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Stable isotope (δ 18 O and δ 2 H) data for precipitation, stream water, and groundwater in Puerto Rico

Puerto Rico is located in the northeastern Caribbean Sea (18.2 °N, 66.3 °W), with the Atlantic Ocean on its northern coast. The U.S. Geological Survey’s Water, Energy, and Biogeochemical Budgets (WEBB) program study area in which most of these data were collected comprises the El Yunque National Forest and surrounding area of eastern Puerto Rico. Samples were collected in two forested watersheds, the Rio Mameyes and the Rio Icacos/Rio Blanco, on opposite sides of a ridge in the Luquillo Mountains on the eastern end of the island (fig. 1). Elevation in both watersheds ranges from sea level to approximately 1,000 meters (m). Near sea level, land use is mixed pasture, moist forest, and residential, grading to completely forested within the boundaries of El Yunque National Forest. Forest type changes with elevation from tabonuco to palo colorado to sierra palm to cloud forest above approximately 950 m (Murphy and others, 2012). The Rio Mameyes watershed is oriented north-northeast, and the basin is underlain by volcaniclastic bedrock (basaltic to andesitic volcanic sandstone/mudstone/conglomerate/breccia). The Rio Icacos/Rio Blanco watershed is oriented south-southeast. The Rio Icacos is one of the headwaters of the Rio Blanco and is underlain by quartz diorite. The lower Rio Blanco basin is underlain by andesitic volcaniclastic bedrock. This report also contains a long-term rain isotope dataset from the San Agustin site, in north-central Puerto Rico (fig. 1). Puerto Rico has a tropical climate dominated by easterly trade winds, and seasonal climate patterns affect the hydrology of the study area. The summer wet season is characterized by convective precipitation from tropical easterly waves, troughs, and cyclonic low-pressure systems, including tropical storms and hurricanes; in contrast, the drier winter season is characterized by trade-wind showers and frontal systems. The highest single-event rainfall totals tend to be associated with tropical storms, hurricanes, and cold fronts, although frequent low-intensity orographic showers occur throughout the year in the mountains. The stable isotope signatures of rainfall (δ 2 H and δ 18 O) are broadly correlated with the weather type that produced the rainfall (Scholl and others, 2009; Scholl and Murphy, 2014).

El Yunque National Forest;Luquillo Mountains;Rio B

Trends in chemical concentration in sediment cores from three lakes in New Jersey and one lake on Long Island, New York

