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Ordovician of the Sauk megasequence in the Ozark region of northern Arkansas and parts of Missouri and adjacent states

Exposures of Ordovician rocks of the Sauk megasequence in Missouri and northern Arkansas comprise Ibexian and lower Whiterockian carbonates with interspersed sandstones. Subjacent Cambrian strata are exposed in Missouri but confined to the subsurface in Arkansas. The Sauk-Tippecanoe boundary in this region is at the base of the St. Peter Sandstone. Ulrich and associates divided the Arkansas section into formations early in the 20th century, principally based on sparse collections of fossil invertebrates. In contrast, the distribution of invertebrate faunas and modern studies of conodonts will be emphasized throughout this chapter. Early workers considered many of the stratigraphic units to be separated by unconformities, but modern analysis calls into question the unconformable nature of some of their boundaries. The physical similarity of the several dolomites and sandstones, complex facies relations, and lack of continuous exposures make identification of individual formations difficult in isolated outcrops. The oldest formation that crops out in the region is the Jefferson City Dolomite, which may be present in outcrops along incised river valleys near the Missouri-Arkansas border. Rare fossil gastropods, bivalves, brachiopods, conodonts, and trilobites permit correlation of the Cotter through Powell Dolomites with Ibexian strata elsewhere in Laurentia. Conodonts in the Black Rock Limestone Member of the Smithville Formation and the upper part of the Powell Dolomite confirm regional relationships that have been suggested for these units; those of the Black Rock Limestone Member are consistent with deposition under more open marine conditions than existed when older and younger units were forming. Brachiopods and conodonts from the overlying Everton Formation assist in interpreting complex facies within that formation and its correlation to equivalent rocks elsewhere. The youngest conodonts in the Everton Formation provide an age limit for the Sauk-Tippecanoe unconformity near the southern extremity of the great American carbonate bank. The correlation to coeval strata in the Ouachita Mountains of central Arkansas and in the Arbuckle Mountains of Oklahoma and to rocks penetrated in wells drilled in the Reelfoot rift basin has been improved greatly in recent years by integration of biostratigraphic data with lithologic information.

Arkansas, Missouri

Lisburne Group (Mississippian and Pennsylvanian), potential major hydrocarbon objective of Arctic Slope, Alaska

The Lisburne Group, a thick carbonate-rock unit of Mississippian and Pennsylvanian age, is one of the most widespread potential reservoir-rock units in northern Alaska. A comprehensive review of the Lisburne in the subsurface of the eastern Arctic Slope indicates attractive reservoir characteristics in a favorable source and migration setting where numerous trapping mechanisms appear to be available. Evaluation of this group as a potential exploration objective is particularly timely because of impending offshore sales in the Beaufort Sea and current exploration programs under way in the Prudhoe Bay area and the Naval Petroleum Reserve. Dolomite and sandstone have been identified as reservoir rocks. Oolitic grainstone is a common rock type, but observations indicate little reservoir potential owing to complete void filling by calcite cement. The most important reservoir rock as judged by thickness, areal extent, and predictability is microsucrosic (10 to 30μ) dolomite of intertidal to supratidal origin. It is present throughout the Lisburne and is most abundant near the middle of the sequence. Northward it decreases in thickness from 1,000 ft (300 m) to less than 100 ft (30 m). Porosity of the dolomite as determined in selected wells averages between 10 and 15% and attains a maximum of slightly more than 25%. Net thickness of reservoir rocks (i.e., rocks with greater than 5% porosity) ranges in these wells from 140 to 390 ft (40 to 120 m). Oil shows are common, and drill-stem tests have yielded as much as 1,600 bbl/day of oil and 22 MMcf/day of gas in the Lisburne pool of the Prudhoe Bay field and as much as 2,057 bbl/day of salt water outside the field area. The occurrence of dolomite over such a large area makes its presence in the offshore Beaufort Sea and adjacent Naval Petroleum Reserve 4 fairly certain. The presence of sandstone as thick as 140 ft (40 m) in the middle and upper part of the Lisburne in two coastal wells suggests that larger areas of sandstone may be found on the north in offshore areas. Shows of oil and gas and a saltwater flow of 1,470 bbl/day have been recorded from this sandstone facies. Shales of Permian and Cretaceous ages unconformably overlie the Lisburne, providing adequate sealing beds above potential reservoirs. Impermeable limestone (completely cemented grainstone) and thin beds of shale may serve as seals within the Lisburne, but the possibility of fractures in these units may negate their sealing capability. The most favorable source rock for Lisburne hydrocarbons appears to be Cretaceous shale that unconformably overlies the Lisburne east of Prudhoe Bay. This shale is reported to be a rich source rock and is the most likely source for the entire Prudhoe Bay field. A source within the Lisburne or within the underlying Kayak Shale is postulated for oil shows in the southernmost Lisburne wells. This postulated source may be in a more basinal facies of the Lisburne and may be similar to dark shale in the upper Lisburne in thrust slices to dark shale in the upper Lisburne in thrust slices in the Brooks Range. Coal in the underlying Endicott Group is a possible source for dry gas. At present, much of this coal probably is in a gas-generating regime downdip from the Prudhoe Bay field. Stratigraphic traps involving the Lisburne Group may have resulted from widespread Permian and Cretaceous unconformities. Structural traps related to normal faulting may be present along the trend of the Barrow arch, and faulted anticlines are numerous in the foothills of the Brooks Range. Combination traps are possible along the trend of the Barrow arch.

