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Selected findings and current perspectives on urban and agricultural water quality by the National Water-Quality Assessment Program

Studies by the USGS National Water-Quality Assessment (NAWQA) program in the last decade describe water-quality conditions in nearly 120 agricultural and 35 urban watersheds ('urban' primarily refers to residential and commercial development over the last 50 years). The findings show that for both urban and agricultural areas, nonpoint chemical contamination is an issue. Much work still needs to be done in urban areas with point source contamination as well, including infrastructure improvements. Appreciable improvements in overall water quality, however, will depend upon effective management of point and nonpoint sources. The findings show that nonpoint chemical contamination is an agricultural and urban issue. Whereas a lot of work still needs to be pursued with point source contamination and infrastructure improvements in urban areas (such as related to combined and sanitary sewer overflows), appreciable improvements in water quality also will depend upon management of nonpoint sources. The NAWQA findings also show that water-quality conditions and aquatic health reflect a complex combination of land and chemical use, land-management practices, population density and watershed development, and natural features, such as soils, geology, hydrology, and climate. Contaminant concentrations vary from season to season and from watershed to watershed. Even among seemingly similar land uses and sources of contamination, different areas can have very different degrees of vulnerability and, therefore, have different rates at which improved treatment or management can lead to water-quality improvements.

Fact Sheet

Wave exposure of Corte Madera Marsh, Marin County, California: A field investigation

Tidal wetlands provide valuable habitat, are an important source of primary productivity, and can help to protect the shoreline from erosion by attenuating approaching waves. These functions are threatened by the loss of tidal marshes, whether due to erosion, sea-level rise, or land-use practices. Erosion protection by wetlands is expected to vary geographically, because wave attenuation in marshes depends on vegetation type, density, and height and wave attenuation over mudflats depends on slope and sediment properties. In macrotidal northern European marshes, a 50 percent reduction in wave height within tens of meters of vegetated salt marsh has been observed. This study was designed to evaluate the role of mudflats and marshes in attenuating waves at a site in San Francisco Bay. In prehistoric times, the shoreline of San Francisco Bay was ringed with tidal wetlands, with mudflats at lower elevations and marshes above. Most of the marshes around the Bay emerged 2,000–4,000 years ago, after the rate of sea-level rise slowed to approximately 1 mm/year. Approximately 80 percent of the acreage of tidal marsh and 40 percent of the acreage of tidal mudflats in San Francisco Bay have been lost to filling and draining since 1800. Tidal wetlands are particularly susceptible to impacts from sea-level rise because the vegetation at each elevation is adapted to a specific tidal-inundation regime. The maintenance of suitable marsh-plain elevations depends on a supply of sediment that can keep up with the rate of sea-level rise. Sea-level rise, which according to recent projections may reach 75 to 190 cm by the year 2100, poses a significant threat to wetlands in San Francisco Bay, where landward migration is frequently impossible due to urbanization of the adjacent landscape. In this study, we collected data in Corte Madera Bay and Marsh to determine whether, and to what degree, waves are attenuated as they transit the Bay and, during high tides, the marsh. Corte Madera Bay was selected as a study site because of its exposure to wind waves, as well as its history of shoreline erosion and marsh restoration and monitoring. Data were collected in the winter of 2010, along a cross-shore transect extending from offshore of the subtidal mudflats into the tidal marsh. This study forms part of the Innovative Wetland Adaptation in the Lower Corte Madera Creek Watershed Project initiated by the Bay Conservation and Development Commission (BCDC) ( http://www.bcdc.ca.gov/planning/climate_change/WetlandAdapt.shtml ).

California

Estimating spatially and temporally varying recharge and runoff from precipitation and urban irrigation in the Los Angeles Basin, California

