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Geologic map of the Kings Mountain and Grover quadrangles, Cleveland and Gaston Counties, North Carolina, and Cherokee and York Counties, South Carolina

This geologic map of the Kings Mountain and Grover 7.5-minute quadrangles, N.C.-S.C., straddles a regional geological boundary between the Inner Piedmont and Carolina terranes. The Kings Mountain sequence (informal name) on the western flank of the Carolina terrane in this area includes the Neoproterozoic Battleground and Blacksburg Formations. The Battleground Formation has a lower part consisting of metavolcanic rocks and interlayered schist, and an upper part consisting of quartz-sericite phyllite and schist interlayered with quartz-pebble metaconglomerate, aluminous quartzite, micaceous quartzite, manganiferous rock, and metavolcanic rocks. The Blacksburg Formation consists of phyllitic metasiltstone interlayered with thinner units of marble, laminated micaceous quartzite, hornblende gneiss, and amphibolite. Layered metamorphic rocks of the Inner Piedmont terrane include muscovite-biotite gneiss, muscovite schist, and amphibolite. The Kings Mountain sequence has been intruded by metatonalite and metatrondhjemite (Neoproterozoic), metadiorite and metagabbro (Paleozoic), and High Shoals Granite (Pennsylvanian). Layered metamorphic rocks of the Inner Piedmont in this area have been intruded by Toluca Granite (Ordovician?), Cherryville Granite and associated pegmatite (Mississippian), and spodumene pegmatite (Mississippian). Diabase dikes (early Jurassic) are locally present throughout the area. Ductile fault zones of regional scale include the Kings Mountain and Kings Creek shear zones. In this area, the Kings Mountain shear zone forms the boundary between the Inner Piedmont and Carolina terranes, and the Kings Creek shear zone separates the Battleground Formation from the Blacksburg Formation. Structural styles change across the Kings Mountain shear zone from steeply-dipping layers, foliations, and folds on the southeast to gently- and moderately-dipping layers, foliations, and recumbent folds on the northwest. Mineral assemblages in the Kings Mountain sequence show a westward decrease from upper amphibolite facies (sillimanite zone) near the High Shoals Granite on the east side of the map to greenschist (epidote-amphibolite) facies in the south-central part of the area near the Kings Mountain shear zone. Amphibolite-facies mineral assemblages in the Inner Piedmont terrane increase in grade from the kyanite zone near the Kings Mountain shear zone to the sillimanite zone in the northwest part of the map. Surficial deposits include alluvium in the stream valleys and colluvium along ridges and steep slopes. These quadrangles are unusual in their richness and variety of mineral deposits, which include spodumene (lithium), cassiterite (tin), mica, feldspar, silica, clay, marble, kyanite and sillimanite, barite, manganese, sand and gravel, gold, pyrite, and iron. (Abstract from pamphlet.)

Open-File Report

Geologic Map of the Kings Mountain and Grover Quadrangles, Cleveland and Gaston Counties, North Carolina, and Cherokee and York Counties, South Carolina

