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Analog-model analysis of effect of wastewater management on the ground-water reservoir in Nassau and Suffolk Counties, New York: Report I: Proposed and current sewerage

By 1995, the water table may fall by as much as 5 metres (16 feet) in east-central Nassau County and as much as 1.8 metres (6 feet) in central Suffolk County as a result of proposed sewerage programs. similar, but generally slightly less, change may occur in the potentiometric head in the Magothy aquifer. Streamflow may decrease by as much as 55 percent in streams draining from Nassau County Sewage Disposal District 3 and as much as 56 percent in streams draining from the Huntington-Northport Sewer District.

Open-File Report↗

Development, description, and application of a geographic information system data base for water resources in karst terrane in Greene County, Missouri

A geographic information system data base was developed for Greene County, Missouri, to provide data for use in the protection of water resources. The geographic information system data base contains the following map layers: geology, cave entrances and passages, county and quadrangle boundary, dye traces, faults, geographic names, hypsography, hydrography, lineaments, Ozark aquifer potentio- metric surface, public land survey system, sink- holes, soils, springs, and transportation. Several serious incidents of ground-water contamination have been reported in the karst terrane developed in soluble carbonate rocks in Greene County. Karst terranes are environmentally sensitive because any contaminant carried by surface runoff has the potential for rapid transport through solution enlarged fractures to the ground-water system. In the karst terrane in Greene County, about 2,500 sinkholes have been located; these sinkholes are potential access points for contamination to the ground-water system. Recent examples of ground-water contamination by sewage, fertilizers, and hydrocarbon chemicals have demonstrated the sensitivity of ground water in the Greene County karst terrane to degradation. The ground-water system is a major source of drinking water for Greene County. The population in Greene County, which includes Springfield, the third largest city in Missouri, is rapidly increasing and the protection of the water resources of Greene County is an increasing concern.

Water-Resources Investigations Report↗

Ground-water levels in Wyoming, 1975

Ground-water levels are measured periodically in a network of about 260 observation wells in Wyoming to record changes in ground-water storage. The areas of water-level observation are mostly where ground water is used in large quantities for irrigation or municipal purposes. This report contains maps showing location of observation wells and water-level changes from 1975 to 1976. Well history, highest and lowest water levels , and hydrographs for most wells also are included in this report. The program of ground-water observation is conducted by the U.S. Geological Survey in cooperation with the Wyoming State Engineer and the city of Cheyenne.

Wyoming↗

Ground-water conditions in the Kaiparowits Plateau area, Utah and Arizona, with emphasis on the Navajo Sandstone

This report presents results of investigation of ground-water conditions in the Kaiparowits Plateau area of south-central Utah and north-central Arizona (fig. 1). The area is under investigation for development of its large quantities of energy resources, primarily coal. Production and transportation of those energy resources would require attendant development of water resources. The purpose of this study was to determine the availability and quality of ground water in major aquifers in the area - namely aquifers in the Entrada, Navajo, and Wingate Sandstones; emphasis was on the Navajo Sandstone. The study was made by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights. Field work was done intermittently during July through October 1979, and October 1980 through October 1981.

Arizona, Utah↗

Permafrost and ground-water conditions in the Glennallen area, Alaska

This report is an outgrowth of permafrost and geologic field studies now in progress in the southeastern Copper River basin, Alaska and is in response to inquiries for information on permafrost and ground-water conditions. Various private and governmental groups have encountered severe differential settlement of building foundations on permafrost, and consequent maintenance problems. Settlement and expansion of communities in the area also have been retarded by the apparent lack of a ready and large source of potable water. The information below is presented to make available data on permafrost and ground-water conditions for the benefit of those undertaking construction projects in the area.

