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Development and Application of Health-Based Screening Levels for Use in Water-Quality Assessments

Health-Based Screening Levels (HBSLs) are non-enforceable water-quality benchmarks that were developed by the U.S. Geological Survey in collaboration with the U.S. Environmental Protection Agency (USEPA) and others. HBSLs supplement existing Federal drinking-water standards and guidelines, thereby providing a basis for a more comprehensive evaluation of contaminant-occurrence data in the context of human health. Since the original methodology used to calculate HBSLs for unregulated contaminants was published in 2003, revisions have been made to the HBSL methodology in order to reflect updates to relevant USEPA policies. These revisions allow for the use of the most recent, USEPA peer-reviewed, publicly available human-health toxicity information in the development of HBSLs. This report summarizes the revisions to the HBSL methodology for unregulated contaminants, and updates the guidance on the use of HBSLs for interpreting water-quality data in the context of human health.

Scientific Investigations Report

Tularemia, an animal-borne disease

the disease tularemia continues to be of such importance in the United States that the Fish and Wildlife Service is constantly receiving requests for information on its nature and on the procedure recommended by field representatives of the Service in their work wiht the public. Such information is summarized in this leaflet. the information on human infections presented and the recommendations made have been endorsed by the United States Public Health Service.

Wildlife Leaflet

Volatile organic compounds in groundwater used for public supply across the United States: Occurrence, explanatory factors, and human-health context

This systematic assessment of occurrence for 85 volatile organic compounds (VOCs) in raw (untreated) groundwater used for public supply across the United States (U.S.), which includes 43 compounds not previously monitored by national studies, relates VOC occurrence to explanatory factors and assesses VOC detections in a human-health context. Samples were collected in 2013 through 2019 from 1537 public-supply wells in aquifers representing 78% of the volume pumped for public drinking-water supply. Laboratory detection limits for VOCs generally were less than 0.1 μg/L. Detections were reported for 36% of the sampled principal-aquifer area (38% of sampled wells) and were most common in wells in shallow, unconfined aquifers in urban areas that produce high proportions of modern-age and oxic groundwater. The disinfection by-product trichloromethane (chloroform) was the most commonly detected VOC associated primarily with anthropogenic sources (24% of the sampled area, 25% of sampled wells), followed by the gasoline oxygenate methyl tert-butyl ether (8.4% of area, 11% of wells). Carbon disulfide (12% of area, 14% of wells) was examined separately because of likely substantial contributions from natural sources. Newly monitored VOCs were each detected in <1% of the sampled area. Although detections of 1,4-dioxane in this first national study of its occurrence in raw groundwater were rare, measured concentrations exceeded the most stringent (non-enforceable) human-health benchmark in 0.5% of the sampled area (9 wells). Two wells had exceedances of enforceable benchmarks for tetrachloroethylene and trichloroethylene, and 50 wells total (representing 2.0% of the sampled area, 3.3% of sampled wells) had combined VOC concentrations exceeding 10% of benchmarks of any type. Compared with previous national findings, this study reports lower rates of VOC detection, but confirms widespread anthropogenic influence on groundwater used for public supply, with relatively few concentrations of individual VOCs or mixtures that approach or exceed human-health benchmarks.

Science of the Total Environment

Hexavalent and total chromium at low reporting concentrations in source-water aquifers and surface waters used for public supply in Illinois, 2013

