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Numerical analysis of the effect of subgrid variability in a physically based hydrological model on runoff, soil moisture, and slope stability

In coarse resolution hydrological modeling we face the problem of subgrid variability, the effects of which are difficult to express and are often hidden in the parameterization and calibration. We present a numerical experiment with the physically based hydrological model ParFlow‐CLM with which we quantify the effect of subgrid heterogeneities in headwater catchments within the cell size typically used for regional hydrological applications. We simulate homogeneous domains and domains with subgrid heterogeneities in topography or soil thickness for two climates and soil types. The presence of side slope is the main error source, leading to large underestimation of runoff, and marginally also of evapotranspiration. The spatial distribution of soil saturation in the presence of subgrid variability in topography also leads to underestimation of landslide risk. Soil thickness is the second influential subgrid property, affecting soil moisture distribution and surface runoff formation. Results are consistent for the climates and the soil types considered. The topographic wetness index approach is tested as a way to downscale soil moisture simulations within the domain. Although this method is successful in reproducing some spatial variability and patterns, it fails when the coarse grid mean soil saturation is inaccurate or subgrid topography does not represent subsurface flow paths accurately. We conclude that ignoring subgrid variability in topography and soil thickness in coarse‐scale hydrological models may lead locally to underestimation of runoff and slope instability. Users of such models should be aware of these biases and consider ways to include subgrid effects in coarse‐scale hydrological predictions.

Water Resources Research

Climatic controls on soil carbon accumulation and loss in a dryland ecosystems

Arid and semiarid ecosystems drive year-to-year variability in the strength of the terrestrial carbon (C) sink, yet there is uncertainty about how soil C gains and losses contribute to this variation. To address this knowledge gap, we embedded C-depleted soil mesocosms, containing litter or biocrust C inputs, within an in situ dryland ecosystem warming experiment. Over the course of one year, changes in microbial biomass and total soil organic C pools were monitored alongside hourly measurements of soil CO 2 flux. We also developed a biogeochemical model to explore the mechanisms that gave rise to observed soil C dynamics. Field data and model simulations demonstrated that water exerted much stronger control on soil biogeochemistry than temperature, with precipitation events triggering large CO 2 pulses and transport of litter- and biocrust-derived C into the soil profile. We expected leaching of organic matter would result in steady accumulation of C within the mineral soil over time. Instead, the size of the total organic C pool fluctuated throughout the year, largely in response to microbial growth: increases in the size of microbial biomass were negatively correlated with the quantity of C residing in the top 2 cm, where most biogeochemical changes were observed. Our data and models suggest that microbial responses to precipitation events trigger rapid metabolism of dissolved organic C inputs, which strongly limit accumulation of autotroph-derived C belowground. Accordingly, changes in the magnitude and/or frequency of precipitation events in this dryland ecosystem could have profound impacts on the strength of the soil C sink.

Utah

Vegetation loss following vertical drowning of Mississippi River deltaic wetlands leads to faster microbial decomposition and decreases in soil carbon

Wetland ecosystems hold nearly a third of the global soil carbon pool, but as wetlands rapidly disappear the fate of this stored soil carbon is unclear. The aim of this study was to quantify and then link potential rates of microbial decomposition after vertical drowning of vegetated tidal marshes in coastal Louisiana to known drivers of anaerobic decomposition altered by vegetation loss. Profiles of potential CH 4 and CO 2 production (surface to 60 cm deep) were measured during anaerobic incubations, organic matter chemistry was assessed with infrared spectroscopy, and soil porewater nutrients and redox potentials were measured in the field along a chronosequence of wetland loss. After vertical drowning, pond soils had lower redox potentials, higher pH values, lower soil carbon and nitrogen concentrations, lower lignin: polysaccharide ratios, more NH 4 + and PO 4 3− , and higher rates of potential CO 2 release than vegetated marsh soils. Potential CH 4 production was similar in vegetated marshes and open water ponds, with depth-dependent decreases in CH 4 production as soil carbon concentrations increased. In these anoxic soils, vegetation loss exerts a primary control on decomposition rates because flooding drives sustained increases in porewater nutrient availability (NH 4 + and PO 4 3 , dissolved organic carbon) and decreases in redox potential (from −150 to −500 mV) that lead to higher potential CO 2 fluxes within a few years. Without new carbon inputs following wetland loss, the sustained decomposition in open water ponds may lead to losses of stored soil carbon and could influence global carbon budgets.