Alaska↗

Development and calibration of a ground-water flow model for the Sparta Aquifer of southeastern Arkansas and north-central Louisiana and simulated response to withdrawals, 1998-2027

The Sparta aquifer, which consists of the Sparta Sand, in southeastern Arkansas and north-central Louisiana is a major water resource and provides water for municipal, industrial, and agricultural uses. In recent years, the demand in some areas has resulted in withdrawals from the Sparta aquifer that substantially exceed replenishment of the aquifer. Considerable drawdown has occurred in the potentiometric surface forming regional cones of depression as water is removed from storage by withdrawals. These cones of depression are centered beneath the Grand Prairie area and the cities of Pine Bluff and El Dorado in Arkansas, and Monroe in Louisiana. The rate of decline for hydraulic heads in the aquifer has been greater than 1 foot per year for more than a decade in much of southern Arkansas and northern Louisiana where hydraulic heads are now below the top of the Sparta Sand. Continued hydraulic-head declines have caused water users and managers alike to question the ability of the aquifer to supply water for the long term. Concern over protecting the Sparta aquifer as a sustainable resource has resulted in a continued, cooperative effort by the Arkansas Soil and Water Conservation Commission, U.S. Army Corps of Engineers, and the U.S. Geological Survey to develop, maintain, and utilize numerical ground-water flow models to manage and further analyze the ground-water system. The work presented in this report describes the development and calibration of a ground-water flow model representing the Sparta aquifer to simulate observed hydraulic heads, documents major differences in the current Sparta model compared to the previous Sparta model calibrated in the mid-1980's, and presents the results of three hypothetical future withdrawal scenarios. The current Sparta model-a regional scale, three-dimensional numerical ground-water flow model-was constructed and calibrated using available hydrogeologic, hydraulic, and water-use data from 1898 to 1997. Significant changes from the previous model include grid rediscretization of the aquifer, extension of the active model area northward beyond the Cane River Formation facies change, and representation of model boundaries. The current model was calibrated with the aid of parameter estimation, a nonlinear regression technique, combined with trial and error parameter adjustment using a total of 795 observations from 316 wells over 4 different years-1970, 1985, 1990, and 1997. The calibration data set provides broad spatial and temporal coverage of aquifer conditions. Analysis of the residual statistics, spatial distribution of residuals, simulated compared to observed hydrographs, and simulated compared to observed potentiometric surfaces were used to analyze the ability of the calibrated model to simulate aquifer conditions within acceptable error. The calibrated model has a root mean square error of 18 feet for all observations, an improvement of more than 12 feet from the previous model. The current Sparta model was used to predict the effects of three hypothetical withdrawal scenarios on hydraulic heads over the period 1998-2027 with one of those extended indefinitely until equilibrium conditions were attained, or steady state. In scenario 1a, withdrawals representing the time period from 1990 to 1997 was held constant for 30 years from 1998 to 2027. Hydraulic heads in the middle of the cone of depression centered on El Dorado decreased by 10 feet from the 1997 simulation to 222 feet below NGVD of 1929 in 2027. Hydraulic heads in the Pine Bluff cone of depression showed a greater decline from 61 feet below NGVD of 1929 to 78 feet below NGVD of 1929 in the center of the cone. With these same withdrawals extended to steady state (scenario 1b), hydraulic heads in the Pine Bluff cone of depression center declined an 2 Development and Calibration of a Ground-Water Flow Model for the Sparta Aquifer of Southeastern Arkansas and North-Central Louisiana and Simulated Response to Withdrawa

Water-Resources Investigations Report↗

Digital-computer model of the principal ground-water reservoir in Beryl-Enterprise area, Escalante Desert, Utah