This geologic map of the Kings Mountain and Grover 7.5-min quadrangles, N.C.-S.C., straddles a regional geological boundary between the Inner Piedmont and Carolina terranes. The Kings Mountain sequence (informal name) on the western flank of the Carolina terrane in this area includes the Neoproterozoic Battleground and Blacksburg Formations. The Battleground Formation has a lower part consisting of metavolcanic rocks and interlayered schist and an upper part consisting of quartz-sericite phyllite and schist interlayered with quartz-pebble metaconglomerate, aluminous quartzite, micaceous quartzite, manganiferous rock, and metavolcanic rocks. The Blacks-burg Formation consists of phyllitic metasiltstone interlayered with thinner units of marble, laminated micaceous quartzite, hornblende gneiss, and amphibolite. Layered metamorphic rocks of the Inner Piedmont terrane include muscovite-biotite gneiss, muscovite schist, and amphibolite. The Kings Mountain sequence has been intruded by metatonalite and metatrondhjemite (Neoproterozoic), metagabbro and metadiorite (Paleozoic?), and the High Shoals Granite (Pennsylvanian). Layered metamorphic rocks of the Inner Piedmont in this area have been intruded by the Toluca Granite (Ordovician?), the Cherryville Granite and associated pegmatite (Mississippian), and spodumene pegmatite (Mississippian). Diabase dikes (early Jurassic) are locally present throughout the area. Ductile fault zones of regional scale include the Kings Mountain and Kings Creek shear zones. In this area, the Kings Mountain shear zone forms the boundary between the Inner Piedmont and Carolina terranes, and the Kings Creek shear zone separates the Battleground Formation from the Blacksburg Formation. Structural styles change across the Kings Mountain shear zone from steeply dipping layers, foliations, and folds on the southeast to gently and moderately dipping layers, foliations, and recumbent folds on the northwest. Mineral assemblages in the Kings Mountain sequence show a westward decrease from upper amphibolite facies (sillimanite zone) near the High Shoals Granite in the eastern side of the map area to upper greenschist (epidote-amphibolite) facies in the south-central part of the area near the Kings Mountain shear zone. Amphibolite-facies mineral assemblages in the Inner Piedmont terrane increase in grade from the kyanite zone near the Kings Mountain shear zone to the sillimanite zone in the northwestern part of the map area. Surficial deposits include alluvium in the stream valleys and colluvium along ridges and steep slopes. These quadrangles are unusual in the richness and variety of the mineral deposits that they contain, which include spodumene (lithium), cassiterite (tin), mica, feldspar, silica, clay, marble, kyanite and sillimanite, barite, manganese, sand and gravel, gold, pyrite, and iron.

Scientific Investigations Map

Distribution and demography of Southwestern Willow Flycatchers in San Diego County, 2015–19

