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USGS2011

Field Reconnaissance Geologic Mapping of the Columbia Hills, Mars: Results from MER Spirit and MRO HiRISE Observations

Chemical, mineralogic, and lithologic ground truth was acquired for the first time on Mars in terrain units mapped using orbital Mars Reconnaissance Orbiter's High Resolution Imaging Science Experiment (MRO HiRISE) image data. Examination of several dozen outcrops shows that Mars is geologically complex at meter length scales, the record of its geologic history is well exposed, stratigraphic units may be identified and correlated across significant areas on the ground, and outcrops and geologic relationships between materials may be analyzed with techniques commonly employed in terrestrial field geology. Despite their burial during the course of Martian geologic time by widespread epiclastic materials, mobile fines, and fall deposits, the selective exhumation of deep and well-preserved geologic units has exposed undisturbed outcrops, stratigraphic sections, and structural information much as they are preserved and exposed on Earth. A rich geologic record awaits skilled future field investigators on Mars. The correlation of ground observations and orbital images enables construction of a corresponding geologic reconnaissance map. Most of the outcrops visited are interpreted to be pyroclastic, impactite, and epiclastic deposits overlying an unexposed substrate, probably related to a modified Gusev crater central peak. Fluids have altered chemistry and mineralogy of these protoliths in degrees that vary substantially within the same map unit. Examination of the rocks exposed above and below the major unconformity between the plains lavas and the Columbia Hills directly confirms the general conclusion from remote sensing in previous studies over past years that the early history of Mars was a time of more intense deposition and modification of the surface. Although the availability of fluids and the chemical and mineral activity declined from this early period, significant later volcanism and fluid convection enabled additional, if localized, chemical activity.

Journal of Geophysical Research E: Planets↗

USGS2012

Northern East Pacific Rise: Magnetic anomaly and bathymetric framework

The oceanic crust in the eastern Pacific between 7°N and 30°N and east of 127°W contains a fairly complete history of the spreading centers associated with the East Pacific Rise since 25 m.y. B.P. (late Oligocene). In this paper, we have summarized the seafloor spreading magnetic-anomaly data and the bathymetric data that reflect the record of this tectonic history. The well-defined magnetic lineations north of the Clarion fracture zone, in the mouth of the Gulf of California, and on the east flank of the East Pacific Rise (EPR) are carefully examined and used to provide a guide for interpreting the spreading pattern between the Clarion and Clipperton fracture zones, southward of the Rivera fracture zone over the Mathematician Ridge, and over the entire EPR east of the Mathematician Ridge between the Rivera and Siqueiros fracture zones. The bathymetric data provide a trace of the fracture zone pattern in each of the above mentioned areas. The fracture zone bathymetry and the seafloor spreading magnetic lineations on the EPR south of the Rivera fracture zone have a distinctive fanning pattern caused by close poles of rotation and plate boundary reorganizations. All these data provide a good record of the plate reorganizations in the middle Miocene at magnetic anomaly 5 A time (12.5 to 11 m.y. B.P.), in the late Miocene at magnetic anomaly 3′−4 time (6.5 m.y. B.P.), and in the Pliocene at magnetic anomaly 2′−3 time (3.5 m.y. B.P.). Several abandoned spreading centers, including the Mathematician Ridge, were left behind as a result of these reorganizations. The Mathematician Ridge is shown to be a set of ridges and trough whose origin is related to the tectonic activity associated with each of the above mentioned reorganizations since anomaly 5A.

Journal of Geophysical Research B: Solid Earth↗

USGS1997

Acidic deposition, cation mobilization, and biochemical indicators of stress in healthy red spruce