Sediment cores were extracted from three lakes in northeastern New Jersey and one lake on western Long Island, New York, as part of the U.S. Geological Survey National Water-Quality Assessment Program. Sediment layers were dated by use of cesium-137 (137Cs), copper, lead, or dichlorodiphenyl-trichloroethane (DDT) profiles. Sediment layers were analyzed for seven selected trace elements, including arsenic, cadmium, chromium, lead, mercury, nickel, and zinc, and five hydrophobic organochlorine compounds, including chlordane, dieldrin, total DDT, total polychlorinated biphenyls (PCBs), and total polycyclic aromatic hydrocarbons (PAHs). All seven trace elements were detected throughout the cores from all four lakes. Concentrations of all elements, except arsenic, were elevated in the three cores from lakes within urbanized watersheds (Packanack Lake, Orange Reservoir, and Newbridge Pond) relative to the concentrations in the lake core collected below the largely forested, reference watershed (Clyde Potts Reservoir). Results of trend analyses indicate that concentrations of all trace elements, with the exception of arsenic and lead, were relatively constant throughout the core from the minimally urbanized Clyde Potts Reservoir. In urban lakes, significant upward trends in concentrations from deeper to shallower sediments were observed either to peak concentrations or throughout the core for all elements, with the exception of chromium at all lakes and arsenic and nickel at Orange Reservoir. This finding indicates that changes in population and land use in the urbanized watersheds over the period of sedimentary record have contributed to upward trends in trace-element concentrations. Although downward trends in concentrations were observed for some trace elements in the years after their concentrations peaked, concentrations of all trace elements in urban lake cores were higher in the most recently deposited sediments than at the base of each respective core. Lead concentrations over time were highly correlated with the population in the vicinity of the lake until the concentration peak in sediment deposited in the mid-1970’s. Concentrations of lead in lake sediment appear to be closely related to the use of leaded gasoline because lead concentrations generally decreased after the use of leaded gasoline was phased-out in the mid-1970’s. Zinc concentrations were highly correlated with population over the entire length of the core. In general, zinc concentrations increased in the three urbanized watersheds, probably in response to increasing population and vehicular use. This trend was not evident at Clyde Potts Reservoir, however, where vehicular traffic in the watershed is minimal. Detectable concentrations of chlordane, total DDT, and total PCBs were present in cores from all lakes; however, dieldrin was detected only in the Newbridge Pond and Packanack Lake cores. Concentrations generally were higher in cores from the urbanized Newbridge Pond and Orange Reservoir watersheds than in those from the minimally urbanized Clyde Potts Reservoir watershed. With the exception of chlordane in the Clyde Potts and Orange Reservoir cores, concentrations of the four organochlorine compounds had significant downward trends from peak concentrations to recently deposited sediment or non-significant trends throughout the core. On the basis of these findings and as a result of regulatory actions prohibiting the production and use of these compounds, downward trends in sedimentary concentrations are expected to continue; however, the persistence of these compounds indicates that a substantial amount of time may be required to purge them from the watersheds. Concentrations of PAHs in sediment generally increased with population growth and urbanization, probably as a result of increased fossil-fuel combustion (gasoline and home-heating fuels and other uses (roads and parking lots paved with asphalt) associated with increased urban development and vehicular traffic. This finding is supported by low concentrations of PAHs in Packanack Lake sediments in the 1930’s, before the watershed was urbanized and when automobiles were comparatively rare. As vehicular use and urbanization increase in these watersheds, the general increase of PAH concentrations in lake sediments can be expected to continue. Data from this study indicate that changes in population, land use, and chemical use in the urbanized watersheds over the period of sedimentary record have contributed to upward trends in concentrations of trace elements and hydrophobic organic compounds. Although downward trends were observed for some constituents in the years after their concentrations peaked, concentrations of most constituents in urban lake cores were higher in the most recently deposited sediments than at the base of each respective core and in the reference lake cores. Similar trends in concentrations of these constituents have been observed in sediment cores from other urban lakes across the United States.

New Jersey, New York

Quality characteristics of ground water in the Ozark aquifer of northwestern Arkansas, southeastern Kansas, southwestern Missouri and northeastern Oklahoma, 2006-07

Because of water quantity and quality concerns within the Ozark aquifer, the State of Kansas in 2004 issued a moratorium on most new appropriations from the aquifer until results were made available from a cooperative study between the U.S. Geological Survey and the Kansas Water Office. The purposes of the study were to develop a regional ground-water flow model and a water-quality assessment of the Ozark aquifer in northwestern Arkansas, southeastern Kansas, southwestern Missouri, and northeastern Oklahoma (study area). In 2006 and 2007, water-quality samples were collected from 40 water-supply wells completed in the Ozark aquifer and spatially distributed throughout the study area. Samples were analyzed for physical properties, dissolved solids and major ions, nutrients, trace elements, and selected isotopes. This report presents the results of the water-quality assessment part of the cooperative study. Water-quality characteristics were evaluated relative to U.S. Environmental Protection Agency drinking-water standards. Secondary Drinking-Water Regulations were exceeded for dissolved solids (11 wells), sulfate and chloride (2 wells each), fluoride (3 wells), iron (4 wells), and manganese (2 wells). Maximum Contaminant Levels were exceeded for turbidity (3 wells) and fluoride (1 well). The Maximum Contaminant Level Goal for lead (0 milligrams per liter) was exceeded in water from 12 wells. Analyses of isotopes in water from wells along two 60-mile long ground-water flow paths indicated that water in the Ozark aquifer was at least 60 years old but the upper age limit is uncertain. The source of recharge water for the wells along the flow paths appeared to be of meteoric origin because of isotopic similarity to the established Global Meteoric Water Line and a global precipitation relation. Additionally, analysis of hydrogen-3 (3H) and carbon-14 (14C) indicated that there was possible leakage of younger ground water into the lower part of the Ozark aquifer. This may be caused by cracks or fissures in the confining unit that separates the upper and lower parts of the aquifer, poorly constructed or abandoned wells, or historic mining activities. Analyses of major ions in water from wells along the flow paths indicated a transition from freshwater in the east to saline water in the west. Generally, ground water along flow paths evolved from a calcium magnesium bicarbonate type to a sodium calcium bicarbonate or a sodium calcium chloride bicarbonate type as water moved from recharge areas in Missouri into Kansas. Much of this evolution occurred within the last 20 to 25 miles of the flow paths along a water-quality transition zone near the Kansas-Missouri State line and west. The water quality of the Kansas part of the Ozark aquifer is degraded compared to the Missouri part. Geophysical and well-bore flow information and depth-dependent water-quality samples were collected from a large-capacity (1,900-2,300 gallons per minute) municipal-supply well to evaluate vertical ground-water flow accretion and variability in water-quality characteristics at different levels. Although the 1,050-foot deep supply well had 500 feet of borehole open to the Ozark aquifer, 77 percent of ground-water flow entering the borehole came from two 20-foot thick rock layers above the 1,000-foot level. For the most part, water-quality characteristics changed little from the deepest sample to the well-head sample, and upwelling of saline water from deeper geologic formations below the well was not evident. However, more saline water may be present below the bottom of the well.