We surveyed for Southwestern Willow Flycatchers ( Empidonax traillii extimus ; flycatcher) at 33 locations along multiple drainages in San Diego County, including portions of Agua Hedionda Creek, Cottonwood Creek, Escondido Creek, Los Penasquitos Creek, Otay River, San Diego River, San Dieguito River, San Luis Rey River, Sweetwater River, and Tijuana River. Resident flycatchers were only found on two drainages in San Diego County, at San Dieguito and San Luis Rey Rivers, with 99 percent occurring on the San Luis Rey River. Resident flycatchers were detected at 18 percent of survey locations (Bonsall, Cleveland National Forest, Rey River Ranch, San Dieguito, and Vista Irrigation District [VID], and VID Lake Henshaw). Resident flycatchers were documented for the first time at Lake Henshaw, the only new location surveyed that supported flycatchers. We detected a minimum of 80 resident flycatchers from 2015 to 2019, most of these were upstream and downstream from Lake Henshaw. Transient flycatchers were found at 42 percent of survey locations; 38 transient individuals were detected at Agua Hedionda Creek, Otay River, San Diego River, San Dieguito River, and the San Luis Rey River. Over the course of this study, 11 locations historically occupied by resident flycatchers were resurveyed; only 5 were found to have resident flycatchers: (1) Bonsall, (2) Cleveland National Forest, (3) Rey River Ranch, (4) San Dieguito, and (5) Vista Irrigation District. The number of resident flycatchers declined from previous high counts at all five locations. Collectively, the number of resident flycatcher territories within the historically occupied area of the upper San Luis Rey River downstream from Lake Henshaw (Cleveland National Forest, Rey River Ranch, and Vista Irrigation District) declined 71 percent between 1999 (48) and 2019 (14); 42 percent of the decline occurred between 1999 and 2016, with an additional decline (50 percent) occurring between 2016 and 2019. In 2016, the distribution of flycatcher territories at the historically occupied area of the upper San Luis Rey River changed relative to the distribution in 1999: the proportion of territories at Cleveland National Forest and Rey River Ranch decreased to 36 percent each, while Vista Irrigation District increased to 29 percent, creating a more equal distribution of territories across the historically occupied area. By 2019, the distribution changed relative to 2016, with most of the territories spread equally between Cleveland National Forest and Rey River Ranch (43 percent each), while the proportion of territories at Vista Irrigation District declined to 14 percent. During countywide surveys, we documented the dispersal of two natal banded flycatchers; both were females that were originally banded as nestlings at Marine Corps Base Camp Pendleton and were seen for the first time as breeding adults. One of the females dispersed to San Dieguito, a distance of 41 kilometers, and a second female dispersed to Cleveland National Forest, a distance of 55 kilometers. We also documented the within-season movement of a uniquely banded male that was seen at the beginning of the 2017 breeding season at Bonsall and was later documented at San Dieguito, a movement distance of 31 kilometers. We completed nest monitoring activities along the upper San Luis Rey River near Lake Henshaw in Santa Ysabel, California from 2016 to 2019. Monitoring occurred at three locations: (1) Cleveland National Forest, (2) Rey River Ranch, and (3) Vista Irrigation District, collectively the upper San Luis Rey River monitoring area. The number of flycatcher territories monitored each year ranged from 14 to 27. We observed polygynous pairings (one male paired with multiple females) in all years, with the lowest rate of polygyny (number of polygynous pairs/total number of pairs) observed in 2016 (10 percent) and the highest in 2017 (70 percent). The proportion of paired males that were polygynous ranged from 5 to 54 percent between 2016 and 2019. We monitored the nesting activity of 14–27 pairs annually during the course of the study. Most of the first nesting attempts were initiated during late May and early June. We monitored 18–41 Southwestern Willow Flycatcher nests per year from 2016 to 2019. Apparent nest success ranged from 11 to 37 percent and differed significantly by year, with higher success in 2016 and 2017 compared to 2018 and 2019. Predation was the presumed to be the primary source of nest failure, with 63–84 percent of failures annually attributed to predation. Although none of the failures were attributed to Brown-headed cowbird ( Molothrus ater ) parasitism, 4–27 percent of nests were parasitized annually from 2016 to 2019, with increased parasitism rates observed in 2018 and 2019 compared