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Neutron activation analysis in hydrology

Neutron activation analysis in hydrogeochemical and related investigations is increasingly practical because of developments in radiation detectors and computerized data processing. While neutron activation is the most widely used kind of activation analysis other kinds (for example, charged particle activation) are available for special applications. Neutron activation analysis is promising because approximately 70 percent of the elements in the periodic table are detected with satisfactory sensitivity, contamination from reagents is eliminated, simultaneous determination of more than 20 elements is often possible, technique is versatile, is applicable to small samples and is non-destructive in the instrumental form. Developments in theU.S. Geological Survey include a special sampling technique for water; a comprehensive technique using carriers precipitated with sulfide to concentrate desired trace elements; a determination of mercury, silver, and gold; determination of aluminum, vanadium and nine other elements; determinations of two groups of rare earth elements; and adaptations of the analytical methods to sediment and biota.

Open-File Report

Channel morphology and large wood control postfire debris-flow erosion and deposition

Runoff-generated debris flows are a known response to wildfire, and accurately predicting the volume of these debris flows is important for estimating the magnitude of downstream hazards. Prior data collection efforts have focused on debris-flow volume measurements at catchment outlets, but few studies have considered how erosion and deposition modulate the volume of sediment arriving at catchment outlets. This study takes advantage of a high-resolution dataset to document the factors that control the total debris-flow volume reaching the catchment outlet during a fatal postfire debris flow. Using pre- and post-event airborne lidar, satellite imagery and field mapping, we found that a postfire debris flow in the Black Hollow catchment in northern Colorado eroded 136,000 ± 30,000 m 3 and redeposited 27,000 ± 7,500 m 3 in the main channel. Most of the in-channel deposition (52% by volume) occurred where a confined channel reach transitioned to an unconfined channel reach downstream, allowing the flow to widen and deposit material. Wood jams played multiple roles in the debris-flow dynamics, both nucleating deposition (25% of the deposit volume was stored behind wood jams) and exacerbating erosion (50% of the total erosion occurred downstream from a wood dam break). The remaining deposition occurred due to spatial changes in channel slope as well as deposition observed at newly formed channel bars. Using these data in this study, we identified topographic and vegetation metrics that can be used (pre-event) to anticipate where deposition may occur in channels prior to a debris flow.

Colorado

On-demand global Landsat evapotranspiration product: Development, evaluation, and dissemination

Global actual evapotranspiration (ET) is one of the essential climate variables needed to understand and manage the relationships among food, energy, and water resources. The U.S. Geological Survey Earth Resources Observation and Science (EROS) Center launched a provisional ET product in 2020, offering on-demand, field-scale global coverage derived from Landsat data through the EROS Science Processing Architecture (ESPA) platform. The ESPA interface provides ET data for cloud-free Landsat overpasses starting in 1982 with Landsat 4 through the current Landsat 9. The ET data are delivered as a Provisional Level-3 Science product created using the Operational Simplified Surface Energy Balance (SSEBop) model. Landsat surface temperature and reference ET are the main model drivers along with vegetation index and net radiation for model parameterization. A large volume of Landsat-based ET orders (e.g., over 1,200,000 images from June 2020 through December 2025) around the world indicate increasing awareness and application of the ET data. The ESPA platform enables land and water resource managers and researchers to access a first-order ET product without requiring advanced knowledge of remote sensing technology or evapotranspiration modeling. We present the methodology and workflow of the on-demand Landsat ET product and its performance evaluations over diverse hydro-climatic settings. The product can help estimate field-scale consumptive water use and thus quickly and consistently assess historical water use, allocation, and budget to inform water management under changing environments. Future ET data aggregated to monthly and seasonal time scales are expected to enhance integration with decision-making tools and procedures.

Remote Sensing of Environment

Isotopic evaluation of the National Water Model reveals missing agricultural irrigation contributions to streamflow across the western United States

The National Water Model (NWM) provides critical analyses and projections of streamflow that support water management decisions. However, the NWM performs poorly in lower-elevation rivers of the western United States (US). The accuracy of the NWM depends on the fidelity of the model inputs and the representation and calibration of model processes and water sources. To evaluate the NWM performance in the western US, we compared observations of river water isotope ratios ( 18 O / "> 16 O and 2 H / "> 1 H expressed in δ notation) to NWM-flux-estimated (model) river reach isotope ratios. The modeled estimates were calculated from long-term (2000–2019) mean summer (June, July, and August) NWM hydrologic fluxes and gridded isotope ratios using a mass balance approach. The observational dataset comprised 4503 in-stream water isotope observations in 877 reaches across 5 basins. A simple regression between observed and modeled isotope ratios explained 57.9 % ( δ 18 O) and 67.1 % ( δ 2 H) of variance, although observations were 0.5 ‰ ( δ 18 O) and 4.8 ‰ ( δ 2 H) higher, on average, than mass balance estimates. The unexplained variance suggest that the NWM does not include all relevant water fluxes to rivers. To infer possible missing water fluxes, we evaluated patterns in observation–model differences using δ 18 O diff ( δ 18 O obs − δ 18 O mod ) and d diff ( δ 2 H diff - 8 ⋅ δ 18 O diff "> ). We detected evidence of evaporation in observations but not model estimates (negative d diff and positive δ 18 O diff ) at lower-elevation, higher-stream-order, arid sites. The catchment actual-evaporation-to-precipitation ratio, the fraction of streamflow estimated to be derived from agricultural irrigation, and whether a site was reservoir-affected were all significant predictors of d diff in a linear mixed-effects model, with up to 15.2 % of variance explained by fixed effects. This finding is supported by seasonal patterns, groundwater levels, and isotope ratios, and it suggests the importance of including irrigation return flows to rivers, especially in lower-elevation, higher-stream-order, arid rivers of the western US.

