ), Willow Flycatcher ( Empidonax traillii ), Yellow-breasted Chat ( Icteria virens ) and Yellow Warbler ( Setophaga petechia ). Local population trends varied among species and years, as did annual productivity (number of young per adult). We found no significant relationship between productivity and the observed population size in the subsequent year for any species, nor did we find an association between productivity and precipitation for the current bio-year. Similarly, survivorship varied across species and years, and there was no obvious relationship between adult survivorship and observed population size for any species except Wrentit ( Chamaea fasciata ), for which the relationship was positive. Adult survivorship was unrelated to precipitation at the MAPS station. Additional years of data will be required to generate sample sizes adequate for more rigorous analyses of survivorship and productivity as predictors of population growth.

California

Regression equations for estimating flood flows for the 2-, 10-, 25-, 50-, 100-, and 500-Year recurrence intervals in Connecticut

Multiple linear-regression equations were developed to estimate the magnitudes of floods in Connecticut for recurrence intervals ranging from 2 to 500 years. The equations can be used for nonurban, unregulated stream sites in Connecticut with drainage areas ranging from about 2 to 715 square miles. Flood-frequency data and hydrologic characteristics from 70 streamflow-gaging stations and the upstream drainage basins were used to develop the equations. The hydrologic characteristics-drainage area, mean basin elevation, and 24-hour rainfall-are used in the equations to estimate the magnitude of floods. Average standard errors of prediction for the equations are 31.8, 32.7, 34.4, 35.9, 37.6 and 45.0 percent for the 2-, 10-, 25-, 50-, 100-, and 500-year recurrence intervals, respectively. Simplified equations using only one hydrologic characteristic-drainage area-also were developed. The regression analysis is based on generalized least-squares regression techniques. Observed flows (log-Pearson Type III analysis of the annual maximum flows) from five streamflow-gaging stations in urban basins in Connecticut were compared to flows estimated from national three-parameter and seven-parameter urban regression equations. The comparison shows that the three- and seven- parameter equations used in conjunction with the new statewide equations generally provide reasonable estimates of flood flows for urban sites in Connecticut, although a national urban flood-frequency study indicated that the three-parameter equations significantly underestimated flood flows in many regions of the country. Verification of the accuracy of the three-parameter or seven-parameter national regression equations using new data from Connecticut stations was beyond the scope of this study. A technique for calculating flood flows at streamflow-gaging stations using a weighted average also is described. Two estimates of flood flows - one estimate based on the log-Pearson Type III analyses of the annual maximum flows at the gaging station, and the other estimate from the regression equation - are weighted together based on the years of record at the gaging station and the equivalent years of record value determined from the regression. Weighted averages of flood flows for the 2-, 10-, 25-, 50-, 100-, and 500-year recurrence intervals are tabulated for the 70 streamflow-gaging stations used in the regression analysis. Generally, weighted averages give the most accurate estimate of flood flows at gaging stations. An evaluation of the Connecticut's streamflow-gaging network was performed to determine whether the spatial coverage and range of geographic and hydrologic conditions are adequately represented for transferring flood characteristics from gaged to ungaged sites. Fifty-one of 54 stations in the current (2004) network support one or more flood needs of federal, state, and local agencies. Twenty-five of 54 stations in the current network are considered high-priority stations by the U.S. Geological Survey because of their contribution to the longterm understanding of floods, and their application for regionalflood analysis. Enhancements to the network to improve overall effectiveness for regionalization can be made by increasing the spatial coverage of gaging stations, establishing stations in regions of the state that are not well-represented, and adding stations in basins with drainage area sizes not represented. Additionally, the usefulness of the network for characterizing floods can be maintained and improved by continuing operation at the current stations because flood flows can be more accurately estimated at stations with continuous, long-term record.

Connecticut

Hydrogeologic framework and hydrologic budget components of the Columbia Plateau Regional Aquifer System, Washington, Oregon, and Idaho

The Columbia Plateau Regional Aquifer System (CPRAS) covers an area of about 44,000 square miles in a structural and topographic basin within the drainage of the Columbia River in Washington, Oregon, and Idaho. The primary aquifers are basalts of the Columbia River Basalt Group (CRBG) and overlying sediment. Eighty percent of the groundwater use in the study area is for irrigation, in support of a $6 billion per year agricultural economy. Water-resources issues in the Columbia Plateau include competing agricultural, domestic, and environmental demands. Groundwater levels were measured in 470 wells in 1984 and 2009; water levels declined in 83 percent of the wells, and declines greater than 25 feet were measured in 29 percent of the wells. Conceptually, the system is a series of productive basalt aquifers consisting of permeable interflow zones separated by less permeable flow interiors; in places, sedimentary aquifers overly the basalts. The aquifer system of the CPRAS includes seven hydrogeologic units-the overburden aquifer, three aquifer units in the permeable basalt rock, two confining units, and a basement confining unit. The overburden aquifer includes alluvial and colluvial valley-fill deposits; the three basalt units are the Saddle Mountains, Wanapum, and Grande Ronde Basalts and their intercalated sediments. The confining units are equivalent to the Saddle Mountains-Wanapum and Wanapum-Grande Ronde interbeds, referred to in this study as the Mabton and Vantage Interbeds, respectively. The basement confining unit, referred to as Older Bedrock, consists of pre-CRBG rocks that generally have much lower permeabilities than the basalts and are considered the base of the regional flow system. Based on specific-capacity data, median horizontal hydraulic conductivity (Kh) values for the overburden, basalt units, and bedrock are 161, 70, and 6 feet per day, respectively. Analysis of oxygen isotopes in water and carbon isotopes in dissolved inorganic carbon from groundwater samples indicates that groundwater in the CPRAS ranges in age from modern (<50 years) to Pleistocene (>10,000 years). The oldest groundwater resides in deep, downgradient locations indicating that groundwater movement and replenishment in parts of this regional aquifer system have operated on long timescales under past natural conditions, which is consistent with the length and depth of long flow paths in the system. The mean annual recharge from infiltration of precipitation for the 23-year period 1985-2007 was estimated to be 4.6 inches per year (14,980 cubic feet per second) using a polynomial regression equation based on annual precipitation and the results of recharge modeling done in the 1980s. A regional-scale hydrologic budget was developed using a monthly SOil WATer (SOWAT) Balance model to estimate irrigation-water demand, groundwater flux (recharge or discharge), direct runoff, and soil moisture within irrigated areas. Mean monthly irrigation throughout the study area peaks in July at 1.6 million acre-feet (MAF), of which 0.45 and 1.15 MAF are from groundwater and surface-water sources, respectively. Annual irrigation water use in the study area averaged 5.3 MAF during the period 1985-2007, with 1.4 MAF (or 26 percent) supplied from groundwater and 3.9 MAF supplied from surface water. Mean annual recharge from irrigation return flow in the study area was 4.2 MAF (1985-2007) with 2.1 MAF (50 percent) occurring within the predominately surface-water irrigated regions of the study area. Annual groundwater-use estimates were made for public supply, self-supplied domestic, industrial, and other uses for the period 1984 through 2009. Public supply groundwater use within the study area increased from 200,600 acre-feet per year (acre-ft/yr) in 1984 to 269,100 acre-ft/yr in 2009. Domestic self-supplied groundwater use increased from 54,580 acre-ft/yr in 1984 to 71,160 acre-ft/yr in 2009. Industrial groundwater use decreased from 53,390 acre-ft/yr in 1984 t

