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Uranium distribution in pseudowollastonite slag from a phosphorus furnace

Silicate slag from the Victor Chemical Company phosphorus furnace at Tarpon Springs, Fla., has been found to consist essentially of pseudowollastonite, α-CaSiO 3 . The first-formed crystals are euhedral laths which form a mesh making up most of the slag. As the slag continues to solidify, its composition changes slightly and more equant, subhedral crystals of pseudowollastonite are deposited within the framework of the earlier material. Finally, anherdral masses of fibrous, poorly crystallized material are deposited in the remaining pore spaces which are not always completely filled. Spherules of iron phosphide, Fe 2 P, occur very sparsely in the slag as inclusions from the immiscible iron phosphide melt. Uranium content increases in the later crystal products of the slag, and by heavy-liquid fractionation it has been possible to segregate partially the phases and to obtain a fourfold concentration of uranium in 5 percent of the material and a twofold concentration in 30 percent of the material. Nuclear-emulsion studies indicate that the last phases of the silicate slag are actually eight times as radioactive as the early phases. In addition, the iron phosphide spherules are comparably enriches in uranium.

Trace Elements Investigations

Reconnaissance examination for uranium at six mines and properties in Idaho and Montana

Six mining properties in Idaho and Montana at which radioactivity had been reported or suspected were briefly examine by J.S. Vhay and W.A. Roberts of the U.S. Geological Survey in October and November 1949. The properties in Idaho are the Grunter mine, from which radio-active mill concentrates have been reported; the Kentuck mine; the Ulysses-kittie Burton Mill; and the Garm-Lemoreaux mine. The properties in Montana are the Armeson-McKenny property in Beaverhead County and the Oro property in Lincoln County. Moderate to high radioactivity was noted at the Garm-Lemoreaux mine and the Armeson-McKenney property. That most of this radioactivity is not caused by uranium is suggested by the low uranium content of the majority of the samples. One sample from a dump of the Garm-Lemoreaux mine assayed 0.11 percent uranium.

Idaho;Montana

Occurrence of uranium-bearing coal, carbonaceous shale, and carbonaceous limestone in the Fall Creek area, Bonneville County, Idaho

Uraniferous coal, carbonaceous shale, and carbonaceous limestone occur in the Bear River formation of Upper Crestaceous age at the Fall Creek prospect, in the Fall Creek area, Bonneville County, IDaho. The uranium compounds are believed to have been derived from mildly radioactive silicic volcanic rocks of the Tertiary age that rest unconformably on all older rocks and once overlay the Bear River formation and its coal. Meteoric water, percolating downward through the silicic volcanic rocks and into the older rocks along joints and faults, is believed to have brought the uranium compounds into contact with the coal and carbonaceous rocks in which the uranium was absorbed.

Idaho

Results of core drilling for uranium-bearing lignites in the Bar H area, Slim Buttes, Harding County, South Dakota

Core drilling in the Car H area, Slim Buttes, Harding County, South Dakota, under a contract with the B. H. Mott Drilling Co., Huntington, West Virginia, was resumed June 12, 1952 after a 6-month recess during the winter and was completed July 18, 1952. The drilling was undertaken to obtain information on the distribution and extent of the uranium-bearing lignite beds along the southeast edge of the Bar H area. Eight holes totalling 885 feet were drilled and 52 feet of lignite core submitted for study and analysis. The report includes detailed lithographic descriptions of the lignite cores, Bureau of Mines coal analyses, and the results of 100 chemical analyses for uranium. The drilling showed that the thicker, more persistent lignite beds exposed in the northern part of the Bar H area were removed by erosion prior to the deposition of the overlaying White River formation in the south-eastern part of the area. The beds penetrated by drilling were not of sufficient thickness or uranium content to add to the previously known reserves.

South Dakota

Uranium occurrences at the Moonlight Mine and Granite Point claims, Humboldt County, Nevada

The Moonlight mine and Granite Foint claims are on the western flank of the Double H Mountains between the Kings River and Quinn, River valleys in northern Humboldt County, Nev. Uranium minerals at the Moonlight mine occur in a vein in intensely altered Tertiary volcanic rocks. The knovm uranium mineralization is spotty and erratic, but ore-grade material is present in the vein. Samples of the vein taken along its outcrop and in the mine shaft contain from less than 0.02 percent to 0.40 percent U308. The uranium minerals change from autunite at the surface to torbernite, 'gummite(?)' and pitchblende below the 90-foot level of the shaft. The Granite Point claims are two miles north of the Moonlight mine at the base of a rhyolite cliff. Radioactivity traverses made along the base and slope of the rhyolite cliff indicate that a large part of the rhyolite is abnormally radioactive. Radioactivity ranges from 0.013 to 0.3 mr/hr and averaged 0.10 mr/hr. in the vicinity of the claims. A sample taken at the base of the rhyolite cliff, at the point of highest radioactivity c6ntains 0.02 percent U3O8.

