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Lewis and Clark's observations and measurements of geomorphology and hydrology, and changes with time

Two VERY different men, Meriwether Lewis and William Clark, joined to J, ~ake the first recorded set of scientific observations and measurements of geomorphology and hydrology west of the Mississippi River. They did not limit themselves to these two scientific topics but were true naturalists, making observations and measurements related to astronomy (Large, 1979; Bedini, 1984; Plamondon, 1991; Bergantino, 1998), biology (Cutright, 1969), ecology, ethnology (Ronda, 1984a), geology (Bluemle, 2001; Bergantino, 1998), and phenology, as well as to the general geographical understanding of the arrangements of rivers and other topographical features of the trans-Mississippi West (Allen, 1975) .

Circular

Relation of periphyton and benthic invertebrate communities to environmental factors and land use at selected sites in part of the upper Mississippi River basin, 1996-98

The Upper Mississippi River Basin is one of the hydrologic systems selected for study by the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey. NAWQA utilizes a multi-disciplinary approach to explain factors that affect water quality. Part of the NAWQA design addresses the relation of land use and environmental factors to periphyton and benthic invertebrate communities in streams. This report focuses on a 122,000 square kilometer area of the Mississippi River Basin, including the Twin Cities metropolitan area (TCMA). The northeastern part of the study area is forested, the southwestern part is agricultural, and the central part is transitional between forest and agriculture. Sampling sites were selected based on a process that identified small streams in predominantly forested, agricultural, and urban settings, and large river sites on the Mississippi River and major tributaries. Periphyton and benthic invertebrate communities were evaluated at each site. Compared to the forested site, periphyton density and biovolume in small streams generally increased as nutrient concentrations associated with urban and agricultural land use increased. Periphyton communities varied within agricultural and urban streams, indicating that physical and chemical factors other than land use also affect periphyton communities. Benthic invertebrate communities also are affected by land use and associated stream habitat. There were few intolerant taxa (Ephemeroptera and Plecoptera) in urban streams, potentially due to high streamflow variability and contaminants from runoff. Ephemeroptera taxa richness was greatest in the agricultural streams. The most abundant Ephemeroptera taxa were those tolerant to high concentrations of suspended sediment. Richness of Plecoptera and Trichoptera taxa were greatest in the forested stream. Biological communities in the St. Croix and Minnesota River generally reflected relatively homogeneous land uses. Biological communities in the Mississippi River reflected changes in water quality and physical habitat as the Minnesota and St. Croix Rivers join the Mississippi River. Periphyton density and biovolume, and the relative abundance of blue-green algae density increased in the Mississippi River at the confluence compared to the Minnesota and St. Croix Rivers. Relative abundance of benthic invertebrate taxa richness and diversity generally decreased downstream in the large rivers as urban and agricultural land use become more prevalent. Impoundments and dredging of the Mississippi River in and downstream from the TCMA exacerbate effects of increasing river size to produce a more lake-like system.

Iowa, Minnesota, North Dakota, South Dakota, Wisco

Characterization of ground-water discharge from bedrock aquifers to the Mississippi and Minnesota Rivers at three areas, Minneapolis-St. Paul area, Minnesota

The hydrogeology at three areas along the Mississippi and Minnesota Rivers in the Minneapolis-St. Paul area were studied to characterize ground-water discharge from bedrock aquifers to the two rivers. Along the Mississippi River between Fridley and Brooklyn Center, a buried valley underlying the Mississippi River cuts through the overlying terrace deposits and glacial-drift deposits into two underlying bedrock hydro- geologic units: the St Peter aquifer, and a rubble zone between the St. Peter and Prairie du Chien-Jordan aquifers. Shallow ground-water flow in the near-surface gray and upper red tills and sand and gravel outwash aquifer discharges to springs along the edge of the river. Ground water flowing through the rubble zone and upper part of the Prairie du Chien-Jordan aquifer probably discharges through alluvial deposits to the river. In study area 2, along the Minnesota River between Eagan and Bloomington, almost 200 feet of post-glacial alluvium, glaciofluvial sand and gravel, Pleistocene lake deposits, and peat fill a bedrock valley under the present-day Minnesota River. As much as 40 feet of post-glacial peat, silty clay, clay, and muck lie near the river-valley walls. Confining units beneath the river channel impede the discharge of ground water from the underlying Prairie du Chien-Jordan aquifer to the river. Ground water discharges to wetlands, lakes, and springs along both the north and south side of the river. Along the Mississippi River at Minneapolis about 5 miles upstream of the confluence of the Minnesota and Mississippi Rivers, the Mississippi River lies in a post-glacial valley cut through thin glacial drift into the St. Peter aquifer. Beneath the river, ground water flows from the St. Peter aquifer through the overlying post-glacial ailuvium to the Mississippi River. No confining unit separates the St. Peter aquifer and the river.