On the basis of their recent review of the human health effects of hexavalent chromium [Cr(VI)] in public drinking water, the U.S. Environmental Protection Agency is considering the need for Federal regulation of Cr(VI). Presently, only total chromium is regulated, at a Maximum Contaminant Level (MCL) of 100 micrograms per liter (&micro;g/L). The occurrence of Cr(VI) in groundwater and surface waters generally is attributed to industrial sources, but can be of natural origin. California&rsquo;s recently established MCL for Cr(VI) of 10 &micro;g/L illustrates the drinking-water concerns associated with Cr(VI). To improve understanding of the possible impact of a Cr(VI)-specific standard that approximates the California level on the management of Illinois&rsquo; public drinking water, the U.S. Geological Survey, in cooperation with the Illinois Environmental Protection Agency, assessed the occurrence and distribution of Cr(VI) in the State&rsquo;s public-water supplies. During 2013, untreated water samples were collected to be analyzed for Cr(VI) and total chromium [Cr(T)] at 119 water-supply wells and 32 surface-water intakes; also, 32 treated surface-water samples were collected near the point of treatment and 32 near the furthest point of distribution. Public-supply sample sites were selected by a stratified random method. Samples typically were analyzed within 24 hours of collection at reporting limits of 0.02 &micro;g/L for Cr(VI) and 0.1 &micro;g/L for Cr(T). The occurrence of Cr(VI) was compared with selected geophysical, physical, and sampling factors that might more fully explain its distribution and magnitude of concentrations. The maximum concentration of Cr(VI) in groundwater was 2.1 &micro;g/L. Maximum concentrations in untreated and treated surface water were 0.29 &micro;g/L and 2.4 &micro;g/L, respectively. All sample concentrations were below the California MCL; only 35 percent were below that State&rsquo;s non-enforceable public health goal of 0.02 of &micro;g/L. Cr(VI) was undetected in 43 percent of untreated groundwater samples, with a median of 0.06 &micro;g/L when detected. All but two (94 percent) of untreated surface-water samples had detections. In untreated surface water, the median concentration was 0.09 &micro;g/L, whereas in treated (tap and distributed) water the median was 0.20 &micro;g/L. Surface waters treated with lime for softening typically had the greatest Cr(VI) concentrations (maximum, 2.4 &micro;g/L; median, 1.2 &micro;g/L). The maximum concentration of Cr(T) in groundwater was 1.8 &micro;g/L. Maximum concentrations in untreated and treated surface water were 1.8 &micro;g/L and 2.5 &micro;g/L, respectively. All sample concentrations were below the Federal MCL. Total chromium was detected in 65 percent of untreated groundwater samples, with a median of 0.40 &micro;g/L, when detected. All but one (97 percent) of untreated surface-water samples had detections. In untreated surface water, the median concentration was 0.40 &micro;g/L, whereas in treated (tap and distributed) water the median was 0.30 &micro;g/L. As with Cr(VI), surface waters treated with lime typically had the greatest Cr(T) concentrations. Examination of factors that might account for or be associated with the occurrence of Cr(VI) in public-supply source waters found few clearly evident factors. Associations in frequencies of occurrence and range of concentrations indicate that surface waters and groundwaters of shallow, unconsolidated, unconfined aquifers, particularly alluvial aquifers, are possibly most commonly affected by anthropogenic sources of Cr(VI). Groundwaters of deep (greater than 500 feet) bedrock aquifers, particularly the Cambrian-Ordovician aquifer system, are possibly most commonly affected by geologic sources of Cr(VI). Additional study, with supporting geologic and geochemical data that were not collected in this study, would be necessary to verify these associations. There was a weak positive relation (&rho; = 0.23) between concentrations of Cr(VI) and Cr(T) in untreated water samples, with a much stronger positive relation (&rho; = 0.86 and &rho; = 0.90, respectively) in samples collected soon after treatment and near the endpoint of distribution. The stronger relation and greater similarity between Cr(VI) and Cr(T) concentrations in treated water samples indicate that Cr(VI) represents a greater proportion of the measured concentrations of Cr(T) in treated waters than in untreated waters. The analysis of spikes and other quality-assurance samples indicate uncertainties associated with obtaining or confirming consistently accurate analytical results for Cr(VI) at near the applied reporting limit of 0.02 &micro;g/L.

Illinois

Statewide sampling to determine spatial distribution, prevalence, and occurrence of per- and polyfluoroalkyl substances (PFAS) in Illinois community water supplies, 2020–21