Hydrology and Earth Systems Science

Latitudinal gradients of snow contamination in the Rocky Mountains associated with anthropogenic sources

Seasonal snow is an important source of drinking water and recreation, and for agriculture in the Rocky Mountain region. Monitoring snow-water quality can inform on the effects to the albedo and energy balance of the snowpack, and the sources of natural and anthropogenic aerosol and gases. This study analyzed metals in the seasonal snowpack from water year (WY) 2018 for 49 sites. Calcium, lanthanum, and cerium concentrations support the importance of mineral dust to the southern Rocky Mountains. Mercury (Hg), zinc (Zn), and cadmium (Cd) concentrations showed a similar spatial pattern to mineral dust, whereas antimony (Sb) concentrations were highest in the northern Rocky Mountains. To assess the relative contributions from dust versus anthropogenic contaminant sources, enrichment factors (EF) were calculated, with values above 10 indicating anthropogenic contamination. For Cd, Hg, Sb, and Zn, EF values exceeded 10 at northern sites. These observations were compared to spatial trends of EF values of Hg from WY2009 to WY2018, regional monitoring networks, and back trajectory analyses. The agreement between these datasets revealed temporally consistent contaminant sources and/or transport processes to the northern Rocky Mountains snowpack. Sources include current and historical mining and smelting in the region. Strategies to limit the emissions of these metals to the Northern Rockies could benefit from focusing on remediation of contaminated sites, and continued monitoring and mitigation of active mining and smelting.

Colorado , Idaho, Montana, New Mexico, Utah, Wyomi

Using visualization science to inform the design of environmental decision-support tools—A case study of the U.S. Geological Survey Waterwatch

Environmental decision-support tools are increasingly being used to serve both expert and non-expert audiences. Many existing tools are primarily expert-focused, and redesigning them can be challenging because experts and non-experts interact with tools differently, existing users may be resistant to changes, and there is little guidance on how to prioritize redesign efforts and demonstrate their efficacy. In this report, we present a case study of a user-centered redesign of an established environmental decision-support tool—the U.S. Geological Survey WaterWatch. WaterWatch supports flood, drought, and other water resource management decisions through the display of water levels at gages across the United States. Using a participatory process, we identified a functional change (replacing the existing rainbow colormap), created an alternative design, and tested the alternative’s usability through two general public surveys. The results showed that replacing the rainbow colormap with a more intuitive diverging colormap improves usability, regardless of the audience’s subjective preference for the rainbow color scheme. In addition, we demonstrated the importance of using legends to improve the audience’s understanding of the map symbols. This study demonstrates how user-centered design approaches can be used to inform the design of high-profile products and tools.

Scientific Investigations Report

Evaluating mass flow meter measurements from chambers for greenhouse gas emissions from orphan wells and other point sources

This study evaluates the performance of a rigid gas flux chamber equipped with a mass flow meter (MFM) for measuring gas emissions from leaking orphan wells and similar pressure-driven gas point sources. We conducted a series of laboratory and field experiments to evaluate the sensitivity, stability, and dynamic range of an MFM chamber system and found an optimal method for sealing the chamber to the ground to isolate the emission source. From these results, we estimate the effects of different soil gas permeabilities on measurements and identify the uncertainty of environmental processes that can impact measurements. Simulations of an MFM chamber are compared to those of a dynamic flux chamber to contrast the data derived with both methodologies and illustrate the potential for measuring high variability leaks with the MFM chamber. Using a low flow resistance MFM and a chamber well-sealed to the ground, it is possible to measure leaks down to 1.08 x 10 -3 cubic meters per hour (m 3 h −1 ) (refenced to 25°/1 atm), corresponding to 0.77 grams per hour (g h −1 ) methane or 2.11 g h −1 carbon dioxide, with a mean uncertainty of 0.89 % relative standard deviation. Environmental processes such as heated gas inside the chamber from solar gain, wind blowing across the chamber vent, and changing humidity in the chamber, can cause variation in MFM measurements. Over 11 d of continuous monitoring under varying weather conditions, the standard deviation of the environmentally sourced signals was found to be 7.40 x 10 -3 m 3 h −1 (equivalent to or 5.27 g h −1 methane or 14.45 g h −1 carbon dioxide). Strategies to obtain the highest quality data from MFM chambers include burying the edges of the chamber below the surface sufficiently deep to seal the chamber edges against gas flow and soaking the dirt with water to lower the chances of escaping gases, while monitoring the gas flow and adjusting the chamber seal to achieve a maximum flow rate.

