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Geochemical interpretations of groundwater flow systems

Interest in the geochemistry of groundwater is increasing owing to the great number of current projects involving underground liquid waste storage, artificial recharge of potable water, accidental contamination of groundwater bodies, sanitary landfills, and pollution monitoring. Geochemical techniques used to facilitate the understanding of a groundwater system range from extremely simple to those requiring sophisticated theories, equipment, and procedures. An interpretation of the simple trilinear diagram for samples collected from the Yucatan Peninsula of Mexico provided evidence that the fresh-water body was only a few tens of meters thick and was underlain everywhere by an extensive body of salt water. A geochemical technique that has been used effectively to identify the source of salt water in coastal aquifers is measurement of the carbon-14 concentrations. Carbon-14 has been used in a regional carbonate aquifer to determine the velocity of groundwater movement, rates of chemical reactions, and distribution of hydraulic conductivity. The application of principles of irreversible thermodynamics to groundwater systems provides a basis for constructing models which permit prediction, over both time and space, of changes in head distribution and chemical character of the water resulting from imposed stresses on the system. In essence, proper application of irreversible thermodynamics combines the potential theory of Hubbert with principles of reversible chemical thermodynamics, such as solution of carbonate minerals, to describe and explain controlling chemical reactions and processes of groundwater systems.

Florida, South Carolina

Geology of the Yucca Mountain site area, southwestern Nevada

Yucca Mountain in southwestern Nevada is a prominent, irregularly shaped upland formed by a thick apron of Miocene pyroclastic-flow and fallout tephra deposits, with minor lava flows, that was segmented by through-going, large-displacement normal faults into a series of north-trending, eastwardly tilted structural blocks. The principal volcanic-rock units are the Tiva Canyon and Topopah Spring Tuffs of the Paintbrush Group, which consist of volumetrically large eruptive sequences derived from compositionally distinct magma bodies in the nearby southwestern Nevada volcanic field, and are classic examples of a magmatic zonation characterized by an upper crystal-rich (>10% crystal fragments) member, a more voluminous lower crystal-poor (<5% crystal fragments) member, and an intervening thin transition zone. Rocks within the crystal-poor member of the Topopah Spring Tuff, lying some 280 m below the crest of Yucca Mountain, constitute the proposed host rock to be excavated for the storage of high-level radioactive wastes. Separation of the tuffaceous rock formations into subunits that allow for detailed mapping and structural interpretations is based on macroscopic features, most importantly the relative abundance of lithophysae and the degree of welding. The latter feature, varying from nonwelded through partly and moderately welded to densely welded, exerts a strong control on matrix porosities and other rock properties that provide essential criteria for distinguishing hydrogeologic and thermal mechanical units, which are of major interest in evaluating the suitability of Yucca Mountain to host a safe and permanent geologic repository for waste storage. A thick and varied sequence of surficial deposits mantle large parts of the Yucca Mountain site area. Mapping of these deposits and associated soils in exposures and in the walls of trenches excavated across buried faults provides evidence for multiple surface-rupturing events along all of the major faults during Pleistocene and Holocene times; these paleoseismic studies form the basis for evaluating the potential for future earthquakes and fault displacements. Thermoluminescence and U-series analyses were used to date the surficial materials involved in the Quaternary faulting events. The rate of erosional downcutting of bedrock on the ridge crests and hillslopes of Yucca Mountain, being of particular concern with respect to the potential for breaching of the proposed underground storage facility, was studied by using rock varnish cation-ratio and 10 Be and 36 Cl cosmogenic dating methods to determine the length of time bedrock outcrops and hillslope boulder deposits were exposed to cosmic rays, which then served as a basis for calculating long-term erosion rates. The results indicate rates ranging from 0.04 to 0.27 cm/k.y., which represent the maximum downcutting along the summit of Yucca Mountain under all climatic conditions that existed there during most of Quaternary time. Associated studies include the stratigraphy of surficial deposits in Fortymile Wash, the major drainage course in the area, which record a complex history of four to five cut-and-fill cycles within the channel during middle to late Quaternary time. The last 2-4 m of incision probably occurred during the last pluvial climatic period, 22-18 ka, followed by aggradation to the present time. Major faults at Yucca Mountain-from east to west, the Paintbrush Canyon, Bow Ridge, Stagecoach Road, Solitario Canyon, Fatigue Wash, Windy Wash, and Northern and Southern Crater Flat Faults-trend predominantly north, are spaced 1-5 km apart, have bedrock displacements ranging from 125 m to as much as 500 m, and exhibit Quaternary movements of several centimeters to a few meters. Displacements are predominantly down to the west, and bedrock/alluvium contacts commonly are marked by fault-line scarps. The predominant northerly fault trend changes to a more northeasterly trend in adjacent areas south

Nevada

Predicting methane emissions and developing reduction strategies for a Central Appalachian Basin, USA, longwall mine through analysis and modeling of geology and degasification system performance

