Mineral resource potential map of the Adams Gap and Shinbone Creek Roadless Areas, Clay County, Alabama
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Miscellaneous Field Studies Map↗
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Convergence of soil nitrogen isotopes across global climate gradients
Quantifying global patterns of terrestrial nitrogen (N) cycling is central to predicting future patterns of primary productivity, carbon sequestration, nutrient fluxes to aquatic systems, and climate forcing. With limited direct measures of soil N cycling at the global scale, syntheses of the 15 N: 14 N ratio of soil organic matter across climate gradients provide key insights into understanding global patterns of N cycling. In synthesizing data from over 6000 soil samples, we show strong global relationships among soil N isotopes, mean annual temperature (MAT), mean annual precipitation (MAP), and the concentrations of organic carbon and clay in soil. In both hot ecosystems and dry ecosystems, soil organic matter was more enriched in 15 N than in corresponding cold ecosystems or wet ecosystems. Below a MAT of 9.8°C, soil δ 15 N was invariant with MAT. At the global scale, soil organic C concentrations also declined with increasing MAT and decreasing MAP. After standardizing for variation among mineral soils in soil C and clay concentrations, soil δ 15 N showed no consistent trends across global climate and latitudinal gradients. Our analyses could place new constraints on interpretations of patterns of ecosystem N cycling and global budgets of gaseous N loss.
Scientific Reports↗
Adsorption of benzene, toluene, and xylene by two tetramethylammonium-smectites having different charge densities
A high-charge smectite from Arizona [cation-exchange capacity (CEC) = 120 meq/100 g] and a low-charge smectite from Wyoming (CEC = 90 meq/100 g) were used to prepare homoionic tetramethylammonium (TMA)-clay complexes. The adsorption of benzene, toluene, and o-xylene as vapors by the dry TMA-clays and as solutes from water by the wet TMA-clays was studied. The adsorption of the organic vapors by the dry TMA-smectite samples was strong and apparently consisted of interactions with both the aluminosilicate mineral surfaces and the TMA exchange ions in the interlayers. In the adsorption of organic vapors, the closer packing of TMA ions in the dry high-charge TMA-smectite, compared with the dry low-charge TMA-smectite, resulted in a somewhat higher degree of shape-selective adsorption of benzene, toluene, and xylene. In the presence of water, the adsorption capacities of both samples for the aromatic compounds were significantly reduced, although the uptake of benzene from water by the low-charge TMA-smectite was still substantial. This lower sorption capacity was accompanied by increased shape-selectivity for the aromatic compounds. The reduction in uptake and increased selectivity was much more pronounced for the water-saturated, high-charge TMA-smectite than for the low-charge TMA-smectite. Hydration of the TMA exchange ions and/or the mineral surfaces apparently reduced the accessibility of the aromatic molecules to interlamellar regions. The resulting water-induced sieving effect was greater for the high-charge TMA-smectite due to the higher density of exchanged TMA-ions. The low-charge Wyoming TMA-smectite was a highly effective adsorbent for removing benzene from water and may be useful for purifying benzene-contaminated water.
Clays and Clay Minerals↗
The use of mineralogic techniques as relative age indicators for weathering profiles on the Atlantic Coastal Plain, USA
Textural, geochemical, and mineralogic study of soils and weathering profiles has led to the practice of applying varioys weathering parameters as relative age indicators. In our studies examined the entire thickness of weathered sediment (i.e., the weathering profile) for evidence of weathering-induced changes in both sand- and clay-sized mineralogy, and used two techniques for relative age determinations. These techniques were developed as tools to support geologic mapping. One of our techniques for determining relative ages is based on the depth of weathering as recorded by progressive loss of denrital sand-sized minerals upward in the weathering profile. This is our preferred tool, especially in areas where weathering profiles have been truncated. We have found a gradual trend of increasing loss of labile sand-sized minerals (e.g., hornblendes, feldspars) and increasing depth of weathering with increasing age of the deposit. Of significance to many research programs, this technique does not require expensive instruments such as an X-ray diffractometer. Our other technique depends on accumulation of stable, secondary clay-sized minerals in the upper part of the weathering profile. In our study area on the Atlantic Coastal Plain of the United States, the stable assemblage consists of vermiculite, kaolinite, gibbsite, and iron oxides and hydroxides. This technique can be effective for relative age determinations where profiles have not been truncated, and can provide useful information on depositional and erosional history. However, in areas of widespread erosion and profile truncation, such as the Carolinas, the utility of this technique for relative age determinations is limited. There, soils were partially or completely removed in many localities in relatively recent times.
