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Opportunities and Needs for Mobile-Computing Technology to Support U.S. Geological Survey Fieldwork

To assess the opportunities and needs for mobile-computing technology at the U.S. Geological Survey (USGS), we conducted an internal, Internet-based survey of bureau scientists whose research includes fieldwork. In summer 2005, 144 survey participants answered 65 questions about fieldwork activities and conditions, technology to support field research, and postfieldwork data processing and analysis. Results suggest that some types of mobile-computing technology are already commonplace, such as digital cameras and Global Positioning System (GPS) receivers, whereas others are not, such as personal digital assistants (PDAs) and tablet-based personal computers (tablet PCs). The potential for PDA use in the USGS is high: 97 percent of respondents record field observations (primarily environmental conditions and water-quality data), and 87 percent take field samples (primarily water-quality data, water samples, and sediment/soil samples). The potential for tablet PC use in the USGS is also high: 59 percent of respondents map environmental features in the field, primarily by sketching in field notebooks, on aerial photographs, or on topographic-map sheets. Results also suggest that efficient mobile-computing-technology solutions could benefit many USGS scientists because most respondents spend at least 1 week per year in the field, conduct field sessions that are least 1 week in duration, have field crews of one to three people, and typically travel on foot about 1 mi from their field vehicles. By allowing researchers to enter data directly into digital databases while in the field, mobile-computing technology could also minimize postfieldwork data processing: 93 percent of respondents enter collected field data into their office computers, and more than 50 percent spend at least 1 week per year on postfieldwork data processing. Reducing postfieldwork data processing could free up additional time for researchers and result in cost savings for the bureau. Generally, respondents support greater use of mobile-computing technology at the USGS and are interested in training opportunities and further discussions related to data archiving, access to additional digital data types, and technology development.

Circular

Publications of the Western Earth Surfaces Processes Team 2005

Introduction The Western Earth Surface Processes Team (WESPT) of the U.S. Geological Survey (USGS) conducts geologic mapping, earth-surface process investigations, and related topical earth science studies in the western United States. This work is focused on areas where modern geologic maps and associated earth-science data are needed to address key societal and environmental issues such as ground-water quality, landslides and other potential geologic hazards, and land-use decisions. Areas of primary emphasis in 2005 included southern California, the San Francisco Bay region, the Mojave Desert, the Colorado Plateau region of northern Arizona, and the Pacific Northwest. The team has its headquarters in Menlo Park, California, and maintains smaller field offices at several other locations in the western United States. The results of research conducted by the WESPT are released to the public as a variety of databases, maps, text reports, and abstracts, both through the internal publication system of the USGS and in diverse external publications such as scientific journals and books. This report lists publications of the WESPT released in 2005 as well as additional 2002, 2003, and 2004 publications that were not included in the previous lists (USGS Open-File Reports 03-363, 2004- 1267, 2005-1362). Most of the publications listed were authored or coauthored by WESPT staff. The list also includes some publications authored by non-USGS cooperators with the WESPT, as well as some authored by USGS staff outside the WESPT in cooperation with WESPT projects. Several of the publications listed are available on the World Wide Web; for these, URL addresses are provided. Many of these web publications are USGS Open-File reports that contain large digital databases of geologic map and related information. Information on ordering USGS publications can be found on the World Wide Web at http://www.usgs.gov/pubprod/, or by calling 1-888-ASK-USGS. The U.S. Geological Survey's web server for geologic information in the western United States is located at http://geology.wr.usgs.gov/. More information is available about the WESPT is available on-line at http://geology.wr.usgs.gov/wgmt.

Open-File Report

Biomonitoring of Environmental Status and Trends (BEST) Program: Environmental contaminants and their effects on fish in the Mississippi River Basin