Arkansas, Kansas, Missouri, Oklahoma

Areal geology of the Little Cone quadrangle, Colorado

The Little Cone quadrangle includes an area of about 59 square miles in eastern San Miguel County in southwestern Colorado. It lies within and adjacent to the northeastern boundary of the Colorado Plateau physiographic province. The precipitous front of the San Juan Mountains lies a few miles to the east and northeast, and an outlier of the San Juans, the San Miguel Mountains, lies about a mile to the south. The quadrangle contains features characteristic of both the plateaus and the mountains, and has been affected by geologic events and processes of two different geologic environments.

Colorado

Preliminary geologic map of the Hemet 7.5' quadrangle, Riverside County, California

The Hemet 7.5' quadrangle is located near the eastern edge of the Perris block of the Peninsular Ranges batholith. The northeastern corner of the quadrangle extends across the San Jacinto Fault Zone onto the edge of the San Jacinto Mountains block. The Perris block is a relatively stable area located between the Elsinore Fault Zone on the west and the San Jacinto Fault Zone on the east. Both of the fault zones are active; the San Jacinto being the seismically most active in southern California. The fault zone is obscured by very young alluvial deposits. The concealed location of the San Jacinto Fault Zone shown on this quadrangle is after Sharp, 1967. The geology of the quadrangle is dominated by Cretaceous tonalite formerly included in the Coahuila Valley pluton of Sharp (1967). The northern part of Sharp's Coahuila Valley pluton is separated out as the Hemet pluton. Tonalite of the Hemet pluton is more heterogeneous than the tonalite of the Coahuila Valley pluton and has a different sturctural pattern. The Coahuila Valley pluton consists of relatively homogeneous hornblende-biotite tonalite, commonly with readily visible large euhedral honey-colored sphene crystals. Only the tip of the adjacent Tucalota Valley pluton, another large tonalite pluton, extends into the quadrangle. Tonalite of the Tucalota Valley pluton is very similar to the tonalite of the Coahuila Valley pluton except it generally lacks readily visible sphene. In the western part of the quadrangle a variety of amphibolite grade metasedimentary rocks are informally referred to as the rocks of Menifee Valley; named for exposures around Menifee Valley west of the Hemet quadrangle. In the southwestern corner of the quadrangle a mixture of schist and gneiss marks a suture that separated low metamorphic grade metasedimentary rocks to the west from high metamorphic grade rocks to the east. The age of these rocks is interpreted to be Triassic and the age of the suturing is about 100 Ma, essentially the same age as the adjacent Coahuila Valley pluton. Rocks within the suture zone consist of a mixture of lithologies from both sides of the suture. Gneiss, schist, and anatectic gneiss are the predominate lithologies within the rocks on the east side of the suture. Lesser amounts of metalithic greywacke and lenticular masses of black amphibolite are subordinate rock types. Biotite, biotite-sillimanite and lesser amounts of garnet-biotite-sillimanite schist and metaquartzite-metalithic greywacke lithologies occur west of the suture. Pleistocene continental beds, termed the Bautista beds occur east of the San Jacinto Fault Zone in the northeast corner of the quadrangle. Most of the Bautista beds were derived from the San Jacinto pluton that is located just to the east of the sedimentary rocks. Along the northern part of the quadrangle is the southern part of a large Holocene-late Pleistocene fan emanating from Baustista Canyon. Sediments in the Bautista fan are characterized by their content of detritus derived from amphibolite grade metasedimentary rocks located in the Bautista Canyon drainage. Between the Holocene-late Pleistocene Bautista fan and the Santa Rosa Hills is the remnant of a much older Bautista Canyon alluvial fan. A pronounced Holocene-late Pleistocene channel was developed along the south fringe of the very old alluvial fan and the Santa Rosa Hill. A now dissected late to middle Pleistocene alluvial complex was produced by the coalesced fans of Goodhart, St. Johns, and Avery canyons, and Cactus Valley. Pleistocene continental beds, termed the Bautista beds occur east of the San Jacinto Fault Zone in the northeast corner of the quadrangle. Most of the Bautista beds were derived from the San Jacinto pluton that is located just to the east of the sedimentary rocks. Along the northern part of the quadrangle is the southern part of a large Holocene-late Pleistocene fan emanating from Baustista Canyon.