Delaware, Maryland, New Jersey, North Carolina, So↗
Summary of the mineral- and energy-resource endowment, BLM roswell resource area, east-central New Mexico
In this summary of two comprehensive resource reports produced by the U.S. Bureau of Mines and the U.S. Geological Survey for the U.S. Bureau of Land Management, we discuss the mineral- and energyresource endowment of the 14-millon-acre Roswell Resource Area, New Mexico, managed by the Bureau of Land Management. The Bureau and Survey reports result from separate studies that are compilations of published and unpublished data and integrate new findings on the geology, geochemistry, geophysics, mineral, industrial, and energy commodities, and resources for the seven-county area. The reports have been used by the Bureau of Land Management in preparation of the Roswell Resource Area Resource Management Plan, and will have future use in nationwide mineral- and energy-resource inventories and assessments, as reference and training documents, and as public-information tools. In the Roswell Resource Area, many metals, industrial mineral commodities, and energy resources are being, or have been, produced or prospected. These include metals and high-technology materials, such as copper, gold, silver, thorium, uranium and/or vanadium, rare-earth element minerals, iron, manganese, tungsten, lead, zinc, and molybdenum; industrial mineral resources, including barite, limestone/dolomite, caliche, clay, fluorspar, gypsum, scoria, aggregate, and sand and gravel; and fuels and associated resources, such as oil, gas, tar sand and heavy oil, coal, and gases associated with hydrocarbons. Other commodities that have yet to be identified in economic concentrations include potash, halite, polyhalite, anhydrite, sulfur, feldspar, building stone and decorative rock, brines, various gases associated with oil and gas exploration, and carbon dioxide. ?? 1993 Oxford University Press.
Nonrenewable Resources↗
Hydrous pyrolysis of New Albany Shale: A study examining maturation changes and porosity development
The characterization of nanoscale organic structures has improved our understanding of porosity development within source-rock reservoirs, but research linking organic porosity evolution to thermal maturity has generated conflicting results. To better understand this connection, an immature (0.25% solid bitumen reflectance; BR o ) sample of the New Albany Shale was used in four isothermal hydrous pyrolysis (HP) experiment sequences at 300°, 320°, 340°, and 370°C, with residues collected periodically for a maximum of 103 days. The HP residues, along with the original immature sample and two naturally matured (1.49 and 1.56% BR o ) New Albany Shale samples were analyzed for organic petrology, total organic carbon (TOC) content, and organic porosity evaluation using correlative light and electron microscopy (CLEM). All of the HP series increased in thermal maturity with increasing duration of pyrolysis, though reflectance for each series plateaued within 25 days of maturation. Initially, TOC in the HP residues decreases (from 14.24 wt. %) with increasing thermal maturity until ∼1.0% BR o where TOC remains at ∼9–10 wt. % for all remaining residues. Qualitative CLEM observations within the 50–100 day 300° and 340°C HP sequences (0.95–1.70% BR o ), and the naturally matured samples, develop organic porosity in smaller (<5 μm in diameter), void-filling solid bitumen that occurs in spaces between clays and other fine-grained minerals. The 370°C HP residues developed significant organic porosity, relative to the other HP temperature series in all solid bitumen accumulations regardless of size. Overall, the study indicates that temperature and duration of artificial maturation play an important role in the abundance of pores in the HP residues. This work expands on our understanding of the conditions needed for the generation and development of organic porosity in the New Albany Shale and potentially in other marine source-rock petroleum systems.