Scientific Investigations Report

Comparison of the U.S. lead recycling industry in 1998 and 2011

Since 1998, the structure of the lead recycling industry has changed and trade patterns of the domestic lead recycling industry have shifted. Although the domestic demand for lead has remained relatively constant since 1998, production of lead has increasingly shifted to the domestic secondary lead industry. The last primary lead smelter in the United States closed at the end of 2013, at which time the secondary lead industry became the sole source of domestic lead production. The amount of lead recovered annually from scrap batteries generally increased from about 900,000 metric tons in 1995 to more than 1,100,000 metric tons in 2012. The percentage of total U.S. lead production attributed to battery scrap increased from 65 percent in 1995 to 87 percent in 2012. Since the North American Free Trade Agreement took effect in 1994, trade patterns among the United States, Canada, and Mexico have changed for recycled lead products. In the late 1990s, the principal sources of lead waste and scrap not derived from batteries were Canada, Mexico, and South America; by 2011, the principal sources were Central America and Asia, with decreasing amounts from Canada and South America. Since 1998, the amount of lead derived from imported batteries and scrap from Canada has ranged from 50 to 90 percent, and the amount imported from Mexico has ranged from 3 to 20 percent. Canada received about 50 percent of the lead contained in spent lead-acid batteries and scrap exported from the United States in 1998, and Mexico received about 4 percent. By 2012, however, the amount of lead scrap exported to Canada had decreased to about 10 percent, and the amount of lead-based scrap products, primarily batteries, exported to Mexico from the United States had increased to 47 percent. Vertical integration of the domestic secondary lead industry and higher costs required to implement more stringent ambient air standards in the United States have led some companies to shift lead recycling operations to Mexico. U.S. secondary lead producers are increasingly competing with Canadian and Mexican facilities for market share.

Scientific Investigations Report

Relations of Water Quality to Streamflow, Season, and Land Use for Four Tributaries to the Toms River, Ocean County, New Jersey, 1994-99

The effects of nonpoint-source contamination on the water quality of four tributaries to the Toms River in Ocean County, New Jersey, have been investigated in a 5-year study by the U.S. Geological Survey (USGS), in cooperation with the New Jersey Department of Environmental Protection (NJDEP). The purpose of the study was to relate the extent of land development to loads of nutrients and other contaminants to these streams, and ultimately to Barnegat Bay. Volumetric streamflow (discharge) was measured at 6 monitoring sites during 37 stormflow and base-flow sampling events over a 5-year period (May 1994-September 1999). Concentrations and yields (area-normalized instantaneous load values) of nitrogen and phosphorus species, total suspended solids, and fecal coliform bacteria were quantified, and pH, dissolved oxygen, and stream stage were monitored during base-flow conditions and storms. Sufficient data were collected to allow for a statistical evaluation of differences in water quality among streams in subbasins with high, medium, and low levels of land development. Long Swamp Creek, in a highly developed subbasin (64.2 percent developed); Wrangle Brook, in a moderately developed subbasin (34.5 percent); Davenport Branch, in a slightly developed subbasin (22.8 percent); and Jakes Branch, in an undeveloped subbasin (0 percent) are the subbasins selected for this study. No point-source discharges are known to be present on these streams. Water samples were collected and analyzed by the NJDEP, and discharge measurements and data analysis were conducted by the USGS. Total nitrogen concentrations were lower in Davenport Branch than in Long Swamp Creek and Wrangle Brook during base flow and stormflow. Concentrations of total nitrogen and nitrate were highest in Wrangle Brook (as high as 3.0 mg/L and 1.6 mg/L, respectively) as a result of high concentrations of nitrate in samples collected during base flow; nitrate loading from ground-water discharge is much higher in Wrangle Brook than in any of the other streams, possibly as a result of an experimental wastewater-(secondary effluent) disposal site that was in operation during the 1980's. Ammonia concentrations were higher in samples from Long Swamp Creek than in those from the other two monitoring sites under all flow conditions, and ammonia yields were higher during stormflow than base flow at all monitoring sites. Concentrations and yields of fecal coliform bacteria and total suspended solids were higher during stormflow than during base flow at all monitoring sites. Concentrations and yields were significantly higher in Long Swamp Creek, a highly developed subbasin and Wrangle Brook, a moderately developed subbasin than in Davenport Branch, a slightly developed subbasin. Concentrations and yields of phosphate species, which also are strongly related to stormflow, were higher during stormflow in Long Swamp Creek than in the other subbasins. Base-flow separation techniques were used on hydrographs generated for storms to distinguish the fraction of discharge and constituent loading attributable to storm runoff (overland flow) from the fraction contributed by ground-water discharge. Precipitation records were used to determine the total annual volumes of ground-water discharge and runoff at each monitoring site. These volumes were used in conjunction with water-quality data to calculate total annual loads of each constituent at each monitoring site, separated into ground-water discharge and runoff fractions. It was determined that loads of ammonia, nitrate, organic nitrogen, total nitrogen, and orthophosphate in ground-water discharge were significantly higher in the moderately developed Wrangle Brook subbasin than in the highly developed Long Swamp Creek subbasin, and that no relation was apparent between the percent of land development and constituent loads from ground-water discharge. The loading of each constituent contributed by ground-water discharge is specific