Coal mine methane is a safety concern in active mines due to explosion risk and an environmental concern due to the greenhouse gas (GHG) properties of methane emissions to the atmosphere. Depending on the mine design and operation, structural and stratigraphic characteristics of the geology, and the properties of coal beds affected by mining, a significant amount of methane can be released during coal extraction. These emissions may be low and uniform, but they also can be high and abrupt, if not captured by using pre- and post-mining methods of degasification or not controlled by ventilation during mining. Therefore, emissions should be monitored and predicted accurately for underground safety and GHG reduction. Ventilation and degasification systems should be designed accordingly by taking into account the mine geological properties and the degasification system's performance. This paper presents a comprehensive study to predict emissions and proposes alternatives to reduce emissions in a longwall mine extracting metallurgical coal from the Pocahontas No. 3 coal bed in Virginia (Central Appalachian Basin), USA. The work focused on mining activity in four adjacent panels through analysis and modeling of geology and evaluation of the performance of the methane control system. Results showed that the mine geology contained a significant amount of gas within and around the panel areas, which was controlled by utilizing different degasification methods besides ventilation during mining. The study showed that after pre-mining degasification using fractured vertical wells and in-seam horizontal wells, each panel potentially contained ∼19 MMscf and ∼ 2 MMscf of gas remaining to be handled by the gob gas ventholes (GGVs) and the ventilation, respectively, per acre of mining. It was shown that extending the pre-mining degasification duration of vertical wells by as much as 4 years or drilling more horizontal wells with closer spacing could significantly reduce ventilation and gob emissions during the mining of coal.

Kentucky, Virginia, West Virginia

City-scale geothermal energy everywhere to support renewable resilience – A transcontinental cooperation

Cities have important and varying incentives to transform their energy sector to all-electric with low carbon emissions. However, they often encounter a number of impediments when attempting to implement such a change. For example, while urban areas have the highest energy demand-density, cities often lack the space for installing additional energy generation and/or long-duration energy storage systems. Cities also have existing environmental issues from energy sources (e.g., pollution from dust, waste heat or noise) that make residents sensitive to energy infrastructure development. Utilizing power from conventional sources, such as natural gas, biomass and hydropower, which usually are distanced from the urban areas, also make cities more vulnerable to supply disruptions. One promising de-carbonizing energy option for cities focuses on their heating and cooling needs, which constitutes around 1/3 of U.S. and 1/2 of European energy consumption (including industrial processes like drying, pasteurization, etc.; Jadun and others, 2017; EU Commission 2022). If heating and cooling loads can be met by geothermal direct-use technologies, then the need for new electric sources can be greatly lessened. Despite the proven efficacy of geothermal energy as a city/community-scale heating and cooling resource, it is currently only a niche resource in the heating and cooling sector, though has significant potential for future growth. Historically, emphasis has been placed on geothermal electricity generation potential that requires higher temperature (greater than 90 °C) resources at drillable depths, but potentially viable areas are geographically limited and typically well removed from urban centers. Key drivers for investments were represented by greater political interest in renewable electricity production, higher revenues and less effort in distributing the produced energy via grids. In contrast, low-temperature (less than 90 °C) geothermal resources can be used directly for heating and cooling almost everywhere and are cost-effective in urban/suburban settings. In addition, the increased prominence of renewable electricity sources, such as wind and solar onto city-scale electric grids, has led to new urgency around questions of energy storage. Underground thermal energy storage (UTES), wherein surplus or waste heat is stored underground for later use, could present a long-duration energy storage solution. From October 2022 through September 2024, a transcontinental consortium consisting of geological surveys, geoscience organizations, industry representatives and universities aims to develop an understanding of the global potential for city-scale geothermal, proposing guidelines to aid in promoting the economic utilization of low temperature geothermal resources. Efforts will focus on providing city managers and other decision makers with the information needed to evaluate and implement suitable city/community-scale geothermal technologies. Funded by the U.S. Geological Survey’s John Wesley Powell Center for Analysis and Synthesis, this interdisciplinary consortium will showcase tools, datasets, and scientific recommendations to accelerate the broader understanding and adoption of renewable energy systems that access geothermal resources. The collaborative research activities include standardization of nomenclatures, resource description and characterization strategies globally. The results from these activities will be combined with a preliminary climate-driven, city-based energy needs related analysis to perform energy supply/demand matching analysis. The identification of city-specific applications that would benefit from the geothermal technologies provides the basis to up-scale city-specific determinations to regional and national assessments of resource estimates. The city-scale geothermal energy research initiative will ultimately provide the synergies and management analysis that can address benefits, environmental impacts, regulatory frameworks, sustainability, and suitability in retrofitted buildings or new as well as existing heating networks.

Conference Paper

An alternative hypothesis for sink development above salt cavities in the Detroit area