Alaska

Quaternary displacement on the Joiner Ridge Fault, eastern Arkansas

The New Madrid seismic zone of the central United States is an intraplate seismic zone with blind structures that are not seismically active but may pose seismic hazards. The Joiner Ridge fault is the 35 km long east-bounding fault of the Joiner Ridge blind horst located in eastern Arkansas approximately 50 km northwest of Memphis, Tennessee. Shallow S-wave (SH-mode) seismic reflection profiles, continuous cores, and radiometric dating of Quaternary alluvium across the Joiner Ridge fault reveal down-to-the-east reverse faulting and folding within of the top of the Eocene strata and overlying Quaternary Mississippi River alluvium. The base of the Quaternary alluvium has an age of 20.3 ka and is vertically displaced 12 m, resulting in an average slip rate of 0.6 + 0.1 mm/yr over the past 20.3 ka. The overlying late Wisconsinan and Holocene alluvial facies are also displaced by the Joiner Ridge fault. These facies increase in thickness across the Joiner Ridge fault and were used to calculate late Wisconsinan and Holocene slip rates. The JRF slipped 7 m between 20.3 ka and 17.5 ka (2.8 ka), reflecting a slip rate of 2.5 + 0.3 mm/yr. From 12.3 ka to 11.5 ka (0.8 ka) the JRF slipped 3 m at an average slip rate of 3.8 + 0.9 mm/yr. There were 2 m of slip on the JRF between 11.5 ka and 8.9 ka (2.6 ka), reflecting a slip rate of 0.8 + 0.3 mm/yr. No apparent slip has occurred on the JRF within the last 8.90 ka. This research illustrates that slip rates on the JRF have varied through the late Wisconsinan and early Holocene, but the Joiner Ridge fault has been inactive since the middle Holocene.

Arkansas

Deepwater debrites and linked megaturbidites in confined basins: An example from the Onnuri Basin, East Sea of Korea

We analyzed data from seven piston cores, multi-channel seismic-reflection (MCS) and chirp profiles, and multibeam echosounder (MBES) data to study the distribution, emplacement time, sedimentary facies, and depositional processes of sediment-gravity-flow deposits in the Onnuri Basin, a confined basin in the East Sea. These data reveal that debris flows have traveled ca. 30 km downslope, forming a seismic facies consisting of stacked, wedge-shaped, transparent units separated by high-amplitude continuous reflectors. Analysis of piston cores shows three distinct sedimentary units, throughout the basin. The lowest unit, I, is a debrite containing numerous mud clasts of varying size and color distributed in a mud-rich matrix; it is absent over elevated basinal highs or ridges, such as the Onnuri Ridge, suggesting that local topography controls its distribution. The debrite forms a recognizable acoustically transparent layer on subbottom chirp profiles (av. 7 m thick), covers approximately 500 km 2 , and has an estimated volume of ∼ 3.5 km 3 . The overlying unit, II, contains normally graded beds composed of massive sand, laminated and cross-laminated sand and silt, and a thick cap of structureless mud. This unit is interpreted to be a megaturbidite deposited from turbidity currents that originated from the flow transformation of debris flows on the upper continental slope. The megaturbidite covers the entire basin (at least 650 km 2 ), and has an average thickness of 2.8 m (maximum thickness of 4.35 m), and comprises a volume of 1.8 km 3 . Variations in grain size and sedimentary structures suggest that the megaturbidite was deposited by progressively waning flows that reflected off basin flanks and ridges. The thick (up to 3.65 m) structureless mud cap further indicates deposition in a confined basin. The sharp basal contact, together with the lack of hemipelagic sediments between debrite and overlying megaturbidite, suggest that both were deposited during the same flow event, likely to have originated from a single catastrophic slope failure. Collapsing slide material evolved into a debris flow, from which a turbidite formed by dilution of the debris flow. Radiocarbon dates suggest that the slope failure occurred about 13–11 ka, a time when sea level was ca. 50 m lower than at the present day. Hemipelagic sediments in the topmost unit, III-2, above the megaturbidite indicate that the basin has been stable since ca. 11 ka. We provide robust evidence that submarine slope failures evolve downslope into slides, debris flows, and finally, thick megaturbidites. This contribution highlights the importance of seafloor morphology on the distribution and stratigraphy of submarine flows in confined basins.

Onnuri Basin

Sequential filling of a late paleozoic foreland basin

Through the use of an extensive data base of geophysical well logs, parasequence-scale subdivisions within a late Paleozoic synorogenic clastic wedge resolve cycles of sequential subsidence of a foreland basin, sediment progradation, subsidence of a carbonate shelf edge, diachronously subsiding discrete depositional centers, and basinwide transgression. Although temporal resolution of biostratigraphic markers is less precise in Paleozoic successions than in younger basins, parasequence-scale subdivisions provide more detailed resolution within marker-defined units in Paleozoic strata. As an example, the late Paleozoic Black Warrior basin in the foreland of the Ouachita thrust belt is filled with a synorogenic clastic wedge, the lower part of which intertongues with the fringe of a cratonic carbonate facies in the distal part of the basin. The stratal geometry of one tongue of the carbonate facies (lower tongue of Bangor Limestone) defines a ramp that grades basinward into a thin black shale. An overlying tongue of the synorogenic clastic wedge (lower tongue of Parkwood Formation) consists of cyclic delta and delta-front deposits, in which parasequences are defined by marine-flooding surfaces above coarsening- and shallowing-upward successions of mudstone and sandstone. Within the lower Parkwood tongue, two genetic stratigraphic sequences (A and B) are defined by parasequence offlap and downlap patterns and are bounded at the tops by basinwide maximum-flooding surfaces. The distribution of parasequences within sequences A and B indicates two cycles of sequential subsidence (deepening) and progradation, suggesting subsidence during thrust advance and progradation during thrust quiescence. Parasequence stacking in sequences A and B also indicates diachronous differential tectonic subsidence of two discrete depositional centers within the basin. The uppermost sequence (C) includes reworked sandstones and an overlying shallow-marine limestone, a vertical succession that reflects no tectonic subsidence, a very minor or null sediment supply, and basinwide transgression. The temporal resolution at parasequence scale significantly improves the resolution of the tectonic history of the thrust belt-foreland basin system.