Illinois, Indiana↗
Hydrothermal minerals and alteration rates at Surtsey volcano, Iceland
The volcanic island Surtsey, off the south coast of Iceland, was created by volcanic activity in 1963–1967. Core from a 181-m-deep hole extending 123 m below sea level shows the results of 12 yr of hydrothermal alteration of basaltic tephra. The primary cause of heating of the tephra and of development of the hydrothermal system was the intrusion of dikes below sea level. At present, the hottest part of the hole, at a maximum temperature of 150 °C, is cooling at ∼0.9 °C per year. Palagonitization of sideromelane glass, a dominant constituent of the tephra, is an important alteration process that is strongly temperature dependent, the rate doubling for every 12 °C increase. At 60 °C, <40% of the glass is palagonitized, but above 100 °C, >90% is palagonitized. Above 120 °C, olivine crystals are replaced on their edges by nontronite; the thickness of clay doubles for each 8 °C increase. Ten hydrothermal minerals have crystallized in the tephra at 25 to 150 °C; the dominant species are smectite (nontronite), analcite, phillipsite, and tobermorite. The primary clay species of palagonite is probably nontronite. Other minerals are halite, opal, calcite, chabazite, xonotlite, anhydrite, and gypsum. No major differences in mineral occurrence are noted above and below sea level, but phillipsite and tobermorite tend to grow larger below sea level, even at the same temperature. Analcite appears at lower temperature (55 °C) above sea level than below sea level (75 °C). Anhydrite is most abundant deep in the hole, where inflowing, cool sea water precipitated sulfate due to reduced sulfate solubility at higher temperatures.
Surtsey↗
Sources of acid and metals from the weathering of the Dinero waste pile, Lake Fork watershed, Leadville, Colorado
Two trenches were dug into the south Dinero mine-waste pile near Leadville, Colorado, to study the weathering of rock fragments and the mineralogic sources of metal contaminants in the surrounding wetland and Lake Fork Watershed. Water seeping from the base of the south Dinero waste-rock pile was pH 2.9, whereas leachate from a composite sample of the rock waste was pH 3.3. The waste pile was mostly devoid of vegetation, open to infiltration of precipitation, and saturated at the base because of placement in the wetland. The south mine-waste pile is composed of poorly sorted material, ranging from boulder-size to fine-grained rock fragments. The trenches showed both matrix-supported and clast-supported zones, with faint horizontal color banding, suggesting zonation of Fe oxides. Secondary minerals such as jarosite and gypsum occurred throughout the depth of the trenches. Infiltration of water and transport of dissolved material through the pile is evidenced by optically continuous secondary mineral deposits that fill or line voids. Iron-sulfate material exhibits microlaminations with shrinkage cracking and preferential dissolution of microlayers that evidence drying and wetting events. In addition to fluids, submicron-sized to very fine-grained particles such as jarosite are transported through channel ways in the pile. Rock fragments are coated with a mixture of clay, jarosite, and manganese oxides. Dissolution of minerals is a primary source of metals. Skeletal remnants of grains, outlined by Fe-oxide minerals, are common. Potassium jarosite is the most abundant jarosite phase, but Pb-and Ag-bearing jarosite are common. Grain-sized clusters of jarosite suggest that entire sulfide grains were replaced by very fine-grained jarosite crystals. The waste piles were removed from the wetland and reclaimed upslope in 2003. This was an opportunity to test methods to identify sources of acid and metals and metal transport processes within a waste pile. A series of entrapment ponds, lined with limestone rip rap, was created where the mine waste was once situated. A flooded adit discharges low-pH metal-bearing waters into the ponds. A white (Zn, Mn)-sulfate precipitate was observed in 2003 around the edges of the most distal pond.