Dendrochemical and biochemical markers link stress in apparently healthy red spruce trees ( Picea rubens ) to acidic deposition. Acidic deposition to spruce forests of the northeastern USA increased sharply during the 1960s. Previous reports related visible damage of trees at high elevations to root and soil processes. In this report, dendrochemical and foliar biochemical markers indicate perturbations in biological processes in healthy red spruce trees across the northeastern USA. Previous research on the dendrochemistry of red spruce stemwood indicated that under uniform environmental conditions, stemwood concentrations of Ca and Mg decreased with increasing radial distance from the pith. For nine forest locations, frequency analysis shows that 28 and 52% of samples of red spruce stemwood formed in the 1960s are enriched in Ca and Mg, respectively, relative to wood formed prior to and after the 1960s. This enrichment in trees throughout the northeastern USA may be interpretable as a signal of increased availability of essential cations in forest soils. Such a temporary increase in the availability of Ca and Mg could be caused by cation mobilization, a consequence of increased acidic deposition. During cation mobilization, essential Ca and Mg as well as potentially harmful Al become more available for interaction with binding sites in the soil and absorbing roots. As conditions which favor cation mobilization continue, Ca and Mg can be leached or displaced from the soil. A measure of the interaction between Ca and Al is the Al/Ca binding ratio (molar charge ratio of exchangeable Al to exchangeable Ca). As the Al/Ca binding ratio in the root zone increased from 0.3 to 1.9, the foliar concentration of the biochemical stress marker putrescine also increased from 45 to 145 nm g −1 . The correlation of the putrescine concentration to the Al/Ca binding ratio (adj. r 2 = 0.68, P < 0.027) suggests that foliar stress may be linked to soil chemistry.

Journal of Environmental Quality↗

USGS2022

Characterization of bituminite in Kimmeridge Clay by confocal laser scanning and atomic force microscopy

This work investigates bituminite (amorphous sedimentary organic matter) in Upper Jurassic Kimmeridge Clay source rock via confocal laser scanning microscopy (CLSM) and atomic force microscopy (AFM). These petrographic tools were used to provide better understanding of the nature of bituminite, which has been historically difficult to identify and differentiate from similar organic matter types in source rocks. As part of an International Committee for Coal and Organic Petrology (ICCP) working group, an immature (0.42% vitrinite reflectance), organic-rich (44.1 wt% total organic carbon content) sample of Kimmeridge Clay was distributed to multiple laboratories for CLSM characterization. The primary observations from CLSM imaging and spectroscopy include: 1) the interpreted presence of Botryococcus algae as a contributor to bituminite precursors; 2) color red-shift of sulfide reflectance and bituminite auto-fluorescence from below the sample surface; 3) positive alteration of bituminite from laser-induced photo-oxidation of the sample surface, including fluorescence blue-shift; 4) fluorescence blue-shift associated to higher fluorescence intensity regions in bituminite indicative of compositional (fluorophore) differences; 5) the need for fluorescence spectroscopy standardization as applied via CLSM; and 6) the suitability of CLSM fluorescence spectroscopy to predict solid bitumen reflectance from bituminite spectral emission via calibration to an extant dataset. Secondary CLSM observations include detection of reflected laser light from highly reflective inclusions in bituminite, including sulfides and fusinite, and radiolytic alteration of bituminite caused by substitution of U for Fe in sulfides. Findings from AFM include the observation that surface roughening or surface flattening of bituminite are induced by differential broad ion beam (BIB) milling and are dependent on the location and scale of AFM topology measurement. This result highlights our still limited understanding of the effects of BIB milling on sedimentary organic matter and indicates the need for further research before this technique can be advanced as a standard practice in petrographic sample preparation. Collectively, the results of this study illustrate the general applicability and versatility of AFM and CLSM as tools for organic petrology research, specifically for better understanding of the nature and properties of the bituminite maceral.

Kimmeridge↗

USGS2011

Evidence for mechanical and chemical alteration of iron-nickel meteorites on Mars: Process insights for Meridiani Planum

