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At least 433 records · Page 24Linked to original sources

DDT and related compounds in pore water of shallow sediments on the Palos Verdes Shelf, California, USA

For nearly two and a half decades following World War II, production wastes from the world's largest manufacturer of technical DDT (1-chloro-4-[2,2,2-trichloro-1-(4-chlorophenyl)ethyl]benzene) were discharged into sewers of Los Angeles County. Following treatment, the wastes were released via a submarine outfall system to nearshore coastal waters where a portion accumulated in shallow sediments of the Palos Verdes Shelf (PVS). An investigation of the pore-water geochemistry of DDT-related compounds (DDX) was undertaken in an effort to understand factors controlling the rate of reductive dechlorination (RDC) of the major DDT degradate, 4,4′-DDE (1-chloro-4-[2,2-dichloro-1-(4-chlorophenyl)ethenyl]benzene). Equilibrium matrix-solid phase microextraction (matrix-SPMEeq) combined with automated thermal desorption-gas chromatography/mass spectrometry (TDGC/MS) was used to determine freely dissolved concentrations of ten DDX analytes in sediment cores collected from three locations on the PVS (stations 3C, 6C, 8C, which are 7 km, 2 km, and 0 km, respectively, downcurrent from the outfall system). Pore-water concentrations (pM) of the principal DDX compounds involved in RDC were: 3C-DDE: 6.0–24, DDMU (1-chloro-4-[2-chloro-1-(4-chlorophenyl)ethenyl]benzene): 11–160, DDNU (1-chloro-4-[1-(4-chlorophenyl)ethenyl]benzene): 1.8–68; 6C-DDE: 5.6–170, DDMU: 5.6–177, DDNU: 1.7–87; 8CDDE: 27–212, DDMU: 31–403, DDNU: 5.5–89. Variations in the spatial distribution of DDX analytes in pore water reflect several factors including proximity to the outfalls, RDC reaction rates, and natural variability in sedimentation and post-depositional transport processes. A comparison of pore-water data produced using matrix-SPME eq /TD-GC/MS and whole-core squeezing/solvent extraction/liquid injection-GC/MS indicates that the majority of the DDE in the upper sediment column (≤about 10 cm) is associated with dissolved/colloidal organic matter. Below that depth, freely-dissolved DDE predominates. The principal organic geochemical phase controlling sorption of DDE in PVS sediments are residual hydrocarbons, the vast majority of which originated from petroleum refinery wastes. Organic carbon-normalized sediment-water distribution coefficients (KOC) were calculated from solid-phase and pore-water concentrations of DDX and organic carbon. Log K OC values (L/kg) were relatively invariant across the shelf and with depth in the sediment column. Shelf-wide compound-specific coefficients (log K OC ) were: DDE: 7.5 ± 0.11, DDMU: 6.92 ± 0.13, DDNU: 6.37 ± 0.19. The spatial uniformity of K OC means that biological exposure and availability of the DDX compounds can, in principle, be estimated from solid-phase chemical measurements.

California↗

A three-dimensional mapping of the ocean based on environmental data

The existence, sources, distribution, circulation, and physicochemical nature of macroscale oceanic water bodies have long been a focus of oceanographic inquiry. Building on that work, this paper describes an objectively derived and globally comprehensive set of 37 distinct volumetric region units, called ecological marine units (EMUs). They are constructed on a regularly spaced ocean point-mesh grid, from sea surface to seafloor, and attributed with data from the 2013 World Ocean Atlas version 2. The point attribute data are the means of the decadal averages from a 57-year climatology of six physical and chemical environment parameters (temperature, salinity, dissolved oxygen, nitrate, phosphate, and silicate). The database includes over 52 million points that depict the global ocean in x, y, and z dimensions. The point data were statistically clustered to define the 37 EMUs, which represent physically and chemically distinct water volumes based on spatial variation in the six marine environmental characteristics used. The aspatial clustering to produce the 37 EMUs did not include point location or depth as a determinant, yet strong geographic and vertical separation was observed. Twenty-two of the 37 EMUs are globally or regionally extensive, and account for 99% of the ocean volume, while the remaining 15 are smaller and shallower, and occur around coastal features. We assessed the vertical distribution of EMUs in the water column and placed them into classical depth zones representing epipelagic (0 m to 200 m), mesopelagic (200 m to 1,000 m), bathypelagic (1,000 m to 4,000 m) and abyssopelagic (>4,000 m) layers. The mapping and characterization of the EMUs represent a new spatial framework for organizing and understanding the physical, chemical, and ultimately biological properties and processes of oceanic water bodies. The EMUs are an initial objective partitioning of the ocean using long-term historical average data, and could be extended in the future by adding new classification variables and by introducing functionality to develop time-specific EMU distribution maps. The EMUs are an open-access resource, and as both a standardized geographic framework and a baseline physicochemical characterization of the oceanic environment, they are intended to be useful for disturbance assessments, ecosystem accounting exercises, conservation priority setting, and marine protected area network design, along with other research and management applications.