The computer model presented in this report was used to simulate the principal ground-water reservoir in the Beryl-Enterprise area, Escalante Desert, Beaver, Iron, and Washington Counties, Utah (Mower, 1981). The details of the formulation of the model, testing of its validity, and the results of predictions are discussed in the cited report. This report was prepared as part of a cooperative program with the Utah Department of Natural Resources, Division of Water Rights, to investigate the water resources of the State. It is an addendum to the principal interpretive report, and it is presented in order to make the model available to anyone desiring to use it for additional predictions. The main program used was the finite-difference model for aquifer simulation in two dimensions documented by Trescott, Pinder, and Larson, (1976). Minor modifications were made to adapt the program to the principal ground-water reservoir in the Beryl-Enterprise area. All the modifications are listed at the top of table 1, and were related to parameter input and output, thus none of the computational subroutines were affected. The parameter arrays (table 1) and map of the area with a grid overlay (pi. 1) are given on following pages. The model simulates an aquifer- under water-table conditions, mostly composed of unconsoliuated basin-fill deposits. The boundaries of the modeled area (pi. 1) generally coincide with the boundaries of the saturated basin fill. However, in the southwest-central part of the model, permeable consolidated rock is included; and that part of the northern boundary between the Black and Wah Wah Mountains is an arbitrary boundary in basin fill between the Beryl-Enterprise area and the Milford area that lies to the northeast. The ignimbrite at Table Butte also was included in the active part of the model. The model includes simulation of discharge by evapotranspiration from phreatophytes. The areal recharge array was used to simulate recharge entering the modeled area at its boundaries and from stream infiltration in the southern corner near Enterprise. In addition, this array included discharge by wells operated during the period simulated as being under steady-state conditions (virtually 1937), and discharging wells simulating flow of water northeast to the Milford area. These wells also were included in the transient-state simulation (1937-77), although any changes in this discharge were modeled using the pumpage array (Group IV, table 1). The wells simulating outflow to the Milford area are shown on plate 1, but the wells pumping in 1937 are not shown unless they also were pumped during 1937-77. The pumpage array was used to simulate: (1) Discharge from wells, (2) discharge after 1977 from a mine in the southwest-central part of the model and recharge resulting form the mine discharge (pi. 1), and (3) changes in discharge in wells operated during the steady-state period. Recharge from irrigation was simulated by reducing pumpage from nodes where irrigation occurs. Discharge from all wells was reduced by 5 percent by multiplying all pumpage by 0.95 in the computer program. North of Newcastle, in T. 35 S., R. 15 W., pumpage was reduced by 35 percent because surface materials are very permeable.

Utah↗

General hydrogeology of the aquifers of Mesozoic age, Upper Colorado River Basin - excluding the San Juan Basin - Colorado, Utah, Wyoming, and Arizona

The objective of the Upper Colorado Regional Aquifer Systems Analyses (RASA) project is to assess quantitatively the occurrence, movement, and availability of water stored in rock formations underlying the basin. This is one of a series of preliminary reports that describe what is currently known (1984) about the geometry and hydrologic properties of the aquifer systems, and the chemistry of the water in known or potential aquifers. This report provides the foundation needed for the assessment of the ground-water resources of the region. The report describes only part of the hydrologic system; that is, formations of Mesozoic age. Younger and older formations significant to the hydrologic system are described in other reports.