Journal of Sedimentary Research

Climate and lake-level history of the northern altiplano, Bolivia, as recorded in holocene sediments of the Rio Desaguadero

Strata exposed in terraces and modern cutbanks along the Rio Desaguadero contain a variety of lithofacies that were deposited in four distinct facies associations. These facies associations document a history of aggradation and downcutting that is linked to Holocene climate change on the Altiplano. Braided-stream, meandering-stream, deltaic and shoreline, and lacustrine sediments preserved in multi-level terraces in the northern Rio Desaguadero Valley record two high-water intervals; one between 4500 and 3900 yr BP and another between 2000 and 2200 yr BP. These wet periods were interrupted by three periods of fluvial downcutting, centered at approximately 4000 yr BP, 3600 yr BP, and after 2000 yr BP. Braided-river sediments preserved in a single terrace level in the southern Rio Desaguadero Valley record a history of nearly continuous fluvial sedimentation from at least 7000 yr BP until approximately 3200 yr BP that was followed by a single episode (post-3210 yr BP) of down-cutting and lateral migration. The deposition and subsequent fluvial downcutting of the northern strata was controlled by changes in effective moisture that can be correlated to Holocene water-level fluctuations of Lake Titicaca. The deposition and dissection of braided-stream sediments to the south are more likely controlled by a combination of base-level change and sediment input from the Rio Mauri.

Journal of Sedimentary Research

Hydrothermal alteration, ore fluid characteristics, and gold depositional processes along a trondhjemite-komatiite contact at Tarmoola, Western Australia

Tarmoola is a structurally controlled Archean orogenic gold deposit hosted in greenschist facies metamorphosed komatiite and trondhjemite in the Leonora district of the Eastern Goldfields province, Yilgarn craton. High-grade (>1 g/t Au) orebodies are located in komatiite wall rock adjacent to the eastern and northeastern margins of the asymmetrical, north-south-striking, Tarmoola trondhjemite intrusion. Gold-bearing veins post-date trondhjemite emplacement (ca. 2700 Ma), quartz diorite dikes (ca. 2667 Ma), and regional greenschist facies metamorphism. Textures and crosscutting relationships in gold-bearing veins indicate two stages of hydrothermal fluid infiltration associated with a single gold-related hydrothermal event: a volumetrically dominant, but gold-poor, stage I fluid and a gold-rich stage II fluid. Gold-bearing veins contain stage I milky quartz and pyrite that are overprinted by stage II quartz-ankerite-muscovite-chalcopyrite-sphalerite-galena-gold-tellurides ?? albite ?? chlorite ?? fuchsite ?? epidote ?? scheelite. Stage I hydrothermal alteration assemblages are different in trondhjemite and komatiite due to contrasting reactions between a common ore fluid and disparate wall-rock chemistry. Stage II fluid-wall rock interaction was minor compared to stage I and is indicated by the overprinting of stage I mineral assemblages by stage II microveins. Wall-rock alteration proximal to veins in trondhjemite is characterized by replacement of igneous plagioclase, amphibole, biotite, and metamorphic chlorite by hydrothermal quartz, muscovite, ankerite, calcite, pyrite, chalcopyrite, sphalerite, galena, tellurides, and gold, whereas in proximal alteration in komatiite, metamorphic chlorite and talc are replaced by ankerite, quartz, muscovite, albite, chlorite, fuchsite, pyrite, chalcopyrite, sphalerite, galena, tellurides, and gold. The stage II fluid was enriched in H2O, CO2, Si, Ca, K, Na, S, Au, Ag, Cu, Pb, W, Bi, As, Mo, Zn, and Te. Based on fluid inclusion studies and stage II mineral equilibria, gold deposited from a homogeneous, neutral to slightly alkaline (pH 5.1-5.5), reduced, low-salinity (<5.5 wt % NaCl equiv) fluid that had a bulk composition of 78 mole percent H2O and 21 mole percent CO2, and trace amounts of CH4, C2H6, H2, Ar, H2S, and He. Gold deposition occurred at 300?? ?? 50??C and 0.5 to 3.0 kbars. Assuming lithostatic fluid pressures, gold precipitated at a 2- to 10-km depth. Stage II gray quartz ??18Ofluid values range from 5.9 to 7.5 per mil, whereas ??Dfluid values calculated from the dehydration of muscovite grains and measured directly from bulk fluid inclusion analyses of stage II gray quartz have ranges of -9 to -35 and -27 to -28 per mil, respectively. Hydrothermal ore fluids were transported from greater crustal depths to the site of gold deposition during the district-scale D3 event by shallowly W dipping, reverse brittle-ductile shear zones in supracrustal rock and along the steeply east dipping trondhjemite contact. Associated subhorizontal east-west shortening caused the reactivation of the eastern trondhjemite margin and subparallel foliation, which facilitated the transport of hydrothermal fluids and the generation of gold-bearing veins and hydrothermal alteration zones in komatiite. East-west-striking fractures in trondhjemite aided the lateral migration of ore fluids away from trondhjemite margins and the formation of east-west-striking gold-bearing veins and broad alteration zones. Gold was most likely transported in the stage II fluid as bisulfide complexes. The sulfidation of trondhjemite and komatiite wall rock by the stage II fluid caused the destabilization of An bisulfide complexes and gold deposition. Potassium, Ca, and CO2 metasomatism of komatiite wall rock may have enhanced gold deposition via the acidification of the stage II fluid. The physicochemical characteristics of the Tarmoola ore fluid and relative timing of gold mineralization are consistent with the Yilgarn-wide,

Economic Geology

Structural controls and evolution of gold-, silver-, and REE-bearing copper-cobalt ore deposits, Blackbird district, east-central Idaho: Epigenetic origins