Scientific Investigations Report

Potentiometric surface of the Mississippi River Valley alluvial aquifer, spring 2016

A potentiometric surface map for spring 2016 was created for the Mississippi River Valley alluvial (MRVA) aquifer using selected available groundwater-altitude data from wells and surface-water-altitude data from streamgages. Most of the wells were measured annually or one time after installation, but some wells were measured more than one time or continually; streamgages are typically operated continuously. Personnel from the Arkansas Natural Resources Commission, Arkansas Department of Health, Arkansas Geological Survey, Illinois Department of Agriculture, Illinois State Water Survey, Louisiana Department of Natural Resources, Louisiana Department of Transportation and Development, Mississippi Department of Environmental Quality, Yazoo Mississippi Delta Joint Water Management District, U.S. Department of Agriculture–Natural Resources Conservation Service, and the U.S. Geological Survey (USGS) routinely collect groundwater data from wells screened in the MRVA aquifer. The USGS and the U.S. Army Corps of Engineers routinely collect data on river stage and discharge for the rivers overlying the MRVA aquifer. The potentiometric surface map for 2016 was created using existing data as part of the USGS Water Availability and Use Science Program to support investigations that characterize the MRVA aquifer. Sufficient groundwater-altitude data were available to create a potentiometric-surface map for spring 2016 for about 81 percent of the aquifer area. The potentiometric contours ranged from 10 to 340 feet. The regional direction of groundwater flow in the MRVA aquifer was generally towards the south-southwest, except in areas of groundwater-altitude depressions, where groundwater flows into the depressions, and near rivers, where groundwater flow generally parallels the flow in the rivers. There are large depressions in the potentiometric surface of the MRVA aquifer in the lower half of the Cache region and in most of the Grand Prairie and Delta regions.

Arkansas, Illinois, Kentucky, Louisiana, Mississip

Dam removal cost databases and drivers

The United States (U.S.) has over 90,000 dams listed in the National Inventory of Dams that provide vital infrastructure to support water management for municipal and industrial uses including irrigation, hydropower, flood control, navigation, recreation, and habitat, among other uses (NID 2023). The Bureau of Reclamation (Reclamation) and U.S. Army Corps of Engineers (USACE) operate and maintain approximately 489 and 740 dams, respectively, as well as associated structures which provide flood risk management, navigation, water supply, hydropower, environmental stewardship, fish and wildlife conservation, and recreation benefits. As dams age, structural and operational maintenance investments increase until a time when decisions on whether to rehabilitate, replace, or decommission the dam need to be made. While most dams continue to provide important value even with maintenance requirements, at least 2,000 dams have been removed in the U.S. during the past 110 years, with an upward trend in the last few decades (American Rivers 2023). Decommissioning a dam may be considered when the purpose of the dam is no longer needed or other factors such as dam safety, fish passage, recreation safety, or river restoration goals take higher priority and are more economically feasible for the dam owner long-term. Dam safety programs, river restoration programs, and asset class management programs need cost estimating methods to consider dam decommissioning when appropriate. Traditional cost estimating approaches in planning stages focus mainly on dam removal construction and may leave out or have uncertainty on important complexities that can have substantial effects on total costs and be critical for project success. As the numbers of dam removal case studies increase, a growing set of cost data has become available (Duda et al. 2023a; Tullos and Bountry 2023; American Rivers 2022). However, total costs vary over five orders of magnitude for similar size dams, and it was unclear why. We evaluated three sets of cost data that had varying level of details regarding elements contributing to dam removal costs reported by project managers working on the dam removal studies and construction means and methods. We created planning-level cost estimating tools to assist with projects needing to consider the dam removal alternative: (1) new databases of case studies (Duda et al. 2023a; Tullos and Bountry 2023); (2) scoping questions to help determine if complexity cost drivers will be present; (3) machine learning based regression trees to estimate a potential cost range; and (4) a Computation Guide for Cost Estimating that can be used to inform discussions on potential dam removal cost items, quantities, and unit costs (appendix A). The collected data showed that dam height is important but is not a reliable predictor of the removal cost without considering other elements. However, knowing some basic characteristics about the average annual flow and geographic location of the dam site, in addition to dam size, can improve the ability to use past case studies for planning-level cost estimating. By additionally incorporating scoping questions related to sediment removal, mitigation, or other infrastructure, the likelihood of complexity cost drivers and the initial uncertainty of a cost estimate can be further reduced especially for small dams. Applying the Computation Guide for Cost Estimating requires more robust information but helps users reduce cost uncertainty. This step further refines the dam removal objective, removal approach (partial or full; phased or instantaneous), engineering design, construction means and methods, quantities, and unit costs, and results in a quantitative cost estimate.

Final Report

Critical minerals in subduction-related magmatic-hydrothermal systems of the United States