California

Geologic Characterization of Young Alluvial Basin-Fill Deposits from Drill Hole Data in Yucca Flat, Nye County, Nevada

Yucca Flat is a topographic and structural basin in the northeastern part of the Nevada Test Site (NTS) in Nye County, Nevada, that has been the site of numerous underground nuclear tests; many of these tests occurred within the young alluvial basin-fill deposits. The migration of radionuclides to the Paleozoic carbonate aquifer involves passage through this thick, heterogeneous section of Tertiary and Quaternary rock. An understanding of the lateral and vertical changes in the material properties of young alluvial basin-fill deposits will aid in the further development of the hydrogeologic framework and the delineation of hydrostratigraphic units and hydraulic properties required for simulating ground-water flow in the Yucca Flat area. This report by the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, presents data and interpretation regarding the three-dimensional variability of the shallow alluvial aquifers in areas of testing at Yucca Flat, data that are potentially useful in the understanding of the subsurface flow system. This report includes a summary and interpretation of alluvial basin-fill stratigraphy in the Yucca Flat area based on drill hole data from 285 selected drill holes. Spatial variations in lithology and grain size of the Neogene basin-fill sediments can be established when data from numerous drill holes are considered together. Lithologic variations are related to different depositional environments within the basin including alluvial fan, channel, basin axis, and playa deposits.

Open-File Report

Lidar-revised geologic map of the Uncas 7.5' quadrangle, Clallam and Jefferson Counties, Washington

