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Bibliographies and location maps of aeromagnetic and aeroradiometric publications of the states west of the Mississippi River and east of approximately 104 degrees longitude

Bibliographies and location maps of selected publications containing aeromagnetic and/or aeroradiometric data have been compiled for each state. These state indexes have been grouped together to form seven open-file reports: four for the conterminous United States (see index map below), one for Alaska and Hawaii, one for Puerto Rico and large areas of the United States (U.S. Regional), and one for the Department of Energy (DOE) National Uranium Resource Evaluation (NURE) Program reports.

Arkansas, Iowa, Kansas, Louisiana, Minnesota, Miss

Bibliographies and location maps of aeromagnetic and aeroradiometric publications for the states east of the Mississippi River and north of the Ohio and Potomac rivers

Bibliographies and location maps of selected publications containing aeromagnetic and/or aeroradiometric data have been compiled for each state. These state indexes have been grouped together to form seven open-file reports: four for the conterminous United States (see index map below), one for Alaska and Hawaii, one for Puerto Rico and large areas of the United States (U.S. Regional), and one for the Department of Energy (DOE) National Uranium Resource Evaluation (NURE) Program reports.

Connecticut, Delaware, Illinois, Indiana, Maine, M

Bibliographies and location maps of aeromagnetic and aeroradiometric publications for the states east of the Mississippi River and south of the Ohio and Potomac rivers

Bibliographies and location maps of selected publications containing aeromagnetic and/or aeroradiometric data have been compiled for each state. These state indexes have been grouped together to form seven open-file reports: four for the conterminous United States (see index map below), one for Alaska and Hawaii, one for Puerto Rico and large areas of the United States (U.S. Regional), and one for the Department of Energy (DOE) National Uranium Resource Evaluation (NURE) Program reports.

Alabama, Florida, Georgia, Kentucky, Mississippi,

Bibliographies and location maps of aeromagnetic and aeroradiometric publications for Alaska and Hawaii

Bibliographies and location maps of selected publications containing aeromagnetic and/or aeroradiometric data have been compiled for each state. These state indexes have been grouped together to form seven open-file reports: four for the conterminous United States (see index map below), one for Alaska and Hawaii, one for Puerto Rico and large areas of the United States (U.S. Regional), and one for the Department of Energy (DOE) National Uranium Resource Evaluation (NURE) Program reports.

Alaska, Hawaii

Bibliographies and location maps of aeromagnetic and aeroradiometric publications for Puerto Rico and large areas of the conterminous United States

Bibliographies and location maps of selected publications containing aeromagnetic and/or aeroradiometric data have been compiled for each state. These state indexes have been grouped together to form seven open-file reports: four for the conterminous United States (see index map below), one for Alaska and Hawaii, one for Puerto Rico and large areas of the United States (U.S. Regional), and one for the Department of Energy (DOE) National Uranium Resource Evaluation (NURE) Program reports.

Puerto Rico

Particle-tracking analysis of contributing areas of public-supply wells in simple and complex flow systems, Cape Cod, Massachusetts

Steady-state, two-and three-dimensional, ground-water flow models coupled with a particle- tracking program were evaluated to determine their effectiveness in delineating contributing areas of existing and hypothetical public-supply wells pumping from two contrasting stratified-drift aquifers of Cape Cod, Mass. Several of the contri- buting areas delineated by use of the three- dimensional models do not conform to simple ellipsoidal shapes that are typically delineated by use of a two-dimensional analytical and numerical modeling techniques, include dis- continuous areas of the water table, and do not surround the wells. Because two-dimensional areal models do not account for vertical flow, they cannot adequately represent many of the hydro- geologic and well-design variables that were shown to complicate the delineation of contributing areas in these flow systems, including the presence of discrete lenses of 1ow hydraulic conductivity, large ratios of horizontal to ver- tical hydraulic conductivity, shallow streams, partially penetrating supply wells, and 1ow pumping rates (less than 0.1 million gallons per day). Nevertheless, contributing areas delineated for two wells in the simpler of the two flow systems--a thin (less than 100 feet), single- layer, uniform aquifer with near-ideal boundary conditions--were not significantly different for the two- or three-dimensional models of the natural system, for a pumping rate of 0.5 million gallons per day. Use of particle tracking helped identify the source of water to simulated wells, which included precipitation recharge, wastewater return flow, and pond water. Pond water and wastewater return flow accounted for as much as 73 and 40 percent, respectively, of the water captured by simulated wells.