Minnesota

Mississippi embayment aquifer system in Mississippi: Geohydrologic data compilation for flow model simulation

As part of the Gulf Coast Regional Aquifer System Analysis (GC RASA) study, data from 184 geophysical well logs were used to define the geohydrologic framework of the Mississippi embayment aquifer system in Mississippi for flow model simulation. Five major aquifers of Eocene and Paleocene age were defined within this aquifer system in Mississippi. A computer data storage system was established to assimilate the information obtained from the geophysical logs. Computer programs were developed to manipulate the data to construct geologic sections and structure maps. Data from the storage system will be input to a five-layer, three-dimensional, finite-difference digital computer model that is used to simulate the flow dynamics in the five major aquifers of the Mississippi embayment aquifer system.

Mississippi

Guidebook of the western United States: Part A - The northern Pacific route, with a side trip to Yellowstone Park

The United States of America comprise an area so vast in extent and so diverse in natural features as well as in characters due to human agency that the American citizen who knows thoroughly his own country must have traveled widely and observed wisely. To 'know America first' is a patriotic obligation, but to meet this obligation the railroad traveler needs to have his eyes directed toward the more important or essential things within his field of vision and then to have much that he sees explained by what is unseen in the swift passage of the train. Indeed, many things that attract his attention are inexplicable except as the story of the past is available to enable him to interpret the present. Herein lie the value and the charm of history, whether human or geologic. The present stimulus given to travel in the home country will encourage many thousands of Americans to study geography at first hand. To make this study most profitable the traveler needs a handbook that will answer the questions that come to his mind so readily along the way. Furthermore, the aim of such a guide should be to stimulate the eye in the selection of the essentials in the scene that so rapidly unfolds itself in the crossing of the continent. In recognition of the opportunity afforded in 1915 to render service of this kind to an unusually large number of American citizens, as well as to visitors from other countries, the United States Geological Survey has prepared a series of guidebooks covering four of the older railroad routes west of the Mississippi. These books are educational in purpose, but the method adopted is to entertain the traveler by making more interesting what he sees from the car window. The plan of the series is to present authoritative information that may enable the reader to realize adequately the scenic and material resources of the region he is traversing, to comprehend correctly the basis of its development, and above all to appreciate keenly the real value of the country he looks out upon, not as so many square miles of territory represented on the map in a railroad folder by meaningless spaces, but rather as land - real estate, if you please - varying widely in present appearance because differing largely in its history, and characterized by even greater variation in values because possessing diversified natural resources. One region may be such as to afford a livelihood for only a pastoral people; another may present opportunity for intensive agriculture; still another may contain hidden stores of mineral wealth that may attract large industrial development; and, taken together, these varied resources afford the promise of long-continued prosperity for this or that State. Items of interest in civic development or references to significant epochs in the record of discovery and settlement may be interspersed with explanations of mountain and valley or statements of geologic history. In a broad way the story of the West is a unit, and every chapter should be told in order to meet fully the needs of the tourist who aims to understand all that he sees. To such a traveler-reader this series of guidebooks is addressed. To this interpretation of our own country the United States Geological Survey brings the accumulated data of decades of pioneering investigation, and the present contribution is only one type of return to the public which has supported this scientific work under the Federal Government.