Oceanography↗

Oceanography of Glacier Bay, Alaska: Implications for biological patterns in a glacial fjord estuary

Alaska, U.S.A, is one of the few remaining locations in the world that has fjords that contain temperate idewater glaciers. Studying such estuarine systems provides vital information on how deglaciation affects oceanographic onditions of fjords and surrounding coastal waters. The oceanographic system of Glacier Bay, Alaska, is of particular interest ue to the rapid deglaciation of the Bay and the resulting changes in the estuarine environment, the relatively high oncentrations of marine mammals, seabirds, fishes, and invertebrates, and the Bay’s status as a national park, where ommercial fisheries are being phased out. We describe the first comprehensive broad-scale analysis of physical and iological oceanographic conditions within Glacier Bay based on CTD measurements at 24 stations from 1993 to 2002. easonal patterns of near-surface salinity, temperature, stratification, turbidity, and euphotic depth suggest that freshwater nput was highest in summer, emphasizing the critical role of glacier and snowmelt to this system. Strong and persistent tratification of surface waters driven by freshwater input occurred from spring through fall. After accounting for seasonal nd spatial variation, several of the external physical factors (i.e., air temperature, precipitation, day length) explained a large mount of variation in the physical properties of the surface waters. Spatial patterns of phytoplankton biomass varied hroughout the year and were related to stratification levels, euphotic depth, and day length. We observed hydrographic atterns indicative of strong competing forces influencing water column stability within Glacier Bay: high levels of freshwater ischarge promoted stratification in the upper fjord, while strong tidal currents over the Bay’s shallow entrance sill enhanced ertical mixing. Where these two processes met in the central deep basins there were optimal conditions of intermediate tratification, higher light levels, and potential nutrient renewal. These conditions were associated with high and sustained hlorophyll a levels observed from spring through fall in these zones of the Bay and provide a framework for understanding he abundance patterns of higher trophic levels within this estuarine system.

Estuaries and Coasts↗

Interpreting the spatio-temporal patterns of sea turtle strandings: Going with the flow

Knowledge of the spatial and temporal distribution of specific mortality sources is crucial for management of species that are vulnerable to human interactions. Beachcast carcasses represent an unknown fraction of at-sea mortalities. While a variety of physical (e.g., water temperature) and biological (e.g., decomposition) factors as well as the distribution of animals and their mortality sources likely affect the probability of carcass stranding, physical oceanography plays a major role in where and when carcasses strand. Here, we evaluate the influence of nearshore physical oceanographic and wind regimes on sea turtle strandings to decipher seasonal trends and make qualitative predictions about stranding patterns along oceanfront beaches. We use results from oceanic drift-bottle experiments to check our predictions and provide an upper limit on stranding proportions. We compare predicted current regimes from a 3D physical oceanographic model to spatial and temporal locations of both sea turtle carcass strandings and drift bottle landfalls. Drift bottle return rates suggest an upper limit for the proportion of sea turtle carcasses that strand (about 20%). In the South Atlantic Bight, seasonal development of along-shelf flow coincides with increased numbers of strandings of both turtles and drift bottles in late spring and early summer. The model also predicts net offshore flow of surface waters during winter - the season with the fewest relative strandings. The drift bottle data provide a reasonable upper bound on how likely carcasses are to reach land from points offshore and bound the general timeframe for stranding post-mortem (< two weeks). Our findings suggest that marine turtle strandings follow a seasonal regime predictable from physical oceanography and mimicked by drift bottle experiments. Managers can use these findings to reevaluate incidental strandings limits and fishery takes for both nearshore and offshore mortality sources. ?? 2005 Elsevier Ltd. All rights reserved.

