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Water-resources appraisal of the Wet Mountain Valley, in parts of Custer and Fremont counties, Colorado

The Wet Mountain Valley is an intermontane trough filled to a depth of at least 6,700 feet with unconsolidated deposits. Ground water occurs under both artesian and water-table conditions within the basin-fill aquifer and ground-water moverment is toward Grape and Texas Creeks. The depth to the water table is less than 10 feet in an area of about 40 square miles along the central part of the valley and is less than 100 feet in most of the remainder of the valley. Ground water stored in the upper 200 feet of saturated basin-fill sediments is estimated to total 1.5 million acre-feet. Yields greater than 50 gallons per minute generally can be expected from wells in the central part of the basin-fill aquifer, and yields less than 50 gallons per minute are generally reported from wells around the edge of the basin-fill aquifer. Yields of wells in the mountainous areas are generally less than 20 gallons per minute. Most streamflow occurs as a result of snowmelt runoff during June and July. The long-term annual runoff at seven stations ranges from an estimated 0.02 cubic foot per second per square mile to an estimated 1.17 cubic feet per second per square mile, generaly increasing with station altitude. Generalized annyal water budgets for two areas in the Wet Mountain Valley indicate that surface-water outflow is only 7 to 11 percent of the total water supply from precipitation and other sources. The remaining water is lost to the atmosphere by evapotranspiration. The quality of both the surface and ground water is generally within the recommended limits for drinking water set by the U.S. Public Health Service. (Woodard-USGS)

Water-Resources Investigations Report

Chemical analyses of surface water in Illinois, 1958–74—Volume I, Des Plaines River basin and Lake Michigan

Samples of surface water were collected and analyzed by the Illinois Environmental Protection Agency and its predecessor, the Stream Pollution Control Bureau of the Illinois Department of Public Health. The results for the period 1958 to 1974 are presented in tabular form and the history of sampling and analytical methods are summarized. Stream discharge data from records of the U.S. Geological Survey are included for all sites where samples were collected at gaging stations or near enough that reliable discharge estimates could be made. The report is contained in three volumes. This volume (Volume I) includes Des Plaines River basin and Lake Michigan. (See also W78-10035 and W78-10036).

Illinois

Chemical analyses of surface water in Illinois, 1958–74—Volume II, Illinois River basin and Mississippi River tributaries north of Illinois River basin

Samples of surface water were collected and analyzed by the Illinois Environmental Protection Agency and its predecessor, the Stream Pollution Control Bureau of the Illinois Department of Public Health. The results for the period 1958 to 1974 are presented in tabular form and the history of sampling and analytical methods are included for all sites where samples were collected at gaging stations or near enough that reliable discharge estimates could be made. The report is contained in three volumes. This volume (Volume II) includes Illinois River basin and Mississippi River tributaries north of Illinois River basin. (See also W78-10034 and W78-10036)

Illinois

Chemical, physical, and radiological quality of selected public water supplies in Florida, November 1977-February 1978

Virtually all treated public water supplies sampled in Florida meet the National Interim Primary and Proposed Secondary Drinking Water Regulations. These findings are based on a water-quality reconnaissance of 129 treated public supplies throughout the State during the period November 1977 through February 1978. While primary drinking water regulation exceedences were infrequent, lead, selenium, and gross alpha radioactivity in a very few water supplies were above established maximum contaminant levels. Additionally, the secondary drinking water regulation parameters--dissolved solids , chloride, sulfate, iron, color, and pH--were occasionally detected in excess of the proposed Federal regulations. The secondary regulations, however, pertain mainly to the aesthetic quality of drinking water and not directly to public health aspects. (Woodard-USGS)

Water-Resources Investigations Report

Fluoride, Nitrate, and Dissolved-Solids Concentrations in Ground Waters of Washington

This study provides basic data on ground-water quality throughout the State. It is intended for uses in planning and management by agencies and individuals who have responsibility for or interest in, public health and welfare. It also provides a basis for directing future studies of ground-water quality toward areas where ground-water quality problems may already exist. The information presented is a compilation of existing data from numerous sources including: the Washington Departments of Ecology and Social and Health Services, the Environmental Protection Agency, as well as many other local, county, state and federal agencies and private corporations. Only data on fluoride, nitrate, and dissolved-solids concentrations in ground water are presented, as these constituents are among those commonly used to determine the suitability of water for drinking or other purposes. They also reflect both natural and man-imposed effects on water quality and are the most readily available water-quality data for the State of Washington. The percentage of wells with fluoride, nitrate, or dissolved-solids concentrations exceeding U.S. Environmental Protection Agency Primary and Secondary Drinking Water Regulations were about 1, about 3, and about 3, respectively. Most high concentrations occurred in widely separated wells. Two exceptions were: high concentrations of nitrate and dissolved solids in wells on the Hanford Department of Energy Facility and high concentrations of nitrate in the lower Yakima River basin. (USGS)