Arizona, Colorado, Utah, Wyoming↗

Delineation of groundwater recharge areas, western Cape Cod, Massachusetts

The unconfined sand-and-gravel aquifer in western Cape Cod, Massachusetts, which is the sole source of water supply for the communities in the area, is recharged primarily from precipitation. The rate of recharge from precipitation is estimated to be about 26 inches per year (in/yr), or about 60 percent of the precipitation rate. This recharge rate yields a flow through the aquifer of about 180 million gallons per day (Mgal/d). Groundwater flows radially outward from the top of the water-table mound in the north-central part of the flow system toward the coast, as indicated by the water-table contours on the large map on this sheet. Recharge that reaches the water table near the top of the mound travels deeper through the aquifer than recharge that reaches the water table closer to the coast. All recharge to the aquifer ultimately discharges to pumping wells, streams, or coastal areas; however, some of this recharge may flow first through kettle ponds before eventually reaching these discharge points. Continued land development and population growth on western Cape Cod, and activities related to the operation of the Massachusetts Military Reservation (MMR), have created concerns regarding the supply of potable water in western Cape Cod and the quality and quantity of water discharging to ponds, streams, and coastal areas. Recent investigations estimated the future demand for drinking water in western Cape Cod, as well as the areas that contribute water to existing and proposed public-supply wells. Determining the source of freshwater that discharges to ponds, streams, and coastal areas is of critical importance in the protection of these natural resources for the communities of western Cape Cod. The purpose of this report is to illustrate concepts of ground-water recharge areas under average pumping and recharge conditions. This report presents results of an investigation conducted by the U.S. Geological Survey (USGS), in cooperation with the Air Force Center for Environmental Excellence (AFCEE), to delineate the areas that contribute recharge to public-supply wells, ponds, streams, and coastal areas on western Cape Cod for average annual pumping and recharge rates for the period of 1994–1996. The time period of 1994–1996 was selected for this analysis because it represents the average stress conditions prior to large-scale pumping, treatment, and reinjection of water from the MMR Installation Restoration Program's ground-water remediation systems. The pumping and reinjection of large amounts of water from these remediation systems would complicate greatly the delineation of ground-water recharge areas and therefore is beyond the scope of this analysis. The Chemical Spill-4 plume-containment system, however, is included in the simulation since it has been operating since 1993 and has been pumping, treating, and reinjecting only about 0.2 Mgal/d of water. Since 1996, however, AFCEE has constructed remediation systems for seven additional contaminant plumes that are not included in this analysis. Currently (1999), these systems are pumping, treating, and reinjecting about 9.7 Mgal/d. By 2002, when all of these systems, including those being designed, are expected to be operating, it is estimated that they will be pumping, treating, and reinjecting as much as 15.6 Mgal/d of water in the western Cape Cod aquifer. For additional information on the hydrology and geology of western Cape Cod, the reader is referred to the following reports: LeBlanc and others (1986), Barlow and Hess (1993), Masterson and others (1997a), Masterson and others (1997b), Masterson and others (1998), Ogden Environmental and Energy Services, Inc. (1998) and Jacobs Engineering Group, Inc. (1999).

Massachusetts↗

Simulation analysis of the ground-water flow system in the Portland Basin, Oregon and Washington

This report presents results derived from a numerical model of the ground-water flow system in the Portland Basin, Oregon and Washington, that was used to test and refine the conceptual understanding of the flow system, estimate the effects of past and future human-caused changes to ground-water recharge and discharge on ground-water levels and streamflow, and determine priorities for ground-water monitoring and data collection that would facilitate improvements in the utility and accuracy of the model.

Water Supply Paper↗

Evaluation of baseline ground-water conditions in the Mosteiros, Ribeira Paul, and Ribeira Fajã Basins, Republic of Cape Verde, West Africa, 2005-06