A daily precipitation-runoff model, referred to as the Los Angeles Basin watershed model (LABWM), was used to estimate recharge and runoff for a 5,047 square kilometer study area that included the greater Los Angeles area and all surface-water drainages potentially contributing recharge to a 1,450 square kilometer groundwater-study area underlying the greater Los Angeles area, referred to as the Los Angeles groundwater-study area. The recharge estimates for the Los Angeles groundwater-study area included spatially distributed recharge in response to the infiltration of precipitation, runoff, and urban irrigation, as well as mountain-front recharge from surface-water drainages bordering the groundwater-study area. The recharge and runoff estimates incorporated a new method for estimating urban irrigation, consisting of residential and commercial landscape watering, based on land use and the percentage of pervious land area. The LABWM used a 201.17-meter gridded discretization of the study area to represent spatially distributed climate and watershed characteristics affecting the surface and shallow sub-surface hydrology for the Los Angeles groundwater study area. Climate data from a local network of 201 monitoring sites and published maps of 30-year-average monthly precipitation and maximum and minimum air temperature were used to develop the climate inputs for the LABWM. Published maps of land use, land cover, soils, vegetation, and surficial geology were used to represent the physical characteristics of the LABWM area. The LABWM was calibrated to available streamflow records at six streamflow-gaging stations. Model results for a 100-year target-simulation period, from water years 1915 through 2014, were used to quantify and evaluate the spatial and temporal variability of water-budget components, including evapotranspiration (ET), recharge, and runoff. The largest outflow of water from the LABWM was ET; the 100-year average ET rate of 362 millimeters per year (mm/yr) accounted for 66 percent of the combined water inflow of 551 mm/yr, including 488 mm/yr from precipitation and 63 mm/yr from urban irrigation. The simulated ET rate varied from a minimum of 0 mm/yr for impervious areas to high values of more than 1,000 mm/yr for many areas, including the south-facing slopes of the San Gabriel Mountains, stream channels underlain by permeable soils and thick root zones, and pervious locations receiving inflows both from urban irrigation and surface water. Runoff was the next largest outflow, averaging 145 mm/yr for the 100-year period, or 26 percent of the combined precipitation and urban-irrigation inflow. Recharge averaged 45 mm/yr, or about 8 percent of the combined inflow from precipitation and urban irrigation. Simulation results indicated that recharge in response to urban irrigation was an important component of spatially distributed recharge, contributing an average of 56 percent of the total recharge to the eight LABWM subdomains containing the Los Angeles groundwater study area. The 100‑year average recharge rate for the eight subdomains was 41 mm/yr, or 8,473 hectare-meters per year (ha-m/yr), with urban irrigation included in the simulation compared to a recharge rate of 18 mm/yr, or 3,741 ha-m/yr, with urban irrigation excluded. In contrast to recharge, the effect of urban irrigation on runoff was slight; runoff was 72,667 ha-m/yr with urban irrigation included compared to 72,618 ha-m/yr with urban irrigation excluded, an increase of only 48 ha-m/yr (about 0.1 percent). Simulation results also indicated that potential recharge from hilly drainages outside of, but bordering and tributary to, the lower-lying area of the Los Angeles groundwater study area, in this study referred to as mountain-front recharge, could provide an important contribution to the total recharge for the groundwater basins. The time-averaged recharge rate was similar to the combined direct and mountain-front recharge components estimated in a previous study and used as input for a calibrated groundwater model. The annual (water year) recharge estimates simulated in this study, however, indicated much greater year-to-year variability, which was dependent on year-to-year variability in the magnitude and distribution of daily precipitation, compared to the previous estimates.

California

Carbon and nitrogen isotopes of different native fish tissues from the Santa Ana River, California

Objective Stable isotopes are commonly used to understand the role of fishes in aquatic food webs. However, variability in species- and tissue-specific isotopic values can affect the inference that is drawn from a stable isotope study. We evaluated differences in stable isotopes of carbon (δ 13 C) and nitrogen (δ 15 N) among three tissue types (white muscle, caudal fin rays, and eye lenses) for Santa Ana Sucker Pantosteus santaanae and Arroyo Chub Gila orcuttii to inform the design of a stable isotope study in the Santa Ana River, an urban river that is located in southern California. Methods We used multivariate analyses to test for differences in the stable isotopes of carbon (δ 13 C) and nitrogen (δ 15 N) among the three tissue types that were collected from Santa Ana Sucker and Arroyo Chub. We also summarized the variability in isotopic values that was recorded over time in fish eye lenses and interpreted this variability in reference to the spatial patterns in isotopic values that have been previously reported throughout the Santa Ana River. Results We found that fin ray tissue and white muscle tissue were not significantly different for either isotope or fish species. Fish eye lenses were significantly higher in δ 13 C than muscle tissue, and eye lenses were significantly higher in δ 15 N than fin ray tissue for both fishes. We also found a greater range in δ 13 C and δ 15 N across eye lens layers for Santa Ana Sucker (δ 13 C = 2.01 ± 0.96‰, δ 15 N = 4.93 ± 4.18‰) than for Arroyo Chub (δ 13 C = 0.96 ± 0.65‰, δ 15 N = 4.63 ± 1.45‰). Conclusion Our results indicate that fin rays may be a viable nonlethal alternative to white muscle tissue for use in a stable isotope study of native fish of the Santa Ana River. Additionally, eye lenses could provide a chemical history of fishes within the river, but species-specific correction factors may be needed if stable isotope values for eye lenses are to be compared with more conventional tissue types (e.g., white muscle).