We collected, examined, and analyzed 1378 fish of 22 species from 47 sites in the Mississippi River basin (MRB) during 1995 and from a reference site in 1996. The sampling sites in the MRB represented National Contaminant Biomonitoring Program (NCBP) stations situated at key points on major rivers and National Water- Quality Assessment Program (NAWQA) stations located on lower-order rivers and streams in the Eastern Iowa Basins (EIB) and Mississippi Embayment (MSE) Study Units. The reference site was the water supply system of the USGS-Leetown Science Center in rural Jefferson County, WV. Common carp (Cyprinus carpio; carp) and black basses (Micropterus spp.; bass), the targeted species, together represented 82% of the fish collected. Each fish was examined in the field for externally and internally visible gross lesions, selected organs were weighed to compute various ponderal and organo-somatic indices, and selected tissues and fluids were obtained and preserved for analysis of biomarkers. Fish health indicators included splenic macrophage aggregates, lysozyme activity, and hispathological analysis of liver, kidney, and other tissues. Reproductive biomarkers included analysis of plasma concentrations of vitellogenin (vtg) and the sex steroid hormones 17-estradiol (E2) and 11-ketotestosterone (11- kt); and the histological determination of percent oocyte atresia (in female fish) and gonadal stage. Hepatic ethoxyresorufin O-deethylase (EROD) activity was also measured. Composite samples of whole fish from each station were grouped by species and gender and analyzed for persistent organochlorine and elemental contaminants and for dioxin-like activity (TCDD-EQ) using the H4IIE rat hepatoma cell bioassay. Organochlorine and inorganic contaminant concentrations in fish were generally low relative to historical levels at most sites, but remained present at concentrations representing threats to piscivorous wildlife in some locations. Toxaphene and DDT (mostly as p,p?-DDE) concentrations remained elevated in fish from the cottongrowing regions of the lower Mississippi valley, and were generally greater in the smaller streams draining agricultural areas (that is, in the MSE Study Unit) than at large river sites. Cyclodiene pesticide concentrations were also greatest in the EIB Study Unit and elsewhere in the corn-growing regions of the mid-MRB. Former point-sources of organochlorine pesticides also remained evident, especially in the Mississippi River near Memphis, TN. Consistent with previous findings, total PCB concentrations tended to be greatest (1-3 g/g) in the industrialized and urbanized Ohio River and Upper Mississippi sub-basins and at Memphis, TN, and were generally correlated with TCDD-EQ and EROD activity. Conversely, PCB concentrations were low (<0.1 g/g) in the more agricultural parts of the MRB. Concentrations of inorganic contaminants were also relatively low and stable or declining relative to past levels at most sites. Exceptions were Hg and Se; Hg concentrations were slightly elevated (>0.3 g/g) in bass from the Mississippi River at Memphis and several other sites and in carp from one MSE site. Concentrations of Se were also great enough to constitute a hazard to piscivorous wildlife (>0.6 g/g) at several MRB sites in the western parts of the MRB and were especially high (4-5 g/g) in fish from John Martin Reservoir, CO, where elevated concentrations were reported previously. Biomarker results indicated that fish from many stations had been exposed to contaminants, but at no sites did findings indicate exposure to high concentrations of toxic chemicals. Noteworthy among biomarker findings was that 73% of the male smallmouth bass (Micropterus dolomieui) from the Mississippi River at Lake City, MN (Lake Pepin) were intersex as indicated by the histological detection of ovotestes; and the combined EROD and H4IIE results indicated that fish from several rural sites in the

Mississippi River basin

A Compilation of Provisional Karst Geospatial Data for the Interior Low Plateaus Physiographic Region, Central United States

Geospatial data needed to visualize and evaluate the hydrogeologic framework and distribution of karst features in the Interior Low Plateaus physiographic region of the central United States were compiled during 2004-2007 as part of the Ground-Water Resources Program Karst Hydrology Initiative (KHI) project. Because of the potential usefulness to environmental and water-resources regulators, private consultants, academic researchers, and others, the geospatial data files created during the KHI project are being made available to the public as a provisional regional karst dataset. To enhance accessibility and visualization, the geospatial data files have been compiled as ESRI ArcReader data folders and user interactive Published Map Files (.pmf files), all of which are catalogued by the boundaries of surface watersheds using U.S. Geological Survey (USGS) eight-digit hydrologic unit codes (HUC-8s). Specific karst features included in the dataset include mapped sinkhole locations, sinking (or disappearing) streams, internally drained catchments, karst springs inventoried in the USGS National Water Information System (NWIS) database, relic stream valleys, and karst flow paths obtained from results of previously reported water-tracer tests.