Trace Elements Memorandum

A reconnaissance for uranium in carbonaceous rocks in southwestern Colorado and parts of New Mexico

Coal and carbonaceous shale of the Dakota formation of Cretaceous age were examined for radioactivity in the Colorado Plateau of southwestern Colorado and northwestern New l1exico during the summer of 1953. Older and younger sedimentary rocks and some igneous rocks also were examined, but in less detail, Weak radioactivity was detected at many places but no new deposits of apparent economic importance were discovered. The highest radioactivity of carbonaceous rocks was detected in black shale, siltstone, and sandstone of the Paradox member of the Hermosa formation of Pennsylvanian age. A sample collected from this member at the Bald Eagle prospect in Gypsum Valley, San Higuel County, Colo. contains 0.10. percent uranium. Carbonaceous rocks were investigated at several localities on the Las Vegas Plateau and the Canadian Escarpment in Harding and San Miguel Counties, northeastern New Mexico. Carbonaceous sandstone and siltstone in the middle sandstone member of the Chinle formation of Triassic age contain uranium at a prospect of the Hunt Oil Company southwest of Sabinoso in northeastern San Miguel County, N. Mex. A channel sample across 3.2 feet of mineralized rocks at this locality contains 0.22 percent uranium. Weak radioactivity was detected at two localities in carbonaceous shale of the Dakota and Purgatoire formations of Cretaceous age.

Trace Elements Memorandum

Effects of uranium-mining releases on ground-water quality in the Puerco River Basin, Arizona and New Mexico

Shallow ground water beneath the Puerco River of Arizona and New Mexico was studied to determine the effects of uranium-mining releases on water quality. Ground-water samples collected from 1989 to 1991 indicate that concentrations of dissolved uranium have decreased. Most samples from the alluvial aquifer downstream from Gallup, New Mexico, met with U.S. Environmental Protection Agency's maximum contaminant levels for gross alpha, gross beta, and radium and the proposed maximum contaminant level for uranium.

Water Supply Paper

Development and description of a composite hydrogeologic framework for inclusion in a geoenvironmental assessment of undiscovered uranium resources in Pliocene- to Pleistocene-age geologic units of the Texas Coastal Plain

A previously completed mineral resources assessment of the Texas Coastal Plain indicated the potential for the future discovery of uranium resources. Geoenvironmental assessments that include the hydrogeologic framework can be used as a tool to understand the potential effects of mining operations. The hydrogeologic framework for this study focused on the composite hydrogeologic unit of the tract permissive for the occurrence of uranium consisting of the upper part of the Miocene-age Fleming Formation/Lagarto Clay, Pliocene-age Goliad and Pleistocene-age Willis Sands, Pleistocene-age Lissie and Beaumont Formations, and Holocene-age alluvial sediments (fluvial alluvium and eolian sand deposits). This composite hydrogeologic unit, which contains the Chicot and Evangeline aquifers of the Gulf Coast aquifer system, is intended for inclusion in a regional-scale geoenvironmental assessment of as yet undiscovered uranium resources. This article provides (1) a brief literature review describing the geologic and hydrogeologic settings, (2) the methodology used to develop a composite hydrogeologic framework, and (3) descriptions and maps of the land-surface altitude, composite hydrogeologic unit base and midpoint depth, water-level altitude, depth of water, unsaturated and saturated zone thickness, and transmissivity and hydraulic conductivity. A composite hydrogeologic unit, created by combining geologic and hydrogeologic data and maps for individual geologic and hydrogeologic units, is intended for use as a tool in a geoenvironmental assessment to evaluate potential contaminant migration through various avenues. Potential applications include using the hydrogeologic framework as an input into a geoenvironmental assessment to help estimate the potential for (1) runoff of contaminants into surface water, (2) infiltration of contaminants into the groundwater (aquifers), or (3) movement of contaminants from the mining area through wind, groundwater-flow, or streamflow in a given permissive tract. The procedures outlined in this paper also provide a method for developing hydrogeologic frameworks that can be applied in other areas where mining may occur.