Colorado↗
Occurrences of alunite, pyrophyllite, and clays in the Cerro La Tiza area, Puerto Rico
A deposit of hydrothermally altered rocks in the Cerro La Tiza area located between the towns of Comerio and Aguas Buenas, approximately 25 kilometers southwest of San Juan, Puerto Rico, was mapped and studied to determine the principal minerals, their extent distribution and origin, and the possibility of their economic utilization, especially in Puerto Rico. The Cerro la Tiza area is about 7 1 / 2 kilometers long, has an average width of about 1 1 / 2 kilometers and embraces a total area of approximately 15 square kilometers. The principal mineralized zone, a dike-like mass of light-colored rocks surrounded by dark-colored volcanic country rocks, occupies the crest and upper slopes of east-trending Cerro La Tiza ridge and is believed to be of Late Cretaceous or Eocene age. This zone is approximately 5,300 meters long, 430 meters wide and has an area of approximately 225 hectares (556 acres). The rocks of the mineralized zone are of mixed character and consist mainly of massive quartzose rocks and banded quartz-alunite rocks closely associated with foliated pyrophyllitic, sericitic and clayey rocks. The principal minerals in probably order of abundance are quartz, alunite, pyrophyllite, kaolin group clays (kaolinite and halloysite) and sericite. Minerals of minor abundance are native sulfure, diaspore, svanbergite (?), sunyite (?), hematite, goethite, pyrite, rutile (?) and very small quantities of unidentified minerals. The mineralized zone has broken down to deposits of earth-rock debris of Quaternary age that cover much of the slopes and flanks of Cerro La Tiza. This debris consists generally of fragments and boulders with a very large size range embedded in a clayey matrix. The distribution of the earth-rock debris with respect to the present topography and drainage suggests that it may have undergone at least two cycles of erosion. Underlying the earth-rock debris and completely enclosing the mineralized zone are country rocks of probably Late Cretaceous age. These consist principally of low flows and volcanic and flow breccias but contain thin interbedded siltstones and sandstones. The lavas are generally predominant at the western end of the area and the breccias at the eastern end. The mineralized zone and the country rocks are sheared along two predominant directions that are approximately N 70 degrees E and N 70 degrees W. The ridge of Cerro La Tiza appears to be a broad shear zone through which hydrothermal emanations gained access to the country rocks. The emanations are believed to have originated from intrusive rocks that probably underlie the area. The surrounding area contains both large and small exposed intrusive bodies. The largest one is the San Lorenzo batholith of Late Cretaceous or Eocene age whose exposed northwest edge is approximately 19 kilometers southeast of the eastern end of the Cerro La Tiza area. Other zones of hydrothermally altered rocks were discovered along a mineralized belt extending eastward from Cerro La Tiza through the Rio Gurabo Valley nearly to the Vieques Passage bordering the east coast of Puerto Rico. Other zones were discovered north and south of this belt and still others were found circumventing the San Lorenzo batholith. The most abundant minerals of the mineralized zone can be exploited for economic utilization in Puerto Rico. Alunite can be utilized in the manufacture of aluminum sulfate for water purification. It can also be used in the manufacture of alumina refractory materials. Pyrophyllite can be used as a carrier for insecticides and fungicides. It can also be utilized for the manufacture of ceramic products, as a filler in the soap industry and as a carrier for paint pigments. Kaolinite can be used in the ceramic industry and in the manufacture of glass as a substitute for feldspar. Halloysite might be utilized as a catalyst support in the cracking of petroleum. Tonnages of reserve ore on Cerro La Tiza are calculated to be 1,590,000 inferred short tons (1,440,000,000 inferred metric tons) of mixed minerals. These tonnages are based on the assumption that the depth of the mineralized zone is one-half of the exposed width. The deposit is well situated for open pit mining, but because of the existing cover of earth-rock debris, soil foliage, exploration should proceed exploitation for better determination of the most promising areas containing the best concentrations of the minerals sought.
Cerro La Tiza↗
Petrology and chemistry of Permian coals from the Paraná Basin: 1. Santa Terezinha, Leão-Butiá and Candiota Coalfields, Rio Grande do Sul, Brazil
The current paper presents results on petrological and geochemical coal seam characterization in Permian coal-bearing strata from the Paraná Basin, southern Brazil. Sequence stratigraphic analysis shows that peat accumulation in Permian time was closely linked to transgressive/regressive cycles, with peat accumulation occurring in a predominantly back barrier/lagoonal setting. Coal petrographic analysis indicates subbituminous coals at Candiota and Leão-Butiá and high volatile bituminous coals at Santa Terezinha, where locally the coal seams are thermally altered by volcanic intrusions. Petrographic composition is highly variable, with seams at Candiota and Santa Terezinha frequently enriched in inertinite. Chemical analyses indicate that all coals are mineral matter-rich (mean 49.09 wt.%), with SiO 2 and Al 2 O 3 dominating as determined by ICP-AES. Quartz is also the predominant mineral detected by X-ray diffraction, where it is associated with feldspar, kaolinite and hematite and iron-rich carbonates. The results from Scanning Electron Microscopy are broadly consistent with the bulk chemical and mineralogical analysis. Quartz and clays are common in all samples analyzed. Other minerals observed were, amongst others, carbonates (calcite, siderite, ankerite), pyrite, monazite, kaolinite, barite, sphalerite, rutile and quartz of volcanic origin. The distribution of trace elements is well within the range typical for coal basins of other areas despite the fact that the Paraná Basin coals are very high in ash yields. The average concentrations for elements of environmental concern (As, B, Be, Cd, Co, Cr, Cu, Hg, Li, Mn, Mo, Ni, Pb, Sb, Se, Tl, U, V, Zn) are similar to or less than the mean values for U.S. coal. However, considered on an equal energy basis, Paraná Basin coals will produce in combustion 5 to 10 times the amount of most elements compared to an equal weight US coal. Concentrations of major and trace elements, such as Fe, B and S, appear to be controlled by depositional setting, with increasing values in coal seams overlain by brackish/marine strata. Hierarchical cluster analysis identified three groups of major minerals and seven groups of trace elements based on similarity levels. On a regional scale, the coalfields can be separated by the differences in rank (Candiota and Leão-Butiá versus Santa Terezinha) and by applying discriminant analysis based on 4 trace elements (Li, As, Sr, Sb). Highest Rb and Sr values occur at Candiota and are linked to syngenetic volcanism of the area, whereas high Y and Sr values at Santa Terezinha can be related to the frequent diabase intrusions in that area.