Data Series

Cell penetrating peptide-mediated delivery of gene-silencing nucleic acids to the invasive common reed Phragmites australis via foliar application

As a popular tool for gene function characterization and gene therapy, RNA interference (RNAi)-based gene silencing has been increasingly explored for potential applications to control invasive species. At least two major hurdles exist when applying this approach to invasive plants: (1) the design and screening of species- and gene-specific biomacromolecules (i.e., gene-silencing agents or GSAs) made of DNA, RNA, or peptides that can suppress the expression of target genes efficiently, and (2) the delivery vehicle needed to penetrate plant cell walls and other physical barriers (e.g., leaf cuticles). In this study, we investigated the cell-penetrating peptide (CPP)-mediated delivery of multiple types of GSAs (e.g., double-stranded RNA (dsRNA), artificial microRNA (amiRNA), and antisense oligonucleotide (ASO)) to knock down a putative phytoene desaturase ( PDS ) gene in the invasive common reed ( Phragmites australis spp. australis ). Both microscopic and quantitative gene expression evidence demonstrated the CPP-mediated internalization of GSA cargos and transient suppression of PDS expression in both treated and systemic leaves up to 7 days post foliar application. Although various GSA combinations and application rates and frequencies were tested, we observed limitations, including low gene-silencing efficiency and a lack of physiological trait alteration, likely owing to low CPP payload capacity and the incomplete characterization of the PDS-coding genes (e.g., the recent discovery of two PDS paralogs) in P. australis . Our work lays a foundation to support further research toward the development of convenient, cost-effective, field-deployable, and environmentally benign gene-silencing technologies for invasive P. australis management.

Mississippi, Ohio

Organic substances in produced and formation water from unconventional natural gas extraction in coal and shale

Organic substances in produced and formation water from coalbed methane (CBM) and gas shale plays from across the USA were examined in this study. Disposal of produced waters from gas extraction in coal and shale is an important environmental issue because of the large volumes of water involved and the variable quality of this water. Organic substances in produced water may be environmentally relevant as pollutants, but have been little studied. Results from five CBM plays and two gas shale plays (including the Marcellus Shale) show a myriad of organic chemicals present in the produced and formation water. Organic compound classes present in produced and formation water in CBM plays include: polycyclic aromatic hydrocarbons (PAHs), heterocyclic compounds, alkyl phenols, aromatic amines, alkyl aromatics (alkyl benzenes, alkyl biphenyls), long-chain fatty acids, and aliphatic hydrocarbons. Concentrations of individual compounds range from < 1 to 100 μg/L, but total PAHs (the dominant compound class for most CBM samples) range from 50 to 100 μg/L. Total dissolved organic carbon (TOC) in CBM produced water is generally in the 1–4 mg/L range. Excursions from this general pattern in produced waters from individual wells arise from contaminants introduced by production activities (oils, grease, adhesives, etc.). Organic substances in produced and formation water from gas shale unimpacted by production chemicals have a similar range of compound classes as CBM produced water, and TOC levels of about 8 mg/L. However, produced water from the Marcellus Shale using hydraulic fracturing has TOC levels as high as 5500 mg/L and a range of added organic chemicals including, solvents, biocides, scale inhibitors, and other organic chemicals at levels of 1000 s of μg/L for individual compounds. Levels of these hydraulic fracturing chemicals and TOC decrease rapidly over the first 20 days of water recovery and some level of residual organic contaminants remain up to 250 days after hydraulic fracturing. Although the environmental impacts of the organics in produced water are not well defined, results suggest that care should be exercised in the disposal and release of produced waters containing these organic substances into the environment because of the potential toxicity of many of these substances.

International Journal of Coal Geology

Evaluating abundance and trends in a Hawaiian avian community using state-space analysis

Estimating population abundances and patterns of change over time are important in both ecology and conservation. Trend assessment typically entails fitting a regression to a time series of abundances to estimate population trajectory. However, changes in abundance estimates from year-to-year across time are due to both true variation in population size (process variation) and variation due to imperfect sampling and model fit. State-space models are a relatively new method that can be used to partition the error components and quantify trends based only on process variation. We compare a state-space modelling approach with a more traditional linear regression approach to assess trends in uncorrected raw counts and detection-corrected abundance estimates of forest birds at Hakalau Forest National Wildlife Refuge, Hawai&lsquo;i. Most species demonstrated similar trends using either method. In general, evidence for trends using state-space models was less strong than for linear regression, as measured by estimates of precision. However, while the state-space models may sacrifice precision, the expectation is that these estimates provide a better representation of the real world biological processes of interest because they are partitioning process variation (environmental and demographic variation) and observation variation (sampling and model variation). The state-space approach also provides annual estimates of abundance which can be used by managers to set conservation strategies, and can be linked to factors that vary by year, such as climate, to better understand processes that drive population trends.