The Cu-Co &plusmn; Au (&plusmn; Ag &plusmn; Ni &plusmn; REE) ore deposits of the Blackbird district, east-central Idaho, have previously been classified as Besshi-type VMS, sedex, and IOCG deposits within an intact stratigraphic section. New studies indicate that, across the district, mineralization was introduced into the country rocks as a series of structurally controlled vein and alteration systems. Quartz-rich and biotite-rich veins (and alteration zones) and minor albite and siderite veinlets maintain consistent order and sulfide mineral associations across the district. Both early and late quartz veins contain chalcopyrite and pyrite, whereas intermediate-stage tourmaline-biotite veins host the cobaltite. Barren early and late albite and late carbonate (generally siderite) form veins or are included in the quartz veins. REE minerals, principally monazite, allanite, and xenotime, are associated with both tourmaline-biotite and late quartz veins. The veins are in mineralized intervals along axial planar cleavage, intrafolial foliation, and shears. Mineralized intervals are hosted by a variety of metasedimentary rocks, including three phyllitic units of Mesoproterozoic age and two schistose units. All of these units are S-tectonites in the footwall of a regional thrust fault. Specifically, the district lies within an oblique thrust ramp containing a series of structural horses (three domains) in a duplex system. The deposits span the three domains and are hosted by metamorphic rocks that range from lower amphibolite facies in the structurally upper domain to lower-middle greenschist facies in the lower domain (an inverted metamorphic sequence). Early quartz and biotite veins were introduced during progressive folding and prolonged peak metamorphic conditions and they underwent late-tectonic retrograde recrystallization and metamorphic mineral growth, to the same extent as the country rocks in each domain. Where little subsequent deformation occurred, early veins are discordant to bedding but, where folding was polyphase and fabrics are penetrative, mineralized zones are concordant with metamorphic compositional layering. Late quartz veins in the zones are associated with retrograde minerals and textures and are only locally deformed. 40 Ar/ 39 Ar dating of unoriented muscovite from the selvage of a late quartz vein yields a Late Cretaceous age of about 83 Ma, the time of retrograde metamorphism associated with introduction of late quartz veins. Textural data at all scales indicate that the host sites for veins and the tectonic evolution of both host rocks and mineral deposits were kinematically linked to Late Cretaceous regional thrust faulting. Heat, fluids, and conduits for generation and circulation of fluids were part of the regional crustal thickening. The faulting also juxtaposed metaevaporite layers in the Mesoproterozoic Yellowjacket Formation over Blackbird district host rocks. We conclude that this facilitated chemical exchange between juxtaposed units resulting in leaching of critical elements (Cl, K, B, Na) from metaevaporites to produce brines, scavenging of metals (Co, Cu, etc) from rocks in the region, and, finally, concentrating metals in the lower-plate ramp structures. Although the ultimate source of the metals remains undetermined, the present Cu-Co &plusmn; Au (&plusmn; Ag &plusmn; Ni &plusmn; REE) Blackbird ore deposits formed during Late Cretaceous compressional deformation .

Idaho

Application of U-Th-Pb phosphate geochronology to young orogenic gold deposits: New age constraints on the formation of the Grass Valley gold district, Sierra Foothills province, California

The Grass Valley orogenic gold district in the Sierra Nevada foothills province, central California, the largest historic gold producer of the North American Cordillera, comprises both steeply dipping east-west (E-W) veins located along lithologic contacts in accreted ca. 300 and 200 Ma oceanic rocks and shallowly dipping north-south (N-S) veins hosted by the Grass Valley granodiorite; the latter have yielded about 70 percent of the 13 million ounces of historic lode gold production in the district. The oceanic host rocks were accreted to the western margin of North America between 200 and 170 Ma, metamorphosed to greenschist and amphibolite facies, and uplifted between 175 and 160 Ma. Large-scale magmatism in the Sierra Nevada occurred between 170-140 Ma and 120-80 Ma, with the Grass Valley granodiorite being emplaced during the older episode of magmatism. Uranium-lead isotopic dating of hydrothermal xenotime yielded the first absolute age of 162&plusmn;5 Ma for the economically more significant N-S veins. The vein-hosted xenotime, as well as associated monazite, are unequivocally of hydrothermal origin as indicated by textural and chemical characteristics, including grain shape, lack of truncated growth banding, lack of a Eu anomaly, and low U and Th concentrations. Furthermore, the crack-seal texture of the veins, with abundant wallrock slivers, suggests their formation as a result of episodic fluid flow possibly related to reoccurring seismic events, rather than a period of fluid exsolution from an evolving magma. The N-S veins are temporally distinct from a younger 153-151 Ma gold event that was previously reported for the E-W veins. Overlapping U-Pb zircon (159.9&plusmn;2.2 Ma) and 40Ar/39Ar biotite and hornblende (159.7&plusmn;0.6 to 161.9&plusmn;1.4 Ma) ages and geothermobarometric calculations indicate that the Grass Valley granodiorite was emplaced at ca. 160 Ma at elevated temperatures (~800&deg;C) within approximately 3 km of the paleosurface and rapidly cooled to the ambient temperature of the surrounding country rocks (<300&deg;C). The age of the granodiorite is indistinguishable from that of the N-S veins, as recorded by the U-Pb age of xenotime in those veins. Consequently, the N-S veins must have formed between 162 and 157 Ma, the maximum permissive age of magma emplacement and the youngest permissive xenotime U-Pb age, respectively, during an E- to ENE-directed compressional regime. The geochemistry of the Grass Valley granodiorite is consistent with it being the product of arc magmatism. It served as a receptive host for mineralization, but it is has no direct genetic relationship to gold mineralization. Initial uplift of the intrusive mass correlates with the initial voluminous fluid flow event and vein formation at depths of no greater than 3 km. The E-W gold-bearing veins hosted within greenschist-facies country rocks adjacent to the intrusion formed during a second hydrothermal event 5-10 million years later than the magmatism and were contemporaneous with a shift to a transtensional deformation denoted by sinistral strike-slip faulting.

California

Alteration and metallization in the Bagdad porphyry copper deposit, Arizona

The porphyritic to seriate-textured quartz monzonite host-rock at Bagdad was changed by hypogene alteration to a granular rock in which the plagioclase became albitic, orthoclase and quartz increased in amount, and hornblende and book-biotite were recrystallized to pale brown leafy biotite. Hypogene sulfides, pyrite and chalcopyrite, were added during the process of alteration, accompanied in part by sericite. Molybdenite is younger than the chalcopyrite. Locally, the host rock was altered to a quartz-orthoclase-sericite facies containing more quartz and orthoclase than is found in the main alteration facies. Chemical analyses indicate that alteration and mineralization of the host rock resulted in loss of iron, lime, and soda, and addition of sulfur, copper, and potash.Supergene changes include the formation of a chalcocite blanket in late Pliocene or early Pleistocene time. Chalcocite replaced chalcopyrite in preference to pyrite. The chalcocite blanket is truncated by the present erosion surface and its distribution can be recognized from the character of the iron oxide left in the leached cavities. Along some of the fractures and faults, supergene clay is present, consisting of kaolinite and a member of the saponite-montmorillonite group.