Atmospheric Measurement Techniques

Streams, springs, and volcanic lakes for volcano monitoring

Introduction Volcanic unrest can trigger appreciable change to surface waters such as streams, springs, and volcanic lakes. Magma degassing produces gases and soluble salts that are absorbed into groundwater that feeds streams and lakes. As magma ascends, the amount of heat and degassing will increase, and so will any related geochemical and thermal signal. Subsurface magma movement can cause pressurization that alters hydrostatic head and may induce groundwater discharge. Fluid-pressure changes have been linked to distal volcano-tectonic earthquakes (White and McCausland, 2016; Coulon and others, 2017) and phreatic eruptions (for example, Yamaoka and others, 2016). Clearly, changes in groundwater and surface waters are both indicators of unrest and clues to how and where magma is rising toward the surface. Where possible, it is prudent to incorporate real-time hydrologic data into multiparameter monitoring of restless volcanoes. Hydrologic dynamics can also be tracked by changes in groundwater levels that are commonly measured in shallow boreholes (see of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–K, 5 p., https://doi.org/10.3133/sir20245062k. ">chapter K , this volume, on boreholes; Hurwitz and Lowenstern, 2024). Although inferred to be common, relatively few volcano-hydrology anomalies are well documented, and many are essentially anecdotal (Newhall and others, 2001), reflecting the fact that high-resolution time series remain rare. Extreme examples include the 2008 eruption of Nevado del Huila, Colombia, where relatively minor phreatomagmatic eruptions were accompanied by expulsion of as much as 300 million cubic meters of groundwater from fissures high on the volcano (Worni and others, 2011), generating large lahars. Substantial decreases in flow rate from springs about 8 kilometers from the summit of Mayon Volcano, Philippines, have been noted before most eruptions in the 20th century (Newhall and others, 2001). Stream monitoring at Redoubt Volcano in 2009 allowed Werner and others (2012) to recognize that groundwater was unable to absorb (or scrub) the high flux of volcanic gas and that a high CO 2 /SO 2 precursor signal had been evident for 5 months prior to the eruption. A key to better interpreting hydrologic anomalies—or even identifying them—is therefore obtaining adequate baseline data. Most hydrologic monitoring at U.S. volcanoes has been accomplished by intermittent sampling surveys with annual or less frequent sampling (for example, https://hotspringchem.wr.usgs.gov/index.php ). More frequent sampling, however, generally is needed to establish reliable baselines. A recent hydrologic and hydrothermal monitoring experiment at 25 sites and 10 of the 12 level 4 (very high threat) volcanoes in the U.S. portion of the Cascade Range demonstrated that there is sufficient temporal variability in hydrothermal fluxes, even during quiescent periods, that one-time measurements will commonly have limited interpretive value (Crankshaw and others, 2018). Thus, surveys are best augmented with data from streamgages (for example, Evans and others, 2004; Bergfeld and others, 2008). Streamflow (water discharge) data allow measured temperature and specific conductance to be converted to heat and solute mass fluxes, which could be insightful parameters for detecting anomalous activity (McCleskey and others, 2012). At the Yellowstone Caldera, long-term monitoring of river solutes has allowed calculation of the chloride flux, a proxy for heat discharge (Hurwitz and others, 2007; McCleskey and others, 2016) from the subsurface magma. This is readily accomplished because data from streamgages are continuously recorded and archived by the U.S. Geological Survey (USGS) National Water Information System (NWIS) (USGS, 2024). Similar studies on stratovolcanoes or shield volcanoes would be scientifically useful, and yet are logistically challenging, requiring streamgages on numerous radial drainages complemented by either frequent manual sampling or numerous deployments of equipment to measure water temperature and specific conductance as a proxy for water chemistry. Another challenge is that some volcanic areas, especially shield volcanoes, are characterized by near-surface porous rocks and soils, such that surface streams are rare and replaced by distant, dilute large-volume springs with only a trace of any original volcanically sourced water (Manga, 2001; Hurwitz and others, 2021). Volcanic lakes are worthy of special attention for monitoring efforts, as their temperature and composition can provide evidence of increased flux of volatile-rich fluids from below. Quantifying changes in volatile and heat release from magma can be simpler in lakes than for volcanoes with radial drainages and no major lakes. Moreover, volcanic lakes pose a range of hazards themselves, including phreatomagmatic eruptions, debris flows, flank collapse, tsunamis, and toxic gas release (Mastin and Witter, 2000; Delmelle and others, 2015; Manville, 2015; Rouwet and others, 2015)—hazards that have historically been responsible for substantial loss of life at many volcanoes worldwide (Manville, 2015). Catastrophic CO 2 release at Lake Nyos, Cameroon, in 1986 suffocated about 1,750 people and about 3,500 livestock and was probably triggered by a large landslide into the gas-saturated lake (Kling