Hawai'i

Field screening of water quality, bottom sediment, and biota associated with irrigation drainage in the Yuma Valley, Arizona, 1995

Because of concerns expressed by the U.S. Congress and the environmental community, the Department of the Interior began a program in late 1985 to identify the nature and extent of water-quality problems induced by irrigation that might exist in the western States. Surface water, bottom sediment, and biota were collected from March through September 1995 along the lower Colorado River and in agricultural drains at nine sites in the Yuma Valley, Arizona, and analyzed for selected inorganic and organic constituents. Analyses of water, bottom sediment, and biota were completed to determine if irrigation return flow has caused, or has the potential to cause, harmful effects on human health, fish, and wildlife in the study area. Concentrations of dissolved solids in surface-water samples collected in March generally did not vary substantially from surface-water samples collected in June. Concentrations of dissolved solids ranged from 712 to 3,000 milligrams per liter and exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level of 500 milligrams per liter for drinking water. Concentrations of chloride in 9 of 18 water samples and concentrations of sulfate in 16 of 18 water samples exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level of 250 milligrams per liter for drinking water. Calcium and sodium were the dominant cations, and chloride and sulfate were the dominant anions. The maximum selenium concentration of 8 micrograms per liter exceeded the U.S. Environmental Protection Agency aquatic-life chronic criterion of 5 micrograms per liter. Concentrations of lead in 7 of 18 water samples and concentrations of mercury in 4 of 18 water samples exceeded the aquatic-life cronic criteria of 3.2 and 0.012 micrograms per liter, respectively. Concentrations of antimony, beryllium, cadmium, and silver in the water samples were below analytical reporting limits. Arsenic was detected in 3 of 9 bottom-sediment samples, and concentrations ranged from 11 to 16 micrograms per gram. Concentrations ofaluminum, beryllium, boron, copper, lead, and zinc were highest in samples from Main Drain at southerly international boundary near San Luis, Arizona. Selenium was detected in all bottom-sediment samples, and concentrations ranged from 0.1 to 0.7 micrograms per gram. Concentrations of cadmium, europium, homium, mercury, molybdenum, silver, tantalum, tin, and uranium were below analytical reporting limits in the bottom-sediment samples. Concentrations of trace elements in bottom-sediment samples were within the ranges found in a study of soils of the western United States and did not indicate a significant accumulation of these constituents. p,p'Dichlorodiphenyldichloroethylene (commonly referred to as p,-p'-DDE) was detected in one bottom-sediment sample at a concentration of 1.4 micrograms per gram. No other organochlorine compounds were detected in the bottom-sediment samples. DDE was present in all fish and bird samples. Almost one-half of the fish samples contained DDE residues that were two times higher than the mean calculated for a national study in 1984-85. Twenty-tree percent of the fish contained more than three times the national mean. Fish from downstream parts of the Main Drain had the highest concentrations of DDE. Although concentrations of DDE in fish and in bird carcasses and eggs were above background levels, residues generally were below thresholds associated with chronic poisoning and reproductive problems in figh and wildlife. Concentrations of 18 trace elements were detected in cattail (Typha sp.) roots, freshwater clam (Corbicula fluminea), fish, and bird samples. Selenium in most fish and in livers of red-winged (Agelaius phoeniceus) and yellow-headed (Xanthocephalus xanthocephalus) blackbirds was above background concentrations but below toxic concentrations. In contrast, selenium was present in a killdeer (Charadrium vociferus) liver sample at potentially toxic con

Water-Resources Investigations Report

Implementation of unmanned aircraft systems by the U.S. Geological Survey

The U.S. Geological Survey (USGS) Unmanned Aircraft Systems (UAS) Project Office is leading the implementation of UAS technology in anticipation of transforming the research methods and management techniques employed across the Department of the Interior. UAS technology is being made available to monitor environmental conditions, analyse the impacts of climate change, respond to natural hazards, understand landscape change rates and consequences, conduct wildlife inventories and support related land management missions. USGS is teaming with the Department of the Interior Aviation Management Directorate (AMD) to lead the safe and cost-effective adoption of UAS technology by the Department of the Interior Agencies and USGS scientists.

