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Iron sulfide minerals at Cement oil field, Oklahoma: Implications for magnetic detection of oil fields

Aeromagnetic anomalies at Cement oil field (Anadarko basin, Oklahoma) have been attributed to authigenic magnetite. The following characteristics of the magnetite, however, indicate that it is contamination introduced by drilling: (1) occurrence as sharp angular blades and as spheres, commonly with metallographic textures typical of industrial alloys and with associated steel and wustite (FeO); (2) presence only in well cuttings and absence from core and quarry samples; and (3) lack of association with detrital framework grains or with authigenic carbonate and sulfide minerals. Ferrimagnetic pyrrhotite occurs in well cuttings, cores, and quarry samples at Cement and is a possible natural source of the magnetic anomalies. Pyrrhotite, which is intergrown with more abundant FeS 2 minerals, formed as a result of hydrocarbon seepage. Pyrrhotite is confined to beds above oil and gas reservoirs. These beds, which lack detrital organic matter, contain higher mineral sulfide and lower mineral sulfate sulfur (1.7 and 0.1 wt %, respectively) than do correlative beds off the field (0.2 and 1.1 wt %, respectively). In the field, isotopic values of sulfide S show a systematic decrease upward through the Permian section from positive values (maximum, +12 per mil at ∼610-760 m depth) to negative values (-1 to -11 per mil between 32 and 230 m; -26 to -30 per mil at the surface). Geochemical results, together with time-temperature data derived from burial curves, limit the major sources of the sulfide in the Fe-S minerals to two possibilities. Isotopically heavy sulfide was generated either inorganically at temperatures >∼90 °C in beds beneath Permian beds, or by bacterial sulfate reduction at temperatures <∼60 °C in Permian strata. If the latter, microbial sulfate reduction occurred under sulfate-limited conditions. The isotopically light sulfide occurring in minerals near the present surface is attributed to bacterial reduction of sulfate. Sulfate-reducing bacteria derived metabolic energy from leaking hydrocarbons and associated organic compounds.

Oklahoma

USGS research on energy resources, 1986; program and abstracts

The extended abstracts in this volume are summaries of the papers presented orally and as posters in the second V. E. McKelvey Forum on Mineral and Energy Resources, entitled "USGS Research on Energy Resources-1986." The Forum has been established to improve communication between the USGS and the earth science community by presenting the results of current USGS research on nonrenewable resources in a timely fashion and by providing an opportunity for individuals from other organizations to meet informally with USGS scientists and managers. It is our hope that the McKelvey Forum will help to make USGS programs more responsive to the needs of the earth science community, particularly the mining and petroleum industries, and Win foster closer cooperation between organizations and individuals. The Forum was named after former Director Vincent E. McKelvey in recognition of his lifelong contributions to research, development, and administration in mineral and energy resources, as a scientist, as Chief Geologist, and as Director of the U.S. Geological Survey. The Forum will be an annual event, and its subject matter will alternate between mineral and energy resources. We expect that the format will change somewhat from year to year as various approaches are tried, but its primary purpose will remain the same: to encourage direct communication between USGS scientists and the representatives of other earth-science related organizations. Energy programs of the USGS include oil and gas, coal, geothermal, uranium-thorium, and oil shale; work in these programs spans the national domain, including surveys of the offshore Exclusive Economic Zone. The topics selected for presentation at this McKelvey Forum represent an overview of the scientific breadth of USGS research on energy resources. They include aspects of petroleum occurrence in Eastern United States rift basins, the origin of magnetic anomalies over oil fields, accreted terranes and energy-resource implications, coal quality, geothermal energy sources, integrated geology and chemistry in uranium-deposit studies, and interpretations of sea-floor geology seen in reconnaissance-scale sidescan-sonar mosaics of the Gulf of Mexico and west coast Exclusive Economic Zone. Data are presented that are being used in building models of geothermal energy settings, basin histories, and the occurrence of energy resources. In addition to the technical sessions presenting the results of USGS research, each congressionally mandated USGS Mineral Resource Program has a display outlining plans and progress. We are all excited about this continuing opportunity to disseminate and discuss our research with our colleagues in industry and academia, and we welcome your suggestions on improving this series of Forums.

Circular

A methodology to assess the historical environmental footprint of in-situ recovery (ISR) of uranium: A demonstration in the Goliad Sand in the Texas Coastal Plain, USA

In-situ recovery (ISR) has been the only technique used to extract uranium from sandstone-hosted uranium deposits in the Pliocene Goliad Sand in the Texas Coastal Plain. Water plays a crucial role throughout the ISR lifecycle of production and groundwater restoration yet neither the water use nor other environmental footprints have been well documented. The goal of this study is to examine historical records for all six ISR operations completed in the Goliad Sand to identify and quantify parameters that indicate the surface and aquifer disturbances, water use, and radon emissions. Overall, the average mine area was 0.00023 ± 0.00006 acres per pound (ac/lb) U 3 O 8 . The average mine pore volume was 48.9 ± 50 gal/lb U 3 O 8 with a minimum affected aquifer volume of 0.51 ± 0.08 cubic feet per pound (cu ft/lb) U 3 O 8. An average of 258 ± 40 gallons (gal) of fluid were disposed per pound (lb) U 3 O 8 , with an average of 169 ± 26 gal/lb U 3 O 8 attributed to restoration and 89 ± 36 gal/lb U 3 O 8 attributed to the uranium production phase. The average radon emitted was 1.06 × 10 −3 ± 7.4 × 10 −4 curies per pound (Ci/lb) U 3 O 8 . Goodness-of-fit ( R 2 ) values are ≥0.79 for linear regressions of the amount of uranium produced versus mine area, mine pore volumes, mine aquifer volumes, water pumped, and total water disposed. The R 2 value for radon emitted was 0.68. However, the water disposed only during the uranium production phase is more strongly correlated to the number of production days ( R 2 = 0.96) than to uranium production ( R 2 = 0.84), whereas the volume of water disposed during restoration is more strongly correlated to the “pore volume” ( R 2 = 0.97) than to uranium production ( R 2 = 0.90). Pore volume is an industry term used to describe the amount of fluid circulated through the aquifer during the uranium production period and stipulated in bond agreements in order to satisfy groundwater restoration requirements. Models constructed in this study can be used to estimate probable water use and the extent of surface and aquifer disturbances associated with ISR-amenable undiscovered uranium resources in the Goliad Sand. The historical perspective offered by the data compiled and correlations may prove useful to both industry and regulators.