Louisiana

Carbon flow from volcanic CO 2 into soil microbial communities of a wetland mofette

Effects of extremely high carbon dioxide (CO 2 ) concentrations on soil microbial communities and associated processes are largely unknown. We studied a wetland area affected by spots of subcrustal CO 2 degassing (mofettes) with focus on anaerobic autotrophic methanogenesis and acetogenesis because the pore gas phase was largely hypoxic. Compared with a reference soil, the mofette was more acidic (ΔpH ~0.8), strongly enriched in organic carbon (up to 10 times), and exhibited lower prokaryotic diversity. It was dominated by methanogens and subdivision 1Acidobacteria, which likely thrived under stable hypoxia and acidic pH. Anoxic incubations revealed enhanced formation of acetate and methane (CH 4 ) from hydrogen (H 2 ) and CO 2 consistent with elevated CH 4 and acetate levels in the mofette soil. 13 CO 2 mofette soil incubations showed high label incorporations with ~512   ng 13 C   g   (dry weight (dw)) soil −1   d −1 into the bulk soil and up to 10.7   ng 13 C   g   (dw) soil −1   d −1 into almost all analyzed bacterial lipids. Incorporation of CO 2 -derived carbon into archaeal lipids was much lower and restricted to the first 10   cm of the soil. DNA-SIP analysis revealed that acidophilic methanogens affiliated withMethanoregulaceae and hitherto unknown acetogens appeared to be involved in the chemolithoautotrophic utilization of 13 CO 2 . Subdivision 1 Acidobacteriaceae assimilated 13 CO 2 likely via anaplerotic reactions because Acidobacteriaceae are not known to harbor enzymatic pathways for autotrophic CO 2 assimilation. We conclude that CO 2 -induced geochemical changes promoted anaerobic and acidophilic organisms and altered carbon turnover in affected soils.

The ISME Journal

Soil water availability shapes species richness in mid-latitude shrub steppe plant communities

Questions Ecological communities are controlled by multiple, interacting abiotic and biotic factors that influence the distribution, abundance, and diversity of species. These processes jointly determine resource availability, resource competition, and ultimately species richness. For many terrestrial ecosystems in dryland climates, soil water availability is the most frequent limiting resource for plant species. We used field sampling coupled with process‐based soil water balance modeling to explore the relative importance of multiple macroclimatic, ecohydrological, and biotic variables on plant species and functional type richness at the landscape scale in dryland plant communities. Location Dryland plant communities dominated by big sagebrush ( Artemisia tridentata ) that span climatic and elevational gradients in Wyoming, USA. Methods We quantified species richness at 1,000 m 2 and used multiple regression to determine whether mean climatic conditions, multiple metrics of soil moisture from a soil water balance model (SOILWAT2), soil physical and chemical properties, and shrub stand structure (biotic) variables were related to species and functional type richness. Results Species richness varied between 16 and 54 across sites. We found that species and functional type richness were related to both macroclimate and ecohydrology, but ecohydrology explained slightly more variation than climate. Biotic variables were always secondary to macroclimate and ecohydrology in our models. Variance partitioning revealed that large portions of variability in species (~54%), forb (~47%), and grass (~40%) richness were explained by ecohydrological variables. Conclusions Our results highlight the importance of the spatial and temporal distribution of soil water for dryland plant species richness and suggest that documenting the ways in which climate, vegetation, and soil properties interact to determine soil water availability is critical for understanding biodiversity patterns in dryland plant communities. This work has relevance for other mid‐latitude, shrub‐dominated dryland plant communities where soil water availability strongly influences ecosystem structure and function.