Geocarto International

Trace fossils and sedimentary facies from a Late Cambrian‐Early Ordovician tide‐dominated shelf (Santa Rosita Formation, northwest Argentina): Implications for ichnofacies models of shallow marine successions

The Santa Rosita Formation is one the most widely distributed lower Paleozoic units of northwest Argentina. At the Quebrada del Salto Alto section, east of Purmamarca, Jujuy Province, it is represented by four sedimentary facies: thick‐bedded planar cross‐stratified quartzose sandstones (A), thin‐bedded planar cross‐stratified quartzose sandstones and mudstones (B), wave‐rippled sandstones and bioturbated mudstones (C), and black and greenish gray shales (D). Paleocurrent data, sandstone architecture, and sedimentary structures from faciès A and B indicate bipolar/bimodal paleoflows, suggesting the action of tidal currents. The succession is interpreted as that of a tide‐dominated shelf, with only secondary influence of wave processes. Trace fossils are restricted to facies B and C. The Cruziana ichnocoenosis is preserved on the soles of thin‐bedded planar cross‐stratified quartzose sandstones (faciès B). This ichnocoenosis consists of Conostichus isp., Cruziana omanica, C. semiplicata, C. cf. tortworthi, Cruziana isp. Helminthopsis abeli, Monomorphichnus bilinearis, M. multilineatus, Palaeophycus tubularis, Rusophycus carbonarias, R. latus , and R. isp. The occurrence of Cruziana semiplicata , C. omanica, C. cf. tortworthi , and Rusophycus latus supports a Late Cambrian‐Tremadoc age. Slabbing of Cruziana shows complex interactions between biologic and sedimentologic processes, and suggests a predominance of exhumed traces, washed out and recast by tractive sand deposition. Sandstone soles are densely packed with biogenic structures and exhibit distinctive clusters of Rusophycus isp. that most likely represent trilobite nesting burrows. The Cruziana ichnocoenosis records the resident fauna of a protected, lower intertidal to subtidal interbar setting. The Skolithos ichnocoenosis is represented by high to low density vertical burrows of Skolithos linearis , which extend downwards to the quartzose sandstone soles of faciès B and cross the Cruziana ichnocoenosis. The Skolithos ichnocoenosis represents colonization by suspension‐feeding organisms following a major change in environmental conditions, related to the migration of lower intertidal to subtidal sandwaves. The Planolites ichnocoenosis consists exclusively of Planolites montanus within mudstones overlying wave‐rippled sandstones (facies C). The Planolites ichnocoenosis records opportunistic colonization by inf aunal deposit feeders that mined the organic‐rich fine‐grained sediment during the waning phase of storms that scoured organic detritus from the sea bottom. The section records, from base to top, a Cruziana‐Skolithos ichnofacies zone, a Skolithos ichnofacies zone and an unbioturbated zone typified by the thick‐bedded cross‐stratified quartzose sandstone (fades A). This trend reflects progressively higher energy conditions linked to the establishment of a large sand wave complex. The presence of a mixed Cruziana‐Skolithos ichnofacies in the lower interval reflects changes in substrate and energy levels, rather than water depth. Accordingly, contrasting ichnocoenoses from interbars (Cruziana) and sandwaves (Skolithos) must be considered an example of ichnofacies controlled by local parameters instead of general bathymétrie trends. Conversely, the vertical replacement of the Cruziana ichnofacies by the Skolithos ichnofacies towards the middle interval of the section reflects the environmental changes associated with the transition between the intertidal and subtidal zones. As overall tidal energy increases from supratidal to subtidal settings, the Skolithos ichnofacies tends to occur seaward of the Cruziana ichnofacies in tide‐dominated shallow marine environments. Therefore, onshore‐offshore ichnofacies replacement in tide‐dominated shallow seas is opposite to that in wave‐dominated marine settings.