Texas

Swatara Creek basin of southeastern Pennsylvania: An evaluation of its hydrologic system

Local concentrations of population in the Swatara Creek basin of Pennsylvania find it necessary to store, transport, and treat water because local supplies are either deficient or have been contaminated by disposal of wastes in upstream areas. Water in the basin is available for the deficient areas and for dilution of the coal-mine drainage in the northern parts and the sewage wastes in the southern parts. Swatara Creek drains 576 square miles just east of Harrisburg, Pa., and is the largest tributary to the Susquehanna River from the north side below Harrisburg. It rises in the southern Pocono Mountains and flows southwestward across the Lebanon Plateau. On an average day Swatara Creek discharges more than 630 million gallons into the Susquehanna River at Middletown, Pa. In a year this amounts to about 23 inches of water over the entire basin and is the residual from an average annual precipitation of 45.5 inches. During an average year the flow in Swatara Creek from the upper third of the basin above Harper Tavern is always greater than 1,300 mgd (million gallons per day) for at least 15 days and is always greater than 25 mgd for at least 350 days. The daily streamflow from the basin averages 1.1 mgd per sq mi, but yields from different areas range from 0.97 to 1.22 mgd per sq mi. These variations are caused chiefly by differences in precipitation and land cover. The area of lowest yield is in the valleys west of Tremont, and the highest yields are in the Upper and Lower Little Swatara Creek subbasins. At high and medium stages the chemical character of the water in the streams is suitable for public and private supplies. At lower stages, defending on the areas and the amounts of contamination by coal-mine drainage and sewage pollution, the natural flow may require some treatment. At low stages the chemical characteristics of the natural flow not affected by man is almost identical with that of the ground water in the area drained by the stream. In general, the total dissolved solids range from about 25 to 400 parts per million and the hardness is as much as about 300 parts per million. The ground-water increment to the base flow of Swatara Creek averages about 240 mgd, or about 8.8 inches annually, for the basin. Generally, ground-water supplies in amounts of less than 0.5 mgd can be developed south of Blue Mountain. Supplies of several million gallons per day have been developed for industrial use from the permeable limestones in the south-central part of the basin. More intensive investigation in other parts of the basin would indicate areas where supplies of more than 0.5 mgd could be developed from properly spaced wells. The chemical character of water from wells depends largely on the host rock. In highly soluble rocks water contains large amount of dissolved solids; in more resistant rocks concentrations are lower. The chemical character of unpolluted ground water generally reflects the composition of the more readily soluble minerals in the local geologic environment. Areas contaminated by septic- tank effluent may have above normal amounts of nitrate and detergent products. Except where polluted, most ground water is suitable for public and industrial uses without extensive treatment. Sites for storage of surface water exist in the part of the basin lying in the valley and ridge area. As much as 30 to 40 percent of the annual flow could be impounded for release as low-flow augmentation for dilution of mine drainage and other wastes in the basin. Low sediment yields of supplying drainage areas would ensure a long life expectancy of reservoirs at these sites. Overbank flooding of the main stem of the Swatara Creek and its tributaries has occurred many times in the past. However, it has not been a hazard because urban development has not encroached on the flood plain. An inundation map of the August 1933 flood provides a basis that urban planners may use to avoid future damage. As water in the Swatara Creek moves downstream to the Susquehanna River, the flow is influenced consecutively by a large annual rainfall on the northern valley and ridge area, the wastes of surface and subsurface coal-mining activities, and less annual rainfall on the part of the basin lying in the Lebanon Plateau area; the flow is supplemented and further influenced by many tributaries and by the industrial and domestic wastes that are carried by these secondary streams. The annual precipitation ranges from 52 inches at the east edge and 49 inches at the west edge of the mountainous part of the basin to about 41 inches at the southwestern part at Middletown. The rainfall generally is adequate during the growing season to mature the crops. The mean annual temperature at Lebanon is about 52&deg;F, and the growing season is about 180 days. In this report the basin has been divided into eight hydrologic zones, leased on runoff, natural use of water, and chemical character of water. Four zones lie in the valley and ridge area, three lie in the Lebanon Plateau area, and one lies in the highland along the southeastern basin boundary. In each of the zones the hydrologic characteristics are virtually the same, but they may be completely different from those in adjacent zones. The boundaries of the zones generally coincide with boundaries between geologic formations, and the areas in each zone include rocks of similar influence on water. Streams in zone 4 at the northeast edge of the plateau have the highest average surface runoff from 1.2 to 1.1 mgd per sq mi whereas those in zone 2 at the northwest edge of the valley and ridge area have the lowest, about 1.0 mgd. Streams in zone 8, along the southeast edge of the basin, have the largest sustained low-flow yield, about 0.26 to 0.19 mgd per sq mi; those in zone 5 overlying the Martinsburg Shale east of Harrisburg have the smallest sustained low-flow yields, 0.03 to 0.01 mgd. Streams in the limestone area of zone 7 have the greatest range in low-flow yields in any one zone from 0.60 to 0 mgd per sq mi. Low-flow yields in zones 1 through 4 range from 0.13 to 0.03 mgd per sq mi. Surface flows from zones 1 and 2 are generally acidic and contain high concentrations of sulfate, iron, and total dissolved solids especially where contaminated with mine wastes. Surface flows from zones 3 and 4 are dilute, slightly alkaline, and suitable for public water supplies. Surface flows from zones 5, 6, and 7 are alkaline and contain moderate concentrations of dissolved solids with waters of highest hardness occurring in zone 7. Surface flows from zone 8 are dilute to moderately mineralized and are relatively high in silica concentration. Nitrate concentrations are high in surf Fee flows below sewage outfalls and in ground water contaminated by septic tank effluent and industrial wastes. Average annual sediment yields of 550 to 650 tons per square mile are characteristic of zones 1 and 2 where strip mining has destroyed the forest cover and coal culm is carried into the streams. From agricultural lands on the Martinsburg Shale in zones 5 and 6, annual sediment yields range from 300 to 350 tons per square mile; but from agricultural lands on the siliceous rocks in zone 8 and zones 3 and 4 in the valley and ridge area, the sediment yield ranges from 200 to 250 tons annually per square mile. Lowest annual sediment yields in the basin are in the forested areas of siliceous rocks in zones 2, 3, 4, and 5, and in the sinkhole topography of the limestones in zone 7 where the yield ranges from 30 to 35 tons and 50 to 60 tons per square mile, respectively. The amount of ground water that can be developed in the basin is dependent on the ability of the underlying rocks to yield water to wells. More than 300 gpm (gallons per minute) can be obtained from wells in alluvial materials in the valley bottoms and in some of the limestones where large solution channels and fractures are penetrated by the wells. From 50 to 300 gpm can be obtained from wells in loosely cemented sandstones and in fractured limestones. From 10 to 50 gpm can be developed from wells in the shales and harder sandstones. The most dense rocks will yield from 1 to 10 gpm from fractures and crevices. Most wells yield water from the upper 350 feet of the formation, for this part contains the most fractures or solution channels. Studies show that the velocity at which a contaminant will move downstream in the basin is related to the discharge of the stream at the time. At a stream discharge of about 400 mgd at Pine Grove, a contaminant in Swatara Creek would require about 40 hours to move from Pine Grove to Middletown. As a result of dispersion and dilution, the maximum concentration of the contaminant at Middletown would be less than 20 percent the concentration at Pine Grove under these conditions. An evaluation of the availability of water in the basin indicates that about I,239 mgd enters as precipitation, 630 mgd leaves as streamflow, 580 mgd is evaporated and transpired, and 56 mgd is diverted for use by man. Not all the diversions for man's use are lost to the basin, as about 27 mgd is returned as sewage for reuse. About one-fourth of the waste water is returned to the ground and the remainder to stream drainageways. Of that diverted by man, 11.6 mgd is used for public supply and 44.4 mgd for industrial and private supplies. Diversions of streamflow furnish 86 percent of the public supply and 27 percent of the industrial supply, and ground-water sources yield the remainder. Municipal and private sewage treatment plants are upgrading the waste water in many places, but no provisions are being made for treatment other than natural dilution and assimilation for the 15 mgd of coal-nine drainage in the northern part of the basin. Technology for economic treatment of mine water is not available at this time, although research in this field is being done. Urbanization eastward from Harrisburg and around Lebanon has increased the population density of the basin. Densities of 500 people per square mile and water use exceeding 2.0 mgd per sq mi can be expected in the future. By the year 2000 the population of the basin may increase 60 percent; and if the per capita rate of use increases 0.5 percent per year the domestic requirements for water will be about two times the present use, or 23 mgd. Similarly, if the present 1:4 ratio of domestic use to industrial use of water continues, at least 89 mgd will be needed for industry in the future. Although an increase to twice the present use of water can be foreseen, or 112 mgd, water for the dilution and assimilation of wastes from treatment systems are not included. Providing water for dilution of wastes from treatment plants has not been a problem, but in the future the amounts needed for this purpose will be greater as the population increases. As water becomes more valuable, treatment of sewage wastes to reduce the biochemical-oxygen-demand load by at least 80 to 90 percent will be necessary to conserve water for more productive uses. As much as 100 mgd may be needed for waste dilution in the basin by year 2000. The present trends in suburban and light industrial development will probably persist in the basin. Problems arising through changes in economic value of water, conflicts in use, and alternatives in development are typical of those confronting the manager of a water-resource system.

