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USGS1989

Sedimentary framework of the southern Maine inner continental shelf: Influence of glaciation and sea-level change

Although the tidally influenced shoreline of Maine is longer than that of virtually any other state, almost no research on its geology has been published. In order to go some way towards remedying this, 1500 km of high-resolution seismic reflection data and 800 km of sidescan sonar imagery have been collected. On the basis of these data and observations made during ten submersible dives, more than 800 bottom samples were collected and evaluated for texture and composition. The understanding of the sedimentary framework of the southern Maine shelf and the processes that maintain it are summarized, and future research directions to evaluate the strategic mineral potential are indicated. In the past 14,000 years, the Maine shelf has experienced a deglaciation and two marine transgressions separated by a regression. The deglaciation was accompanied by the first transgression and deposited till interbedded with up to 40 m of glaciomarine sediment (the Presumpscot Formation) across the shelf. The first transgression culminated about 12,500 yrs B.P., and its landward limit is marked by large glaciomarine deltas 50-100 km landward of the present-day coast. Sea level fell until about 9500 yrs B.P., when shorelines were cut at about the 65 m depth and some large "lowstand deltas" were deposited. Sea level has risen since then and in the general absence of modern river sediment input marine processes have reworked the older sediment. Five shelf environments have been defined in terms of their surficial sediment and stratigraphy. Nearshore ramps are sandy regions extending to about 30 m deep offshore of sandy beaches. These may be reworked lowstand deltas, and possess the thickest bodies of sand in the region. Nearshore basins are mud-filled troughs seaward of coastal areas lacking significant river input. Slumping glaciomarine deposits provide most of the Holocene mud that floors these basins. Rocky zones are extensive areas of exposed rock most common in the 30-50 m depth range. These are areas of high carbonate productivity and provide shell fragments to adjacent areas. The outer basins are muddy regions that begin at the 65 m shoreline and extend beyond the 100 m isobath to the deep Gulf of Maine. Finally, shelf valleys are former stream courses that connect nearshore ramps and basins to the outer basins. These bedrock-framed valleys are filled with sand and mud and are apparently still active conduits for the offshore movement of sediment. The mineralogy of the shelf sediment is complex, and it is not yet clear whether glacial homogenization has obliterated distinctions between river drainage basins and the adjacent shelf. Studies are continuing into northern Maine and analysis of the heavy mineralogy of the shelf sediment utilizing a 2 m Humphrey Spiral to process large grab samples and cores has begun. ?? 1989.

Marine Geology↗

USGS2011

Hyperspectral analysis of rocky surfaces on the Earth and other planetary systems: Chapter 27

This book is focused on studies of vegetation on Earth using hyperspectral remote sensing methods. However, it is appropriate to extend the application of these methods out to other rocky bodies in our Solar System for a variety of reasons. First, minerals, soils, and rocks form the substrate on which vegetation grows on Earth. Compositional analyses of these components with hyperspectral data provide essential background information for distinguishing, identifying, and removing their effects on vegetation spectra. Second, variation in distribution, chemical and physical properties among soil and rock, has been demonstrated to have a significant effect on factors such as moisture retention, dust production, and the presence and distribution of biological species ranging from bacteria, fungi, grasses, shrubs, trees, and small mammals to humans [1]. These factors in turn can have profound influences on human health.

Book chapter↗

USGS1977

The origin of garnet in the anorthosite-charnockite suite of the Adirondacks

Detailed analysis of textural and chemical criteria in rocks of the anorthosite-charnockite suite of the Adirondack Highlands suggests that development of garnet in silica-saturated rocks of the suite occurs according to the reaction: {Mathematical expression}, where ?? is a function of the distribution of Fe and Mg between the several coexisting ferromagnesian phases. Depending upon the relative amounts of Fe and Mg present, quartz may be either a reactant or a product. Using an aluminum-fixed reference frame, this reaction can be restated in terms of a set of balanced partial reactions describing the processes occurring in spatially separated domains within the rock. The fact that garnet invariably replaces plagioclase as opposed to the other reactant phases indicates that the aluminum-fixed model is valid as a first approximation. This reaction is univariant and produces unzoned garnet. It differs from a similar equation proposed by de Waard (1965) for the origin of garnet in Adirondack metabasic rocks, i.e. 6 Orthopyroxene+2 Anorthite = Clinopyroxene+Garnet+2 Quartz, the principle difference being that iron oxides (ilmenite and/or magnetite) are essential reactant phases in the present reactions. The product assemblage (garnet+clinopyroxene+plagioclase ?? orthopyroxene ?? quartz) is characteristic of the clinopyroxene-almandine subfacies of the granulite facies. ?? 1977 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