This report documents current (2005-06) baseline ground-water conditions in three basins within the West African Republic of Cape Verde (Mosteiros on Fogo, Ribeira Paul on Santo Antão, and Ribeira Fajã on São Nicolau) based on existing data and additional data collected during this study. Ground-water conditions (indicators) include ground-water levels, ground-water recharge altitude, ground-water discharge amounts, ground-water age (residence time), and ground-water quality. These indicators are needed to evaluate (1) long-term changes in ground-water resources or water quality caused by planned ground-water development associated with agricultural projects in these basins, and (2) the feasibility of artificial recharge as a mitigation strategy to offset the potentially declining water levels associated with increased ground-water development. Ground-water levels in all three basins vary from less than a few meters to more than 170 meters below land surface. Continuous recorder and electric tape measurements at three monitoring wells (one per basin) showed variations between August 2005 and June 2006 of as much as 1.8 meters. Few historical water-level data were available for the Mosteiros or Ribeira Paul Basins. Historical records from Ribeira Fajã indicate very large ground-water declines during the 1980s and early 1990s, associated with dewatering of the Galleria Fajã tunnel. More-recent data indicate that ground-water levels in Ribeira Fajã have reached a new equilibrium, remaining fairly constant since the late 1990s. Because of the scarcity of observation wells within each basin, water-level data were combined with other techniques to evaluate ground-water conditions. These techniques include the quantification of ground-water discharge (well withdrawals, spring discharge, seepage to springs, and gallery drainage), field water-quality measurements, and the use of environmental tracers to evaluate sources of aquifer recharge, flow paths, and ground-water residence times. In the Mosteiros Basin, measured well and spring discharge is about 220,000 cubic meters per year. For the Ribeira Paul Basin, measured well discharge, spring discharge, and ground-water seepage to springs is about 1,600,000 cubic meters per year. Ribeira Fajã Basin is the driest of the three basins with a precipitation rate of about half that of the other two basins. The only measurable ground-water discharge from this basin is from Galleria Fajã, estimated to be about 150,000 cubic meters per year. Measured discharge for all three basins does not include submarine outflow or agricultural/phreatophyte consumptive use (Paul Basin, only) and is assumed to be less than total ground-water discharge. Ground-water ages indicate that recharge to wells and springs occurred from more than 50 years ago at some locations to within the past decade at other sites. Ground water in Paul is younger than that in the other two basins, indicating that recharge generally occurred within the past 50 years. Ground water at all the dateable sites using tritium/helium in both the Mosteiros and Ribeira Fajã Basins show that recharge occurred more than 50 years before the sampling dates. Ground-water tritium/helium age dating was not possible at some sites in Mosteiros and Ribeira Fajã Basins because of the presence of helium in the aquifer derived from the mantle or aquifer matrix. However, this helium was useful for accurate age dating of the unaffected ground-water sites. Dissolved gases indicate that most ground-water recharge occurs at mid and high altitudes within all three basins; calculated recharge altitudes ranged from 700 to more than 2,000 meters. In the Mosteiros and Ribeira Fajã Basins, recharge altitudes are much higher than the wells and springs. This suggests that it may take many years for artificial recharge to result in a beneficial impact on the aquifer in areas where the agricultural projects are implemented. Recharge altitudes in Paul Basin also were generally higher than their respective ground-water discharge sampling sites except for one spring, Seladinha. This spring, in combination with generally younger ground-water ages in Paul, indicates the existence of some short flow paths where artificial recharge may possibly enhance available water resources within a few years. The salinity of wells and springs is generally low in the Ribeira Paul and Ribeira Fajã Basins, but somewhat higher in Mosteiros Basin. Specific-conductance measurements of wells and springs in Ribeira Paul and Ribeira Fajã ranged from about 200 to 700 microsiemens per centimeter at 25 degrees Celsius. Although the Monte Vermelho spring in Mosteiros Basin also has very low salinity (200 microsiemens per centimeter at 25 degrees Celsius), water from the wells along the coastal plain has specific-conductance measurements of as much as 16,000 microsiemens per centimeter at 25 degrees Celsius. These higher values indicate some brackish water intrusion. Additional ground-water development of the Mosteiros coastal plain may exacerbate this situation.

Mosteiros basin, Ribeira Fajã basin, Ribeira Paul ↗

Model-estimated ground-water recharge and hydrograph of ground-water discharge to a stream

The computer model PULSE, described in this report, can be used to construct a hydrograph of ground-water discharge to a stream. The model is applicable to a ground-water flow system that is driven by areally uniform recharge to the water table, and in which ground water discharges to a gaining stream. One of the two formulations used by the model allows for an instantaneous recharge pulse and subsequent ground-water discharge to the stream. The other formulation, which allows for a gradual hydrologic gain or loss term in addition to the instantaneous pulse, can be used to simulate the effects of gradual recharge to the water table, ground-water evapotranspiration, or downward leakage to a deeper aquifer.