The weathering of meteorites found on Mars involves chemical and physical processes that can provide clues to climate conditions at the location of their discovery. Beginning on sol 1961, the Opportunity rover encountered three large iron meteorites within a few hundred meters of each other. In order of discovery, these rocks have been assigned the unofficial names Block Island, Shelter Island, and Mackinac Island. Each rock presents a unique but complimentary set of features that increase our understanding of weathering processes at Meridiani Planum. Significant morphologic characteristics interpretable as weathering features include (1) a large pit in Block Island, lined with delicate iron protrusions suggestive of inclusion removal by corrosive interaction; (2) differentially eroded kamacite and taenite lamellae in Block Island and Shelter Island, providing relative timing through crosscutting relationships with deposition of (3) an iron oxide-rich dark coating; (4) regmaglypted surfaces testifying to regions of minimal surface modification, with other regions in the same meteorites exhibiting (5) large-scale, cavernous weathering (in Shelter Island and Mackinac Island). We conclude that the current size of the rocks is approximate to their original postfall contours. Their morphology thus likely results from a combination of atmospheric interaction and postfall weathering effects. Among our specific findings is evidence supporting (1) at least one possible episode of aqueous acidic exposure for Block Island; (2) ripple migration over portions of the meteorites; (3) a minimum of two separate episodes of wind abrasion; alternating with (4) at least one episode of coating-forming chemical alteration, most likely at subzero temperatures.

Journal of Geophysical Research E: Planets↗

USGS2023

Pre-eruptive outgassing and pressurization, and post-fragmentation bubble nucleation, recorded by vesicles in breadcrust bombs from vulcanian activity at Guagua Pichincha Volcano, Ecuador

Breadcrust bombs formed during Vulcanian eruptions are assumed to originate from the shallow plug or dome. Their rim to core texture reflects the competition between cooling and degassing timescales, which results in a dense crust with isolated vesicles contrasting with a highly vesicular vesicle network in the interior. Due to relatively fast quenching, the crust can shed light on pre- and syn-eruptive conditions prior to or during fragmentation, whereas the interior allows us to explore post-fragmentation vesiculation. Investigation of pre- to post-fragmentation processes in breadcrust bombs from the 1999 Vulcanian activity at Guagua Pichincha, Ecuador, via 2D and 3D textural analysis reveals a complex vesiculation history, with multiple, spatially localized nucleation and growth events. Large vesicles (Type 1), present in low number density in the crust, are interpreted as pre-eruptive bubbles formed by outgassing and collapse of a permeable bubble network during ascent or stalling in the plug. Haloes of small, syn-fragmentation vesicles (Type 2), distributed about large vesicles, are formed by pressurization and enrichment of volatiles in these haloes. The nature of the pressurization process in the plug is discussed in light of seismicity and ground deformation signals, and previous textural and chemical studies. A third population (Type 3) of post-fragmentation small vesicles appears in the interior of the bomb, and growth and coalescence of Type 2 and 3 vesicles causes the transition from isolated to interconnected bubble network in the interior. We model the evolution of viscosity, bubble growth rate, diffusion timescales, bubble radius and porosity during fragmentation and cooling. These models reveal that thermal quenching dominates in the crust whereas the interior undergoes a viscosity quench caused by degassing, and that the transition from crust to interior corresponds to the onset of percolation and development of permeability in the bubble network.

Guagua Pichincha Volcano↗

USGS2012

Evidence for a shallow pluton beneath the Goat Rocks Wilderness, Washington, from gravity and magnetic data

A gravity and aeromagnetic study was conducted in and adjacent to the Goat Rocks Wilderness area, Washington. This work was done in conjunction with geologic and geochemical studies which were critically important to our interpretation. The Bouguer gravity anomaly map displays a large central positive gravity anomaly and three superimposed smaller positive anomalies. The main anomaly, about 26 by 11 km with an amplitude of about 16 mGal seems to delineate a dense large pluton or sheeted dike complex intruding less dense, older volcanic and sedimentary rocks lying directly below the volcano. The pluton or sheeted dike complex may have fed the Goat Rocks volcano throughout its 1–2 m.y. history. Three small feeders, mapped on the surface as andesite intrusions, may be the cause of three smaller gravity anomalies superimposed on the main anomaly. The magnetic anomaly maps also exhibit a large central anomaly whose source is the Goat Rocks pluton. The magnetic data suggest that the three shallow intrusive cupolas have undergone a significant amount of hydrothermal alteration. In addition, to some extent the magnetic data reflect the terrain of the area. Topographic highs produce magnetic highs, and topographic lows produce magnetic lows. The deviations from this pattern delineate subsurface geology. Magnetic lows may be of particular interest in locating zones of mineralization where magnetic minerals have been altered and have become significantly less magnetic.