During the World War and Cold War eras (1910s–1990s), domestic consumption of numerous mineral commodities relied increasingly on imported supplies. Consumption reliance has since expanded to include 50 “critical minerals” (elements and mineral commodities) that are mostly to entirely imported and subject to curtailment by suppliers or supply chain disruption. New domestic supplies of critical minerals are being pursued by mining companies and by several federal departments and agencies. Information on domestic deposits and resources of critical minerals is being compiled by the U.S. Geological Survey Mineral Resources Program, which has organized investigations by mineral system, deposit type, and commodity. Production, reserves, resources, and inventories of 21 critical minerals in domestic magmatic-hydrothermal deposits related to subduction-generated magmatism, and in tailings, slag, slimes, and electrolyte from copper concentrators, smelters, and refineries that processed some deposits, are largely restricted to Western States and Alaska. The critical mineral commodities Al, Sb, As, Bi, Co, fluorite, Ga, Ge, In, Mn, Ni, Nb, Pd, Pt, potash, Re, Ta, Te, Sn, W, and V are variably concentrated in porphyry/skarn copper-(molybdenum), skarn-replacement-vein (S-R-V) tungsten, polymetallic sulfide S-R-V intermediate sulfidation (IS), high-sulfidation gold-silver, low-sulfidation gold-silver, and lithocap alunite deposit types. These deposit types occur in porphyry copper-molybdenum-gold, alkalic porphyry, porphyry tin (granite related), and reduced intrusion-related mineral systems. Production, reserves, and resources of Co, Ni, Nb, Pd, Pt, Ta, Sn, and V in subduction-related deposits in Western States are insignificant to small, mostly equivalent to months to a few years of recent annual domestic consumption (2016–2020). Significant inventories, equivalent to 2 or more years of consumption of aluminum, antimony, potash, and tungsten in unmined S-R-V tungsten, polymetallic sulfide S-R-V-IS, and lithocap alunite deposits vary from approximately 2 to 8 years. Several decades of consumption of arsenic, bismuth, fluorite, gallium, germanium, and indium exist in some polymetallic sulfide S-R-V-IS and lithocap alunite deposit types. Based on concentrations of critical minerals in reserves, resources, drill holes, and deposit domains (ore types), and in captive refinery records, the largest domestic inventories of Sb, As, Bi, Re, and Te, and possibly Ga, Ge, In, Sn, and W, are in porphyry copper-molybdenum (Cu-Mo) deposits in Alaska, Idaho, Utah, and Arizona, and in interim products of processing porphyry Cu-Mo deposit ores for recovery of copper and molybdenum. Concentrations of critical minerals in archival specimens and sample collections, although somewhat biased by collection and conservation decisions and categorization, are broadly proportionate to those in reserves, resources, and drill holes. These concentrations imply significant inventories of some critical minerals in deposits for which production, resources, and refinery records are unavailable or incomplete. Because of the large masses of ores mined and processed annually (hundreds of millions of metric tons) and in reserves and resources (hundreds of millions of metric tons to billions of metric tons), calculated inventories of critical minerals in porphyry Cu-Mo deposits are equivalent to decades and centuries of recent consumption. However, these inventories should not be considered consumable supplies without reserve definition and development of economically viable mining plans and recovery techniques. An expeditious strategy for elimination or reduction of import reliance is recovery, and improved recovery efficiency, of Sb, As, Bi, Re, and Te, and possibly Ga, Ge, In, Ni, Sn, Ti, and W; during concentration and refining of copper and molybdenum minerals in ores of operating porphyry Cu-Mo mines; and in unmined porphyry Cu-Mo resources. These chalcophile, siderophile, and lithophile critical minerals, often undetectable in ore, are concentrated (hundreds of parts per million to percents) in slimes and electrolyte during copper electrorefining or could be recovered, in part, during sulfide concentration and smelting. Other than rhenium (recovered during molybdenum refining) and tellurium, all have been routinely discarded. Subsidization (for example, commodity price guarantees, tax credits, recovery technology development), political initiative, and (or) sustained market favorability could support new production of critical mineral commodities from subduction-related magmatic-hydrothermal deposits in Western States. In addition, insufficient domestic refining capacity could relegate the large inventories of critical minerals in porphyry Cu-Mo reserves and resources (for example, Pebble, Alaska; Resolution and Copper World [Rosemont], Arizona) to exportation in concentrates and importation insecurity, fortifying their present status.

Scientific Investigations Report

Effects of land use and retention practices on sediment yields in the Stony Brook basin, New Jersey

The average annual rate of suspended-sediment discharge of the Stony Brook at Princeton, N.J. (44.5 square miles) is about 8,800 tons, or 200 tons per square mile. Annual yields within the basin, which is in the Piedmont Lowlands section of the Piedmont physiographic province in west-central New Jersey, range from 25 to 400 tons per square mile. Storm runoff that transports suspended materials in excess of a ton carries 90 percent of the total suspended-sediment discharge from the basin. Observations of particlesize distributions indicate that the suspended material carried during storms is 55 percent silt, 40 percent clay, and 5 percent sand. A trend analysis of sediment records collected at Princeton between 1956 and 1970 indicated an increase in suspended-sediment discharge per unit of water discharge during 1956-61. From early 1962 to late 1967, sediment trends were difficult to interpret owing to complicating factors, such as reservoir construction, urbanization, and extreme drought. After 1967, yields decreased. Variations in sediment yields during the study are attributed to the integrated influence of several factors. A 2.9 percent decrease in croplands and an increase of 5.1 percent in idle and urban land use probably produced a net increase in sediment yields. Construction of seven sediment-retention reservoirs under Public Law 566 resulted in temporary increases in sediment yields. However, based on a trap-efficiency investigation at 1 site, the combined effect of operation of these 7 reservoirs is estimated to result in a 20 percent reduction in sediment discharge from the basin. Other factors that influence the noted decrease include reduction in yields during 5 years of drought, 1962-66, and reduced construction and development during the latter part of the study period resulting from a general economic slowdown.

Water Supply Paper

Surface-Water Quality and Nutrient Loads in the Nepaug Reservoir Watershed, Northwestern Connecticut, 1999-2001

Water quality was characterized at three tributary watersheds to the Nepaug Reservoir-Nepaug River, Phelps Brook, and Clear Brook-from October 1998 through September 2001 to document existing water-quality conditions and evaluate potential future effects of the removal of sand and gravel from areas of the watershed. Some removal operations may include removal of vegetation and top soil and steepening of slopes. Routine water samples collected monthly in all three watersheds were analyzed for nutrients, organic carbon, major ions, and fecal indicator bacteria. Results of the analyses indicate that, in general, the water quality in all three tributary watersheds is good and meets standards established for drinking-water supplies for nitrate, but does not always meet contact-recreation standards for bacteria. Median concentrations of total nitrogen, total phosphorus, and total organic carbon were highest in the routine monthly samples from Phelps Brook and lowest from Clear Brook. Samples also were collected during selected storms to examine changes in concentrations of nutrients during periods of high streamflow. The maximum values measured for total nitrogen, total phosphorus, and total organic carbon were in storm samples from Clear Brook. The Nepaug River watershed delivered the largest loads of total nitrogen, total phosphorus, and total organic carbon to the reservoir. Yields of nutrients and organic carbon differed significantly from year to year and among the three watersheds. Yields of total nitrogen and total organic carbon were largest from Phelps Brook and smallest from Clear Brook. The yields of total phosphorus were largest from Nepaug River and smallest from Phelps Brook. In comparison to other watersheds in Connecticut, annual loads and yields from the three streams were lower than those of developed urban areas and comparable to those of other rural and forested basins. Delivery of nutrients and organic carbon to the reservoir took place mostly during the spring with the exception of those constituents delivered during Tropical Storm Floyd, a large fall storm.