International Journal of Coal Geology↗
Geology of the Anlauf and Drain quadrangles, Douglas and Lane counties, Oregon
The Anlauf and Drain quadrangles, Oregon, lie about 20 miles south of the City of Eugene, in Douglas and Lane Counties. They constitute an area of about 435 square miles that includes parts of both the Cascade Range and Coast Range physiographic provinces. A sequence of lower Tertiary sedimentary and volcanic rocks with a maximum thickness of about 20,000 feet is exposed in the area. The oldest part of this sequence is the Umpqua formation of early Eocene age consisting of a lower Member of vesicular and amygdaloidal olivine basalt flows, a middle member of water-laid vitric and lapilli crystal tuff, and an upper member of interbedded fissile siltstone and basaltic sandstone which contains a 300-foot tongue of massive to thick-bedded basaltic sandstone near its top. These rocks are predominantly of marine origin, although the general absence of pillow structures Which are common in basaltic lavas of equivalent age elsewhere in the Coast Ranges suggests that some of the flows were poured out subaerially. The overlying tuff member, however, contains Foraminifera and in places has a lime content slightly in excess of 10 percent. Mollusca and Foraminifera indicate that the Umpqua formation is of early Eocene age and is a correlative of the Capay formation of California. The Tyee formation of middle Eocene age overlies the Umpqua formation and consists of more than 5,000 feet of rhythmically deposited sandstone and siltstone in beds 2 to 30 feet thick. The basal part of each bed consists of medium- to coarse-grained sandstone that grades upward into line-grained sandstone and siltstone. The principal constituents of the sandstone are quartz, partly altered feldspar, mica, clay, and fragments of basalt, fine-grained argillaceous rocks, and mica schist. Other detrital minerals include epidote, garnet, blue-green hornblende, tourmaline, and zoisite. The depositional environment of the Tyee formation is poorly known, although the rhythmic-graded bedding suggests turbidity currents. About 500 feet of sandstone and siltstone assigned to the Spencer formation of late Eocene age unconformably overlies the Tyee formation. The Spencer formation, better exposed in the east-central part of the Coast Ranges, contains marine fossils but also has thin impure coal beds, indicative of strand-line accumulation. The sandstone in the Spencer formation is very similar to that in the Tyee formation, from which it was probably derived. The Fisher formation contains about 5,500 feet of nonmarine pyroclastic and Volcanic rocks that are related to the volcanic rock sequences of the western Cascade Range. The formation is characterized by a wide variety of rock types, including conglomerate, tuffaceous sandstone and siltstone, vitric and crystal tuff, waterlaid and mudflow breccia, and andesitic lava flows. These rocks generally occur in lenticular beds that have little stratigraphic significance. The rocks apparently accumulated on a plain slightly above sea level that was subjected alternately to flooding by running water and to desiccation. Fossil leaves from the lowermost part of the Fisher formation are of late Eocene age; the upper part of the formation is of early, and possibly middle, Oligocene age. A few exposures of olivine basalt were mapped in the extreme northern part of the Anlauf quadrangle. The flows, more extensively exposed to the north, overlie the Fisher formation, and, therefore, are tentatively considered to be post-Oligocene in age. All these stratigraphic units, but principally the Fisher formation, are cut by dikes, sills, and stocklike bodies of porphyritic basalt, diabase, and norite. Contemporaneously with the emplacement of most of these rocks, in late Miocene(?) time, hydrothermal solutions locally altered the sedimentary and extrusive igneous rocks and deposited cinnabar and other sulfide minerals, carbonates, and silica. Three parallel northeastward-trending anticlines in the older marine rocks are the most conspicuous structural features in the area. These folds plunge both to the northeast and southwest and expose in their central parts basalt flows of the Umpqua formation. The rocks along the west margin of the area dip westward into a structural basin in the adjacent Elkton quadrangle, whereas to the east the Fisher formation generally has an easterly dip typical of the nonmarine rocks in the western Cascade Range. Geologic studies in the Anlauf and Drain quadrangles were undertaken principally to evaluate the petroleum possibilities of the area. Available data indicate that source beds and reservoir rock suitable for the formation and accumulation of petroleum are absent in this part of the Coast Ranges, but because of the lack of subsurface information, this evaluation is only tentative. Mineral deposits of economic value in the area include quicksilver and alumina clay.