Washington↗

USGS2012

Tectonics and conductivity structures in the Southern Washington Cascades

The tectonic setting of the southern Washington Cascades has been studied with the aid of magnetotelluric (MT) and other geophysical data. The main feature of interest in the geophysical data is a broad high-conductivity anomaly mapped with MT and geomagnetic variation (GMV) data. This anomaly is located roughly within the triangle formed by the volcanoes Mount Rainier, Mount St. Helens, and Mount Adams but exceeds beyond Mount Rainier to the northwest. We interpret the cause of the anomaly to be conductive rocks with resistivities of 1–4 ohm m and thicknesses possibly greater than 15 km. These conductive rocks are found 2–8 km beneath the overlying less conductive volcanic and sedimentary rocks at the surface. Two aeromagnetic lows follow the trend of the conductivity anomaly, and linear belts of strike-slip seismicity are coincident with both these magnetic lows. One of the aeromagnetic lows is coincident with the western margin of the conductivity anomaly. The geophysical data appear to outline a suture zone of probable Eocene age caused by accretion of a large seamount complex (Siletzia) and that may contain large thicknesses of compressed forearc basin and accretionary prism sedimentary rocks of Cretaceous to Eocene age. Part of the shallower conductive rocks may be associated with carbonaceous continental and transitional marine sedimentary rocks of the Puget Group. The contact between the hypothesized compressed basin and the accreted terranes to the west may localize the release of shear stresses in this region of oblique subduction. Several possible explanations for the conductivity anomaly are considered in addition to the compressed basin hypothesis.

Washington↗

USGS2015

Density dependence, whitebark pine, and vital rates of grizzly bears

Understanding factors influencing changes in population trajectory is important for effective wildlife management, particularly for populations of conservation concern. Annual population growth of the grizzly bear ( Ursus arctos ) population in the Greater Yellowstone Ecosystem, USA has slowed from 4.2–7.6% during 1983–2001 to 0.3–2.2% during 2002–2011. Substantial changes in availability of a key food source and bear population density have occurred. Whitebark pine ( Pinus albicaulis ), the seeds of which are a valuable but variable fall food for grizzly bears, has experienced substantial mortality primarily due to a mountain pine beetle ( Dendroctonus ponderosae ) outbreak that started in the early 2000s. Positive growth rates of grizzly bears have resulted in populations reaching high densities in some areas and have contributed to continued range expansion. We tested research hypotheses to examine if changes in vital rates detected during the past decade were more associated with whitebark pine decline or, alternatively, increasing grizzly bear density. We focused our assessment on known-fate data to estimate survival of cubs-of-the-year (cubs), yearlings, and independent bears (≥2 yrs), and reproductive transition of females from having no offspring to having cubs. We used spatially and temporally explicit indices for grizzly bear density and whitebark pine mortality as individual covariates. Models indicated moderate support for an increase in survival of independent male bears over 1983–2012, whereas independent female survival did not change. Cub survival, yearling survival, and reproductive transition from no offspring to cubs all changed during the 30-year study period, with lower rates evident during the last 10–15 years. Cub survival and reproductive transition were negatively associated with an index of grizzly bear density, indicating greater declines where bear densities were higher. Our analyses did not support a similar relationship for the index of whitebark pine mortality. The results of our study support the interpretation that slowing of population growth during the last decade was associated more with increasing grizzly bear density than the decline in whitebark pine. Grizzly bear density and its potential effect on vital rates and population trajectory warrant consideration for management of the grizzly bear population in the Greater Yellowstone Ecosystem.