Wyoming

Soil respiration and photosynthetic uptake of carbon dioxide by ground-cover plants in four ages of jack pine forest

Soil carbon dioxide (CO2) emission (soil respiration), net CO2 exchange after photosynthetic uptake by ground-cover plants, and soil CO2 concentration versus depth below land surface were measured at four ages of jack pine (Pinus banksiana Lamb.) forest in central Saskatchewan. Soil respiration was smallest at a clear-cut site, largest in an 8-year-old stand, and decreased with stand age in 20-year-old and mature (60-75 years old) stands during May-September 1994 (12.1, 34.6, 31.5, and 24.9 mol C??m-2, respectively). Simulations of soil respiration at each stand based on continuously recorded soil temperature were within one standard deviation of measured flux for 48 of 52 measurement periods, but were 10%-30% less than linear interpolations of measured flux for the season. This was probably due to decreased soil respiration at night modeled by the temperature-flux relationships, but not documented by daytime chamber measurements. CO2 uptake by ground-cover plants ranged from 0 at the clear-cut site to 29, 25, and 9% of total growing season soil respiration at the 8-year, 20-year, and mature stands. CO2 concentrations were as great as 7150 ppmv in the upper 1 m of unsaturated zone and were proportional to measured soil respiration.

Canadian Journal of Forest Research

Below the disappearing marshes of an urban estuary: historic nitrogen trends and soil structure

Marshes in the urban Jamaica Bay Estuary, New York, USA are disappearing at an average rate of 13 ha/yr, and multiple stressors (e.g., wastewater inputs, dredging activities, groundwater removal, and global warming) may be contributing to marsh losses. Among these stressors, wastewater nutrients are suspected to be an important contributing cause of marsh deterioration. We used census data, radiometric dating, stable nitrogen isotopes, and soil surveys to examine the temporal relationships between human population growth and soil nitrogen; and we evaluated soil structure with computer-aided tomography, surface elevation and sediment accretion trends, carbon dioxide emissions, and soil shear strength to examine differences among disappearing (Black Bank and Big Egg) and stable marshes (JoCo). Radiometric dating and nitrogen isotope analyses suggested a rapid increase in human wastewater nutrients beginning in the late 1840s, and a tapering off beginning in the 1930s when wastewater treatment plants (WWTPs) were first installed. Current WWTPs nutrient loads to Jamaica Bay are approximately 13 995 kg N/d and 2767 kg P/d. At Black Bank, the biomass and abundance of roots and rhizomes and percentage of organic matter on soil were significantly lower, rhizomes larger in diameter, carbon dioxide emission rates and peat particle density significantly greater, and soil strength significantly lower compared to the stable JoCo Marsh, suggesting Black Bank has elevated decomposition rates, more decomposed peat, and highly waterlogged peat. Despite these differences, the rates of accretion and surface elevation change were similar for both marshes, and the rates of elevation change approximated the long term relative rate of sea level rise estimated from tide gauge data at nearby Sandy Hook, New Jersey. We hypothesize that Black Bank marsh kept pace with sea level rise by the accretion of material on the marsh surface, and the maintenance of soil volume through production of larger diameter rhizomes and swelling (dilation) of waterlogged peat. JoCo Marsh kept pace with sea-level rise through surface accretion and soil organic matter accumulation. Understanding the effects of multiple stressors, including nutrient enrichment, on soil structure, organic matter accumulation, and elevation change will better inform management decisions aimed at maintaining and restoring coastal marshes.

New York

Evaluating microbial purification during soil treatment of wastewater with multicomponent tracer and surrogate tests

Soil treatment of wastewater has the potential to achieve high purification efficiency, yet the understanding and predictability of purification with respect to removal of viruses and other pathogens is limited. Research has been completed to quantify the removal of virus and bacteria through the use of microbial surrogates and conservative tracers during controlled experiments with three-dimensional pilot-scale soil treatment systems in the laboratory and during the testing of full-scale systems under field conditions. The surrogates and tracers employed included two viruses (MS-2 and PRID-1 bacteriophages), one bacterium (ice-nucleating active Pseudomonas ), and one conservative tracer (bromide ion). Efforts have also been made to determine the relationship between viruses and fecal coliform bacteria in soil samples below the wastewater infiltrative surface, and the correlation between Escherichia coli concentrations measured in percolating soil solution as compared with those estimated from analyses of soil solids. The results suggest episodic breakthrough of virus and bacteria during soil treatment of wastewater and a 2 to 3 log (99-99.9%) removal of virus and near complete removal of fecal coliform bacteria during unsaturated flow through 60 to 90 cm of sandy medium. Results also suggest that the fate of fecal coliform bacteria may be indicative of that of viruses in soil media near the infiltrative surface receiving wastewater effluent. Concentrations of fecal coliform in percolating soil solution may be conservatively estimated from analysis of extracted soil solids.