Oregon↗
An assessment of hydrothermal alteration in the Santiaguito lava dome complex, Guatemala: implications for dome collapse hazards
A combination of field mapping, geochemistry, and remote sensing methods has been employed to determine the extent of hydrothermal alteration and assess the potential for failure at the Santiaguito lava dome complex, Guatemala. The 90-year-old complex of four lava domes has only experienced relatively small and infrequent dome collapses in the past, which were associated with lava extrusion. However, existing evidence of an active hydrothermal system coupled with intense seasonal precipitation also presents ideal conditions for instability related to weakened clay-rich edifice rocks. Mapping of the Santiaguito dome complex identified structural features related to dome growth dynamics, potential areas of weakness related to erosion, and locations of fumarole fields. X-ray diffraction and backscattered electron images taken with scanning electron microscopy of dacite and ash samples collected from around fumaroles revealed only minor clay films, and little evidence of alteration. Mineral mapping using ASTER and Hyperion satellite images, however, suggest low-temperature (<150 °C) silicic alteration on erosional surfaces of the domes, but not the type of pervasive acid-sulfate alteration implicated in collapses of other altered edifices. To evaluate the possibility of internal alteration, we re-examined existing aqueous geochemical data from dome-fed hot springs. The data indicate significant water–rock interaction, but the Na–Mg–K geoindicator suggests only a short water residence time, and δ18O/δD ratios show only minor shifts from the meteoric water line with little precipitation of secondary (alteration) minerals. Based on available data, hydrothermal alteration on the dome complex appears to be restricted to surficial deposits of hydrous silica, but the study has highlighted, importantly, that the 1902 eruption crater headwall of Santa María does show more advanced argillic alteration. We also cannot rule out the possibility of advanced alteration within the dome complex interior that is not accessible to the methods used here. It may therefore be prudent to employ geophysical methods to make further assessments in the future.
Bulletin of Volcanology↗
Pore systems and organic petrology of cretaceous Mowry and Niobrara source-rock reservoirs, Powder River Basin, Wyoming, USA
The Powder River Basin (PRB) is a world-class oil province, in large part thanks to contributions from premier source rocks, Cretaceous Mowry and Niobrara shales. Both formations are also unconventional reservoirs. A critical aspect of evaluating production potential and finding sweet spots is the nature of the pore systems in these fine-grained source-rock reservoirs. Variation by stratigraphic interval is important for selecting optimum target zones for horizontal wells. Understanding variation in pore type, size, and connectivity and relationships with mineralogy and fabric help in determining prospectivity in different parts of the basin. Deciphering controls on pore-system development helps predict intervals and locations of optimum reservoir quality. Imaging of Niobrara and Mowry samples from a range of thermal maturities provided observations and data on pore systems, organic matter (OM) types and associations with mineralogy and fabric, wettability, and microporosity associated with both diagenetic and detrital clays. Imaging techniques included scanning electron microscopy, organic petrography and correlative scanning electron microscopy, and mapping of mineralogy through energy dispersive spectroscopy. Mean solid bitumen (BR o ) and vitrinite reflectance (VR o ) values indicate all samples are in the oil window with values ranging from 0.52 to 1.15%. Organic fluorescence is prominent in amorphous OM, solid bitumen and some vitrinite in the early oil window. The fluorescence is extinguished at higher thermal maturity. Carbonate pellets (in Niobrara) mainly contain migrated solid bitumen and residual live oil and little or no terrigenous OM (vitrinite and inertinite). However, terrigenous OM is common in siliceous/argillaceous laminae in both formations, where it occurs with amorphous OM, some of which has converted in situ to a solid bitumen petroleum residue. One key finding is the widespread presence of migrated OM at very early oil window maturity. Distribution of such OM and associated wettability alteration is fabric-controlled, at all levels of thermal maturity studied. Clay morphology and abundance and supporting rigid mineral grain framework strongly influence pore development, preservation, and connectivity in both formations. Carbonate content is a good proxy for reservoir quality in Niobrara intervals due to association of porous solid bitumen with calcareous fecal pellets. High recrystallized microquartz content is associated with the best reservoir intervals in the Mowry.