Idaho, Montana, Wyoming↗

USGS2007

Generation of fine hydromagmatic ash by growth and disintegration of glassy rinds

The deposits of mafic hydromagmatic eruptions are more fine grained and variable in vesicularity than dry magmatic deposits. Blocky, equant shapes of many hydromagmatic clasts also contrast with droplet, thread, and bubble wall morphology of dry magmatic fragments. Small (<∼180 μ m), blocky hydromagmatic pyroclasts have traditionally been interpreted to result from discrete vapor explosions, although such explosions tend to occur only under certain conditions. This paper considers a process of hydromagmatic ash formation that involves repeated growth and disintegration of glassy rinds on pyroclast surfaces as they deform within turbulent flows. This process, termed “turbulent shedding”, may occur during the expansion phase of vapor explosions or during turbulent but nonexplosive mixing of magma with water, steam, or water sprays. The occurrence of turbulent shedding and the resulting fragment sizes depend on the timescale for rind growth and the timescale between disturbances that remove or disintegrate glassy rinds. Turbulent shedding is directly observable in some small littoral jets at Kilauea. Calculations suggest that, in the presence of liquid water or water sprays, glassy rinds having a thickness of microns to millimeters should form in milliseconds to seconds. This is similar to the timescale between turbulent velocity fluctuations that can shred lava globules and remove such rinds. The fraction of a deposit consisting of fine ash should increase with the duration of this process: Large‐scale Surtseyan jets generate hundreds or thousands of shedding events; bubble bursts or tephra jets at Kilauea's coast may produce only a few.

Journal of Geophysical Research B: Solid Earth↗

USGS2007

Hydrothermal fluid flow and deformation in large calderas: Inferences from numerical simulations

[1] Inflation and deflation of large calderas is traditionally interpreted as being induced by volume change of a discrete source embedded in an elastic or viscoelastic half-space, though it has also been suggested that hydrothermal fluids may play a role. To test the latter hypothesis, we carry out numerical simulations of hydrothermal fluid flow and poroelastic deformation in calderas by coupling two numerical codes: (1) TOUGH2 [Pruess et al., 1999], which simulates flow in porous or fractured media, and (2) BIOT2 [Hsieh, 1996], which simulates fluid flow and deformation in a linearly elastic porous medium. In the simulations, high-temperature water (350°C) is injected at variable rates into a cylinder (radius 50 km, height 3–5 km). A sensitivity analysis indicates that small differences in the values of permeability and its anisotropy, the depth and rate of hydrothermal injection, and the values of the shear modulus may lead to significant variations in the magnitude, rate, and geometry of ground surface displacement, or uplift. Some of the simulated uplift rates are similar to observed uplift rates in large calderas, suggesting that the injection of aqueous fluids into the shallow crust may explain some of the deformation observed in calderas.

Journal of Geophysical Research B: Solid Earth↗

USGS2012

Crustal structure of the northwestern Basin and Range Province from the 1986 Program for Array Seismic Studies of the Continental Lithosphere Seismic Experiment

A portion of northwestern Nevada was imaged to determine the crustal structure and to assess reported differences between refraction versus reflection determinations of Moho depth and how the crustal composition and structure has been influenced by volcanic and extension mechanisms. Interpretation of the refraction/wide-angle reflection data suggests that the crust is fairly uniform in thickness and varies by less than 5 km over the 280 km east-west profile and 3 km over its 220 km north-south length. The velocity structure is characterized by five layers: 1) an uppermost crust, composed of sedimentary rocks and basement that has an average velocity of 5.7 km s-1; 2) a middle crust that extends to a depth of 18-22 with an average velocity of 6.1 km s-1; 3) a 10-12 km thick lower crust with an average velocity of 6.6 km s-1; 4) a 2-5 km thick transitional crust-mantle boundary defined by a 7.6 km s-1 velocity; and 5) an upper mantle with an average Pn velocity of 7.9-8.0 km s-1. A uniform upper mantle composition across the Basin and Range is suggested and the homogeneity of the velocity structure beneath the western Basin and Range argues for a youthful Moho and crust that has been reworked by province-wide late Cenozoic extension, episodic magmatism, and underplating. -from Authors