Texas

Seasonal activity and diets of bats at uranium mines and adjacent areas near the Grand Canyon

Little information exists on the habitat use and feeding ecology of insectivorous bats in arid ecosystems, especially at and near uranium mines in northern Arizona, within the Grand Canyon watershed. In 2015–2016, we conducted mist-netting, nightly acoustic monitoring (>1 year), and diet analyses of bats, as well as insect sampling, at 2 uranium mines (Pinenut and Arizona 1) with water containment ponds. Because of physical barriers and limited general access to areas within the mine yard, mist-netting was limited to outside of the perimeter fence and away from the containment ponds. Mist-netting also occurred at 2 nearby sites that served as proxies to the mines. Bats captured directly at the mines included one pregnant Antrozous pallidus and 3 adult male Parastrellus hesperus . At the proxy sites, we captured 45 individuals identified as A. pallidus , Corynorhinus townsendii , Eptesicus fuscus , Euderma maculatum , Lasionycteris noctivagans , Myotis californicus , Myotis ciliolabrum , P. hesperus , and Tadarida brasiliensis . The nightly and seasonal presence of bats, as shown through acoustic recordings at each mine, coincided with the seasonal migratory and hibernation behaviors of the bat species. Statistical comparisons of acoustic recordings with precipitation data collected over one year show that seasonal monsoon rains generally had a negative effect on the nightly activity and presence of bats. Diets of P. hesperus from both mines were comprised mostly of coleopterans but also included smaller volumes of Hymenoptera, Hemiptera, Lepidoptera, Diptera, and Neuroptera. The diet of A. pallidus was comprised solely of Coleoptera. Diets of bat species from the proxy sites were characteristic of their known feeding ecology, which ranged from the consumption of soft-bodied insects (e.g., moths) by C. townsendii to the consumption of hard-bodied insects (e.g., beetles) by E. fuscus . Ultimately, the increased knowledge of the natural history of bats through multiple methods of data collection allows for a better understanding of complex arid ecosystems. It also provides resources needed for the management of habitat associated with alternative energy, such as uranium mining.

Arizona

Geochemical processes controlling uranium mobility in mine drainages

Comprehensive models of ore genesis incorporate metal sources, transport and concentration mechanisms, and preservation mechanisms. Analogous concepts apply to the problem of metal migration from mines, mine wastes, and mine tailings, including: the concentrations, mineralogical occurrence, and availability of metals in mineral deposits, host rocks, mine wastes, and tailings (the source); the mechanisms for metal mobilization and transport during weathering; the mechanisms for metal fixation and the permanence of the fixation. Similarly, undisturbed mineral deposits or alteration zones that are exposed at the Earth's surface may be natural sources from which metals can be solubilized during weathering. Uranium (U), a naturally-occurring radioactive element, may be present in mineral deposits in sufficient concentrations that in itself constitutes ore. It may also be present in ores of other metals at concentrations that exceed average crustal abundances. Any uranium that is not completely removed from these ores in the mining and milling process may be available for mobilization into ground or surface waters via the weathering and oxidation of solid tailings or mine waste piles. This chapter discusses the relative importance of various geochemical processes that control uranium mobility via weathering in both mined and unmined mineralized environments. The data presented in this paper focus on mined areas because the great extent of historic mining in the field areas examined for this study preclude extensive consideration of undisturbed areas.

Book chapter

Sedimentary depositional environments of uranium and petroleum host rocks of the Jackson Group, south Texas

Determination of depositional environments in rocks of the Jackson Group of late Eocene age aids in the exploration for uranium and petroleum in south Texas. During deposition of the Jackson Group, conditions were similar to those existing along the modern Gulf Coast of Texas except for a less arid climate and a greater supply of volcanic sediment. Sedimentary depositional environments recognized in both the modern coast and the Jackson rocks, in order from sea toward land, are: shoreface, beach, lagoon and bay, and paludal. Sediment deposited in these environments in places is interbedded with or transected by fluvial sediment. Both uranium and petroleum are found in the shoreface, beach, and fluvial facies. These facies are characterized by permeable well-sorted sandstone, which is commonly overlain and underlain by less permeable mudstone. A typical vertical sequence in ascending order through a unit containing a beach sandstone facies is (1) lagoonal or paludal clay stone and siltstone, (2) crossbedded fine-grained beach sandstone which contains Ophiomorpha burrows and, which, in places, is locally interbedded with lacustrine or lagoonal mudstone, (3) weakly laminated beach sandstone which contains root impressions at the top and Ophiomorpha , and (4) lagoonal or paludal claystone and siltstone. Gulfward, the beach sandstone apparently grades into highly burrowed, generally finer grained, more poorly sorted, less porous shoreface rocks. The beach facies may include barrier island beaches and mainland beaches, some of which were probably cheniers. Beach facies sandstone units extend many miles along the depositional strike, which nearly parallels the present outcrop strike, but extend only a mile or two (2-3 km) normal to the depositional strike into the subsurface. Recognition of the various facies in outcrops and drill holes is necessary for determination of true stratigraphic relations and for aid in exploration for beach and fluvial sandstone favorable for uranium and petroleum accumulations.