California

Loss of street trees predicted to cause 6000 L/tree increase in leaf-on stormwater runoff for Great Lakes urban sewershed

Urban forests are recognized as a nature-based solution for stormwater management. This study assessed the underlying processes and extent of runoff reduction due to street trees with a paired-catchment experiment conducted in two sewersheds of Fond du Lac, Wisconsin. Computer models are flexible, fast, and low-cost options to generalize and assess the hydrologic processes determined in field studies. A state-of-the-art, public-domain model, which explicitly simulates urban tree hydrology, i-Tree Hydro, was used to simulate the paired-catchment experiment, and results from field observations and simulation predictions were compared to assess model validity and suitability as per conditions in the broader Great Lakes basin. Model parameters were aligned with observed conditions using automatic and manual calibration. Model performance metrics were used to quantify the weekly performance of calibration and to validate predictions. Those calibration metrics differed substantially between the two periods simulated, but most calibration metrics remained positive, indicating the model was not fitting only the period used for calibration. Predicted avoided runoff for a five-month leaf-on period was 64 L/m2 of canopy, 4 % lower than the field-estimated avoided runoff of 66 L/m2 of canopy. Interception was the most directly comparable process between the model and field observations. Based on 5 storms sampled, field estimation of precipitation intercepted and retained on trees averaged 63 % and ranged from 22 % to 81 %, while model estimation averaged 61 % and ranged from 36 % to 99 %. This model was able to fit predictions to observed catchment discharge but required extensive manual calibration to do so. The i-Tree Hydro model predicted avoided runoff comparable with the field study and earlier assessments. Additional field studies in similar settings are needed to confirm findings and improve transferability to other tree species and environmental settings.

Wisconsin

Concentrations and characteristics of organic carbon in surface water in Arizona: Influence of urbanization

Dissolved (DOC) and total (TOC) organic carbon concentrations and compositions were studied for several river systems in Arizona, USA. DOC composition was characterized by ultraviolet and visible absorption and fluorescence emission (excitation wavelength of 370 nm) spectra characteristics. Ephemeral sites had the highest DOC concentrations, and unregulated perennial sites had lower concentrations than unregulated intermittent sites, regulated sites, and sites downstream from wastewater-treatment plants (p < 0.05). Reservoir outflows and wastewater-treatment plant effluent were higher in DOC concentration (p < 0.05) and exhibited less variability in concentration than inflows to the reservoirs. Specific ultraviolet absorbance values at 254 nm were typically less than 2 m-1(milligram DOC per liter)-1 and lower than values found in most temperate-region rivers, but specific ultraviolet absorbance values increased during runoff events. Fluorescence measurements indicated that DOC in desert streams typically exhibit characteristics of autochthonous sources; however, DOC in unregulated upland rivers and desert streams experienced sudden shifts from autochthonous to allochthonous sources during runoff events. The urban water system (reservoir systems and wastewater-treatment plants) was found to affect temporal variability in DOC concentration and composition. (C) 2000 Elsevier Science B.V.Dissolved (DOC) and total (TOC) organic carbon concentrations and compositions were studied for several river systems in Arizona, USA. DOC composition was characterized by ultraviolet and visible absorption and fluorescence emission (excitation wavelength of 370 nm) spectra characteristics. Ephemeral sites had the highest DOC concentrations, and unregulated perennial sites had lower concentrations than unregulated intermittent sites, regulated sites, and sites downstream from wastewater-treatment plants (p<0.05). Reservoir outflows and wastewater-treatment plant effluent were higher in DOC concentration (p<0.05) and exhibited less variability in concentration than inflows to the reservoirs. Specific ultraviolet absorbance values at 254 nm were typically less than 2 m-1(milligram DOC per liter)-1 and lower than values found in most temperate-region rivers, but specific ultraviolet absorbance values increased during runoff events. Fluorescence measurements indicated that DOC in desert streams typically exhibit characteristics of autochthonous sources; however, DOC in unregulated upland rivers and desert streams experienced sudden shifts from autochthonous to allochthonous sources during runoff events. The urban water system (reservoir systems and wastewater-treatment plants) was found to affect temporal variability in DOC concentration and composition.The influence of urbanization, becoming increasingly common in arid regions, on dissolved organic carbon (DOC) concentrations in surface water resources was studied. DOC concentration and composition, seasonal watershed runoff events, streamflow variations, water management practices, and urban infrastructure in several Arizona watersheds were monitored. Ephemeral sites had the highest DOC levels, and unregulated perennial sites and lower concentrations than unregulated intermittent sites, regulated sites, and sites downstream from wastewater treatment plants. Reservoir outflows and wastewater treatment plant effluent had higher and less variable DOC concentrations than inflows to reservoirs. UV absorbance values, fluorescence measurements, and other indicators suggest that urban water systems (reservoirs and wastewater treatment plants) affect temporal variability in DOC concentration and composition.