USGS1972

Metamorphic assemblages and the direction of flow of metamorphic fluids in four instances of serpentinization

Fluids related to Serpentinization are of at least three types. The first reported (Barnes and O'Neil, 1969) is a fluid of local meteoric origin, the chemical and thermodynamic properties of which are entirely controlled by olivine, orthopyroxene, brucite, and serpentine reactions. It is a Ca +2 -OH −1 type and is shown experimentally to be capable of reacting with albite to yield calcium hydroxy silicates. Rodingites may form where the Ca +2 -OH −1 type waters flow across the ultramafic contact and react with siliceous country rock. The second type of fluid has its chemical composition largely controlled before it enters the ultramafic rocks, but reactions within the ultramafic rocks fix the thermodynamic properties by reactions of orthopyroxene, olivine, calcite, brucite, and serpentine. The precipitation of brucite from this fluid clearly shows that fluid flow allows reaction products to be deposited at a distance from the point of solution. Thus, textural evidence for volume relations during Serpentinization may not be valid. The third type of fluid has its chemical properties fixed in part before the reactions with ultramafic rocks, in part by the reactions of orthopyroxene, olivine, and serpentine and in part by reactions with siliceous country rock at the contact. The reactions of the ultramafic rock and country rock with the fluid must be contemporaneous and require flow to be along the contact. This third type of fluid is grossly supersaturated with talc and tremolite, both found along the contact. The occurrence of magadiite, kenyaite, mountainite, and rhodesite along the contact is probably due to a late stage low-temperature reaction of fluids of the same thermodynamic properties as those that formed the talc and tremolite at higher temperatures. Oxygen isotope analyses of some of these minerals supports this conclusion. Rodingites form from Ca +2 -rich fluids flowing across the contact; talc and tremolite form from silica-rich fluids flowing along the contact. Isotopic analyses of the fluids indicate varied origins including unaltered local meteoric water and connate water. Complexion Spring water may be a sample of only slightly altered Jurassic or Cretaceous sea water.

Contributions to Mineralogy and Petrology↗

USGS2003

Water-quality and algal conditions in the Clackamas River basin, Oregon, and their relations to land and water management

In 1998, the U.S. Geological Survey sampled the Clackamas River, its major tributaries, and reservoirs to characterize basic water quality (nutrients, dissolved oxygen, pH, temperature, and conductance), water quantity (water sources within the basin), and algal conditions (biomass and species composition). Sampling locations reflected the dominant land uses in the basin (forest management, agriculture, and urban development) as well as the influence of hydroelectric projects, to examine how these human influences might be affecting water quality and algal conditions. Nuisance algal growths, with accompanying negative effects on water quality, were observed at several locations in the basin during this study. Algal biomass in the lower Clackamas River reached a maximum of 300 mg/m2 chlorophyll a, producing nuisance algal conditions, including fouled stream channels and daily fluctuations in pH and dissolved oxygen concentrations to levels that did not meet water-quality standards. Algal biomass was highest at sites immediately downstream from the hydroelectric project's reservoirs and/or powerhouses. Nuisance algal conditions also were observed in some of the tributaries, including the North Fork of the Clackamas River, Clear Creek, Rock Creek, and Sieben Creek. High amounts of drifting algae increased turbidity levels in the Clackamas River during June, which coincided with a general increase in the concentration of disinfection by-products found in treated Clackamas River water used for drinking, presumably due to the greater amounts of organic matter in the river. The highest nutrient concentrations were found in the four lowermost tributaries (Deep, Richardson, Rock, and Sieben Creeks), where most of the agriculture and urban development is concentrated. Of these, the greatest load of nutrients came from Deep Creek, which had both high nutrient concentrations and relatively high streamflow. Streams draining forestland in the upper basin (upper Clackamas River and Oak Grove Fork) had the highest concentrations of phosphorus (and lowest concentrations of nitrogen), and streams draining forestland in the middle basin (Clear Creek, Eagle Creek, and the North Fork of the Clackamas River) had relatively high concentrations of nitrogen (and low concentrations of phosphorus). In contrast, relatively low concentrations of both nitrogen and phosphorus were found at the two reference streams, reflecting their pristine condition. Relatively high phosphorus levels in the upper basin are probably due to the erosion of naturally occurring phosphorus deposits in this area. Likely sources of nitrogen (mostly nitrate) in the forested watersheds include nitrogen-fixing plants, atmospheric deposition, timber harvesting, and applications of urea fertilizers.