Journal of Geophysical Research↗

USGS2005

Petrologic constraints on the thermal structure of the Cascades arc

Primitive late Cenozoic basaltic lavas from the Cascades volcanic arc near latitude 46°N comprise two distinct compositional groups. Group I includes samples with low Ba/Nb (<20) and other compositional similarities to oceanic island and MORB lavas from within-plate settings. In contrast, Group II exhibits enrichment of Ba and large-ion lithophile elements (LILE) and depletion of Nb and high-field strength elements (HFSE) as seen commonly in calcalkalic lavas from other volcanic arcs. Lavas of both groups are widely distributed across the transect, and Group I lavas are found as much as 30–40 km trenchward of stratovolcanoes that define the High Cascades ‘volcanic front (VF)’. The most primitive lavas are sparsely porphyritic, have elevated Ni, Cr, and Mg#, high calculated magmatic temperatures (1200–1300 °C), and lack evidence of shallow (crustal level) storage and crystallization. Compositions of parental liquids were calculated for each primitive sample on the premise of Fe–Mg equilibrium with mantle peridotite. Assuming that such magmas ascended rapidly from accumulation zones in the mantle, we estimate P and T of segregation. We infer that (a) Group I magmas ascended from systematically greater depths (∼50–70 km) than Group II (∼30–50 km), implying the possible existence of compositional stratification in the mantle wedge; (b) Group I basalts show the least evidence for slab-derived contributions in their sources despite their apparently greater segregation depths (approaching the locus of the Cascadia slab beneath the frontal arc region); (c) Group II lavas with the strongest slab compositional signature have temperatures far exceeding the wet peridotite solidus at high pressure; and (d) the inferred thermal structure of the mantle wedge is very warm, implying a significant component of mantle upwelling and convection. Group I lavas are interpreted as decompression melts from this mantle, and their compositions suggest that their source was little modified by slab-derived contributions. We speculate that melting to produce Group II magmas occurs in the shallow mantle, possibly in response to heating by hot ascending Group I magmas. If true, it seems unlikely that the slab-like signal in Group II lavas can be attributed to modern slab inputs; rather, we postulate that this signature may reflect melting of lithospheric mantle domains containing a ‘stored’ slab-derived component inherited from earlier stages of Cascadia subduction. This scenario differs from the standard paradigm for subduction zones (SZs), and stresses the importance of convecting asthenospheric mantle in driving arc magmatism, particularly in warm subduction zones where slab fluid contributions likely are minimal. In contrast, because tectonic conditions in more typical volcanic arcs favor subduction of cooler, less dehydrated oceanic lithosphere, slab-derived fluids may promote extensive flux-melting in the wedge. Such melts may dominate the magmatic output and mask wedge contributions. The Cascade arc thus provides rarely afforded insights into arc magma genesis.

British Columbia, California, Oregon, Washington↗

USGS2012

Deformation in the White Mountain seismic gap, California-Nevada, 1972-1982

A 100×40 km trilateration network extending from Bishop, California, to near Hawthorne, Nevada, crosses the east end of the Long Valley caldera, site of renewed magma inflation in the 1979–1980 interval, and spans most of the White Mountain seismic gap. The network was surveyed in 1972, 1973, 1976, 1979, 1980, and 1982. The 1980 survey may be contaminated by a scale error. In addition, leveling surveys across the caldera have been run in 1932, 1957, 1975, 1980, 1982, and 1983. Interpretation of the deformation is complicated by the occurrence of the May 1980 Mammoth Lakes earthquake sequence (four earthquakes M L ≥6) at the south edge of the caldera as well as other moderate earthquakes within the White Mountain seismic gap. The vertical deformation is largely accounted for by 0.10‐ to 0.15‐km 3 expansion of a spherical magma chamber 8–10 km beneath the resurgent dome within the Long Valley caldera sometime between July 1979 and September 1980 with an additional expansion of perhaps 0.05 km 3 between September 1980 and July 1982. Some additional sources of deformation within the aftershock zone of the Mammoth Lakes earthquakes seem to be required to explain the horizontal deformation. We show that right‐lateral slip on vertical faults extending WNW from each of the three largest earthquakes in the Mammoth Lakes sequence provides the required additional deformation, but this solution is by no means unique. There are simply too few data to define the rather complex deformation that apparently occurred within the aftershock zone. There is little doubt, however, that inflation of a magma chamber beneath the resurgent dome within the Long Valley caldera was involved in the deformation.