Water-Resources Investigations Report↗

Reconnaissance of the ground-water resources of the upper Fremont River valley, Wayne County, Utah

This report presents the results of an investigation of the ground-water resources of the upper Fremont River valley, Utah, which was carried out during the period July 1966-June 1967, by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights. The purpose of the investigation was to determine: the source, occurrence, availability, approximate quantity, movement, and chemical quality of ground water in the valley; the recharge to and discharge from the ground-water reservoir; the extent and effects of use and development on the ground-water resources; the relation of ground water to streamflow; and if and where additional studies are needed. The report is concerned primarily with ground water in the valley fill and adjacent volcanic rocks and secondarily with the general hydrology of the upper Fremont River valley drainage basin. The field investigation was made mostly during the summer and fall of 1966. Data were collected for 63 wells and 16 springs in the valley. Records for wells and springs are given in table 4; drillers' logs of selected wells are given in table 5, and well locations are shown in figure 5. All the wells (except a few small-discharge wells) and all major springs were visited. The specific conductance of water was determined at most wells and springs; chemical analyses were made of water from selected wells and springs. Conductance data are included in table 4 and chemical analyses are given in table 6. The yield of water from wells and the water levels or artesian pressures were measured or estimated. Water-level measurements were made at monthly intervals 6 at 10 selected wells. Altitudes of the land surface at wells and springs were estimated from topographic maps or by hand leveling or determined by altimeter. Aerial photographs were used in the field to locate wells, boundaries of meadows or cultivated areas, edge of valley fill, and other features.

Utah↗

Basic elements of ground-water hydrology with reference to North Carolina

This report was prepared as an aid to developing a better understanding of the groundwater resources of North Carolina. It consists of 46 essays grouped into five parts. The topics covered by these essays range from the most basic aspects of ground-water hydrology to the identification and correction of problems that affect the operation of supply wells. The essays were designed both for self study and for use in workshops on ground-water hydrology and the development and operation of ground-water supplies. From the standpoint of self study, it is assumed that the reader does not have any prior knowledge of geology or ground-water hydrology. Those readers with such knowledge can simply skip those topics with which they are already familar. (USGS)

North Carolina↗

Documentation and verification of VST2D; a model for simulating transient, Variably Saturated, coupled water-heat-solute Transport in heterogeneous, anisotropic 2-Dimensional, ground-water systems with variable fluid density

This report describes a model for simulating transient, Variably Saturated, coupled water-heatsolute Transport in heterogeneous, anisotropic, 2-Dimensional, ground-water systems with variable fluid density (VST2D). VST2D was developed to help understand the effects of natural and anthropogenic factors on quantity and quality of variably saturated ground-water systems. The model solves simultaneously for one or more dependent variables (pressure, temperature, and concentration) at nodes in a horizontal or vertical mesh using a quasi-linearized general minimum residual method. This approach enhances computational speed beyond the speed of a sequential approach. Heterogeneous and anisotropic conditions are implemented locally using individual element property descriptions. This implementation allows local principal directions to differ among elements and from the global solution domain coordinates. Boundary conditions can include time-varying pressure head (or moisture content), heat, and/or concentration; fluxes distributed along domain boundaries and/or at internal node points; and/or convective moisture, heat, and solute fluxes along the domain boundaries; and/or unit hydraulic gradient along domain boundaries. Other model features include temperature and concentration dependent density (liquid and vapor) and viscosity, sorption and/or decay of a solute, and capability to determine moisture content beyond residual to zero. These features are described in the documentation together with development of the governing equations, application of the finite-element formulation (using the Galerkin approach), solution procedure, mass and energy balance considerations, input requirements, and output options. The VST2D model was verified, and results included solutions for problems of water transport under isohaline and isothermal conditions, heat transport under isobaric and isohaline conditions, solute transport under isobaric and isothermal conditions, and coupled water-heat-solute transport. The first three problems considered in model verification were compared to either analytical or numerical solutions, whereas the coupled problem was compared to measured laboratory results for which no known analytic solutions or numerical models are available. The test results indicate the model is accurate and applicable for a wide range of conditions, including when water (liquid and vapor), heat (sensible and latent), and solute are coupled in ground-water systems. The cumulative residual errors for the coupled problem tested was less than 10–8 cubic centimeter per cubic centimeter, 10-5 moles per kilogram, and 102 calories per cubic meter for liquid water content, solute concentration and heat content, respectively. This model should be useful to hydrologists, engineers, and researchers interested in studying coupled processes associated with variably saturated transport in ground-water systems.