Journal of Environmental Quality

Measurement of net nitrogen and phosphorus mineralization in wetland soils using a modification of the resin-core technique

A modification of the resin-core method was developed and tested for measuring in situ soil N and P net mineralization rates in wetland soils where temporal variation in bidirectional vertical water movement and saturation can complicate measurement. The modified design includes three mixed-bed ion-exchange resin bags located above and three resin bags located below soil incubating inside a core tube. The two inner resin bags adjacent to the soil capture NH 4 + , NO 3 - , and soluble reactive phosphorus (SRP) transported out of the soil during incubation; the two outer resin bags remove inorganic nutrients transported into the modified resin core; and the two middle resin bags serve as quality-control checks on the function of the inner and outer resin bags. Modified resin cores were incubated monthly for a year along the hydrogeomorphic gradient through a floodplain wetland. Only small amounts of NH 4 + , NO 3 - , and SRP were found in the two middle resin bags, indicating that the modified resin-core design was effective. Soil moisture and pH inside the modified resin cores typically tracked changes in the surrounding soil abiotic environment. In contrast, use of the closed polyethylene bag method provided substantially different net P and N mineralization rates than modified resin cores and did not track changes in soil moisture or pH. Net ammonification, nitrifi cation, N mineralization, and P mineralization rates measured using modified resin cores varied through space and time associated with hydrologic, geomorphic, and climatic gradients in the floodplain wetland. The modified resin-core technique successfully characterized spatiotemporal variation of net mineralization fluxes in situ and is a viable technique for assessing soil nutrient availability and developing ecosystem budgets.

Biogeochemistry

Growth and invasive potential of Sapium sebiferum (Euphorbiaceae) within the coastal prairie region: the effects of soil and moisture regime

The introduced tree Sapium sebiferum (Euphorbiaceae) is considered a serious threat to the preservation of the coastal prairie region of Louisiana and Texas, although it is currently uncommon in the western part of the region. The objective of this study was to evaluate the potential effects of location, soils, and available moisture on the growth and survival of S. sebiferum in coastal prairie. In a field experiment, S. sebiferum mortality was significantly greater at a western site than at central and eastern sites. The greatest mortality and least growth of surviving plants occurred on a soil from the western region, regardless of site. A greenhouse study also found that S. sebiferum growth was lowest on the western soil. Watering frequency significantly affected S. sebiferum growth, except on the western soil. Sapium sebiferum growth responded to both nitrogen and phosphorum additions for all soils. Soil analyses revealed the highest sand, sodium, and phosphorus contents, and much higher electrical conductivity in the western soil. It is concluded that the soil examined from the western region is unfavorable for S. sebiferum growth, though not to the extent to preclude S. sebiferum completely. Evidence suggests that soil salinity may be the primary cause of the poor S. sebiferum growth at the western site.

Louisiana, Texas

Soil nitrogen accretion along a floodplain terrace chronosequence in northwest Alaska: Influence of the nitrogen-fixing shrub Shepherdia canadensis