Arizona

Some aspects of the origin of the Ironwood iron-formation of Michigan and Wisconsin

The Ironwood iron-formation of the Gogebic Range of Michigan and Wisconsin is made up of several rock types, each of which is characterized by a different iron-rich mineral: hematite, magnetite, pyrite, iron carbonate, or iron silicate (minnesotaite, stilpnomelane). Where the Ironwood iron-formation is relatively unaltered the Plymouth, Norrie, and Anvil members consist of wavy-bedded magnetite and silicate-rich rocks, whereas the Yale and Pence members consist of even-bedded carbonate, silicate, magnetite, and pyrite-rich rocks. These rock types represent primary facies of the iron-formation that were deposited under differing physical and chemical conditions during a period of continuous iron-rich sedimentation. Animikie sedimentation in the Gogebic district began with the deposition of sandstone and dolomitic limestone in a shallow sea advancing over a low-lying land mass of lower Precambrian granite and green-stone. Continued advance of the sea, with effective separation of clastic material near shore, permitted the dominantly chemical sedimentation of the iron- formation in somewhat deeper water. The development of an off-shore basin with partially restricted circulation would have facilitated such deposition. Minor fluctuations in the physical and chemical conditions within the depositional environment are reflected in the differing facies of the iron-formation. Deposition of the iron and silica-rich chemical sediments was terminated by increased tectonism and the deposition of the thick sequence of slates and graywackes of the Tyler formation.

Michigan, Wisconsin

Massive sulfide deposits of the Southern Appalachians central Virginia volcanic-plutonic belt as a host for massive sulfide deposits

Strata-bound massive sulfide deposits of the central Virginia Piedmont occur in a volcanic- plutonic belt composed of Lower Cambrian(?) metamorphosed volcanic rocks and locally of pre-Upper Ordovician, low potassium granitoid rocks. The belt, interpreted as an ancient island arc, begins about 50 km south of Washington, D. C, and extends some 175 km south- westward. The volcanic rocks within the belt are located along the flanks of the Quantico- Columbia synclinorium and the Arvonia syncline. The Chopawamsic Formation, a western facies of the belt, consists of volcanic rocks that have the geochemical features (rare earth and immobile elements) of a tholeiitic island-arc suite; it also contains calc-alkaline components. Tholeiitic amphibolites of the Ta River Metamorphic Suite on the eastern side of the belt form an oceanward facies of the island arc, coeval with the Chopawamsic. This distribution suggests an underlying westward-dipping Cambrian(?) subduction zone. Contrasts in stratigraphy, geochemistry, and magnetic and gravity features indicate that the central Virginia volcanic- plutonic belt is not related to the Carolina slate belt as has been proposed in the past. Known sulfide bodies in the Chopawamsic and its coeval units total about 13.5 million tons. The Mineral district on the northwest flank of the Quantico-Columbia synclinorium has the largest deposits and contains about 10 million tons. Sulfide bodies in the belt consist largely of pyrite with minor sphalerite and chalcopyrite; Zn and Pb are important in a few of the smaller deposits. There are local concentrations of sphalerite and other base metal minerals within the major pyritic deposits (Zn = 1-12.5%; Cu - 1-2%; Pb as much as 5%). The dom- inantly sphaleritic deposits are found in and northward for about 15 km from the Mineral district. Sulfide mineralization is found in all types of volcanic rock, but the large sulfide bodies on the northwest flank of the Quantico-Columbia synclinorium are in felsite. Am- phibolite, containing local beds of iron-formation, is abundant on the southeast flank of the Arvonia syncline; however, most sulfide mineralization there took place in felsitic to intermediate layers. Mineralization, attributed to submarine volcanic exhalation, took place during formation of the island arc.

Economic Geology

The geometry and kinematics of the latest paleozoic Allatoona Fault, one of the youngest thrusts in the southernmost Appalachian Hinterland, Alabama and Georgia, U.S.A.

The Allatoona thrust fault in the southernmost hinterland of the Appalachian Blue Ridge-Piedmont megathrust sheet is among the latest structures in the kinematic sequence of events along the west flank of the orogen. It is an out-of-sequence, craton-directed thrust fault that cuts metamorphic isograds and earlier thrusts, and it has a nearly linear trace of ≥280 km, making it one of the major thrust faults in the orogen. On the northwest, the fault cuts Pennsylvanian or younger(?) regional cross antiforms that cause significant orogenic curvature of older underlying thrust sheets and is likely Permian in age. To the southeast, however, units within the fault hanging wall maintain a nearly constant width resulting in a significant change in the regional structural architecture of the orogen. In the central segment of the fault, where it marks the western/eastern Blue Ridge domain boundary, a ~20 km-long eyelid window (Mulberry Rock window) framed by three amphibolite facies thrust sheets overlying the greenschist facies Talladega belt allochthon, allows a 3-D view into the structural architecture, kinematics, and trajectories of the regional thrusts. Two earlier thrusts within the window (Mulberry Rock and Burnt Hickory Ridge thrusts, with a combined minimum horizontal net slip component of 27 km) are cut by the Allatoona fault, which is a ~15 m-wide high strain zone with top-to-the-northwest displacement, and a >17.2 km horizontal net slip vector. Structural branch points between the Allatoona and Mulberry Rock thrusts indicate that the Mulberry Rock allochthon is a large north-trending horse beneath the Allatoona fault, centered on the Mulberry Rock window, which is likely the result of oblique ramp thrusting over the massive Mulberry Rock Gneiss. The Allatoona fault cuts down obliquely into the tectonostratigraphy progressively deeper both to the northeast and northwest, locally approaching underlying foreland thrust sheets, and cutting older regional structures. To the northeast, the Allatoona fault lies at the base of the Dahlonega gold belt, becoming an internal eastern Blue Ridge thrust at Dawsonville, Georgia. Although that sequence extends another 120 km into North Carolina, continuation of the Allatoona fault that additional distance is in debate. Regardless, the Allatoona is one of the kinematically latest and longest faults in the southern Appalachian orogen.

