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Probability of detecting elevated concentrations of nitrate in ground water in a six-county area of south-central Idaho

A probability map constructed for this study identified several areas in a six-county region of south-central Idaho with high probabilities of detecting elevated concentrations (greater than 2 milligrams per liter) of nitrate. An increasing proportion of Idaho’s ground water being used for drinking water and large increases in the inputs of nitrogen to ground water in Cassia, Gooding, Jerome, Lincoln, Minidoka, and Twin Falls Counties have prompted concerns about the quality of the resource. The probability map was constructed to assist regulatory and resource agencies in managing land use and protecting water resources. To construct the probability map, hydrogeologic and anthropogenic data were integrated with ground-water quality data in a geographic information system. The resulting data set contained land use, geology, precipitation, soil characteristics, depth to ground water, nitrogen input, and ground-water velocity information for each of the 1,365 samples collected from 1991 to 2001. Logistic regression analysis was used to determine the most statistically significant variables related to the detection of elevated nitrate concentrations. The resulting multivariate probability model showed that ground-water velocity, nitrogen input, precipitation, soil drainage, land use, and depth to ground water were significantly correlated with elevated nitrate concentrations. A subset of the water-quality data set was used to verify these results. Linear regression of the percentage of predicted probabilities of elevated nitrate concentrations and the actual percentage of elevated nitrate concentrations with the model data set and the verification data set both showed good correlations: r-squared values were 0.96 and 0.97, respectively. Statistical comparisons of both data sets showed that ground-water samples containing elevated nitrate concentrations had significantly higher probabilities of detection (p < 0.001) than samples without elevated nitrate concentrations. On the basis of these results, a map identifying the probability of detecting elevated nitrate concentrations was constructed. High-probability areas on the map coincided with regions of agricultural land use and high nitrogen input, except in southern Gooding County and western Jerome County. In these areas, high ground-water velocities representing a predominance of regional ground water resulted in a low probability of detecting elevated nitrate concentrations. Areas of poor prediction tended to be congregated along the transition zone between high and low ground-water velocities in Jerome and Gooding Counties, indicating a mix of regional and recently recharged ground water.

Idaho

Acid neutralizing capacity and leachate results for igneous rocks, with associated carbon contents of derived soils, Animas River AML site, Silverton, Colorado

Mine planning efforts have historically overlooked the possible acid neutralizing capacity (ANC) that local igneous rocks can provide to help neutralize acidmine drainage. As a result, limestone has been traditionally hauled to mine sites for use in neutralizing acid drainage. Local igneous rocks, when used as part of mine life-cycle planning and acid mitigation strategy, may reduce the need to transport limestone to mine sites because these rocks can contain acid neutralizing minerals. Igneous hydrothermal events often introduce moderately altered mineral assemblages peripheral to more intensely altered rocks that host metal-bearing veins and ore bodies. These less altered rocks can contain ANC minerals (calcite-chlorite-epidote) and are referred to as a propylitic assemblage. In addition, the carbon contents of soils in areas of new mining or those areas undergoing restoration have been historically unknown. Soil organic carbon is an important constituent to characterize as a soil recovery benchmark that can be referred to during mine cycle planning and restoration. <br/> This study addresses the mineralogy, ANC, and leachate chemistry of propylitic volcanic rocks that host polymetallic mineralization in the Animas River watershed near the historical Silverton, Colorado, mining area. Acid titration tests on volcanic rocks containing calcite (2 &ndash; 20 wt %) and chlorite (6 &ndash; 25 wt %), have ANC ranging from 4 &ndash; 146 kg/ton CaCO<sub>3</sub> equivalence. Results from a 6-month duration, kinetic reaction vessel test containing layered pyritic mine waste and underlying ANC volcanic rock (saturated with deionized water) indicate that acid generating mine waste (pH 2.4) has not overwhelmed the ANC of propylitic volcanic rocks (pH 5.8). Sequential leachate laboratory experiments evaluated the concentration of metals liberated during leaching. Leachate concentrations of Cu-Zn-As-Pb for ANC volcanic rock are one-to-three orders of magnitude lower when compared to leached solution from mine waste used in the kinetic reaction vessel test. This finding suggests that mine waste and not ANC rock may generate the majority of leachable metals in a field scenario. <br/> The organic carbon content of naturally reclaimed soils derived from weathering of propylitically-altered andesite was determined in catchments where ANC studies were initiated. Soils were found to have total carbon concentrations (TOC) that exceed global average soil TOC abundances by as much as 1.5 &ndash; 5 times. These data support an environmental management system involving use of ANC rocks as part of life-cycle mine planning to reduce post-mine closure acid mitigation measures. Carbon contents of undisturbed soils in mined catchments can possibly be used to validate post-reclamation success and help quantify carbon sequestration for CO<sub>2</sub> emission offset trading as carbon markets mature.

Colorado

Interactions of mercury with dissolved organic carbon in the Florida Everglades

There has been increased awareness by both public and scientific communities over mercury contamination of game fish in South Florida. Effective management strategies for dealing with this problem will require a more thorough understanding of the factors and processes that result in the generation and transport of mercury, and control its reactivity in the Everglades. The role of mercury complexation by dissolved organic carbon (DOC) has been proposed by several investigators as a primary mechanism for the transport of mercury in aquatic systems. However, this relationship has been simply proposed based on a strong correlation between dissolved mercury and DOC concentrations in ground, lake and stream waters. Interactions with DOC may be an important process for controlling the transport and bioavailability of mercury. The issue of carbon reactivity in South Florida is especially relevant due to the high natural production of organic carbon in the peat soils and wetlands, the relatively high carbon content of shallow ground water systems in the region, the interactions of organic matter with mercury, other trace metals, and anthropogenic compounds, accumulation of organic carbon in corals and carbonate precipitates, and the potential changes in the quality and reactivity of dissolved organic carbon (DOC) resulting from land use practices. This study will attempt to meet the need to more clearly understand the dynamics of organic matter mercury interactions in the Florida Everglades by focusing research on the effect of dissolved organic carbon (DOC) on the transport and reactivity of Hg in the Everglades.