Massachusetts

Integrated mineral-resource and mineral-environmental assessments of public lands: Applications for land management and resource planning

Mineral-deposit geology is an important control on natural contamination from unmined mineral deposits, and on the environmental effects of mining and mineral processing. The U. S. Geological Survey, Office of Mineral Resources (USGS/OMR) is now integrating geology-based environmental assessments into its mineral resource assessments of public and other lands. This report presents prototype mineralenvironmental assessments of the State of Colorado and the San Juan National Forest. The following pages will show examples of how geologic information can be used to help predict and prevent adverse environmental effects of mineralresource development.

Colorado

Annotated bibliography of selected publications, through 1996, Cheyenne municipal well field areas, Cheyenne, Wyoming

Annotated bibliographies for 55 hydrology and geology manuscripts pertaining to the Cheyenne municipal wells fields are listed in this report. For each manuscript, a citation is provided, a summaryparagraph is presented, key words are listed, and a location of the report is given. The report lists manuscripts, conference proceedings, and guidebooks published by the U. S. Geological Survey, State of Wyoming, Geological Society of America, Wyoming State Geological Survey, private consultants, and University of Wyoming. Information on geological formations, structural geology, aquifer characteristics, water levels, well- field production, water-demand projections, and water quality is included in the manuscripts. The Cheyenne Board of Public Utilities, the University of Wyoming, and the U. S. Geological Surveycooperatively produced this annotated bibliography to allow easy access and efficient utilization of existing data. The manuscripts were authored between 1910 and 1996, reflecting work completed over a long period of development in the Cheyenne, Wyoming area. Some manuscripts did not receive broad distribution and indexing, thus they have been difficult to locate in the past. By having the references and summaries within one report, time and effort to gather previous study results will be minimized.

Wyoming

The Loma Prieta, California, earthquake of October 17, 1989 - Public response: Chapter B in The Loma Prieta, California, earthquake of October 17, 1989: Societal Response (Professional Paper 1553)

Major earthquakes provide seismologists and engineers an opportunity to examine the performance of the Earth and the man-made structures in response to the forces of the quake. So, too, do they provide social scientists an opportunity to delve into human responses evoked by the ground shaking and its physical consequences. The findings from such research can serve to guide the development and application of programs and practices designed to reduce death, injury, property losses, and social disruption in subsequent earthquakes. This chapter contains findings from studies focused mainly on public response to the Loma Prieta earthquake; that is, on the behavior and perceptions of the general population rather than on the activities of specific organizations or on the impact on procedures or policies. A major feature of several of these studies is that the information was collected from the population throughout the Bay area, not just from persons in the most badly damaged communities or who had suffered the greatest losses. This wide range serves to provide comparisons of behavior for those most directly affected by the earthquake with others who were less directly affected by it but still had to consider it very “close to home.”

California

Hydrogeologic investigation, water chemistry analysis, and model delineation of contributing areas for City of Tallahassee public-supply wells, Tallahassee, Florida

Ground water from the Upper Floridan aquifer is the sole source of water supply for Tallahassee, Florida, and the surrounding area. The City of Tallahassee (the City) currently operates 28 water-supply wells; 26 wells are distributed throughout the City and 2 are located in Woodville, Florida. Most of these wells yield an ample supply of potable water; however, water from several wells has low levels of tetrachloroethylene (PCE). The City removes the PCE from the water by passing it through granular-activated carbon units before distribution. To ensure that water-supply wells presently free of contamination remain clean, it is necessary to understand the ground-water flow system in sufficient detail to protect the contributing areas. Ground-water samples collected from four public-supply wells were analyzed for tritium ( 3 H), chlorofluorocarbons (CFCs), and sulfur hexafluoride (SF 6 ). Using data for the CFC compounds, apparent ground-water ages ranged from 7 to 31 years. For SF 6 , the apparent ages tended to be about 5 to 10 years younger than those from CFCs. Apparent ages based on the tritium/tritiogenic helium-3 ( 3 H/ 3 He trit ) method ranged from 26 to 33 years. The three dating methods indicate that the apparent age of ground water generally decreases from northern to southern Leon County. This southward trend of decreasing ages is consistent with increasing amounts of recharge that occur as ground water moves from north to south. The ground-water age data derived by geochemical and tracer analyses were used in combination with the flow model and particle tracking to determine an effective porosity for the Hawthorn clays and Upper Floridan aquifer. The effective porosities for the Upper Floridan aquifer that resulted in best model matches were averaged to produce an effective porosity of 7 percent, and the effective porosities for the Hawthorn clays that resulted in a match were averaged to produce an effective porosity of 22 percent. Probabilistic contributing areas were determined for 26 City wells using MODFLOW and MODPATH. For each probabilistic contributing area delineated, the model was run 100 times and the results were analyzed statistically. For each of the 100 runs, a different hydraulic conductivity for each of the zones was assigned to the Upper Floridan aquifer. The hydraulic conductivities were generated randomly assuming a lognormal probability distribution; the mean of the distribution was equal to the hydraulic conductivity from the calibrated model. The 5-year time-dependent capture zones (TDCZs), assuming effective porosities of 0.1, 1, and 7 percent for four representative wells, were delineated. The higher probabilities of capture (greater than 40, 60, and 80 percent) were similar for all effective porosities, and the TDCZ delineated using a 7-percent porosity was slightly smaller; the lower probabilities of capture (greater than 10 and 20 percent) showed a large range of variability.