In 2000 and 2001, the Puget Sound Lidar Consortium obtained 1 pulse/m 2 lidar data for about 65 percent of the Uncas 7.5' quadrangle. For a brief description of LIDAR (LIght Detection And Ranging) and this data acquisition program, see Haugerud and others (2003). This map combines geologic interpretation (mostly by Haugerud and Tabor) of the 6-ft (2-m) lidar-derived digital elevation model (DEM) with the geology depicted on the Preliminary Geologic Map of the Uncas 7.5' Quadrangle, Clallam and Jefferson Counties, Washington, by Peter J. Haeussler and others (1999). The Uncas quadrangle in the northeastern Olympic Peninsula covers the transition from the accreted terranes of the Olympic Mountains on the west to the Tertiary and Quaternary basin fills of the Puget Lowland to the east. Elevations in the map area range from sea level at Port Discovery to 4,116 ft (1,255 m) on the flank of the Olympic Mountains to the southwest. Previous geologic mapping within and marginal to the Uncas quadrangle includes reports by Cady and others (1972), Brown and others (1960), Tabor and Cady (1978a), Yount and Gower (1991), and Yount and others (1993). Paleontologic and stratigraphic investigations by University of Washington graduate students (Allison, 1959; Thoms, 1959; Sherman, 1960; Hamlin, 1962; Spencer, 1984) also encompass parts of the Uncas quadrangle. Haeussler and Wells mapped in February 1998, following preliminary mapping by Yount and Gower in 1976 and 1979. The description of surficial map units follows Yount and others (1993) and Booth and Waldron (2004). Bedrock map units are modified from Yount and Gower (1991) and Spencer (1984). We used the geologic time scale of Gradstein and others (2005). The Uncas quadrangle lies in the forearc of the Cascadia subduction zone, about 6.25 mi (10 km) east of the Cascadia accretionary complex exposed in the core of the Olympic Mountains (Tabor and Cady, 1978b). Underthrusting of the accretionary complex beneath the forearc uplifted and tilted eastward the Coast Range basalt basement and overlying marginal basin strata, which comprise most of the rocks of the Uncas quadrangle. The Eocene submarine and subaerial tholeiitic basalt of the Crescent Formation on the Olympic Peninsula is thought to be the exposed mafic basement of the Coast Range, which was considered by Snavely and others (1968) to be an oceanic terrane accreted to the margin in Eocene time. In this interpretation, the Coast Range basalt terrane may have originated as an oceanic plateau or by oblique marginal rifting, but its subsequent emplacement history was complex (Wells and others, 1984). Babcock and others (1992) and Haeussler and others (2003) favor the interpretation that the basalts were the product of an oceanic spreading center interacting with the continental margin. Regardless of their origin, onlapping strata in southern Oregon indicate that the Coast Range basalts were attached to North America by 50 Ma; but on southern Vancouver Island, where the terrane-bounding Leech River Fault is exposed, Brandon and Vance (1992) concluded that suturing to North America occurred in the broad interval between 42 and 24 Ma. After emplacement of the Coast Range basalt terrane, the Cascadia accretionary wedge developed by frontal accretion and underplating (Tabor and Cady, 1978b; Clowes and others, 1987). Domal uplift of the part of the accretionary complex beneath the Olympic Mountains occurred after ~18 Ma (Brandon and others, 1998). Continental and alpine glaciation during Quaternary time reshaped the uplifted rocks of the Olympic Mountains.

Washington

Distribution and abundance of gold in stream sediments and moraine debris, McCarthy quadrangle, Alaska

A geochemical survey was conducted in the McCarthy quadrangle Alaska, to identify areas containing anomalous concentrations of various metallic and nonmetallic elements. This study incorporates the results of analyses for gold from 764 stream sediment and glacial moraine debris samples collected in the quadrangle, and analyzed by the U.S. Geological Survey between 1961 and 1976 using atomic absorption spectrophotometry. No analytical results for gold are available for stream sediment samples from the White River area, located in the northeastern part of the quadrangle. The accompanying map shows the distribution and relative abundance of gold in stream sediment and glacial moraine debris samples. Geochemical analyses have been grouped and are represented by symbols on a base map, which includes topography and generalized geology. The range of analytical values and the symbol that represents it are shown on the histogram. Graphical representation of analytical values on the map permits easy observation of any large variation resulting from separate or duplicate samples collected at the same or nearby localites.

Alaska

Geologic Characterization of Young Alluvial Basin-Fill Deposits from Drill-Hole Data in Yucca Flat, Nye County, Nevada

Yucca Flat is a topographic and structural basin in the northeastern part of the Nevada Test Site in Nye County, Nevada, that has been the site of numerous underground nuclear tests; many of these tests occurred within the young alluvial basin-fill deposits. The migration of radionuclides to the Paleozoic carbonate aquifer involves passage through this thick, heterogeneous section of Tertiary and Quaternary rock. An understanding of the lateral and vertical changes in the material properties of young alluvial basin-fill deposits will aid in the further development of the hydrogeologic framework and the delineation of hydrostratigraphic units and hydraulic properties required for simulating ground-water flow in the Yucca Flat area. This report by the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, presents data and interpretation regarding the three-dimensional variability of the shallow alluvial aquifers in areas of testing at Yucca Flat, data that are potentially useful in the understanding of the subsurface flow system. This report includes a summary and interpretation of alluvial basin-fill stratigraphy in the Yucca Flat area based on drill-hole data from 285 selected drill holes. Spatial variations in lithology and grain size of the Neogene basin-fill sediments can be established when data from numerous drill holes are considered together. Lithologic variations are related to different depositional environments within the basin such as alluvial fan, channel, basin axis, and playa deposits.