Water-Resources Investigations Report↗

USGS1944

"Ribbon rock", an unusual beryllium-bearing tactite

The beryllium deposits at Iron Mountain, near the northern end of the Sierra Cuchillo in Sierra and Socorro Counties, New Mexico, are unusual products of contact metamorphism. They occur in irregular bodies of tactile formed by replacement of Paleozoic limestone, generally at or near contacts with small intrusive masses of rhyolite, aplite, and fine-grained granite. The metamorphism took place in mid-Tertiary time. Beryllium is present chiefly in the complex silicate minerals helvite and danalite, and is a minor constituent of the garnet grossularite, a boron-bearing idocrase, and chlorite. These minerals are known to occur in noteworthy concentrations in only one type of rock, a peculiar rhythmically layered variety of tactile to which the name "ribbon rock" is given. The structure of such tactite is very conspicuous, and appears in section as thin, finely crenulated bands of magnetite alternating with similar bands of silicate minerals and finely crystalline fluorite. Concentric banding about fluorite-rich pod-like masses is common. Bodies of "ribbon rock" range in size from inch-thick lenses to large masses amounting to thousands of tons; most appear to have been formed along contacts between re-crystallized limestone and massive magnetite-andradite tactite, chiefly by replacing fluids penetrating the limestone from fractures. The layered structure is interpreted as a diffusion effect.The formation of massive and "ribbon rock" tactites can be traced through a range of falling temperature from a stage characterized by deposition from iron-rich vapors to a stage in which hydrothermal solutions were dominant. Both vapors and liquids appear to have been acid. Reducing conditions undoubtedly existed during the latter part of the hydrothermal stage. The occurrence of beryllium in "ribbon rock," but not in typical massive tactite, may signify that its compounds in deposits at or near intrusive contacts are confined to rocks of hydrothermal origin. The occurrence of "ribbon rock" is suggested as a potentially useful clue for recognition of beryllium-bearing contact deposits elsewhere; at least two other occurrences of what apparently is "ribbon rock" have been described in the literature.

New Mexico↗

USGS2014

Correlation chart of Pennsylvanian rocks in Alabama, Tennessee, Kentucky, Virginia, West Virginia, Ohio, Maryland, and Pennsylvania showing approximate position of coal beds, coal zones, and key stratigraphic units