Subsidence and sink formation resulting from brining operations in the Windsor-Detroit area include the 1954 sink at the Canadian Salt Company brine field near Windsor, Ontario, and the 1971 sinks at the BASF Wyandotte Corporation brine field at Grosse Ile, Mich. Earlier investigations into both occurrences concluded that the mechanism of sink development consisted of the gradual stoping of poorly supported brine-gallery roof rock to the near surface with subsequent surface collapse. A more recent study attempted to describe the mechanism of sink development in terms of the geometry of a cylindrical chimney formed by stoping of roof rock, the height of a cavity at depth, the depth of overlying rock, and the bulking ratio of the rubble formed during stoping. Persons with extensive experience in solution mining in the Windsor-Detroit area have expressed doubt that the stoping mechanism could fully explain the development of these sinks. Further, they have proposed that the relatively shallow (300-ft-deep) Sylvania Sandstone, in this case, may be responsible for the sinks by a secondary undermining mechanism to be examined in this paper. The mechanism involves downwarping of the beds overlying the salt cavity and development of a shallower cavity in the Sylvania Sandstone by downward migration of cohesionless sand grains from the Sylvania through openings in the disturbed rock to the lower cavity. This study indicates that under natural conditions the Sylvania will not migrate, even in the presence of large underground water flows because the sandstone possesses some cohesion throughout its depth. However, further investigation has formulated a mechanism that could allow the Sylvania Sandstone to loose its cohesion in response to high horizontal stresses. These stresses could be the result of deformation that accompanies general subsidence and (or) of past geologic processes. Included in this study were experimental and analytical investigations. As determined by uniaxial and triaxial testing, the Sylvania Sandstone in the Detroit area has been shown to have low compressive strength. In addition, it exhibits an explosive type failure whereby over 50 percent of the sample is reduced to loose granular sand. As a result of these characteristics, the Sylvania Sandstone can loose its cohesion when subjected to high horizontal stresses. Efforts at mechanically modeling the Sylvania were made to account for the measurements and observations. Linear arch theory was used for an elastic analysis. Linear arch theory predicts two modes of failure: (1) arch crushing, a compressive failure of the upper portion of the arch due to compressive stresses exceeding the compressive strength of the material, and (2) arch collapse, a sagging of the beds due to compressive strains which reduce the arch line to a length less than the original arch length. The arch crushing mode of failure would then yield the loose granular sand as observed in laboratory testing. Arch collapse would simply result in bed sagging without granulation of the sandstone. Arch collapse is favored by thin-bedded material while arch crushing is favored by thick-bedded material. Arch crushing seems to be a likely mode of failure for the Windsor-Detroit sinks. It is believed that after a crushing failure the sand-water slurry (specific gravity 1.2) which exceeds the density of the cavity brine will migrate downward through cracks and open joints eventually reaching the practically limitless open spaces of the rubble column and salt cavity. As the extent of the cavity within the Sylvania increases in depth and width because of sand migration, a critical span will be reached where the immediately overlying upper Sylvania and the overlying Detroit River Dolomite will fail. The collapse will allow a path for the approximately 100 ft of clay to collapse, resulting in a sink as the surface manifestation.

Open-File Report

Using DC resistivity ring array surveys to resolve conductive structures around tunnels or mine-workings

In underground environments, conventional direct current (DC) resistivity surveys with a single linear array of electrodes produce fundamentally non-unique inversions. These non-uniqueness and model resolution issues stem from limitations placed on the location of transmitters (TXs) and receivers (RXs) by the geometry of existing tunnels and boreholes. Poor excitation and/or sampling of the region of interest (ROI) can create artifacts and reduce the resolution of the recovered model. To address these problems we propose the use of an ensemble of ring arrays, which are created by placing one or more electrodes in each face (sidewalls, floor, and ceiling) of the tunnel to form a ring of electrodes at each along-tunnel location. Using a series of increasingly complex synthetic models, we assess the benefits of ring arrays and show that they can be used to better constrain the location and shape of anomalous bodies around the tunnel. Although ring arrays significantly improve the resolution of the recovered model, the size of the comprehensive ring array survey increases rapidly with the number of electrodes used. To balance model resolution and survey size, we developed a physics-based survey design methodology. In this methodology, TXs are selected based upon secondary charge accumulations on a test block that is moved throughout the ROI. Although this survey design methodology does not produce a strictly optimal survey, it balances model resolution and survey size in a practical and computationally efficient manner. Since the ring array more accurately estimates the around-tunnel location of targets and ensures that targets on all sides of the tunnel are detected, it is ideally suited to tunnel-based environments. Our results show that only about 6 % "> 6% of the possible TXs and 0.5 % "> 0.5% of the RXs in the comprehensive ring array survey are needed to retain the improvements in resolution. Therefore, economical ring array surveys can be designed for both reconnaissance and target characterization. Following the inversion of the reconnaissance dataset, additional rings can be added to reduce the inter-ring spacing or off-tunnel boreholes can be added to the region around identified anomalies to increase resolution as required.

Journal of Applied Geophysics

Results of Hydraulic Tests in Miocene Tuffaceous Rocks at the C-Hole Complex, 1995 to 1997, Yucca Mountain, Nye County, Nevada