Florida

Application of a coupled vegetation competition and groundwater simulation model to study effects of sea level rise and storm surges on coastal vegetation

Global climate change poses challenges to areas such as low-lying coastal zones, where sea level rise (SLR) and storm-surge overwash events can have long-term effects on vegetation and on soil and groundwater salinities, posing risks of habitat loss critical to native species. An early warning system is urgently needed to predict and prepare for the consequences of these climate-related impacts on both the short-term dynamics of salinity in the soil and groundwater and the long-term effects on vegetation. For this purpose, the U.S. Geological Survey&rsquo;s spatially explicit model of vegetation community dynamics along coastal salinity gradients (MANHAM) is integrated into the USGS groundwater model (SUTRA) to create a coupled hydrology&ndash;salinity&ndash;vegetation model, MANTRA. In MANTRA, the uptake of water by plants is modeled as a fluid mass sink term. Groundwater salinity, water saturation and vegetation biomass determine the water available for plant transpiration. Formulations and assumptions used in the coupled model are presented. MANTRA is calibrated with salinity data and vegetation pattern for a coastal area of Florida Everglades vulnerable to storm surges. A possible regime shift at that site is investigated by simulating the vegetation responses to climate variability and disturbances, including SLR and storm surges based on empirical information.

Journal of Marine Science and Engineering

Southern Rockies Landscape Conservation Cooperative unit watershed erosion potential prioritization for check-dam installation

Changes in land-use practices and the extirpation (local extinction) of beaver populations in the early 20th century during European settlement are believed to have resulted in many changes in how streams in the Western United States function. Some of the negative changes that have resulted include stream channelization, soil erosion, changing vegetation, water turbidity, and a loss of overland flow. Efforts to restore streams and reduce soil erosion by water have included reintroductions of beaver, incorporating Native American traditional knowledge of dry-land farming techniques, and the installation of rigid check-dams. Many of these efforts have been successful in improving both intermittent and perennial stream function. Therefore, stakeholders in the Southern Rockies Landscape Conservation Cooperative (SRLCC) have identified a need to prioritize streams within their region of interest for the installation of check-dams to continue restoration and conservation efforts and to improve sediment catchment. Using Natural Resource Conservation Service soil databases, topographic features derived from digital elevation models, stream networks, and regional climatic patterns, I developed a ranking system for watershed potential erosion rates and suitability for check-dam placement across the SRLCC. This ranking system serves as a first step for land managers to prioritize areas for check-dam installation based on relatively static factors (soil properties, topography, and hydrology) that can contribute to rates of soil erosion by water and the stability of check-dams. Many other relatively dynamic factors over time can contribute to rates of soil erosion by water, such as recent wildfire events, changes in weather patterns and extreme climate events, and changing land-use such as grazing, logging, mining, development, and cultivation. These factors that influence vegetative and biological soil crusts cover are also important elements to the potential erosion of soil by water. Because of this, SRLCC stakeholders might consider further evaluation of the watersheds identified here as high ranking. Final watershed prioritization among the high-ranking watersheds identified here should include current knowledge of land-use and land-cover estimates to identify areas at risk for soil erosion or degree of existing erosion problems.

Open-File Report

Arctic and boreal ecosystems of western North America as components of the climate system

Synthesis of results from several Arctic and boreal research programmes provides evidence for the strong role of high-latitude ecosystems in the climate system. Average surface air temperature has increased 0.3??C per decade during the twentieth century in the western North American Arctic and boreal forest zones. Precipitation has also increased, but changes in soil moisture are uncertain. Disturbance rates have increased in the boreal forest; for example, there has been a doubling of the area burned in North America in the past 20 years. The disturbance regime in tundra may not have changed. Tundra has a 3-6-fold higher winter albedo than boreal forest, but summer albedo and energy partitioning differ more strongly among ecosystems within either tundra or boreal forest than between these two biomes. This indicates a need to improve our understanding of vegetation dynamics within, as well as between, biomes. If regional surface warming were to continue, changes in albedo and energy absorption would likely act as a positive feedback to regional warming due to earlier melting of snow and, over the long term, the northward movement of treeline. Surface drying and a change in dominance from mosses to vascular plants would also enhance sensible heat flux and regional warming in tundra. In the boreal forest of western North America, deciduous forests have twice the albedo of conifer forests in both winter and summer, 50-80% higher evapotranspiration, and therefore only 30-50% of the sensible heat flux of conifers in summer. Therefore, a warming-induced increase in fire frequency that increased the proportion of deciduous forests in the landscape, would act as a negative feedback to regional warming. Changes in thermokarst and the aerial extent of wetlands, lakes, and ponds would alter high-latitude methane flux. There is currently a wide discrepancy among estimates of the size and direction of CO2 flux between high-latitude ecosystems and the atmosphere. These discrepancies relate more strongly to the approach and assumptions for extrapolation than to inconsistencies in the underlying data. Inverse modelling from atmospheric CO2 concentrations suggests that high latitudes are neutral or net sinks for atmospheric CO2, whereas field measurements suggest that high latitudes are neutral or a net CO2 source. Both approaches rely on assumptions that are difficult to verify. The most parsimonious explanation of the available data is that drying in tundra and disturbance in boreal forest enhance CO2 efflux. Nevertheless, many areas of both tundra and boreal forests remain net sinks due to regional variation in climate and local variation in topographically determined soil moisture. Improved understanding of the role of high-latitude ecosystems in the climate system requires a concerted research effort that focuses on geographical variation in the processes controlling land-atmosphere exchange, species composition, and ecosystem structure. Future studies must be conducted over a long enough time-period to detect and quantify ecosystem feedbacks.