Water-Resources Investigations Report

Occurrence of beds of low hydraulic conductivity in surficial deposits of Florida

The disposal of municipal and industrial wastes on or at shallow depths below land surface can result in contamination of ground water--the source of drinking water for more than 90 percent of Florida 's residents. This threat to public health has resulted in new State groundwater regulations. Knowledge of the ability of surficial deposits to retard movement of contaminants is important to the implementation of these regulations. This map report shows areas where beds of at least 10 feet thickness with a hydraulic conductivity (saturation) of less than 0.1 foot per day occur within 50 feet below land surface, based mainly on interpretations of lithology. The map is intended as a guide for making preliminary assessments and should not be considered definitive of permeability beneath a specific site. Available determinations of hydraulic conductivities of surficial deposits in Florida are shown in table format. (USGS)

Florida

Water resources of Oley Township, Berks County, Pennsylvania

Oley Township covers an area of 24 square miles, about half of which is underlain by highly permeable carbonate rocks. Nondomestic wells in these rocks typically have yields of 200 gallons per minute, and some wells yield more than 1,000 gallons per minute. Ground-water yield for Oley Township is about 0.5 million gallons per day per square mile. Thus, about 12 million gallons per day could be pumped from wells on a sustained basis. However, pumping this amount would adversely affect streamflow. A series of discharge measurements on Manatawny Creek in January 1983 showed that the creek was gaining approximately 12 cubic feet per second where it crosses the more- permeable carbonate rocks. Thus, the streams are directly connected to these aquifers. The northern and western parts of the township are mostly underlain by shale, quartzite, granite, gneiss, and carbonate rocks of low permeability, and some wells do not yield enough water for domestic supplies. A water-table map shows that two active quarries in low-permeability rocks have had little effect on the hydrologic system. Specific yields are about 4.5 percent for the carbonate rocks; 5 percent for quartzite, granite, and gneiss; 1 percent for the noncarbonate sedimentary rocks; and 1.5 percent for the Jacksonburg Limestone, which consists of argillaceous limestone. In 1982--a year of average precipitation--the ground-water contribution to total streamflow ranged from 56 to 88 percent. Basins with the highest percentage of carbonate rock contribute the largest amount of ground water to streamflow. Evapotranspiration averaged about 26 inches in 1982. Water loss was 32 inches in the Limekiln Creek basin; this suggests that about 6 inches of precipitation bypassed the Limekiln Creek gaging station as ground-water underflow. The most serious water-quality problems are excessive nitrate concentrations and bacterial contamination. Water from 3 of 19 wells in carbonate rocks had nitrate concentrations in excess of the U.S. Environmental Protection Agency maximum contaminant level of 10 milligrams per liter. Water from 5 of the 19 wells had fecal streptococci counts of more than 20 colonies per 100 milliliters. Although most agencies concerned with the protection of public health have not set limits for fecal streptococci, they are pathogenic, and their presence in drinking water is undesirable.

Water-Resources Investigations Report

Analysis of ground-water-quality data of the Upper Colorado River basin, water years 1972-92

As part of the U.S. Geological Survey's National Water-Quality Assessment program, an analysis of the existing ground-water-quality data in the Upper Colorado River Basin study unit is necessary to provide information on the historic water-quality conditions. Analysis of the historical data provides information on the availability or lack of data and water-quality issues. The information gathered from the historical data will be used in the design of ground-water-quality studies in the basin. This report includes an analysis of the ground-water data (well and spring data) available for the Upper Colorado River Basin study unit from water years 1972 to 1992 for major cations and anions, metals and selected trace elements, and nutrients. The data used in the analysis of the ground-water quality in the Upper Colorado River Basin study unit were predominantly from the U.S. Geological Survey National Water Information System and the Colorado Department of Public Health and Environment data bases. A total of 212 sites representing alluvial aquifers and 187 sites representing bedrock aquifers were used in the analysis. The available data were not ideal for conducting a comprehensive basinwide water-quality assessment because of lack of sufficient geographical coverage. Evaluation of the ground-water data in the Upper Colorado River Basin study unit was based on the regional environmental setting, which describes the natural and human factors that can affect the water quality. In this report, the ground-water-quality information is evaluated on the basis of aquifers or potential aquifers (alluvial, Green River Formation, Mesaverde Group, Mancos Shale, Dakota Sandstone, Morrison Formation, Entrada Sandstone, Leadville Limestone, and Precambrian) and land-use classifications for alluvial aquifers. Most of the ground-water-quality data in the study unit were for major cations and anions and dissolved-solids concentrations. The aquifer with the highest median concentrations of major ions was the Mancos Shale. The U.S. Environmental Protection Agency secondary maximum contaminant level of 500 milligrams per liter for dissolved solids in drinking water was exceeded in about 75 percent of the samples from the Mancos Shale aquifer. The guideline by the Food and Agriculture Organization of the United States for irrigation water of 2,000 milligrams per liter was also exceeded by the median concentration from the Mancos Shale aquifer. For sulfate, the U.S. Environmental Protection Agency proposed maximum contaminant level of 500 milligrams per liter for drinking water was exceeded by the median concentration for the Mancos Shale aquifer. A total of 66 percent of the sites in the Mancos Shale aquifer exceeded the proposed maximum contaminant level. Metal and selected trace-element data were available for some sites, but most of these data also were below the detection limit. The median concentrations for iron for the selected aquifers and land-use classifications were below the U.S. Environmental Protection Agency secondary maximum contaminant level of 300 micrograms per liter in drinking water. Median concentration of manganese for the Mancos Shale exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level of 50 micrograms per liter in drinking water. The highest selenium concentrations were in the alluvial aquifer and were associated with rangeland. However, about 22 percent of the selenium values from the Mancos Shale exceeded the U.S. Environmental Protection Agency maximum contaminant level of 50 micrograms per liter in drinking water. Few nutrient data were available for the study unit. The only nutrient species presented in this report were nitrate-plus-nitrite as nitrogen and orthophosphate. Median concentrations for nitrate-plus-nitrite as nitrogen were below the U.S. Environmental Protection Agency maximum contaminant level of 10 milligrams per liter in drinking water except for 0.02 percent of the sites in the alluvial aquifer and 0.03 percent of the sites in the Mancos Shale. Concentrations of orthophosphate did not vary significantly among aquifers or land-use classifications. Historic water-quality data from wells and springs helped to characterize the regional distribution of ground-water quality information in the Upper Colorado River Basin study unit. The historical ground-water data summarized in this report will be used in the design of a ground-water-quality network. Because ground-water-quality issues in the study unit are related to high dissolved solids, sulfate, selenium, and nutrients, this report discusses some of the important findings related to these issues.