Florida

Summary of selected U.S. Geological survey data on domestic well water quality for the Centers for Disease Control's National Environmental Public Health Tracking Program

About 10 to 30 percent of the population in most States uses domestic (private) water supply. In many States, the total number of people served by domestic supplies can be in the millions. The water quality of domestic supplies is inconsistently regulated and generally not well characterized. The U.S. Geological Survey (USGS) has two water-quality data sets in the National Water Information System (NWIS) database that can be used to help define the water quality of domestic-water supplies: (1) data from the National Water-Quality Assessment (NAWQA) Program, and (2) USGS State data. Data from domestic wells from the NAWQA Program were collected to meet one of the Program's objectives, which was to define the water quality of major aquifers in the United States. These domestic wells were located primarily in rural areas. Water-quality conditions in these major aquifers as defined by the NAWQA data can be compared because of the consistency of the NAWQA sampling design, sampling protocols, and water-quality analyses. The NWIS database is a repository of USGS water data collected for a variety of projects; consequently, project objectives and analytical methods vary. This variability can bias statistical summaries of contaminant occurrence and concentrations; nevertheless, these data can be used to define the geographic distribution of contaminants. Maps created using NAWQA and USGS State data in NWIS can show geographic areas where contaminant concentrations may be of potential human-health concern by showing concentrations relative to human-health water-quality benchmarks. On the basis of national summaries of detection frequencies and concentrations relative to U.S. Environmental Protection Agency (USEPA) human-health benchmarks for trace elements, pesticides, and volatile organic compounds, 28 water-quality constituents were identified as contaminants of potential human-health concern. From this list, 11 contaminants were selected for summarization of water-quality data in 16 States (grantee States) that were funded by the Environmental Public Health Tracking (EPHT) Program of the Centers for Disease Control and Prevention (CDC). Only data from domestic-water supplies were used in this summary because samples from these wells are most relevant to human exposure for the targeted population. Using NAWQA data, the concentrations of the 11 contaminants were compared to USEPA human-health benchmarks. Using NAWQA and USGS State data in NWIS, the geographic distribution of the contaminants were mapped for the 16 grantee States. Radon, arsenic, manganese, nitrate, strontium, and uranium had the largest percentages of samples with concentrations greater than their human-health benchmarks. In contrast, organic compounds (pesticides and volatile organic compounds) had the lowest percentages of samples with concentrations greater than human-health benchmarks. Results of data retrievals and spatial analysis were compiled for each of the 16 States and are presented in State summaries for each State. Example summary tables, graphs, and maps based on USGS data for New Jersey are presented to illustrate how USGS water-quality and associated ancillary geospatial data can be used by the CDC to address goals and objectives of the EPHT Program.

Scientific Investigations Report

Hydrogeology, Chemical Characteristics, and Transport Processes in the Zone of Contribution of a Public-Supply Well in York, Nebraska