Pennsylvania

Remote sensing inventory and geospatial analysis of brick kilns and clay quarrying in Kabul, Afghanistan

Reconstruction and urban development in Kabul, Afghanistan, has prompted vast expansion of the clay quarrying and brick making industry. This study identified the extent and distribution of clay quarrying and brick kilns in the greater Kabul area between 1965 and 2018. Very high-resolution satellite imagery was interpreted to quantify and characterize the type, number, and location of brick kilns for 1965, 2004, 2011, and 2018. Geospatial analysis of kilns together with geologic data and the results of hyperspectral image analysis yielded information regarding the extent of relevant mineral resources. Finally, kernel density analysis of kiln locations for each date called attention to their shifting spatial distribution. The study found that the clay quarrying and brick making industry has expanded exponentially. The type of kilns has transitioned from artisanal style clamp kilns to small-scale Bull’s Trench Kilns (BTK), and ultimately to Fixed Chimney Bull’s Trench Kilns (FCBTK). While quarrying has occurred entirely within quaternary windblown loess and clay deposits, artisanal clamp kilns were located in fine sediments containing montmorillonite and FCBTKs have developed in sediments containing calcite and muscovite. The study’s inventory of kilns was then used to estimate kiln workforce at 27,500 workers and production at 1.579 billion bricks per year.