Colorado

Effects of hydrologic, biological, and environmental processes on sources and concentrations of fecal bacteria in the Cuyahoga River, with implications for management of recreational waters in Summit and Cuyahoga Counties, Ohio

Discharges of fecal bacteria (fecal coliform bacteria and Escherichia coli ) to the middle main stem of the Cuyahoga River from storm water, combined sewers, and incompletely disinfected wastewater have resulted in frequent exceedances of bacteriological water-quality standards in a 23-mile reach of the river that flows through the Cuyahoga Valley National Recreation Area. Contamination of the middle main stem of the Cuyahoga River by bacteria of fecal origin and subsequent transport to downstream areas where water-contact recreation is an important use of the river are a concern because of the potential public-health risk from the presence of enteric pathogens. Independent field investigations of bacterial decay, dilution, dispersion, transport, and sources, and bacterial contamination of streambed sediments, were completed in 1991-93 during periods of rainfall and runoff. The highest concentration of fecal coliform bacteria observed in the middle main stem during three transport studies exceeded the single-sample fecal coliform standard applicable to primary-contact recreation by a factor of approximately 1,300 and exceeded the Escherichia coli standard by a factor of approximately 8,000. The geometric-mean concentrations of fecal bacteria in the middle main stem were 6.7 to 12.3 times higher than geometric-mean concentrations in the monitored tributaries, and 1.8 to 7.0 times larger than the geometric-mean concentrations discharged from the Akron Water Pollution Control Station. Decay rates of fecal bacteria measured in field studies in 1992 ranged from 0.0018 per hour to 0.0372 per hour for fecal coliform bacteria and from 0.0022 per hour to 0.0407 per hour for Escherichia coli. Most of the decay rates measured in June and August were significantly higher than decay rates measured in April and October. Results of field studies demonstrated that concentrations of fecal coliform bacteria were 1.2 to 58 times higher in streambed sediments than in the overlying water. Sediments are likely to be a relatively less important source of fecal bacteria during rainfall and runoff in the middle main stem relative to bacterial loading from point sources. Numerical streamflow and transport simulation models were calibrated and verified with data collected during field studies. Of the constituents modeled, bacteria exhibited the poorest correspondence between observed and simulated values. The simulation results for a dye tracer indicated that the model reasonably reproduced the timing of dissolved constituents as well as dilution and dispersion effects. Calibrated and verified models for 1991 and 1992 data sets were used to simulate the improvements to bacteriological water quality that might result from reductions in concentrations of fecal bacteria discharged from two major sources. The model simulation resulting in the greatest improvement in bacteriological water-quality was one in which concentrations of fecal coliform bacteria and Escherichia coli were reduced by 90 percent in the Cuyahoga River at the Old Portage gaging station, and to geometric-mean bathing-water standards in the effluent of the Akron Water Pollution Control Station (BWS/90 scenario). Compared to the results of the base-simulation, when the BWS/90 scenario was applied in the 1991 model simulation, Escherichia coli concentrations were reduced 98.5 percent at Botzum, 97.5 percent at Jaite, and 91.1 percent at Independence. For 1992 model simulations, similar percent reductions in the concentrations of Escherichia coli were predicted at the three stream sites when the same reductions were applied to sources. None of the model simulations resulted in attainment of bacteriological water-quality standards. The potential benefits of source reductions to human health and recreational uses were estimated by comparing the number of illnesses per 1,000 people from concentrations of Escherichia coli associated with the BWS/90 simulation, with the base simulation, and with the geometric-mean standard for Escherichia coli. The predicted 22 to 26 illnesses per 1,000 people predicted by the E. coli concentrations resulting from BWS/90 simulation are 2.8 to 3.3 times higher than the 8 illnesses per 1,000 people associated with the geometric-mean primary-contact water-quality standard for Escherichia coli. Risks associated with the base simulation are 4.6 to 4.9 times higher than that associated with the geometric-mean primary- contact water-quality standard for Escherichia coli. The illness risks predicted from the BWS/90 scenario, although larger than acceptable, would nevertheless be an improvement over conditions that were encountered during field studies in 1991-93.