Journal of Hydrology

A comparison of water-quality and stormwater inflow and outflow during habitat restoration at the McEwen storm drainage pond, South Valley, Albuquerque, New Mexico, 2020–22

In 2020, the U.S. Geological Survey began targeted monitoring, in partnership with Bernalillo County, at three locations within the McEwen storm drainage pond to evaluate and compare the water quality of stormwater as it enters and exits the study area, which is channelized and routes urban stormwater runoff through a wetland area. Stage in McEwen pond and precipitation at a nearby precipitation gage were evaluated to observe relations between rainfall and stage, as well as how long the stage remained elevated at the site. Peak stage ranged from 0.73 to 2.4 feet, with the time to reach peak stage at McEwen pond ranging from 45 minutes to 10 hours and 45 minutes. The stage remained elevated for a median of 3 days. Monitored water-quality parameters included physical parameters, bacteria, sediment, and nutrients. Bacteria was the only parameter that frequently exceeded the New Mexico Water Quality standard. Significant differences (p less than 0.05) among sites were few, consisting of those for total nitrogen and dissolved ammonia concentrations, which decreased toward the middle of the pond and were lower in the outflow from the pond compared to concentrations at the east and west sites. The middle of McEwen pond showed an increase in the percentage of fine-grained sediment, which suggests that larger particles settled into the pond and were further filtered as water traveled through the swales. Concentrations of suspended sediment and dissolved nutrients were significantly lower in 2022 compared to previous years. Although the site is still undergoing restoration and plants are becoming established, observations over the last several years indicate that site restoration has resulted in changes to the study area through processes such as nutrient uptake and the filtering of larger sediment particles.

New Mexico

Approaches for assessing long-term annual yields of highway and urban runoff in selected areas of California with the Stochastic Empirical Loading and Dilution Model (SELDM)

The California Department of Transportation, commonly known as CalTrans, and other municipal separate storm sewer system permittees in California as well as other State departments of transportation nationwide need information about potential loads and yields (loads per unit area) of constituents of concern in stormwater runoff and discharges from stormwater best management practices (BMPs). Although its National Pollution Discharge Elimination System stormwater permit is focused on areas subject to total maximum daily load (TMDL) regulations, CalTrans builds and maintains BMPs to minimize the adverse effects of roadway runoff on receiving waters throughout the State. This report describes approaches used by the U.S. Geological Survey in cooperation with CalTrans for using the Stochastic Empirical Loading and Dilution Model (SELDM) to assess long-term annual yields of highway and urban runoff in selected areas of California. In this study, a series of regional and local yields were simulated to provide statewide planning-level estimates and more refined TMDL-specific yield values. SELDM was used to analyze 368 State roadway and urban runoff yields for 53 runoff quality constituents. The analyses included 222 random-seed analyses, 60 regional State roadway-runoff analyses, 24 regional urban roadway-runoff analyses, and 62 focused TMDL-area analyses. This report describes approaches and statistics used to analyze available hydrologic and runoff quality data in all analyses. Results for all analyses are provided in the model archive, but only a selected subset of results are presented as examples in this report. State roadway runoff, urban runoff, and BMP discharge yields for total suspended solids, total nitrogen, total phosphorus, and total zinc were selected as examples because they are widespread constituents of concern with substantial amounts of State roadway and urban runoff monitoring data. In this report, a hypothetical basin was specified by using available geographic information to demonstrate use of the State roadway and urban runoff yields to estimate long-term annual stormwater loads from developed areas. Application of these yields to the hypothetical basin indicates that although State-roadway yields may be higher than urban-runoff yields for some constituents, State-roadway loads may be a small proportion of total stormwater loads because State roadways themselves are a small fraction of the total impervious area in such basins. Although application of results from this study may have considerable uncertainty for any particular stormwater outfall, the study does provide robust estimates to support basin-scale runoff-load analyses in California. These analyses also provide estimates for the 12 U.S. Environmental Protection Agency level III ecoregions that are completely or partially within the boundaries of the State of California.

California

Effects of combined-sewer overflows and urban runoff on the water quality of Fall Creek, Indianapolis, Indiana