Bulletin

Guidebook of the western United States: Part B - The overland route, with a side trip to Yellowstone Park

The United States of America comprise an area so vast in extent and so diverse in natural features as well as in characters due to human agency that the American citizen who knows thoroughly his own country must have traveled widely and observed wisely. To 'know America first' is a patriotic obligation, but to meet this obligation the railroad traveler needs to have his eyes directed toward the more important or essential things within his field of vision and then to have much that he sees explained by what is unseen in the swift passage of the train. Indeed, many things that attract his attention are inexplicable except as the story of the past is available to enable him to interpret the present. Herein lie the value and the charm of history, whether human or geologic. The present stimulus given to travel in the home country will encourage many thousands of Americans to study geography at first hand. To make this study most profitable the traveler needs a handbook that will answer the questions that come to his mind so readily along the way. Furthermore, the aim of such a guide should be to stimulate the eye in the selection of the essentials in the scene that so rapidly unfolds itself in the crossing of the continent. In recognition of the opportunity afforded in 1915 to render service of this kind to an unusually large number of American citizens as well as to visitors from other countries, the United States Geological Survey has prepared a series of guidebooks covering four of the older railroad routes west of the Mississippi. These books are educational in purpose, but the method adopted is to entertain the traveler by making more interesting what he sees from the car window. The plan of the series is to present authoritative information that may enable the reader to realize adequately the scenic and material resources of the region he is traversing, to comprehend correctly the basis of its development, and above all to appreciate keenly the real value of the country he looks out upon, not as so many square miles of territory represented on the map in a railroad folder by meaningless spaces, but rather as land - real estate, if you please - varying widely in present appearance because differing largely in its history and characterized by even greater variation in values because possessing diversified natural resources. One region may be such as to afford a livelihood for only a pastoral people; another may present opportunity for intensive agriculture; still another may contain hidden stores of mineral wealth that may attract large industrial development; and taken together these varied resources afford the promise of long-continued prosperity for this or that State. Items of interest in civic development or references to significant epochs in the record of discovery and settlement may be interspersed with explanations of mountain and valley or statements of geologic history. In a broad way, the story of the West is a unit, and every chapter should be told in order to meet fully the needs of the tourist who aims to understand all that he sees. To such a traveler-reader this series of guidebooks is addressed. To this interpretation of our own country the United States Geological Survey brings the accumulated data of decades of pioneering investigation, and the present contribution is only one type of return to the public which has supported this scientific work under the Federal Government. In preparing the description of the country traversed by the Overland Route the geographic and geologic information already published as well as unpublished material in the possession of the Geological Survey has been utilized, but to supplement this material Messrs. Lee, Stone, and Gale made a field examination of the entire route in 1914, Mr. Lee working between Omaha and Ogden, Mr. Stone between Ogden and Yellowstone, and Mr. Gale between Ogden and San Francisco. Information has been furnished by Profs. J. C. Merriam a

Bulletin

Guidebook of the western United States: Part C - The Santa Fe route, with a side trip to Grand Canyon of the Colorado

The United States of America comprise an area so vast in extent and so diverse in natural features as well as in characters due to human agency that the American citizen who knows thoroughly his own country must have traveled widely and observed wisely. To 'know America first' is a patriotic obligation, but to meet this obligation the railroad traveler needs to have his eyes directed toward the more important or essential things within his field of vision and then to have much that he sees explained by what is unseen in the swift passage of the train. Indeed, many things that attract his attention are inexplicable except as the story of the past is available to enable him to interpret the present. Herein lie the value and the charm of history, whether human or geologic. The present stimulus given to travel in the home country will encourage many thousands of Americans to study geography at first hand. To make this study most profitable the traveler needs a handbook that will answer the questions that come to his mind so readily along the way. Furthermore, the aim of such a guide should be to stimulate the eye in the selection of the essentials in the scene that so rapidly unfolds itself in the crossing of the continent. In recognition of the opportunity afforded in 1915 to render service of this kind to an unusually large number of American citizens, as well as to visitors from other countries, the United States Geological Survey has prepared a series of guidebooks covering four of the older railroad routes west of the Mississippi. These books are educational in purpose, but the method adopted is to entertain the traveler by making more interesting what he sees from the car window. The plan of the series is to present authoritative information that may enable the reader to realize adequately the scenic and material resources of the region he is traversing, to comprehend correctly the basis of its development, and above all to appreciate keenly the real value of the country he looks out upon, not as so many square miles of territory represented on the map in a railroad folder by meaningless spaces, but rather as land - real estate, if you please - varying widely in present appearance because differing largely in its history and characterized by even greater variation in values because possessing diversified natural resources. One region may be such as to afford a livelihood for only a pastoral people; another may present opportunity for intensive agriculture; still another may contain hidden stores of mineral wealth that may attract large industrial development; and taken together these varied resources afford the promise of long-continued prosperity for this or that State. Items of interest in civic development or references to significant epochs in the record of discovery and settlement may be interspersed with explanations of mountain and valley or statements of geologic history. In a broad way, the story of the West is a unit, and every chapter should be told in order to meet fully the needs of the tourist who aims to understand all that he sees. To such a traveler-reader this series of guidebooks is addressed. To this interpretation of our own country the United States Geological Survey brings the accumulated data of decades of pioneering investigation, and the present contribution is only one type of return to the public which has supported this scientific work under the Federal Government. In preparing the description of the country traversed by the Santa Fe Route the geographic and geologic information already published as well as unpublished material in the possession of the Geological Survey has been utilized, but to supplement this material Mr. Darton made a field examination of the entire route in 1914. Information has been furnished by Erasmus Haworth, J. E. Todd, and R. T. Hill, as well as by others whose writings are listed in the bibliography at the end of the text. Cooperation has been rendered by the United States Reclamation Service and by bureaus of the Department of Agriculture. Railroad officials and other citizens have also generously given their aid, and other members of the Survey have freely cooperated in the work. For the purpose of furnishing the traveler with a graphic presentation of each part of his route, the accompanying maps, 25 sheets in all, have been prepared, with a degree of accuracy probably never bsfore attained in a guidebook, aiid their arrangement has been planned to meet the convenience of the reader. The special topographic surveys necessary to complete these maps of the route were made by W. O. Tufts.