Alabama, Georgia, South Carolina

Silurian-Devonian age and tectonic setting of the Connecticut Valley-Gaspé trough of Vermont using U-Pb SHRIMP analyses of detrital zircons

U-Pb SHRIMP ages of detrital zircons from metasedimentary rocks of the Connecticut Valley-Gaspe' trough in Vermont corroborate a Silurian-Devonian age of deposition for these strata and constrain their provenances. Ages of randomly selected detrital zircons obtained from quartzites within the Waits River and Gile Mountain Formations range from Archean to Devonian with Mesoproterozoic, Neoproterozoic, Ordovician, and Silurian age populations suggesting both eastern and western sources of the sediments. The two youngest single-grain detrital zircon ages from samples collected in the Waits River Formation are 418 ± 7 and 415 ± 2 Ma. The youngest single-grain detrital zircon age from the eastern part of the Gile Mountain Formation is 411 ± 8. The youngest detrital zircons from the western portion of the Gile Mountain Formation comprise an age population with a weighted average of 409 ± 5 Ma. These~409 Ma zircons are likely of volcanic origin, perhaps derived from the Piscataquis magmatic belt to the east. The absence of younger volcanic zircons in the coarser-grained eastern facies of the Gile Mountain Formation suggests the eastern sediments are older and were buried during Piscataquis volcanism and deposition in the west. The shift in protoliths from calcareous silts and muds of the Waits River Formation to quartzo-feldspathic sands of the Gile Mountain Formation implies a change from a continental slope-like depositional environment to a near-shore or terrestrial environment of deposition. This change supports a transition in the nature of the basin from an intercontinental back-arc extensional setting to a foreland basin setting. Maximum depositional ages of sediments above and below this facies boundary constrain the timing of transition in basin style between about 415 and 411 Ma. Given the timing of the approaching Acadian wedge, this shift in basin style likely reflects westward migration of thrust sheets during the Acadian orogeny. The finegrained nature of the youngest silts, muds and turbidites suggests that sedimentation occurred in increasingly deeper water. The implied basin subsidence was likely caused by lithospheric flexure as the Acadian wedge approached from the east. The timing of this subsidence is constrained to be younger than the youngest zircons at about 409 Ma.

Vermont

The geology of a part of Acadia and the nature of the Acadian orogeny across Central and Eastern Maine

The zone of Acadian collision between the Medial New England and Composite Avalon terranes is well preserved in Maine. A transect from northwest (Rome) to southeast (Camden) crosses the eastern part of Medial New England comprising the Central Maine basin, Liberty-Orrington thrust sheet, and Fredericton trough, and the western part of Composite Avalon, including the Graham Lake, Clarry Hill, and Clam Cove thrust sheets. U-Pb geochronology of events before, during, and after the Acadian orogeny helps elucidate the nature and distribution of tectonostratigraphic belts in this zone and the timing of some Acadian events in the Northern Appalachians. The Central Maine basin consists of sedimentary and volcanic rocks of Middle Ordovician (∼470 to ∼460 Ma) age overlain with probable conformity by latest Ordovician(?) through earliest Devonian marine rift and flysch sedimentary rocks; these are intruded by weakly to undeformed plutonic rocks of Early and Middle Devonian age (∼399–378 Ma). The Fredericton trough consists of Early Silurian gray pelite and sandstone to earliest Late Silurian calcareous turbidite, deformed and variably metamorphosed prior to the emplacement of Late Silurian (∼422 Ma) and Early to Late Devonian (∼418 to ∼368 Ma) plutons. The Liberty-Orrington thrust sheet consists of Cambrian(?)-Ordovician (>∼474 to ∼469 Ma and younger) clastic sedimentary and volcanic rocks intruded by highly deformed Late Silurian (∼424 to ∼422 Ma) and Devonian (∼418 to ∼389 Ma) plutons, possibly metamorphosed in Late Silurian time (prior to ∼417 Ma), and metamorphosed to amphibolite facies in Early to Middle Devonian time (∼400 to ∼381 Ma). The Graham Lake thrust sheet contains possible Precambrian rocks, Cambrian sedimentary rocks with a volcanic unit dated at ∼503 Ma, and Ordovician rocks with possible Caradocian Old World fossils, metamorphosed and deformed in Silurian time and intruded by mildly to undeformed Late Silurian (∼421 Ma) and Late Devonian (∼371 to ∼368 Ma) plutons. The Clarry Hill thrust sheet consists of poorly studied, highly metamorphosed Cambrian (?) rocks. The Clam Cove thrust sheet contains highly deformed Precambrian limestone, shale, sandstone, and conglomerate, metamorphosed to epidote amphibolite facies and intruded by a mildly deformed pluton dated at ∼421 Ma. Metamorphism, deformation, and voluminous intrusive igneous activity of Silurian age are common to both the most southeastern parts of Medial New England and the thrust sheets of Composite Avalon. In contrast to Medial New England, the thrust sheets of Composite Avalon show only modest effects of Devonian deformation and metamorphism. Regional stratigraphic relations, paleontologic findings, and U-Pb geochronology suggest that the Graham Lake, Clarry Hill, and Clam Cove thrust sheets are far-traveled allochthons that were widely separated from Medial New England in the Silurian. One hundred nine (109) new U-Pb analyses of zircon, monazite, and sphene from 25 samples of metamorphosed, stratified, and intrusive igneous rocks are used to decipher the history of events along the transect. In our view, many of the structures within Medial New England were formed during the closing of the back-arc ocean during the waning stages of the Taconian orogeny. These features include the precursors to the upright folds found in Silurian sedimentary rocks, the west-facing Liberty-Orrington thrust sheet, and the Silurian plutons of Medial New England. Acadian tectonic features, including flysch sedimentation, igneous activity, deformation with nappe emplacement, and metamorphism record the progressive loading of Medial New England by a stack of thrust nappes emplaced in latest Silurian to Middle Devonian time. The Acadian orogeny is a prolonged event, lasting from earliest Late Silurian to the Late Devonian, whose evolution involved: (1) convergence between Medial New England and Composite Avalon along an east-dipping subduction zone from earliest Late Silurian to Early Devonian time; (2) collision and concurrent delamination of lithospheric mantle beneath Medial New England in Early Devonian time resulting in deformation, high-grade metamorphism, and intrusive igneous activity in the most eastern part of Medial New England and the western parts of Composite Avalon; (3) Early to Middle Devonian northwest-migrating penetrative deformations of the Acadian Main stage, including northwest-directed thrusting and recumbent folding followed by tightening of folds possibly produced in the waning stages of the Taconian orogeny and forming folded wave trains of isoclinal folds (∼419 to ∼404 Ma), (4) asymmetrical folds produced by east-west shortening (∼399 to ∼380 Ma); and (5) final westward emplacement of Composite Avalon thrust sheets onto Medial New England in Late Devonian time (∼380 to ∼371 Ma). The present boundary between rocks of Medial New England and Composite Avalon at the surface is the Sennebec Pond fault, a high-angle fault that cuts the Graham Lake and Clarry Hill thrusts, and is intruded by the Mt. Waldo pluton (∼371), one of several Late Devonian plutons (∼371 to ∼367 Ma) that mark the end of the Acadian orogeny in coastal Maine. The thrust sheets of Composite Avalon carried rocks of peri-Gondwanan affinity and with possible Old World fauna many kilometers to the west over Medial New England, thus potentially hiding the original suture at depth under the Gulf of Maine.

