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Chemical and isotopic characteristics of methane in groundwater of Ohio, 2016

In 2016, the U.S. Geological Survey, in cooperation with the Ohio Water Development Authority, investigated the hydrogeologic setting, chemical and isotopic characteristics, and origin of methane in groundwater of Ohio. Understanding the occurrence and distribution of methane in groundwater is important in terms of public safety because methane in water wells can pose a risk of explosion. In addition, documenting the chemical and isotopic characteristics of methane in groundwater can make an important contribution to future stray gas investigations. Water samples were collected from 15 domestic water wells known to produce methane, which were in 12 counties in diverse parts of Ohio. The wells were 75–345 feet deep and tapped a range of aquifer types, including glacial deposits and bedrock of Upper Ordovician, Upper Devonian, Lower Mississippian, and Pennsylvanian ages. Although the hydrogeologic settings were varied, there was a broad similarity among the well sites in that the bedrock was predominantly shale and the glacial deposits were predominantly clay. The wells were sampled for dissolved inorganic constituents; dissolved organic carbon; methane and other dissolved gases; stable isotopes (carbon, hydrogen, and oxygen) of methane, water, and dissolved inorganic carbon; and carbon-14 of methane. Gas composition and stable isotopes of methane were used to differentiate thermogenic and microbial methane. The degree of fractionation of hydrogen and carbon isotopes was used to evaluate the pathway of microbial methanogenesis (carbon dioxide [CO 2 ] reduction or acetate fermentation) and the effects of secondary processes such as oxidation, mixing, and migration. The concentration of carbon-14 of methane was used to evaluate the relative age of the carbon source. The quality of water from the 15 wells differed greatly; water types ranged from CaMgHCO 3 to NaCl, and total dissolved solids concentrations ranged from 318 to 2,940 milligrams per liter (mg/L). Methane concentrations ranged from 1.2 to 120 mg/L. Of the 15 samples, 12 had methane concentrations greater than 28 mg/L, the level that can pose a risk of explosion. Of the 15 samples, 12 had chemical and isotopic characteristics or "signatures" consistent with microbial methane formed by CO 2 reduction. CO 2 reduction is commonly associated with microbial degradation of organic matter in anaerobic aquifers and with the formation of microbial shale gas and coalbed methane along margins of sedimentary basins. Two of 15 samples were interpreted as having a component of thermogenic methane based on the δ 13 C of methane (−50.96 and −47.74 parts per thousand [per mil]) and gas dryness (28 and 5). One of 15 samples (from the shallowest well) had chemical and isotopic characteristics consistent with methane oxidation by sulfate reduction based on light δ 13 C of dissolved inorganic carbon (−31.6 per mil) and evidence of sulfate reduction in terms of the odor and appearance of the water. For the 12 samples interpreted as microbial methane formed by CO 2 reduction, the δ 13 C of methane varied from −75 to −56 per mil. Multiple samples from the same aquifer demonstrated a general trend of increasing δ 13 C of methane with depth. Samples with lighter δ 13 C of methane (−75 to −62 per mil) were from shallower wells (or wells with shallow open intervals), and the isotopic signature of the water was consistent with modern or postglacial groundwater recharge. Three samples with heavier δ 13 C of methane (−61 to −56 per mil) were from deeper wells or more confined aquifers where the isotopic signature of water was consistent with older (glacial) recharge. In addition, δ 13 C of dissolved inorganic carbon was enriched (+12 to +18.9 per mil), and carbon-14 of methane was consistent with carbon associated with Paleozoic bedrock or older glacial deposits. These observations are generally consistent with increased Rayleigh-type fractionation at greater depths; however, other interpretations are possible. Isotopic signatures can be ambiguous, especially in areas with complex geologic histories that include multiple episodes of migration, mixing, and (or) oxidation. Many of the wells were in proximity to multiple potential natural and anthropogenic pathways of methane migration; however, it is not possible to determine if the methane in any of the wells is related to human activities based on the chemical and isotopic data collected for this study.