Kabul

Anthropogenic and natural lead isotopes in Fe-hydroxides and Fe-sulphates in a watershed associated with arsenic-enriched groundwater, Maine, USA

A survey of the natural and anthropogenic sources of lead contributing to secondary minerals in sulphidic schists associated with arsenic-enriched groundwater in Coastal Maine shows that the most likely source is natural Pb, particularly from coexisting sulphide minerals. The secondary minerals also reflect notable contributions from anthropogenic Pb. The Pb isotopes establish pathways by which Pb, and by inference As, could have been transported from As-bearing minerals (arsenian pyrite, arsenopyrite, lollingite, orpiment, arsenic oxide and others), via sulphide oxidation or carbonation reactions into multiple generations of secondary minerals (goethite, hematite, jarosite, natrojarosite and others). Lead isotopic compositions of the sulphides and secondary minerals determined by thermal ionization mass spectrometry ( n =53) range widely. Lead and As contents of the sulphides and secondary minerals overlap, and are generally positively correlated. Pyrite, the dominant sulphide in sulphidic schists associated with As-enriched groundwater in Coastal Maine, has values of 206 Pb/ 204 Pb from 18.186 to 18.391, 207 Pb/ 204 Pb from 15.617 to 15.657, 208 Pb/ 204 Pb from 38.052 to 38.210, 206 Pb/ 207 Pb from c . 1.1625 to 1.1760 and 208 Pb/ 207 Pb from c . 2.4276 to 2.4394. Mixtures of Fe-hydroxide and oxide minerals (predominantly goethite and hematite) and secondary Fe-sulphate minerals (jarosite, natrojarosite, rozenite and melanterite) in the sulphidic schists have overlapping but generally higher values of 206 Pb/ 204 Pb from 18.495 to 19.747 (one sample at 21.495), 207 Pb/ 204 Pb from 15.595 to 15.722 (one sample at 15.839), 208 Pb/ 204 Pb from 38.186 to 39.162, 206 Pb/ 207 Pb from c. 1.1860 to 1.2575 (one sample at 1.3855) and 208 Pb/ 207 Pb from c . 2.4441 to 2.4865 than the sulphides. Sulphides from Zn-Pb metal mines are somewhat less radiogenic than sulphides from the schists. Other sulphides (mostly pyrite) associated with pegmatites and granitic rocks are heterogeneous and more radiogenic than the pyrite-rich sulphidic schists. Sulphides from other regional bedrock units also have heterogeneous isotope values. Lead isotopic compositions of the sulphides from the sulphidic schists and coexisting Fe-oxides and Fe-sulphates produced by weathering and alteration overlap, but the secondary minerals extend toward more radiogenic values that broadly indicate the addition of Pb from anthropogenic origin. As a component of Pb from extensively used arsenical pesticides may also be present in the secondary minerals, the range in Pb isotope values is consistent with multiple sources: natural Pb from the schists and anthropogenic Pb (industrial and possibly from agricultural activities). Contributions from past mining activities or from other bedrock sources are not implicated.

Maine

Anthropogenic vs. natural pollution: An environmental study of an industrial site under remediation (Naples, Italy)

Heavy metal concentrations and Pb isotopic composition were determined in the soils, slags, scums and landfill materials from a shut down industrial (brownfield) site. This was the second largest integrated steelworks in Italy, and is now under remediation by a Government project. It is located in the outskirts of Napoli on the Bagnoli-Fuorigrotta plain (BFP), which is part of the Campi Flegrei (CF) volcanic caldera, where many spas and geothermal springs occur. The purpose of this work is to distinguish the natural (geogenic) component, originated by hydrothermal activity, from anthropogenic contamination owing to industrial activity. 'In-situ sediments' (soils), slags, scums and landfill materials from 20 drill-cores were selected from a network of 197 drills carried out on a 100 ?? 100 m grid, covering the entire brownfield site. In general, heavy metal enrichments in the upper 3 m of the cores strongly suggest mixing between natural (geogenic) and anthropogenic components. Pb isotopic data are suggestive of three potential end members, and confirm the existence of a strong natural component in addition to contamination from anthropogenic activities. The slags, scums and landfill materials have been proved, through mineralogy and leachate experiments, to be geochemically stable; this shows that metal pollutants are not bio-available and, hence, do not pose a risk to future developments on this site. The natural contribution of hydrothermal fluids to soil pollution, in addition to the non-bio-availability of metal pollutants from industrial materials, indicate that heavy metal remediation of soils in this area would be of little use. Continuous discharge from mineralized hydrothermal solutions would cancel out any remediation effort.