Bulletin

Guidebook of the western United States: Part E - The Denver & Rio Grande Western route

The United States of America comprise an area so vast in extent and so diverse in natural features as well as in characters due to human agency that the American citizen who knows thoroughly his own country must have traveled widely and observed wisely. To 'know America first' is a patriotic obligation, but to meet this obligation the railroad traveler needs to have his eyes directed toward the more important or essential things within his field of vision and then to have much that he sees explained by what is unseen in the swift passage of the train. Indeed, many things that attract his attention are inexplicable except as the story of the past is available to enable him to interpret the present. Herein lie the value and the charm of history, whether human or geologic. The present stimulus given to travel in the home country will encourage many thousands of Americans to study geography at first hand. To make this study most profitable the traveler needs a handbook that will answer the questions that come to his mind so readily along the way. Furthermore, the aim of such a guide should be to stimulate the eye in the selection of the essentials in the scene that so rapidly unfolds itself in the crossing of the continent. In recognition of the opportunity to render service of this kind to an unusually large number of American citizens, as well as to visitors from other countries, the United States Geological Survey has published a series of guidebooks covering four of the older railroad routes west of the Mississippi. The present volume is an addition to this series and covers one of the finest scenic routes of the continent. These books are educational in purpose, but the method adopted is to entertain the traveler by making more interesting what he sees from the car window. The plan of the series is to present authoritative information that may enable the reader to realize adequately the scenic and material resources of the region he is traversing, to comprehend correctly the basis of its development, and above all to appreciate keenly the real value of the country he looks out upon, not as so many square miles of territory represented on the map in a railroad folder by meaningless spaces, but rather as land - real estate, if you please - varying widely in present appearance because differing largely in its history, and characterized by even greater variation in values because possessing diversified natural resources. One region may be such as to afford a livelihood for only a pastoral people; another may present opportunity for intensive agriculture; still another may contain hidden stores of mineral wealth that may attract large industrial development; and, taken together, these varied resources afford, the promise of long-continued prosperity for this or that State. Items of interest in civic development or references to significant epochs in the record of discovery and settlement may be interspersed. with explanations of mountain and valley or statements of geologic history. In a broad way the story of the West is a unit, and every chapter should be told in order to meet fully the needs of the tourist who aims to understand all that he sees. To such a traveler-reader this series of guidebooks is addressed. To this interpretation of our own country the United States Geological Survey brings the accumulated data of decades of pioneering investigation, and the present contribution is only one type of return to the public which has supported this scientific work under the Federal Government - a by-product of research. In the preparation of the description of the country traversed by the Denver & Rio Grande Western Route the geographic and geologic information already published as well as unpublished material in the possession of the Geological Survey has been utilized, but to supplement this material Mr. Campbell made a field examination of the entire route in 1915-1916. Information has been furnished by others,