Ohio

Pesticides data-collection activities of the U.S. Geological Survey in Texas

The water-resources investigations program of the Geological Survey has the objective of seeing that the Nation's water resources are appraised and that the necessary water data to develop and manage them efficiently are available when needed. In carrying out this objective, the Survey is the primary source of hydrologic data that are basic not only to the quantification of the water resource but also to its development and conservation. In recent years, the need has developed for the Survey to provide data and technology to predict the impact of man's activities upon the water resource and the water environment. To accomplish its mission, the Geological Survey determines the source, quantity, quality, distribution, movement, and availability of both surface and ground water. This work includes the assessment of the chemical, physical, and biological quality of water resources and its relation to various parts of the hydrologic cycle; research to improve the scientific basis of investigations and techniques; design and operation of a national water-data network; and publication of its investigations.

Texas

Ground-water conditions in southern Utah Valley and Goshen Valley, Utah

The investigation of ground-water conditions in southern Utah Valley and Goshen Valley, Utah, was made by the U. S. Geological Survey as part of a cooperative program with the Utah Department of Natural Resources, Division of Water Rights, to investigate the water resources of the State. The purposes of the investigation were to (1) determine the occurrence, recharge, discharge, movement, storage, chemical quality, and availability of ground water; (2) appraise the effects of increased withdrawal of water from wells; and (3) evaluate the effect of the Central Utah Project on the ground-water reservoir and the water supply of Utah Lake. This report presents a description of the aquifer system in the two valleys, a detailed description of the ground-water resources, and conclusions about potential development and its effect on the hydrologic conditions in the valleys. Two supplementary reports are products of the investigation. A basic-data release (Cordova, 1969) contains most of the basic data collected for the investigation, including well characteristics, drillers' logs, water levels, pumpage from wells, chemical analyses of ground and surface waters, and discharge of selected springs, drains, and streams. An interpretive report (Cordova and Mower, 1967) contains the results of a large-scale aquifer test in southern Utah Valley.

Utah

Hydrology, water quality, and potential alternatives for water-resources development in the Río Majada and Río Lapa basins near the Albergue Olimpico, southern Puerto Rico

A water-resources investigation was conducted during 1989 in the Rio Lapa mountain basins in southern Puerto Rico, to define the hydrology, water quality, and to describe alternatives for additional water- resources supply. The total water budget for both surface- and ground-water resources in the study area was estimated to be 7,530 acre-feet per year for 1989. The water budget for the ground-water system, from which water needs are supplied in the study area, was estimated to be 2,760 acre-feet per year for 1989. Concentration of dissolved solids and fecal bacteria increased during the dry season as both streamflow and ground-water levels decreased. Water samples collected at two stream sites exceeded the recommended U.S. Environmental Protection Agency fecal bacteria concentration for natural water of 2,000 colonies per 100 milliliters during June to November 1989. Water samples obtained from a well in the Rio Lapa Valley exceeded the secondary drinking-water standard for dissolved solids of 500 milligrams per liter during four dry months. In addition, fecal bacteria concentrations at this water-supply well exceeded the primary fecal- bacteria drinking-water standard of 1 colony per 100 milliliter during June to October 1989. Existing water resources can probably be developed to meet additional demands of 110 acre-feet per year pro- jected for 1995. Storage of the surface-water runoff during the wet season and its gradual release to the study area could offset ground-water declines during the dry season. Ground-water withdrawals can be increased by the construction and use of low- capacity wells to reduce the amount of water lowing out of the study area.