The Appalachian basin, one of the largest Pennsylvanian bituminous coal-producing regions in the world, currently contains nearly one-half of the top 15 coal-producing States in the United States (Energy Information Agency, 2006). Anthracite of Pennsylvanian age occurs in synclinal basins in eastern Pennsylvania, but production is minimal. A simplified correlation chart was compiled from published and unpublished sources as a means of visualizing currently accepted stratigraphic relations between the rock formations, coal beds, coal zones, and key stratigraphic units in Alabama, Tennessee, Kentucky, Virginia, West Virginia, Ohio, Maryland, and Pennsylvania. The thickness of each column is based on chronostratigraphic divisions (Lower, Middle, and Upper Pennsylvanian), not the thickness of strata. Researchers of Pennsylvanian strata in the Appalachian basin also use biostratigraphic markers and other relative and absolute geologic age associations between the rocks to better understand the spatial relations of the strata. Thus, the stratigraphic correlation data in this chart should be considered provisional and will be updated as coal-bearing rocks within the Appalachian coal regions continue to be evaluated. Most geologic formations are identified and defined by the distinctive lithologic features they contain. However, formations of Pennsylvanian age in the Appalachian basin and the Pennsylvania Anthracite region have traditionally been described and named to reflect the presence or absence of economic coal beds and coarse-grained sandstone units, most of which have since been proven to be locally or regionally discontinuous (Ruppert and Rice, 2001). Many of the stratigraphic names and boundaries used for the coals and other geologic units in the Pennsylvanian rocks differ between States or regions (fig. 1). Because local and regional stratigraphic complexities occur within some States, a multiplicity of State-specific names is introduced that may be confusing to those conducting regional geologic assessments in the basin. Nonetheless, many of these stratigraphic names and boundaries have some elements that allow for regional stratigraphic correlation. For instance, many coals in the northern Appalachian basin coal region are easier to trace over greater distances than coals in the central and southern Appalachian basin coal regions (fig. 2). The Upper Pennsylvanian Pittsburgh coal bed (fig. 1) of the northern Appalachian basin coal region, for example, occurs as a synchronogenic bed deposited on a laterally continuous surface of sediments (Cross, 1954; Tewalt and others, 2001). The base of the Pittsburgh coal bed is designated as the contact between the Conemaugh Group (Upper Pennsylvanian) and the overlying Monongahela Group in western Pennsylvania, western Maryland, Ohio, and West Virginia (fig. 1). Therefore, in areas where the Pittsburgh coal bed is present, there is little controversy over its position or the placement of the boundary between the Conemaugh and Monongahela Groups. In other regions of the basin, group and formation boundaries are more difficult to identify over extensive areas. One example is the placement of the contact between the New River Formation and the overlying Kanawha Formation—a boundary that is not easily defined beyond the area where these units were first defined in West Virginia. At the type section of the Kanawha Formation, the base of the Lower Douglas coal zone (fig. 1) defines the contact between the Kanawha Formation and the underlying New River Formation (Rice and others, 1994b). However, subsequent mapping has demonstrated that the Lower Douglas coal zone is regionally discontinuous and in many parts of West Virginia is absent (Blake and others, 2002). Where absent, the Nuttall Sandstone Member of the underlying New River Formation sometimes occurs in the stratigraphic position of the Lower Douglas coal zone. Yet, even the Nuttall Sandstone Member has been found to be regionally discontinuous and of varying thickness throughout its extent, features that hinder its use as a regional stratigraphic marker bed in the Appalachian basin. Because of the many names used to identify individual coal beds and coal zones in the historic Appalachian basin coal-mining districts, coal bed designations may differ even more than stratigraphic nomenclature. In eastern Kentucky, northwest of the Pine Mountain thrust fault on the Cumberland overthrust sheet, for example, coal beds or coal zones equivalent to the Lower Elkhorn coal zone (within the Pikeville Formation) are identified also as the Eagle coal zone, Pond Creek coal zone, and Blue Gem coal bed (fig. 1). Southeast of the Pine Mountain thrust fault, yet still in Kentucky, equivalent coals in this same interval are known as the Imboden and Rich Mountain. Moreover, this same interval of coal is identified as the Blue Gem coal in Tennessee, the Imboden coal bed or Campbell Creek or Pond Creek coal zones in Virginia, and the Eagle coal zone in West Virginia.

Appalachian basin↗

USGS2017

Paleozoic and mesozoic GIS data from the Geologic Atlas of the Rocky Mountain Region: Volume 1

The Rocky Mountain Association of Geologists (RMAG) is, once again, publishing portions of the 1972 Geologic Atlas of the Rocky Mountain Region (Mallory, ed., 1972) as a geospatial map and data package. Georeferenced tiff (Geo TIFF) images of map figures from this atlas has served as the basis for these data products. Shapefiles and file geodatabase features have been generated and cartographically represented for select pages from the following chapters: • Phanerozoic Rocks (page 56) • Cambrian System (page 63) • Ordovician System (pages 78 and 79) • Silurian System (pages 87 - 89) • Devonian System (pages 93, 94, and 96 - 98) • Mississippian System (pages 102 and 103) • Pennsylvanian System (pages 114 and 115) • Permian System (pages 146 and 149 - 154) • Triassic System (pages 168 and 169) • Jurassic System (pages 179 and 180) • Cretaceous System (pages 197 - 201, 207 - 210, 215, - 218, 221, 222, 224, 225, and 227). The primary purpose of this publication is to provide regional-scale, as well as local-scale, geospatial data of the Rocky Mountain Region for use in geoscience studies. An important aspect of this interactive map product is that it does not require extensive GIS experience or highly specialized software.

Book↗

USGS1989

Enrichment of trace elements in garnet amphibolites from a paleo-subduction zone: Catalina Schist, southern California