Global Change Biology

Recent nitrogen storage and accumulation rates in mangrove soils exceed historic rates in the urbanized San Juan Bay Estuary (Puerto Rico, United States)

Tropical mangrove forests have been described as “coastal kidneys,” promoting sediment deposition and filtering contaminants, including excess nutrients. Coastal areas throughout the world are experiencing increased human activities, resulting in altered geomorphology, hydrology, and nutrient inputs. To effectively manage and sustain coastal mangroves, it is important to understand nitrogen (N) storage and accumulation in systems where human activities are causing rapid changes in N inputs and cycling. We examined N storage and accumulation rates in recent (1970 – 2016) and historic (1930 – 1970) decades in the context of urbanization in the San Juan Bay Estuary (SJBE, Puerto Rico), using mangrove soil cores that were radiometrically dated. Local anthropogenic stressors can alter N storage rates in peri-urban mangrove systems either directly by increasing N soil fertility or indirectly by altering hydrology (e.g., dredging, filling, and canalization). Nitrogen accumulation rates were greater in recent decades than historic decades at Piñones Forest and Martin Peña East. Martin Peña East was characterized by high urbanization, and Piñones, by the least urbanization in the SJBE. The mangrove forest at Martin Peña East fringed a poorly drained canal and often received raw sewage inputs, with N accumulation rates ranging from 17.7 to 37.9 g m –2 y –1 in recent decades. The Piñones Forest was isolated and had low flushing, possibly exacerbated by river damming, with N accumulation rates ranging from 18.6 to 24.2 g m –2 y –1 in recent decades. Nearly all (96.3%) of the estuary-wide mangrove N (9.4 Mg ha –1 ) was stored in the soils with 7.1 Mg ha –1 sequestered during 1970–2017 (0–18 cm) and 2.3 Mg ha –1 during 1930–1970 (19–28 cm). Estuary-wide mangrove soil N accumulation rates were over twice as great in recent decades (0.18 ± 0.002 Mg ha –1 y –1 ) than historically (0.08 ± 0.001 Mg ha –1 y –1 ). Nitrogen accumulation rates in SJBE mangrove soils in recent times were twofold larger than the rate of human-consumed food N that is exported as wastewater (0.08 Mg ha –1 y –1 ), suggesting the potential for mangroves to sequester human-derived N. Conservation and effective management of mangrove forests and their surrounding watersheds in the Anthropocene are important for maintaining water quality in coastal communities throughout tropical regions.

Puerto Rico, San Juan Bay Estuary

Ambient and potential denitrification rates in marsh soils of Northeast Creek and Bass Harbor Marsh watersheds, Mount Desert Island, Maine

Nutrient enrichment from atmospheric deposition, agricultural activities, wildlife, and domestic sources is a concern at Acadia National Park on Mount Desert Island, Maine, because of the potential problems of degradation of water quality and eutrophication in estuaries. Degradation of water quality has been observed at Bass Harbor Marsh estuary in the park but only minimally in Northeast Creek estuary. Previous studies at Acadia National Park have estimated nutrient inputs to estuaries from atmospheric deposition and surface-water runoff, and have identified shallow groundwater as an additional potential source of nutrients. Previous studies at Acadia National Park have assumed that a certain fraction of the nitrogen input was removed through microbial denitrification, but rates of denitrification (natural or maximum potential) in marsh soils have not been determined. The U.S. Geological Survey, in cooperation with Acadia National Park, measured in-place denitrification rates in marsh soils in Northeast Creek and in Bass Harbor Marsh watersheds during summer 2008 and summer 2009. Denitrification was measured under ambient conditions as well as after additions of inorganic nitrogen and glucose. In-place denitrification rates under ambient conditions were similar to those reported for other coastal wetlands, although they were generally lower than those reported for salt marshes having high ambient concentrations of nitrate (NO 3 ). Denitrification rates generally increased by at least an order of magnitude following NO 3 additions, with or without glucose (as the carbohydrate) additions, compared with the ambient treatments that received no nutrient additions. The treatment that added both glucose and NO 3 resulted in a variety of denitrification responses when compared with the addition of NO 3 alone. In most cases, the addition of glucose to a given rate of NO3 addition resulted in higher rates of denitrification. These variable responses indicate that the amount of labile carbohydrates can limit denitrification even if NO 3 is present. For most sites in both watersheds, the maximum denitrification rates ranged from of 150 to 900 micromoles of nitrous oxide per square meter per hour. These rates were equivalent to the release of 37 to 221 grams of nitrogen per square meter per year. Weak positive correlations were observed for soil temperature and for measured ammonium concentration in groundwater. Weak negative correlations were observed between denitrification rate and water level and specific conductance. The rates of denitrification in Bass Harbor Marsh and Northeast Creek under ambient conditions, both of which were relatively low, indicate that NO 3 availability is low in both systems. It is evident from the addition of combined treatments of NO 3 and glucose that these marsh soils are capable of comparatively high rates of denitrification, therefore, estuarine eutrophication is not a result of nitrogen inputs to marsh soils that are in excess of the denitrification capacity in these systems. If terrestrial inputs to the estuary are the cause of the observed eutrophic condition in Bass Harbor Marsh, then these inputs to the estuary must bypass the marsh in channelized surface flow, or perhaps they circumvent the marsh in shallow groundwater seepage along subsurface pathways that enter the estuary directly.