Puerto Rico

Assessment of selected constituents in surface water of the upper Snake River basin, Idaho and western Wyoming, water years 1975-89

In 1991, a water-quality investigation of the upper Snake River Basin was initiated as part of the U.S. Geological Survey's National Water-Quality Assessment Program. The initial task of the assessment was to compile and analyze available nutrient, suspended sediment, and pesticide data collected in the basin. For analysis of nutrients and suspended sediment, data collected during water years 1980-89 were used. For pesticides, an additional 5 years of data were included for a total assessment period encompassing water years 1975-89. Nearly 9,000 analyses of nutrients and suspended sediment from more than 450 stations were retrieved from the U.S. Environmental Protection Agency STORET and U.S. Geological Survey WATSTORE data bases. Nineteen stations had sufficient analyses for quantitative assessment. Of the 19 stations analyzed, 4 are located on relatively unaffected stream reaches, 8 are at or near mouths of tributary basins affected by agricultural activities, and 7 are on the main stem of the Snake River. Data indicate that nitrite plus nitrate and total phosphorus concentrations generally increased in a downstream direction along the Snake River; concentrations were largest at the mouths of drainage basins tributary to the Snake River. Water-quality stations were categorized as unaffected or minimally affected, agriculturally affected, or main stem to compare nutrient concentrations between drainage basins of differing land use/land cover. Concentrations of nitrite plus nitrate, total nitrogen, dissolved orthophosphate, and total phosphorus were significantly (p<0.05) larger at agriculturally affected and main-stem stations than at unaffected stations; and concentrations of nitrite plus nitrate, total nitrogen, and total phosphorus at agriculturally affected stations were significantly larger than at main-stem stations. Significant differences in seasonal concentrations of some nutrient species also were noted. Few suspended sediment and pesticide data were available for the study basin. Only six stations had sufficient data for quantitative assessment of suspended sediment. A direct positive relation exists between suspended sediment concentration and streamflow; concentrations are largest in April, May, and June at high streamflow. Most of the pesticide data compiled from STORET and WATSTORE were collected during water years 1975-79. Only 33 pesticide samples, excluding samples collected for a Rural Clean Water Program, were collected from surface water and bottom sediment during water years 1980-89. Bottom sediment collected near the mouth of the Henrys Fork during the late 1970's had the largest concentrations of pesticides in the basin; DOT, ODD, and DDE concentrations exceeded 10 micrograms per kilogram. Mass movement of nutrients and suspended sediment in the upper Snake River Basin is controlled primarily by changes in streamflow. Between two and three times as much total nitrogen, total phosphorus, and suspended sediment were transported out of the basin in water year 1984 (high-flow year) compared with 1989 (low-flow year). Reservoirs on the main stem of the Snake River probably trap much of the nutrient and most of the suspended sediment load generated from upper parts of the basin. A more extensive data-collection program in the upper Snake River Basin is needed to address a number of water-quality issues. These include an analysis of effects of land use on the quality of surface water; quantification of mass movement of nutrients and suspended sediment at key locations in the basin; distribution of aquatic organisms; and temporal and spatial distribution of pesticides in surface water, bottom sediment, and biota.

Idaho;Montana;Nevada;Utah;Wyoming

A field investigation of phreatophyte‐induced fluctuations in the water table

Hydrographs from shallow wells in vegetated riparian zones frequently display a distinctive pattern of diurnal water table fluctuations produced by variations in plant water use. A multisite investigation assessed the major controls on these fluctuations and the ecohydrologic insights that can be gleaned from them. Spatial and temporal variations in the amplitude of the fluctuations are primarily a function of variations in (1) the meteorological drivers of plant water use, (2) vegetation density, type, and vitality, and (3) the specific yield of sediments in the vicinity of the water table. Past hydrologic conditions experienced by the riparian zone vegetation, either in previous years or earlier within the same growing season, are also an important control. Diurnal water table fluctuations can be considered a diagnostic indicator of groundwater consumption by phreatophytes at most sites, so the information embedded within these fluctuations should be more widely exploited in ecohydrologic studies.

