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Methods for quantifying interactions between groundwater and surface water

Driven by the need for integrated management of groundwater (GW) and surface water (SW), quantification of GW–SW interactions and associated contaminant transport has become increasingly important. This is due to their substantial impact on water quantity and quality. In this review, we provide an overview of the methods developed over the past several decades to investigate GW–SW interactions. These methods include geophysical, hydrometric, and tracer techniques, as well as various modeling approaches. Different methods reveal valuable information on GW–SW interactions at different scales with their respective advantages and limitations. Interpreting data from these techniques can be challenging due to factors like scale effects, heterogeneous hydrogeological conditions, sediment variability, and complex spatiotemporal connections between GW and SW. To facilitate the selection of appropriate methods for specific sites, we discuss the strengths, weaknesses, and challenges of each technique, and we offer perspectives on knowledge gaps in the current science.

Annual Review of Environment and Resources

Keeping pace: Migrating sea lampreys adjust swim speed in response to shifting water velocity to maintain a constant ground speed

Upstream migrating fish must balance energetic costs with environmental and ecological constraints. Theoretical models predict that fish can conserve energy by adjusting swim speed in response to changing water velocity, but detailed field tests of these predictions remain rare. We used fine-scale acoustic telemetry and hydrodynamic modeling to track adult sea lamprey (Petromyzon marinus) migrating through a river and evaluated how movement speeds varied with environmental conditions and individual traits. Swim speed increased with faster water velocities, while ground speed remained constant, supporting the hypothesis that lampreys regulate swim effort to maintain a fixed migration pace. The average ground speed aligned with a predicted optimum of ∼1 body length per second. Both swim and ground speeds declined slightly in deeper water, suggesting a trade-off between movement efficiency and predator avoidance. These findings provide field-based support for a theoretical model of energy optimization and underscore how migratory fish adaptively adjust behavior to local hydrodynamic conditions. Our results highlight the value of using high-resolution tracking and environmental modeling to reveal behavioral tactics that underlie efficient migration strategies.

Michigan

The role of groundwater in contributing to surface water salinization in the Upper Colorado River Basin

Freshwater salinization impacts the availability of water for human use and ecosystem needs worldwide. It has been estimated that total dissolved solids (TDS) in the Colorado River Basin cause $350 million/year in damages and substantial resources are devoted to reducing TDS loading to streams. This study describes the development and application of coupled watershed models that enable TDS source tracking through the subsurface and across the landscape at a seasonal timestep for 35 years in the Upper Colorado River Basin. Results indicate that, on average, 75% of TDS loading to streams originates as baseflow, and 50% of loading is lagged in delivery by longer than one season. Snowmelt was identified as a dominant process controlling the transport of lagged TDS to streams. This approach informs when and where TDS mitigation efforts may be effective in a watershed that serves as a critical water supply for the southwestern United States.

Arizona, Colorado, New Mexico, Utah, Wyoming

Comparison of two approaches for determining ground-water discharge and pumpage in the lower Arkansas River Basin, Colorado, 1997-98