Texas

World distribution of uranium deposits

Deposit data derived from IAEA UDEPO (http://infcis.iaea.org/UDEPO/About.cshtml) database with assistance from P. Bruneton (France) and M. Mihalasky (U.S.A.). The map is an updated companion to "World Distribution of Uranium Deposits (UDEPO) with Uranium Deposit Classification, IAEA Tech-Doc-1629". Geology was derived from L.B. Chorlton, Generalized Geology of the World, Geological Survey of Canada, Open File 5529 , 2007. Map production by M.C. Fairclough (IAEA), J.A. Irvine (Austrailia), L.F. Katona (Australia) and W.L. Slimmon (Canada). World Distribution of Uranium Deposits, International Atomic Energy Agency, Vienna, Austria. Cartographic Assistance was supplied by the Geological Survey of South Australia, the Saskatchewan Geological Survey and United States Geological Survey to the IAEA. Coastlines, drainage, and country boundaries were obtained from ArcMap, 1:25 000 000 scale, and are copyrighted data containing the intellectual property of Environmental Systems Research Institute (ESRI). The use of particular designations of countries or territories does not imply any judgment by the publisher, the IAEA, as to the legal status of such countries or territories, of their authorities and institutions or of the delimitation of their boundaries. Any revisions or additional geological information known to the user would be welcomed by the International Atomic Energy Agency and the Geological Survey of Canada.

Report

Data release of reprocessed select National Uranium Resources Evaluation program samples in Wyoming

The U.S. Atomic Energy Commission established the National Uranium Resources Evaluation (NURE) program in 1973 to identify uranium resources throughout the United States. Part of this program focused on the collection of stream-sediment samples and subsequent geochemical analyses of these samples for uranium, in addition to 47 other elements. As part of the original program, 18,424 stream-sediment samples were collected from Wyoming and analyzed. All original samples are stored at the U.S. Geological Survey’s (USGS) National Geochemical Sample Archive (NGSA). The Wyoming State Geological Survey (WSGS) recently selected 159 of the original Wyoming NURE stream samples to be reanalyzed using modern and standardized analytical equipment. The raw results of the reanalysis are provided with this report.

Wyoming

Uranium-series dating of carbonate (tufa) deposits associated with quaternary fluctuations of Pyramid Lake, Nevada

Uranium-series dating of dense tufa deposited in a small cave, at former lake margins, and in large tufa mounds clarifies the timing of lake-level variation during the past 400,000 yr in the Pyramid Lake basin. A moderate-sized lake occasionally overflowed the Emerson Pass sill at elevation of ???1207 m between ca. 400,000 and 170,000 and from ca. 60,000 to 20,000 yr B.P., as shown by 230Th/234U ages of the cave samples, 230Th-excess ages of tubular tufas, and average isochron-plot ages of shoreline-deposited tufas. (By comparison, modern Pyramid Lake is ???50 m below this sill). There is a lack of tufa record during the intervening period from ca. 170,000 to 60,000 yr B.P. After ca. 20,000 yr, Pyramid Lake underwent abrupt changes in level and, based on previous 14C ages, reached its highest elevation (ca 1335 m) at ca. 14,000 yr B.P. The youngest uranium-series ages are comparable with previously reported 14C ages. ?? 1996 University of Washington.

Quaternary Research

Ecological aspects of microorganisms inhabiting uranium mill tailings

Numbers and types of microorganisms in uranium mill tailings were determined using culturing techniques. Arthrobacter were found to be the predominant microorganism inhabiting the sandy tailings, whereas Bacillus and fungi predominated in the slime tailings. Sulfate-reducing bacteria, capable of leaching radium, were isolated in low numbers from tailings samples but were isolated in significantly high numbers from topsoil in contact with the tailings. The results are placed in the context of the magnitude of uranium mill tailings in the United States, the hazards posed by the tailings, and how such hazards could be enhanced or diminished by microbial activities. Patterns in the composition of the microbial population are evaluated with respect to the ecological variables that influence microbial growth. ?? 1987 Springer-Verlag New York Inc.