Geochemistry: Exploration, Environment, Analysis

Mapping the glacial geology of the Central Great Lakes region in three dimensions: A model for state-federal cooperation

Planners need to evaluate complex and competing public-policy options for managing water, land, and biological resources; they must ensure economic growth, meet the needs of an increasing population, assess hazards, and manage the environment in a sustainable manner. The State Geological Surveys of Illinois, Indiana, Michigan, and Ohio and the U.S. Geological Survey (USGS) receive many requests from local, State, and Federal planners and officials for geologic information. Thick and complex layers of glacial and related sediments blanket the bedrock of these States: a three-dimensional understanding of these deposits is critical to making informed resource-management and other planning decisions. At two recent forums (in Indianapolis, March 1997, and Columbus, Ohio, February 1999), more than 200 attendees from more than 60 local, State, and Federal agencies provided a clear message. They need three-dimensional geologic information to use in making decisions on the following issues: • Quality, quantity, distribution, and accessibility of surface and ground water • Aggregate sources and land-use conflicts • Energy and mineral resource management • Environmental management and mitigation of land and water contamination • Acceleration of the permitting processes of regulatory agencies • Industrial, commercial, residential, and infrastructure siting and construction • Agricultural land loss, erosion, sedimentation, and agrichemical use • Waste-disposal planning and mitigation • Habitat alteration and biodiversity • Coastal erosion, landslides, radon, floods, and earthquakes

Illinois, Indiana, Michigan, Ohio

Global nonfuel mineral exploration trends 2001-2015

This review summarizes significant exploration trends related to active sites and budgets, mineral commodities and regional factors for the years 2001-2015. Data were compiled by specialists in the USGS-NMIC, and reported annually in the USGS-NMIC Minerals Yearbook series and in the May issue of Mining Engineering magazine. External data for these analyses were derived from industry sources, published literature, and SNL Metals & Mining, an offering of S&P Global Market Intelligence (New York, NY).

Mining Engineering

Geologic map of the Dusar area, Herat Province, Afghanistan; Modified from the 1973 original map compilations of V.I. Tarasenko and others

The geologic maps and cross sections presented in this report are redrafted and modified versions of the Geologic map and map of useful minerals of the Dusar area (scale 1:50,000) and Geologic sketch map of the Dusar and Namak-sory ore occurrences (scale 1:10,000), located in the Herat Province, Afghanistan. The original maps and cross sections are contained in unpublished Soviet report no. 0290 (Tarasenko and others, 1973) prepared in cooperation with the Ministry of Mines and Industries of the Royal Government of Afghanistan, in Kabul during 1973 under contract no. 50728. The redrafted maps and cross sections (modified from Tarasenko and others, 1973) illustrate the geological structure and mineral occurrences of the Dusar copper-gold-silver-lead-zinc prospect area of western Afghanistan, located within the Dusar-Shaida copper and tin area of interest (AOI), Herat Province, Afghanistan. Mineralization in the Dusar area is hosted within Early Jurassic to Early Cretaceous stratified volcanic and sedimentary rocks associated with numerous diabase and gabbro-diabase intrusive bodies and is generally near a major northeast-trending system of faults and quartz veins. Host rocks consist of quartz keratophyre and quartz-feldspar porphyry, with layers of schist, phyllite, and quartz-chlorite and chlorite-sericite slate; and limestone and shale, with schist and carbonate-chlorite and chlorite slate. Known mineralization includes an extensive quartz vein system, shown on the map as the “northern occurrence,” as well as the Dusar and Namak-sory gossan zones, interpreted to have formed from remnant pyrite mineralization. The veins of the northern occurrence and their altered host rocks are known to contain anomalous to economic concentrations of precious and base metals, with concentrations locally in excess of 2 parts per million gold, 100 parts per million silver, 5 percent copper, and 1 percent lead. These veins occur in swarms, and are hosted along structures that are approximately concordant with the plane of the metamorphic fabric. The veins consist mostly of quartz, with minor carbonate and sulfide minerals, and display weak alteration halos along their margins. The gossans are locally anomalous in these metals, but their size and extent makes them attractive exploration targets for potential massive sulfide mineralization. The Dusar gossan zone is a massive, ochreous, and siliceous limonitic rock, approximately 2,200 meters long, 30 to 250 meters wide, and 2.0 to 7.2 meters thick. Drilling below the Dusar gossan intersected a siliceous, sericitic, and limonitic rock underlain by quartz keratophyre with abundant disseminated pyrite. Mineralized sections grade 0.06 weight percent copper and up to 0.05 weight percent zinc. The Namak-sory gossan zone contains a similar deposit with anomalous concentrations of copper, zinc, and gold. The redrafted maps and cross sections reproduce the topology of rock units, contacts, and faults of the original Soviet maps and cross sections, and include minor modifications based on examination of the originals and observations made during two brief field visits by USGS staff in August, 2010, and June, 2013.

Dusar Area, Herat Province

Powder X-ray diffraction laboratory, Reston, Virginia

The powder x-ray diffraction (XRD) laboratory is managed jointly by the Eastern Mineral and Environmental Resources and Eastern Energy Resources Science Centers. Laboratory scientists collaborate on a wide variety of research problems involving other U.S. Geological Survey (USGS) science centers and government agencies, universities, and industry. Capabilities include identification and quantification of crystalline and amorphous phases, and crystallographic and atomic structure analysis for a wide variety of sample media. Customized laboratory procedures and analyses commonly are used to characterize non-routine samples including, but not limited to, organic and inorganic components in petroleum source rocks, ore and mine waste, clay minerals, and glassy phases. Procedures can be adapted to meet a variety of research objectives.

Virginia

China, the Democratic Republic of the Congo, and artisanal cobalt mining from 2000 through 2020

From 2000 through 2020, demand for cobalt to manufacture batteries grew 26-fold. Eighty-two percent of this growth occurred in China and China’s cobalt refinery production increased 78-fold. Diminished industrial cobalt mine production in the early-to-mid 2000s led many Chinese companies to purchase ores from artisanal cobalt miners in the Democratic Republic of the Congo (DRC), many of whom have been found to be children. Despite extensive research on artisanal cobalt mining, fundamental questions about its production remain unanswered. This gap is addressed here by estimating artisanal cobalt production, processing, and trade. The results show that, while total DRC cobalt mine production grew from 11,000 metric tons (t) in 2000 to 98,000 t in 2020, artisanal production only grew from 1,000 to 2,000 t in 2000 to 9,000 to 11,000 t in 2020 (with a peak of 17,000 to 21,000 t in 2018). Artisanal production’s share of world and DRC cobalt mine production peaked around 2008 at 18 to 23% and 40 to 53%, respectively, before trending down to 6 to 8% and 9 to 11% in 2020, respectively. Artisanal production was chiefly exported to China or processed within the DRC by Chinese firms. An average of 72 to 79% of artisanal production was processed at facilities within the DRC from 2016 through 2020. As such, these facilities may be potential monitoring points for artisanal production and its downstream consumers. This finding may help to support responsible sourcing initiatives and better address abuses related to artisanal cobalt mining by focusing local efforts at the artisanal processing facilities through which most artisanal cobalt production flows.