Water Resources Research

Occurrence and transport of cadmium, lead, and zinc in the Spokane River basin, Idaho and Washington, water years 1999-2001

A water-quality investigation of the Clark Fork-Pend Oreille and Spokane River Basins began in 1997 as part of the U.S. Geological Survey National Water-Quality Assessment Program. As part of the investigation, selected streams in the Spokane River Basin were sampled for trace metals during water years 1999–2001. These data, combined with data collected as part of a U.S. Environmental Protection Agency Remedial Investigation/ Feasibility Study, were used to assess the occurrence, loads, and transport of cadmium, lead, and zinc at 21 streamflow-gaging stations in the Spokane River Basin. Concentrations of dissolved and total cadmium, lead, and zinc varied widely both at and among stations. At most stations, dissolved cadmium and zinc composed most of the total concentrations; dissolved lead generally composed less than 10 percent of the total lead concentration. From the South Fork Coeur d’Alene River near Mullan downstream to the South Fork Coeur d’Alene River near Pinehurst, concentrations of trace metals increased 2 to 4 orders of magnitude. The mean flow-weighted concentrations of total cadmium, lead, and zinc near Pinehurst for water years 1999–2001 were 5.7, 80, and 810 micrograms per liter ( µg/L), respectively. On the Coeur d’Alene River near Harrison, downstream from the confluence of the metal-enriched South Fork and the relatively dilute North Fork Coeur d’Alene River, the mean flow-weighted concentrations of total cadmium, lead, and zinc were 1.6, 88, and 240 µg/L, respectively. Trace-metal concentrations were smaller in the Spokane River than in the Coeur d’Alene River because of dilution and retention in Coeur d’Alene Lake. The mean flowweighted concentrations of total cadmium, lead, and zinc in the Spokane River near Post Falls were 0.32, 3.1, and 71 µg/L, respectively. Regression models relating the mass transport, or load, of trace metals to changes in stream discharge and time were successful in simulating the variability in trace-metal concentrations and loads. The median coefficient of determination for the load models for the 21 stations was largest for total lead (92 percent) and smallest for dissolved and total cadmium (82 percent). Whereas most of the cadmium and zinc loads in the Spokane River Basin were derived from the South Fork Coeur d’Alene River, most of the lead load was derived from the Coeur d’Alene River downstream from the confluence of the North and South Forks. Major tributary sources of trace metals to the South Fork Coeur d’Alene River were Canyon Creek, Ninemile Creek, and Government Gulch. These three tributaries contributed about 3,000 pounds of cadmium, 23,000 pounds of lead, and 310,000 pounds of zinc annually to the South Fork Coeur d’Alene River. Erosion and transport of sediment-bound lead in the Coeur d’Alene River was the primary source of total lead, accounting for almost 400,000 pounds annually during water years 1999–2000. Ground-water discharge in the area of the Bunker Hill Superfund site was a major source of zinc in the South Fork Coeur d’Alene River, contributing more than 250,000 pounds per year. During water years 1999–2000, the average annual loads of cadmium, lead, and zinc transported from the Coeur d’Alene, St. Joe, and St. Maries Rivers to Coeur d’Alene Lake were 8,900, 500,000, and 1.4 million pounds, respectively. The Coeur d’Alene River accounted for more than 99 percent of the total load of each of these three metals entering the lake. About 4,600 pounds of cadmium, 44,000 pounds of lead, and 980,000 pounds of zinc were transported from Coeur d’Alene Lake into the Spokane River. Between the Spokane River near Post Falls, Idaho, and the Spokane River at Long Lake, Washington, there was an annual net loss of about 2,600, 20,000, and 250,000 pounds of cadmium, lead, and zinc, respectively. About 2,000 pounds of cadmium, 24,000 pounds of lead, and 730,000 pounds of zinc were transported annually downstream from Long Lake toward the Columbia River.