Scientific Investigations Report

Geology and ground-water resources of the upper Grande Ronde River basin, Union County, Oregon

The upper Grande Ronde River basin is a 1,400-square-mile area in northeastern Oregon, between the Blue Mountains to the west and the Wallowa Mountains to the east. The area is drained by the Grande Ronde River, which flows northeast through this region and is tributary to the Snake River. The climate is generally moderate; temperature extremes recorded at La Grande are 22°F. below zero and 108°F. above. The average annual precipitation ranges from 13 to 20 inches in the Grande Ronde Valley to . more than 35 inches in the mountain highlands surrounding the valley. The topography of. the area is strongly controlled by the geologic structures, principally those related to block faulting. The terrain ranges from the nearly flat floors of the Grande Ronde and Indian Valleys, whose elevations are 2,600 to about 2,750 feet, to the mountainous uplands, whose average elevations are about 5,000 feet and which have local prominences exceeding 6,500 feet. The rocks in the upper Grande Ronde River basin, from oldest to youngest, are metamorphic rocks of pre-Tertiary age; igneous masses of diorite and granodiorite that intruded the metamorphic rocks; tuff-breccia, welded and silicified tuff, and andesite and dacite flows, of Tertiary age; the Columbia River basalt of Miocene and possibly early Pliocene age; fanglomerate and lacustrine deposits of Pliocene and Pleistocene age; and younger deposits . of alluvium, colluvium, and welded tuff. In the graben known as the Grande Ronde Valley, which is the principal populated district in the area, the valley fill deposits are as thick as 2,000 feet. The valley is bordered by the scarps of faults, the largest of which have displacements of more than 4.000 feet. Most of the wells in the area obtain small to moderate supplies of water from unconfined aquifers in the val1ey fill and alluvial fan deposits. Moderate to large quantities of water are obtained from aquifers carrying artesian water in the fan alluvium and the Columbia River basalt. The available supplies of ground water greatly exceed the relatively small amounts that are being used, and the natural supplies are ..adequate for foreseeable domestic, industrial, irrigation, and municipal. requirements. Yields of future wells probably could be improved appreciably over those of present wells by exercising close attention to subsurface conditions during construction, and by greater use of well screens, gravel envelopes, and well development techniques. The chemical quality of the ground water in general is excellent. All waters sampled are potable and are within the desired ranges of hardness and salinity for most public, industrial, and irrigation uses. The average temperature of shallow ground water drawn from, the alluvial fill was 3°F. above the mean annual air temperature. That of water obtained from the basalt is 6°F. above the temperatures computed from the 'normal' gradient of 1.8°F. per 100 feet of increased depth.

Oregon

Ground-water records for southeastern Oklahoma : Part 1, records of wells, test-holes, and springs

The U. S. Geological Survey has collected data on Oklahoma's ground-water resources since 1934. Most of these data were collected as part of specific ground-water studies conducted in cooperation with various Federal, State, and local agencies. Although a large amount of ground-water data have been published, they are scattered through a variety of reports and are not readily available on a regional basis. Furthermore, a considerable amount of data have never been published and can be obtained only from the files of the Geological Survey. The purpose of this report is to make available both published and unpublished records for approximately 1,780 wells, test-holes, and springs in 16 counties in northeastern Oklahoma. In addition, selected references to pertinent ground-water reports covering parts of the 16-county area are included for those requiring more specific information. The stratigraphic nomenclature and age determinations used in the report are those accepted by the Oklahoma Geological Survey and do not necessarily agree with those of the U.S. Geological Survey. Acknowledgment is extended to the many hundreds of individuals who have provided the data compiled in this report.