and others, 1987; Evans and others, 1993). Gas-charged springs in Soda Bay within Clear Lake (California) have caused almost a dozen deaths to bathers in the past hundred years (ABC News, 2000). A 2005 example of lake overturn and abundant gas release was documented at Mount Chiginagak in Alaska (Schaefer and others, 2008) but did not result in any human casualties. Although thermally stratified lakes, which promote trapping of exsolved magmatic gas, tend to develop in tropical regions, the phenomenon can also arise where salinity creates meromixis (a condition in which a lake does not mix completely), as occurs in Mono Lake, California (Jellison and Melack, 1993; Jellison and others, 1998). If magma erupts or flows into a lake, the interaction between hot magma and cold water can be explosive (Mastin and others, 2004; Zimanowski and others, 2015) and substantially expand the area affected by the eruption. Another hazard is the breaching of crater rims by landslides triggered by volcanic and (or) seismic activity. Under some circumstances, substantial volumes of water can be displaced, leading to large floods and lahars. Late Holocene lake flooding from Aniakchak Crater in the Alaska Peninsula (Waythomas, 2022) and from Paulina Lake in Newberry Crater, Oregon (Chitwood and Jensen, 2000), caused by the failure of outlet sills, testify to the substantial hazards at lake-filled calderas. Several volcanic systems in the United States host lakes known to receive heat and gas from underlying magma. These lakes vary widely in area, depth, and chemical composition. Lakes are present at level 4 volcanoes, including Crater Lake and Newberry Volcano in Oregon; Yellowstone Caldera in Wyoming; Long Valley Caldera, Clear Lake volcanic field, Medicine Lake, and Salton Buttes in California; and Aniakchak Crater, Mount Katmai, Fisher Caldera, Mount Okmok, and Kaguyak Crater, among others, in Alaska. A water lake was present in Halemaʻumaʻu, the crater of Kīlauea, Hawai‘i (fig. F1), from October 2019 to December 2020. Level 3 volcanoes with lakes include Mono Lake volcanic field (Calif.), Mount Bachelor (Ore.), Ukinrek Maars and Mount Chiginagak (Alaska), and Soda Lake (Nevada). In addition, there are lakes at many levels 1 and 2 volcanoes. In the United States, there are no strongly acidic lakes that receive abundant input of magmatic gas, such as those found at Mount Ruapehu (New Zealand), Ijen and Kelud (Indonesia), and Poás (Costa Rica). Nevertheless, many contain fluids that provide clues to magmatic processes below. Since publication of a previous report on recommended instrumentation for volcano monitoring (Moran and others, 2008), continuous hydrologic monitoring has become increasingly feasible. However, changes in water pressure, temperature, and chemistry remain, in general, poorly studied phenomena at volcanoes (Sparks, 2003; National Academies of Sciences, Engineering, and Medicine, 2017). Recent efforts by the USGS have included the temporary study of Cascade Range volcanoes, which included frequent (15 minute to hourly) temporal sampling of temperature, depth, and conductivity (Crankshaw and others, 2018; Ingebritsen and Evans, 2019). At Yellowstone Caldera, many streamgages have now added thermistors and specific conductance sensors, allowing estimation of time-dependent chloride flux as a proxy for variations in subsurface heat flux (McCleskey and others, 2012, 2016). Efforts to better understand lakes have also accelerated, with bathymetric mapping and sampling carried out at several locations in the United States. Especially thorough work was done at Yellowstone Lake thanks to the Hydrothermal Dynamics of Yellowstone Lake (HD-YLAKE, https://hdylake.org ) project, funded primarily by the National Science Foundation. In addition to geophysical surveys and recovery of cores and other samples, HD-YLAKE investigations included remotely operated vehicle (ROV) investigations of hydrothermal vents on the lake floor (fig. F2). Data collected by the ROV provided a better understanding of the thermal and chemical influx from lake-bottom hydrothermal systems (Sohn and others, 2017). In this chapter, we focus on detecting changes in the chemistry, temperature, discharge, or water levels of streams, springs, and lakes that can be caused by seismicity, volumetric strains, or increases in gas flux associated with ascending magma. There is unavoidable overlap with other chapters of this report. Samples of water and gas can also be obtained in boreholes ( of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–K, 5 p., https://doi.org/10.3133/sir20245062k. ">chapter K , this volume; Hurwitz and Lowenstern, 2024), both shallow and deep. Gas monitoring ( of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–E, 11 p., https://doi.org/10.3133/sir20245062e.">chapter E , this volume; Lewicki and others, 2024) relies in part on samples from springs and wells, particularly where measurable gas plumes are absent. Water acts as a trigger and lubricant for landslides and sediment-rich floods, and so hydrology has obvious relevance for lahar monitoring, as discussed in of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–H, 6 p., https://doi.org/10.3133/sir20245062h. ">chapter H (this volume; Thelen and others, 2024). Shared situational awareness among scientists engaged in geophysical, gas, and hydrologic monitoring will improve overall understanding of the volcanic hazard.