Idaho;Washington

Water resources of Washakie County, Wyoming

Data on the surface- and ground-water resources are complied to summarize the water resources of Washakie County. This study, prepared in cooperation with the Wyoming State Engineer, is one in a series investigating the water resources of Wyoming counties . The three principal types of streams in the county are perennial, intermittent, and ephemeral. Perennial streams have continuous streamflows, and high streamflows are associated with snowmelt runoff; low streamflows usually occur in the winter months when the snowpack is frozen and ground-water discharge is at its smallest rate. Intermittent and ephemeral streams are characterized by periods of no flow, and high streamflows are associated with snowmelt or thunderstorms. The principal aquifers are as follows: alluvium of Quaternary age, Willwood Formation of Tertiary age, Fort Union Formation of Tertiary age, and the formations of primarily Paleozoic age--Goose Egg Formation, Tensleep Sandstone, Madison Limestone, Bighorn Dolomite, and Flathead Sandstone. Reported yields from wells completed in the alluvium ranged from 10 to 40 gallons per minute, and reported yields from wells completed in the Willwood Formation ranged from 1 to 28 gallons per minute. Yields as large as 2,500 gallons per minute are reported from wells completed in the Madison Limestone, Bighorn Dolomite, and Flathead Sandstone. Calcium magnesium sodium sulfate water and sodium sulfate water with concentrations of dissolved solids greater than 1,000 milligrams per liter are common in the alluvium, Willwood Formation and Fort Union Formation. Water samples from six of eight wells completed in the Willwood Formation have trace concentrations of herbicides. Calcium carbonate water with small dissolved-solids concentrations is common in the aquifers in Paleozoic formations.

Wyoming

Hydrology, description of computer models, and evaluation of selected water-management alternatives in the San Bernardino area, California

The San Bernardino area of southern California has complex water-management issues. As an aid to local water managers, this report provides an integrated analysis of the surface-water and ground-water systems, documents ground-water flow and constrained optimization models, and provides seven examples using the models to better understand and manage water resources of the area. As an aid to investigators and water managers in other areas, this report provides an expanded description of constrained optimization techniques and how to use them to better understand the local hydrogeology and to evaluate inter-related water-management problems. In this report, the hydrology of the San Bernardino area, defined as the Bunker Hill and Lytle Creek basins, is described and quantified for calendar years 1945-98. The major components of the surface-water system are identified, and a routing diagram of flow through these components is provided. Annual surface-water inflow and outflow for the area are tabulated using gaged measurements and estimated values derived from linear-regression equations. Average inflow for the 54-year period (1945-98) was 146,452 acre-feet per year; average outflow was 67,931 acre-feet per year. The probability of exceedance for annual surface-water inflow is calculated using a Log Pearson Type III analysis. Cumulative surface-water inflow and outflow and ground-water-level measurements indicate that the relation between the surface-water system and the ground-water system changed in about 1951, in about 1979, and again in about 1992. Higher ground-water levels prior to 1951 and between 1979 and 1992 induced ground-water discharge to Warm Creek. This discharge was quantified using streamflow measurements and can be estimated for other time periods using ground-water levels from a monitoring well (1S/4W-3Q1) and a logarithmic-regression equation. Annual wastewater discharge from the area is tabulated for the major sewage and power-plant facilities. More...

Open-File Report

Ground water in Oklahoma

One of the first requisites for the intelligent planning of utilization and control of water and for the administration of laws relating to its use is data on the quantity, quality, and mode of occurrence of the available supplies. The collection, evaluation and interpretation, and publication of such data are among the primary functions of the U. S. Geological Survey, Since 1895 the Congress has made appropriations to the Survey for investigation of the water resources of the Nation. In 1929 the Congress adopted the policy of dollar-for-dollar cooperation with the States and local governmental agencies in water resources investigations of the U. S. Geological Survey, In 1937 a program of ground-water investigations was started in cooperation with the Oklahoma Geological Survey, and in 1949 this program was expanded to include cooperation with the Oklahoma Planning and Resources Board, In 1957 the State Legislature created the Oklahoma Water Resources Board as the principal State water agency and it became the principal local cooperator.