Per- and polyfluoroalkyl substances (PFAS) are a group of synthetic chemicals that have been manufactured and used globally since the 1940s. PFAS are used for their oil- and water-repellent properties, ability to reduce friction, and their flame-retardant nature. PFAS are widely used in a variety of products, including clothing, carpet, food packaging, and firefighting foam. The properties that make them useful in manufacturing, however, also make them persistent and mobile, causing potential exposures to the environment and humans. Known as “forever chemicals,” these compounds resist degradation and have been determined to bioaccumulate in humans and wildlife. The Illinois Environmental Protection Agency (IEPA) collected a total of 1,711 samples (includes quality-control samples) of finished water at 1,428 entry points from 1,017 Illinois community water supply (CWS) systems and analyzed the water samples for PFAS. The results following confirmation samples indicated a mean of 99 percent of all sample results were below the minimum reporting level (MRL) of 2 nanograms per liter (ng/L). Of the detections at or above the MRL, 7 of 18 PFAS were detected in 149 of 1,428 entry points (about 10 percent). Of the nearly 7.4 million residents directly served by the CWS systems sampled, more than 1.3 million residents (about 18 percent) are served by CWS systems that had at least one detection of PFAS above the MRL of 2 ng/L. The most frequently detected PFAS were perfluorobutanesulfonic acid (about 6.2 percent, 37 ng/L maximum concentration), perfluorooctanesulfonic acid (PFOS) (about 5.0 percent, 150 ng/L maximum concentration), and perfluorooctanoic acid (PFOA) (about 4.8 percent, 25 ng/L maximum concentration). Of the 1,428 entry point samples from the CWS systems, 149 samples had confirmed detections of PFAS, with 93 of those 149 (about 62 percent) samples having at least one PFAS with a concentration that exceeded the median detected concentration of 3.2 ng/L. The highest concentrations detected were 150 ng/L (PFOS) and 140 ng/L (perfluorohexanesulfonic acid) at one CWS location which has been shut down and a different source of water has been provided to the consumers. Although PFAS detections were more common in CWS systems using surface-water sources (about 35 percent, 30 of 85) and mixed sources (50 percent, 5 of 10) compared to those using groundwater sources (about 9 percent, 114 of 1,333), a greater range of PFAS concentrations were observed in groundwater CWS systems (2 to 150 ng/L) than in surface-water CWS systems (2 to 15 ng/L). Statistically significant differences were determined between some detected PFAS (PFOA, PFOS, and perfluorohexanoic acid) and the source of drinking water (groundwater, surface water, or mixed). This report summarizes the occurrence and spatial distribution of PFAS in CWS systems across Illinois. The results from this sampling effort could be used by Illinois public health officials to identify the potential risk of PFAS in drinking water to human health.

Illinois

Mapping monkeypox transmission risk through time and space in the Congo Basin

Monkeypox is a major public health concern in the Congo Basin area, with changing patterns of human case occurrences reported in recent years. Whether this trend results from better surveillance and detection methods, reduced proportions of vaccinated vs. non-vaccinated human populations, or changing environmental conditions remains unclear. Our objective is to examine potential correlations between environment and transmission of monkeypox events in the Congo Basin. We created ecological niche models based on human cases reported in the Congo Basin by the World Health Organization at the end of the smallpox eradication campaign, in relation to remotely-sensed Normalized Difference Vegetation Index datasets from the same time period. These models predicted independent spatial subsets of monkeypox occurrences with high confidence; models were then projected onto parallel environmental datasets for the 2000s to create present-day monkeypox suitability maps. Recent trends in human monkeypox infection are associated with broad environmental changes across the Congo Basin. Our results demonstrate that ecological niche models provide useful tools for identification of areas suitable for transmission, even for poorly-known diseases like monkeypox.