The abundance, P - T stability, solubility, and element-partitioning behavior of minerals such as rutile, garnet, sphene, apatite, zircon, zoisite, and allanite are critical variables in models for mass transfer from the slab to the mantle wedge in deep regions of subduction zones. The influence of these minerals on the composition of subduction-related magmas has been inferred (and disputed) from inverse modelling of the geochemistry of island-arc basalt, or by experiment. Although direct samples of the dehydration + partial-melting region of a mature subduction zone have not been reported from subduction complexes, garnet amphibolites from melanges of circumpacific and Caribbean blueschist terranes reflect high T (>600°C) conditions in shallower regions. Such rocks record geochemical processes that affected deep-seated, high- T portions of paleo-subduction zones. In the Catalina Schist, a subduction-zone metamorphic terrane of southern California, metasomatized and migmatitic garnet amphibolites occur as blocks in a matrix of meta-ultramafic rocks. This mafic and ultramafic complex may represent either slab-derived material accreted to the mantle wedge of a nascent subduction zone or a portion of a shear zone closely related to the slab-mantle wedge contact, or both. The trace-element geochemistry of the complex and the distribution of trace elements among the minerals of garnet amphibolites were studied by INAA, XRF, electron microprobe, and SEM. In order of increasing alteration from a probable metabasalt protolith, three common types of garnet amphibolite blocks in the Catalina Schist are: (1) non-migmatitic, clinopyroxene-bearing blocks, which are compositionally similar to MORB that has lost an albite component; (2) garnet-amphibolite blocks, which have rinds that reflect local interaction between metabasite, metaperidotite, and fluid; and (3) migmatites that are extremely enriched in Th, HFSE, LREE, and other trace elements. These trace-element enrichments are mineralogically controlled by rutile, garnet, sphene, apatite, zircon, zoisite, and allanite. Alkali and alkaline earth elements are much less enriched in the solid assemblage, and thus appear to be decoupled from the other elements in the inferred metasomatic process(es). The compositions of migmatitic garnet amphibolite blocks seem to complement that of “average” island-arc tholeiite. Trace-element metasomatism reflects fluid-solid, rather than melt-solid, interaction. The metasomatic effects indicate that H 2 O-rich fluid, perhaps with a significant component of Na-Al silicate and alkalis, carried Th, U, Sr, REE, and HFSE. Fractionations of LREE in migmatites resemble those of migmatitic metasedimentary rocks underlying the mafic and ultramafic complex. “Exotic” LREE deposited in allanite in migmatites could have been derived from fluids in equilibrium with subducted sediment. If the paleo-subduction zone represented by the mafic and ultramafic complex of the Catalina Schist had continued its thermal and fluid evolution, a selvage of similarly enriched rocks might have been generated along the slab-mantle wedge contact between ~30 and 85 km depth. Rocks affected by “subduction-zone metasomatism,” although rarely recognized at the surface, could be volumetrically significant products of the initiation of subduction and may prove to be geochemical probes of convergent margins that approach the significance of xenoliths in the study of other magmatic environments.

Geochimica et Cosmochimica Acta↗

USGS1976

Geology and mineral deposits of the Needle Mountains District, Southwestern Colorado

The Needle Mountains district is set in highly fractured Precambrian granitic rocks that have intruded and metamorphosed older Precambrian metasedimentary rocks. The Precambrian rocks are overlain by outliers of Paleozoic strata and intruded by a late Tertiary stock. Past mineral production reportedly was limited to silver and gold ores presumably taken from small fissure veins. Although the economic potential of the district has not been adequately explored, some evidence indicates potential for base metal deposits.

Colorado↗

USGS2018

Groundwater availability of the Williston Basin, United States and Canada

Executive Summary The Williston Basin of the Northern Great Plains is a sedimentary basin—a geologic bowl-like structure filled with layered sedimentary rocks dating as far back as the Paleozoic age. The basin, which is nationally important for the production of energy resources, spans Montana, North Dakota, and South Dakota in the United States, and Manitoba and Saskatchewan in Canada. The three uppermost principal aquifer systems are the glacial, lower Tertiary, and Upper Cretaceous aquifer systems. As deep as 3,000 feet (ft) at the center of the basin, these are the most accessible aquifer systems in the basin and are the primary sources of potable groundwater in much of this area. The glacial aquifer system consists of Quaternary-age unconsolidated till, silt, clay, outwash sand and gravel, and occasional cobbles and boulders. The lower Tertiary and Upper Cretaceous aquifer systems consist primarily of sandstone, siltstone, mudstone, shale, and coal. As energy demands have increased in the basin, horizontal drilling and hydraulic-fracturing have been used (especially since 2005) to develop previously inaccessible formations—namely, the Bakken and Three Forks Formations. The basin has yielded a large supply of domestic oil and natural gas since the 1950s, but the technologies required to extract those materials use large amounts of freshwater. The increasing freshwater demands of energy production in the Williston Basin, in addition to population growth, have led to a need for new tools to assess groundwater resources.