In 2001, the U.S. Geological Survey, as part of the National Water Quality Assessment (NAWQA) Program, initiated a topical study of Transport of Anthropogenic and Natural Contaminants (TANC) to PSW (public-supply wells). Local-scale and regional-scale TANC study areas were delineated within selected NAWQA study units for intensive study of processes effecting transport of contaminants to PSWs. This report describes results from a local-scale TANC study area at York, Nebraska, within the High Plains aquifer, including the hydrogeology and geochemistry of a 108-square-kilometer study area that contains the zone of contribution to a PSW selected for study (study PSW), and describes factors controlling the transport of selected anthropogenic and natural contaminants to PSWs. Within the local-scale TANC study area, the High Plains aquifer is approximately 75 m (meter) thick, and includes an unconfined aquifer, an upper confining unit, an upper confined aquifer, and a lower confining unit with lower confined sand lenses (units below the upper confining unit are referred to as confined aquifers) in unconsolidated alluvial and glacial deposits overlain by loess and underlain by Cretaceous shale. From northwest to southeast, land use in the local-scale TANC study area changes from predominantly irrigated agricultural land to residential and commercial land in the small community of York (population approximately 8,100). For the purposes of comparing water chemistry, wells were classified by degree of aquifer confinement (unconfined and confined), depth in the unconfined aquifer (shallow and deep), land use (urban and agricultural), and extent of mixing in wells in the confined aquifer with water from the unconfined aquifer (mixed and unmixed). Oxygen (delta 18O) and hydrogen (delta D) stable isotopic values indicated a clear isotopic contrast between shallow wells in the unconfined aquifer (hereinafter, unconfined shallow wells) and most monitoring wells in the confined aquifers (hereinafter, confined unmixed wells). Delta 18O and delta D values for a minority of wells in the confined aquifers were intermediate between those for the unconfined shallow wells and those for the confined unmixed wells. These intermediate values were consistent with mixing of water from unconfined and confined aquifers (hereinafter, confined mixed wells). Oxidation-reduction conditions were primarily oxic in the unconfined aquifer and variably reducing in the confined aquifers. Trace amounts of volatile organic compounds (VOC), particularly tetrachloroethylene (PCE) and trichloroethylene (TCE), were widely detected in unconfined shallow urban wells and indicated the presence of young urban recharge waters in most confined mixed wells. The presence of degradation products of agricultural pesticides (acetochlor and alachlor) in some confined mixed wells suggests that some fraction of the water in these wells also was the result of recharge in agricultural areas. In the unconfined aquifer, age-tracer data (chlorofluorocarbon and sulfur hexafluoride data, and tritium to helium-3 ratios) fit a piston-flow model, with apparent recharge ages ranging from 7 to 48 years and generally increasing with depth. Age-tracer data for the confined aquifers were consistent with mixing of 'old' water, not containing modern tracers recharged in the last 60 years, and exponentially-mixed 'young' water with modern tracers. Confined unmixed wells contained less than (<) 3 percent (%) young water mixed with a much larger fraction greater than or equal to (>=) 97% of old water. Confined mixed wells contained >30% young water and mean ages ranged from 12 to 14 years. Median concentrations of nitrate (as nitrogen, hereinafter, nitrate-N) were 17.3 and 16.0 mg/L (milligram per liter) in unconfined shallow urban and agricultural wells, respectively, indicating a range of likely nitrate sources. Septic systems are most numerous near the edge of the urban area and appear to be

Scientific Investigations Report

Hydrogeology, chemical characteristics, and water sources and pathways in the zone of contribution of a public-supply well in San Antonio, Texas