Scientific Investigations Report

Regional models for postfire debris-flow likelihood and rainfall thresholds across the western United States

The U.S. Geological Survey (USGS) uses an empirical model developed with logistic regression (the ‘M1’ model) to rapidly assess debris-flow likelihood and to identify quantitative rainfall thresholds for debris flows after wildfire in the western United States. The M1 model was calibrated to a debris-flow inventory from southern California (United States) and has been applied throughout the western United States. Limited spatial coverage in the calibration dataset has motivated evaluation of M1 model accuracy outside the calibration region (e.g., the Sierra Nevada or the eastern Cascade Range, United States). Previous test cases showed that M1 overpredicts debris-flow likelihood and underpredicts rainfall thresholds for some locations (e.g., Arizona, northern California, Colorado, New Mexico, United States). We sought to improve the regional applicability of a debris-flow likelihood model by expanding the debris-flow inventory used for calibration, testing multiple potential models and generating an updated model framework. The updated inventory includes 3788 observations from 67 burned areas paired with short duration rainfall ratios. The updated model framework consists of a modified model structure and sets of coefficients calibrated separately to the entire updated inventory and to subsets of the inventory that intersect three Environmental Protection Agency (EPA) Level 2 ecoregions (Mediterranean California, Upper Gila Mountains and Western Cordillera). Comparisons of predictions from the updated models with observed rainfall and debris-flow activity show that the updated models outperform the M1 model by ~15%–60% and improve the uniformity of predictive performance across the western United States. The updated models also reduce false positive rates relative to M1 and generate rainfall thresholds that are better aligned with relative differences in regional climatology and debris-flow activity.

Arizona, California, Colorado, Idaho, Montana, Nev

Characterization of hydrogeologic units using matrix properties, Yucca Mountain, Nevada

Determination of the suitability of Yucca Mountain, in southern Nevada, as a geologic repository for high-level radioactive waste requires the use of numerical flow and transport models. Input for these models includes parameters that describe hydrologic properties and the initial and boundary conditions for all rock materials within the unsaturated zone, as well as some of the upper rocks in the saturated zone. There are 30 hydrogeologic units in the unsaturated zone, and each unit is defined by limited ranges where a discrete volume of rock contains similar hydrogeologic properties. These hydrogeologic units can be easily located in space by using three-dimensional lithostratigraphic models based on relation- ships of the properties with the lithostratigraphy. Physical properties of bulk density, porosity, and particle density; flow properties of saturated hydraulic conductivity and moisture-retention characteristics; and the state variables (variables describing the current state of field conditions) of saturation and water potential were determined for each unit. Units were defined using (1) a data base developed from 4,892 rock samples collected from the coring of 23 shallow and 8 deep boreholes, (2) described lithostratigraphic boundaries and corresponding relations to porosity, (3) recognition of transition zones with pronounced changes in properties over short vertical distances, (4) characterization of the influence of mineral alteration on hydrologic properties such as permeability and moisture-retention characteristics, and (5) a statistical analysis to evaluate where boundaries should be adjusted to minimize the variance within layers. This study describes the correlation of hydrologic properties to porosity, a property that is well related to the lithostratigraphy and depositional and cooling history of the volcanic deposits and can, therefore, be modeled to be distributed laterally. Parameters of the hydrogeologic units developed in this study and the relation of flow properties to porosity that are described can be used to produce detailed and accurate representations of the core-scale hydrologic processes ongoing at Yucca Mountain.

Nevada

Assessing legacy nitrogen in groundwater using numerical models of the Long Island aquifer system, New York