Water-Resources Investigations Report↗

Documentation of model input and output values for simulation of pumping effects in Paradise Valley, a basin tributary to the Humboldt River, Humboldt County, Nevada

Documentation is provided of model input and sample output used in a previous report for analysis of ground-water flow and simulated pumping scenarios in Paradise Valley, Humboldt County, Nevada.Documentation includes files containing input values and listings of sample output. The files, in American International Standard Code for Information Interchange (ASCII) or binary format, are compressed and put on a 3-1/2-inch diskette. The decompressed files require approximately 8.4 megabytes of disk space on an International Business Machine (IBM)- compatible microcomputer using the MicroSoft Disk Operating System (MS-DOS) operating system version 5.0 or greater.

Open-File Report↗

Ground-water quality in Geauga County, Ohio — Review of previous studies, status in 1999, and comparison of 1986 and 1999 data

Most residents in Geauga County, Ohio, rely on ground water as their primary source of drinking water. With population growing at a steady rate, the possibility that human activity will affect ground-water quality becomes considerable. This report presents the results of a study by the U.S. Geological Survey (USGS), in cooperation with the Geauga County Planning Commission and Board of County Commissioners, to provide a brief synopsis of work previously done within the county, to assess the present (1999) ground-water quality, and to determine any changes in groundwater quality between 1986 and 1999. Previous studies of ground-water quality in the county have consistently reported that manganese and iron concentrations in ground water in Geauga County often exceed the U.S. Environmental Protection Agency (USEPA) Secondary Maximum Contaminant Level (SMCL). Road salt and, less commonly, oil-field brines and volatile organic compounds (VOCs) have been found in ground water at isolated locations. Nitrate has not been detected above the USEPA Maximum Contaminant Level (MCL) of 10 milligrams per liter as N; however, nitrate has been found in some locations at levels that may indicate the effects of fertilizer application or effluent from septic systems. Between June 7 and July 1, 1999, USGS personnel collected a total of 31 water-quality samples from wells completed in glacial deposits, the Pottsville Formation, the Cuyahoga Group, and the Berea Sandstone. All samples were analyzed for VOCs, sulfide, dissolved organic carbon, major ions, trace elements, alkalinity, total coliforms, and Escherichia coli bacteria. Fourteen of the samples also were analyzed for tritium. Water-quality data were used to determine (1) suitability of water for drinking, (2) age of ground water, (3) stratigraphic variation in water quality, (4) controls on water quality, and (5) temporal variation in water quality. Water from 16 of the 31 samples exceeded the Geauga County General Health District’s standard of 0 colonies of total coliform bacteria per 100 milliliters of water. Esthetically based SMCLs were exceeded in the indicated number of wells for pH (8), sulfate (1), dissolved solids (3), iron (19), and manganese (18). Hydrogen sulfide was detected at or above the detection limit of 0.01 milligram per liter in 17 of the 31 water samples. A range of water types was found among and within the four principal stratigraphic units. The waters can be categorized in three groups based on predominant anion type: bicarbonatetype waters, chloride-type waters, and sulfatetype waters. Chloride-to-bromide ratio analyses indicate that water from 8 of the 31 wells is in some way affected by human activity. Five other samples were in a chloride-to-bromide ratio range that could indicate possible effects of human activity. Ground-water-quality data from the current study were compared to data collected in 1986. Statistical analyses of data from the 16 wells that were sampled in both years did not indicate any significant changes that could be attributed to human activity.

Ohio↗