In 2001, the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey initiated a series of studies on the transport of anthropogenic and natural contaminants (TANC) to public-supply wells (PSWs). The main goal of the TANC project was to better understand the source, transport, and receptor factors that control contaminant movement to PSWs in representative aquifers of the United States. Regional- and local-scale study areas were selected from within existing NAWQA study units, including the south-central Texas Edwards aquifer. The local-scale TANC study area, nested within the regional-scale NAWQA study area, is representative of the regional Edwards aquifer. The PSW selected for study is within a well field of six production wells. Although a single PSW was initially selected, because of constraints of well-field operation, samples were collected from different wells within the well field for different components of the study. Data collected from all of the well-field wells were considered comparable because of similar well construction, hydrogeology, and geochemistry. An additional 38 PSWs (mostly completed in the confined part of the aquifer) were sampled throughout the regional aquifer to characterize water quality. Two monitoring well clusters, with wells completed at different depths, were installed to the east and west of the well field (the Zarzamora and Timberhill monitoring well clusters, respectively). One of the monitoring wells was completed in the overburden to evaluate potential hydrologic connectivity with the Edwards aquifer. Geophysical and flowmeter logs were collected from one of the well-field PSWs to determine zones of contribution to the wellbore. These contributing zones, associated with different hydrogeologic units, were used to select monitoring well completion depths and groundwater sample collection depths for depth-dependent sampling. Depth-dependent samples were collected from the PSW from three different depths and under three different pumping conditions. Additionally, selected monitoring wells and one of the well-field PSWs were sampled several times in response to a rainfall and recharge event to assess short-term (event-scale) temporal variations in water quality. For comparison purposes, groundwater samples were categorized as being from regional aquifer PSWs, from the well field (wellhead samples), from the monitoring wells (excluding the overburden well), from the overburden well, from the PSW depth-dependent sampling, and from temporal sampling. Groundwater samples were analyzed for inorganic, organic, isotopic, and age-dating tracers to characterize geochemical conditions in the aquifer and provide understanding of the mechanisms of mobilization and movement of selected constituents from source areas to a PSW. Sources, tracers, and conditions used to assess water quality and processes affecting the PSW and the aquifer system included (1) carbonate host rock composition; (2) physicochemical constituents; (3) major and trace element concentrations; (4) saturation indices with respect to minerals in aquifer rocks; (5) elemental ratios, such as magnesium to calcium ratios, that are indicative of water-rock interaction processes; (6) oxidation-reduction conditions; (7) nutrient concentrations, in particular nitrate concentrations; (8) the isotopic composition of nitrate, which can point to specific nitrate sources; (9) strontium isotopes; (10) stable isotopes of hydrogen and oxygen; (11) organic contaminant concentrations, including pesticides and volatile organic compounds; (12) age tracers, apparent-age distribution, and dissolved gas data used in age interpretations; (13) depth-dependent water chemistry collected from the PSW under different pumping conditions to assess zones of contribution; and (14) temporal variability in groundwater composition from the PSW and selected monitoring wells in response to an aquifer recharge event. Geochemical results indicate that the well-field and monitoring well samples were largely representative of groundwater in the regional confined aquifer. Constituents of concern in the Edwards aquifer for the long-term sustainability of the groundwater resource include the nutrient nitrate and anthropogenic organic contaminants. Nitrate concentrations (as nitrogen) for regional aquifer PSWs had a median value of 1.9 milligrams per liter, which is similar to previously reported values for the regional aquifer. Nitrate-isotope compositions for groundwater samples collected from the well-field PSWs and monitoring wells had a narrow range, with values indicative of natural soil organic values. A comparison with historical nitrate-isotope values, however, suggests that a component of nitrate in groundwater from biogenic sources might have increased over the last 30 years. Several organic contaminants (the pesticide atrazine, its degradate deethylatrazine, trichloromethane (chloroform; a drinking-water disinfection byproduct), and the solvent tetrachloroethene (PCE)) were widely distributed throughout the regional aquifer and in the local-scale TANC study area at low concentrations (less than 1 microgram per liter). Higher concentrations of PCE were detected in samples from the well-field PSWs and Zarzamora monitoring wells relative to the regional aquifer PSWs. The urban environment is a likely source of contaminants to the aquifer, and these results indicate that one or more local urban sources might be supplying PCE to the Zarzamora monitoring wells and the well-field wells. Samples from the well field also had high concentrations of chloroform relative to the monitoring wells and regional aquifer PSWs. For samples from the regional aquifer PSWs, the most frequently detected organic contaminants generally decreased in concentration with increasing well depth. Deeper wells might intercept longer regional flow paths with higher fractions of older water or water recharged in rural recharge areas in the western part of the aquifer that have been less affected by anthropogenic contaminants. A scenario of hypothetical contaminant loading was evaluated by using results from groundwater-flow-model particle tracking to assess the response of the aquifer to potential contamination. Results indicate that the aquifer responds quickly (less than 1 year to several years) to contaminant loading; however, it takes a relatively long time (decades) for concentrations to reach peak values. The aquifer also responds quickly (less than 1 year to several years) to the removal of contaminant loading; however, it also takes a relatively long time (decades) to reach near background concentrations. Interpretation of geochemical age tracers in this well-mixed karst system was complicated by contamination of a majority of measured tracers and complexities of extensive mixing. Age-tracer results generally indicated that groundwater samples were composed of young, recently recharged water with piston-flow model ages ranging from less than 1 to 41 years, with a median of 17 years. Although a piston-flow model is typically not valid for karst aquifers, the model ages provide a basis for comparing relative ages of different samples and a reference point for more complex hydrogeologic models for apparent-age interpretations. Young groundwater ages are consistent with particle-tracking results from hydrogeologic modeling for the local-scale TANC study area. Age-tracer results compared poorly with other geochemical indicators of groundwater residence time and anthropogenic effects on water quality, indicating that hydrogeologic conceptual models used in groundwater age interpretations might not adequately account for mixing in this karst system. Groundwater samples collected from the well field under a variety of pumping conditions were relatively homogeneous and well mixed for numerous geochemical constituents (with the notable exception of age tracers). Groundwater contributions to the PSW were dominated by well-mixed, relatively homogeneous groundwater, typical of the regional confined aquifer. Zones of preferential flow were determined for the PSW, but groundwater samples from different stratigraphic units were not geochemically distinct. Variations in chemical constituents in response to a rainfall and aquifer recharge event occurred but were relatively minor in the PSW and monitoring wells. This observation is consistent with the hypothesis that the response to individual recharge events in the confined aquifer, unless intersecting conduit flow paths, might be attenuated by mixing processes along regional flow paths. Results of this study are consistent with the existing conceptual understanding of aquifer processes in this karst system and are useful for water-resource development and management practices.