Ichnos: An International Journal for Plant and Ani

Framing scenarios of binational water policy with a tool to visualize, quantify and valuate changes in ecosystem services

In the Santa Cruz Watershed, located on the Arizona-Sonora portion of the U.S.-Mexico border, an international wastewater treatment plant treats wastewater from cities on both sides of the border, before discharging it into the river in Arizona. These artificial flows often subsidize important perennial surface water ecosystems in the region. An explicit understanding of the benefits of maintaining instream flow for present and future generations requires the ability to assess and understand the important trade-offs implicit in water-resource management decisions. In this paper, we outline an approach for modeling and visualizing impacts of management decisions in terms of rare terrestrial and aquatic wildlife, vegetation, surface water, groundwater recharge, real-estate values and socio-environmental vulnerable communities. We identify and quantify ecosystem services and model the potential reduction in effluent discharge to the U.S. that is under scrutiny by binational water policy makers and of concern to stakeholders. Results of service provisioning are presented, and implications for policy makers and resource managers are discussed. This paper presents a robust ecosystem services assessment of multiple scenarios of watershed management as a means to discern eco-hydrological responses and consider their potential values for future generations living in the borderlands.

Arizona;Sonora

Groundwater flux and nutrient loading in the northeast section of Bear Lake, Muskegon County, Michigan, 2015

Bear Lake in North Muskegon, Michigan, is listed as part of the Muskegon Lake area of concern as designated by the U.S. Environmental Protection Agency. This area of concern was designated as a result of eutrophication and beneficial use impairments. On the northeast end of Bear Lake, two man-made retention ponds (Willbrandt Pond East and Willbrandt Pond West), formerly used for celery farming, may contribute nutrients to Bear Lake. Willbrandt Ponds (East and West) were previously muck fields that were actively used for celery farming from the early 1900s until 2002. The restoration and reconnection of the Willbrandt Ponds into Bear Lake prompted concerns of groundwater nutrient loading into Bear Lake. Studies done by the State of Michigan and Grand Valley State University revised initial internal phosphorus load estimates and indicated an imbalance in the phosphorus budget in Bear Lake. From June through November 2015, the U.S. Geological Survey (USGS) did an investigative study to quantify the load of nutrients from shallow groundwater around the Willbrandt Ponds in an effort to update the phosphorus budget to Bear Lake. Seven sampling locations were established, including five shallow groundwater wells and two surface-water sites, in the Willbrandt pond study area and Bear Lake. A total of 12 nutrient samples and discrete water-level measurements were collected from each site from June through November 2015. Continuous water-level data were recorded for both surface-water monitoring locations for the entire sampling period. Water-level data indicated that Willbrandt Pond West had the highest average water-level elevation of all sites monitored, which indicated the general direction of flux is from Willbrandt Pond West to Bear Lake. Nutrient and chloride loading from Willbrandt Pond West to Bear Lake was calculated using two distinct methods: Dupuit and direct seepage methods. Shallow groundwater loading calculations were determined by using groundwater levels to first determine a flux of shallow groundwater, then nutrient concentrations to determine a load. It was determined that Willbrandt Pond East and Willbrandt Pond West contributed between 2 to 4 percent of the total annual phosphorus load to Bear Lake by way of shallow groundwater flow. Annual loads calculated for other constituents include orthophosphate (40–100 pounds per year [lb P/yr]), total nitrogen (200–830 lb/yr), chloride (12,700–32,100 lb/yr), and ammonia (130–670 lb N/yr). Study results indicated that mean groundwater and surface-water nutrient concentrations calculated in this study were higher than reported Michigan statewide values. The data collected in this study allow understanding of groundwater nutrient loading into Bear Lake in an effort to help inform future restoration and management decisions.

Michigan

Targeted quantitation of 6ppd-quinone in fish tissue samples with liquid chromatography-tandem mass spectrometry

The tire additive transformation product N -(1,3-dimethylbutyl)- N’ -phenyl- p -phenylenediamine-quinone (6PPD-quinone) has recently garnered global attention due to its acute toxicity to some salmonids, such as coho salmon ( Oncorhynchus kisutch ), and its ubiquitous presence in urban stormwater systems. In the present study, we developed and compared the extraction efficiency of two sample preparation methodologies for quantification of 6PPD-quinone among two fish tissue sample types that included fillet of smallmouth bass ( Micropterus dolomieu ) and whole-body samples of O. kisutch fry subjected to in vivo exposure tests with 6PPD-quinone. The two sample preparation methods tested included an accelerated solvent extraction (ASE) approach and a sonication extraction approach. Both sample preparation methods included identical purification steps for the crude sample extracts with enhanced matrix removal cartridges. The purified sample extracts were subjected to targeted analysis of 6PPD-quinone using ultra-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). The results showed that extractions made with the reported ASE method demonstrated significantly higher absolute recovery (80–96%) of the extracted internal standard, [ 13 C 6 ]-6PPD-quinone, than sonication-based extractions (74–80%) in both fish tissue sample types. The proposed ASE method shows acceptable limits of quantification (0.37–0.67 ng g −1 ), linearity (R 2 > 0.996), and repeatability (RSD ≤ 9%). This work advances research capabilities for investigations on the toxicokinetic processes of 6PPD-quinone in biological samples.