Williston Basin↗

USGS2015

Examination of the Reelfoot Rift Petroleum System, south-central United States, and the elements that remain for potential exploration and development

The Reelfoot rift is one segment of a late Proterozoic(?) to early Paleozoic intracontinental rift complex in the south-central United States. The rift complex is situated beneath Mesozoic to Cenozoic strata of the Mississippi embayment of southeastern Missouri, northeastern Arkansas, and western Tennessee and Kentucky. The rift portion of the stratigraphic section consists primarily of synrift Cambrian and Ordovician strata, capped by a postrift sag succession of Late Ordovician to Cenozoic age. Potential synrift source rocks have been identified in the Cambrian Elvins Shale. Thermal maturity of Paleozoic strata within the rift ranges from the oil window to the dry gas window. Petroleum generation in Elvins source rocks likely occurred during the middle to late Paleozoic. Upper Cretaceous sedimentary rocks unconformably overlie various Paleozoic units and define the likely upper boundary of the petroleum system. No production has been established in the Reel-foot rift. However, at least nine of 22 exploratory wells have reported petroleum shows, mainly gas shows with some asphalt or solid hydrocarbon residue. Regional seismic profiling shows the presence of two large inversion structures (Blytheville arch and Pascola arch). The Blytheville arch is marked by a core of structurally thickened Elvins Shale, whereas the Pascola arch reflects the structural uplift of a portion of the entire rift basin. Structural uplift and faulting within the Reelfoot rift since the late Paleozoic appear to have disrupted older conventional hydrocarbon traps and likely spilled any potential conventional petroleum accumulations. The remaining potential resources within the Reelfoot rift are likely shale gas accumulations within the Elvins Shale; however, reservoir continuity and porosity as well as pervasive faulting appear to be significant future challenges for explorers and drillers.

GCSSEPM Foundation Perkins-Rosen Research Conferen↗

USGS2014

Lateritic, supergene rare earth element (REE) deposits

Intensive lateritic weathering of bedrock under tropical or sub-tropical climatic conditions can form a variety of secondary, supergene-type deposits. These secondary deposits may range in composition from aluminous bauxites to iron and niobium, and include rare earth elements (REE). Over 250 lateritic deposits of REE are currently known and many have been important sources of REE. In southeastern China, lateritic REE deposits, known as ion-adsorption type deposits, have been the world’s largest source of heavy REE (HREE). The lateritized upper parts of carbonatite intrusions are being investigated for REE in South America, Africa, Asia and Australia, with the Mt. Weld deposit in Australia being brought into production in late 2012. Lateritic REE deposits may be derived from a wide range of primary host rocks, but all have similar laterite and enrichment profiles, and are probably formed under similar climatic conditions. The weathering profile commonly consists of a depleted zone, an enriched zone, and a partially weathered zone which overlie the protolith. Lateritic weathering may commonly extend to depths of 30 to 60 m. REE are mobilized from the breakdown of primary REE-bearing minerals and redeposited in the enriched zone deeper in the weathering horizon as secondary minerals, as colloids, or adsorbed on other secondary minerals. Enrichment of REE may range from 3 to 10 times that of the source lithology; in some instances, enrichment may range up to 100 times.

Conference Paper↗

USGS1973

Availability of water from limestone and dolomite aquifers in southwest Ohio and the relation of water quality to the regional flow system

The largest ground-water supplies from the 150 to 450-foot thick carbonate-rock aquifer in southwest Ohio are available in a 2,800 squaremile area on the crest and eastern flank of the Cincinnati arch. Well production in the high-yield area is mainly from the Newburg zone, a permeable stratum in the lower part of the Bass Island group. A ' structure contour map on the top of the Lockport Dolomite shows that the Newburg zone conforms to the configuration of the Cincinnati arch. The chemical quality of the water in the consolidated-rock aquifers is intimately related to the regional flow system, and undergoes a progressive change from a calcium bicarbonate-type in recharge areas to a calcium sulfate-type in areas of natural discharge.

Ohio↗

USGS2015

Assessment of unconvential (tight) gas resources in Upper Cook Inlet Basin, South-central Alaska