Scientific Investigations Report

Computation and analysis of the instantaneous-discharge record for the Colorado River at Lees Ferry, Arizona — May 8, 1921, through September 30, 2000

A gaging station has been operated by the U.S. Geological Survey at Lees Ferry, Arizona, since May 8, 1921. In March 1963, Glen Canyon Dam was closed 15.5 miles upstream, cutting off the upstream sediment supply and regulating the discharge of the Colorado River at Lees Ferry for the first time in history. To evaluate the pre-dam variability in the hydrology of the Colorado River, and to determine the effect of the operation of Glen Canyon Dam on the downstream hydrology of the river, a continuous record of the instantaneous discharge of the river at Lees Ferry was constructed and analyzed for the entire period of record between May 8, 1921, and September 30, 2000. This effort involved retrieval from the Federal Records Centers and then synthesis of all the raw historical data collected by the U.S. Geological Survey at Lees Ferry. As part of this process, the peak discharges of the two largest historical floods at Lees Ferry, the 1884 and 1921 floods, were reanalyzed and recomputed. This reanalysis indicates that the peak discharge of the 1884 flood was 210,000±30,000 cubic feet per second (ft 3 /s), and the peak discharge of the 1921 flood was 170,000±20,000 ft 3 /s. These values are indistinguishable from the peak discharges of these floods originally estimated or published by the U.S. Geological Survey, but are substantially less than the currently accepted peak discharges of these floods. The entire continuous record of instantaneous discharge of the Colorado River at Lees Ferry can now be requested from the U.S. Geological Survey Grand Canyon Monitoring and Research Center, Flagstaff, Arizona, and is also available electronically at http://www.gcmrc.gov. This record is perhaps the longest (almost 80 years) high-resolution (mostly 15- to 30-minute precision) times series of river discharge available. Analyses of these data, therefore, provide an unparalleled characterization of both the natural variability in the discharge of a river and the effects of dam operations on a river. Following the construction and quality-control checks of the continuous record of instantaneous discharge, analyses of flow duration, sub-daily flow variability, and flood frequency were conducted on the pre- and post-dam parts of the record. These analyses indicate that although the discharge of the Colorado River varied substantially prior to the closure of Glen Canyon Dam in 1963, operation of the dam has caused changes in discharge that are more extreme than the pre-dam natural variability. Operation of the dam has eliminated flood flows and base flows, and thereby has effectively "flattened" the annual hydrograph. Prior to closure of the dam, the discharge of the Colorado River at Lees Ferry was lower than 7,980 ft 3 /s half of the time. Discharges lower than about 9,000 ft 3 /s were important for the seasonal accumulation and storage of sand in the pre-dam river downstream from Lees Ferry. The current operating plan for Glen Canyon Dam no longer allows sustained discharges lower than 8,000 ft 3 /s to be released. Thus, closure of the dam has not only cut off the upstream supply of sediment, but operation of the dam has also largely eliminated discharges during which sand could be demonstrated to accumulate in the river. In addition to radically changing the hydrology of the river, operation of the dam for hydroelectric-power generation has introduced large daily fluctuations in discharge. During the pre-dam era, the median daily range in discharge was only 542 ft 3 /s, although daily ranges in discharge exceeding 20,000 ft 3 /s were observed during the summer thunderstorm season. Relative to the pre-dam period of record, dam operations have increased the daily range in discharge during all but 0.1 percent of all days. The post-dam median daily range in discharge, 8,580 ft 3 /s, exceeds the pre-dam median discharge of 7,980 ft 3 /s. Operation of the dam has also radically changed the frequency of floods on the Colorado River at Lees Ferry. The frequency of floods with peak discharges larger than about 29,000 ft 3 /s has greatly decreased, while the frequency of smaller floods, with peak discharges between 18,500 and 29,000 ft 3 /s, has increased substantially. Operation of the dam has greatly extended the duration of smaller floods; for example, each of the four longest periods of sustained flows in excess of 18,500 ft 3 /s occurred after closure of the dam.

Arizona

Wind River subbasin restoration annual report of USGS activities January 2017 through December 2017