In March 1994, the Colorado Division of Water Resources (CDWR) adopted “Rules Governing the Measurement of Tributary Ground Water Diversions Located in the Arkansas River Basin” (Office of the State Engineer, 1994); these initial rules were amended in February 1996 (Office of the State Engineer, 1996). The amended rules require users of wells that divert tributary ground water to annually report the water pumped monthly by each well. The rules allow a well owner to report the pumpage measured by a totalizing flowmeter (TFM) or pumpage determined from electrical power data and a power conversion coefficient (PCC) (Hurr and Litke, 1989). Opinions by representatives of the State of Kansas, presented before the Special Master hearing a court case [State of Kansas v. State of Colorado, No. 105 Original (1996)] concerning post-Compact well pumping, stated that the PCC approach does not provide the same level of accuracy and reliability as a TFM when used to determine pumpage. In 1997, the U.S. Geological Survey (USGS), in cooperation with the CDWR, began a 2-year study to compare ground-water pumpage estimates made using the TFM and the PCC approaches. The study area was along the Arkansas River between Pueblo, Colorado, and the Colorado-Kansas State line (fig. 1). The two approaches for estimating ground-water discharge and pumpage were compared for more than 100 wells completed in the alluvial aquifer of the Arkansas River Basin. The TFM approach uses an inline flowmeter to directly measure instantaneous discharge and the total volume of water pumped at a well. The PCC approach uses electrical power consumption records and a power conversion coefficient to estimate the pumpage at ground-water wells. This executive summary describes the results of the comparison of the two approaches. Specifically, (1) the differences in instantaneous discharge measured with three portable flowmeters and measured with an inline TFM are evaluated, and the statistical differences in paired instantaneous discharge between the two approaches are determined; (2) short- and long-term variations in the PCC’s are presented; (3) differences in pumpage between the two approaches are evaluated, and the statistical differences in pumpage between the two approaches are determined; (4) potential sources of discrepancy between pumpage estimates are discussed; and (5) differences in total network pumpage using the two approaches are presented. During the irrigation seasons of 1997 and 1998, instantaneous discharge and electrical power demand were measured at randomly selected wells to determine PCC’s. At more than 100 wells, the PCC’s determined during the 1998 season were applied to total electrical power consumption data that was recorded between the initial and final readings at each network well site in 1998 to estimate total ground-water pumpage. At each site, an inline TFM was installed in a full-flowing, acceptable test section of pipe on the discharge side of the pump where the measurement of discharge was made. Measurements of instantaneous ground-water discharge also were made using three different types of portable flowmeters. The average velocity multiplied by the cross-sectional area of the discharge pipe was used to compute the discharge in gallons per minute. Whenever possible, discharge measurements were made at each network site using all three types of portable flowmeters.

Colorado

The water quality of Livingston Reservoir on the Trinity River, Southeastern Texas

The concentrations of dissolved solids, chloride, and sulfate in Livingstone Reservoir on the Trinity River in southeastern Texas usually average less than 250 mg/1 (milligrams per litre), 40 mg/1, and 50 mg/1, respectively. The water is usually hard or moderately hard (61 to 180 mg/1 as calcium carbonate). The concentrations of principal dissolved constituents in the reservoir are usually maximum during summer and fall when evaporation is high and inflow is low. Thermal stratification of the reservoir usually begins in March and persists until September or October. Neither the seasonal variation of dissolved constituents in inflow to the reservoir nor thermal stratification has resulted in significant stratification of the principal dissolved constituents. However, thermal stratification has resulted in significant seasonal and areal variations of dissolved oxygen, which results in higher concentration of dissolved iron, dissolved manganese, total phosphorus, and total inorganic nitrogen.

Texas

Beyond optimality: Dryland ecosystems infrequently use water efficiently for carbon gain

Optimality theory assumes plants maximize carbon gain per unit water lost and is often implemented to scale leaf-level carbon gain and water use to regional and global scales. Optimality theory is often mathematically represented by assuming plant water-use efficiency (WUE) scales with VPD k , where k = ½ represents expected optimal behavior. It is unclear, however, if this relationship holds in arid and semi-arid ecosystems that are strongly impacted by soil and atmospheric moisture status. We used data from seven flux tower sites along an aridity gradient in New Mexico to answer: how does the relationship between WUE and VPD compare to expectations based on optimality theory? To address this question, we integrated the Dynamic Evapotranspiration Partitioning Approach for Rapid Timescales with a stochastic antecedent model to estimate ecosystem-level WUE (GPP/T) and the net sensitivity of WUE to VPD, or k Dynamic , which we compare to the theoretical optimal sensitivity of k = ½. Our results show that optimality theory is not always appropriate, and k Dynamic often deviates from ½, especially at some of the more arid sites or during periods of low soil moisture. At less arid, higher elevation sites, k Dynamic is most consistent with optimality theory at moderate VPD levels, but not at high VPD. In general, the sensitivity of WUE to VPD is highly variable such that k Dynamic exhibits notable daily and seasonal variability, suggesting highly dynamic stomatal behavior. These results emphasize that representing plant water-use strategies as dynamic in time and space is critical to improving large-scale estimates of plant water use.