Oklahoma

Hydrogeologic characteristics of the valley-fill aquifer in the Arkansas River Valley, Bent County, Colorado

The investigation on which this report is based is a part of a comprehensive evaluation of the water resources of the Arkansas River valley undertaken by the U.S. Geological Survey in cooperation with the Colorado Water Conservation Board and the Southeastern Colorado Water Conservancy District. The study reach extends 150 miles from Pueblo to the Kansas State line (see fig. 1 index map). The water-resources investigation of the stream aquifer system in the Arkansas River valley, which began in 1963, is being made to provide information about the water resources for planning, management, and administration of the supply. The objectives of the investigation are to define the effects of present water use, to determine the relation between ground and surface water, and to evaluate the effects of proposed changes in water law and management. The major steps in the study are: (1) Inventory the water resources, (2) describe the hydrogeologic character of the aquifer, (3) document and evaluate the effects of development, (4) construct and verify models to aid in the evaluation of the hydrology, and (5) develop models to test water-management plans and to optimize water use.

Colorado

Initial assessment of the ground-water resources in the Monterey Bay region, California

The Association of Monterey Bay Area Governments (AMBAG) has been designated as the areawide waste-treatment-management planning agency for the Monterey Bay region under Sec. 208 of the Federal Water Pollution Control Act Amendments of 1972 (Public Law 92-500). Sec. 208 establishes the authority and responsibility of the designated local agency to investigate water-quality problems and plan solutions to them. In developing a waste-management program all aspects of water resources must be evaluated. AMBAG's 208 work plan established an initial problem assessment phase designed to serve as the basis for subsequent 208 program tasks. AMBAG requested that the U.S. Geological Survey make that portion of the initial assessment that was concerned with ground water. This report presents the findings of the assessment.

California

Zinc isotope investigation of surface and pore waters in a mountain watershed impacted by acid rock drainage

The pollution of natural waters with metals derived from the oxidation of sulfide minerals like pyrite is a global environmental problem. However, the metal loading pathways and transport mechanisms associated with acid rock drainage reactions are often difficult to characterize using bulk chemical data alone. In this study, we evaluated the use of zinc (Zn) isotopes to complement traditional geochemical tools in the investigation of contaminated waters at the former Waldorf mining site in the Rocky Mountains, Colorado, U.S.A. Geochemical signatures and statistical analysis helped in identifying two primary metal loading pathways at the Waldorf site. The first was characterized by a circumneutral pH, high alkalinity, and high Zn/Cd ratios. The second was characterized by acidic pHs and low Zn/Cd ratios. Zinc isotope signatures in surface water samples collected across the site were remarkably similar (the δ 66 Zn, relative to JMC 3-0749-L, for most samples ranged from 0.20 to 0.30‰ ± 0.09‰ 2σ). This probably suggests that the ultimate source of Zn is consistent across the Waldorf site, regardless of the metal loading pathway. The δ 66 Zn of pore water samples collected within a nearby metal-impacted wetland area, however, were more variable, ranging from 0.20 to 0.80‰ ± 0.09‰ 2σ. Here the Zn isotopes seemed to reflect differences in groundwater flow pathways. However, a host of secondary processes might also have impacted Zn isotopes, including adsorption of Zn onto soil components, complexation of Zn with dissolved organic matter, uptake of Zn into plants, and the precipitation of Zn during the formation of reduced sulfur species. Zinc isotope analysis proved useful in this study; however, the utility of this isotopic tool would improve considerably with the addition of a comprehensive experimental foundation for interpreting the complex isotopic relationships found in soil pore waters.

Colorado

U.S. Geological Survey cooperative water-resources programs in Chester County, Pennsylvania