We used Passive Integrated Transponder (PIT)-tagging and a series of instream PIT-tag interrogation systems (PTISs) to investigate life-histories, populations, and efficacy of habitat restoration actions for wild Steelhead Oncorhynchus mykiss in the Wind River subbasin, WA. No hatchery Steelhead have been planted in the Wind River subbasin since 1997, and hatchery adults are estimated to be less than one percent of adults in most years (pers comm. Thomas Buehrens, Washington Department of Fish and Wildlife). Numerous restoration actions have been implemented in the subbasin, including Hemlock Dam removal on Trout Creek in 2009. Data from our study, and companion work by Washington Department of Fish and Wildlife (WDFW), are contributing to Bonneville Power Administration’s (BPA) Research Monitoring and Evaluation (RM&E) Program Strategy of Fish Population Status Monitoring (www.cbfish.org/ProgramStrategy.mvc/ViewProgramStrategySummary/1), specifically the substrategies of: 1) Assessing the Status and Trends of Diversity of Natural Origin Fish Populations and to Uncertainties Research regarding differing life histories of a wild Steelhead population, 2) Assessing the Status and Trend of Adult Natural Origin Fish Populations, and 3) Monitoring and Evaluating the Effectiveness of Tributary Habitat Actions Relative to Environmental, Physical, or Biological Performance Objectives. Our headwaters parr PIT tagging, WDFW parr, smolt, and adult tagging and our instream PTISs are providing data movements and life histories of parr, smolt, and adult Steelhead. During summer 2017, we PIT-tagged age-0 and age-1 Steelhead parr in headwater areas of the Wind River subbasin to characterize population traits and investigate life-history diversity, including growth and pre-smolt downstream movement. Repeat sampling and smolt traps provide opportunities for recapture, and instream PTISs and Columbia River infrastructure provide opportunity for detection of PIT-tagged fish. Throughout the year, we maintained a series of instream PTISs to monitor movement of tagged Steelhead parr, smolts, and adults. This included adding the second array to our upper Wind River PITS, increasing solar capacity and adding improved power cables to some sites. Detections at the instream PTISs have demonstrated trends of age-0 and age-1 parr emigration from natal areas during summer and fall, in addition to the expected movement of parr and smolts in spring. These data are increasing our understanding of varied life histories of juvenile Steelhead; paired with other Steelhead population work in the subbasin we hope to begin to understand factors which may influence parr movements. Long-term monitoring of PIT-tagged fish over multiple years is providing information on contribution of various life-history strategies to smolt production and adult returns. Movements of PIT-tagged adult Steelhead were also recorded at instream PTISs. These data have allowed us to assess adult returns to tributary watersheds within the Wind River subbasin. Determination of adult use of tributary watersheds is providing data to contribute to evaluation of the efficacy of the removal of Hemlock Dam on Trout Creek. Hemlock Dam, located at rkm 2.0 of Trout Creek was removed in summer 2009. The dam had had contributed to hydrologic impairment of Trout Creek and had potential negative effects on Steelhead. The improved upper Wind River PTIS (better site characteristics and grid power) will allow estimates of subbasin adult escapement upstream of that site. Evaluating and planning restoration efforts are of interest to many managers and agencies to ensure efficient use of resources. The evaluation of various life-histories of Lower Columbia River Steelhead within the Wind River subbasin will provide information to better track populations, and to direct habitat restoration and water allocation planning. Increasingly detailed Viable Salmonid Population information, such as that provided by PIT-tagging and instream PTISs networks like those we operate in the Wind River subbasin, will provide data to inform policy and management, as life-history strategies and production bottlenecks are identified and understood.

Washington

Trends in major-ion constituents and properties for selected sampling sites in the Tongue and Powder River watersheds, Montana and Wyoming, based on data collected during water years 1980-2010

The primary purpose of this report is to present information relating to flow-adjusted temporal trends in major-ion constituents and properties for 16 sampling sites in the Tongue and Powder River watersheds based on data collected during 1980–2010. In association with this primary purpose, the report presents background information on major-ion characteristics (including specific conductance, calcium, magnesium, potassium, sodium adsorption ratio, sodium, alkalinity, chloride, fluoride, dissolved sulfate, and dissolved solids) of the sampling sites and coal-bed methane (CBM) produced water (groundwater pumped from coal seams) in the site watersheds, trend analysis methods, streamflow conditions, and factors that affect trend results. The Tongue and Powder River watersheds overlie the Powder River structural basin (PRB) in northeastern Wyoming and southeastern Montana. Limited extraction of coal-bed methane (CBM) from the PRB began in the early 1990’s, and increased dramatically during the late 1990’s and early 2000’s. CBM-extraction activities produce discharges of water with high concentrations of dissolved solids (particularly sodium and bicarbonate ions) relative to most stream water in the Tongue and Powder River watersheds. Water-quality of CBM produced water is of concern because of potential effects of sodium on agricultural soils and potential effects of bicarbonate on aquatic biota. Two parametric trend-analysis methods were used in this study: the time-series model (TSM) and ordinary least squares regression (OLS) on time, streamflow, and season. The TSM was used to analyze trends for 11 of the 16 study sites. For five sites, data requirements of the TSM were not met and OLS was used to analyze trends. Two primary 10-year trend-analysis periods were selected. Trend-analysis period 1 (water years 1986–95; hereinafter referred to as period 1) was selected to represent variability in major-ion concentrations in the Tongue and Powder River watersheds before potential effects of CBM-extraction activities. Trend analysis period 2 (water years 2001–10; hereinafter referred to as period 2) was selected because it encompassed substantial CBM-extraction activities and therefore might indicate potential effects of CBM-extraction activities on water quality of receiving streams in the Tongue and Powder River watersheds. For sites that did not satisfy data requirements for the TSM, OLS was used to analyze trends for period 2 (if complete data were available) or a 6-year period (2005–10). Flow-rate characteristics of CBM-produced water were estimated to allow general comparisons with streamflow characteristics of the sampling sites. The information on flow-rate characteristics of CBM-produced water in relation to streamflow does not account for effects of disposal, treatment, or other remediation activities on the potential quantitative effects of CBM-produced water on receiving streams. In many places, CBM-produced water is discharged into impoundments or channels in upper reaches of tributary watersheds where water infiltrates and does not directly contribute to streamflow. For Tongue River at State line (site 4) mean annual pumping rate of CBM-produced water during water years 2001–10 (hereinafter referred to as mean CBM pumping rate) was 6 percent of the mean of annual median streamflows during water years 2001–10 (hereinafter referred to as 2001–10 median streamflow). For main-stem Tongue River sites 5, 7, and 10, mean CBM pumping rate was 8–12 percent of 2001–10 median streamflow. For main-stem Powder River sites (sites 12, 13, and 16), mean CBM pumping rates were 26, 28, and 34 percent of 2001–10 median streamflows, respectively. For main-stem Tongue River sites analyzed by using the TSM and downstream from substantial CBM-extraction activities [Tongue River at State line (site 4), Tongue River at Tongue River Dam (site 5), Tongue River at Birney Day School (site 7), and Tongue River at Miles City (site 10)], generally small significant or nonsignificant decreases in most constituents are indicated for period 1. For period 2 for these sites, the TSM trend results do not allow confident conclusions concerning detection of effects of CBM-extraction activities on stream water quality. Detection of significant trends in major-ion constituents and properties for period 2 generally was infrequent, and direction, magnitudes, and significance of fitted trends were not strongly consistent with relative differences in water quality between stream water and CBM-produced water. The TSM indicated significant or generally large magnitude increases in median values of sodium adsorption ratio (SAR), sodium, and alkalinity for period 2 for sites 5 and 7, which might indicate potential effects of CBM-extraction activities on stream water. However, other factors, including operations of Tongue River Reservoir, irrigation activities, contributions of saline groundwater, and operations of the Decker coal mine, confound confident determination of causes of detected significant trends for sites 5 and 7. For all mainstem Tongue River sites, trends for period 2 generally are within ranges of those for period 1 before substantial CBM-extraction activities. For main-stem Powder River sites analyzed by using the TSM [Powder River at Sussex (site 11), Powder River at Arvada (site 12), Powder River at Moorhead (site 13), and Powder River near Locate (site 16)], significant or generally large magnitude decreases in median values of SAR, sodium, estimated alkalinity, chloride, fluoride, specific conductance, and dissolved solids are indicated for period 1. Patterns in trend results for period 1 for main-stem Powder River sites are consistent with effects of Salt Creek oil-brine reinjection that started in 1990. Trend results for all main-stem Powder River sites downstream from substantial CBM-extraction activities (sites 12, 13, and 16) indicate evidence of potential effects of CBM-extraction activities on stream water quality, although evidence is stronger for sites 12 and 13 than for site 16. Evidence in support of potential CBM effects includes significant increases in median values of SAR, sodium, and estimated alkalinity for period 2 for sites 12, 13, and 16 that are consistent with relative differences between stream water and CBM-produced water. Significant increases in median values of these constituents for period 2 are not indicated for Powder River at Sussex (site 11) upstream from substantial CBM-extraction activities. In interpreting the trend results, it is notable that the fitted trends evaluate changes in median concentrations and also notable that changes in median concentrations that might be attributed to CBM-extraction activities probably are more strongly evident during low to median streamflow conditions than during mean to high streamflow conditions. This observation is relevant in assessing trend results in relation to specific water-quality concerns, including effects of water-quality changes on irrigators and effects on stream biota and ecology.