Four hydraulic tests were conducted by the U.S. Geological Survey at the C-hole complex at Yucca Mountain, Nevada, between May 1995 and November 1997. These tests were conducted as part of ongoing investigations to determine the hydrologic and geologic suitability of Yucca Mountain as a potential site for permanent underground storage of high-level nuclear waste. The C-hole complex consists of three 900-meter-deep boreholes that are 30.4 to 76.6 meters apart. The C-holes are completed in fractured, variably welded tuffaceous rocks of Miocene age. Six hydrogeologic intervals occur within the saturated zone in these boreholes - the Calico Hills, Prow Pass, Upper Bullfrog, Lower Bullfrog, Upper Tram, and Lower Tram intervals. The Lower Bullfrog and Upper Tram intervals contributed about 90 percent of the flow during hydraulic tests. The four hydraulic tests conducted from 1995 to 1997 lasted 4 to 553 days. Discharge from the pumping well, UE-25 c #3, ranged from 8.49 to 22.5 liters per second in different tests. Two to seven observation wells, 30 to 3,526 meters from the pumping well, were used in different tests. Observation wells included UE-25 c #1, UE-25 c #2, UE-25 ONC-1, USW H-4, UE-25 WT #14, and UE-25 WT #3 in the tuffaceous rocks and UE-25 p #1 in Paleozoic carbonate rocks. In all hydraulic tests, drawdown in the pumping well was rapid and large (2.9-11 meters). Attributable mostly to frictional head loss and borehole-skin effects, this drawdown could not be used to analyze hydraulic properties. Drawdown and recovery in intervals of UE-25 c #1 and UE-25 c #2 and in other observation wells typically was less than 51 centimeters. These data were analyzed. Hydrogeologic intervals in the C-holes have layered heterogeneity related to faults and fracture zones. Transmissivity, hydraulic conductivity, and storativity generally increase downhole. Transmissivity ranges from 4 to 1,600 meters squared per day; hydraulic conductivity ranges from 0.1 to 50 meters per day; and storativity ranges from 0.00002 to 0.002. Transmissivity in the Miocene tuffaceous rocks decreases from 2,600 to 700 meters squared per day northwesterly across the 21-square-kilometer area affected by hydraulic tests at the C-hole complex. The average transmissivity of the tuffaceous rocks in this area, as determined from plots of drawdown in most or all observation wells as functions of time or distance from the pumping well, is 2,100 to 2,600 meters squared per day. Average storativity determined from these plot ranges is 0.0005 to 0.002. Hydraulic conductivity ranges from less than 2 to more than 10 meters per day; it is largest where prominent northerly trending faults are closely spaced or intersected by northwesterly trending faults. During hydraulic tests, the Miocene tuffaceous rocks functioned as a single aquifer. Drawdown occurred in all monitored intervals of the C-holes and other observation wells, regardless of the hydrogeologic interval being pumped. This hydraulic connection across geologic and lithostratigraphic contacts is believed to result from interconnected faults, fractures, and intervals with large matrix permeability. Samples of UE-25 c #3 water, analyzed from 1995 to 1997, seem to indicate that changes in the quality of the water pumped from that well are probably due solely to lateral variations in water quality within the tuffaceous rocks.

Water-Resources Investigations Report

Modified GIC estimation using 3-D Earth conductivity

Geomagnetically induced currents (GICs) are quasi-direct current (DC) electric currents that flow in technological conductors during geomagnetic storms. Extreme GICs are hazardous to man-made infrastructure. GICs enter and exit the technological systems, such as the electric power grid, at grounding points, and their magnitudes depend on the currents that flow underground. They are, therefore, a function of the Earth's electrical conductivity, represented at ground level as Earth impedances, as well as the resistance parameters of the power network. Traditional GIC estimation practices are based on Earth impedances obtained from laterally homogeneous or piecewise layered-Earth models. We refer to these methods, collectively, as the 1-D approximation. However, GIC hazard mitigation can be improved with more accurate GIC modeling that takes the spatially heterogeneous Earth's conductivity into account. Here, we propose a modified approximation for GIC estimation that is very similar to the 1-D approximation but is instead derived from empirical 3-D Earth impedances. Our formulation sets up the computation of static, frequency-dependent power line telluric response functions, which, once computed, may be considered part of the power grid system model. These response functions may then be used for historical scenario analysis of GIC hazards and for simplified real-time, albeit approximate, GIC estimation in a power grid. This modest modification to the simpler local field formulation approach avoids real-time integration of geoelectric fields along power lines while taking the realistic 3-D Earth into account in a rigorous manner. Once implemented, the method provides a power grid operator with the benefits of convenience and computational speed for a first look real-time operational GIC hazard assessment. We estimate that the proposed modified 3-D GIC modeling approach produces GIC values that are well within 50% of those obtained with the full-scale power line integration of spatially variable geoelectric fields, for storms comparable in scale to the 2003 Halloween storm, all geological structures, and power lines located in the contiguous United States and other low- to middle-latitude regions.