Texas

Ecosystem services valuation to support decisionmaking on public lands—A case study of the San Pedro River watershed, Arizona

This report details the findings of the Bureau of Land Management–U.S. Geological Survey Ecosystem Services Valuation Pilot Study. This project evaluated alternative methods and tools that quantify and value ecosystem services, and it assessed the tools’ readiness for use in the Bureau of Land Management decisionmaking process. We tested these tools on the San Pedro River watershed in northern Sonora, Mexico, and southeast Arizona. The study area includes the San Pedro Riparian National Conservation Area (managed by the Bureau of Land Management), which has been a focal point for conservation activities and scientific research in recent decades. We applied past site-specific primary valuation studies, value transfer, the Wildlife Habitat Benefits Estimation Toolkit, and the Integrated Valuation of Ecosystem Services and Tradeoffs (InVEST) and Artificial Intelligence for Ecosystem Services (ARIES) models to value locally important ecosystem services for the San Pedro River watershed—water, carbon, biodiversity, and cultural values. We tested these approaches on a series of scenarios to evaluate ecosystem service changes and the ability of the tools to accommodate scenarios. A suite of additional tools were either at too early a stage of development to run, were proprietary, or were place-specific tools inappropriate for application to the San Pedro River watershed. We described the strengths and weaknesses of these additional ecosystem service tools against a series of evaluative criteria related to their usefulness for Bureau of Land Management decisionmaking. Using these tools, we quantified gains or losses of ecosystem services under three categories of scenarios: urban growth, mesquite management, and water augmentation. These results quantify tradeoffs and could be useful for decisionmaking within Bureau of Land Management district or field offices. Results are accompanied by a relatively high level of uncertainty associated with model outputs, valuation methods, and discount rates applied. Further guidance on representing uncertainty and applying uncertain results in decisionmaking would benefit both tool developers and those offices in using ecosystem services to compare management tradeoffs. Decisionmakers and Bureau of Land Management managers at the State-, district-, and field-office level would also benefit from continuing model improvements, training, and guidance on tool use that can be provided by the U.S. Geological Survey, the Bureau of Land Management, and the Department of the Interior. Tradeoffs were identified in the level of effort needed to parameterize and run tools and the amount and quality of information they provide to the decision process. We found the Wildlife Habitat Benefits Estimation Toolkit, Ecosystem Services Review, and United Nations Environment Programme–World Conservation Monitoring Centre Ecosystem Services Toolkit to be immediately feasible for application by the Bureau of Land Management, given proper guidance on their use. It is also feasible for the Bureau of Land Management to use the InVEST model, but in early 2012 the process of parameterizing the model required resources and expertise that are unlikely to be available in most Bureau of Land Management district or field offices. Application of past primary valuation is feasible, but developing new primary-valuation studies is too time consuming for regular application. Value transfer approaches (aside from the Wildlife Habitat Benefits Estimation Toolkit) are best applied carefully on the basis of guidelines described in this report, to reduce transfer error. The ARIES model can provide useful information in regions modeled in the past (Arizona, California, Colorado, and Washington), but it lacks some features that will improve its usability, such as a generalized model that could be applied anywhere in the United States. Eleven other tools described in this report could become useful as the tools more fully develop, in high-profile cases for which additional resources are available for tool application or in case-study regions where place-specific models have already been developed. To improve the value of these tools in decisionmaking, we suggest scientific needs that agencies such as U.S. Geological Survey can help meet—for instance, development and support of data archives. Such archives could greatly reduce resource needs and improve the reliability and consistency of results. Given the rapid state of evolution in the field, periodic follow-up studies on ecosystem services tools would help to ensure that the Bureau of Land Management and other public land management agencies are kept up to date on new tools and features that bring ecosystem services closer to readiness for use in regular decisionmaking.

Arizona;Sonora

Simulated water-table and pond-level responses to proposed public water-supply withdrawals in the Hyannis Ponds Wildlife Management Area, Barnstable, Massachusetts

The glacial kettle ponds in the Hyannis Ponds Wildlife Management Area in Barnstable, Massachusetts, support a community of rare and endangered plants. The ponds are hydraulically connected to the unconfined aquifer that underlies Cape Cod. The plants are adapted to the rise and fall of water levels in the ponds as the water table fluctuates in response to seasonal and year-to-year natural changes in recharge. Pumping from wells for public water supply and recharge of wastewater at water pollution control facilities and septic systems also affect groundwater levels. The Hyannis Water System has proposed to install two additional wells in the Hyannis Ponds Wildlife Management Area and adjust rates of withdrawals and recharge of wastewater return flows for the municipal system that serves the village of Hyannis in the town of Barnstable. The proposal has raised concerns that pumping from the proposed wells could cause long-term average changes in pond levels that could adversely affect the critical pond-shore plant habitat. An available three-dimensional steady-state groundwater-flow model was used to simulate the hydrologic effects of nine pumping and wastewater return-flow scenarios prepared by the Hyannis Water System. These effects were quantified by comparison of water levels simulated for the scenarios to water levels simulated for a reference condition based on 2015 withdrawal and wastewater return-flow rates. Maps of water-level responses were prepared to show the effects of pumping from a single well at different locations in the Hyannis Ponds Wildlife Management Area on the water levels of six ponds. Steady-state simulations of the nine scenarios indicated that the shapes of the simulated water-table contours near the wildlife management area changed only slightly at the regional scale, with the largest shifts near the wildlife management area and the Barnstable Water Pollution Control Facility. The simulated changes in pond levels at 10 ponds of interest for the nine scenarios relative to the simulated pond levels for the 2015 reference condition ranged from small increases (less than 0.1 foot) in one pond each in two scenarios to declines (drawdowns) of 1.03–1.11 feet at three ponds in one scenario. Water levels at the Barnstable Water Pollution Control Facility increased because part of the increase in total withdrawals from the Hyannis Water System wells was recharged as wastewater at the water pollution control facility.