Environmental Toxicology and Chemistry

A critical time for mercury science to inform global policy

Mercury is a global pollutant released into the biosphere by varied human activities including coal combustion, mining, artisanal gold mining, cement production, and chemical production. Once released to air, land and water, the addition of carbon atoms to mercury by bacteria results in the production of methylmercury, the toxic form that bioaccumulates in aquatic and terrestrial food chains resulting in elevated exposure to humans and wildlife. Global recognition of the mercury contamination problem has resulted in the Minamata Convention on Mercury, which came into force in 2017. The treaty aims to protect human health and the environment from human-generated releases of mercury curtailing its movement and transformations in the biosphere. Coincident with the treaty’s coming into force, the 13th International Conference of Mercury as a Global Pollutant (ICMGP-13) was held in Providence, Rhode Island USA. At ICMGP-13, cutting edge research was summarized and presented to address questions relating to global and regional sources and cycling of mercury, how that mercury is methylated, the effects of mercury exposure on humans and wildlife, and the science needed for successful implementation of the Minamata Convention. Human activities have the potential to enhance mercury methylation by remobilizing previously released mercury, and increasing methylation efficiency. This synthesis concluded that many of the most important factors influencing the fate and effects of mercury and its more toxic form, methylmercury, stem from environmental changes that are much broader in scope than mercury releases alone. Alterations of mercury cycling, methylmercury bioavailability and trophic transfer due to climate and land use changes remain critical uncertainties in effective implementation of the Minamata Convention. In the face of these uncertainties, important policy and management actions are needed over the short-term to support the control of mercury releases to land, water and air. These include adequate monitoring and communication on risk from exposure to various forms of inorganic mercury as well as methylmercury from fish and rice consumption. Successful management of global and local mercury pollution will require integration of mercury research and policy in a changing world.

Environmental Science & Technology

Scientific developments ISFD3

Highlights, trends, and consensus from the 63 papers submitted to the Scientific Developments theme of the Third International Symposium on Flood Defence (ISFD) are presented. Realizing that absolute protection against flooding can never be guaranteed, trends in flood management have shifted: (1) from flood protection to flood-risk management, (2) from reinforcing structural protection to lowering flood levels, and (3) to sustainable management through integrated problem solving. Improved understanding of watershed responses, climate changes, applications of GIS and remote-sensing technologies, and advanced analytical tools appeared to be the driving forces for renewing flood-risk management strategies. Technical competence in integrating analytical tools to form the basin wide management systems are demonstrated by several large, transnation models. However, analyses from social-economic-environmental points of view are found lag in general. ?? 2006 Taylor & Francis Group.

Conference Paper

The National Wind Erosion Research Network: Building a standardized long-term data resource for aeolian research, modeling and land management

The National Wind Erosion Research Network was established in 2014 as a collaborative effort led by the United States Department of Agriculture&rsquo;s Agricultural Research Service and Natural Resources Conservation Service, and the United States Department of the Interior&rsquo;s Bureau of Land Management, to address the need for a long-term research program to meet critical challenges in wind erosion research and management in the United States. The Network has three aims: (1) provide data to support understanding of basic aeolian processes across land use types, land cover types, and management practices, (2) support development and application of models to assess wind erosion and dust emission and their impacts on human and environmental systems, and (3) encourage collaboration among the aeolian research community and resource managers for the transfer of wind erosion technologies. The Network currently consists of thirteen intensively instrumented sites providing measurements of aeolian sediment transport rates, meteorological conditions, and soil and vegetation properties that influence wind erosion. Network sites are located across rangelands, croplands, and deserts of the western US. In support of Network activities, http://winderosionnetwork.org was developed as a portal for information about the Network, providing site descriptions, measurement protocols, and data visualization tools to facilitate collaboration with scientists and managers interested in the Network and accessing Network products. The Network provides a mechanism for engaging national and international partners in a wind erosion research program that addresses the need for improved understanding and prediction of aeolian processes across complex and diverse land use types and management practices.