Maine

Groundwater recharge estimates for Maine using a Soil-Water-Balance model—25-year average, range, and uncertainty, 1991 to 2015

To address the lack of information on the spatial and temporal variability of recharge to groundwater systems in Maine, a study was initiated in cooperation with the Maine Geological Survey to use the U.S. Geological Survey Soil-Water-Balance model to evaluate annual average potential recharge across the State over a 25-year period from 1991 to 2015. The Maine Soil-Water-Balance model was calibrated using annual observations of recharge, runoff, and evapotranspiration for 32 calibration watersheds in the State during 2001–12 (902 total observations). Observations of recharge, runoff, and evapotranspiration were developed for each watershed to reduce the possibility of nonunique combinations of model parameters during the calibration. The Maine Soil-Water-Balance model was run using an optional evapotranspiration calculation method that provides more control for calibration than the standard method. The model was calibrated using the Parameter ESTimation software suite. The overall mean model error (average of all annual residuals for recharge, runoff, and precipitation) was 0.39 inch. The mean of the absolute value of the residuals, or the mean absolute error, was 2.32 inches. The root mean squared error for the calibrated model overall was 3.14 inches. Statistical tests indicated that the model residuals are normally distributed. To determine the potential uncertainty in the median annual potential recharge that results from uncertainty in the parameters as they relate to information contained in the observations, 300 alternate model realizations were run, and the standard deviation of the median potential recharge value at every pixel was calculated. Simulated 25-year median potential recharge across the State is widely variable; this variability closely follows patterns of precipitation, with additional variability contributed by the patchwork nature of the combinations of land-use class and hydrologic soil group inputs, and distribution of available water capacity in the soil across the State. Overall, the 25-year median annual potential recharge across the State is 7.5 inches, ranging from a low of about 5 inches to over 30 inches. The statewide range in the 25-year minimum values is from just over 2 inches to just over 20 inches. The statewide range in the 25-year maximum potential recharge is between 15 and 48 inches per year. The model areas with the highest simulated median potential recharge include areas underlain by type A soils (sandy and well drained), particularly those that also have land uses with low or little vegetation (blueberry barrens, developed, open space, scrub/shrub, and cropland, for example). The potential recharge values for these areas are similar to previously published values for comparable soil types. The 25-year average potential recharge grids were compared to recharge evaluated through groundwater-flow models or other methods in four hydrogeologic settings at six study areas in the State. A key factor in the ability of the Soil-Water-Balance model to reproduce the earlier study results was whether the available water-capacity data were an appropriate match for the hydrologic soil groups. The Maine Soil-Water-Balance model does a good job in representing an accurate potential recharge under circumstances where the surficial mapped soils extend below the surface to the water-table aquifer and where the available water-capacity data are in an appropriate range for the hydrologic soil group. One hydrogeologic setting that was challenging for the model was where a silt and clay layer was below a shallow soil unit that did not have available water-capacity data that were appropriate for the hydrologic soil group. In these cases, typically the available water-capacity data were very low, not accounting for the impedance of water flow provided by the underlying soil. The model also does not simulate well areas where bedrock surfaces are above the water table but below the plant rooting zone. The data products accompanying this report are intended to be used to provide first-cut estimates of recharge for geographic areas no smaller than the smallest watersheds used in the calibration of the model—or about 1.5 square miles. It is recommended that the grids are used to calculate an area-wide average potential recharge for any given area of study, and an uncertainty around the mean should be calculated from the standard deviation grid at the same time.

Maine

Reviews and syntheses: Variable inundation across Earth's terrestrial ecosystems

The structure, function, and dynamics of Earth's terrestrial ecosystems are profoundly influenced by how often (frequency) and how long (duration) they are inundated with water. A diverse array of natural and human-engineered systems experience temporally variable inundation whereby they fluctuate between inundated and non-inundated states. Variable inundation spans extreme events to predictable sub-daily cycles. Variably inundated ecosystems (VIEs) include hillslopes, non-perennial streams, wetlands, floodplains, temporary ponds, tidal systems, storm-impacted coastal zones, and human-engineered systems. VIEs are diverse in terms of inundation regimes, water chemistry and flow velocity, soil and sediment properties, vegetation, and many other properties. The spatial and temporal scales of variable inundation are vast, ranging from sub-meter to whole landscapes and from sub-hourly to multi-decadal. The broad range of system types and scales makes it challenging to predict the hydrology, biogeochemistry, ecology, and physical evolution of VIEs. Despite all experiencing the loss and gain of an overlying water column, VIEs are rarely considered together in conceptual, theoretical, modeling, or measurement frameworks and approaches. Studying VIEs together has the potential to generate mechanistic understanding that is transferable across a much broader range of environmental conditions, relative to knowledge generated by studying any one VIE type. We postulate that enhanced transferability will be important for predicting changes in VIE function in response to global change. Here we aim to catalyze cross-VIE science that studies drivers and impacts of variable inundation across Earth's VIEs. To this end, we complement expert mini-reviews of eight major VIE systems with overviews of VIE-relevant methods and challenges associated with scale. We conclude with perspectives on how cross-VIE science can derive transferable understanding via unifying conceptual models in which the impacts of variable inundation are studied across multi-dimensional environmental space.

Biogeosciences

Chemistry of burning the forest floor during the FROSTFIRE experimental burn, interior Alaska, 1999

Wildfires represent one of the most common disturbances in boreal regions, and have the potential to reduce C, N, and Hg stocks in soils while contributing to atmospheric emissions. Organic soil layers of the forest floor were sampled before and after the FROSTFIRE experimental burn in interior Alaska, and were analyzed for bulk density, major and trace elements, and organic compounds. Concentrations of carbon, nutrients, and several major and trace elements were significantly altered by the burn. Emissions of C, N, and Hg, estimated from chemical mass balance equations using Fe, Al, and Si as stable constituents, indicated that 500 to 900 g C and up to 0 to 4 ?? 10-4 g Hg/M2 were lost from the site. Calculations of nitrogen loss range from -4 to +6 g/m2 but were highly variable (standard deviation 19), with some samples showing increased N concentrations post-burn potentially from canopy ash. Noncombustible major nutrients such as Ca and K also were inherited from canopy ash. Thermogravimetry indicates a loss of thermally labile C and increase of lignin-like C in char and ash relative to unburned counterparts. Overall, atmospheric impacts of boreal fires include large emissions of C, N and Hg that vary greatly as a function of severe fire weather and its access to deep organic layers rich in C, N, and Hg. In terrestrial systems, burning rearranges the vertical distribution of nutrients in fuels and soils, the proximity of nutrients and permafrost to surface biota, and the chemical composition of soil including its nutrient and organic constituents, all of which impact C cycling. Copyright 2004 by the American Geophysical Union.