Microbial Ecology

Derivation of soil screening thresholds to protect chisel-toothed kangaroo rat from uranium mine waste in northern Arizona

Chemical data from soil and weathered waste material samples collected from five uranium mines north of the Grand Canyon (three reclaimed, one mined but not reclaimed, and one never mined) were used in a screening-level risk analysis for the Arizona chisel-toothed kangaroo rat ( Dipodomys microps leucotis ); risks from radiation exposure were not evaluated. Dietary toxicity reference values were used to estimate soil-screening thresholds presenting risk to kangaroo rats. Sensitivity analyses indicated that body weight critically affected outcomes of exposed-dose calculations; juvenile kangaroo rats were more sensitive to the inorganic constituent toxicities than adult kangaroo rats. Species-specific soil-screening thresholds were derived for arsenic (137 mg/kg), cadmium (16 mg/kg), copper (1,461 mg/kg), lead (1,143 mg/kg), nickel (771 mg/kg), thallium (1.3 mg/kg), uranium (1,513 mg/kg), and zinc (731 mg/kg) using toxicity reference values that incorporate expected chronic field exposures. Inorganic contaminants in soils within and near the mine areas generally posed minimal risk to kangaroo rats. Most exceedances of soil thresholds were for arsenic and thallium and were associated with weathered mine wastes.

Arizona

Identifying natural and anthropogenic variability of uranium at the well scale, Homestake Superfund site, near Milan, New Mexico, USA

The San Mateo Creek Basin in New Mexico, USA is located within the Grants Mineral Belt-an area with numerous uranium (U) ore deposits, mines, and milling operations. Six monitoring wells set in an alluvial aquifer near the Homestake Mining Co. Superfund site in the lower San Mateo Creek Basin were logged with a suite of borehole geophysical tools including spectral gamma-ray (SGR), vertically profiled with passive samplers for U and selenium (Se) concentrations, and purged sampled for same constituents. The integrated approach allowed for an assessment on the role of heterogeneity (both physical and chemical) in determining U concentrations in groundwater. Uranium, as measured with SGR logging, is ubiquitous in the alluvial aquifer and the underlying Chinle Group. Aqueous U concentrations appear to be inversely related to thorium (Th) concentrations, as measured by the SGR log, indicating the possibility that U is bound in or adsorbed to clays in the aquifer. The stratigraphy of the alluvium likely plays a role in elevated concentrations of aqueous U. Interbedded clay and sand layers allow for the mobilization of U in oxic sandy layers from U adsorbed in sediments in reduced clay layers. The stratigraphy also plays a role in the degree of mixing of groundwater in the formation and well. Mixing can obscure the ability to identify U sources. Mixing is exacerbated by the relatively long screens (> 20 ft long or > 6.1 m) of the monitoring wells.

New Mexico

The distribution and mobility of uranium in glassy and zeolitized tuff, Keg Mountain area, Utah, U.S.A.

The distribution and mobility of uranium in a diagenetically altered, 8 Ma old tuff in the Keg Mountain area, Utah, are modelled in this study. The modelling represents an improvement over similar earlier studies in that it: (1) considers a large number of samples (76) collected with good geologic control and exhibiting a wide range of alteration; (2) includes radiometric data for Th, K and RaeU (radium equivalent uranium) as well as U; (3) considers mineralogic and trace-element data for the same samples; and (4) analyzes the mineral and chemical covariation by multivariate statistical methods. The variation of U in the tuff is controlled mainly by its primary abundance in glass and by the relative abundance of non-uraniferous detritus and uraniferous accessory minerals. Alteration of glass to zeolite, even though extensive, caused no large or systematic change in the bulk concentration of U in the tuff. Some redistribution of U during diagenesis is indicated by association of U with minor alteration products such as opal and hydrous Fe-Mn oxide minerals. Isotopic studies indicate that the zeolitized tuff has been open to migration of U decay products during the last 0.8 Ma. The tuff of Keg Mountain has not lost a statistically detectable fraction of its original U, even though it has a high (??? 9 ppm) trace U content and has been extensively altered to zeolite. Similar studies in a variety of geological environments are required in order to identify the particular combination of conditions most favorable for liberation and migration of U from tuffs. ?? 1980.

Chemical Geology