Biological Conservation↗

Regionalizing indicators for marine ecosystems: Bering Sea–Aleutian Island seabirds, climate, and competitors

Seabirds are thought to be reliable, real-time indicators of forage fish availability and the climatic and biotic factors affecting pelagic food webs in marine ecosystems. In this study, we tested the hypothesis that temporal trends and interannual variability in seabird indicators reflect simultaneously occurring bottom-up (climatic) and competitor (pink salmon) forcing of food webs. To test this hypothesis, we derived multivariate seabird indicators for the Bering Sea–Aleutian Island (BSAI) ecosystem and related them to physical and biological conditions known to affect pelagic food webs in the ecosystem. We examined covariance in the breeding biology of congeneric pelagic gulls (kittiwakes Rissa tridactyla and R. brevirostris) andauks (murres Uria aalge and U. lomvia), all of whichare abundant and well-studiedinthe BSAI. At the large ecosystem scale, kittiwake and murre breeding success and phenology (hatch dates) covaried among congeners, so data could be combined using multivariate techniques, but patterns of responsedifferedsubstantially betweenthe genera.Whiledata fromall sites (n = 5)inthe ecosystemcould be combined, the south eastern Bering Sea shelf colonies (St. George, St. Paul, and Cape Peirce) provided the strongest loadings on indicators, and hence had the strongest influence on modes of variability. The kittiwake breeding success mode of variability, dominated by biennial variation, was significantly related to both climatic factors and potential competitor interactions. The murre indicator mode was interannual and only weakly related to the climatic factors measured. The kittiwake phenology indicator mode of variability showed multi-year periods (“stanzas”) of late or early breeding, while the murre phenology indicator showed a trend towards earlier timing. Ocean climate relationships with the kittiwake breeding success indicator suggestthat early-season (winter–spring) environmental conditions and the abundance of pink salmon affect the pelagic food webs that support these seabirds in the BSAI ecosystem.

Alaska↗

Spatial variation and low diversity in the major histocompatibility complex in walrus ( Odobenus rosmarus )

Increased global temperature and associated changes to Arctic habitats will likely result in the northward advance of species, including an influx of pathogens novel to the Arctic. How species respond to these immunological challenges will depend in part on the adaptive potential of their immune response system. We compared levels of genetic diversity at a gene associated with adaptive immune response [Class II major histocompatibility complex (MHC), DQB exon 2] between populations of walrus ( Odobenus rosmarus ), a sea ice-dependent Arctic species. Walrus was represented by only five MHC DQB alleles, with frequency differences observed between Pacific and Atlantic populations. MHC DQB alleles appear to be under balancing selection, and most (80 %; n = 4/5) of the alleles were observed in walruses from both oceans, suggesting broad scale differences in the frequency of exposure and diversity of pathogens may be influencing levels of heterozygosity at DQB in walruses. Limited genetic diversity at MHC, however, suggests that walrus may have a reduced capacity to respond to novel immunological challenges associated with shifts in ecological communities and environmental stressors predicted for changing climates. This is particularly pertinent for walrus, since reductions in summer sea ice may facilitate both northward expansion of marine species and associated pathogens from more temperate regions, and exchange of marine mammals and associated pathogens through the recently opened Northwest Passage between the Atlantic and Pacific Oceans in the Canadian high Arctic.

Polar Biology↗

Carbonate-hosted microbial communities are prolific and pervasive methane oxidizers at geologically diverse marine methane seep sites

At marine methane seeps, vast quantities of methane move through the shallow subseafloor, where it is largely consumed by microbial communities. This process plays an important role in global methane dynamics, but we have yet to identify all of the methane sinks in the deep sea. Here, we conducted a continental-scale survey of seven geologically diverse seafloor seeps and found that carbonate rocks from all sites host methane-oxidizing microbial communities with substantial methanotrophic potential. In laboratory-based mesocosm incubations, chimney-like carbonates from the newly described Point Dume seep off the coast of Southern California exhibited the highest rates of anaerobic methane oxidation measured to date. After a thorough analysis of physicochemical, electrical, and biological factors, we attribute this substantial metabolic activity largely to higher cell density, mineral composition, kinetic parameters including an elevated V max , and the presence of specific microbial lineages. Our data also suggest that other features, such as electrical conductance, rock particle size, and microbial community alpha diversity, may influence a sample’s methanotrophic potential, but these factors did not demonstrate clear patterns with respect to methane oxidation rates. Based on the apparent pervasiveness within seep carbonates of microbial communities capable of performing anaerobic oxidation of methane, as well as the frequent occurrence of carbonates at seeps, we suggest that rock-hosted methanotrophy may be an important contributor to marine methane consumption.