Wyoming↗
Chemical transfers along slowly eroding catenas developed on granitic cratons in southern Africa
A catena is a series of distinct but co-evolving soils arrayed along a slope. On low-slope, slowly eroding catenas the redistribution of mass occurs predominantly as plasma, the dissolved and suspended constituents in soil water. We applied mass balance methods to track how redistribution via plasma contributed to physical and geochemical differentiation of nine slowly eroding (~ 5 mm ky − 1 ) granitic catenas. The catenas were arrayed in a 3 × 3 climate by relief matrix and located in Kruger National Park, South Africa. Most of the catenas contained at least one illuviated soil profile that had undergone more volumetric expansion and less mass loss, and these soils were located in the lower halves of the slopes. By comparison, the majority of slope positions were eluviated. Soils from the wetter climates (550 and 730 mm precipitation yr − 1 ) generally had undergone greater collapse and lost more mass, while soils in the drier climate (470 mm yr − 1 ) had undergone expansion and lost less mass. Effects of differences in catena relief were less clear. Within each climate zone, soil horizon mass loss and strain were correlated, as were losses of most major elements, illustrating the predominant influence of primary mineral weathering. Nevertheless, mass loss and volumetric collapse did not become extreme because of the skeleton of resistant primary mineral grains inherited from the granite. Colloidal clay redistribution, as traced by the ratio of Ti to Zr in soil, suggested clay losses via suspension from catena eluvial zones. Thus illuviation of colloidal clays into downslope soils may be crucial to catena development by restricting subsurface flow there. Our analysis provides quantitative support for the conceptual understanding of catenas in cratonic landscapes and provides an endmember reference point in understanding the development of slowly eroding soil landscapes.
Geoderma↗
Endogenic carbonate sedimentation in Bear Lake, Utah and Idaho, over the last two glacial-interglacial cycles
Sediments deposited over the past 220,000 years in Bear Lake, Utah and Idaho, are predominantly calcareous silty clay, with calcite as the dominant carbonate mineral. The abundance of siliciclastic sediment indicates that the Bear River usually was connected to Bear Lake. However, three marl intervals containing more than 50% CaCO 3 were deposited during the Holocene and the last two interglacial intervals, equivalent to marine oxygen isotope stages (MIS) 5 and 7, indicating times when the Bear River was not connected to the lake. Aragonite is the dominant mineral in two of these three high-carbonate intervals. The high-carbonate, aragonitic intervals coincide with warm interglacial continental climates and warm Pacific sea-surface temperatures. Aragonite also is the dominant mineral in a carbonate-cemented microbialite mound that formed in the southwestern part of the lake over the last several thousand years. The history of carbonate sedimentation in Bear Lake is documented through the study of isotopic ratios of oxygen, carbon, and strontium, organic carbon content, CaCO 3 content, X-ray diffraction mineralogy, and HCl-leach chemistry on samples from sediment traps, gravity cores, piston cores, drill cores, and microbialites. Sediment-trap studies show that the carbonate mineral that precipitates in the surface waters of the lake today is high-Mg calcite. The lake began to precipitate high-Mg calcite sometime in the mid-twentieth century after the artificial diversion of Bear River into Bear Lake that began in 1911. This diversion drastically reduced the salinity and Mg 2+ :Ca 2+ of the lake water and changed the primary carbonate precipitate from aragonite to high-Mg calcite. However, sediment-trap and core studies show that aragonite is the dominant mineral accumulating on the lake floor today, even though it is not precipitating in surface waters. The isotopic studies show that this aragonite is derived from reworking and redistribution of shallow-water sediment that is at least 50 yr old, and probably older. Apparently, the microbialite mound also stopped forming aragonite cement sometime after Bear River diversion. Because of reworking of old aragonite, the bulk mineralogy of carbonate in bottom sediments has not changed very much since the diversion. However, the diversion is marked by very distinct changes in the chemical and isotopic composition of the bulk carbonate. After the last glacial interval (LGI), a large amount of endogenic carbonate began to precipitate in Bear Lake when the Pacific moisture that filled the large pluvial lakes of the Great Basin during the LGI diminished, and Bear River apparently abandoned Bear Lake. At first, the carbonate that formed was low-Mg calcite, but ???11,000 years ago, salinity and Mg 2+ :Ca 2+ thresholds must have been crossed because the amount of aragonite gradually increased. Aragonite is the dominant carbonate mineral that has accumulated in the lake for the past 7000 years, with the addition of high-Mg calcite after the diversion of Bear River into the lake at the beginning of the twentieth century. Copyright ?? 2009 The Geological Society of America.