New Mexico

Simulated effects of future water availability and protected species habitat in a perennial wetland, Santa Barbara County, California

This study evaluates the potential water availability in Barka Slough and the effects of changing hydrological conditions on the aquatic habitat of five protected species. Barka Slough is a historically perennial wetland at the downstream western end of the San Antonio Creek Valley watershed (SACVW). A previously published hydrologic model of the SACVW for 1948–2018 was extended to include 2019–2021 and then modified to simulate the future years of 2022–2051. Two models simulating the future years of 2022–2051 were constructed, each with different climate inputs: (1) a repeated historical climate and (2) a 2070-centered Drier Extreme Warming climate (2070 DEW). The model with the 2070 DEW climate had warmer temperatures and an increase in average annual precipitation driven by larger, albeit more infrequent, precipitation events than the model with the historical climate. Simulated groundwater pumpage resulted in cumulative groundwater storage depletion and groundwater-level decline in Barka Slough in both future models. The simulations indicate that Barka Slough may transition from a perennial to an ephemeral wetland. Streamflow, stream disconnection, and depth to groundwater are key habitat metrics for federally listed species in Barka Slough. Future seasonal conditions for each metric are more likely to affect federally listed species’ habitats under 2070 DEW climatic conditions. Future seasonal streamflow volume may negatively impact unarmored threespine stickleback ( Gasterosteus aculeatus williamsoni ) and tidewater goby ( Eucyclogobis newberryi) habitats. Future seasonal stream disconnection may negatively impact the unarmored threespine stickleback habitat. Future groundwater-level decline may negatively impact Gambel’s watercress ( Nasturtium gambelii ) and La Graciosa thistle ( Cirsium scariosum var. loncholepis ) habitats and could influence the ability to use Barka Slough as a restoration or reintroduction site for these species. Results from this study can be used to inform water management decisions to sustain future groundwater availability in the SACVW.

California

Taking heat (downstream): Simulating groundwater and thermal equilibrium controls on annual paired air–water temperature signal transport in headwater streams

Headwater stream temperature often exhibits spatial variation at the kilometer-scale, but the relative importance of the underlying hydrogeological processes and riverine perturbations remains poorly understood. In this study, we investigated the relative importance of groundwater (GW) and other processes on downstream annual stream temperature signal characteristics using deterministic heat budget model (HFLUX) scenarios within an idealized stream reach representative of mountainous forested conditions. We summarized annual stream thermal regimes from the relationship of paired sinusoidal air and water temperature signals (amplitude ratio, phase lag, and mean ratio). Results showed that downstream changes in annual temperature depended on the thermal gradient between water and the hypothetical equilibrium temperature (where all heat fluxes sum to zero). GW inflow, riparian shading, and the boundary input signal were the most significant factors affecting downstream annual water temperature signals, while flow volume and channel dimensions impacted how quickly annual temperature signals changed. Effects of GW were dominated by advective rather than conductive heat exchange processes, but conduction played a larger role when GW input was more spatially diffuse. Our results indicated several mechanisms by which local processes may affect stream thermal resilience to disturbances and can help guide management of wildfire and climate change.

Journal of Hydrology

Perchlorate, metals, organic compounds, and lead isotopes in groundwater, surface water, shallow groundwater, and soil within and near the Middleton Municipal Airport–Morey Field (C29), Middleton, Wisconsin, 2022