Massachusetts

Water Quality of groundwater used for public supply in principal aquifers of the western United States

Groundwater provides nearly half of the Nation’s drinking water. As the Nation’s population grows, the importance of (and need for) high-quality drinking-water supplies increases. As part of a national-scale effort to assess groundwater quality in principal aquifers (PAs) that supply most of the groundwater used for public supply, the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Project staff sampled six principal aquifers in the western United States between 2013 and 2017: (1) the Basin and Range carbonate-rock aquifers, (2) Basin and Range basin-fill aquifers, (3) Rio Grande aquifer system, (4) High Plains aquifer, (5) Colorado Plateaus aquifers, and (6) Columbia Plateau basaltic-rock aquifers. These six PAs supply a large part of the Nation’s drinking water and cover a large geographic extent of the western conterminous United States. Groundwater samples were analyzed for a large suite of water-quality constituents including major ions, nutrients, trace elements, volatile organic compounds (VOCs), pesticide compounds, radioactive constituents, age tracers, and, in selected PAs, perchlorate. Two types of assessments were made: (1) a status assessment that describes the quality of the groundwater resource at time of collection and (2) an understanding assessment that evaluates relations between groundwater quality and potential explanatory factors that represent characteristics of the aquifer system. The assessments characterize untreated groundwater quality, which might be different than the quality of drinking water delivered to consumers. The assessments are based on water-quality data collected from 352 wells and 6 springs using an equal-area grid sampling design. This sampling approach allows for the estimation of the proportion of high, moderate, or low concentrations relative to federal water-quality benchmarks of selected constituents in the area of each PA. Results were compared to established benchmarks for drinking-water quality to provide context for evaluating the quality of untreated groundwater: Federal regulatory benchmarks for protecting human health, non-regulatory human-health benchmarks, and non-regulatory benchmarks for nuisance chemicals. Not all constituents that were analyzed have benchmarks and thus were not considered for assessments. Concentrations are characterized as high if they are greater than their benchmark. Concentrations are considered moderate if they are greater than one-half their benchmark (for inorganic constituents), or greater than one-tenth their benchmark (for organic constituents). Concentrations are considered low if they are less than moderate or the constituent was not detected. Status assessment results indicated that inorganic constituents more commonly occurred at high and moderate concentrations in the six PAs than organic constituents, and organic constituents predominately occurred at low concentrations. Inorganic constituents that exceeded health-based benchmarks (high concentrations) were present in all six PAs; aquifer-scale proportion were 30 percent in the Rio Grande aquifer system, 22 percent in the Basin and Range basin-fill aquifers, 20 percent in the Basin and Range carbonate-rock aquifers, 19 percent in the High Plains aquifer, 16 percent in the Colorado Plateaus aquifers, and 8 percent in the Columbia Plateau basaltic-rock aquifers. Arsenic, fluoride, manganese, and total dissolved solids were the constituents most commonly present at high concentrations. Organic constituents with human-health benchmarks (pesticide compounds and VOCs) did not occur at high concentrations and moderate concentrations were infrequent; aquifer-scale proportions ranged from 0 to 5 percent. Detections of organic compounds at low concentrations, however, occurred in all six PAs, with detection frequencies ranging from 10 to 26 percent for pesticide compounds and from 10 to 46 percent for VOCs. Specific organic constituents with detection frequencies greater than 10 percent were four herbicides (atrazine, didealkylatrazine, bromoform, and propazine), one insecticide (propoxur), and two VOCs (the trihalomethanes chloroform and bromodichloromethane). Where collected—in the Rio Grande aquifer system and High Plains aquifer—perchlorate did not occur at high concentrations; moderate aquifer-scale proportions were 3 and 11 percent, respectively. The understanding assessment included statistical tests to evaluate relations between constituent concentrations and potential explanatory factors to identify natural and human factors that affect groundwater quality. Potential explanatory factors included depth to bottom of well perforation, groundwater age category, land use, aquifer lithology, hydrologic conditions, and geochemical conditions. Higher concentrations of trace elements, radioactive constituents, and constituents with non-health-based benchmarks generally were associated with unconsolidated sand and gravel aquifer lithologies, premodern groundwater age, greater aridity, and more alkaline pH. Organic constituents with detection frequencies greater than 10 percent generally were associated with urban land use, shallower well depths, and higher total dissolved solids concentrations. The results for the six western PAs provide important insights into the quality of groundwater that is used for drinking water in the western United States, as well as natural and human factors that affect groundwater quality in this region.