Nitrogen enters terrestrial ecosystems through multiple pathways during primary succession. We measured accumulation of total soil nitrogen and changes in inorganic nitrogen (N) pools across a 300-y sequence of river terraces in northwest Alaska and assessed the contribution of the nitrogen-fixing shrub Shepherdia canadensis . Our work compared 5 stages of floodplain succession, progressing from a sparsely vegetated silt cap to dense shrubby vegetation, balsam poplar-dominated ( Populus balsamifera ) and white spruce-dominated ( Picea glauca ) mixed forests, and old-growth white spruce forest. Total soil N (0–30 cm depth) increased throughout the age sequence, initially by 2.4 g N·m −2 ·y −1 during the first 120 y of terrace development, then by 1.6 g N·m −2 ·y −1 during the subsequent 2 centuries. Labile soil N, measured by anaerobic incubation, increased most rapidly during the first 85 y of terrace formation, then remained relatively constant during further terrace development. On recently formed terraces, Shepherdia shrubs enriched soil N pools several-fold compared to soil beneath Salix spp. shrubs or intercanopy sites. Total and labile soil N accretion was proportional to Shepherdia cover during the first century of terrace development, and mineral soil δ 15 N content indicated that newly formed river terraces receive substantial N through N-fixation. About half the 600 g total N·m −2 accumulated across the river terrace chronosequence occurred during the 120 y when S. canadensis was dominant. Sediment deposited by periodic flooding continued to add N to terrace soils after the decline in Shepherdia abundance and may have contributed 25% of the total N found in the floodplain terrace soils.

Alaska

Micrometeorological, evapotranspiration, and soil-moisture data at the Amargosa Desert Research site in Nye County near Beatty, Nevada, 2006-11

This report describes micrometeorological, evapotranspiration, and soil-moisture data collected since 2006 at the Amargosa Desert Research Site adjacent to a low-level radio-active waste and hazardous chemical waste facility near Beatty, Nevada. Micrometeorological data include precipitation, solar radiation, net radiation, air temperature, relative humidity, saturated and ambient vapor pressure, wind speed and direction, barometric pressure, near-surface soil temperature, soil-heat flux, and soil-water content. Evapotranspiration (ET) data include latent-heat flux, sensible-heat flux, net radiation, soil-heat flux, soil temperature, air temperature, vapor pressure, and other principal energy-budget data. Soil-moisture data include periodic measurements of volumetric water-content at experimental sites that represent vegetated native soil, devegetated native soil, and simulated waste disposal trenches - maximum measurement depths range from 5.25 to 29.25 meters. All data are compiled in electronic spreadsheets that are included with this report.

Nevada

Mississippi Basin Carbon Project: Upland soil database for sites in Nishnabotna River basin, Iowa

The conversion of land from its native state to an agricultural use commonly results in a significant loss of soil carbon (Mann, 1985; Davidson and Ackerman, 1993). Globally, this loss is estimated to account for as much as 1/3 of the net CO 2 emissions for the period of 1850 to 1980 (Houghton and others, 1983). Roughly 20 to 40 percent of original soil carbon is estimated to be lost as CO 2 as a result of agricultural conversion, or "decomposition enhancement". Global models use this estimate along with land conversion data to provide agricultural contributions of CO 2 emissions for global carbon budgets (Houghton and others, 1983; Schimel, 1995). Soil erosion rates are significantly (10X) higher on croplands than on their undisturbed equivalents (Dabney and others, 1997). Most of the concern over erosion is related to diminished productivity of the uplands (Stallings, 1957; McGregor and others, 1969; Rhoton, 1990) or to increased hazards and navigability of the lowlands in the late 1800's to early 1900's. Yet because soil carbon is concentrated at the soil surface, with an exponential decline in concentration with depth (Harden et al, 1999), it is clear that changes in erosion rates seen on croplands must also impact soil carbon storage and terrestrial carbon budgets as well. As yet, erosional losses of carbon are not included in global carbon budgets explicitly as a factor in land conversion nor implicitly as a portion of the decomposition enhancement. However, recent work by Lal and others (1995) and by Stallard (1998) suggests that significant amounts of eroded soil may be stored in man-made reservoirs and depositional environments as a result of agricultural conversion. Moreover, Stallard points out that eroding soils have the potential for replacing part of the carbon trapped in man-made reservoirs. If true, then the global carbon budget may grossly underestimate or ignore a significant sink term resulting from the burial of eroded soil.