Maine

Variations in pore-water quality, mineralogy, and sedimentary texture of clay-silts in the lower Miocene Kirkwood Formation, Atlantic City, New Jersey

Properties of and pore-water solute chemistry in confining units in the New Jersey Coastal Plain were studied to determine whether leakage of solute-enriched pore water from confining units affects regional aquifer-water chemistry, which ultimately may result in aquifer waters with high sodium and bicarbonate concentrations. Pore-water samples collected from a continuously cored borehole in the lower Miocene Kirkwood Formation at Atlantic City, NJ, were analyzed: 15 samples were obtained from clay-silt confining-unit sediments, and four samples were from silt interbeds in the sand of the major confined aquifer in the region, the Atlantic City 800-ft sand. The samples were analyzed to assess interrelations among mineralogy, texture, fluidretention properties, sediment chemistry, and pore-water chemistry, and to document the scale of variation in these properties. Linear regressions were developed to describe the relations of constituents dissolved in 14 pore-water samples collected from the lower confining unit overlying the Atlantic City 800-ft sand and from the silt interbeds in the upper sand unit of the Atlantic City 800-ft sand. The regressions were for concentrations of magnesium and calcium (m = 0.27, R2 = 0.99); concentrations of sodium and the sum of calcium and magnesium (m = 0.17, R 2 = 0.92); concentrations of sulfate and the sum of calcium and magnesium (m = 1.14, R 2 = 0.99); and concentrations of sodium and sulfate (m = 0.14, R 2 = 0.89). The percentage of fine sand was greatest in the shallowest sampled interval, where pore-water concentrations of calcium, magnesium, and sulfate were greatest. The pore-water samples were of three distinct water-quality types (hydrogeochemical facies): a calcium-sulfate type, a mixed calcium-sodium-sulfate-chloride-bicarbonate type, and a sodium-sulfate-bicarbonate-chloride type. The first two types were found only in the lower confining unit; the third type was found only in the composite confining unit underlying the Atlantic City 800-ft sand. Each of these hydrogeochemical facies generally is found within distinct intervals over a range of tens of feet in the core. Krige estimates of pore-water–constituent variations with depth were made by using only the analytical results for the 14 samples from the lower confining unit overlying the Atlantic City 800-ft sand and the silt interbeds in the upper sand unit of the Atlantic City 800-ft sand. Geostatistical analysis of the pore-water–quality data generally resulted in two types of semivariograms. One semivariogram type best fits concentration trends with depth for calcium, magnesium, strontium, sodium, sulfate, and specific conductance; lithium and chloride may also fit this semivariogram type. The other semivariogram type best fits concentration trends with depth for silica, cation exchange capacity, and dissolved inorganic carbon. The scale of variation of the concentrations and properties is indicated by the maximum lag autocorrelation distance of the theoretical semivariograms (the range) and ranged from 44 to 110 ft (13.4–33.5 m). The scale of variation of pore-water major-ion concentrations of sulfate, chloride, calcium, and magnesium alone is on the order of 65–70 ft (19.8–21.3 m). The semivariograms for all pore-water constituents except silica have significant variance at the smallest lag distance, indicating that the constituent concentration varied over a larger scale than the sampling interval. The dominant exchangeable cation in the sediment is calcium. Cation exchange reactions do not appear to be the dominant process in the sediments of the lower confining unit above the Atlantic City 800-ft sand, because a linear correlation exists between the concentration of sodium and the sum of calcium and magnesium concentrations in the pore water; concentrations of all these constituents increase in the upward flow direction, and the ratio of sodium to chloride in the pore water is about 1.0. Two significant principal components explained 82.5% of the total variation in pore-water solute chemistry. Principal component 1 represents about 53% of the variation in pore-water quality and includes calcium, magnesium, sulfate, strontium, and lithium. Coupled chemical processes in the confining units, such as incongruent dissolution of carbonate and other mineral phases or redox transformations of sulfur, likely explain the covariance of these constituents. Principal component 2 represents about 30% of the variation and includes sodium, dissolved inorganic carbon, and chloride. Covariance of sodium and chloride probably is caused by the presence of residual seawater.

New Jersey

Late Miocene (Santa Margarita Sandstone) shallow marine clastics

The Santa Margarita Sandstone of late middle and early late Miocene age is located in the western Santa Cruz Mountains of central California. It represents a marine, tide-dominated, transgressive deposit which, during the early stage of the marine transgression formed a seaway connection between the Pacific Ocean and the interior San Joaquin basin to the east. The strong tidal current flow which developed as a result of this setting caused the deposition and preservation of large-scale, essentially unidirectional cross-bedded sets of shelf sand and gravel. During this field trip 3 quarry exposures within Scotts Valley (figure 1 and 2) located near the central part of the seaway deposits will be examined observing both lateral and vertical facies relationships as well as textural variations preserved within the Santa Margarita Sandstone. On the last stop, stop 4, located to the west within the seaway deposits both lateral facies relationships in relation to the previous stops will be observed and discussed as well as examine petroleum-saturated sandstones.