The Middleton Municipal Airport–Morey Field (C29) is in the City of Middleton and adjacent to the towns of Middleton and Springfield, Wisconsin. Nearby homes in the towns rely on private drinking water wells, and residents are concerned about the potential contamination of groundwater and surface water by airport activities, including flights by small aircraft that use leaded aviation fuel and a fireworks display in July 2021. The U.S. Geological Survey, in cooperation with the Town of Middleton, completed a study in 2022 to characterize the occurrence and sources of perchlorate, metals (including lead), and organic compounds in samples of groundwater, surface water, shallow groundwater, and soils within and near the airport. Lead isotopes were also measured to determine sources of lead by comparing samples to environmental references. Magnitudes of concentrations from samples of water and soil collected in 2022, and their spatial patterns across site locations, indicate the fireworks display in July 2021 was a likely source of perchlorate and metals in the airport study area. The highest perchlorate concentration was measured in surface water at the southeastern corner of the airport near the fireworks launch site; the highest concentrations of fireworks-associated metals were measured in shallow groundwater near the same location. Fireworks were not the only possible source of perchlorate and metals in the airport study area because both were also detected upgradient and away from the fireworks launch site. Ratios of lead isotopes indicate that lead measured in water and soil within the airport study area was primarily sourced from background atmospheric lead deposition or Wisconsin galena lead ore. However, two groundwater samples (one upgradient and one downgradient from the airport; both with concentrations less than 1 microgram per liter) had isotopic signatures matching leaded aviation fuel sold at the airport.

Wisconsin

Solute transport and modeling of water quality in a small stream

An injection of chloride, sodium, and stable strontium was made at a constant rate for 3 hours into Uvas Creek, Santa Clara County, Calif., to determine the mass transport processes in a small stream. Five observation points were selected within a 610-metre reach of the stream below the injection site. Water samples were collected at the observation points during and immediately after the injection. A mathematical model of the stream was obtained by solving analytically and optimally the one-dimensional mass transport equation of the solutes in the stream. Comparison of field results with a simplified mathematical model indicates the dominance of convection in the behavior of sodium and chloride. The concentration of chloride and sodium can be closely simulated by the model. However, strontium cannot be well represented by the simplified model, which contains a first-order decay-type sink.

California

Assessing the state of hydrologic science in the Upper Klamath Basin—A comprehensive review of data, tools, and models

Water demand in the Upper Klamath Basin (UKB) from various stakeholders and ecological needs often outstrips available supply, leading to persistent management challenges. This study reviews the state of hydrologic science within the UKB as of 2025—specifically, the tools, data, and models available for assessing five key components of the water system: (1) surface water; (2) precipitation; (3) evapotranspiration; (4) groundwater; and (5) water use. The UKB water supply is critical for Native American communities, regional agriculture, and federally listed fishes and faces challenges from competing needs, climate variability, and operational/regulatory requirements. We assess existing datasets, regional and national models, and historical studies to understand the available resources and identify gaps that may hinder integrated water assessments and management. Our findings indicate areas where improvements in data collection and model precision could improve the accuracy of water-availability forecasts and support water-management practices. This review can inform near-term forecasting, assist in optimizing water-resource data collection and management strategies, and support regional water-availability assessments of the basin.

Oregon

Projecting stream water quality using Weighted Regression on Time, Discharge, and Season (WRTDS): An example with drought conditions in the Delaware River Basin

Future water availability depends on understanding the responses of constituent concentrations to hydrologic change. Projecting future water quality remains a methodological challenge, particularly when using discrete observations with limited temporal resolution. This study introduces Weighted Regression on Time, Discharge, and Season for Projection (WRTDS-P), a novel, computationally efficient method that enables the projection of daily stream water quality under varying hydrologic conditions using commonly available discrete monitoring data. WRTDS-P model performance was validated using 39 sites in the Delaware River Basin (DRB) and four key constituents: specific conductance (SC), nitrate (NO 3 − ), magnesium (Mg 2+ ) and calcium (Ca 2+ ). Projections were tested against holdout data from the final 1 to 5 years of each time series, demonstrating robust predictive capability, with median Nash-Sutcliffe efficiencies of 0.67 for SC, 0.56 for NO 3 − , 0.65 for Ca 2+ , and 0.79 for Mg 2+ . Model uncertainty was correlated with indicators of hydrologic or geochemical mass-sinks, such as groundwater storage and adsorption in wetland soils. Drought scenario analyses for SC used ranges of reduced discharge including flows from the 1965 drought of record. Scenarios predicted widespread increases of SC, especially in southern DRB streams where baseline SC levels are already elevated. Fractional increases of SC were more uniformly distributed, indicating potential risk to sensitive ecosystems. Notably, drought-induced SC increases were positively correlated with interannual SC trends, indicating that hydrologic extremes could exacerbate ongoing salinization. This work provides a transferable and interpretable framework for projecting future water quality and assessing hydrologic risk to water resources and aquatic ecosystems.