In 1986, the U.S. Geological Survey and the Indianapolis Department of Public Works began a study to evaluate the effects of combined-sewer overflows and urban runoff discharging to Fall Geek on the White River. This report describes the effects of combined-sewer overflows and urban runoff on the water quality of Fall Creek during summer 1987 by comparing the water quality during base flow with that during storm runoff and by comparing water quality in the urbanized area with that in the less urbanized area upstream from the combined-sewer overflows. Data were collected at three streamflow-gaging stations located upstream from, downstream from, and in the middle of 27 combined-sewer overflows on Fall Creek. The most downstream station also was immediately downstream from the discharge of filter backwash from a water-treatment plant for public supply. Specific conductance and concentrations of major ions and dissolved solids in base flow increased downstream in response to surface-water withdrawn for public supply, ground-water inflow, and the discharge of filter backwash. Concentrations of dissolved oxygen were least in the reach of Fall Creek in the middle of the combined- sewer overflows where black sludge deposits covered the stream bottom. Concentrations of nitrate plus nitrite and ammonia steadily increased downstream, whereas concentrations of organic nitrogen, phosphorus, and orthophosphate only increased at the most downstream station. Nearly all concentrations of chromium, copper, lead, nickel, and zinc at the upstream and middle stations were less than the detection limit of 10 micrograms per liter. Detectable concentrations of these metals and high concentrations of suspended solids in base-flow samples at the most downstream station were caused by the discharges from the water-treatment plant. Concentrations of dissolved oxygen measured at the station in the middle of the combined-sewer overflows were less than the Indiana minimum ambient water-quality standard of 4.0 milligrams per liter during all storms. Concentrations of ammonia, oxygen demand, copper, lead, zinc, and fecal coliform bacteria at the stations downstream from the combined-sewer overflows were much higher in storm runoff than in base flow. Increased concentrations of oxygen demand in runoff probably were caused by combined-sewer overflows, urban runoff, and the resuspension of organic material deposited on the streambed. Some of the increased concentrations of lead, zinc, and probably copper can be attributed to the discharge and resuspension of filter backwash

Indiana

A simplified approach for monitoring hydrophobic organic contaminants associated with suspended sediment: Methodology and applications

Hydrophobic organic contaminants, although frequently detected in bed sediment and in aquatic biota, are rarely detected in whole-water samples, complicating determination of their occurrence, load, and source. A better approach for the investigation of hydrophobic organic contaminants is the direct analysis of sediment in suspension, but procedures for doing so are expensive and cumbersome. We describe a simple, inexpensive methodology for the dewatering of sediment and present the results of two case studies. Isolation of a sufficient mass of sediment for analyses of organochlorine compounds and PAHs is obtained by in-line filtration of large volumes of water. The sediment is removed from the filters and analyzed directly by standard laboratory methods. In the first case study, suspended-sediment sampling was used to determine occurrence, loads, and yields of contaminants in urban runoff affecting biota in Town Lake, Austin, TX. The second case study used suspended-sediment sampling to locate a point source of PCBs in the Donna Canal in south Texas, where fish are contaminated with PCBs. The case studies demonstrate that suspended-sediment sampling can be an effective tool for determining the occurrence, load, and source of hydrophobic organic contaminants in transport.

Archives of Environmental Contamination and Toxico

Effects of urbanization on the chemical, physical, and biological characteristics of small Blackland Prairie streams in and near the Dallas-Fort Worth metropolitan area, Texas

In 2001, the U.S. Geological Survey National Water Quality Assessment Program began a series of studies in the contiguous United States to examine the effects of urbanization on the chemical, physical, and biological characteristics of streams. Small streams in the Texas Blackland Prairie level III ecoregion in and near the Dallas-Fort Worth metropolitan area were the focus of one of the studies. The principal objectives of the study, based on data collected in 2003-04 from 28 subbasins of the Trinity River Basin, were to (1) define a gradient of urbanization for small Blackland Prairie streams in the Trinity River Basin on the basis of a range of urban intensity indexes (UIIs) calculated using land-use/land-cover, infrastructure, and socioeconomic characteristics; (2) assess the relation between this gradient of urbanization and the chemical, physical, and biological characteristics of these streams; and (3) evaluate the type of relation (that is, linear or nonlinear, and whether there was a threshold response) of the chemical, physical, and biological characteristics of these streams to the gradient of urbanization. Of 94 water-chemistry variables and one measure of potential toxicity from a bioassay, the concentrations of two pesticides (diazinon and sima-zine) and one measure of potential toxicity (P450RGS assay) from compounds sequestered in semipermeable membrane devices were significantly positively correlated with the UII. No threshold responses to the UII for diazinon and simazine concentrations were observed over the entire range of the UII scores. The linear correlation for diazinon with the UII was significant, but the linear correlation for simazine with the UII was not. No statistically significant relations between the UII and concentrations of suspended sediment, total nitrogen, total phosphorous, or any major ions were indicated. Eleven of 59 physical variables from streamflow were significantly correlated with the UII. Temperature was not significantly correlated with the UII, and none of the physical habitat measurements were significantly correlated with the UII. Seven physical variables categorized as streamflow flashiness metrics were significantly positively correlated with the UII, two of which showed a linear but not a threshold response to the UII. Four flow-duration metrics were significantly negatively correlated with the UII, of which two showed a linear response to the UII, one showed a threshold response, and one showed neither. None of the fish metrics were significantly correlated with the UII in the Blackland Prairie streams. Two qualitative multi-habitat benthic macroinvertebrate metrics, predator richness and percentage filterer-collector richness, were significantly correlated with the UII; predator richness was negatively correlated with the UII, and percentage filterer-collector richness was positively correlated with the UII. No threshold response to the UII was observed for either metric, but both showed a significant linear response to the UII. Three richest targeted habitat (RTH) benthic macroinvertebrate metrics, Margalef's richness, predator richness, and omnivore richness were significantly negatively correlated with the UII. Margalef's richness was the only RTH metric that indicated a threshold response to the UII. The majority of unique taxa collected in the periphytic algae samples were diatoms. Six RTH periphytic algae metrics were correlated with the UII and five of the six showed no notable threshold response to the UII; but all five showed significant linear responses to the UII. Only the metric OT_VL_DP, which indicates the presence of algae that are tolerant of low dissolved oxygen conditions, showed a threshold response to the UII. Six depositional target habitat periphytic algae metrics were correlated with the UII, five of which showed no threshold response to the UII; three of the five showed significant linear responses to the UII, one showed a borderline significant