Space Weather

Geologic map of the Yucca Mountain region, Nye County, Nevada

Yucca Mountain, Nye County, Nev., has been identified as a potential site for underground storage of high-level radioactive waste. This geologic map compilation, including all of Yucca Mountain and Crater Flat, most of the Calico Hills, western Jackass Flats, Little Skull Mountain, the Striped Hills, the Skeleton Hills, and the northeastern Amargosa Desert, portrays the geologic framework for a saturated-zone hydrologic flow model of the Yucca Mountain site. Key geologic features shown on the geologic map and accompanying cross sections include: (1) exposures of Proterozoic through Devonian strata inferred to have been deformed by regional thrust faulting and folding, in the Skeleton Hills, Striped Hills, and Amargosa Desert near Big Dune; (2) folded and thrust-faulted Devonian and Mississippian strata, unconformably overlain by Miocene tuffs and lavas and cut by complex Neogene fault patterns, in the Calico Hills; (3) the Claim Canyon caldera, a segment of which is exposed north of Yucca Mountain and Crater Flat; (4) thick densely welded to nonwelded ash-flow sheets of the Miocene southwest Nevada volcanic field exposed in normal-fault-bounded blocks at Yucca Mountain; (5) upper Tertiary and Quaternary basaltic cinder cones and lava flows in Crater Flat and at southernmost Yucca Mountain; and (6) broad basins covered by Quaternary and upper Tertiary surficial deposits in Jackass Flats, Crater Flat, and the northeastern Amargosa Desert, beneath which Neogene normal and strike-slip faults are inferred to be present on the basis of geophysical data and geologic map patterns. A regional thrust belt of late Paleozoic or Mesozoic age affected all pre-Tertiary rocks in the region; main thrust faults, not exposed in the map area, are interpreted to underlie the map area in an arcuate pattern, striking north, northeast, and east. The predominant vergence of thrust faults exposed elsewhere in the region, including the Belted Range and Specter Range thrusts, was to the east, southeast, and south. The vertical to overturned strata of the Striped Hills are hypothesized to result from successive stacking of three south-vergent thrust ramps, the lowest of which is the Specter Range thrust. The CP thrust is interpreted as a north-vergent backthrust that may have been roughly contemporaneous with the Belted Range and Specter Range thrusts. The southwest Nevada volcanic field consists predominantly of a series of silicic tuffs and lava flows ranging in age from 15 to 8 Ma. The map area is in the southwestern quadrant of the southwest Nevada volcanic field, just south of the Timber Mountain caldera complex. The Claim Canyon caldera, exposed in the northern part of the map area, contains thick deposits of the 12.7-Ma Tiva Canyon Tuff, along with widespread megabreccia deposits of similar age, and subordinate thick exposures of other 12.8- to 12.7-Ma Paintbrush Group rocks. An irregular, blocky fault array, which affects parts of the caldera and much of the nearby area, includes several large-displacement, steeply dipping faults that strike radially to the caldera and bound south-dipping blocks of volcanic rock. South and southeast of the Claim Canyon caldera, in the area that includes Yucca Mountain, the Neogene fault pattern is dominated by closely spaced, north-northwest- to north-northeast-striking normal faults that lie within a north-trending graben. This 20- to 25-km-wide graben includes Crater Flat, Yucca Mountain, and Fortymile Wash, and is bounded on the east by the 'gravity fault' and on the west by the Bare Mountain fault. Both of these faults separate Proterozoic and Paleozoic sedimentary rocks in their footwalls from Miocene volcanic rocks in their hanging walls. Stratigraphic and structural relations at Yucca Mountain demonstrate that block-bounding faults were active before and during eruption of the 12.8- to 12.7-Ma Paintbrush Group, and significant motion on these faults continued unt

IMAP

Water resources inventory of Connecticut Part 3: lower Thames and southeastern coastal river basins