Delaware, New Jersey, New York, Pennsylvania

Comparison of water quality in shallow groundwater near agricultural areas in the Delaware Coastal Plain, 2014 and 2019

The State of Delaware has encouraged agricultural conservation practices to improve nutrient uptake by crops and mitigate nutrient transport to groundwater in the surficial aquifer. To study recent changes in groundwater quality, the U.S. Geological Survey and the Delaware Department of Agriculture (DDA) developed a network of shallow wells near agricultural areas throughout the Delaware Coastal Plain. This network was designed to characterize water quality related to agricultural practices and to detect any recent changes in shallow groundwater quality, in particular groundwater nitrate concentrations. The shallow well network was first sampled in 2014 and resampled in 2019. In 2019, field parameters (including dissolved oxygen, pH, specific conductance, and temperature), major ions, nutrients, stable isotopes of water, and isotopes of nitrate were measured in groundwater samples collected between October and December. Wells were organized into three groups based on their geochemical characteristics measured in 2014: the Agricultural, Urban, and Mixed Groups. Results from the 2019 sampling showed little change in water quality from the 2014 sampling. Land-use factors continued to be the driving influence between groups. Groundwater moves slowly and changes in groundwater quality are likely to respond slowly to changes in conservation practices. Continued sampling of both groundwater quality in this network and monitoring land management practices can help detect groundwater quality trends in the future.

Delaware

Application of acoustical methods for estimating water flow and constituent loads in Perdido Bay, Florida

Water flow and quality data were collected from December 1994 to September 1995 to evaluate variations in discharge, water quality, and chemical fluxes (loads) through Perdido Bay, Florida. Data were collected at a cross section parallel to the U.S. Highway 98 bridge. Discharges measured with an acoustic Doppler current profiler (ADCP) and computed from stage-area and velocity ratings varied roughly between + or - 10,000 cubic feet per second during a typical tidal cycle. Large reversals in flow direction occurred rapidly (less than 1 hour), and complete reversals (resulting in near peak net-upstream or downstream discharges) occurred within a few hours of slack water. Observations of simultaneous upstream and downstream flow (bidirectional flow) were quite common in the ADCP measurements, with opposing directions of flow occurring predominantly in vertical layers. Continuous (every 15 minutes) discharge data were computed for the period from August 18, 1995, to September 28, 1995, and filtered daily mean discharge values were computed for the period from August 19 to September 26, 1995. Data were not computed prior to August 18, 1995, either because of missing data or because the velocity rating was poorly defined (because of insufficient data) for the period prior to landfall of hurricane Erin (August 3, 1995). The results of the study indicate that acoustical techniques can yield useful estimates of continuous (instantaneous) discharge in Perdido Bay. Useful estimates of average daily net flow rates can also be obtained, but the accuracy of these estimates will be limited by small rating shifts that introduce bias into the instantaneous values that are used to compute the net flows. Instantaneous loads of total nitrogen ranged from -180 to 220 grams per second for the samples collected during the study, and instantaneous loads of total phosphorous ranged from -10 to 11 grams per second (negative loads indicate net upstream transport). The chloride concentrations from the water samples collected from Perdido Bay indicated a significant amount of mixing of saltwater and freshwater. Mixing effects could greatly reduce the accuracy of estimates of net loads of nutrients or other substances. The study results indicate that acoustical techniques can yield acceptable estimates of instantaneous loads in Perdido Bay. However, estimates of net loads should be interpreted with great caution and may have unacceptably large errors, especially when saltwater and freshwater concentrations differ greatly.