Arizona, California, Colorado, Idaho, North Dakota

Nearshore single-beam bathymetry data collected in 2015, Dauphin Island, Alabama

Dauphin Island, Alabama, is a barrier island located in the northern Gulf of Mexico that supports local residences, tourism, commercial infrastructure, and historic Fort Gaines. During the past decade, Dauphin Island was affected by several major hurricanes—Hurricanes Ivan (2004), Katrina (2005), and Isaac (2012)—and storms, along with sea-level rise, continue to present a threat to island stability. State and Federal managers are using a scientific approach to identify, formulate, and implement a long-term plan to provide restoration options for Dauphin Island, thereby helping increase its resilience against future storms and sea-level rise. Island morphology, including current bathymetry and shoreline data, is one scientific domain being investigated in an effort to produce a comprehensive restoration plan funded by an interagency grant from the National Fish and Wildlife Foundation Gulf Environmental Benefit Fund . In August 2015, the U.S. Geological Survey ( USGS ) St. Petersburg Coastal and Marine Science Center ( SPCMSC ), in cooperation with the U.S. Army Corps of Engineers at the U.S. Army Engineer Research and Development Center, Mobile District, and the State of Alabama, conducted bathymetric surveys of the nearshore waters surrounding Dauphin Island. This report provides a detailed methodology for the data acquisition and post-processing of 1,165-line kilometers (km) of single-beam bathymetry data collected under the USGS–SPCMSC Alabama Barrier Island Restoration Study . These data were acquired and processed under USGS field activity number 2015–326–FA . Data are provided in three datums: (1) the International Terrestrial Reference Frame of 2000, ellipsoid height (from –47.04 meters (m) to –29.36 m); (2) the North American Datum of 1983, CORS96 realization (NAD83 (CORS96)) horizontal, and the North American Vertical Datum 1988 GEOID12A vertical (from –0.24 m to –17.33 m); and (3) NAD83 (CORS96) horizontal, and mean lower low water vertical (from –0.12 m to –17.93 m). The x,y,z point datasets, trackline shapefiles, digital and handwritten Field Activity Collection Systems logs, one 50-m digital elevation model, and formal Federal Geographic Data Committee metadata are obtainable from the Data Downloads page or the associated USGS data release .

Alabama

Selective transport of palynomorphs in marine turbiditic deposits: An example from the Ascension-Monterey Canyon system offshore central California

The pollen assemblage of a deep-sea core (15G) collected at lower bathyal depths (3491 m) on a levee of Monterey Canyon off central California was investigated to gain insights into the delivery processes of terrigenous material to submarine fans and the effect this transport has on the palynological record. Thirty-two samples were obtained down the length of the core, 19 from hemipelagic and mixed mud deposits considered to be the background record, and 13 others from displaced flow deposits. The pollen record obtained from the background samples documents variations in the terrestrial flora as it adapted to changing climatic conditions over the last 19,000 cal yrs BP. A Q-mode cluster analysis defined three pollen zones: a Glacial Pollen Zone (ca. 20,000–17,000 cal yr BP), an overlying Transitional Pollen Zone (ca. 17,000–11,500 cal yr BP), and an Interglacial Pollen Zone (ca. 11,500 cal yr BP to present). Another Q-mode cluster analysis, of both the background mud and flow deposits, also defined these three pollen zones, but four of the 13 turbiditic deposits were assigned to pollen zones older than expected by their stratigraphic position. This was due to these samples containing statistically significant fewer palynomorphs than the background muds as well as being enriched (∼10–35% in some cases) in hydraulically-efficient Pinus pollen. A selective bias in the pollen assemblage, such as demonstrated here, may result in incorrect interpretations (e.g., climatic shifts or environmental perturbations) based on the floral record, indicating turbiditic deposits should be avoided in marine palynological studies. Particularly in the case of fine-grained flow deposits that may not be visually distinct, granulometry and grain size frequency distribution curves may not be enough to identify these biased deposits. Determining the relative abundance and source of displaced shallow-water benthic foraminifera entrained in these sediments serves as an excellent additional tool to do so.

California