Texas

Adjusting annual maximum peak discharges at selected stations in northeastern Illinois for changes in land-use conditions

The effects of urbanization on annual maximum peak discharges in northeastern Illinois and nearby areas from 1945 to 2009 were analyzed with a two-step longitudinal-quantile linear regression approach. The peak discharges were then adjusted to 2010 land-use conditions. The explanatory variables used were daily precipitation at the time of the peak discharge event and a housing density-based measure of developed land use. The effect of the implementation of stormwater detention was assessed indirectly. Peak discharge records affected by the construction of large reservoirs that affect channel routing were identified and were split into segments at the time of completion of the reservoir. Longitudinal regressions of the peak discharge records on linear and logarithmic transformations of the selected measures of urbanization and precipitation were tested, and the best fitting model was selected for quantile regression and adjustment of the peak discharges. Because the uncertainties of streamgage-by-streamgage regressions of peak discharges as a function of urbanization are so large, a regional urbanization response was computed. Streamgages used in this study fit the following two criteria: (1) drainage area is at most 200 square miles and, (2) at least 10 consecutive years of peak discharge record are available. In the first step of the regression analysis, linear longitudinal regression models with fixed intercepts estimated for each segment of the peak discharge records were computed. The segment intercepts were then subtracted from the discharge records to homogenize the discharge dataset across the segments in preparation for the quantile regression analysis. From the quantile regression analysis, the effect of urbanization on peak discharge varies strongly with the exceedance probability of the peak discharge event; coefficients monotonically increase from 0.340 to 0.969 over exceedance probabilities from 0.002 to 0.99. The regression analyses yield estimates of the population-wide effect of the explanatory variables on the dependent variables as a function of exceedance probability. These estimates are similar to the coefficients of the regional regression relations in USGS regional flood-frequency studies such as those implemented in the Web application StreamStats; although in the longitudinal analysis used in this study, it is the temporal not the spatial (between-streamgage) variations that are taken into account. The observed and adjusted values for each streamgage are tabulated. To illustrate the overall effect of the adjustments, differences in the mean, standard deviation, and skewness of the log-transformed observed and urbanization-adjusted peak discharge series by streamgage are computed. For almost every streamgage where an adjustment was applied (no increase in urbanization was reported for a few streamgages), the mean increased and the standard deviation decreased; the effect on skewness values was more variable but usually they increased. Significant positive peak discharge trends were common in the observed values, occurring at 27.3 percent of streamgages at a p -value of 0.05 according to a Kendall&rsquo;s tau correlation test; in the adjusted values, the incidence of such trends was reduced to 7.0 percent.

Illinois

Historic and forecasted population and land-cover change in eastern North Carolina, 1992-2030

The Southeast Regional Partnership for Planning and Sustainability (SERPPAS) was formed in 2005 as a partnership between the Department of Defense (DOD) and State and Federal agencies to promote better collaboration in making resource-use decisions. In support of this goal, the U.S. Geological Survey (USGS) conducted a study to evaluate historic population growth and land-cover change, and to model future change, for the 13-county SERPPAS study area in southeastern North Carolina (fig. 1). Improved understanding of trends in land-cover change and the ability to forecast land-cover change that is consistent with these trends will be a key component of efforts to accommodate local military-mission imperatives while also promoting sustainable economic growth throughout the 13-county study area. The study had three principal objectives: 1. Evaluate historic changes in population and land cover for the period 1992&ndash;2006 using both previously existing as well as newly generated land-cover data. 2. Develop models to forecast future change in land cover using the data gathered in objective 1 in conjunction with ancillary data on the suitability of the various sub-areas within the study area for low- and high-intensity urban development. 3. Deliver these results&mdash;including an executive-level briefing and a USGS technical report&mdash;to DOD, other project cooperators, and local counties in hard-copy and digital formats and via the Web through a map-based data viewer. This report provides a general overview of the study and is intended for general distribution to non-technical audiences.