Since 1969, the U.S. Geological Survey (USGS) has had a cooperative water-resources investigation program with Chester County to measure and describe the water resources of the County. Generally, the USGS provides one-half of the program funding, and local cooperators are required to provide matching funds. Cooperation has been primarily with the Chester County Water Resources Authority (CCWRA), with participation from the Chester County Health Department and funding from the Chester County Board of Commissioners. Municipalities and the Red Clay Valley Association also have provided part of the funding for several projects. This report describes how the long-term partnership between the USGS and Chester County, Pa., provides the County with the information that it needs for sound water-resources management. The CCWRA was created in 1961, primarily for land acquisition and planning for flood-control and water-supply projects. With the backing of the Brandywine Valley Association, the CCWRA started its first cooperative project with the USGS in 1969. It was a study of the water-quality condition of Chester County streams with an emphasis on benthic macroinvertebrates and stream chemistry. The kinds of projects and data collection conducted by the USGS have changed with the needs of Chester County and the mission of the CCWRA. Chester County is experiencing rapid population growth (it had the tenth-highest rate of growth in the nation from 1980 to 1990). This growth places considerable stress on water resources and has caused the CCWRA to broaden its focus from flood control to water-supply planning, water quality, and ground-water and surface-water management. The results of USGS studies are used by the CCWRA and other County agencies, including the Planning Commission, Health Department, and Parks and Recreation Department, for conducting day-to-day activities and planning for future growth. The results also are used by the CCWRA to provide guidance and technical assistance to municipalities, water suppliers, industrial dischargers, watershed and conservancy associations and other civic organizations, state and Federal agencies, river basin commissions, and the private sector. The cooperative water-resources program, which is described in the following sections, benefits not only the citizens of Chester County but also serves the interests of the Federal Government. Innovative studies conducted in Chester County provide methods and interpretations that often can be used nationwide, and the headwaters of several interstate drainages lie within the County. Major program thrusts include collection of surface-water, ground-water, and water-quality data and interpretive studies. The use of this information also is described.

Pennsylvania

Hydrogeologic data for the Coconino Plateau and adjacent areas, Coconino and Yavapai counties, Arizona

Data on geology, topography, hydrology, climate, land use, and vegetation were compiled between October 2000 and September 2001 and assembled into a database for use by local and regional waterresource managers and for future water-resource investigations. The hydrologic data include information on wells, springs, streamflow, water chemistry, and water use. Limitations of the data and additional data needs also were prepared. The roughly 5,000-square-mile Coconino Plateau contains a complex regional aquifer that has become increasingly important as a source of water supply for domestic, municipal, and in-stream uses owing to population growth and development. The flow characteristics of the regional aquifer are poorly understood because the aquifer is deeply buried, which limits exploratory drilling and testing, and because the geologic structure, which controls the occurrence and movement of ground water, is complex. The study area is about 10,300 square miles and, besides containing the entire Coconino Plateau, includes parts of adjacent areas where ground water from the Coconino Plateau discharges. Selected data are presented in tabular or graphical form. All data are available in electronic form.

Arizona

Water Resources Data for California, 1965; Part 2: Water Quality Records

Water-resources investigations of the U.S. Geological Survey include the collection of water quality data on the chemical and physical characteristics of surface and ground-water supplies of the Nation. These data for the 1965 water year for the quality of surface waters in California are presented in this report. Data for a few water quality stations in bordering States are also included. The data were collected by the Water Resources Division of the U.S Geological Survey under the direction of Walter Hofmann, district chief. Water quality information is presented for chemical quality, fluvial sediment, and water temperatures. The chemical quality includes concentrations of individual dissolved constituents and certain properties or characteristics such as hardness, sodium-adsorption-ratio, specific conductance, and pH. Fluvial sediment information is given for suspended-sediment discharges and concentrations and for particle-size distribution of suspended sediment and bed material. Water temperature data represent once-daily observations except for stations where a continuous temperature recorder furnishes information from which daily minimums and maximums are obtained.

California

Water resources data for Indiana, 1968

The surface-water records for the 1968 water year for gaging stations, partial-record stations, and miscellaneous sties within the State of Indiana are given in this report. For convenience there are also included records for a few pertinent gaging stations in bordering States. Water-resources investigations of the U.S. Geological Survey include the collection of water quality data on the chemical and physical characteristics of surface- and ground-water supplies of the Nation. These data for the 1968 water year for the quality of surface water in Indiana are presented in this report.

Indiana