Iowa

Part A: Geochemistry of Soil Samples from 50 Solution-Collapse Features on the Coconino Plateau, Northern Arizona

Soil sampling surveys were conducted during 1984-1986 across 50 solution-collapse features exposed on the Coconino Plateau of northern Arizona in order to determine whether soil geochemistry can be used to distinguish mineralized breccia pipes from unmineralized collapse features. The 50 sampled features represent the variety of collapse features that crop out on plateau surfaces in northwestern Arizonaoodeeplyorooted solution-collapse breccia pipes, near-surface gypsum collapses, and sinkholes. Of the 50 features that were sampled in this study, 3 are confirmed breccia pipes that contain significant uranium and base-metal minerals, I is believed to be a sinkhole with no economic potential, and 4 are stratabound copper deposits whose possible relationship to breccia pipes is yet to be determined. The remaining collapse features are suspected to overlie breccia pipes, although some of these may represent near surface gypsum collapse features. However, no exploratory drilling results or breccia exposures exist to indicate their underlying structure. The low cost and ease of soil sampling suggested that this technique be evaluated for breccia pipe exploration. This report provides the locations and geochemical results for the soil sampling surveys and brief descriptions of the 50 collapse features. The analytical results of almost 2,000 soil samples are provided in tabular hardcopy and dBase III Plus diskcopy format. The analytical data is provided in digital format to allow the reader to choose their own methods for evaluating the effectiveness of soil sampling over known and suspected breccia pipes. A pilot survey conducted over 17 collapse features in 1984 suggested that soil sampling might be useful in distinguishing mineralized breccia pipes from other circular features. Followup detailed surveys in 1985 and 1986 used a radial sampling pattern at each of 50 sites; at least one third of the samples were collected from areas outside of the collapse feature to provide background data. Samples were consistently collected from 3-4 inches depth after the pilot survey showed that metal concentrations were similar in samples from 3-4 inches and 7-8 inches depth. The geochemical analyses of the <80 mesh fractions of the soil samples were performed by the U.S. Geological Survey Analytical Laboratories and Geochemical Services, Inc. The analytical methods applied to these samples by the U.S. Geological Survey laboratories included inductively coupled plasma-atomic emission spectroscopy, X-ray fluorescence spectrometry, neutron activation, atomic absorption, delayed neutron activation, and classical wet chemistry for carbon, fluorine, and sulfur. Geochemical Services, Inc. analyzed the soil samples by inductively coupled plasma emission spectroscopy.

Open-File Report

Geochemistry of Soil Samples from 50 Solution-Collapse Features on the Coconino Plateau, Northern Arizona

Soil sampling surveys were conducted during 1984-1986 across 50 solution-collapse features exposed on the Coconino Plateau of northern Arizona in order to determine whether soil geochemistry can be used to distinguish mineralized breccia pipes from unmineralized collapse features. The 50 sampled features represent the variety of collapse features that crop out on plateau surfaces in northwestern Arizonaoodeeplyorooted solution-collapse breccia pipes, near-surface gypsum collapses, and sinkholes. Of the 50 features that were sampled in this study, 3 are confirmed breccia pipes that contain significant uranium and base-metal minerals, I is believed to be a sinkhole with no economic potential, and 4 are stratabound copper deposits whose possible relationship to breccia pipes is yet to be determined. The remaining collapse features are suspected to overlie breccia pipes, although some of these may represent near surface gypsum collapse features. However, no exploratory drilling results or breccia exposures exist to indicate their underlying structure. The low cost and ease of soil sampling suggested that this technique be evaluated for breccia pipe exploration. This report provides the locations and geochemical results for the soil sampling surveys and brief descriptions of the 50 collapse features. The analytical results of almost 2,000 soil samples are provided in tabular hardcopy and dBase III Plus diskcopy format. The analytical data is provided in digital format to allow the reader to choose their own methods for evaluating the effectiveness of soil sampling over known and suspected breccia pipes. A pilot survey conducted over 17 collapse features in 1984 suggested that soil sampling might be useful in distinguishing mineralized breccia pipes from other circular features. Followup detailed surveys in 1985 and 1986 used a radial sampling pattern at each of 50 sites; at least one third of the samples were collected from areas outside of the collapse feature to provide background data. Samples were consistently collected from 3-4 inches depth after the pilot survey showed that metal concentrations were similar in samples from 3-4 inches and 7-8 inches depth. The geochemical analyses of the <80 mesh fractions of the soil samples were performed by the U.S. Geological Survey Analytical Laboratories and Geochemical Services, Inc. The analytical methods applied to these samples by the U.S. Geological Survey laboratories included inductively coupled plasma-atomic emission spectroscopy, X-ray fluorescence spectrometry, neutron activation, atomic absorption, delayed neutron activation, and classical wet chemistry for carbon, fluorine, and sulfur. Geochemical Services, Inc. analyzed the soil samples by inductively coupled plasma emission spectroscopy.