Global Biogeochemical Cycles

Evaluation of long-term water-level declines in basalt aquifers near Mosier, Oregon

The Mosier area lies along the Columbia River in northwestern Wasco County between the cities of Hood River and The Dalles, Oregon. Major water uses in the area are irrigation, municipal supply for the city of Mosier, and domestic supply for rural residents. The primary source of water is groundwater from the Columbia River Basalt Group (CRBG) aquifers that underlie the area. Concerns regarding this supply of water arose in the mid-1970s, when groundwater levels in the orchard tract area began to steadily decline. In the 1980s, the Oregon Water Resources Department (OWRD) conducted a study of the aquifer system, which resulted in delineation of an administrative area where parts of the Pomona and Priest Rapids aquifers were withdrawn from further appropriations for any use other than domestic supply. Despite this action, water levels continued to drop at approximately the same, nearly constant annual rate of about 4 feet per year, resulting in a current total decline of between 150 and 200 feet in many wells with continued downward trends. In 2005, the Mosier Watershed Council and the Wasco Soil and Water Conservation District began a cooperative investigation of the groundwater system with the U.S. Geological Survey. The objectives of the study were to advance the scientific understanding of the hydrology of the basin, to assess the sustainability of the water supply, to evaluate the causes of persistent groundwater-level declines, and to evaluate potential management strategies. An additional U.S. Geological Survey objective was to advance the understanding of CRBG aquifers, which are the primary source of water across a large part of Oregon, Washington, and Idaho. In many areas, significant groundwater level declines have resulted as these aquifers were heavily developed for agricultural, municipal, and domestic water supplies. Three major factors were identified as possible contributors to the water-level declines in the study area: (1) pumping at rates that are not sustainable, (2) well construction practices that have resulted in leakage from aquifers into springs and streams, and (3) reduction in aquifer recharge resulting from long-term climate variations. Historical well construction practices, specifically open, unlined, uncased boreholes that result in cross-connecting (or commingling) multiple aquifers, allow water to flow between these aquifers. Water flowing along the path of least resistance, through commingled boreholes, allows the drainage of aquifers that previously stored water more efficiently. The study area is in the eastern foothills of the Cascade Range in north central Oregon in a transitional zone between the High Cascades to the west and the Columbia Plateau to the east. The 78-square mile (mi 2 ) area is defined by the drainages of three streams - Mosier Creek (51.8 mi 2 ), Rock Creek (13.9 mi 2 ), and Rowena Creek (6.9 mi 2 ) - plus a small area that drains directly to the Columbia River.The three major components of the study are: (1) a 2-year intensive data collection period to augment previous streamflow and groundwater-level measurements, (2) precipitation-runoff modeling of the watersheds to determine the amount of recharge to the aquifer system, and (3) groundwater-flow modeling and analysis to evaluate the cause of groundwater-level declines and to evaluate possible water resource management strategies. Data collection included the following: 1. Water-level measurements were made in 37 wells. Bi-monthly or quarterly measurements were made in 30 wells, and continuous water-level monitoring instruments were installed in 7 wells. The measurements principally were made to capture the seasonal patterns in the groundwater system, and to augment the available long-term record. 2. Groundwater pumping was measured, reported, or estimated from irrigation, municipal and domestic wells. Flowmeters were installed on 74 percent of all high-capacity irrigation wells in the study area. 3. Borehole geophysical data were collected from a known commingling well. These data measured geologic properties and vertical flow through the well. 4. Streamflow measurements were made in Rock, Rowena, and Mosier Creeks. A long-term recording stream-gaging station was reestablished on Mosier Creek to provide a continuous record of streamflow. Streamflow measurements also were made along the creeks periodically to evaluate seasonal patterns of exchange between streams and the groundwater system. Major findings from the study include: 1. Annual average precipitation ranges from 20 to 54 inches across the study area with an average value of about 30 inches. Based on rainfall-runoff modeling, about one-third of this water infiltrates into the aquifer system. 2. Currently, about 3 percent of the water infiltrated into the groundwater system is extracted for municipal, agricultural, and rural residential use. The remainder of the water flows through the aquifer system, discharging into local streams and the Columbia River. About 80 percent of recent pumping supports crop production. The city of Mosier public supply wells account for about 10 percent of total pumping, with the remaining 10 percent being pumped from the private wells of rural residents. 3. Groundwater-flow simulation results indicate that leakage through commingling wells is a significant and likely the dominant cause of water level declines. Leakage patterns can be complex, but most of the leaked water likely flows out the CRBG aquifer system through very permeable sediments into Mosier Creek and its tributary streams in the OWRD administrative area. Model-derived estimates attribute 80-90 percent of the declines to commingling, with pumping accounting for the remaining 10-20 percent. Although decadal trends in precipitation have occurred, associated changes in aquifer recharge are likely not a significant contributor to the current water level declines. 4. As many as 150 wells might be commingling. To evaluate whether or not the local combination of geology and well construction have resulted in aquifer commingling at a particular well, the well needs to be tested by measuring intraborehole flow. During geophysical testing of one known commingling well, the flow rate through the well between aquifers ranged between 70 and 135 gallons per minute (11-22 percent of total annual pumping in the study area). Historically, when aquifer water levels were 150-200 feet higher, this flow rate would have been correspondingly higher. 5. Because aquifer commingling through well boreholes is likely the dominant cause of aquifer declines, flow simulations were conducted to evaluate the benefit of repairing wells in specified locations and the benefit of recharging aquifers using diverted flow from study area creeks. As part of this analysis, maps were generated that show which areas are more vulnerable to commingling. These maps indicate that the value of repairing wells in the area generally coincident with the OWRD administrative area is higher than in areas farther upstream in the watershed. Simulation results also indicate that artificial recharge of the aquifers using diverted creek water will not significantly improve water levels in the aquifer system unless at least some commingling wells are repaired first. Repairs would entail construction of wells in a manner that prevents commingling of multiple aquifers. The value of artificially recharging the aquifers improves as more wells are repaired because the aquifer system more efficiently stores water.