Ohio

Fraser River watershed, Colorado — Assessment of available water-quantity and water-quality data through water year 1997

The water-quantity and water-quality data for the Fraser River watershed through water year 1997 were compiled for ground-water and surface-water sites. In order to assess the water-quality data, the data were related to land use/land cover in the watershed. Data from 81 water-quantity and water-quality sites, which consisted of 9 ground-water sites and 72 surface-water sites, were available for analysis. However, the data were limited and frequently contained only one or two water-quality analyses per site. The Fraser River flows about 28 miles from its headwaters at the Continental Divide to the confluence with the Colorado River. Ground-water resources in the watershed are used for residential and municipal drinking-water supplies. Surface water is available for use, but water diversions in the upper parts of the watershed reduce the flow in the river. Land use/land cover in the watershed is predominantly forested land, but increasing urban development has the potential to affect the quantity and quality of the water resources. Analysis of the limited ground-water data in the watershed indicates that changes in the land use/land cover affect the shallow ground-water quality. Water-quality data from eight shallow monitoring wells in the alluvial aquifer show that iron and manganese concentrations exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level. Radon concentrations from these monitoring wells exceeded the U.S. Environmental Protection Agency proposed maximum contaminant level. The proposed radon contaminant level is currently being revised. The presence of volatile organic compounds at two monitoring wells in the watershed indicates that land use affects the shallow ground water. In addition, bacteria detected in three samples are at concentrations that would be a concern for public health if the water was to be used as a drinking supply. Methylene blue active substances were detected in the ground water at some sites and are a possible indication of contamination from wastewater. Age of the alluvial ground water ranged from 10 to 30 years; therefore, results of land-management practices to improve water quality may not be apparent for many years. Surface-water-quality data for the Fraser River watershed are sparse. The surface-water-quality data show that elevated concentrations of selected constituents generally are related to specific land uses in the watershed. For one sample (about 2 percent; 1 of 53), dissolved manganese concentration exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level. Two samples from two surface-water sites in the watershed exceeded the un-ionized ammonia chronic criterion. Spatial distribution of nutrient species (ammonia, nitrite, nitrate, and total phosphorus) shows that elevated concentrations occur primarily downstream from urban areas. Sites with five or more years of record were analyzed for temporal trends in concentration of nutrient species. Downward trends were identified for ammonia and nitrite for three surface-water sites. For nitrate, no trends were observed at two sites and a downward trend was observed at one site. Total phosphorus showed no trend for the site near the mouth of the Fraser River. Downward trends in the nutrient species may reflect changes in the wastewater-treatment facilities in the watershed. Bacteria sampling completed in the watershed indicates that more bacteria are present in the water near urban settings. The limited ground-water and surface-water data for the Fraser River watershed provide a general assessment of the quantity and quality of these resources. Concentrations of most water-quality constituents generally are less than ground- and surface-water-quality standards, but the presence of bacteria, some volatile organic compounds, methylene blue active substances, and increased nutrients in the water may indicate that land use is affecting the water quality.

Colorado

Reconnaissance of geology and ground water in the lower Grand River valley, South Dakota, with a section on Chemical quality of the ground water