Open-File Report

Part B: Geochemistry of Soil Samples from 50 Solution-Collapse Features on the Coconino Plateau, Northern Arizona

Soil sampling surveys were conducted during 1984-1986 across 50 solution-collapse features exposed on the Coconino Plateau of northern Arizona in order to determine whether soil geochemistry can be used to distinguish mineralized breccia pipes from unmineralized collapse features. The 50 sampled features represent the variety of collapse features that crop out on plateau surfaces in northwestern Arizonaoodeeplyorooted solution-collapse breccia pipes, near-surface gypsum collapses, and sinkholes. Of the 50 features that were sampled in this study, 3 are confirmed breccia pipes that contain significant uranium and base-metal minerals, I is believed to be a sinkhole with no economic potential, and 4 are stratabound copper deposits whose possible relationship to breccia pipes is yet to be determined. The remaining collapse features are suspected to overlie breccia pipes, although some of these may represent near surface gypsum collapse features. However, no exploratory drilling results or breccia exposures exist to indicate their underlying structure. The low cost and ease of soil sampling suggested that this technique be evaluated for breccia pipe exploration. This report provides the locations and geochemical results for the soil sampling surveys and brief descriptions of the 50 collapse features. The analytical results of almost 2,000 soil samples are provided in tabular hardcopy and dBase III Plus diskcopy format. The analytical data is provided in digital format to allow the reader to choose their own methods for evaluating the effectiveness of soil sampling over known and suspected breccia pipes. A pilot survey conducted over 17 collapse features in 1984 suggested that soil sampling might be useful in distinguishing mineralized breccia pipes from other circular features. Followup detailed surveys in 1985 and 1986 used a radial sampling pattern at each of 50 sites; at least one third of the samples were collected from areas outside of the collapse feature to provide background data. Samples were consistently collected from 3-4 inches depth after the pilot survey showed that metal concentrations were similar in samples from 3-4 inches and 7-8 inches depth. The geochemical analyses of the <80 mesh fractions of the soil samples were performed by the U.S. Geological Survey Analytical Laboratories and Geochemical Services, Inc. The analytical methods applied to these samples by the U.S. Geological Survey laboratories included inductively coupled plasma-atomic emission spectroscopy, X-ray fluorescence spectrometry, neutron activation, atomic absorption, delayed neutron activation, and classical wet chemistry for carbon, fluorine, and sulfur. Geochemical Services, Inc. analyzed the soil samples by inductively coupled plasma emission spectroscopy.

Open-File Report

Part C: Geochemistry of Soil Samples from 50 Solution-Collapse Features on the Coconino Plateau, Northern Arizona