to 2016 and 2017. We “rescued” 11 parasitized nests between 2016 and 2019 by removing cowbird eggs; if those nests had been allowed to fail, apparent nest success would have been up to 45 percent lower annually. Flycatcher egg clutch size ranged from 2.8±0.8 to 3.1±0.8 annually and did not vary significantly between years. The number of fledglings per pair ranged from 0.5±1.0 to 1.6±1.5 annually from 2016 to 2019. There was a significant difference in the number of young fledged per pair between years, with pairs in 2016 producing more than three times the number of fledglings compared to 2019. The percent of pairs fledging at least one young ranged from 18 to 62 percent annually but did not vary significantly by year. Analysis of flycatcher daily nest survival rates suggested that both early and late winter precipitation influenced nest survival, with increases in early winter precipitation positively influencing nest survival and later winter precipitation negatively influencing nest survival. The second-best supported model included year, with the lowest daily nest survival occurring in 2018 and 2019. A total of 119 flycatchers were newly banded over the course of this study; 36 adult flycatchers were banded with a unique color combination, and 83 nestlings (57 of which survived to fledging) were banded with a single band on the left or right leg. In addition, two adults that were banded before 2015 were observed in the monitoring area. Between 2015 and 2019, we accumulated 94 resights of 49 individual color-banded adult flycatchers that ranged in age from 1 to 8 years old. Banding allowed us to examine differences in annual survivorship among flycatchers of different ages and sexes. We estimated annual survivorship of adult males to be 69±7 percent, which is higher than estimates of female survivorship (45±10 percent). Annual survivorship of first-year flycatchers ranged from 24 to 41 percent, which is roughly half the estimates calculated for adult flycatchers (52–75 percent). We found no evidence that precipitation in the previous breeding year had an effect on flycatcher survival. We were also able to observe dispersal and movement among adults and first-year flycatchers. Average first-year dispersal distance was 3.1±2.6 kilometers, with the longest dispersal (8.5 kilometers) by a natal female dispersing from the monitoring area to Lake Henshaw. Of the first-year flycatchers, 65 percent returned to the monitoring area to establish an adult breeding territory, while the remaining 35 percent dispersed to Lake Henshaw. Territory fidelity among adult flycatchers was high with 69±13 percent of returning adults occupying the same territory (or within 100 meters) from the previous year. There was no significant difference in territory fidelity between males and females, or across years. Nesting success in the previous year appeared to be a strong driver of territory fidelity, with adults more likely to return to the same territory following years when they successfully fledged young. The average between-year movement for returning adult flycatchers was 0.5±0.8 km. We documented the movement of two adult males from the monitoring area to Lake Henshaw. Between-year movement distances did not differ by sex or year. Resident flycatchers in the upper San Luis Rey River monitoring area used five habitat types from 2016 to 2019: (1) willow-oak, (2) willow-ash, (3) oak-sycamore, (4) mixed willow riparian, and (5) willow-sycamore, with willow-oak the most commonly used habitat type. The most commonly recorded dominant species at flycatcher territories included coast live oak ( Quercus agrifolia ), red or arroyo willow ( Salix laevigata or Salix lasiolepis ), California sycamore ( Platanus racemosa ), and velvet ash ( Fraxinus velutina ). In 2018, we anecdotally began to observe dead and dying oaks in the monitoring area, which we believe to be the result of goldspotted oak borer ( Agrilus auroguttatus ) infestation. At the conclusion of this study, we investigated the overall change in normalized difference vegetation index (NDVI) in flycatcher territories within the monitoring area. The greatest negative change in NDVI occurred in territories closest to Lake Henshaw, and many of the affected territories were no longer occupied in the later years of the study. Flycatchers used 13 plant species for nesting at the monitoring area from 2016 to 2019; 70 percent of all nests were placed in coast live oak. None of the nest characteristics including host height, nest height, distance to the edge of the host, or distance to the edge of the vegetation clump where the nest was placed differed between years. In 2016, successful nests were placed higher than unsuccessful nests; no other within-year differences were observed.