The area described in this report is the flood plain of the Grand River and the bordering benchlands in Perkins and Corson Counties, S. Dak., from a point about 6 miles west of the town of Shadehill to the confluence of the Grand and Missouri Rivers near Mobridge. The exposed bedrock formations include the Pierre shale, the Fox Hills sandstone, and the Hell Creek formation of Late Cretaceous age, and-the Ludlow member of the Fort Union formation of Tertiary (Paleocene) age. Some stringers of the Cannonball formation probably interfinger with beds of the Ludlow member but none of the former was identified during the field investigations. The Pierre shale is exposed from the mouth of the Grand River to approximately the center of the area. Although a few wells in the area obtain water from this formation, it is not generally considered to be a source of supply. The Fox Hills sandstone, the Hell Creek formation, and the Ludlow member of the Fort Union formation are exposed successively upstream and, where saturated, yield small to moderate quantities of water to wells. Unconsolidated deposits of silt, sand, and gravel occur in several physiographic positions; they underlie the high benchland on both sides of the river, the poorly defined terraces along the river, and the flood plain throughout its entire length. Possibly all these unconsolidated deposits are water bearing; however, where the deposits on the benchland and in the terraces are dissected by streams, they probably contain little or no water. The average depth to ground water along the lower Grand River valley is about 17 feet. Probably, the flow of ground water in the bottom lands is nearly parallel to and slightly toward the surface stream. The measurements of the water level in observation wells for the period 1946-48 indicate that the fluctuations of the water table are small. The results of analyses of 13 samples of ground water from the alluvium and the Hell Creek formation show that the suitability of the ground water for use varies because of the considerable range in mineralization and composition. Dissolved solids ranged from 343 to 4,250 parts per million (ppm), hardness from 11 to 1,130 ppm, and percentage of sodium from 25 to 98. Concentrations of some of the individual constituents exceed standards of the United States Public Health Service. The water is moderately hard and contains undesirable amounts of iron and moderate to large amounts of dissolved solids. In general, the water quality ranges from excellent to unsuitable for irrigation use. The result of the mixing of the ground water with recharge water from Shadehill Reservoir cannot be predicted on the basis of available data. The geologic and hydrologic data in this report were obtained from earlier reports and from field observations during the period 1946-48. The report includes a geologic map and tabulated well records.

South Dakota

Geology and ground-water resources of the upper Lodgepole Creek drainage basin, Wyoming, with a section on chemical quality of the water

The principal sources of ground-water supply in the upper Lodgepole Creek drainage basin-the part of the basin west of the Wyoming-Nebraska State line-are the Brule formation of Oligocene age, the Arikaree formation of Miocene age, the Ogallala formation of Pliocene age, and the unconsolidated deposits of Quaternary age. The Brule formation is a moderately hard siltstone that generally is not a good aquifer. However, where it is fractured or where the upper part consists of pebbles of reworked siltstone, it will yield large quantities of water to wells. Many wells in the Pine Bluffs lowland, at the east end of the area, derive water from the Brule. The Arikaree formation, which consists of loosely to moderately cemented fine sand, will yield small quantities of water to wells but is not thick enough or permeable enough to supply sufficient water for irrigation. Only a few wells derive water from it. The Ogallala formation consists of lenticular beds of clay, silt, sand, and gravel which, in part, are cemented with calcium carbonate. Only the lower part of the formation is saturated. Nearly all the wells in the upland part of the area tap the Ogallala, but they supply water in amounts sufficient for domestic and stock use only. Two of the wells have a moderately large discharge, and other wells of comparable discharge probably could be drilled in those parts of the upland where the saturated part of the Ogallala is fairly thick. Most of the unconsolidated deposits of Quaternary age are very permeable and, where a sufficient thickness is saturated, will yield large quantities of water to wells. These deposits are a significant source of water supply in the southeastern part of the area. The Chadron formation of Oligocene age, which underlies the Brule formation, is a medium- to coarse-grained sandstone where it crops out in the Islay lowland. No wells tap the Chadron, but it probably would yield small quantities of water to wells. It lies at a relatively shallow depth beneath most of the Islay lowland, near the west end of the area, and at a depth of about 800 feet beneath the Pine Bluffs lowland. In the latter area it probably is finer grained and may not be permeable enough to yield water to wells. All the ground water in the area is derived from precipitation. It is estimated that about 5 percent of the precipitation infiltrates directly to the zone of saturation. The remainder either is evaporated immediately; is retained by the soil, later to be evaporated or transpired; or is discharged by overland flow to the surface drainage courses. Most of the water that reaches the surface drainage courses eventually sinks to the zone of saturation or is evaporated. The slope of the water table and the movement of ground water are generally eastward. The depth to water ranges from less than 10 feet in parts of the valley to about 300 feet in the upland areas. In much of the Pine Bluffs lowland, the depth to water is less than 50 feet. Ground water not pumped from wells within the area is discharged by evapotranspiration where the water table is close to the land surface, by outflow into streams, or by underflow eastward beneath the State line. The chemical quality of ground water from the principal sources is remarkably uniform, and the range in concentration of dissolved constituents is narrow. In general, the water is of the calcium bicarbonate type, is hard (hardness as CaC03 is as high as 246 ppm), and contains less than about 400 parts per million of dissolved solids, which is a moderate mineralization. Silica constitutes a large proportion of the dissolved solids. The water is suitable for irrigation and, except for iron in water from some wells that tap the Ogallala formation, meets the drinking water standards of the U.S. Public Health Service for chemical constituents. Because the water is siliceous, alkaline, and hard, it is unsuitable for many industrial uses unless treated.