Nitrogen transported along groundwater flow paths in coastal aquifers can contribute substantially to nitrogen loading into surface water receptors, particularly in hydrologic systems dominated by groundwater discharge. Nitrogen entrained in the aquifer is a function of land use and associated nitrogen sources at the time of groundwater recharge, which may differ considerably from present-day sources. Legacy nitrogen can result in substantial discrepancies between observed present-day nitrogen loading to surface water receptors and loading estimated from present-day sources. Additionally, legacy nitrogen can continue to discharge into surface waters after nitrogen mitigation actions have been undertaken. Here, we use a numerical modeling framework to compare three methods of estimating time-varying historical nitrogen loads to four water bodies (receptors) on eastern Long Island, New York. The methods span a range of data requirements and process complexity, from instantaneous receptor loads calculated from steady-state groundwater contributing areas, to transient loads estimated by explicitly simulating legacy groundwater nitrogen transport over a century with large changes in nitrogen sources and hydrologic conditions. The effects of legacy nitrogen on estimated receptor loads varied temporally and spatially within the study area. Depending on antecedent nitrogen inputs and hydrologic conditions, historical annual nitrogen loads estimated from transient simulations accounting for legacy nitrogen can be quite similar (<10% difference) or substantially different (±100%) from those estimated from simpler instantaneous methods. Continued input of present-day nitrogen sources using methods that account for legacy nitrogen results in asymptotic increases in receptor nitrogen loads over time, indicating that simulated present-day receptor nitrogen loads are not in equilibrium with present-day inputs. For these receptors in disequilibrium, models simulating transient groundwater nitrogen transport could be used to account for legacy nitrogen lag times to help resource managers evaluate the potential effectiveness of proposed nitrogen mitigation actions.

EarthArXiv

Exploring landscape and geologic controls on spatial patterning of streambank groundwater discharge in a mixed land use watershed

Preferential groundwater discharge features along stream corridors are ecologically important at local and stream network scales, yet we lack quantification of the multiscale controls on the spatial patterning of groundwater discharge. Here we identify physical attributes that best explain variation in the presence and lateral extent of preferential groundwater discharges along two 5th order streams, the Housatonic and Farmington Rivers, and 32 1st to 4th order reaches across the Farmington River network. We mapped locations of preferential groundwater discharge exposed along streambanks using handheld thermal infrared cameras paired with high-resolution topographic and land use land cover datasets, surficial soil characteristic maps, and depth-to-bedrock geophysical measurements. The unconfined Housatonic River, MA, USA (12 km) had fewer discharge locations and less lateral extent (41 discharge locations with 38 m of active discharge/km of river) compared to the partially confined Farmington River, CT, USA (26 km; 169 discharge locations with 129 m of active discharge/km of river). Using a moving window analysis, we found along both rivers that discharge was more likely to occur where bank slopes were steeper, floodplain extent was narrower, and degree of confinement was higher. Along the Farmington River, groundwater discharge was more likely to occur where saturated hydraulic conductivity was higher and depth-to-bedrock was shallower. Among the 32 stream reaches surveyed (33.2 km of total stream length) within the Farmington River watershed, preferential discharge was observed in all but two stream reaches, varied from 0 to 25% of lateral extent along stream banks (mean = 6%), and was more likely to occur where stream reach slopes were steep, saturated hydraulic conductivity was high, and watershed urbanization was low. Our results show that, though both surface (e.g., topographic, land use land cover) and subsurface (e.g., soil characteristics, bedrock depth) factors control the prevalence of streambank preferential groundwater discharge, the dominant controls vary across valley settings and stream sizes.

Connecticut, Massachusetts

The saline groundwater legacy of a large buried coastal paleo-estuary

Elevated groundwater salinity in coastal regions threatens the beneficial use of fresh groundwater. Coastal groundwater management typically focuses on preventing intrusion from modern sources of seawater; however, past geological processes can also leave a legacy of saline groundwater now hidden in the subsurface. Here, multiple extensive airborne electromagnetic surveys provide detailed evidence of residual salinity from a paleo-estuary filling a late Pleistocene incised valley impacting more than 10,000 km 2 that is now hidden beneath coastal Louisiana’s deltaic plain. Our results show that the three-dimensional pattern of saline groundwater beneath Louisiana mimics that of near-surface aquifers surrounding the modern Delaware Bay estuary, fingerprinting the signature of the past drowning of a large, incised valley of the Mississippi River following post-glacial sea-level rise. These findings demonstrate a new framework for understanding legacy sources of saltwater critical for managing stressed water resources along global coastlines.

Louisiana

Linking permafrost to the abundance, biomass, and energy density of fish in Arctic headwater streams

Permafrost thaw alters groundwater flow, river hydrology, stream-catchment interactions, and the availability of carbon and nutrients in headwater streams. The impact of permafrost on watershed hydrology and biogeochemistry of headwater streams has been demonstrated, but there is little understanding of how permafrost influences fish in these ecosystems. We examined relations among permafrost characteristics, the resulting changes in water temperature, stream hydrology (e.g., discharge flashiness), and macroinvertebrates, with the abundance, biomass, and energy density of juvenile Dolly Varden ( Salvelinus malma ) and Arctic Grayling ( Thymallus arcticus ) across 10 headwater streams in northwestern Alaska. Macroinvertebrate density was driven by concentrations of dissolved carbon and nutrients supporting stream food webs. Dolly Varden abundance was primarily related to water temperature with fewer fish in warmer streams, whereas Dolly Varden energy density decreased with the flashiness of the headwater streams. Dolly Varden biomass was related to both temperature and bottom-up food web effects. The energy density of Arctic Grayling decreased with warmer temperatures and discharge flashiness. These relations demonstrate the importance of terrestrial–aquatic connections in permafrost landscapes and indicate the complexity of landscape effects on fish. Because permafrost thaw is one of the most impactful changes occurring as the Arctic warms, an improved understanding of how stream temperature, hydrology, and bottom-up food web processes influence fish populations can aid forecasting of future conditions across the Arctic.