Proceedings of the National Academy of Sciences (P↗

Agency approach to allocation of human capital and program composition for human-marine mammal interaction management in the United States

Introduction: Marine mammals have served important and diverse roles throughout human history. Once exploited to near extinction, many species in the United States (U.S.) have recovered dramatically under the Marine Mammal Protection Act (MMPA). The U.S. National Marine Fisheries Service (NMFS) has jurisdiction to administer the MMPA for cetaceans and most pinnipeds. While most take is now prohibited, NMFS still dedicates significant time and resources to protecting and conserving marine mammals. As human populations continue to grow and exploit marine environments, opportunities for human-marine mammal interactions (HMMI) have increased. Resources may fail to keep up with growing needs for conservation investments, so that many agencies struggle to adequately meet social and legal requirements. Methods: This study evaluated NMFS’ approach to addressing HMMI through a mixed-methods (semi-structured interviews, quantitative questionnaire, and facilitated workshops) expert elicitation analysis of resource allocation (i.e., staff time) and priorities of NMFS Science Center (SC) and Regional Office (RO) staff across five geographic regions to understand how employee time is allocated, the degree to which employee time allocation is aligned with self-reported job descriptions, and employee perceptions of actions or investments which would improve their ability to mitigate HMMI. Results and Discussion: SC staff reported spending more time on Biological and Administrative tasks , while RO staff allocated more time to Policy, Social science , and Outreach tasks . SC employees spent less time on Biological tasks than specified by their perceived job descriptions, suggesting resource constraints. Participants identified Biological research and monitoring as top priorities, followed by Policy tasks . Identified actions included increasing research capacity, enhancing enforcement, expanding social science expertise, and improving outreach programs. The study reveals mismatches between mandated activities and available resources, suggesting strategic reallocation or increased funding may benefit the agency in effectively addressing growing HMMI challenges.

Frontiers in Marine Science↗

Multiple-factor influences upon feeding flight rates at wading bird colonies (Alias: Are flight-line counts useful?)

The temporal patterns of feeding, resting, and reproductive behavior in colonial wading birds have been studied by a number of investigators (Recher and Recher 1972, King 1974, Capen 1978, Custer and Osborn 1978, Kushlan 1978) both on a short-term (daily) and long-term (annual) basis. In coastal marine environments, activities at colonies are influenced by tides (Recher and Recher 1972, Krebs 1974, Custer and Osborn 1978), time of day (Kushlan 1978) and phase of the nesting cycle (Kahl 1964). The purpose of this paper is twofold: (1) to examine the effects of tide, time of day (physical factors), nesting phase, colony site, and spe cies identity (biological factors) on feeding flight rates at breeding col onies and, as a result of this, (2) to evaluate the usefulness of feeding flight counts as an index of the number of nests in the colony. Earlier work suggests that the relationship between the number of in dividuals flying to and from the nesting colony may be quite consistent with nest numbers. Thus, by monitoring flights from remote locations, ob servers might obtain relatively accurate census data while minimizing time and disturbance at colonies. Recent concern for the deleterious impact of humans at waterbird colonies (Buckley and Buckley 1976, Ellison and Cleary 1978) underscores the need to investigate alternative census methods.

Conference Paper↗

Contaminants in the Gulf of Maine-What's here and should we worry?

The Gulf of Maine is a dynamic environment that has highly variable bottom type and localized depositional and transport processes. It is used and impacted by the people around it who hope to use the marine system for many purposes such as fishing, recreation, housing, sewage and dumped disposal, shipping, recreation, and preservation. In order to identify "pollution", which is defined as detrimental effects in the ecosystem that are attributable to human activity, the spatial and temporal distribution of contaminants in Gulf of Maine sediments are established using data that have been compiled into a Contaminated-Sediment Database for the Gulf of Maine. The potential for high contaminant levels in the sediments to induce toxic effects in the Gulf ecosystem is then assessed. In the Gulf of Maine, we have large urban centers that adversely affect the marine ecosystem well offshore through a variety of human activities. We are also in the fortunate position of still having many relatively pristine marine areas. It is unlikely that we will reach an endpoint of "zero toxic effects" in the ecosystem; however, much of the information needed to move closer to the shared goal of managing a sustainable ecosystem in the Gulf of Maine is currently available. Future success will rely on continued efforts to 1) identify rate-limiting physical and biological processes, 2) provide appropriate data synthesis and 3) involve the public.