PNAS

Mineral resource of the month: sulfur

The article presents information on sulfur. Sulfur is said to be among the few solid elements found in elemental form in nature and has industrial uses. Changes in the sulfur production process over the years are discussed as well as the mining process developed by German engineer Herman Frasch that involves melting the sulfur underground and pumping it to the surface.

Earth

World minerals outlook—Cobalt, gallium, helium, lithium, magnesium, palladium, platinum, and titanium through 2029

Given the rapid expansion in the demand for mineral commodities that underpin worldwide economic growth and technological advancement, information regarding expected country-level mine production and production capacity is becoming increasingly important to industry stakeholders, end users, and policymakers. Production capacity can limit future supply, depending on how rapidly that capacity is able to expand. Current capacity can be evaluated on the basis of past production. Decreases to future capacity can be taken into account from announcements of planned shutdowns of mines or processing facilities, which are frequently publicized well in advance of such closures. Likewise, capacity expansions, which usually involve multiple stages—such as permitting, financing, and construction (all of which take time)—can also be estimated. As such, it is possible to evaluate midterm future capacity based on estimates of today’s capacities along with consideration of future investment plans. This World Minerals Outlook provides estimated capacities for cobalt, gallium, helium, lithium, magnesium, palladium, platinum, and titanium for 2025 through 2029. The results of this analysis indicate that two mineral commodities important to the manufacture of lithium-ion batteries—cobalt and lithium—are expected to have large capacity growth in the next few years, likely owing to expectations for increased demand for these batteries. For gallium, helium, palladium, and platinum, capacity is expected to remain stable or exhibit moderate growth. Still, these expected capacity levels are higher than current production, allowing for future production growth. The production capacity outlook is opaque for magnesium and titanium metal, which have a significant fraction of current production in nonmarket economies, such as China and Russia. Ultimately, though, where free market conditions prevail, full utilization of capacity potential for those commodities is likely to depend on supply deficits and prices that are above production costs.

Scientific Investigations Report

Heavy mineral sands resources in China

About 200 known coastal deposits of heavy mineral sands (HMS) occur in China, in which considerable mineral resources of titanium, zircon, rare earth elements, and thorium exist in the forms of ilmenite, rutile, zircon, and monazite. More than 20 of these HMS deposits are reported as having been or are actively being mined in China during the past three decades, of which 12 have been reported to have industrial resources. Commercially important deposits occur almost entirely in Cenozoic beach and sand dune deposits, principally along China’s eastern coast (e.g., Shandong Province) and southern coast (e.g., Guangxi, Guangdong, Hainan, and Fujian provinces), and particularly on Hainan island. There are also important deposits of HMS along coastal areas of Taiwan. China has the largest share of the world’s economic ilmenite resources in HMS deposits (31%). A variety of igneous and associated metamorphic rocks along the coastal areas of China provided an abundant source of heavy minerals for the formation of the HMS occurrences. Studies of titanium-rich HMS deposits have shown that ilmenite is mostly sourced from igneous rocks. For example, 40% of the bedrock of Hainan island consists of Triassic and Cretaceous granites emplaced into rocks of the Cathyasia Block, and all of the HMS districts on the island lie no more than 15 km downstream from a Middle Triassic suite of syenite to granite intrusions. The southern coastal regions of Guangdong and Guangxi provinces are dominated by Jurassic granodiorite, biotite granite, two-mica granite, and A-type granite, with minor gabbro and syenite. Identified accessory minerals in the Jurassic alkaline granitoids include zircon, apatite, allanite, titanite, magnetite, ilmenite, monazite, and niobite. Thus, multiple plutons are in proximity to the Cenozoic coastal plain and are available as bedrock sources for the detrital titanium minerals, zircon, and monazite. More than 100 HMS deposits and prospects have been identified in Shandong Province, consisting of more than 20 varieties of heavy minerals in quartz sand, which include zircon, ilmenite, rutile, monazite, magnetite, xenotime, and gold (in general order of abundance) derived from Precambrian metamorphic basement and Mesozoic intrusions. Of these minerals, zircon, magnetite, gold, and quartz sand have economic significance. The quartz sands are used by the glass and construction industries. The placers mainly occur in and adjacent to the littoral zones of the northern and southern coasts of the Jiaodong Peninsula in Shandong province. Seven beach placer, HMS prospective areas have been delineated in coastal areas of the peninsula. Due to nearly exhausted placer reserves in the Chinese coastal zones, as well as increased environmental restrictions, future prospecting for heavy minerals will likely focus on ancient beach systems in China’s inland sedimentary basins. Also, offshore deposits of HMS in shallow coastal waters are other potential sources of heavy minerals, such as the Baoding Sea zircon-titanium, minerals-rich placer under development near Wanning on Hainan. Similarly, there is potential for offshore HMS deposits in shallow waters of the entire coastal area of southern Taiwan that remains to be fully evaluated. Reconnaissance sampling along Taiwan island’s coasts has revealed the potential for extensive, high-grade HMS accumulations nearshore.