Florida

Water-quality assessment of south-central Texas — Descriptions and comparisons of nutrients, pesticides, and volatile organic compounds at three intensive fixed sites, 1996-98

Water-quality samples were collected during April 1996-April 1998 at three intensive fixed sites in the San Antonio region of the South-Central Texas study unit as part of the U.S. Geological Survey National Water-Quality Assessment Program. The sampling strategy for the intensive fixed-site assessment is centered on obtaining information about the occurrence and seasonal patterns of selected constituents including nutrients, pesticides, and volatile organic compounds. The three sites selected to determine the effects of agriculture and urbanization on surface-water quality in the study unit are Medina River at LaCoste (agriculture indicator site), Salado Creek (lower station) at San Antonio (urban indicator site), and San Antonio River near Elmendorf (integrator site). Concentrations of two nutrients, dissolved nitrite plus nitrate nitrogen and total phosphorus, were largest at the integrator site, which is downstream of municipal wastewater treatment plants. Nitrite plus nitrate nitrogen concentrations at this site often exceeded the U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL) for drinking water. All total phosphorus concentrations at the site exceeded the EPA recommended maximum concentration for streams not discharging directly into reservoirs. Nitrite plus nitrate nitrogen concentrations at the integrator site tended to be smaller, and total phosphorus concentrations at the urban site tended to be larger in samples collected during stormflow than during base flow. The most detections and largest concentrations of three pesticides (atrazine, diazinon, and prometon) were in samples collected at the urban site. Some pesticide concentrations at the agriculture site showed a seasonal pattern of increasing concentrations during spring, the peak application season. Four pesticides (atrazine, deethylatrazine, diazinon, and prometon) were detected in at least 38 percent of samples collected at all three sites. The concentrations of all detected pesticides that have an MCL were less than the MCL at the three sites. More volatile organic compounds (VOC) were detected at the urban indicator site than at the agriculture indicator site, mostly likely because more sources are located in urbanized areas. The most VOCs detected and the largest concentrations of two VOCs (chloroform and tetrahydrofuran) were in samples from the integrator site. More VOCs were detected in samples collected at the integrator site during stormflow than during base flow. The concentrations of all detected VOCs that have an MCL were less than the MCL at the three sites.

Texas

Groundwater and surface-water interactions in the Lower Duwamish Waterway, Seattle, Washington

The U.S. Geological Survey (USGS), in cooperation with the Washington State Department of Ecology (Ecology), conducted a study to describe the current understanding of the regional groundwater system of the lower Duwamish River valley and groundwater and surface-water interactions in the lower Duwamish Waterway. The lower Duwamish Waterway is the final 5-mile (mi) reach of the Duwamish River before it empties into Elliott Bay in Puget Sound near Seattle, Washington. A nearshore site (hereinafter referred to as “Nearshore Site” to distinguish the particular site from general discussions of nearshore areas) along the western shoreline of the Duwamish River, about 1.5 mi upstream from the river mouth, was selected for focused groundwater data collection by USGS. Data loggers were deployed in seven groundwater wells and one stilling well in the Duwamish River to measure specific conductance, temperature, and depth at 15-minute intervals for a period of about 2 years. At the Nearshore Site during 2020–22, water levels in the shallow wells were 3–8 feet (ft) higher than water levels in the deep wells, providing evidence for a low-permeability layer between the shallow and deep aquifers in this area. The shallow wells had a pronounced seasonal variability, with high water levels in winter and low water levels in summer. Data from the deep wells showed far less seasonal variability, with slight increases in winter and a near-constant water level from spring to autumn. The deep wells had a strong hydraulic connection to the Duwamish River, as evidenced by the synchronous water-level variability during the tidal cycle, whereas the shallow wells had minimal to no tidal response. The potentiometric maps developed for the Nearshore Site and surrounding areas indicate large differences in groundwater-flow directions for the shallow and deep aquifers at low and high tides. For the shallow aquifer, flow is toward the lower Duwamish Waterway near the Nearshore Site, regardless of the tidal condition. For the deep aquifer, a potentiometric trough forms parallel to the shoreline during high tide, indicating that groundwater flow converges from the uplands to the west and the Duwamish River to the east. The geometry of the potentiometric surfaces between the nearshore-most well and the shoreline is complex and is further confounded by intermittent shoreline armoring and other buried infrastructure, which could serve as either a barrier or a conduit to flow. Groundwater and surface-water interactions in the lower Duwamish Waterway are inherently complex as a result of three overarching factors. First, water levels in the lower reaches of the Duwamish River vary daily by 11–16 ft because of tides from Puget Sound, which create large swings in the hydraulic gradient in the nearshore groundwater system. Second, the density and chemical composition of water in the Duwamish River change daily with the tides and seasonally, which constrains how river water entering the nearshore sediments interacts with discharging groundwater. Third, the nearshore subsurface and shoreline conditions are heterogenous because of extensive shoreline armoring over the past century, which governs the flow of groundwater and infiltrating river water. These unique features of groundwater and surface-water interactions in the lower Duwamish Waterway thus govern the transport of terrestrial contaminants to the lower Duwamish Waterway. Furthermore, the heterogenous aquifer properties in the lower Duwamish Waterway contribute to spatially and temporally dynamic contaminant-transport processes.