Maine, Massachusetts, New Hampshire↗

Mapping the seabed and habitats in National Marine Sanctuaries - Examples from the East, Gulf and West Coasts

The National Marine Sanctuary System requires seabed and habitat maps to serve as a basis for managing sanctuary resources and for conducting research. NOAA, the agency that manages the sanctuaries, and the USGS have conducted mapping projects in three sanctuaries (Stellwagen Bank NMS, Flower Garden Banks NMS, and Channel Islands NMS) with an emphasis on collaboration of geologists and biologists from the two agencies and from academic institutions. Mapping of seabed habitats is a developing field that requires the integration of geologic and biologic studies and the use of swath imaging techniques such as multibeam and sidescan sonar. Major products of swath mapping are shaded-relief topographic imagery which shows seabed features in great detail, and backscatter imagery which provides an indication of the types of materials that constitute the seabed. Sea floor images provide an excellent basis for conducting the groundtruthing studies (using video, photo, and sampling techniques) that are required to collect the data necessary for making meaningful interpretative maps of the seabed. The compilation of interpretive maps showing seabed environments and habitats also requires the development of a sea floor classification system that will be a basis for comparing, managing, and researching characteristic areas of the seabed. Seabed maps of the sanctuaries are proving useful for management and research decisions that address commercial and recreational fishing, habitat disturbance, engineering projects, tourism, and cultural resources.

Marine Technology Society Journal↗

Physiological characteristics of wild Atlantic salmon post-smolts during estuarine and coastal migration

Changes were measured in some of the major physiological variables associated with seawater adaptability, growth and energetics in wild Atlantic salmon Salmo salar smolts and post-smolts migrating from the river and through the estuary, fjord and coastal areas in the River Orkla and the Trondheimsfjord, Norway during late May to early June. Gill Na+,K+-ATPase activity increased to levels of 12-16 ??mol ADP mg protein-1 h -1 in post-smolts caught in higher salinity zones, probably representing long-term levels of Atlantic salmon post-smolts in oceanic conditions. Muscle moisture was regulated within narrow limits (77.7-78.7%) in fish from all zones during both years, suggesting that post-smolts adapt to marine conditions without any long-term disturbance of hydro-mineral balance. Lipid and glycogen content showed a general trend towards depletion from the river, through the fjord and into the ocean. There was, however, no significant change in protein content. The present results confirm that smolts are naturally 'energy deficient' during downstream migration, and suggest that post-smolts also mobilize energy reserves during their early marine phase, while protein is allocated for somatic growth. Plasma growth hormone (GH) levels increased transiently during passage through the estuary and fjord, with lower levels observed in post-smolts caught off-shore, i.e. in fish which were feeding on marine prey and had adapted to the marine environment. These physiological changes may confer substantial selective advantages during the critical early marine phase of anadromous salmonids, and hence are adaptive for long-term survival in sea water. ?? 2003 The Fisheries Society of the British Isles.

Journal of Fish Biology↗

Complementary approaches to diagnosing marine diseases: a union of the modern and the classic

Linking marine epizootics to a specific aetiology is notoriously difficult. Recent diagnostic successes show that marine disease diagnosis requires both modern, cutting-edge technology (e.g. metagenomics, quantitative real-time PCR) and more classic methods (e.g. transect surveys, histopathology and cell culture). Here, we discuss how this combination of traditional and modern approaches is necessary for rapid and accurate identification of marine diseases, and emphasize how sole reliance on any one technology or technique may lead disease investigations astray. We present diagnostic approaches at different scales, from the macro (environment, community, population and organismal scales) to the micro (tissue, organ, cell and genomic scales). We use disease case studies from a broad range of taxa to illustrate diagnostic successes from combining traditional and modern diagnostic methods. Finally, we recognize the need for increased capacity of centralized databases, networks, data repositories and contingency plans for diagnosis and management of marine disease.

Philosophical Transactions of the Royal Society B:↗

Recommendations for a barrier island breach management plan for Fire Island National Seashore, including the Otis Pike High Dune Wilderness Area, Long Island, New York