Book chapter

Mineral Resource of the Month: Talc

When people think of talc, they often think of talcum and baby powder. However, these uses of talc are minor compared to its use in industrial manufacturing. The leading use of talc in the United States is in the production of ceramics, where it is a source of magnesium oxide, serves as a flux to reduce firing temperatures, and improves thermal shock characteristics of the final product. Worldwide, the major use of talc is as a paper constituent, where it fills the interstices between cellulose paper fibers, reduces paper transparency, improves ink receptivity, and absorbs undesirable tree sap residues that can generate blemishes in the paper.

Earth

Water resources of the Green Bay area, Wisconsin

The Green Bay area comprises an area of about 525 square miles in eastern Wisconsin at the south end of Green Bay. It includes the western three-fourths of Brown County and the eastern one-ninth of Outagamie County. In 1960, the population of the area was estimated at 124,000. The most prominent topographic feature is the northwest-facing, southwestward trending Niagara escarpment. The area northwest of the escarpment drains into Green Bay via the Fox River, Suamico River, Duck Creek, and their tributaries. The area southeast of the escarpment is drained by streams that flow into Lake Michigan. The chief sources of surface water in the Green Bay area are the Fox River, Green Bay, and Lake Michigan. Smaller amounts of water are available from the East and Suamico Rivers and other streams. A sandstone aquifer is the principal source of the ground-water supply. The Niagara dolomite, although largely undeveloped, is potentially an important aquifer in the eastern part of the area. Small amounts of water are obtained also from the Platteville formation and from deposits of Pleistocene and Recent age. Water from the surfaceand ground-water sources is moderately hard to very hard. The Fox River, tributary to Lake Michigan at Green Bay, is a significant source of water for industrial use in the Green Bay area. The Menasha Dam, which controls release of water from the Lake Winnebago pool, is the major regulation on the Fox River, and it has considerable effect in reducing peak flows and supplementing low flows in the lower Fox River. The average discharge of the lower Fox River for the period 1898-1959, as measured at the gaging station at Rapide Croche Dam, was 2,687 mgd (million gallons per day). The longest consecutive period during which the discharge averaged less than 500 mgd was 80 days. The average discharge can be expected to fall below 700 mgd about once every 5 years for a 7-day period. In 1959, the average withdrawal of water from the Fox River was about 62 mgd. The water in the river is of the calcium magnesium bicarbonate type and is hard. The small streams in the area are utilized chiefly for stock watering; some of the water, however, is used for irrigation. The water in the small streams is more highly mineralized than the water in the Fox River and is very hard. Large quantities of water are available from Green Bay, but the disposal of industrial waste into the bay has restricted the use of the water. The major withdrawal is for condenser cooling, and, in 1959, it averaged about 415 mgd. The water from Green Bay is moderately hard but is of better chemical quality than the water from the Fox River and the small streams in the area. The only withdrawals of water from Lake Michigan for use in the Green Bay area are made by the city of Green Bay. In 1959, these withdrawals averaged 7.8 mgd. The lower Fox River is not subject to extremes of flow owing to the dampening effect of the Lake Winnebago pool and the regulation of flow at Menasha Dam. Cloudbursts over the lower Fox River valley below Menasha Dam, however, have occasionally caused extremely high water, as in 1922, when the discharge at the mouth of the Fox River was estimated to be about 50,000 mgd. Daily discharges greater than about 13,000 mgd occurred only 7 times in the period 1918-59. The 50-year flood of 15,500 mgd represents an average runoff of less than 2.6 mgd per square mile of drainage area, a relatively low runoff for a 50-year flood in Wisconsin. The sandstone aquifer is the principal source of ground water in the Green Bay area and furnishes water for public supply and industrial use. This aquifer includes rocks of Late Cambrian age, and the Prairie du Chien group and St. Peter sandstone of Ordovician age; it ranges in thickness from 550 to 640 feet. Ground water is found in openings along fractures and bedding planes and in the interstices between sand grains. The sandstone aquifer can support additional development of large supplies of ground water. Wells can be developed in most of the area that will yield 500 gpm (gallons per minute) or more, provided they are properly spaced and penetrate the entire thickness of the aquifer. It is estimated that the perennial yield of the sandstone in the Green Bay area could be at least 30 mgd if the aquifer is properly developed; only 5.4 mgd was withdrawn in 1959. The water from this sandstone aquifer is of the calcium magnesium bicarbonate type, is very hard, and, at a few places, contains objectionable amounts of iron. The Niagara dolomite, potentially a source of moderate to large quantities of water in the eastern part of the area, probably will yield 500 gpm or more to wells. In 1959, the average withdrawal of water for all uses was estimated at 495 mgd, of which 98.2 percent was from surface-water sources and 1.8 percent was from wells. About 485 mgd of water was withdrawn for industrial use, 6 mgd for public supply, and 4 mgd for rural use. The industrial use of water averaged 441 mgd for condenser cooling, 38 mgd fot processing by the paper industry, and 6 mgd for other industrial uses. The city of Green Bay used 7.8 mgd of water from Lake Michigan; other public supplies in the area used 2.6 mgd from wells. Of the withdrawals of water for rural use, about 75 percent was from wells and about 25 percent was from streams. The discharge of wastes into the lower Fox River and its tributary streams has altered the quality of the natural water. The wastes consist chiefly of treated municipal sewage and treated and untreated wastes from the paper industry, rendering plants, a sugar mill, and other industries. The industrial waste makes up about 90 percent of the oxygen-demand loading in the lower Fox River, and treated municipal sewage accounts for about 10 percent. The dissolved-oxygen concentration of water in the lower Fox River decreases rapidly in the vicinity of Green Bay during the summer when the river water is warm. If the periods when the river water is warmest, generally during July and early August, were to coincide with periods of lowest annual streamflow, generally in late August, the river would be unable to assimilate the loading of decomposable organic matter. In an emergency, industrial and public supply wells could supply at least 6 mgd for a sustained period and probably as much as 10 mgd for a period of several days. Six of the wells that formerly supplied the city of Green Bay are maintained in operating condition and could furnish about the same quantity of water as the industrial and other public supply wells. Small streams in the area would be supplemental sources of water, and the water in the Fox River and Green Bay is easily accessible.