The lower Thames and southeastern coastal river basins have a relatively abundant supply of water of generally good quality which is derived from streams entering the area and precipitation that has fallen on the area. Annual precipitation has ranged from about 32 inches to 65 inches and has averaged about 48 inches over a 30-year period. Approximately 22 inches of water are returned to the atmosphere each year by evaporation and transpiration; the remainder of the annual precipitation either flows overland to streams or percolates downward to the water table and ultimately flows out of the report area through estuaries and coastal streams or as underflow through the deposits beneath. During the autumn and winter months precipitation normally is sufficient to cause a substantial increase in the amount of water stored underground and in surface reservoirs within the report area, whereas in the summer most of the precipitation is lost through evaporation and transpiration, resulting in sharply reduced stream-flow and lowered ground-water levels. The mean monthly storage of water on an average is about 3.8 inches higher in November than it is in June. The amount of water that flows through and out of the report area represents the total amount of water potentially available for use by man. For the 30-year period 1931 through 1960, the annual runoff from the report area has averaged nearly 26 inches (200 billion gallons), from the entire Thames River basin above Norwich about 24 inches (530 billion gallons), and from the Pawcatuck River basin about 26 inches (130 billion gallons). A total average annual runoff of 860 billion gallons is therefore available. Although runoff indicates the total amount of water potentially available, it is usually not economically feasible for man to use all of it. On the other hand, with increased development, it is possible that some water will be reused several times. The water available may be tapped as it flows through the area or is temporarily stored in streams, lakes, and aquifers. The amounts that can be developed vary from place to place and time to time, depending on the amount of precipitation, on the size of drainage area, on the thickness, permeability, and areal extent of aquifers, and on the variations in chemical and physical quality of the water. Differences in streamflow from point to point are due primarily to differences in the proportion of stratified drift in the drainage basin above each point, which affect the timing of streamflow, and to differences in precipitation, which affect the amount of streamflow. Ground water can be obtained from wells almost anywhere in the area, but the amount obtainable at any particular point depends upon the type and water-bearing properties of the aquifers. For practical purposes, the earth materials in the report area comprise three aquifers--stratified drift, bedrock, and till. Stratified drift is the only aquifer generally capable of yielding more than 100 gpm (gallons per minute) to individual wells. It covers about 20 percent of the area and occurs chiefly in lowlands where it overlies till and bedrock. The coefficient of permeability of the coarse-grained unit of stratified drift averages about 1,500 gbd (gallons per day) per sq ft. Drilled, screened wells tapping this unit are known to yield from 4 to 88o gpm and average 146 gpm. Dug wells in coarse-grained stratified drift supply about 2 gpm per foot of drawdown over a period of a few hours. Fine-grained stratified drift has an average coefficient of permeability of about 300 gpd per sq ft and can usually yield supplies sufficient for household use to dug wells. Bedrock and till are widespread in extent but generally provide only small water supplies. Bedrock is tapped chiefly by drilled wells, about 90 percent of which will supply at least 3 gpm. Very few, however, will supply more than 50 gpm. Till is tapped in a few places by dug wells which can yield small supplies of only a few hundred gpd throughout all or most of the year. The coefficient of permeability of till ranges from about 0.2 gpd per sq ft to 120 gpd per sq ft. The amount of ground water potentially available in the report area depends upon the amount of ground-water outflow, the amount of ground water in storage, and the quantity of water available by induced infiltration from streams and lakes. From data on permeability, saturated thickness, recharge, yield from aquifer storage, well performance, and streamflow, preliminary estimates of ground-water availability can be made for any point in the report area. Long-term yields estimated for 18 areas of stratified drift especially favorable for development of large ground-water supplies ranged from 1.3 to 66 mgd. Detailed site studies to determine optimum yields, drawdowns, and spacing of individual wells are needed before major ground-water development is undertaken in these or other areas. The chemical quality of water in the report area is generally good to excellent. Samples of naturally occurring surface water collected at 24 sites contained less than 151 ppm (parts per million) of dissolved solids and less than 63 ppm of hardness. Water from wells is more highly mineralized than naturally occurring water from streams. Even so only 12 percent of the wells sampled yielded water with more than 200 ppm of dissolved solids and only 8 percent yielded water with more than 120 ppm of hardness. Even in major streams, which are used to transport industrial waste, hardness rarely exceeds 60 ppm and the dissolved mineral content is generally less than 200 ppm. At a few places in the town of Montville however, waters may contain dissolved mineral concentrations of 2,000 to 4,000 ppm. Iron and manganese in both ground water and surface water are the only constituents whose concentrations commonly exceed recommended limits for domestic and industrial use. Most wells in the report area yield clear water with little or no iron or manganese, but distributed among them are wells yielding ground water that contains enough of these dissolved constituents to be troublesome for most uses. Iron concentrations in naturally occurring stream water exceed 0.3 ppm under low-flow conditions at 33 percent of the sites sampled. Large concentrations of iron in stream water result from discharge of iron-bearing water from aquifers or from swamps where it is released largely from decaying vegetation. Ground water more than 30 feet below the land surface has a relatively constant temperature, usually between 48°F and 52°F. Water temperature in very shallow wells may fluctuate from about 38°F in February or March to about 55°F in late summer. Water temperature in the larger streams fluctuates much more widely, ranging from 32°F at least for brief periods in winter, to about 85°F occasionally during summer. The quality of suspended sediment transported by streams in the area is negligible. Turbidity in streams is generally not a problem although amounts large enough to be troublesome may occur locally at times. The total amount of water used in the report area for all purposes during 1964 was about 118,260 million gallons, of which 105,600 million gallons was estuarine water used for cooling by industry. The average per capita water use, excluding estuarine, temporary summer residence, and institutional water was equivalent to 186 gpd. Public water systems supplied the domestic needs of nearly tw0-thirds the population of the report area. All of the 19 systems, which were sampled, provided water of better quality than the U.S. Public Health Service suggests for drinking water standards.