The U.S Army Corps of Engineers, New York District is developing engineering plans, including economic costs and benefits, for storm damage reduction along an 83 mile stretch of the coastal barrier islands and beaches on the south shore of Long Island, NY from Fire Island Inlet east to the Montauk Point headland. The plan, expected to include various alternatives for storm protection and erosion mitigation, is referred to as the Fire Island to Montauk Point Reformulation Plan (FIMP). These plans are expected to follow the Corps of Engineers’ Environmental Operating Principles striving for long term environmental sustainability and balance between environmental protection and protection of human health and property. Fire Island National Seashore (FIIS), a 19,579 acre unit of the National Park System includes a 32 mile long coastal barrier island located within the FIMP project area. A seven-mile section of the park, Otis Pike Fire Island High Dune Wilderness Area, is also a designated Federal Wilderness Area. The FIIS includes not only the barrier island and sand dunes, but also several islands, sand flats and wetlands landward of the barrier, submerged parts of Great South Bay shoreface, extending approximately 4,000 feet into the bay with the inner shelf region extending approximately 1,000 feet seaward of the Fire Island shoreline. The Fire Island barrier islands, a sand-starved system dominated by highly dynamic processes, are struggling to maintain their integrity in the face of sea-level rise and storms. Adding to the dilemma is that development on the barriers and the mainland has increased greatly during the past 50 years. As such, managers and decision makers in federal agencies, state agencies and local governments are challenged to balance tradeoffs between protection of lives and property, public access and long term conservation of natural habitats and processes and the plants and animals that depend on these habitats. National Park Service (NPS) policy stipulates that natural coastal processes be maintained to the greatest extent possible and not be impeded so as to conserve landforms, habitats and natural ecosystem resources that reply on the landforms and processes for long-term sustainability of the national park. Storms and associated processes such as waves, tides, currents and relative sea-level change are critical elements for the formation and evolution of these barrier islands, sand dunes, back-barrier sand flats and lagoons and vegetated wetlands. Processes such as wave run-up, overwash and barrier beaching, which occur during elevated storm surge are all necessary processes in enabling the efficient transfer of sediments, nutrients and marine water from the Atlantic Ocean across barriers and into Great South Bay. A large body of scientific data and information published over the past 50 years shows that such transfers of sediment and water from the ocean to the bays are essential for the long-term maintenance of the barrier island and back-bay systems and their biologically diverse habitats an d ecosystems. Current relative sea-level rise (~12 in/century) is chronic and pervasive in driving Long Island coastal change and with the likelihood of accelerating sea level rise in the near future, coastal hazards such as erosion, inundation, and storm surge flooding will increase, with corresponding increased risk to life and property on both Fire Island and on the mainland. In addition, the cumulative effects over the past century and more, both direct and indirect, of human impacts on the Long Island coast have altered the barrier beach and dunes and sediment transport processes. These impacts have likely increased the potential for breaching and increased risk to life and property on the coast and the mainland. Examples of direct impacts are: the stone jetties at Moriches, Shinnecock, and Fire Island tidal inlets and groin field structures at Westhampton that alter littoral processes, armoring and erosion-control stabilization of the headlandds such as the Montauk Point headlands, and deepening of navigation channels by dredging through the tidal inlets and in the bays. Indirect impacts that have a bearing on decisions to deal with breaching are: high-risk development of the barrier islands and low-lying areas of the mainland vulnerable to flooding, and the dredging of nearshore sand shoals for beach nourishment. The NPS strives to employ a coastal management framework for decision making that is based on assessment of the physical and ecological properties of the shoreline as well as human welfare and property. In order to protect developed areas of Fire Island and the mainland from loss of life, flooding, and other economic and physical damage, the NPS will likely need to consider allowing artificial closure of some breaches within the FIIS under certain circumstances. The decision by the NPS to allow breaches to evolve naturally and possibly close or to allow artificially closing breaches is based on four criteria: 1. Volumes of sediment transported landward and exchange of water and nutrients; 2. Elevated water levels and flooding risk to mainland life and property; 3. Engineering processes of artificial closure; and 4. Economic costs and benefits of artificial closure. This report for breach management presents protocols which specify when breach closures within the FIIS might be desirable and necessary, as well as provides recommendations for structural breach closure engineering operations which are indented to minimize negative impacts to the natural wilderness values and cultural resources within the FIIS, particularly the Otis Pike Wilderness Area. The goal of the plan is to strike a balance between protecting natural resources and allowing natural processes to operate and avoiding loss of life and excessive property damage.

New York↗

Biological, Physical, And Chemical Data From Gulf of Mexico Core PE0305-GC1

This paper presents benthic foraminiferal census data, and magnetic susceptibility, 210Pb , radiocarbon, and geochemical measurements from gravity core PE0305-GC1 (=GC1). Core GC1 was collected from the Louisiana continental shelf as part of an initiative to investigate the geographic and temporal extent of hypoxia, low-oxygen water, in the Gulf of Mexico. Hypoxia (<1.4 ml/l or <2 ppm oxygen concentration) in Gulf of Mexico waters can eventually lead to death of marine species. The development of hypoxia off the Mississippi delta has increased steadily since routine and systematic measurements were begun in 1985 and has been linked to the use of fertilizer in the Mississippi basin. Benthic foraminifers provide a proxy to track the development of hypoxia prior to 1985. Previous work determined that the relative occurrence of three low-oxygen-tolerant species is highest in the hypoxia zone. The cumulative percentage of these three species (% Pseudononion atlanticum + % Epistominella vitrea, + % Buliminella morgani = PEB index of hypoxia) was used to investigate fluctuation in paleohypoxia in four cores, including the upper 60 cm of GC1. In this report, we compile all available data from GC1 as the basis for further publications.