Wisconsin

Water resources inventory of Connecticut Part 6: Upper Housatonic River basin

The upper Housatonic River basin report area has an abundant supply of water of generally good quality, which is derived from precipitation on the area and streams entering the area. Annual precipitation has averaged about 46 inches over a 30-year period. Of this, approximately 22 inches of water is returned to the atmosphere each year by evaporation and transpiration; the remainder flows overland to streams or percolates downward to the water table and ultimately flows out of the report area in the Housatonic River or in smaller streams tributary to the Hudson River. During the autumn and winter precipitation normally is sufficient to cause a substantial increase in the amount of water stored in surface reservoirs and in aquifers, whereas in the summer, losses through evaporation and transpiration result in sharply reduced streamflow and lowered ground-water levels. Mean monthly storage of water in November is 2.8 inches more than it is in June. The amount of water that flows into, through, and out of the report area represents the total amount potentially available for use ignoring reuse. For the 30-year period 1931 through 1960, the annual runoff from precipitation has averaged 24 inches (294 billion gallons). During the same period, inflows from Massachusetts and New York have averaged 220 and 64 billion gallons per year, respectively. A total average annual runoff of 578 billion gallons is therefore available. Although runoff indicates the total amount of water potentially available, it is rarely feasible to use all of it. On the other hand, with increased development, some water may be reused several times. The water availability may be tapped as it flows through the area or is temporarily stored in streams, lakes, and aquifers. The amounts that can be developed differ from place to place and time to time, depending on the amount of precipitation, on the size of drainage area, on the thickness, transmissivity, and areal extent of aquifers, and on the variations in chemical and physical quality of water. Differences in precipitation cause differences in the amount of streamflow whereas differences in the proportion of stratified drift affect its timing. Water can be obtained from wells almost anywhere in the area, but the amount obtainable at any particular point depends on the type and water-bearing properties of the aquifers tapped. Stratified-drift aquifers are the only ones generally capable of yielding more than 100 gpm (gallons per minute) to individual wells. Drilled, screened wells tapping this unit yield from 17 to 1,400 gpm, with a median yield of 200 gpm. Till and bedrock are widespread but generally provide only small supplies of water. Till is tapped in a few places by dug wells, which can yield small supplies of only a few hundred gallons per day throughout all or most of the year. Bedrock is the chief aquifer for privately owned domestic and rural supplies; it is tapped by drilled wells, about 90 percent of which will supply at least 2 gpm. Only 1 of 10 bedrock wells, however, will supply more than 30 gpm. The amount of ground water potentially available in the report area depends upon the thickness and hydraulic properties of aquifers, the amount of salvageable natural discharge of ground water, and the quantity of water available by induced infiltration from streams and lakes. From data on transmissivity, thickness, recharge, well performance, and streamflow, preliminary estimates of ground-water availability can be made for most stratified-drift aquifers in the report area. Long-term yields estimated for eight areas of stratified drift especially favorable for development of large ground-water supplies ranged from 0.6 to 5 mgd (million gallons per day). Detailed site studies are needed to verity these estimates and to determine optimum yields, drawdowns, and spacing of individual wells before major ground-water development is undertaken in these or other areas. The chemical quality of water in the report area is generally good; carbonate-bedrock units exert considerable local influence on water quality. Samples of naturally occurring surface water collected at 24 sites during low flow averaged 90 mg/l (milligrams per liter) dissolved solids and 60 mg/l hardness. Water from wells is generally more highly mineralized than naturally occurring water from streams. About 37 percent of the wells sampled yielded water with more than 200 mg/l dissolved solids and 50 percent yielded water with more than 120 mg/l hardness. These concentrations reflect the high degree of mineralization of ground water in carbonate bedrock and unconsolidated deposits derived from this bedrock. The larger streams, which transport varying amounts of industrial and domestic effluents, averaged about 150 mg/l dissolved solids and 90 mg/l hardness. Iron and manganese concentrations in both ground water and surface water at some places exceed recommended limits for domestic and industrial use. Most wells in the report area yield water with little or no iron or manganese. In certain localities however, the probability is high of encountering water with excessive concentrations of these constituents. Schists, especially the unit in the northwestern corner of the basin, are the likely sources of water with excessive iron and manganese. Iron concentrations in naturally occurring stream water exceed 0.3 mg/l under low-flow conditions at 29 percent of the sites sampled. These excessive concentrations result from discharge of iron-bearing water from aquifers or from swamps where iron is released from decaying vegetation. Water temperature in the larger streams ranges from 0°C (degrees Celsius) to about 28°C. Ground water between 30 feet and 200 feet below the land surface has a relatively constant temperature, usually between 8°C and 11°C. The quantity of suspended sediment transported by streams under natural conditions is negligible. Even in streams affected by man, turbidity is rarely a problem. The total amount of water used in the report area for all purposes during 1967 was about 6,360 million gallons, or 140 gpd per person. Public supplies furnished the domestic needs of nearly half the population of the area. All of the 14 public supplies sampled provided water that meets the drinking water standards of the U.S. Public Health Service.

Connecticut