Connecticut

Water resources inventory of Connecticut Part 2: Shetucket River Basin

The Shetucket River basin has a relatively abundant supply of water of generally good quality which is derived from precipitation that has fallen on the basin. Annual precipitation has ranged from about 30 inches to 75 inches and has averaged about 45 inches over a 35-year period. Approximately 20 inches of water are returned to the atmosphere each year by evaporation and transpiration; the remainder of the annual precipitation either flows overland to streams or percolates downward to the water table and ultimately flows out of the basin in the Shetucket River or as underflow through the deposits beneath. During the autumn and winter months precipitation normally is sufficient to cause a substantial increase in the amount of water stored underground and in surface reservoirs within the basins whereas in the summer most of the precipitation is lost through evaporation and transpiration, resulting in sharply reduced streamflow and lowered groundwater levels. The mean monthly storage of water in the basin on an average is 3.5 inches higher in November than it is in June. The amount of water that flows out of the basin in the Shetucket River represents the total amount of water potentlally available for use by man. Annual runoff from the entire basin above the Quinebaug River has ranged from about 13 to 42 inches since 1929, and has averaged about 23 inches (300 billion gallons). Although runoff indicates the total amount of water potentially available, it is usually not economically or legally feasible for man to use all of it. On the other hand, with increased development, It is possible that some water will be reused several times. The water available may be tapped as it flows through the area or is temporarily stored in streams, lakes, and aquifers. The amounts that can be developed vary from place to place and time to time, depending on the amount of precipitation, on the size of drainage area, on the thickness, permeability and areal extent of aquifers, and on the variations in chemical and physical quality of the water. Differences in streamflow from point to point are due primarily to differences in the proportion of stratified drift in the drainage basin above each point, which affect the timing of streamflow, and to differences in precipitation, which affect the amount of streamflow. Information on streamflow from gaging stations may be extended to ungaged sites by accounting for both of these factors ,in calculations. Future floods on the upper Willimantic River or the Shetucket River are unlikely to cause major damage so long as buildings are not constructed below the highest flood elevations to be expected with the present system of reservoirs for flood control. Ground water can be obtained from wells almost anywhere in the Shetucket River basin, but the amount obtainable from individual wells at any particular point depends upon the type and water-bearing properties of the aquifers present. For practical purposes, the earth materials in the basin comprise three aquifers--stratified drift, till, and bedrock, Stratified drift is the only aquifer generally capable of yielding more than 100 gpm to individual wells. This aquifer covers about 18 percent of the basin and occurs chiefly In lowlands where it overlies till or bedrock. Coefficient of permeability of the coarse-grained unit of stratified drift averages about 1,900 gpd per sq ft. Drilled, screened wells tapping this unit, are known to yield from 200 to 675 gpm. Dug wells in coarse-grained stratified drift should supply at least 2 gpm per foot of drawdown over an 8-hour period. Fine-grained stratified drift has an average coefficient of permeability of about 400 gpd per sq ft and can usually yield to dug wells supplies sufficient for household use. Till and bedrock are widespread in extent but can provide only small to moderate water supplies. Till is tapped chiefly by dug wells; permanent supplies of more than 200 gpd can be obtained from dug wells at a majority of sites in areas of till, but there are many sites where the till is too impermeable or too thin to provide this much water throughout the year. The coefficient of permeability of till ranges from about 0.2 gpd per sq ft to 55 gpd per sq it. Bedrock Is tapped chiefly by drilled wells, about 90 percent of which will supply at least 3 gpm. Very few, however, will supply more than 50 gpm. The amount of ground water potentially available In an area depends upon the amount of groundwater outflow, the amount of ground water in storage, and the quantity of water available by Induced infiltration from streams and lakes. From data on permeability, saturated thickness, recharge, yield from aquifer storage, well performance, and streamflow, preliminary estimates of ground-water availability can be made for any point in the basin. Long-term yields estimated for 15 areas especially favorable for development of large ground-water supplies ranged from 1.3 to 61.8 mgd. Detailed site studies to determine optimum yields, drawdowns, and spacing of individual wells are needed before major ground-water development is undertaken In these or other areas. The chemical quality of water in the Shetucket basin Is generally good to excellent. Samples of naturally occurring surface water collected from 32 sites contained less than 61 ppm of dissolved solids and less than 32 ppm of hardness. Water from wells is more highly mineralized than naturally occurring water from streams. Even so only 7 percent of wells sampled yielded water with more than 200 ppm of dissolved sol-ids and only 9 percent yielded water with more than 120 ppm of hardness. Even in the major rivers, which are used to transport industrial waste, the dissolved mineral content is less than 100 ppm and hardness rarely exceeds 40 ppm. One notable exception occurs in the lower reaches of Little River where an exceptional amount of industrial waste is discharged into the river near Versailles. This waste is particularly noticeable during low streamflow. Iron and manganese In both ground water and surface water are the only constituents whose concentrations commonly exceed recommended limits for domestic and industrial use. Most wells in the basin yield clear water with little or no iron or manganese, but distributed among them are wells with ground water that contains enough of these dissolved constituents to be troublesome for most uses. iron concentrations in naturally occurring stream water exceeded 0.3 ppm under tow-flow conditions at 20 percent of the sites sampled. Large concentrations of iron in stream water result from discharge of iron-bearing ground water or from the discharge of water from swamps. In swamps the iron is released largely from decaying vegetation. Ground water more than 30 feet below the land surface has a relatively constant temperature, usually between 48°F and 50°F. Water temperature in very shallow wells may fluctuate from about 38°F in February or March to about 55°F in late summer. Water temperature in the larger streams fluctuates much more widely, ranging from 32°F at least for brief periods in winter, to about 85°F occasionally during The quantity of suspended sediment transported by streams in the basin is negligible, though amounts large enough to be troublesome may occur locally at times. The total amount of water used In the Shetucket Rlver basin for all purposes during 1961 was about 5,810 million gallons~ which is equivalent to 208 gpd per person, Public water systems supplied the domestic needs of nearly half the population of the basin; 10 systems were sampled, all of which provided water of better quality than the U.S. Public Health Service suggests for drinking water standards.