North Carolina

River chloride trends in snow-affected urban watersheds: increasing concentrations outpace urban growth rate and are common among all seasons

Chloride concentrations in northern U.S. included in this study have increased substantially over time with average concentrations approximately doubling from 1990 to 2011, outpacing the rate of urbanization in the northern U.S. Historical data were examined for 30 monitoring sites on 19 streams that had chloride concentration and flow records of 18 to 49 years. Chloride concentrations in most studied streams increased in all seasons (13 of 19 in all seasons; 16 of 19 during winter); maximum concentrations occurred during winter. Increasing concentrations during non-deicing periods suggest that chloride was stored in hydrologic reservoirs, such as the shallow groundwater system, during the winter and slowly released in baseflow throughout the year. Streamflow dependency was also observed with chloride concentrations increasing as streamflow decreased, a result of dilution during rainfall- and snowmelt-induced high-flow periods. The influence of chloride on aquatic life increased with time; 29% of sites studied exceeded the concentration for the USEPA chronic water quality criteria of 230 mg/L by an average of more than 100 individual days per year during 2006&ndash;2011. The rapid rate of chloride concentration increase in these streams is likely due to a combination of possible increased road salt application rates, increased baseline concentrations, and greater snowfall in the Midwestern U.S. during the latter portion of the study period.

Science of the Total Environment

Abundance of microplastics in a typical urban wetland in China: Association with occurrence and carbon storage

Microplastics (MPs) are gaining attention for their widespread presence and toxicity in ecosystems. However, their role as a carbon source in urban wetland carbon sinks is still unclear. In this study, the microplastic-carbon (MP-C) was firstly quantified based on the abundance and occurrence characteristics, including MP morphology, size and type in the Sanyang Wetland, a typical urban wetland of China. MP abundances ranged from 2.4 ± 0.6–14.9 ± 1.5 items/L in surface water and 6.6 ± 1.2 × 10 3 to 46.3 ± 5.9 × 10 3 items/kg in sediment. The predominant morphological characterization of MPs was fragments smaller than 200 μm in size, consisting of PP, PE, and PET, which suggests that the main source was domestic wastewater discharge nearby. Notably, in the Sanyang wetland, the contribution of MP-C to total organic carbon (TOC) was estimated to be 0.023 0.20 % in water and 0.026 0.28 % in sediment. With the continuous production of plastics globally, these values were predicted to increase to 0.12 0.71 % and 0.83 4.12 % by 2100, respectively. Although the estimations relied on simplified geometric assumptions for MP volume and theoretical carbon content, these approaches provide a reasonable basis for understanding MP-C dynamics in wetlands under current analytical constraints. The integration of MP-C characterization during environmental monitoring and management strategies would enhance our understanding of MP pollution's role in the carbon cycle.

Journal of Hazardous Materials

Flood damage costs beyond buildings—A Lake Champlain case study

Introduction Floods account for more than 75 percent of Federal disaster declarations and lead other natural disasters in economic costs. Early-warning systems have lowered flood-related fatalities, but costs continue to rise as flood-prone areas continue to be urbanized (U.S. Geological Survey, 2006). A Lake Champlain case study shows that at moderate flood heights, the economic costs of non-structural damages or losses—such as temporary lodging, residential debris removal, commercial revenue losses, and road repair—can be greater than economic damages to buildings. For unprecedented flood heights, non-structural damages can still total more than 10 percent of structural damage costs.

New York, Vermont

Stormwater quality of infrastructure elements in Rapid City, South Dakota, 2016–18