Montana;Wyoming

Hydrogeology and simulation of groundwater flow in fractured-rock aquifers of the Piedmont and Blue Ridge Physiographic Provinces, Bedford County, Virginia

An annual groundwater budget was computed as part of a hydrogeologic characterization and monitoring effort of fractured-rock aquifers in Bedford County, Virginia, a growing 764-square-mile (mi 2 ) rural area between the cities of Roanoke and Lynchburg, Virginia. Data collection in Bedford County began in the 1930s when continuous stream gages were installed on Goose Creek and Big Otter River, the two major tributaries of the Roanoke River within the county. Between 2006 and 2014, an additional 2 stream gages, 3 groundwater monitoring wells, and 12 partial-record stream gages were operated. Hydrograph separation methods were used to compute base-flow recharge rates from the continuous data collected from the continuous stream gages. Mean annual base-flow recharge ranged from 8.3 inches per year (in/yr) for the period 1931&ndash;2012 at Goose Creek near Huddleston (drainage area 188 mi 2 ) to 9.3 in/yr for the period 1938&ndash;2012 at Big Otter River near Evington (drainage area 315 mi 2 ). Mean annual base-flow recharge was estimated to be 6.5 in/yr for the period 2007&ndash;2012 at Goose Creek at Route 747 near Bunker Hill (drainage area 125 mi 2 ) and 8.9 in/yr for the period 2007&ndash;2012 at Big Otter River at Route 221 near Bedford (drainage area 114 mi 2 ). Base-flow recharge computed from the partial-record data ranged from 5.0 in/yr in the headwaters of Goose Creek to 10.5 in/yr in the headwaters of Big Otter River. A steady-state groundwater-flow simulation for Bedford County was developed to test the conceptual understanding of flow in the fractured-rock aquifers and to compute a groundwater budget for the four major drainages: James River, Smith Mountain and Leesville Lakes, Goose Creek, and Big Otter River. Model results indicate that groundwater levels mimic topography and that minimal differences in aquifer properties exist between the Proterozoic basement crystalline rocks and Late Proterozoic-Cambrian cover crystalline rocks. The Big Otter River receives 40.8 percent of the total daily groundwater outflow from fractured-rock aquifers in Bedford County; Goose Creek receives 25.8 percent, the James River receives 18.2 percent, and Smith Mountain and Leesville Lakes receive 15.2 percent. The remaining percentage of outflow is attributed to pumping from the aquifer (consumptive use).

Virginia

Comparison of methods for estimating ground-water recharge and base flow at a small watershed underlain by fractured bedrock in the Eastern United States

This study by the U.S. Geological Survey (USGS), in cooperation with the Agricultural Research Service (ARS), U.S. Department of Agriculture, compared multiple methods for estimating ground-water recharge and base flow (as a proxy for recharge) at sites in east-central Pennsylvania underlain by fractured bedrock and representative of a humid-continental climate. This study was one of several within the USGS Ground-Water Resources Program designed to provide an improved understanding of methods for estimating recharge in the eastern United States. Recharge was estimated on a monthly and annual basis using four methods?(1) unsaturated-zone drainage collected in gravity lysimeters, (2) daily water balance, (3) water-table fluctuations in wells, and (4) equations of Rorabaugh. Base flow was estimated by streamflow-hydrograph separation using the computer programs PART and HYSEP. Estimates of recharge and base flow were compared for an 8-year period (1994-2001) coinciding with operation of the gravity lysimeters at an experimental recharge site (Masser Recharge Site) and a longer 34-year period (1968-2001), for which climate and streamflow data were available on a 2.8-square-mile watershed (WE-38 watershed). Estimates of mean-annual recharge at the Masser Recharge Site and WE-38 watershed for 1994-2001 ranged from 9.9 to 14.0 inches (24 to 33 percent of precipitation). Recharge, in inches, from the various methods was: unsaturated-zone drainage, 12.2; daily water balance, 12.3; Rorabaugh equations with PULSE, 10.2, or RORA, 14.0; and water-table fluctuations, 9.9. Mean-annual base flow from streamflow-hydrograph separation ranged from 9.0 to 11.6 inches (21-28 percent of precipitation). Base flow, in inches, from the various methods was: PART, 10.7; HYSEP Local Minimum, 9.0; HYSEP Sliding Interval, 11.5; and HYSEP Fixed Interval, 11.6. Estimating recharge from multiple methods is useful, but the inherent differences of the methods must be considered when comparing results. For example, although unsaturated-zone drainage from the gravity lysimeters provided the most direct measure of potential recharge, it does not incorporate spatial variability that is contained in watershed-wide estimates of net recharge from the Rorabaugh equations or base flow from streamflow-hydrograph separation. This study showed that water-level fluctuations, in particular, should be used with caution to estimate recharge in low-storage fractured-rock aquifers because of the variability of water-level response among wells and sensitivity of recharge to small errors in estimating specific yield. To bracket the largest range of plausible recharge, results from this study indicate that recharge derived from RORA should be compared with base flow from the Local-Minimum version of HYSEP.