Open-File Report↗

Predicting spatial and temporal distribution of Indo-Pacific lionfish ( Pterois volitans ) in Biscayne Bay through habitat suitability modeling

Invasive species may exhibit higher levels of growth and reproduction when environmental conditions are most suitable, and thus their effects on native fauna may be intensified. Understanding potential impacts of these species, especially in the nascent stages of a biological invasion, requires critical information concerning spatial and temporal distributions of habitat suitability. Using empirically supported environmental variables (e.g., temperature, salinity, dissolved oxygen, rugosity, and benthic substrate), our models predicted habitat suitability for the invasive lionfish ( Pterois volitans ) in Biscayne Bay, Florida. The use of Geographic Information Systems (GIS) as a platform for the modeling process allowed us to quantify correlations between temporal (seasonal) fluctuations in the above variables and the spatial distribution of five discrete habitat quality classes, whose ranges are supported by statistical deviations from the apparent best conditions described in prior studies. Analysis of the resulting models revealed little fluctuation in spatial extent of the five habitat classes on a monthly basis. Class 5, which represented the area with environmental variables closest to the best conditions for lionfish, occupied approximately one-third of Biscayne Bay, with subsequent habitats declining in area. A key finding from this study was that habitat suitability increased eastward from the coastline, where higher quality habitats were adjacent to the Atlantic Ocean and displayed marine levels of ambient water quality. Corroboration of the models with sightings from the USGS-NAS database appeared to support our findings by nesting 79 % of values within habitat class 5; however, field testing (i.e., lionfish surveys) is necessary to confirm the relationship between habitat classes and lionfish distribution.

Florida↗

Behaviour of calcium carbonate in sea water

Anomalies in the behaviour of calcium carbonate in natural solutions diminish when considered in context. Best values found by traditional oceanographie methods for the apparent solubility product constant K ' CaCO 3 in sea water at atmospheric pressure are consistent mineralogically—at 36 parts per thousand salinity and T-25°C, K ' aragonlte is estimated as 1.12 × 10 −6 and K ' calcite as 0.61 × 10 −6 . At 30°C the corresponding values are 0.98 × 10 −6 for aragonite and 0.53 × 10 −6 for calcite. Because the K ' computations do not compensate for ionic activity, however, they cannot give thermodynamically satisfactory results. It is of interest, therefore, that approximate methods and information now available permit the estimation from the same basic data of an activity product constant K CaCO 3 close to that found in solutions to which Debye-Hückel theory applies. Such methods indicate approximate K aragonite 7.8 × 10 −9 for surface sea water at 29°C; K calcite would be proportionately lower. Field data and experimental results indicate that the mineralogy of precipitated CaCO 3 depends primarily on degree of supersaturation, thus also on kinetic or biologic factors that facilitate or inhibit a high degree of supersaturation. The shallow, generally hypersaline bank waters west of Andros Island yield aragonitic sediments with O 18 O 16 "> O18O16 ratios that imply precipitation mainly during the warmer months, when the combination of a high rate of evaporation, increasing salinity (and ionic strength), maximal temperatures and photosynthetic removal of CO 2 result in high apparent supersaturation. The usual precipitate from solutions of low ionic strength is calcite, except where the aragonite level of supersaturation is reached as a result of diffusion phenomena ( e.g. dripstones), gradual and marked evaporation, or biologic intervention. Published data also suggest the possibility of distinct chemical milieus for crystallographic variations in skeletal calcium carbonate. It appears that in nature aragonite precipitates from solutions that are supersaturated with respect to both calcite and aragonite and calcite between saturation levels for the two species. Such a relation is consistent with Ostwald's rule of successive reactions. Aragonitc of marine origin persists in contact with supersaturated interstitial solutions at ordinary temperature and pressure. Conversion to calcite follows transfer to solutions undersaturated with respect to aragonite or upon exposure to the moist atmosphere.