As runoff flows over the land or impervious surfaces (paved streets, parking lots, and building roofs), it accumulates debris, chemicals, sediment, and other contaminants that can adversely affect water quality if the runoff discharge remains untreated. Pathogens, commonly measured using fecal indicator bacteria such as Escherichia coli , enterococci, or fecal coliform, are the most-frequent cause of water-quality impairment in rivers and streams in the United States. Rapid Creek originates in the western Black Hills area and flows east through Rapid City, South Dakota, to its mouth at the Cheyenne River. The water quality of Rapid Creek is important because the reach that flows through Rapid City is a valuable spawning area for a self-sustaining trout fishery, is actively used for recreation, and is a seasonal municipal water supply for the City of Rapid City. These uses (fishery, recreation, and water supply) are considered beneficial uses by the South Dakota Department of Environment and Natural Resources. Numerical criteria have been established for total suspended solids and Escherichia coli concentrations, among other water-quality constituents, for these beneficial uses. The objectives of this study were to improve the method by which fecal indicator bacteria and total suspended solids are quantified in the urban drainages within Rapid City and to provide information that helps identify origins of fecal indicator bacteria and total suspended solids. This information can be used in hydrologic models to estimate fecal indicator bacteria and total suspended solid loading from certain infrastructure elements in urban environments. Stormwater samples analyzed for Escherichia coli , total suspended solids, specific conductance, and pH were collected in three drainage basin flowpaths within Rapid City: Jackson, Wildwood, and the Eco Prayer Park. Data-collection activities for this study focused on upgradient urban flowpath elements during rainfall events. This approach builds upon previous stormwater assessments that characterized the water quality in urban basin outlets near the downstream end of the stormwater flowpaths. Within each flowpath group, 4–6 sites were selected to represent the various infrastructure elements of the runoff process. These elements included roof downspouts, parking lots, street curbs and gutters, open channels, underground storm sewers, and stormwater ponds or best-management practice facilities. In general, the concentrations of Escherichia coli and total suspended solids increased in the downstream direction for all flowpath sites. The wash-off process after the first flush is evident for total suspended solids and specific conductance; however, Escherichia coli concentrations did not necessarily follow the same pattern. Escherichia coli concentrations in the latter part of the runoff period were similar to or greater than the initial concentrations of the first set of samples. Stormwater-quality data were summarized by infrastructure type (roof downspout, parking lot, street curb, and channel/storm sewer) to provide information about approximate water-quality concentrations originating at the upper end of urban flowpaths. Escherichia coli and total suspended solid concentrations were lowest in samples collected from locations most isolated from human influence (roof downspouts); the median concentrations at these sites were 4 most probable number per 100 milliliters and 15 milligrams per liter, respectively. The delivery potential of fecal indicator bacteria and sediment from parking lots and street curbs was similar; median concentrations of Escherichia coli and total suspended solids were around 150–220 most probable number per 100 milliliters and 56–86 milligrams per liter, respectively. The downstream receiving channels and storm sewers where stormwater was aggregated typically contained the highest Escherichia coli concentrations (median was 1,800 most probable number per 100 milliliters), but the total suspended solid concentrations were similar to upstream elements in the flowpath (median was 69 milligrams per liter). The data collected from this study demonstrate that stormwater is contaminated with fecal indicator bacteria upon initial contact with impervious surfaces and highlight the importance of controlling the volume of stormwater discharges into receiving waterbodies via storage structures and pervious elements. Diluting stormwater with high concentrations of Escherichia coli with the receiving water’s (Rapid Creek) lower concentration of Escherichia coli is likely the primary mechanism for meeting the beneficial-use criterion threshold of 235 most probable number per 100 milliliters. Although total suspended solid concentrations in the upper parts of the basin (parking lots and street curbs) also begin at concentrations (56 to 86 milligrams per liter) above the beneficial-use criterion for Rapid Creek (53 milligrams per liter), current stormwater-control practices (storage ponds, swales, and wetlands) may be able to reduce suspended-sediment concentrations to meet this threshold.

South Dakota

Air pollution and respiratory hospital admissions in Shiraz, Iran, 2009 to 2015

Air pollution has been identified as one of the most challenging health issues in urban areas worldwide. The aim of this study was to investigate the association between short-term exposure to ambient air pollution and respiratory disease over a long-term period in Shiraz, one of the largest cities in Iran. Methods: hospital admissions due to respiratory diseases (asthma, pneumonia, chronic obstructive pulmonary disease(COPD) and pleural effusion) in residents of Shiraz between March 21, 2009 and March 20, 2015 were included. Demographics for each patient and meta data to include principal meteorological variables (temperature and relative humidity) and five ambient pollutants (CO, O 3 , SO 2 , NO 2 , and PM 10 ) were also included. Statistical analysis was performed by Poisson regression in single-pollutant generalized linear model with principal component analysis (GLPCA) to analyze the relationship between pollutants and hospital admissions at the 0–9 cumulative lag day period. Pearson correlation test was used to determine the relationship between different pollutants, temperature and humidity. Results It was found that the highest increase in asthma admission was related to PM 10 (relative risk (RR) = 1.31, 95% CI = 1.17, 1.47). For COPD, the rate of hospital visits significantly increased with the increase in NO 2 concentration (RR = 1.17, 95% CI = 1.09.1.27). In the children's hospital, O 3 (RR = 1.25, 95% CI = 1.06, 1.47) and SO 2 (RR = 1.17, 95% CI = 1.07, 1.28) affected the asthma admissions and all contaminants (highest RR observed was for NO 2 (RR = 1.28 95% CI = 1.18, 1.40) affected pneumonia admissions on cumulative lag days of 0–9. Conclusions: These data confirm an association between ambient air pollutants and hospital admissions due to respiratory disease.

Shiraz