PLoS ONE

Water resources inventory of Connecticut Part 6: Upper Housatonic River basin

The upper Housatonic River basin report area has an abundant supply of water of generally good quality, which is derived from precipitation on the area and streams entering the area. Annual precipitation has averaged about 46 inches over a 30-year period. Of this, approximately 22 inches of water is returned to the atmosphere each year by evaporation and transpiration; the remainder flows overland to streams or percolates downward to the water table and ultimately flows out of the report area in the Housatonic River or in smaller streams tributary to the Hudson River. During the autumn and winter precipitation normally is sufficient to cause a substantial increase in the amount of water stored in surface reservoirs and in aquifers, whereas in the summer, losses through evaporation and transpiration result in sharply reduced streamflow and lowered ground-water levels. Mean monthly storage of water in November is 2.8 inches more than it is in June. The amount of water that flows into, through, and out of the report area represents the total amount potentially available for use ignoring reuse. For the 30-year period 1931 through 1960, the annual runoff from precipitation has averaged 24 inches (294 billion gallons). During the same period, inflows from Massachusetts and New York have averaged 220 and 64 billion gallons per year, respectively. A total average annual runoff of 578 billion gallons is therefore available. Although runoff indicates the total amount of water potentially available, it is rarely feasible to use all of it. On the other hand, with increased development, some water may be reused several times. The water availability may be tapped as it flows through the area or is temporarily stored in streams, lakes, and aquifers. The amounts that can be developed differ from place to place and time to time, depending on the amount of precipitation, on the size of drainage area, on the thickness, transmissivity, and areal extent of aquifers, and on the variations in chemical and physical quality of water. Differences in precipitation cause differences in the amount of streamflow whereas differences in the proportion of stratified drift affect its timing. Water can be obtained from wells almost anywhere in the area, but the amount obtainable at any particular point depends on the type and water-bearing properties of the aquifers tapped. Stratified-drift aquifers are the only ones generally capable of yielding more than 100 gpm (gallons per minute) to individual wells. Drilled, screened wells tapping this unit yield from 17 to 1,400 gpm, with a median yield of 200 gpm. Till and bedrock are widespread but generally provide only small supplies of water. Till is tapped in a few places by dug wells, which can yield small supplies of only a few hundred gallons per day throughout all or most of the year. Bedrock is the chief aquifer for privately owned domestic and rural supplies; it is tapped by drilled wells, about 90 percent of which will supply at least 2 gpm. Only 1 of 10 bedrock wells, however, will supply more than 30 gpm. The amount of ground water potentially available in the report area depends upon the thickness and hydraulic properties of aquifers, the amount of salvageable natural discharge of ground water, and the quantity of water available by induced infiltration from streams and lakes. From data on transmissivity, thickness, recharge, well performance, and streamflow, preliminary estimates of ground-water availability can be made for most stratified-drift aquifers in the report area. Long-term yields estimated for eight areas of stratified drift especially favorable for development of large ground-water supplies ranged from 0.6 to 5 mgd (million gallons per day). Detailed site studies are needed to verity these estimates and to determine optimum yields, drawdowns, and spacing of individual wells before major ground-water development is undertaken in these or other areas. The chemical quality of water in the report area is generally good; carbonate-bedrock units exert considerable local influence on water quality. Samples of naturally occurring surface water collected at 24 sites during low flow averaged 90 mg/l (milligrams per liter) dissolved solids and 60 mg/l hardness. Water from wells is generally more highly mineralized than naturally occurring water from streams. About 37 percent of the wells sampled yielded water with more than 200 mg/l dissolved solids and 50 percent yielded water with more than 120 mg/l hardness. These concentrations reflect the high degree of mineralization of ground water in carbonate bedrock and unconsolidated deposits derived from this bedrock. The larger streams, which transport varying amounts of industrial and domestic effluents, averaged about 150 mg/l dissolved solids and 90 mg/l hardness. Iron and manganese concentrations in both ground water and surface water at some places exceed recommended limits for domestic and industrial use. Most wells in the report area yield water with little or no iron or manganese. In certain localities however, the probability is high of encountering water with excessive concentrations of these constituents. Schists, especially the unit in the northwestern corner of the basin, are the likely sources of water with excessive iron and manganese. Iron concentrations in naturally occurring stream water exceed 0.3 mg/l under low-flow conditions at 29 percent of the sites sampled. These excessive concentrations result from discharge of iron-bearing water from aquifers or from swamps where iron is released from decaying vegetation. Water temperature in the larger streams ranges from 0°C (degrees Celsius) to about 28°C. Ground water between 30 feet and 200 feet below the land surface has a relatively constant temperature, usually between 8°C and 11°C. The quantity of suspended sediment transported by streams under natural conditions is negligible. Even in streams affected by man, turbidity is rarely a problem. The total amount of water used in the report area for all purposes during 1967 was about 6,360 million gallons, or 140 gpd per person. Public supplies furnished the domestic needs of nearly half the population of the area. All of the 14 public supplies sampled provided water that meets the drinking water standards of the U.S. Public Health Service.