Water Supply Paper

Exploratory drilling for ground water in the Mountain Iron-Virginia area, St. Louis County, Minnesota

The Mountain Iron-Virginia area is a broad, southwest-trending valley in the central part of the Mesabi Range. The valley, which heads in the Laurentian Divide, and covers about 120 square miles, coincides approximately with a bedrock valley filled with as much as 150 feet of glacial deposits. A complex sequence of glacioaqueous sediments made up of clay, silt, sand, and gravel was delineated from test holes drilled at 238 sites. These sediments range in thickness from 0 to 125 feet and can be considered a hydrologic unit, bounded below by sandy till or bedrock and above by as much as 60 feet of clayey till. The piezometric surface ranges from 0 to about 70 feet below land surface, thus, the glacioaqueous deposits are not everywhere completely saturated. In places, however, the water is under artesian pressure. Within the Mountain Iron-Virginia area about 50 square miles are underlain by deposits 20 feet or more in thickness of silt, sand, or gravel that constitute an aquifer that is a large potential source for additional water supplies. Except for iron and manganese, which are present in excessive amounts in some wells, the water meets U.S. Public Health Service standards for municipal supplies. Pumping tests of wells in the permeable sand or gravel deposits at five sites indicate that yields of several hundred gallons per minute and possibly as much as 2,000 gpm (gallons per minute) can be expected.

Minnesota

Ground-water contamination and legal controls in Michigan

The great importance of the fresh ground-water resources of Michigan is evident because 90 percent of the rural and about 70 percent of the total population of the State exclusive of the Detroit metropolitan area are supplied from underground sources. The water-supply and public-health problems that have been caused by some cases of ground-water contamination in the State illustrate the necessity of protecting this vital resource. Manmade and natural contaminants, including many types of chemical and organic matter, have entered many of the numerous aquifers of the State. Aquifers have been contaminated by waste-laden liquids percolating from the surface or from the zone of aeration and by direct injection to the aquifer itself. Industrial and domestic wastes, septic tanks, leaking sewers, flood waters or other poor quality surface waters, mine waters, solids stored or spread at the surface, and even airborne wastes all have been sources of ground-water contamination in Michigan. In addition, naturally occurring saline waters have been induced into other aquifers by overpumping or unrestricted flow from artesian wells, possibly by dewatering operations, and by the deepening of surface stream channels. Vertical migration of saline waters through open holes from formations underlying various important aquifers also has spoiled some of the fresh ground waters in the State. In spite of the contamination that has occurred, however, the total amount of ground water that has been spoiled is only a small part of the total resource. Neither is the contamination so widespread as that of the surface streams of Michigan. Overall legal authority to control most types of ground-water contamination in the State has been assigned by the Michigan Legislature to the Water Resources Commission, although the Department of Conservation and the Health Department also exercise important water-pollution control functions. The Michigan Supreme Court, in an important case upholding the power of the Water Resources Commission to control pollution of ground water, in effect has introduced the doctrine of reasonable use into the law of the State. Excluding controls administered by the Department of Conservation on activities of the oil and gas industry, however, legal controls have not been used abate intrusion of natural saline waters into fresh-water aquifers in response to pumping and other manmade changes in the hydrologic regimen.

Michigan

Chemical quality of surface waters in the Brazos River basin in Texas

The Brazos River basin, which makes up 15 percent of the land area of Texas, extends from the High Plains, where altitudes reach 4,200 feet and the average precipitation ranges from 15 to 20 inches a year, to the Gulf of Mexico where the annual rainfall is 45-^50 inches. Large reservoirs have been built in the Brazos River basin, but the use of the stored water has been limited because the salinity often makes the water undesirable for municipal and industrial use. However, the water is generally satisfactory for irrigation. Records for the Brazos River show that the salinity of the water was a problem even as early as 1906 and that the water more often than not failed to meet today's chemical-quality standards for a municipal supply. The salt load of the Brazos River comes from the entire basin and is the result of solution, accretion of undetermined amounts of oil-field brine, and accretion of brine from springs and seeps such as those in Salt Croton Creek which contribute about 400 tons of chloride a day. Much of the salinity of the Brazos River is due to inflow of brines above Possum Kingdom Dam. The area above Possum Kingdom Dam is about 52 percent of the total area in the Brazos River basin but contributes only about 17 percent of the total runoff; however, about 50 percent of the annual salt load comes from this part of the basin. Quality-of-water records show a wide difference in the salinity of the steams in different parts of the basin, Dissolved-solids concentrations ranged from about 100 ppm (parts per million) for flood water to 300,000 ppm for saturated brines from springs. The quality of the surface water in the Brazos River basin is discussed by areas and by stream reaches. This study indicates that the water of the Salt Fork Brazos River is too saline for most uses. The water of the Double Mountain Fork Brazos River is less saline and might be used for irrigation; however, it probably could not be used as a municipal supply or as a supply for most industries. The water of the dear Fork Brazos River is generally good but is adversely affected by brine pollution. Chemical-quality records for the Lampasas, Leon, and Navasota Rivers indicate that the water of these streams is of excellent quality; however, more data are needed to determine variations. The quality of the water in other tributaries could only be inferred from the results of miscellaneous sampling and from the probable effect of the underlying rocks. The weighted-average concentration of constituents in the Brazos River at Richmond indicated that inflow below Whitney Reservoir has a dilution effect on the river. For 12 of the 14 years of record, the weighted-average dissolved-solids concentration of the Brazos River at Richmond was lessi than, the 500 ppm maximum limit recommended by the U.S. Public Health Service (1961). This study indicates that water stored in Possum Kingdom and Whitney Reservoirs tends to become stratified, with the more saline water being at the greater depths. Samples collected in 1956 at Whitney Reservoir showed that the chloride concentration at the bottom was almost twice that at the surface. After a flood in June 1957, the dissolved-solids concentrations of bottom releases at Possum Kingdom were almost double those of surface releases through the spillway even though the flood volume had been more than twice the capacity of the reservoir. The quality of water in the lower main stem can be improved by control and disposal of brines in the upper basin. Also, the maximum concentrations in the water of the lower main stem can be lowered by dilution with water stored in reservoirs on tributaries that yield water of good quality.