California

Germanium and uranium in coalified wood from upper Devonian black shale

Microscopic study of black, vitreous, carbonaceous material occurring in the Chattanooga shale in Tennessee and in the Cleveland member of the Ohio shale in Ohio has revealed coalified woody plant tissue. Some samples have shown sufficient detail to be identified with the genus Cauixylon . Similar material has been reported in the literature as “bituminous” or “asphaltic” stringers. Spectrographic analyses of the ash from the coalified wood have shown unusually high percentages of germanium, uranium, vanadium, and nickel. The inverse relationship between uranium and germanium in the ash and the ash content of various samples shows an association of these elements with the organic constituents of the coal. On the basis of geochemical considerations, it seems most probable that the wood or coalified wood was germanium-bearing at the time logs or woody fragmenta were floated into the basins of deposition of the Chattanooga shale and the Cleveland member of the Ohio shale. Once within the marine environment, the material probably absorbed uranium with the formation of organo-uranium compounds such as exist in coals. It is suggested that a more systematic search for germaniferous coals in the vicinity of the Chattanooga shale and the Cleveland member of the Ohio shale might be rewarding.

Geochimica et Cosmochimica Acta

Application of an updated atmospheric model to explore volcano infrasound propagation and detection in Alaska

Winds and temperature gradients greatly affect the long-range propagation of infrasound . The spatio-temporal variability of these parameters must therefore be accurately characterized to correctly interpret recorded infrasound at long distances, specifically to differentiate between source and propagation effects. Here we present the first results of an open source reanalysis model, termed Alaska Volcano Observatory Ground-to-Space (AVO-G2S), constructed to accurately characterize the atmosphere and model long-range infrasound propagation from volcanic eruptions in Alaska. We select a number of case studies to examine recent eruptions of Alaskan volcanoes whose ash emissions posed a threat to air traffic, including the two most recent eruptions of Pavlof Volcano and two typical explosions from Cleveland Volcano. Strong tropospheric ducting and low noise at the station during the 21 July 2015 explosion of Cleveland Volcano led to an automated detection of the explosion at an infrasound array 992 km away, whereas low signal-to-noise ratio for the 6 November 2014 Cleveland Volcano explosion helps explain the non-detection in real-time of a predicted strong stratospheric arrival. For the November 2014 Pavlof eruption, discrepancies between local seismic data and a distal infrasound array 460 km away cannot be solely explained by changes in atmospheric conditions, though some features of the complex propagation predictions follow the trends in long-range infrasound signals. The most recent eruption of Pavlof Volcano in March 2016 shows minimal changes in propagation conditions throughout the eruption and therefore indicates that the signals detected at long-range primarily reflect source processes. These results show how detailed examination of the acoustic propagation conditions provides insight into detection capability and eruption dynamics. Future work will implement AVO-G2S and high-resolution long-range infrasound propagation modeling in real-time for Alaskan volcanoes of interest.

Alaska

Reconstructing the paleoceanographic and redox conditions responsible for variations in uranium content in North American Devonian black shales

The uranium (U) content, and more recently, the ratio between 238 U and 235 U in black shales are commonly applied as a proxy to determine redox conditions and infer organic-richness. Uranium contents typically display a linear relationship with total organic carbon (TOC) in shales. This relationship is due to the processes and mechanisms responsible for the incorporation of U into the sediment during the deposition and remineralization of organic matter. This U/TOC relationship can vary, however, and some shales display uncharacteristically low U content despite having high TOC content, while others show large enrichments of U relative to TOC. Here we examine the U to TOC ratios and U-isotope compositions of three Upper Devonian-Lower Mississippian shales: the Woodford Shale, the Cleveland Shale, and the Bakken Shale, with two study sites in Oklahoma, one site in eastern Kentucky, and three sites in eastern Montana and western North Dakota, respectively. The U/TOC ratios of each shale are distinct from one another exhibiting average ratios ranging from 3 in the Cleveland Shale, to over 10 in the Bakken Shale. The distinct geochemical composition of the three shales suggests that, although lithologically similar, each study site represents a markedly different and dynamic depositional environment. The low average U/TOC (~3) along with the relatively high δ 238 U values (~0.03‰) of the Cleveland Shale core suggests deposition along the basin margin under normal marine conditions with periods of reduced bottom water oxygenation, likely due to fluctuations in the location of the pycnocline. The Woodford Shale on the other hand, shows higher U/TOC ratios (~4, George core, ~9, Poe core) and δ 238 U (~0.02‰ average, George core, ~0.06‰ average, Poe core), which suggests an unrestricted setting with intermittent euxinic conditions. In contrast, high U/TOC ratios (2–15), and very high δ 238 U values (up to 0.55‰) in the Bakken Shale cores indicate intense metal draw-down into sediments under sulfidic waters. The results show that when the U/TOC ratios and U-isotopic compositions of each studied shale are compared to modern anoxic basins and upwelling areas, it allows for an enhanced understanding of the paleoenvironmental conditions such as basin restriction and redox state of waters within the Late Devonian epicontinental seas of North America.

Palaeogeography, Palaeoclimatology, Palaeoecology

Status of Water Levels and Selected Water-Quality Conditions in the Sparta-Memphis Aquifer in Arkansas and the Status of Water Levels in the Sparta Aquifer in Louisiana, Spring 2005