Connecticut

Water-resources appraisal of the Wet Mountain Valley, in parts of Custer and Fremont counties, Colorado

The Wet Mountain Valley is an intermontane trough filled to a depth of at least 6,700 feet with unconsolidated deposits. Ground water occurs under both artesian and water-table conditions within the basin-fill aquifer and ground-water moverment is toward Grape and Texas Creeks. The depth to the water table is less than 10 feet in an area of about 40 square miles along the central part of the valley and is less than 100 feet in most of the remainder of the valley. Ground water stored in the upper 200 feet of saturated basin-fill sediments is estimated to total 1.5 million acre-feet. Yields greater than 50 gallons per minute generally can be expected from wells in the central part of the basin-fill aquifer, and yields less than 50 gallons per minute are generally reported from wells around the edge of the basin-fill aquifer. Yields of wells in the mountainous areas are generally less than 20 gallons per minute. Most streamflow occurs as a result of snowmelt runoff during June and July. The long-term annual runoff at seven stations ranges from an estimated 0.02 cubic foot per second per square mile to an estimated 1.17 cubic feet per second per square mile, generaly increasing with station altitude. Generalized annyal water budgets for two areas in the Wet Mountain Valley indicate that surface-water outflow is only 7 to 11 percent of the total water supply from precipitation and other sources. The remaining water is lost to the atmosphere by evapotranspiration. The quality of both the surface and ground water is generally within the recommended limits for drinking water set by the U.S. Public Health Service. (Woodard-USGS)

Water-Resources Investigations Report

Interdisciplinary science in support of environmental health along the United States-Mexico border

The diverse, fragile ecosystems of the borderlands have been pushed beyond sustainable levels due to rapid population growth and land-use changes. Water shortages and pollution, poor air quality, increased soil salinities, residual pesticides and heavy metal contaminants are some of the many stressors that are degrading the quality of life in the borderlands. The relationship between human health and environmental quality challenges public officials, medical professionals, and resource managers on both sides of the border in their efforts to provide for and maintain healthy communities. To help understand the relationship between environmental and human health, the U.S. Geological Survey's (USGS) Border Environmental Health Initiative (BEHI) created an Internet Map Service (IMS) with binational georeferenced data. The goal is to have seamless integration of borderwide datasets at regional and local scales that can lend understanding of the linkages between the condition of the physical environment and public health issues.

Fact Sheet

Retrospective analysis of the epidemiologic literature, 1990–2015, on wildlife-associated diseases from the Republic of Korea

To assess the status of research on wildlife diseases in the Republic of Korea (ROK) and to identify trends, knowledge gaps, and directions for future research, we reviewed epidemiologic publications on wildlife-associated diseases in the ROK. We identified a relatively small but rapidly increasing body of literature. The majority of publications were focused on public or livestock health and relatively few addressed wildlife health. Most studies that focused on human and livestock health were cross-sectional whereas wildlife health studies were mostly case reports. Fifteen diseases notifiable to the World Organisation for Animal Health were identified and 21 diseases were identified as notifiable to either the Korean Ministry of Health, Welfare, and Family Affairs or the Korean Ministry of Agriculture. Two diseases were reported as occurring as epidemics; highly pathogenic avian influenza (HPAI) and virulent Newcastle disease. Six diseases or disease agents were described in the literature as emerging including HPAI, rabies, Babesia microti , avian coronaviruses, scrub typhus, and severe fever thrombocytopenia syndrome virus. The diseases for which there were the largest number of publications were HPAI and rabies. The majority of wildlife-associated zoonotic disease publications focused on food-borne parasitic infections or rodent-associated diseases. Several publications focused on the potential of wildlife as reservoirs of livestock diseases; in particular, water deer ( Hydropotes inermis ) and wild boar ( Sus scrofa ). In contrast, there were few publications on diseases of concern for wildlife populations or research to understand the impacts of these diseases for wildlife management. Increased focus on prospective studies would enhance understanding of disease dynamics in wildlife populations. For the high-consequence diseases that impact multiple sectors, a One Health approach, with coordination among the public health, agricultural, and environmental sectors, would be important. This type of review can provide useful information for countries or regions planning or implementing national wildlife health programs.