Oregon

Gypsies in the palace: Experimentalist's view on the use of 3-D physics-based simulation of hillslope hydrological response

As a fundamental unit of the landscape, hillslopes are studied for their retention and release of water and nutrients across a wide range of ecosystems. The understanding of these near-surface processes is relevant to issues of runoff generation, groundwater-surface water interactions, catchment export of nutrients, dissolved organic carbon, contaminants (e.g. mercury) and ultimately surface water health. We develop a 3-D physics-based representation of the Panola Mountain Research Watershed experimental hillslope using the TOUGH2 sub-surface flow and transport simulator. A recent investigation of sub-surface flow within this experimental hillslope has generated important knowledge of threshold rainfall-runoff response and its relation to patterns of transient water table development. This work has identified components of the 3-D sub-surface, such as bedrock topography, that contribute to changing connectivity in saturated zones and the generation of sub-surface stormflow. Here, we test the ability of a 3-D hillslope model (both calibrated and uncalibrated) to simulate forested hillslope rainfall-runoff response and internal transient sub-surface stormflow dynamics. We also provide a transparent illustration of physics-based model development, issues of parameterization, examples of model rejection and usefulness of data types (e.g. runoff, mean soil moisture and transient water table depth) to the model enterprise. Our simulations show the inability of an uncalibrated model based on laboratory and field characterization of soil properties and topography to successfully simulate the integrated hydrological response or the distributed water table within the soil profile. Although not an uncommon result, the failure of the field-based characterized model to represent system behaviour is an important challenge that continues to vex scientists at many scales. We focus our attention particularly on examining the influence of bedrock permeability, soil anisotropy and drainable porosity on the development of patterns of transient groundwater and sub-surface flow. Internal dynamics of transient water table development prove to be essential in determining appropriate model parameterization. ?? 2010 John Wiley & Sons, Ltd.

Hydrological Processes

The concurrent use of novel soil surface microclimate measurements to evaluate CO2 pulses in biocrusted interspaces in a cool desert ecosystem

Carbon cycling associated with biological soil crusts, which occupy interspaces between vascular plants in drylands globally, may be an important part of the coupled climate-carbon cycle of the Earth system. A major challenge to understanding CO 2 fluxes in these systems is that much of the biotic and biogeochemical activity occurs in the upper few mm of the soil surface layer (i.e., the ‘mantle of fertility’), which exhibits highly dynamic and difficult to measure temperature and moisture fluctuations. Here, we report a multi-sensor approach to simultaneously measuring temperature and moisture of this biocrust surface layer (0–2 mm), and the deeper soil profile, concurrent with automated measurement of surface soil CO 2 effluxes. Our results illuminate robust relationships between biocrust water content and field CO 2 pulses that have previously been difficult to detect and explain. All observed CO 2 pulses over the measurement period corresponded to surface wetting events, including when the wetting events did not penetrate into the soil below the biocrust layer (0–2 mm). The variability of temperature and moisture of the biocrust surface layer was much greater than even in the 0–5 cm layer of the soil beneath the biocrust, or deeper in the soil profile. We therefore suggest that coupling surface measurements of biocrust moisture and temperature to automated CO 2 flux measurements may greatly improve our understanding of the climatic sensitivity of carbon cycling in biocrusted interspaces in our study region, and that this method may be globally relevant and applicable.