A geologic model was developed for the assessment of potential Mesozoic tight-gas resources in the deep, central part of upper Cook Inlet Basin, south-central Alaska. The basic premise of the geologic model is that organic-bearing marine shales of the Middle Jurassic Tuxedni Group achieved adequate thermal maturity for oil and gas generation in the central part of the basin largely due to several kilometers of Paleogene and Neogene burial. In this model, hydrocarbons generated in Tuxedni source rocks resulted in overpressure, causing fracturing and local migration of oil and possibly gas into low-permeability sandstone and siltstone reservoirs in the Jurassic Tuxedni Group and Chinitna and Naknek Formations. Oil that was generated either remained in the source rock and subsequently was cracked to gas which then migrated into low-permeability reservoirs, or oil initially migrated into adjacent low-permeability reservoirs, where it subsequently cracked to gas as adequate thermal maturation was reached in the central part of the basin. Geologic uncertainty exists on the (1) presence of adequate marine source rocks, (2) degree and timing of thermal maturation, generation, and expulsion, (3) migration of hydrocarbons into low-permeability reservoirs, and (4) preservation of this petroleum system. Given these uncertainties and using known U.S. tight gas reservoirs as geologic and production analogs, a mean volume of 0.64 trillion cubic feet of gas was assessed in the basin-center tight-gas system that is postulated to exist in Mesozoic rocks of the upper Cook Inlet Basin. This assessment of Mesozoic basin-center tight gas does not include potential gas accumulations in Cenozoic low-permeability reservoirs.

Alaska↗

USGS2011

Geochemistry of hydrothermal fluids from the PACMANUS, Northeast Pual and Vienna Woods hydrothermal fields, Manus Basin, Papua New Guinea

Processes controlling the composition of seafloor hydrothermal fluids in silicic back-arc or near-arc crustal settings remain poorly constrained despite growing evidence for extensive magmatic–hydrothermal activity in such environments. We conducted a survey of vent fluid compositions from two contrasting sites in the Manus back-arc basin, Papua New Guinea, to examine the influence of variations in host rock composition and magmatic inputs (both a function of arc proximity) on hydrothermal fluid chemistry. Fluid samples were collected from felsic-hosted hydrothermal vent fields located on Pual Ridge (PACMANUS and Northeast (NE) Pual) near the active New Britain Arc and a basalt-hosted vent field (Vienna Woods) located farther from the arc on the Manus Spreading Center. Vienna Woods fluids were characterized by relatively uniform endmember temperatures (273–285 °C) and major element compositions, low dissolved CO 2 concentrations (4.4 mmol/kg) and high measured pH (4.2–4.9 at 25 °C). Temperatures and compositions were highly variable at PACMANUS/NE Pual and a large, newly discovered vent area (Fenway) was observed to be vigorously venting boiling (358 °C) fluid. All PACMANUS fluids are characterized by negative δ D H 2 O "> δDH 2 O values, in contrast to positive values at Vienna Woods, suggesting substantial magmatic water input to circulating fluids at Pual Ridge. Low measured pH (25 °C) values (∼2.6–2.7), high endmember CO 2 (up to 274 mmol/kg) and negative δ 34 S H 2 S "> δ 34 S H2 S values (down to −2.7‰) in some vent fluids are also consistent with degassing of acid-volatile species from evolved magma. Dissolved CO 2 at PACMANUS is more enriched in 13 C (−4.1‰ to −2.3‰) than Vienna Woods (−5.2‰ to −5.7‰), suggesting a contribution of slab-derived carbon. The mobile elements (e.g. Li, K, Rb, Cs and B) are also greatly enriched in PACMANUS fluids reflecting increased abundances in the crust there relative to the Manus Spreading Center. Variations in alkali and dissolved gas abundances with Cl at PACMANUS and NE Pual suggest that phase separation has affected fluid chemistry despite the low temperatures of many vents. In further contrast to Vienna Woods, substantial modification of PACMANUS/NE Pual fluids has taken place as a result of seawater ingress into the upflow zone. Consistently high measured Mg concentrations as well as trends of increasingly non-conservative SO 4 behavior, decreasing endmember Ca/Cl and Sr/Cl ratios with increased Mg indicate extensive subsurface anhydrite deposition is occurring as a result of subsurface seawater entrainment. Decreased pH and endmember Fe/Mn ratios in higher Mg fluids indicate that the associated mixing/cooling gives rise to sulfide deposition and secondary acidity production. Several low temperature (⩽80 °C) fluids at PACMANUS/NE Pual also show evidence for anhydrite dissolution and water–rock interaction (fixation of B) subsequent to seawater entrainment. Hence, the evolution of fluid compositions at Pual Ridge reflects the cumulative effects of water/rock interaction, admixing and reaction of fluids exsolved from silicic magma, phase separation/segregation and seawater ingress into upflow zones.