Alaska

Distinguishing natural sources from anthropogenic events in seismic data

As seismic data are increasingly used to investigate a diverse range of subsurface phenomena beyond regular fast-rupturing earthquakes (Peng and Gomberg, 2010; Beroza and Ide, 2011), it is important to acknowledge that human-generated ground vibrations may be mistaken for naturally generated subsurface processes (Larose et al., 2015; Li et al., 2018). Correct discrimination of natural processes from anthropogenic noise is especially pressing given the trend in seismic detection research toward automated algorithms and machine learning methods (Yoon et al., 2015; Kong et al., 2019;Mousavi and Beroza, 2022) and the growth in seismic data collection in new environments such as urban and industry settings (e.g., Díaz et al.,2017).

Seismological Research Letters

Gulf Coast Basin CORE-CM initiative final report

The Bureau of Economic Geology at the University of Texas at Austin (UT-BEG) is leading the Gulf Coast Carbon Ore, Rare Earth, and Critical Minerals (CORE-CM) Initiative to assess the potential to produce critical minerals (CMs), including rare earth elements (REEs) from coal, coal ash, and produced water related to oil and gas production, and related materials (alumina processing waste [red mud], heavy mineral sands, graphite, and zeolite) within the Gulf Coast Basin. This project represents the first phase in a long-term program and provides reconnaissance data that will be foundational for future work by assessing resources and suggesting plans to be conducted in future work and expanding stakeholder engagement. The project includes several tasks designed to identify, characterize, and assess several necessary aspects for development of CMs and REEs in the Gulf Coast Basin.

Gulf Coast basin

Groundwater hydrology, groundwater and surface-water interactions, water quality, and groundwater-flow simulations for the Wet Mountain Valley alluvial aquifer, Custer and Fremont Counties, Colorado, 2017–19

In 2017, the U.S. Geological Survey, in cooperation with the Upper Arkansas Water Conservancy District, began a study to provide a comprehensive analysis of the Wet Mountain Valley alluvial aquifer, Custer and Fremont Counties, Colorado. The study included collection of data pertaining to groundwater hydrology, groundwater and surface-water interactions, and water quality in the alluvial aquifer. In addition to providing foundational information on the hydrology of the alluvial aquifer, a numerical groundwater-flow model was developed to estimate the potential effects of additional storage of groundwater in the alluvial aquifer. Groundwater-level elevation data from 30 wells were used to estimate groundwater-flow directions in the alluvial aquifer, which were generally from the southwest to northeast, away from the Sangre de Cristo Mountains and towards perennial streams in the center of the valley. Although some seasonal variation was apparent in groundwater-level elevation records, no statistically significant seasonal trends were indicated. Statistically significant long-term trends were indicated in groundwater-level elevation records for 8 of the 30 wells, and of these wells with statistically significant trends, all but 1 indicated a negative trend of groundwater-level elevations. Spatial evaluation of wells with statistically significant negative groundwater-level elevation trends showed many are in areas of denser well drilling for domestic or other uses, indicating increasing groundwater use could potentially be causing groundwater-level elevation declines. There were instances of wells with no statistically significant groundwater-level elevation trends also located in areas of greater density of well completions. Additional investigations may be necessary to more fully characterize the processes responsible for negative groundwater-level elevation trends. Streamflow gain or loss calculations were completed for low flow in 2017–19 and for high flow in 2018 in nine reaches of streams within the study area. Stream reaches of the upper Texas Creek, upper Grape Creek, upper-middle Grape Creek, and Taylor Creek displayed consistent streamflow loss in each period from 2017 to 2019. These stream reaches represent long-term sources of recharge to the alluvial aquifer. Streamflow gain or loss varies through time in other stream reaches (lower Texas Creek, lower-middle Grape Creek, lower Grape Creek below Westcliffe, and lower Grape Creek above DeWeese Reservoir). The temporally variable behavior indicates these stream reaches may be sources of groundwater recharge or areas of groundwater discharge, likely depending on temporal dynamics between the elevation of the water table and the stream. Water-quality samples were collected from 10 groundwater wells and 10 stream sites during September through November 2019. All groundwater and stream samples were analyzed for major and trace elements and stable isotopes of water. A subset of groundwater samples was also analyzed for the environmental tracers sulfur hexafluoride, tritium, and noble gases. Comparison of water-quality results to U.S. Environmental Protection Agency drinking water-quality standards indicated no constituents exceeded primary standards for human health. Spatial evaluation of water quality indicated the concentrations of various constituents are likely controlled by groundwater and surface-water interactions and by spatial variability in bedrock geology underlying the alluvial aquifer. Specifically, streams shown to gain from groundwater had water chemistry constituent compositions similar to groundwater, whereas streams exiting the Sangre de Cristo Mountains tended to have compositions consistent with snowmelt. Groundwater geochemistry appeared to be partially controlled by oxidation-reduction processes and by proximity to igneous rocks in the Wet Mountains. Environmental tracers used to estimate groundwater age indicated all sampled groundwater contained tracers representing modern recharge (approximately less than 65 years old) but mixing of premodern recharge (approximately more than 65 years old) also occurs. Spatial evaluation of environmental tracers indicated large faults may be conduits for upwelling of older groundwater. No trends were observed in groundwater age with well depth, indicating all sampled wells are located within the zone of active groundwater flow. The presence of modern groundwater in wells with statistically significant negative groundwater-level elevation trends indicates groundwater storage depletions may be partially offset by capture of modern recharge. Repeated sampling of groundwater age would be necessary, however, to determine if any trends in groundwater age exist, which may indicate changing groundwater recharge, storage, or discharge. Additional investigations could also consider quantifying groundwater age in deeper wells to more fully define the depth of active groundwater flow. A numerical groundwater-flow model was developed to estimate components of the water budget, simulate groundwater and surface-water interactions, and evaluate the potential effects of aquifer storage and recovery. Simulated groundwater-level elevations from the calibrated groundwater-flow model are similar to the observed pattern of groundwater-level elevations with higher elevations in the western part of the study area along the Sangre de Cristo Mountains. Simulated water-budget components indicate most of the recharge to the alluvial aquifer is derived from streamflow losses, which is consistent with observations of losing streams along the mountain front. The largest groundwater discharge component of the alluvial aquifer was to streams in the center of the valley, where observations of stream gain or loss indicated the predominance of gaining conditions. Comparison of groundwater and surface-water interactions between the calibrated groundwater-flow model for 2000-19 (the base-case model) and a simulation including additional recharge, representing potential aquifer storage and recovery operations, indicated the additional recharge distributed throughout the area had minimal effects on streamflow in the nearby Grape Creek. An analysis of subregional groundwater budgets showed approximately 54 percent of the additional recharge flowed back to nearby Grape Creek, and the other 46 percent was distributed laterally into adjacent cells in the alluvial aquifer. The comparison of simulations and subregional water budget show the additional recharge did not substantially alter groundwater-level elevations or basin wide groundwater storage. Although the analysis of additional recharge provided in the numerical groundwater-flow model considers only one of many possible recharge scenarios, the model provides a useful tool that could be modified for various scenarios to understand potential effects of managed aquifer recharge.