Geochimica et Cosmochimica Acta↗

California State Waters Map Series — Offshore of Fort Ross, California

Introduction In 2007, the California Ocean Protection Council initiated the California Seafloor Mapping Program (CSMP), designed to create a comprehensive seafloor map of high-resolution bathymetry, marine benthic habitats, and geology within the 3-nautical-mile limit of California&rsquo;s State Waters. The CSMP approach is to create highly detailed seafloor maps through collection, integration, interpretation, and visualization of swath sonar data, acoustic backscatter, seafloor video, seafloor photography, high-resolution seismic-reflection profiles, and bottom-sediment sampling data. The map products display seafloor morphology and character, identify potential marine benthic habitats, and illustrate both the surficial seafloor geology and shallow subsurface geology. The Offshore of Fort Ross map area is located in northern California, on the Pacific coast of Sonoma County, about 90 km north of San Francisco and 60 km south of Point Arena. The onshore part of the map area is largely undeveloped, used primarily for grazing and recreation; the small town of Jenner (population, 136), located at the mouth of the Russian River, is the largest cultural center. The coast and shoreline are rugged and scenic, characterized by rocky promontories, kelp-rich coves, and nearshore rocks and sea stacks. U.S. Highway 1 extends along the coast through the map area, crossing the Russian River and passing through Sonoma Coast State Park and Fort Ross State Historic Park. The Offshore of Fort Ross map area is cut by the northwest-striking San Andreas Fault, the right-lateral transform boundary between the North American and Pacific plates. The fault intersects the shoreline a few kilometers south of Fort Ross at Timber Gulch, and it juxtaposes Jurassic, Cretaceous, Paleocene, and Eocene rocks of the Franciscan Complex to the northeast and Tertiary sedimentary rocks to the southwest. In this area, the San Andreas Fault has an estimated slip rate of 17 to 24 mm/yr. The devastating great 1906 California earthquake (M7.8) is thought to have nucleated on the San Andreas Fault offshore of San Francisco, about 90 km to the south, with the rupture extending northward through the Offshore of Fort Ross map area to the south flank of Cape Mendocino. Approximately 3.6 m of lateral offset occurred at Timber Gulch during this event. The San Andreas Fault has an important influence on coastal geomorphology. The coastline in the northern part of the map area, southwest of the onshore San Andreas Fault, is characterized by steep shoreline bluffs and as many as four uplifted, relatively flat marine terraces that range in elevation from about 15 to 100 m. Northeast of the San Andreas Fault, about 12 km of coastline is marked by steep, landslide-prone cliffs that commonly are 200 to 300 m high. The mouth of the Russian River and its estuary cut through the steep coastal topography in the southern part of the Offshore of Fort Ross map area. The Russian River drains a large watershed (3,470 km 2 ), and it has an annual discharge of about 2 km 3 (1,600,000 acre-feet) and an annual sediment load of about 900,000 metric tons. The map area is part of the Russian River littoral cell, in which the predominant longshore drift is to the south. Small pocket beaches are most common along the shoreline, but longer linear beaches are present near the mouth of the Russian River. The seafloor in the north half of the map area is characterized by rocky outcrops of Tertiary sedimentary rocks. The rugged nearshore zone and the inner shelf area (to water depths of about 50 m) typically slopes gently seaward, whereas the smooth midshelf area within California&rsquo;s State Waters (about 50 to 85 m deep) is relatively flat. In contrast, the nearshore to midshelf area in the south half of the map area, which lies directly offshore of the mouth of the Russian River, has a more uniform, relatively flat slope. Shallow-marine and shelf sediments were deposited in the last about 21,000 years during the sea-level rise that followed the Last Glacial Maximum (LGM). Sea level was about 125 m lower than present during the LGM, at which time the entire Offshore of Fort Ross map area was emergent and the shoreline was about 20 km west of its present location. Circulation over the continental shelf in the map area (and in the broader northern California region) is dominated by the southward-flowing California Current, the eastern limb of the North Pacific Gyre. Associated upwelling brings cool, nutrient-rich waters to the surface, resulting in high biological productivity. The current flow generally is southeastward during the spring and summer; however, during the fall and winter, the otherwise persistent northwest winds are sometimes weak or absent, causing the California Current to move farther offshore and the Davidson Current, a weaker, northward-flowing countercurrent, to become active. Throughout the year, this part of the northern California coast is exposed to four wave climate regimes: the north Pacific swell, the southern swell, northwest wind waves, and local wind waves. The north Pacific swell dominates in winter months (typically November through March). During summer months, the largest waves come from the southern swell, generated by storms in the south Pacific and offshore of Central America. Northwest wind waves affect the coast throughout the year, whereas local wind waves are most common from October to April. Potential marine benthic habitat types in the Offshore of Fort Ross map area include unconsolidated continental-shelf sediments, mixed continental-shelf substrate, and hard continental-shelf substrate. Rocky shelf outcrops and rubble are considered the primary habitat type for rockfish and lingcod, both of which are recreationally and commercially important species.

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