Connecticut

Fate and pathways of injection-well effluent in the Florida Keys

Twenty-four wells (21 locations) were core drilled into the limestone beneath the Keys, reef tract, and outer reefs to determine if sewage effluents injected in Class V wells onshore are reaching offshore reef areas via underground flow. These wells were fitted with PVC casings and well screens and were sampled every three months for a period of one year. Analyses showed consistent hypersalinity in most wells and a marked increase in nitrogen (as ammonia) in offshore ground water. Other forms of nitrogen (NO 2 and NO 3 ) and phosphorous were not particularly elevated in offshore ground water but were above the levels found in surface marine water. The highest levels of nitrogen (NO 2 and NO 3 ) and phosphorous were in shallow onshore ground waters. Sources for the nutrients in the shallow onshore ground water consist of septic tanks and cesspools (@ 24,000 and 5,000 in the Florida Keys, respectively), agricultural fertilizers, and natural vegetation. Ammonia concentrations were low in shallow ground waters beneath the Florida Keys, probably because of oxidizing conditions. Tidal pumping is particularly active, especially nearshore. Hydraulic heads sufficient to elevate well water as much as 7 cm above sea level during falling tides were detected in all nearshore wells. During rising tides, the situation was reversed and water flowed into the wells. Tidal pumping implies considerable water movement both in and out of the upper few meters of limestone. Tidal pumping is a likely mechanism for mixing and transferring nutrient-rich ground water into the overlying marine waters. Although tidal pumping should cause rather complete mixing and dilution of any freshwater-based effluents entering the limestone via the more than 600 disposal wells in the Florida Keys, the ground waters in the 30- to 40-ft-depth range (9-12 m) nevertheless remained slightly hypersaline relative to sea water throughout the year. Fecal coliform and fecal streptococcal bacteria were associated with three Lower Keys offshore wells and two shallow onshore wells at Key Largo. On occasions, these bacteria were detected farther offshore, once in a well 4 miles off Key Largo. The bacterial analyses for Key Largo (both onshore and offshore) are supported by two independent bacteriological researchers using more sophisticated methods than the standard 100-ml membrane-filter method used in this study. Fecal bacteria can serve as tracers; thus, we conclude their presence is possible evidence for offshore transport of ground waters originating on Key Largo. Elevated nutrients (ammonia) and slightly elevated dissolved total phosphorous in offshore ground waters, however, cannot be tied to onshore sources with existing data. Rock analyses of material from our cores do not prove or disprove the hypothesis that limestone beneath the Keys or reef tract is serving as a sink for phosphorus or other nutrients. The data, however, do not rule out phosphorus uptake by limestone adjacent to disposal sources. For the purposes of this study, monitoring wells were not positioned sufficiently close to injection wells to determine if uptake of phosphorous is taking place. Ground waters were found to contain more dissolved solids than could be accounted for if hypersalinity resulted from simple evaporation of sea water. These data indicate that ground waters in the vicinity of our wells are dissolving solids from the rock rather than precipitating material within the rock framework; however, as mentioned above, our wells were not positioned sufficiently close to disposal wells to determine if localized uptake is occurring. Examination of rock cores from these wells revealed a general distribution of reef- and grainstone-facies belts. The Upper and Middle Keys are composed of a thin coral reef facies that extends only a few hundred feet seaward of the Keys. Reef facies give way to mudstone facies within a few yards of shore on the Florida Bay side of the Keys. On the seaward side of the Keys, beneath Hawk Channel and White Bank, the Pleistocene limestone is a mixed grainstone, packstone, and wackstone facies. Corals are rare or absent. The Pleistocene limestone beneath the outer reefs 4 to 5 miles offshore, however, consists of reef facies with the same coral fauna as that found on Key Largo. This pattern of two major reef-facies belts separated by a 2- to 4-mile-wide belt of grainstone facies may have as yet undetermined effects on groundwater circulation beneath the Florida reef tract. Grainstone is approximately an order of magnitude less permeable than the coralline Key Largo Limestone facies. The Q3 surface, a major subsurface unconformity thought to form an effective confining zone elsewhere in south Florida, was not detected in wells drilled more than 1 mile from shore. This unconformity, however, was detected in all wells drilled on or near the Keys. What was found to be a more effective and widespread confining layer is the Holocene sediment deposited on the Pleistocene limestone during the past 6,000 to 7,000 years. These relatively impermeable sediments are extensive, forming a belt up to 5 miles wide beginning about 0.5 mile offshore. Holocene sediments generally consist of low-permeability lime mud just above the Pleistocene surface, overlain by more permeable carbonate sands and reefs. Leakage of ground water by tidal pumping is not likely to occur through lime-mud-dominated areas such as Hawk Channel but is likely to occur through isolated porous and permeable Holocene reefs situated on Pleistocene limestone highs, and in places where Holocene sediment does not cover the limestone bedrock. Leakage is therefore limited to 1) a shallow-water 0.5-mile-wide nearshore belt of exposed Key Largo Limestone, 2) Holocene patch reefs, which grow on mud-free topographic rock highs, and 3) along the seaward side of the outermost reef in 35 to 65 ft (10-20 m) of water, where Holocene reef and sediment accumulations are thin or absent. This study did not address direct measurements of lateral groundwater movement or a hydrologic mechanism for transporting hypersaline ground water away from the Florida Keys. More recent work, however (Halley et al., 1994), shows that sea level in Florida Bay is higher than on the Atlantic side of the Keys more than 50% of the time. Higher sea level on the bay side of the Keys provides a potential for groundwater flow toward the Atlantic most of the time. Use of tracers (dyes or harmless bacteriological tracers) injected into the center of tightly spaced clusters of monitoring wells is a simple way to ascertain the net direction and rate of groundwater movement. Knowing the direction and rate of groundwater movement is needed for prediction and modeling efforts in the future

Florida