Washington

Water-quality study of a reach of the Merced River in Yosemite National Park and vicinity, California, April 1973 through September 1974

A 25-mile (40-kilometre) reach of the Merced River was studied to provide the National Park Service with water-quality data prior to the operation of a new sewage-treatment plant. Data were collected periodically at four Merced River and two inflow stations. Discharge varied seasonally with highest flow occurring at the time of spring snowmelt runoff. Lowest flow occurred during late summer, coinciding with high park visitor use and elevated water temperature. Water-quality variables investigated were discharge, temperature, major chemical constituents, selected trace metals, specific conductance, suspended sediment, turbidity, dissolved oxygen, pH, alkalinity, carbon dioxide, total organic carbon, nitrogen, phosphorus, algal growth potential, coliform bacteria, periphyton, and benthic invertebrates. Diel measurements were made at some stations to delineate daily fluctuations in selected water-quality variables. Results indicate that water in the reach of the Merced River studied was of good quality. The river had low concentrations of dissolved solids (8 to 41 milligrams per litre) and low alkalinity values (2 to 24 milligrams per litre of alkalinity as CaCO 3 ). Mean concentrations of nitrogen and phosphorus were highest in the Merced River at Rancheria Flat. Algal growth potential tests showed that phosphorus was limiting algal growth at Happy Isles Bridge, El Capitan Bridge, and South Fork Merced River, whereas nitrogen was limiting growth at Rancheria Flat. Input of excessive nitrogen and phosphorus concentrations in the Merced River during the summer low-flow period, and mixing with warm tributary inflow could cause excessive algal growth and production. The algal types found were diatoms, green algae, and blue-green algae. Biomass/chlorophyll a ratios in the Merced River were low (0.3 to 7.7). Benthic invertebrates consisted chiefly of Diptera, Ephemeroptera, and Plecoptera.

California

Per- and polyfluoroalkyl substances in waters associated with oil and gas development in the Denver Basin

Use of per- and polyfluoroalkyl substances (PFAS) in the petroleum industry could be a cause for concern due to the large volumes of produced water (PW) generated during oil and gas extraction, the reuse of these wastes in water-stressed regions, and adverse health outcomes related to PFAS exposures. However, PW PFAS characterization is nearly absent in the literature, and hydraulic fracturing (HF) chemical disclosures often omit the identities of additives as proprietary. Here we evaluate PFAS in PW samples from three petroleum wells in the Denver Basin during their first year of production. Total concentrations of targeted PFAS (Σ 40 PFAS) were < 35 ng/L in PW samples, with short-chain PFAS like perfluorobutanoic acid persisting throughout the sampled duration. Analysis of freshwater inputs for hydraulic fracturing (Σ 40 PFAS ~ 113 ng/L) and mixed fracture fluid (Σ 40 PFAS ~ 69 ng/L) indicated much of the targeted PFAS content was derived from the input water, and not from HF additives, however samples subjected to oxidation indicated the presence of PFAS precursors that would not be detected by targeted analysis. This study highlights that while PFAS content is low in the studied PWs, the potential for redistribution of PFAS in the environment may be a consideration for reuse applications.

Colorado, Nebraska, Wyoming