Biogeochemistry

Geology and water resources of Owens Valley, California

Owens Valley, a long, narrow valley located along the east flank of the Sierra Nevada in east-central California, is the main source of water for the city of Los Angeles. The city diverts most of the surface water in the valley into the Owens River-Los Angeles Aqueduct system, which transports the water more than 200 miles south to areas of distribution and use. Additionally, ground water is pumped or flows from wells to supplement the surface-water diversions to the river-aqueduct system. Pumpage from wells needed to supplement water export has increased since 1970, when a second aqueduct was put into service, and local concerns have been expressed that the increased pumpage may have had a detrimental effect on the environment and the indigenous alkaline scrub and meadow plant communities in the valley. The scrub and meadow communities depend on soil moisture derived from precipitation and the unconfined part of a multilayered aquifer system. This report, which describes the hydrogeology of the aquifer system and the water resources of the valley, is one in a series designed to (1) evaluate the effects that ground-water pumping has on scrub and meadow communities and (2) appraise alternative strategies to mitigate any adverse effects caused by pumping. Two principal topographic features are the surface expression of the geologic framework--the high, prominent mountains on the east and west sides of the valley and the long, narrow intermountain valley floor. The mountains are composed of sedimentary, granitic, and metamorphic rocks, mantled in part by volcanic rocks as well as by glacial, talus, and fluvial deposits. The valley floor is underlain by valley fill that consists of unconsolidated to moderately consolidated alluvial fan, glacial and talus, and fluvial and lacustrine deposits. The valley fill also includes interlayered recent volcanic flows and pyroclastic rocks. The bedrock surface beneath the valley fill is a narrow, steep-sided graben that is structurally separated into the Bishop Basin to the north and the Owens Lake Basin to the south. These two structural basins are separated by (1) a bedrock high that is the upper bedrock block of an east-west normal fault, (2) a horst block of bedrock (the Poverty Hills), and (3) Quaternary basalt flows and cinder cones that intercalate and intrude the sedimentary deposits of the valley fill. The resulting structural separation of the basins allowed separate development of fluvial and lacustrine depositional systems in each basin. Nearly all the ground water in Owens Valley flows through and is stored in the saturated valley fill. The bedrock, which surrounds and underlies the valley fill, is virtually impermeable. Three hydrogeologic units compose the valley-fill aquifer system, a defined subdivision of the ground-water system, and a fourth represents the valley fill below the aquifer system and above the bedrock. The aquifer system is divided into horizontal hydrogeologic units on the basis of either (1) uniform hydrologic characteristics of a specific lithologic layer or (2) distribution of the vertical hydraulic head. Hydrogeologic unit 1 is the upper unit and represents the unconfined part of the system, hydrogeologic unit 2 represents the confining unit (or units), and hydrogeologic unit 3 represents the confined part of the aquifer system. Hydrogeologic unit 4 represents the deep part of the ground-water system and lies below the aquifer system. Hydrogeologic unit 4 transmits or stores much less water than hydrogeologic unit 3 and represents either a moderately consolidated valley fill or a geologic unit in the valley fill defined on the basis of geophysical data. Nearly all the recharge to the aquifer system is from infiltration of runoff from snowmelt and rainfall on the Sierra Nevada. In contrast, little recharge occurs to the system by runoff from the White and Inyo Mountains or from direct precipitation on the valley floor. Ground water flows from the margins of the valley towards the center of the valley; the ground water then flows south to the terminus of the system at Owens (dry) Lake. Ground water flows south from Bishop Basin to Owens Lake Basin through the narrows that constrict the flow opposite Poverty Hills. The aquifer system in the northern half of Owens Lake Basin is divided into east and west halves by the barrier effect caused by the Owens Valley fault. Discharge from the aquifer system is primarily by pumpage and evapotranspiration, and to a lesser extent by flowing wells, springs, underflow, and leakage to the Owens River-Los Angeles aqueduct system. Withdrawals from pumped or flowing wells is the largest component of discharge and accounts for about 50 percent of the outflow from the system. Transpiration by scrub and meadow plant communities, and to a lesser extent by irrigated alfalfa pasture, accounts for about 40 percent of the system's discharge. Natural hydraulic conductivity ranges from less than 400 to about 12,000 feet per day in the basalt flows, the more permeable material in the aquifer system. Where the basalts are fractured by explosives and drilling techniques, actual transmissivities can be greater than 1,000,000 feet squared per day. Hydraulic conductivities in sedimentary deposits of the aquifer system range from less than a few feet per day in lacustrine clays to more than 300 feet per day in gravel stringers and beach deposits in the transition zone between alluvial fan deposits and fluvial and lacustrine deposits. Degree of confinement in the aquifer system generally increases to the south and east in both the Bishop and Owens Lake Basins. The vertical hydraulic gradient across hydrogeologic unit 2 and confining beds in hydrogeologic units 1 and 3 is a function of (1) the asymmetric recharge and hydraulic head created by the dominant recharge from Sierra Nevada runoff and (2) the areal extent and thickness of the confining beds. Although most of the pumpage is from hydrogeologic unit 3, some coincident drawdown has been recorded in nonpumped wells that tap unit 1. Drawdown in hydrogeologic unit 1 is a function of changes in (1) lateral flow through hydrogeologic unit 1, (2) upward flow of ground water through the confining beds, (3) downward leakage of water from hydrogeologic unit 1 to unit 3 through wells, (4) direct withdrawal from well intervals open to hydrogeologic unit 1, and (5) increased evapotranspiration. The water in the aquifer system is generally of excellent quality for public supply and irrigation, with the exception of water stored in thick sequences of lacustrine silts and clays near Owens Lake. The water is principally a calcium bicarbonate type and dissolved-solids concentrations range from approximately 104 to 325 milligrams per liter. Water in the lacustrine sediments of Owens (dry) Lake is a sodium bicarbonate type and dissolved-solids concentrations are about 5,400 milligrams per liter.

California

Geology and water resources of Owens Valley, California

Owens Valley, a long, narrow valley located along the east flank of the Sierra Nevada in east-central California, is the main source of water for the city of Los Angeles. The city diverts most of the surface water in the valley into the Owens River-Los Angeles Aqueduct system, which transports the water more than 200 miles south to areas of distribution and use. Additionally, ground water is pumped or flows from wells to supplement the surface-water diversions to the river-aqueduct system. Pumpage from wells needed to supplement water export has increased since 1970, when a second aqueduct was put into service, and local concerns have been expressed that the increased pumpage may have had a detrimental effect on the environment and the indigenous alkaline scrub and meadow plant communities in the valley. The scrub and meadow communities depend on soil moisture derived from precipitation and the unconfined part of a multilayered aquifer system. This report, which describes the hydrogeology of the aquifer system and the water resources of the valley, is one in a series designed to (1) evaluate the effects that groundwater pumping has on scrub and meadow communities and (2) appraise alternative strategies to mitigate any adverse effects caused by, pumping. Two principal topographic features are the surface expression of the geologic framework--the high, prominent mountains on the east and west sides of the valley and the long, narrow intermountain valley floor. The mountains are composed of sedimentary, granitic, and metamorphic rocks, mantled in part by volcanic rocks as well as by glacial, talus, and fluvial deposits. The valley floor is underlain by valley fill that consists of unconsolidated to moderately consolidated alluvial fan, transition-zone, glacial and talus, and fluvial and lacustrine deposits. The valley fill also includes interlayered recent volcanic flows and pyroclastic rocks. The bedrock surface beneath the valley fill is a narrow, steep-sided graben that is structurally separated into the Bishop Basin to the north and the Owens Lake Basin to the south. These two structural basins are separated by (1) a bedrock high that is the upper bedrock block of an east-west normal fault, (2) a horst block of bedrock (the Poverty Hills), and (3) Quaternary basalt flows and cinder cones that intercalate and intrude the sedimentary deposits of the valley fill. The resulting structural separation of the basins allowed separate development of fluvial and lacustrine depositional systems in each basin. Nearly all the ground water in Owens Valley flows through and is stored in the saturated valley fill. The bedrock, which surrounds and underlies the valley fill, is virtually impermeable. Three hydrogeologic units compose the valley-fill aquifer system, a defined subdivision of the ground-water system, and a fourth represents the valley fill below the aquifer system and above the bedrock. The aquifer system is divided into horizontal hydrogeologic units on the basis of either (1) uniform hydrologic characteristics of a specific lithologic layer or (2) distribution of the vertical hydraulic head. Hydrogeologic unit 1 is the upper unit and represents the unconfined part of the system, hydrogeologic unit 2 represents the confining unit (or units), and hydrogeologic unit 3 represents the confined part of the aquifer system. Hydrogeologic unit 4 represents the deep part of the ground-water system and lies below the aquifer system. Hydrogeologic unit 4 transmits or stores much less water than hydrogeologic unit 3 and represents either a moderately consolidated valley fill or a geologic unit in the valley fill defined on the basis of geophysical data. Nearly all the recharge to the aquifer system is from infiltration of runoff from snowmelt and rainfall on the Sierra Nevada. In contrast, little recharge occurs to the system by runoff from the White and Inyo Mountains or from direct precipitation on the valley floor. Ground wat