Special Paper of the Geological Society of America↗
Measurement of clay surface areas by polyvinylpyrrolidone (PVP) sorption and its use for quantifying illite and smectite abundance
A new method has been developed for quantifying smectite abundance by sorbing polyvinylpyrrolidone (PVP) on smectite particles dispersed in aqueous solution. The sorption density of PVP-55K on a wide range of smectites, illites and kaolinites is ~0.99 mg/m 2 , which corresponds to ~0.72 g of PVP-55K per gram of montmorillonite. Polyvinylpyrrolidone sorption on smectites is independent of layer charge and solution pH. PVP sorption on SiO 2 , Fe 2 O 3 and ZnO normalized to the BET surface area is similar to the sorption densities on smectites. γ-Al 2 O 3 , amorphous Al(OH) 3 and gibbsite have no PVP sorption over a wide range of pH, and sorption of PVP by organics is minimal. The insensitivity of PVP sorption densities to mineral layer charge, solution pH and mineral surface charge indicates that PVP sorption is not localized at charged sites, but is controlled by more broadly distributed sorption mechanisms such as Van der Waals’ interactions and/or hydrogen bonding. Smectites have very large surface areas when dispersed as single unit-cell-thick particles (~725 m 2 /g) and usually dominate the total surface areas of natural samples in which smectites are present. In this case, smectite abundance is directly proportional to PVP sorption. In some cases, however, the accurate quantification of smectite abundance by PVP sorption may require minor corrections for PVP uptake by other phases, principally illite and kaolinite. Quantitative XRD can be combined with PVP uptake measurements to uniquely determine the smectite concentration in such samples.
Clays and Clay Minerals↗
Geology, geochemistry, and mineral resource assessment of the southern Nantahala Wilderness and adjacent roadless areas, Rabun and Towns counties, Georgia, and Clay and Macon counties, North Carolina
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Bulletin↗
Ball clay and bentonite deposits of the central and western Gulf of Mexico Coastal Plain, United States
The Gulf of Mexico Coastal Plain produces approximately 85 percent of the ball clay used in the United States. The best commercial-grade clay deposits are composed of poorly crystalline kaolinite and small amounts of Md illite and (or) smectite. Sand and silt and iron oxide minerals are virtually absent, but quartz is present in the clay-size fraction. The best grade ball clays are found as lenses limited to the Wilcox Group (Paleocene and lower Eocene) and Claiborne Group (middle Eocene). Reserves of ball clay are sufficient for the present, but because of the lenticular nature of the clay bodies, close-spaced drilling, detailed sampling, mineralogic analyses, and ceramic testing are needed to prove future reserves. Approximately 11 percent of the total bentonite produced in the United States comes from the Gulf Coast region. The commercial-grade bentonites are composed primarily of smectite with little or no Md illite and kaolinite. The nonclay impurities are quartz, feldspar, muscovite, biotite, calcite, dolomite, gypsum, and heulandite. Commercial bentonites occur in the Upper Cretaceous formations in Alabama and Mississippi, in Paleocene formations in Mississippi and Tennessee, and in Eocene and Miocene formations in Texas. The demand for low-swelling bentonite of the Gulf Coastal Plain has not increased along with the demand for swelling bentonite; therefore the reserves are adequate.
Alabama, Arkansas, Kentucky, Louisiana, Mississipp↗