Open-File Report

Regional controls on geomorphology, hydrology, and ecosystem integrity in the Orinoco Delta, Venezuela

Interacting river discharge, tidal oscillation, and tropical rainfall across the 22,000 km2 Orinoco delta plain support diverse fresh and brackish water ecosystems. To develop environmental baseline information for this largely unpopulated region, we evaluate major coastal plain, shallow marine, and river systems of northeastern South America, which serves to identify principal sources and controls of water and sediment flow into, through, and out of the Orinoco Delta. The regional analysis includes a summary of the geology, hydrodynamics, sediment dynamics, and geomorphic characteristics of the Orinoco drainage basin, river, and delta system. Because the Amazon River is a major source of sediment deposited along the Orinoco coast, we summarize Amazon water and sediment input to the northeastern South American littoral zone. We investigate sediment dynamics and geomorphology of the Guiana coast, where marine processes and Holocene history are similar to the Orinoco coast. Major factors controlling Orinoco Delta water and sediment dynamics include the pronounced annual flood discharge; the uneven distribution of water and sediment discharge across the delta plain; discharge of large volumes of water with low sediment concentrations through the Rio Grande and Araguao distributaries; water and sediment dynamics associated with the Guayana littoral current along the northeastern South American coast; inflow of large volumes of Amazon sediment to the Orinoco coast; development of a fresh water plume seaward of Boca Grande; disruption of the Guayana Current by Trinidad, Boca de Serpientes, and Gulf of Paria; and the constriction at Boca de Serpientes. ?? 2002 Elsevier Science B.V. All rights reserved.

Geomorphology

Potentiometric surface of the Cockfield aquifer in southeastern Arkansas and the Wilcox aquifers in southern and northeastern Arkansas, October 1996-July 1997

The Cockfield and Wilcox aquifers are secondary sources of water for local use in southern and northeastern Arkansas, where in 1995 more than 51 million gallons per day of water was withdrawn. During October 1996 to July 1997, water levels in the Cockfield and Wilcox aquifers were measured in 104 wells in Arkansas. The potentiometric surface data reveal spatial trends in both aquifers across the study areas. The regional direction of ground-water flow of the Cockfield aquifer is generally southeastward, away from the outcrop area, except where affected by intense ground-water withdrawals. The potentiometric surface indicates that heavy pumpage has altered or reversed the natural direction of flow in some areas. Flow in these areas is toward centers of pumping within cones of depression. A cone of depression caused by the pumpage near Greenville, Mississippi, extends into Chicot, Desha, and Drew Counties. This cone of depression has altered flow patternArkansas. Long-term hydrographs of six wells, during the period 1971-1996, showed water levels declined at an average rate between 0.5 and 1.0 foot per year at these locations. The regional direction of ground-water flow in the Wilcox aquifers is generally toward the east and south, away from the outcrop except where water levels are affected by intense ground-water withdrawals. The potentiometric surface indicates that heavy pumpage has altered or reversed the natural direction of ground-water flow in some areas. Flow in these areas is toward centers of pumping within cones of depression. Two cones of depression are centered in the vicinity of Paragould and West Memphis, Arkansas, where ground-water withdrawals have altered the natural direction of flow. Long-term hydrographs of seven wells, during the period 1971- 1996, show water-level declines in the Wilcox aquifer in northeastern Arkansas generally were between 0.5 and 1.0 foot per year but were more than 1.0 foot per year in two wells. The U.S. Geological Survey in cooperation with the Arkansas Soil and Water Conservation Commission and the Arkansas Geological Commission has monitored water levels in the Cockfield and Wilcox aquifers since the 1960's. During October 1996 to July 1997, 53 water-level measurements were made in wells completed in the Cockfield aquifer, 13 water-level measurements were made in wells completed in the Wilcox aquifer in southern Arkansas, and 38 water-level measurements were made in wells com- pleted in the Wilcox aquifer in northeastern Arkansas. The purpose of these measurements was to provide information to describe the recent potentiometric surfaces and long-term water-level trends in the Cockfield and Wilcox aquifers. This report presents the results as potentiometric surface maps and as long-term water-level hydrographs.