Scientific Investigations Report

Demographic responses of least terns and piping plovers to the 2011 Missouri River flood—A large-scale case study

A catastrophic flood event on the Missouri River system in 2011 led to substantial changes in abundance and distribution of unvegetated sand habitat. This river system is a major component of the breeding range for interior Least terns ( Sternula antillarum ; “terns”) and piping plovers ( Charadrius melodus ; “plovers”), both of which are Federally listed ground-nesting birds that prefer open, unvegetated sand and gravel nesting substrates on sandbars and shorelines. The 2011 flood inundated essentially all tern and plover nesting habitat during 2011, but it had potential to generate post-flood habitat conditions that favored use by terns and plovers in subsequent years. We compared several tern and plover demographic parameters during the pre-flood and post-flood periods on the Garrison Reach and Lake Sakakawea, North Dakota, to determine how this event influenced these species (both species on the Garrison Reach, and plovers only on Lake Sakakawea). The principal parameters we measured (nest survival, chick survival, and breeding population) showed spatial and temporal variation typical of opportunistic species occupying highly variable habitats. There was little evidence that nest survival of least terns differed between pre- and post-flood. During 2012 when habitat was most abundant on the Garrison Reach and Lake Sakakawea, piping plover nest survival was higher than in any other year in the study, but returned to rates comparable to pre-flood years in 2013. Chick survival for terns on the Garrison Reach and plovers on Lake Sakakawea showed a similar pattern to plover nest survival, with the 2012 rate exceeding all other years of the study, and the remaining pre-flood and post-flood years being generally similar but slightly higher in post-flood years. However, plover chick survival on the Garrison Reach in 2012 was similar to pre-flood years, and increased annually thereafter to its highest rate in 2014. Although wide confidence intervals precluded firm conclusions about flood effects on breeding populations, the general pattern suggested lower populations of plovers but higher populations of least terns immediately after the flood. Despite near total absence of breeding habitat on either study area during the flood of 2011, populations of both species persisted after the flood due to their propensity to disperse and/or forgo breeding for at least a year. Tern and plover populations have similarly persisted and recovered after the flood, but their mechanisms for persistence likely differ. Data on tern dispersal is generally lacking, but they are thought to show little fidelity to their natal grounds, have a propensity to disperse potentially long distances, and routinely forgo breeding until their second year, thus a lost opportunity to breed in a given area may be easily overcome. Plovers exhibit stronger demographic ties to the general area in which they previously nested, yet they occupy much broader nesting habitat features than terns and exploit three major landforms in the Dakotas (free-flowing rivers, reservoir shorelines, and wetland shorelines). Consequently, dispersal to and from non-Missouri River habitats and potential to exploit non-traditional habitats likely sustained the Northern Great Plains population through the flood event. Terns and plovers normally occupy similar habitats on the Missouri River and both species experienced similar loss of a breeding season due to the flood. Persistence of these populations after the flood underscores the importance of understanding their unique demographic characteristics and the context within which the Missouri River operates.

North Dakota

Trends in nutrient concentration and load for streams in the Mississippi River Basin, 1974-94

Trends in nutrient concentration and load are computed for 40 stations on 24 streams in the Mississippi River Basin. The drainage area of the Mississippi Basin covers about 42 percent of the conterminous United States, and the Mississippi River discharges about 420 billion gallons per day of freshwater to the Gulf of Mexico. The period for which trends are analyzed varies for each station but generally comprises water years 1974&ndash;94. Stations included in this analysis are part of the National Stream Quality Accounting Network operated by the U.S. Geological Survey. LOWESS (LOcally WEighted Scatterplot Smoothing) smooth lines superimposed on graphs of flow-adjusted residuals of concentration versus time and load versus time indicate short-term trends for each station. Kendall-Theil robust lines superimposed on the same graphs indicate long-term trends. Long-term trends were evaluated using the slope of the Kendall-Theil robust line and Kendall&rsquo;s tau. Annual loads are estimated with regression analysis and corrected for log-transformation bias with the MVUE (Minimum Variance Unbiased Estimator). Trends in annual streamflow are presented to aid in the interpretation of nutrient trends. Statistically significant long-term increases in flow-adjusted residual concentrations of total nitrogen were detected at 14 stations, decreases were detected at 6 stations, and no significant trends were detected at 20 stations. Statistically significant long-term increases in total nitrogen load were detected at 5 stations, decreases were detected at 4 stations, and no significant trends were detected at 31 stations. Statistically significant long-term increases in flow-adjusted residual concentrations of total phosphorus were detected at 2 stations, decreases were detected at 25 stations, and no significant trends were detected at 13 stations. Statistically significant long-term increases in total phosphorus load were detected at 1 station, decreases were detected at 13 stations, and no significant trends were detected at 26 stations. The mean annual yields were computed from the estimated mean annual loads. Mean annual nitrogen yields are largest for three watersheds in the upper Mississippi Basin; estimated yield of each is greater than 5.0 tons per square mile. Nine stations in the Ohio River Basin have estimated mean annual nitrogen yields greater than 2.0 tons per square mile. Estimated mean annual phosphorus yield is greater than 0.250 ton per square mile at 7 stations, 5 in the Ohio Basin and 2 in the upper Mississippi Basin. Statistically significant trends in annual streamflow were detected at seven stations. Annual streamflow influences trends in load, even when the streamflow trends are not statistically significant.

Mississippi River Basin