Water Supply Paper

Reconnaissance of the chemical quality of surface waters of the Neches River basin, Texas

The kinds and quantities of minerals dissolved in the surface water of the Neches River basin result from such environmental factors as geology, streamflow patterns and characteristics, and industrial influences. As a result of high rainfall in the basin, much of the readily soluble material has been leached from the surface rocks and soils. Consequently, the water in the streams is usually low in concentrations of dissolved minerals and meets the U.S. Public Health Service drinking-water standards. In most streams the concentration of dissolved solids is less than 250 ppm (parts per million). The Neches River drains an area of about 10,000 square miles in eastern Texas. From its source in southeast Van Zandt County the river flows in a general southeasterly direction and empties into Sabine Lake, an arm of the Gulf of Mexico. In the basin the climate ranges from moist subhumid to humid, and the average annual rainfall ranges from 46 inches is the northwest to more than 52 inches in the southeast. Annual runoff from the basin has averaged 11 inches; however, runoff rates vary widely from year to year. The yearly mean discharge of the Neches River at Evadale has ranged from 994 to 12,720 cubic feet per second. The rocks exposed in the Neches River basin are of the Quaternary and Tertiary Systems and range in age from Eocene to Recent. Throughout most of the basin the geologic formations dip generally south and southeast toward the gulf coast. The rate of dip is greater than that of the land surface; and as a result, the older formations crop out to the north of the younger formations. Water from the outcrop areas of the Wilcox Group and from the older formations of the Claiborne Group generally has dissolved-solids concentrations ranging from 100 to 250 ppm; water from the younger formations has concentrations less than 100 ppm. The northern half of the basin has soft water, with less than 60 ppm hardness. The southern half of .the basin has very soft water, usually with less than 30 ppm hardness. The chloride concentrations are less than 20 ppm in surface water in the southern half of the basin and usually range from 20 to 100 ppm in the northern half of the basin. Concentrations greater than 100 ppm are found only where pollution is occurring. The Neches River basin has an abundance of surface water, but uneven distribution of runoff makes storage projects necessary to provide dependable water supplies. The principal existing reservoirs, with the exception of Striker Creek Reservoir, contain water of excellent quality. Chemical-quality data for the Striker Creek drainage area indicate that its streams are affected by .the disposal of brines associated with oil production. Sam Rayburn Reservoir began impounding water in 1965. The water impounded should prove of acceptable quality for most uses, but municipal and industrial wastes released into the Angelina River near Lufkin may have a degrading effect on the quality of the water, especially during extended periods of low flows. Water available for storage at the many potential reservoir sites will be of good quality; but, if the proposed salt-water barrier is to impound acceptable water, the disposal of oilfield brine into Pine Island Bayou should be discontinued.