California↗

USGS2013

Whole-coal versus ash basis in coal geochemistry: a mathematical approach to consistent interpretations

Several standard methods require coal to be ashed prior to geochemical analysis. Researchers, however, are commonly interested in the compositional nature of the whole-coal, not its ash. Coal geochemical data for any given sample can, therefore, be reported in the ash basis on which it is analyzed or the whole-coal basis to which the ash basis data are back calculated. Basic univariate (mean, variance, distribution, etc.) and bivariate (correlation coefficients, etc.) measures of the same suite of samples can be very different depending which reporting basis the researcher uses. These differences are not real, but an artifact resulting from the compositional nature of most geochemical data. The technical term for this artifact is subcompositional incoherence. Since compositional data are forced to a constant sum, such as 100% or 1,000,000 ppm, they possess curvilinear properties which make the Euclidean principles on which most statistical tests rely inappropriate, leading to erroneous results. Applying the isometric logratio (ilr) transformation to compositional data allows them to be represented in Euclidean space and evaluated using traditional tests without fear of producing mathematically inconsistent results. When applied to coal geochemical data, the issues related to differences between the two reporting bases are resolved as demonstrated in this paper using major oxide and trace metal data from the Pennsylvanian-age Pond Creek coal of eastern Kentucky, USA. Following ilr transformation, univariate statistics, such as mean and variance, still differ between the ash basis and whole-coal basis, but in predictable and calculated manners. Further, the stability between two different components, a bivariate measure, is identical, regardless of the reporting basis. The application of ilr transformations addresses both the erroneous results of Euclidean-based measurements on compositional data as well as the inconsistencies observed on coal geochemical data reported on different bases.

International Journal of Coal Geology↗

USGS2012

The high-pressure electronic structure of magnesiowustite (Mg, Fe)O: applications to the physics and chemistry of the lower mantle

The electronic structure of magnesiowustite is investigated using self-consistent field X α scattered wave (SCF- X α-SW) molecular orbital calculations on (FeO 6 ) 10− and (FeMg 12 O 14 ) 2− clusters. Calculated one-electron transition energies are used to interpret the optical spectrum of (Mg, Fe)O. The results are applied to the electrical and thermal conductivity of the lower mantle. The spin pairing of Fe 2+ and the effect of pressure on bonding in magnesiowustite, with some inferences regarding the incorporation of oxygen in the outer core, is also addressed. The approach used here appears to give a reliable description of the energy and pressure dependence of the spin-allowed 5 T 2 g → 5 E g ligand field transition and the spin-pairing transition of Fe 2+ in (Mg, Fe)O. However, the oxygen to metal charge transfer transitions in (Mg, Fe)O are not as reliably determined insofar as the p - d band gap varies with cluster size and the energies of the charge transfer states cannot be found without including configurational interaction. Nevertheless, it is argued that the charge transfer transitions that are intrinsic to (Fe, Mg)O are of a sufficiently high energy to be irrelevant to the electrical and thermal conductivity of the lower mantle. This is especially true if Fe 2+ adopts the low-spin configuration. The geophysically significant properties of (Fe, Mg)O probably result from defect Fe 3+ .

Journal of Geophysical Research↗

USGS2012

The geology and distribution of impact craters on Venus: What are they telling us?