Colorado

Groundwater response to managed aquifer recharge at the Southeast Houghton Artificial Recharge Project in Tucson, Arizona

Managed aquifer recharge is a widespread practice for storing water in the subsurface as groundwater. At a managed aquifer recharge facility in southern Arizona, groundwater-level and repeat microgravity data were collected to monitor aquifer response. These data were used to inform parameter identification for an unsaturated-zone flow model used to simulate the recharge process. The facility, the Southeast Houghton Artificial Recharge Project (SHARP), consists of 3 surface basins (about 27,600 square meters [6.8 acres] total surface area) where recycled water is distributed in recharge cycles lasting several months, with dry periods in between. During the study period, December 2020–December 2022, Tucson Water (the City of Tucson’s water utility) reported 6.56×10 6 cubic meters of water (5,320 acre-feet) recharged. Monitoring included groundwater-level observations at 3 monitoring wells and repeat microgravity measurements at as many as 22 locations (some stations were destroyed between surveys). Six gravity surveys were carried out using absolute- and relative-gravity meters. Large gravity increases, more than 250 microgals, were observed during the first repeat survey, 3.5 months after the start of recharge, but only in the immediate vicinity of the recharge basins. Data show that water moved downward to the water table, and storage changes in the unsaturated zone away from the facility were likely minimal. Gravity decreased at stations more than 1 kilometer from the facility, consistent with regional groundwater-level changes. Groundwater-level increases in wells adjacent to the recharge basins began 2 months after the second repeat gravity survey, and 5.5 months after recharge began. Unsaturated-zone flow modeling was carried out using software that simulates water movement and parameter estimation. Model calibration was carried out by minimizing an objective function calculated from the differences between simulated and observed groundwater levels, and between simulated and observed repeat microgravity data. Including repeat microgravity data in the objective function reduced the uncertainty in estimated parameter values for saturated hydraulic conductivity and saturated water content. Modeling indicated that the unsaturated zone between the recharge basins and the water table does not become saturated even after 685 days of simulated infiltration. This gradual wetting may account for increasing infiltration rates over time, as hydraulic conductivity increases with increasing water content. Unsaturated-zone water content decreased rapidly between recharge cycles. Model-simulated groundwater mounding extended about 1 kilometer from the center of SHARP after the 685-day period following the onset of recharge.

Arizona