Bulletin

Index of surface-water records to September 30, 1955. Part 5 - Hudson Bay and upper Mississippi River basins

This index lists the streamflow and reservoir stations in the Hudson Bay and upper Mississippi River basins for which records have been or are to be published in reports of the Geological Survey for periods prior to September 30, 1955. Periods of record for the same station published by other agencies are listed only when they contain more detailed information or are for periods not reported in publications of the Geological Survey. The stations are listed in the downstream order first adopted for use in the 1951 series of water-supply papers on surface water supply of the United States. Starting at the headwater of each stream all stations are listed in a downstream direction. Tributary streams are indicated by indention and are inserted between main-stem stations in the order in which they enter the main stream. To indicate the rank of any tributary on which a record is available and the stream to which it is immediately tributary, each indention in the listing of stations represents one rank. A stream name only is inserted where necessary for the purpose of showing the proper rank or order of tributaries. Station names are given in their most recently published forms. Parentheses around part of a station name indicate that the enclosed word or words were used in an earlier published name of the station or in a name under which records were published by some agency other than the Geological Survey. The drainage areas, in square miles, are the latest figures published or otherwise available at this time. Drainage areas that were obviously inconsistent with other drainage areas on the same stream have been omitted. Under "period of record" breaks of less than a 12-month period are not shown. A dash not followed immediately by a closing date shows that the station was continued in operation beyond September 30, 1955. The years given are calendar years. All periods of record not contained in water-supply papers on surface water supply of the United States are indicated by appropriate footnotes. Records both of gage height and of discharge are listed for streamflow stations, and records of gage height and of contents (or of change in contents) are listed for stations on reservoirs. Records of gage heights only and records consisting only of monthly figures either of streamflow or reservoir contents are designated by symbols and footnotes. For early years when daily discharges were not generally published by the Geological Survey, published daily gage heights and a published rating table were considered to be equivalent to daily discharges.

Circular

Aggregate resource availability in the conterminous United States, including suggestions for addressing shortages, quality, and environmental concerns

One-third of America's major roads are in poor or mediocre condition, and over one-quarter of the bridges are either structurally deficient or functionally obsolete. A 70-percent increase in annual aggregate production may be required to upgrade the transportation infrastructure. Natural aggregate is widespread throughout the conterminous United States, but the location of aggregate is determined by geology and is non-negotiable. Natural aggregate is in short supply in the Coastal Plain and Mississippi embayment, Colorado Plateau and Wyoming Basin, glaciated Midwest, High Plains, and the non-glaciated Northern Plains. A variety of techniques have been used to overcome local shortages, such as the use of substitute materials, recycling, and importing high-quality aggregates from more distant locations. Although potential sources of aggregate are widespread throughout the United States, many sources may not meet certain physical property requirements, such as soundness, hardness, strength, porosity, and specific gravity, or they may contain contaminants or deleterious materials that render them unusable. Encroachment by conflicting land uses, permitting considerations, environmental issues, and societal pressures can prevent or limit development of otherwise suitable aggregate. The use of sustainable aggregate resource management can help ensure an economically viable supply of aggregate. Sustainable aggregate resource management techniques that have successfully been used include (1) protecting potential resources from encroachment; (2) using marginal-quality local aggregate for applications that do not demand a high-quality resource; (3) using substitute materials such as clinker, scoria, and recycled asphalt and concrete; and (4) using rail and water to transport aggregates from remote sources.

Open-File Report

Opportunities and challenges in using Solid Phase Adsorption Toxin Tracking (SPATT) samplers for monitoring cyanotoxins in freshwater and estuarine environments

Cyanobacterial toxins (cyanotoxins) represent a substantial threat to drinking water supplies and safe recreational uses of freshwater resources in watersheds worldwide. Monitoring cyanotoxins can be difficult because toxin events are variable in both space and time, are not always persistent, can be moved easily by wind and currents, and may be degraded biotically or abiotically. Thus, monitoring programs that collect discrete samples on a monthly or even bimonthly interval can miss key events and underestimate cyanotoxin risk or if they capture a high-concentration event, can give a false impression that cyanotoxins are a widespread health hazard. The use of Solid Phase Adsorption Toxin Tracking (SPATT) samplers helps address this issue by providing a time-weighted average estimate of dissolved cyanotoxin occurrence and relative concentrations. SPATT samplers have been used as a complement to traditional monitoring programs and can help elucidate cyanotoxin dynamics. SPATT samplers have been used by six U.S. Geological Survey (USGS) Water Science Centers (New York, California, Oregon, Upper Midwest, New Jersey, and Lower Mississippi-Gulf) to monitor various cyanotoxins in waterbodies such as streams, rivers, lakes, waterfalls, estuaries, and drinking-water intakes. Despite their use across the USGS, there is little guidance available to ensure consistent approaches and data quality across the Bureau. This report summarizes best practices for SPATT deployment and analysis, synthesizes data and describes lessons learned from USGS studies, identifies priority knowledge gaps, and offers considerations for future targeted experiments to help improve data collection and interpretation.