Magellan has revealed an ensemble of impact craters on Venus that is unique in many important ways. We have compiled a data base describing the 842 craters on 89% of Venus' surface mapped through orbit 2578. (The craters range in diameter from 1.5 to 280 km.) We have studied the distribution, size‐density, morphology, geology, and associated surface properties of these craters both in the aggregate and, for some craters, in greater detail. We find that (1) the spatial distribution of craters is highly uniform; (2) the size‐density distribution of large craters (diameters ≥35 km) is similar to the young crater populations on other terrestrial planets but at a much lower density that indicates an average age of only about 0.5 Ga (based on the estimated population of Venus‐crossing asteroids); (3) unlike the case on other planets, the density of small craters (diameters ≤35 km) declines rapidly with decreasing diameters because of atmospheric filtering; (4) the spectrum of crater modification differs greatly from that on other planets: 62% of all craters are pristine, only 4% are embayed by lavas, and the remainder are affected by tectonism, but none are severely and progressively depleted (as extrapolated from the size‐density distribution of larger craters); (5) large craters have a progression of morphologies generally similar to those on other planets, but small craters are typically irregular or multiple rather than bowl shaped; (6) diffuse radar‐bright or ‐dark features surround some craters, and 367 similar diffuse “splotches” with no central crater are observed; and (7) other crater features unique to Venus include radar‐bright or ‐dark parabolic arcs opening westward and extensive outflows originating in crater ejecta. The first three of these observations are entirely unexpected. We interpret them as indicating that the planet's cratering record was erased by a global resurfacing event or events, the latest ending about 0.5 Ga, after which volcanic activity declined (but did not cease entirely). Since the last resurfacing event, a maximum of 10% of the planet has been resurfaced and only about 4% of the craters have been obliterated. Convective thermal evolution models support this interpretation (Arkani‐Hamed and Toksoz, 1984). Observations 3–7 confirm quantitatively the expectation that the dense atmosphere of Venus has strongly affected the production of craters. Large impactors have been relatively unaffected, intermediate‐sized ones have been fragmented and have produced overlapping or multiple craters, a narrow size range has produced shock‐induced “splotches” but no craters, and the smallest bodies have had no observable effect on the surface. The number of craters eliminated by the “atmospheric filter” is enormous, about 98% of the craters between 2 and 35 km in diameter that Magellan might have observed on a hypothetical airless Venus. Unique crater‐related features such as parabolas and outflow deposits demonstrate the roles of Venus' high atmospheric density and temperature in modifying the crater formation process. Finally, heavily fractured craters and lava‐embayed craters are found to have higher than average densities along the major fracture belts and rifted uplands connecting Aphrodite Terra and Atla, Beta, Themis, and Phoebe regiones. These craters thus provide physical evidence for recent volcanic and tectonic activity at a low level.

Journal of Geophysical Research E: Planets↗

USGS2021

Post-wildfire hydrologic recovery in Mediterranean climates: A systematic review and case study to identify current knowledge and opportunities

Post-fire hydrologic research typically focuses on the first few years after a wildfire , leading to substantial uncertainty regarding the longevity of impacts. The time needed for hydrologic function to return to pre-fire conditions is critical information for post-fire land and water management decisions. This is particularly true in Mediterranean climates , where water is scarce and in high demand, and the severity and area burned by wildfires are increasing. In part, uncertainty about hydrologic recovery is due to lack of a consistent definition or interpretation of what constitutes “recovery.” Here, we systematically reviewed empirical studies from Mediterranean climates with at least three years of post-fire hydrologic data with the objectives of (a) assessing the recovery period, (b) identifying a definition of post-fire hydrologic recovery, (c) demonstrating a simple analytical approach to aid in assessment of recovery, and (d) outlining research needs and opportunities to better quantify post-fire recovery. We assessed the hydrologic effects reported in 38 sites that were monitored for 3–20 years. Eighteen sites were considered recovered within seven years; however, the recovery time was inconsistent across sites and was not related to location, response variable, or study design. The likelihood of recovery within the study period also decreased with increasing proportion of the watershed area burned. Importantly, we have also proposed a standardized definition and an approach to quantifying hydrologic recovery that may facilitate cross-study comparisons and a deeper understanding of recovery. Specifically, we propose hydrologic recovery has occurred when a specific post-fire hydrologic function or condition of interest returns to the 95% confidence interval of the pre-fire condition. In support of this definition, we have demonstrated applying this simple approach to assess recovery and presented future research topics to improve our understanding of long-term post-fire catchment responses. In addition to the need for more studies that quantify hydrologic responses farther into the post-fire period, understanding post-fire changes in soil structural and hydraulic properties through time will improve our mechanistic understanding of post-fire hydrologic responses and recovery.

Journal of Hydrology↗