Arkansas

A dryland river transformed—the Little Colorado, 1936–2010

The Little Colorado River, in northeastern Arizona, is a major tributary of the Colorado River. Over a span of 74 years, the U.S. Geological Survey (USGS) has mapped substantial migration of the river channel between the City of Winslow and the Navajo Nation community of Leupp (Tólchíí kooh). In a human lifetime, the river has moved more than 1 mile across its valley floor. Channel migration and flooding pose a considerable risk to the life and property of people living near the river. USGS scientists are working to better understand the potential for further channel adjustments and flooding to help provide communities at risk with the information they need to address these threats and make future development decisions.

Arizona

Geologic datasets for weights of evidence analysis in Northeast Washington: 4. mineral industry activity in Washington, 1985-1997

This report includes a table of 339 sites representing mineral activities for mining and mineral exploration in the State of Washington from 1985 through 1997. The table was primarily compiled from annual reports in Washington Geologic Newsletter and Washington Geology. The information was compiled for use in a weights-of-evidence analysis of mineral resources in northeastern Washington.

Washington

Geologic datasets for weights of evidence analysis in Northeast Washington: 4. mineral industry activity in Washington, 1985-1997

This report includes a table of 339 sites representing mineral activities for mining and mineral exploration in the State of Washington from 1985 through 1997. The table was primarily compiled from annual reports in Washington Geologic Newsletter and Washington Geology. The information was compiled for use in a weights-of-evidence analysis of mineral resources in northeastern Washington.

Washington

Pesticide concentrations in wetlands on the Lake Traverse Reservation, South and North Dakota, July 2006

During July 2006, water samples were collected from selected Lake Traverse wetlands within the historic Reservation boundary in northeastern South Dakota and southeastern North Dakota as part of a reconnaissance-level assessment by the U.S. Geological Survey (USGS) and Sisseton-Wahpeton Oyate (SWO) Sioux Tribe. Eighteen wetlands were sampled by the SWO and USGS personnel after primary pesticide application occurred on the Lake Traverse Reservation. Samples were analyzed for 61 pesticide compounds. In addition, the samples were analyzed for physical properties that might help further characterize the water quality of the wetlands. During July 2006, water samples were collected from 18 wetlands and were analyzed for 61 widely used pesticide compounds. Pesticides were detected in 17 of the 18 sampled wetlands. In the 17 wetlands in which pesticides weredetected, the number of pesticides detected ranged from two to eight. Of the 61 pesticides for which the samples were analyzed, 51 pesticides were not detected in any of the wetland samples. Ten pesticides were detected in water samples from at least one of the wetlands at small concentrations. Atrazine and de-ethyl atrazine were detected in samples from 17 of the 18 wetlands. The minimum, maximum, and median concentrations of dissolved atrazine detected were 0.007, 0.12, and 0.064 microgram per liter (?g/L), respectively. Two pesticides (picloram and simazine) were detected in only one wetland each. None of the pesticide concentrations exceeded any U.S. Environmental Protection Agency Maximum Contaminant Levels for drinking water, and concentrations were much less than levels considered toxic for humans or aquatic species.

North Dakota, South Dakota

Characteristics of Fault Zones in Volcanic Rocks Near Yucca Flat, Nevada Test Site, Nevada

During 2005 and 2006, the USGS conducted geological studies of fault zones at surface outcrops at the Nevada Test Site. The objectives of these studies were to characterize fault geometry, identify the presence of fault splays, and understand the width and internal architecture of fault zones. Geologic investigations were conducted at surface exposures in upland areas adjacent to Yucca Flat, a basin in the northeastern part of the Nevada Test Site; these data serve as control points for the interpretation of the subsurface data collected at Yucca Flat by other USGS scientists. Fault zones in volcanic rocks near Yucca Flat differ in character and width as a result of differences in the degree of welding and alteration of the protolith, and amount of fault offset. Fault-related damage zones tend to scale with fault offset; damage zones associated with large-offset faults (>100 m) are many tens of meters wide, whereas damage zones associated with smaller-offset faults are generally a only a meter or two wide. Zeolitically-altered tuff develops moderate-sized damage zones whereas vitric nonwelded, bedded and airfall tuff have very minor damage zones, often consisting of the fault zone itself as a deformation band, with minor fault effect to the surrounding rock mass. These differences in fault geometry and fault zone architecture in surface analog sites can serve as a guide toward interpretation of high-resolution subsurface geophysical results from Yucca Flat.

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