Water Supply Paper

Assessing the feasibility of satellite-based thresholds for hydrologically driven landsliding

Elevated soil moisture and heavy precipitation contribute to landslides worldwide. These environmental variables are now being resolved with satellites at spatiotemporal scales that could offer new perspectives on the development of landslide warning systems. However, the application of these data to hydro-meteorological thresholds (which account for antecedent soil moisture and rainfall) first need to be evaluated with respect to proven, direct measurement-based thresholds that use rain gauges and in situ soil moisture sensors. Here, we compare ground-based hydrologic data to overlapping satellite-based data before, during, and after a recent season of widespread shallow landsliding in the San Francisco Bay Area (California, USA). We then explore how the remotely sensed information could be used to empirically define hypothetical thresholds for shallow landsliding. We find that the ground-based thresholds developed with a single monitoring station show superior performance because the in situ soil saturation data better reflect the gravity-dominated subsurface flow conditions that are characteristic of hillslopes during the rainy season. Although the satellite-based thresholds can identify most of the landslide days, they include a greater number of false alarms due to overestimates of soil moisture between major storm events. To avoid the type of false alarms that are characteristic of our satellite-based thresholds, further post-processing of the near-surface hydrologic response data to better reflect gravity-dominated drainage should be integrated into satellite-based model outputs. Our results encourage further deployment of ground stations in landslide-prone terrain and cautious exploration of satellite-based hydro-meteorological thresholds where in situ networks are nonexistent.

California

Preface—Evaluating the response of critical zone processes to human impacts with sediment source fingerprinting

1) Background: Critical Zone Processes in the Anthropocene The Earth’s Critical Zone encompasses a suite of interconnected processes in the near-surface lithosphere, pedosphere, biosphere, atmosphere, and hydrosphere (Brantley et al., 2007; Lin, 2010) (Fig. 1). Processes and interactions both within and between these various Critical Zone components supports life-sustaining ecosystem services and resources that establish the foundation for humanity (NRC, 2001). This includes the formation production of fertile soils, flourishing vegetation, productive rivers, lakes and oceans, and our life-sustaining atmosphere (Gaillardet, 2014; Guo and Lin, 2016). Rapid population growth, land use intensification, and global environmental change are disturbing many of these fundamental Critical Zone processes. More than half of the Earth’s terrestrial surface is now impacted by anthropogenic activities (e.g., clearing, grazing, plowing, mining, and logging) (Hooke et al., 2012; Richter and Mobley, 2009). These changes are so widespread and pervasive that the great acceleration of socioeconomic development that occurred around 1950 (Fig. 2) has been recommended to delineate the dawn of the Anthropocene (Waters et al., 2016). Although the utility of adopting and delineating the Anthropocene as the current epoch is subject to debate (Crutzen, 2002; Ruddiman et al., 2015; Smith and Zeder, 2013), the concept effectively highlights both the nature and the extent of our global impact on Earth’s Critical Zone. Soil forming processes and ecosystem services provided by the pedosphere are central to the Critical Zone (Banwart et al., 2011; Lin, 2010). Many of these processes have been disturbed by the agricultural intensification that coincided with the great acceleration resulting in unsustainable land use practices now outpacing soil formation processes (Brantley et al., 2007). As agricultural landscapes now cover an area equivalent to what was scoured during the last glacial maximum (Amundson et al., 2007), the broad-scale intensification of anthropogenic activities has resulted in significant on- and off-site impacts. On-site, soil loss has resulted in decreases in soil fertility and agricultural yields (Ladha et al., 2009) threatening the ability to feed the world’s growing population (Brantley et al., 2007). Off-site, the excess delivery of particulate matter downstream is degrading riverine, lacustrine, and estuarine ecosystems (Bilotta and Brazier, 2008; Clark, 1985; Owens et al., 2005). The challenge, as noted by Brantley et al., (2007), is that despite our society having over 10,000 years of experience working with soils, our conceptual and quantitative models remain inadequate at predicting Critical Zone dynamics under current conditions. Notwithstanding growing pressure for improved environmental management, we still have a limited capacity to predict changes in the Critical Zone in response to anthropogenic activities owing to the multiple spatial and temporal scales at which these complex processes and feedbacks are manifest. As river basin systems are impacted by many of these processes, a deep understanding of soil-sediment continuum dynamics may provide a valuable framework for evaluating the disturbance response of Critical Zone processes. Understanding these processes may also provide land and resource managers with the information necessary to manage both the on-site and off-site effects of accelerated soil erosion.

Journal of Soils and Sediments