Scientific Investigations Report

EAARL Coastal Topography-Mississippi and Alabama Barrier Islands, Post-Hurricane Gustav, 2008

These remotely sensed, geographically referenced elevation measurements of lidar-derived bare-earth (BE) and first-surface (FS) topography datasets were produced collaboratively by the U.S. Geological Survey (USGS), St. Petersburg Coastal and Marine Science Center, St. Petersburg, FL; the National Park Service (NPS), Gulf Coast Network, Lafayette, LA; and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of a portion of the Mississippi and Alabama barrier islands, acquired post-Hurricane Gustav (September 2008 hurricane) on September 8, 2008. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multispectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of lidar data in an interactive or batch mode. Modules for presurvey flight-line definition, flight-path plotting, lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations. For more information about similar projects, please visit the Decision Support for Coastal Science and Management website.

Data Series

Occurrence of endocrine active compounds and biological responses in the Mississippi River— Study design and data, June through August 2006

Concern that selected chemicals in the environment may act as endocrine active compounds in aquatic ecosystems is widespread; however, few studies have examined the occurrence of endocrine active compounds and identified biological markers of endocrine disruption such as intersex occurrence in fish longitudinally in a river system. This report presents environmental data collected and analyzed by the U.S. Geological Survey, Minnesota Pollution Control Agency and St. Cloud State University as part of an integrated biological and chemical study of endocrine disruption in fish in the Mississippi River. Data were collected from water, bed sediment, and fish at 43 sites along the river from the headwaters at Lake Itasca to 14 miles downstream from Brownsville, Minnesota during June through August 2006. Twenty-four individual compounds were detected in water samples, with cholesterol, atrazine, N,N-diethyl-meta-toluamide, metolachlor, and hexahydrohexamethylcyclopentabenzopyran detected most frequently (in at least 10 percent of the samples). The number of compounds detected in water per site ranged from 0 to 8. Forty individual compounds were detected in bed-sediment samples. The most commonly detected compounds (in at least 50 percent of the samples) were indole, beta-sitosterol, cholesterol, beta-stigmastanol, 3-methyl-1H-indole, p-cresol, pyrene, phenol, fluoranthene, 3-beta coprostanol, benzo[a]pyrene, acetophenone, and 2,6-dimethylnaphthalene. The total number of detections in bed sediment (at a site) ranged from 3 to 31. The compounds NP1EO, NP2EO, and 4-nonylphenol were detected in greater than 10 percent of the samples. Most (80 percent) female fish collected had measurable concentrations of vitellogenin. Vitellogenin also was detected in 62, 63, and 33 percent of male carp, smallmouth bass, and redhorse, respectively. The one male walleye sample plasma sample analyzed had a vitellogenin detection. Vitellogenin concentrations were lower in male fish (not detected to 10.80 micrograms per milliliter) than female fish (0.04 to 248,079 micrograms per milliliter). Gonadosomatic Index values ranged from 0.02 to 7.49 percent among all male fish and were greater for male carp than for the other three species. No intersex (oocytes present in testes tissue) was found in any male fish sampled.

Minnesota, Wisconsin

Chemical analyses of surface water in Illinois, 1975-77--Volume III, Ohio River tributaries and Mississippi River tributaries south of Illinois River basin

Samples of surface water were collected and analyzed by the Illinois Environmental Protection Agency. The results from water years 1975 to 1977 are presented in three volumes. The history of sampling and analytical methods used during that period are summarized. Stream discharge data from records of the U.S. Geological Survey are included for all sites where samples were collected at gaging stations or near enough that reliable discharge estimates could be made. Volume III includes Ohio River tributaries and Mississippi River tributaries south of Illinois River basin.