Report

Geology of the Lake Mary quadrangle, Iron County, Michigan

The Lake Mary quadrangle is in eastern Iron County, in the west part of the Upper Peninsula of Michigan. The quadrangle is underlain by Lower and Middle Precambrian rocks, formerly designated Archean and Algonkian rocks, and is extensively covered by Pleistocene glacial deposits. A few Upper Precambrian (Keweenawan) diabase dikes and two remnants of sandstone and dolomite of early Paleozoic age are also found in the area. The major structural feature is the Holmes Lake anticline, the axis of which strikes northwest through the northeast part of the quadrangle. Most of the quadrangle, therefore, is underlain by rock of the west limb of the anticline. To the northwest along the fold axis, the Holmes Lake anticline is separated from the Amasa oval by a saddle of transverse folds in the vicinity of Michigamme Mountain in the Kiernan quadrangle. The Lower Precambrian rocks are represented by the Dickinson group and by porphyritic red granite whose relation to the Dickinson group is uncertain, but which may be older. The rocks of the Dickinson group are chiefly green to black metavolcanic schist and red felsite, some of the latter metarhyolite. The dark schist is commonly magnetic. The Dickinson group underlies the core area of the Holmes Lake anticline, which is flanked by steeply dipping Middle Precambrian formations of the Animikie series. A major unconformity separates the Lower Precambrian rocks from the overlying Middle Precambrian rocks. In ascending order the formations of the Middle Precambrian are the Randville dolomite, the Hemlock formation, which includes the Mansfield iron-bearing slate member, and the Michigamme slate. An unconformity occurs between the Hemlock formation and Michigamme slate. The post-Hemlock unconformity is thought to be represented in the Lake Mary quadrangle by the absence of iron-formation of the Amasa formation, which is known to lie between the Hemlock and the Michigamme to the northwest of the Lake Mary quadrangle in the Crystal Falls quadrangle. Post-Hemlock erosion may account also for the absence of iron-formation of the Fence River formation on the east limb of the Holmes Lake anticline within the Lake Mary quadrangle. The Randville dolomite is not exposed and is known only from diamond drilling in the northeast part of the area where it occurs in the east and west limbs of the Holmes Lake anticline. The formation has a maximum thickness of about 2,100 feet; this includes a lower arkosic phase, some of which is quartz pebble conglomerate, a medial dolomitic phase, and an upper slate phase. The triad is gradational. Included within the formation are a few beds of chloritic schist thought to be of volcanic origin. An unconformity between the Randville and the succeeding Hemlock is not indicated in the quadrangle, but is probably present. The Hemlock formation is best exposed in the northwest and south-central parts of the area. The apparent thickness of the formation is 10,000- 17,000 feet. It is composed mainly of mafic metavolcanic rocks and intercalated slate and iron-formation. In the north part of the quadrangle the volcanic rocks are greenstone, which includes altered basaltic flow rocks, volcanic breccia, tuff, and slate. Pillow structures are common in the metabasalt. It is not certain if any Hemlock rocks are present in the east limb of the Holmes Lake anticline. In the south part of the quadrangle, the rocks of the Hemlock are chiefly chlorite and hornblende schist and hornfels. Pyroxene hornfels is sparingly present. At least two sedimentary slate belts are included in the Hemlock formation. One of these, the Mansfield iron-bearing slate member, includes in its upper part an altered chert-siderite iron-formation 30 to over 150 feet thick from which iron ore has been mined at the Mansfield location. The position of the iron-bearing rocks has been determined magnetically, and past explorations for iron ore are discussed. Though probably; unconformable, the contact between the Hemlock and the Michigamme formations appears conformable. The Michigamme slate consists of at least 4,000 feet of interbedded mica schist and granulite, the altered equivalents of the slate and graywacke characteristic of the Michigamme in adjacent areas. The Michigamme rocks are best exposed in the south part of the quadrangle in the vicinity of Peavy Pond. Two periods of regional metamorphism have resulted in the alteration of almost all of the rocks of the quadrangle. The Lower Precambrian rocks underwent at least one period of metamorphism, uplift, and erosion before the deposition of the Randville dolomite. After the deposition of the Michigamme slate, a post-Middle Precambrian period of regional metamorphism occurred with attending deformation and igneous intrusion. The grade of metamorphism rises toward the south in the area. The rocks in the northern two-thirds of the quadrangle are representative of greenschist facies of regional metamorphism, whereas the rocks in the southern onethird of the quadrangle are representative of the albite-epidote-amphibolite, the amphibolite, and the pyroxene hornfels facies, the metamorphic node centering about the intrusive Peavy Pond complex in the Peavy Pond area. The Precambrian sedimentary and volcanic rocks are cut by intrusive igneous rocks of different types and several different ages. Gabbroic sills and dikes invaded the Hemlock rocks at some time after the Hemlock was deposited and before the post-Middle Precambrian orogeny and metamorphism. Some contact metamorphism attended the intrusion of the major sills. One of the sills, the West Kiernan sill, is well differentiated. A syntectonic igneous body, composed of gabbro and minor ultramafic parts and fringed with intermediate and felsic differentiates and hybrids, the Peavy; Pond complex, was intruded into the Hemlock and Michigamme formations during the post-Middle Precambrian orogeny. The complex is situated in the Peavy Pond area at the crest of the regional metamorphic node. Contact-altered sedimentary and volcanic rocks margin the complex. The effects of regional metamorphism have been superposed on the contact metamorphic rocks peripheral to the complex and on the igneous rocks of the complex as well. The mafic augite-bearing rocks of the complex emplaced early in the orogeny were deformed by granulation at the peak of the deformation and subsequently metamorphosed to hornblende rocks. Some of the intermediate and felsic rocks of the complex were foliated by the deformation, while the more fluid, felsic parts of the complex were intruded under orogenic stress and crystallized after the peak of deformation. The deformation culminated in major faulting during which the formations were dislocated, and some of the granite of the complex was extremely brecciated. A few diabase dikes, probably of Keweenawan age, have intruded the deformed and altered Animikie rocks. The only known metallic resource is iron ore. The Mansfield mine produced 1¥2 million tons of high-grade iron ore between the years 1890 and 1913. Sporadic exploration since 1913 has failed to reveal other ore deposits of economic importance.

Michigan