Water Supply Paper

Availability of ground water in the lower Pawcatuck River basin, Rhode Island

The lower Pawcatuck River basin in southwestern Rhode Island is an area of about 169 square miles underlain by crystalline bedrock over which lies a relatively thin mantle of glacial till and stratified drift. Stratified drift, consisting dominantly of sand and gravel, occurs in irregularly shaped linear deposits that are generally less than a mile wide and less than 125 feet thick; these deposits are found along the Pawcatuck River, its tributaries, and abandoned preglacial channels. Deposits of stratified sand and gravel constitute the principal aquifer in the lower Pawcatuck basin and the only one capable of sustaining yields of 100 gallons per minute or more to individual wells. Water available for development in this aquifer consists of water in storage--potential ground-water runoff to streams--plus infiltration that can be induced from streams. Minimum annual ground-water runoff from the sand and gravel aquifer is calculated to be at least 1.17 cubic feet per second per square mile, or 0.76 million gallons per day per square mile. Potential recharge by induced infiltration is estimated to range from about 250 to 600 gallons per day per linear foot of streambed for the principal streams. In most areas, induced infiltration from streams constitutes the major source of water potentially available for development by wells. Because subsurface hydraulic connection in the sand and gravel aquifer is poor in several places, the deposits are conveniently divisible into several ground-water reservoirs. The potential yield from five of the most promising ground-water reservoirs is evaluated by means of mathematical models. Results indicate that continuous withdrawals ranging from 1.3 to 10.3 million gallons per day, and totaling 31 million gallons per day, are obtainable from these reservoirs. Larger yields may be recovered by different well placement, spacing, construction and development, pumping practice, and so forth. Withdrawals at the rates indicated will reduce streamflow downstream from pumping centers but generally will not result in streams going dry, provided the water is returned to the basin. Export of water from the basin will require careful consideration of the effects of such withdrawals on low streamflow. Export from the Pawcatuck basin of 27 million gallons per day, estimated to be available from ground-water reservoirs in the upper Pawcatuck basin, in addition to 37.5 million gallons per day available in the lower Pawcatuck basin, will markedly reduce low streamflow. The 90-percent duration flow of the Pawcatuck River at Westerly would be reduced from 75 million gallons per day to perhaps as little as 21 million gallons per day. The chemical quality of water from both the sand and gravel aquifer and associated streams is suitable for most purposes. The water is soft, slightly acidic, and typically has a dissolved-solids content of less than 75 milligrams per liter. Some treatment may be required locally for removal of iron and manganese to meet recommended standards of the U.S. Public Health Service for drinking water.

Rhode Island

Geology and ground water in Door County, Wisconsin, with emphasis on contamination potential in the Silurian dolomite

Door County is in northeastern Wisconsin and is an area of 491 square miles. The county forms the main body of the peninsula between Green Bay and Lake Michigan. The land surface is an upland ridge controlled by the underlying bedrock. The west edge of the ridge forms an escarpment facing Green Bay. Silurian dolomite is the upper bedrock unit throughout most of the county and is the most important aquifer. This bedrock is exposed in much of the county, particularly north of Sturgeon Bay; elsewhere, it is covered by a generally thin mantle of soil or drift. The bedrock units are divided into two major aquifer systems in Door County; the Silurian dolomite aquifer system and the sandstone aquifer system, consisting of Ordovician and Cambrian bedrock units. These two major systems are separated by the Maquoketa Shale of Ordovician age, a nearly impermeable, generally nonproductive unit. The Silurian dolomite aquifer system is itself divided into the Niagaran aquifer and the underlying Alexandrian aquifer. Water occurs in the Silurian dolomite aquifer system in two types of openings-nearly vertical joints (fractures) and horizontal to slightly dipping bedding-plane joints. Vertical joints are more common in the upper part of the Niagaran aquifer. These yield small amounts of water to wells. Bedding-plane joints transmit most of the water in the lower part of the Niagaran aquifer and in the Alexandrian aquifer. The bedding-plane joints, because they are poorly interconnected, act as semiartesian conduits separated by impermeable rock. Eight water-bearing zones in generally continuous bedding-plane joints have been mapped. The dolomite is recharged from direct precipitation and snowmelt. It discharges water to pumping wells and by natural springs discharge to Lake Michigan and Green Bay and to interior lakes and streams. Wells in the Silurian dolomite aquifer system have adequate yields to meet most needs, except in the southwest corner of the county, where the dolomite is thin or absent. Transmissivity values range from a low of 4.0 feet squared per day in the Niagaran aquifer near Sturgeon Bay to more than 13 000 feet squared per day for the Alexandrian aquifer near Fish Creek. Water from Silurian dolomite is a very hard calcium magnesium bicarbonate type, with objectionable concentrations of iron and nitrate in water from some wells. Sanitary quality, as indicated by tests for total coliform bacteria, has been a chronic problem in certain areas. Concentrations of indicator organisms are greatest during or immediately after rapid ground-water recharge, with concentrations rapidly decreasing after periods of recharge. Wells close to septic systems and in areas underlain by fractured near-surface bedrock have the greatest incidence of contamination. The type and thickness of unconsolidated material has a direct effect on the entry of bacteria into the ground-water system. Bacterial attenuation increases with increasing soil depth and reduction in soil permeability. After bacterial contaminants reach the water table within fractured bedrock, little attenuation occurs, and the contaminants can travel long distances in a short time. Ground water of good sanitary quality but exceeding recommended limits of the U.S. Public Health Service for sulfate and chloride is probably available from the sandstone aquifer by drilling wells 700 to 1300 feet deep. To minimize the possibility of obtaining contaminated ground water, well construction should include properly locating the wells upgradient and as far as practical from contamination sources, setting and pressure grouting well casings to an adequate depth into firm bedrock, and casing the well into the zone of saturation.

Wisconsin