Illinois

Quality of Shallow Groundwater and Drinking Water in the Mississippi Embayment-Texas Coastal Uplands Aquifer System and the Mississippi River Valley Alluvial Aquifer, South-Central United States, 1994-2004

The Mississippi embayment-Texas coastal uplands aquifer system is an important source of drinking water, providing about 724 million gallons per day to about 8.9 million people in Texas, Louisiana, Mississippi, Arkansas, Missouri, Tennessee, Kentucky, Illinois, and Alabama. The Mississippi River Valley alluvial aquifer ranks third in the Nation for total withdrawals of which more than 98 percent is used for irrigation. From 1994 through 2004, water-quality samples were collected from 169 domestic, monitoring, irrigation, and public-supply wells in the Mississippi embayment-Texas coastal uplands aquifer system and the Mississippi River Valley alluvial aquifer in various land-use settings and of varying well capacities as part of the U.S. Geological Survey's National Water-Quality Assessment Program. Groundwater samples were analyzed for physical properties and about 200 water-quality constituents, including total dissolved solids, major inorganic ions, trace elements, radon, nutrients, dissolved organic carbon, pesticides, pesticide degradates, and volatile organic compounds. The occurrence of nutrients and pesticides differed among four groups of the 114 shallow wells (less than or equal to 200 feet deep) in the study area. Tritium concentrations in samples from the Holocene alluvium, Pleistocene valley trains, and shallow Tertiary wells indicated a smaller component of recent groundwater than samples from the Pleistocene terrace deposits. Although the amount of agricultural land overlying the Mississippi River Valley alluvial aquifer was considerably greater than areas overlying parts of the shallow Tertiary and Pleistocene terrace deposits wells, nitrate was rarely detected and the number of pesticides detected was lower than other shallow wells. Nearly all samples from the Holocene alluvium and Pleistocene valley trains were anoxic, and the reducing conditions in these aquifers likely result in denitrification of nitrate. In contrast, most samples from the Pleistocene terrace deposits in Memphis, Tennessee, were oxic, and the maximum nitrate concentration measured was 6.2 milligrams per liter. Additionally, soils overlying the Holocene alluvium and Pleistocene valley trains, generally in areas near the wells, had lower infiltration rates and higher percentages of clay than soils overlying the shallow Tertiary and Pleistocene terrace deposits wells. Differences in these soil properties were associated with differences in the occurrence of pesticides. Pesticides were most commonly detected in samples from wells in the Pleistocene terrace deposits, which generally had the highest infiltration rates and lowest clay content. Median dissolved phosphorus concentrations were 0.07, 0.11, and 0.65 milligram per liter in samples from the shallow Tertiary, Pleistocene valley trains, and Holocene alluvium, respectively. The widespread occurrence of dissolved phosphorus at concentrations greater than 0.02 milligram per liter suggests either a natural source in the soils or aquifer sediments, or nonpoint sources such as fertilizer and animal waste or a combination of natural and human sources. Although phosphorus concentrations in samples from the Holocene alluvium were weakly correlated to concentrations of several inorganic constituents, elevated concentrations of phosphorus could not be attributed to a specific source. Phosphorus concentrations generally were highest where samples indicated anoxic and reducing conditions in the aquifers. Elevated dissolved phosphorus concentrations in base-flow samples from two streams in the study area suggest that transport of phosphorus with groundwater is a potential source contributing to high yields of phosphorus in the lower Mississippi River basin. Water from 55 deep wells (greater than 200 feet deep) completed in regional aquifers of Tertiary age represent a sample of the principal aquifers used for drinking-water supply in the study area. The wells were screened in both confined and

Scientific Investigations Report

Chemical analyses of surface water in Illinois, 1975-77--Volume II, Illinois River basin and Mississippi River tributaries north of Illinois River basin

Samples of surface water were collected and analyzed by the Illinois Environmental Protection Agency. The results from water years 1975 to 1977 are presented in three volumes. The history of sampling and analytical methods used during that period are summarized. Stream discharge data from records of the U.S. Geological Survey are included for all sites where samples were collected at gaging stations or near enough that reliable discharge estimates could be made. Volume II includes the Illinois River basin and Mississippi River tributaries north of Illinois River basin.

Illinois