Manus Basin↗

USGS2002

Comparison of petroleum generation kinetics by isothermal hydrous and nonisothermal open-system pyrolysis

This study compares kinetic parameters determined by open-system pyrolysis and hydrous pyrolysis using aliquots of source rocks containing different kerogen types. Kinetic parameters derived from these two pyrolysis methods not only differ in the conditions employed and products generated, but also in the derivation of the kinetic parameters (i.e., isothermal linear regression and non-isothermal nonlinear regression). Results of this comparative study show that there is no correlation between kinetic parameters derived from hydrous pyrolysis and open-system pyrolysis. Hydrous-pyrolysis kinetic parameters determine narrow oil windows that occur over a wide range of temperatures and depths depending in part on the organic-sulfur content of the original kerogen. Conversely, open-system kinetic parameters determine broad oil windows that show no significant differences with kerogen types or their organic-sulfur contents. Comparisons of the kinetic parameters in a hypothetical thermal-burial history (2.5 ??C/my) show open-system kinetic parameters significantly underestimate the extent and timing of oil generation for Type-US kerogen and significantly overestimate the extent and timing of petroleum formation for Type-I kerogen compared to hydrous pyrolysis kinetic parameters. These hypothetical differences determined by the kinetic parameters are supported by natural thermal-burial histories for the Naokelekan source rock (Type-IIS kerogen) in the Zagros basin of Iraq and for the Green River Formation (Type-I kerogen) in the Uinta basin of Utah. Differences in extent and timing of oil generation determined by open-system pyrolysis and hydrous pyrolysis can be attributed to the former not adequately simulating natural oil generation conditions, products, and mechanisms.

Organic Geochemistry↗

USGS1954

Sedimentary facies of iron-formation

The sedimentary iron -formations of Precambrian age in the Lake Superior region can be divided on the basis of the dominant original iron mineral into four principal facies : sulfide, carbonate, oxide, and silicate. As chemical sediments, these rocks reflect certain aspects of the chemistry of the depositional environments. The major control, at least for the sulfide, carbonate, and oxide types, probably was the oxidation potential. The evidence indicates that deposition took place in restricted basins, which were separated from the open sea by thresholds that inhibited free circulation and permitted development of abnormalities in oxidation potential and water composition. The sporadic distribution of metamorphism and of later oxidation permits description of the primary facies on the basis of unoxidized, essentially unmetamorphosed material. The sulfide facies is represented by black slates in which pyrite may make up as much as 40 percent of the rock. The free-carbon content of these rocks typically ranges from 5 to 15 percent, indicating that ultra-stagnant conditions prevailed during deposition. Locally, the pyritic rocks contain layers of iron -rich carbonate. The carbonate facies consists, in its purer form, of interbedded iron -rich carbonate and chert. It is a product of an environment in which oxygen concentration was sufficiently high to destroy most of the organic material but not high enough to permit formation of ferric compounds. The oxide facies is found as two principal types, one characterized by magnetite and the other by hematite. Both minerals appear to be of primary origin. The magnetite-banded rock is one of the dominant lithologies in the region; it consists typically of magnetite interlayered with chert, carbonate, or iron silicate, or combinations of the three. Its mineralogy and association suggest origin under weakly oxidizing to moderately reducing conditions, but the mode of precipitation of magnetite is not clearly understood. The hematite-banded rocks consist of finely crystalline hematite interlayered with chert or jasper. Oolitic structure is common. This facies doubtless accumulated in a strongly oxidizing, probably near-shore, environment similar to that in which younger hema-titic ironstones such as the Clinton oolite were deposited. The silicate facies contains one or more of the hydrous ferrous silicates (greenalite, minnesotaite, stilpnomelane, chlorite) as a major constituent. Granule structure, similar to that of glauconite, is typical of some varieties; others are nongranular and finely laminated. The most common association of the silicate rocks is with either carbonate- or magnetite-bearing rocks, which suggests that the optimum conditions for deposition ranged from slightly oxidizing to slightly reducing. The relationship between the iron -rich rocks and volcanism, stressed by many authors, is considered by the writer to be structural, not chemical: in the Lake Superior region both iron -deposition and volcanism are believed to be related to geosynclinal development during Huronian time. In Michigan, the lower Huronian rocks are iron -poor quartzite and dolomite-typical "stable-shelf" deposits; much of the upper Huronian consists of iron -poor graywacke and slate with associated volcanic rocks -a typical "geosynclinal" assemblage. Thus the iron -rich beds of the middle Huronian and lower part of the upper Huronian were deposited during a transitional stage in structural history. The major environmental requirement for deposition of iron - formation is the closed or restricted basin; this requirement coincides in time with what would be a normal stage in evolution of the geosyncline: namely, structural development of offshore buckles or swells that subsequently develop into island arcs characterized by volcanism.

Lake Superior↗