Arizona, California, Colorado, Idaho, Kansas, Mont

Groundwater availability, geochemistry, and flow pathways to public-supply wells in the Atlantic Coastal Plain and bedrock aquifers, Aiken County and part of Lexington County, South Carolina, 2015–2019

Between 2015 and 2019, the U.S. Geological Survey (USGS) studied concerns related to projected increases in demand for groundwater, in collaboration with municipal water providers and county managers within the study area, Aiken County and part of Lexington County, South Carolina. A three-dimensional (3D), numerical groundwater-flow model of the Atlantic Coastal Plain (ACP) aquifers, confining units, and the underlying bedrock aquifer in the study area was constructed using the USGS software program MODFLOW–NWT in conjunction with a groundwater-recharge model using the Soil-Water-Balance (SWB) model. Water budgets for dry (2012) and wet (2015) year conditions, future (2017–2065) groundwater-demand scenarios based on general circulation models (GCMs) of future climates, and future agricultural irrigation demands were simulated. Overall, the GCMs projected increased recharge rates. Simulation of projected increased demand on groundwater by agriculture irrigation indicated little drawdown in the study area. Groundwater-quality samples were collected from representative public-supply wells (PSWs) and analyzed in the field and laboratory. In general, the groundwater in the ACP aquifers is acidic, dilute, and oxic. Conversely, groundwater in the bedrock aquifer was of neutral pH, mineralized, and anoxic. Total-radium concentrations across all PSWs ranged from 0.55 to 6.69 picocuries per liter (pCi/L). Groundwater from some PSWs contained detectable but low concentrations of commonly and historically used volatile organic compounds, such as chloroform, methyl tert -butyl ether (MTBE), cis -1,2-dichloroethylene ( cis -1,2-DCE), 1,1-dichloroethane (1,1-DCA), and 1,1-dichloroethylene (1,1-DCE). The stable isotopes of groundwater sampled from all wells indicate the possibility that groundwater from the bedrock aquifer may discharge into the ACP. Finally, groundwater age-dating results and MODPATH simulations indicate recharge between the 1950s and 1980s for PSWs in the ACP and recharge between the 1940s and 1950s for PSWs in bedrock. Maximum groundwater-flow pathways ranged from 270 to 7,470 feet, with the longest simulated-flow pathway for wells pumped at higher rates.

South Carolina

Monitoring and assessment of urban stormwater best management practices at selected Chicago public schools in Chicago, Illinois, from September 1, 2016, to July 1, 2017

The Space to Grow program helps transform aging and neglected schoolyards of Chicago Public Schools into outdoor community spaces with the goal of promoting health and learning while addressing neighborhood flooding issues. Virgil I. Grissom Elementary School and Donald L. Morrill Math and Science School were selected in 2014 for schoolyard upgrades and the installation of various green infrastructure (GI) improvements. The U.S. Geological Survey installed sensors to measure precipitation, groundwater levels, and stormwater runoff volumes from September 1, 2016, to July 1, 2017. At Virgil I. Grissom Elementary School, about 933,000 gallons of water fell on the schoolyard during the monitoring period. No discharge was recorded coming from the GI sewer lines, but backflow indicated water was flowing from the sewer line draining the impervious running track into the combined manhole structure and backwards into the GI retention basins (as designed). This design allowed for a 100-percent capture rate. Native soil at Virgil I. Grissom Elementary School also was conducive to rapid infiltration. Soil borings at Virgil I. Grissom Elementary School indicated about 10.5 feet (ft) of fine sand overlying silty clay to a depth of at least 16 ft. At Donald L. Morrill Math and Science School, about 1,120,000 gallons of water fell on the schoolyard during the monitoring period. About 72.5 precent of this water was discharged into the sewer system, and the other 27.5 percent was captured by the GI. Unlike Virgil I. Grissom Elementary School, the soil profile at Donald L. Morrill Math and Science School consisted of about 5 ft of clay loam overlying stiff blue clay to a depth of at least 12 ft. The sewer line coming from the GI under the football field was at the bottom of the reservoir. This design seemed to allow water to flow out of the line before being absorbed by the retention basin.

Illinois