Soil sampling surveys were conducted during 1984-1986 across 50 solution-collapse features exposed on the Coconino Plateau of northern Arizona in order to determine whether soil geochemistry can be used to distinguish mineralized breccia pipes from unmineralized collapse features. The 50 sampled features represent the variety of collapse features that crop out on plateau surfaces in northwestern Arizonaoodeeplyorooted solution-collapse breccia pipes, near-surface gypsum collapses, and sinkholes. Of the 50 features that were sampled in this study, 3 are confirmed breccia pipes that contain significant uranium and base-metal minerals, I is believed to be a sinkhole with no economic potential, and 4 are stratabound copper deposits whose possible relationship to breccia pipes is yet to be determined. The remaining collapse features are suspected to overlie breccia pipes, although some of these may represent near surface gypsum collapse features. However, no exploratory drilling results or breccia exposures exist to indicate their underlying structure. The low cost and ease of soil sampling suggested that this technique be evaluated for breccia pipe exploration. This report provides the locations and geochemical results for the soil sampling surveys and brief descriptions of the 50 collapse features. The analytical results of almost 2,000 soil samples are provided in tabular hardcopy and dBase III Plus diskcopy format. The analytical data is provided in digital format to allow the reader to choose their own methods for evaluating the effectiveness of soil sampling over known and suspected breccia pipes. A pilot survey conducted over 17 collapse features in 1984 suggested that soil sampling might be useful in distinguishing mineralized breccia pipes from other circular features. Followup detailed surveys in 1985 and 1986 used a radial sampling pattern at each of 50 sites; at least one third of the samples were collected from areas outside of the collapse feature to provide background data. Samples were consistently collected from 3-4 inches depth after the pilot survey showed that metal concentrations were similar in samples from 3-4 inches and 7-8 inches depth. The geochemical analyses of the <80 mesh fractions of the soil samples were performed by the U.S. Geological Survey Analytical Laboratories and Geochemical Services, Inc. The analytical methods applied to these samples by the U.S. Geological Survey laboratories included inductively coupled plasma-atomic emission spectroscopy, X-ray fluorescence spectrometry, neutron activation, atomic absorption, delayed neutron activation, and classical wet chemistry for carbon, fluorine, and sulfur. Geochemical Services, Inc. analyzed the soil samples by inductively coupled plasma emission spectroscopy.

Open-File Report

Part D: Geochemistry of Soil Samples from 50 Solution-Collapse Features on the Coconino Plateau, Northern Arizona

Soil sampling surveys were conducted during 1984-1986 across 50 solution-collapse features exposed on the Coconino Plateau of northern Arizona in order to determine whether soil geochemistry can be used to distinguish mineralized breccia pipes from unmineralized collapse features. The 50 sampled features represent the variety of collapse features that crop out on plateau surfaces in northwestern Arizonaoodeeplyorooted solution-collapse breccia pipes, near-surface gypsum collapses, and sinkholes. Of the 50 features that were sampled in this study, 3 are confirmed breccia pipes that contain significant uranium and base-metal minerals, I is believed to be a sinkhole with no economic potential, and 4 are stratabound copper deposits whose possible relationship to breccia pipes is yet to be determined. The remaining collapse features are suspected to overlie breccia pipes, although some of these may represent near surface gypsum collapse features. However, no exploratory drilling results or breccia exposures exist to indicate their underlying structure. The low cost and ease of soil sampling suggested that this technique be evaluated for breccia pipe exploration. This report provides the locations and geochemical results for the soil sampling surveys and brief descriptions of the 50 collapse features. The analytical results of almost 2,000 soil samples are provided in tabular hardcopy and dBase III Plus diskcopy format. The analytical data is provided in digital format to allow the reader to choose their own methods for evaluating the effectiveness of soil sampling over known and suspected breccia pipes. A pilot survey conducted over 17 collapse features in 1984 suggested that soil sampling might be useful in distinguishing mineralized breccia pipes from other circular features. Followup detailed surveys in 1985 and 1986 used a radial sampling pattern at each of 50 sites; at least one third of the samples were collected from areas outside of the collapse feature to provide background data. Samples were consistently collected from 3-4 inches depth after the pilot survey showed that metal concentrations were similar in samples from 3-4 inches and 7-8 inches depth. The geochemical analyses of the <80 mesh fractions of the soil samples were performed by the U.S. Geological Survey Analytical Laboratories and Geochemical Services, Inc. The analytical methods applied to these samples by the U.S. Geological Survey laboratories included inductively coupled plasma-atomic emission spectroscopy, X-ray fluorescence spectrometry, neutron activation, atomic absorption, delayed neutron activation, and classical wet chemistry for carbon, fluorine, and sulfur. Geochemical Services, Inc. analyzed the soil samples by inductively coupled plasma emission spectroscopy.

Open-File Report