The U.S. Geological Survey in cooperation with the Arkansas Natural Resources Commission, the Arkansas Geological Commission, and the Louisiana Department of Transportation and Development has monitored water levels in the Sparta Sand of Claiborne Group and Memphis Sand of Claiborne Group since the 1920's. Ground-water withdrawals have increased while water levels have declined since monitoring was initiated. This report has been produced to describe ground-water levels in the aquifers in the Sparta Sand and Memphis Sand and provide information for the management of this valuable resource. The 2005 potentiometric-surface map of the aquifers in the Sparta Sand and Memphis Sand was constructed using water-level data collected in 333 wells in Arkansas and 120 wells in Louisiana during the spring of 2005. The highest water-level altitude measured in Arkansas was 327 feet above National Geodetic Vertical Datum of 1929 located in Grant County in the outcrop at the western boundary of the study area; the lowest water-level altitude was 189 feet below National Geodetic Vertical Datum of 1929 in Union County. The highest water-level altitude measured in Louisiana was 246 feet above National Geodetic Vertical Datum of 1929 located in Bossier Parish in the outcrop area near the western boundary of the study area; the lowest water-level altitude was 226 feet below National Geodetic Vertical Datum of 1929 in central Ouachita Parish. Three large depressions centered in Columbia, Jefferson, and Union Counties in Arkansas are the result of large withdrawals for industrial and public supplies. In Louisiana, three major pumping centers are in Ouachita, Jackson, and Lincoln Parishes. Water withdrawals from these major pumping centers primarily is used for industrial and public-supply purposes. Withdrawals from Ouachita and Lincoln Parishes and Union County, Arkansas, primarily for industrial purposes, have caused the resulting cones of depression to coalesce so that the -40 foot potentiometric contour encircles the three pumping centers. Seven smaller depressions are evident on the 2005 Sparta-Memphis potentiometric-surface map located in Webster and Winn Parishes, Louisiana, and Calhoun, Cleveland, western Columbia, Desha, and Lafayette Counties, Arkansas. The depression in Calhoun County initially was shown in the 1996-1997 potentiometric surface. The depression in Desha County initially was shown in the 1999 potentiometric surface. The depressions in Webster and Winn Parishes were shown as early as 1975. The depressions in Cleveland, western Columbia, and Lafayette Counties initially were shown in the 2003 potentiometric surface. A map of differences in water-level measurements between 2001 and 2005 was constructed using the difference between water-level measurements from 294 wells in Arkansas and 29 wells in Louisiana. The difference in water levels between 2001 and 2005 ranged from -30.1 to 44.6 feet. The largest rise of 44.6 feet in water level measured was in Union County in Arkansas. The largest decline of 30.1 feet in water level measured was in Columbia County in Arkansas. Areas with a general rise in water levels in Arkansas are shown in Arkansas, Columbia, Craighead, Jefferson, Prairie, and the western half of Union Counties. The area around west-central Union County had rises as much as 44.6 feet, with seven wells showing a rise of 20 feet or greater, which is an annual rise of 5 feet or greater. Areas in Arkansas with a general decline in water level are shown in western Bradley, eastern Calhoun, Cleveland, Cross, Desha, Drew, Lafayette, Lee, Lincoln, Lonoke, Poinsett, and the eastern half of Union Counties. In Louisiana, the water-level difference map showed a general rise in water levels in northern Claiborne, northern Webster, and northwestern Union Parishes mainly because of a decrease in industrial withdrawals in southern Arkansas, particularly Union County. Another rise in water level was indicated in western

Scientific Investigations Report

Germanium and uranium in coalified wood from Upper Devonian black shale

Microscopic study of black, vitreous, carbonaceous material occurring in the Chattanooga shale in Tennessee and in the Cleveland member of the Ohio shale in Ohio has revealed coalified woody plant tissue. Some samples have shown sufficient detail to be identified with the genus Callixylon. Similar material has been reported in the literature as "bituminous" or "asphaltic" stringers. Spectrographic analyses of the ash from the coalified wood have shown unusually high percentages of germanium, uranium, vanadium, and nickel. The inverse relationship between uranium and germanium in the ash and the ash content of various samples shows an association of these elements with the organic constituents of the coal. On the basis of geochemical considerations, it seems most probable that the wood or coalified wood was germanium-bearing at the time logs or woody fragments were floated into the basins of deposition of the Chattanooga shale and the Cleveland member of the Ohio shale. Once within the marine environment, the material probably absorbed uranium with the formation of organo-uranium compounds such as have been found to exist in coals. It is suggested that a more systematic search for germaniferous coals in the vicinity of the Chattanooga shale and the Cleveland member of the Ohio shale might be rewarding.

Trace Elements Investigations