Journal of Wildlife Diseases

Proceedings of the U.S. Geological Survey Interdisciplinary Microbiology Workshop, Estes Park, Colorado, October 15-17, 2008

Preface A U.S. Geological Survey Interdisciplinary Microbiology Workshop was held in Estes Park, Colorado, on October 15-17, 2008. Participants came from all USGS regions and disciplines. This report contains abstracts from 36 presentations and 35 poster sessions and notes from 5 breakout sessions. The seven presentation topics follow: Ecology of wildlife and fish disease Mechanisms of fish and wildlife disease Microbial ecology Geographic patterns/visualization Public health and water quality Geomicrobiology Ecosystem function The six poster session topics follow: Wildlife disease Disease detection methods Water quality Microbial ecology Metabolic processes Tools and techniques Five working groups met in breakout sessions on October 16, 2008. The highlights for each working group are summarized in this report, and their goals are listed below: Working Group I: to plan a Fact Sheet on interdisciplinary microbiology in the USGS Working Group II: to plan a USGS interdisciplinary microbiology Web site Working Group III: to suggest ways to broadcast and publicize the types of microbiology conducted at the USGS Working Group IV: to identify emerging issues in USGS interdisciplinary microbiology research Working Group V: to identify potential opportunities for interdisciplinary microbiology work at the USGS After the workshop, the USGS interdisciplinary microbiology Web site was activated in June 2009 at http://microbiology.usgs.gov/.

Scientific Investigations Report

Earth science and public health: Proceedings of the Second National Conference on USGS Health-Related Research

The mission of the U.S. Geological Survey (USGS) is to serve the Nation by providing reliable scientific information to describe and understand the earth; minimize loss of life and property from natural disasters; manage water, biological, energy, and mineral resources; and enhance and protect our quality of life. As the Nation?s largest water, earth, and biological science and civilian mapping agency, the USGS can play a significant role in providing scientific knowledge and information that will improve our understanding of the relations of environment and wildlife to human health and disease. USGS human health-related research is unique in the Federal government because it brings together a broad spectrum of natural science expertise and information, including extensive data collection and monitoring on varied landscapes and ecosystems across the Nation. USGS can provide a great service to the public health community by synthesizing the scientific information and knowledge on our natural and living resources that influence human health, and by bringing this science to the public health community in a manner that is most useful. Partnerships with health scientists and managers are essential to the success of these efforts. USGS scientists already are working closely with the public health community to pursue rigorous inquiries into the connections between natural science and public health. Partnering agencies include the Armed Forces Institute of Pathology, Agency for Toxic Substances Disease Registry, Centers for Disease Control and Prevention, U.S. Environmental Protection Agency, Food and Drug Administration, Mine Safety and Health Administration, National Cancer Institute, National Institute of Allergy and Infectious Disease, National Institute of Environmental Health Sciences, National Institute for Occupational Safety and Health, U.S. Public Health Service, and the U.S. Army Medical Research Institute of Infectious Diseases. Collaborations between public health scientists and earth scientists can lead to improved solutions for existing and emerging environmental health problems. This report summarizes the presentations and discussions held at the Second National Conference on USGS Health-Related Research, held at the USGS national headquarters in Reston, Virginia. The report presents 68 abstracts of technical presentations made at the conference and summaries of six topical breakout sessions. The abstracts cover a broad range of issues and demonstrate connections between human health and the quality and condition of our environment and wildlife. The summaries of the topical breakout sessions present ideas for advancing interdisciplinary science in areas of earth science and human health.

Scientific Investigations Report

Population vulnerability and evacuation challenges in California for the SAFRR tsunami scenario

The SAFRR tsunami scenario models the impacts of a hypothetical yet plausible tsunami associated with a magnitude 9.1 megathrust earthquake east of the Alaska Peninsula. This report summarizes community variations in population vulnerability and potential evacuation challenges to the tsunami. The most significant public-health concern for California coastal communities during a distant-source tsunami is the ability to evacuate people out of potential inundation zones. Fatalities from the SAFRR tsunami scenario could be low if emergency managers can implement an effective evacuation in the time between tsunami generation and arrival, as well as keep people from entering tsunami-prone areas until all-clear messages can be delivered. This will be challenging given the estimated 91,956 residents, 81,277 employees, as well as numerous public venues, dependent-population facilities, community-support businesses, and high-volume beaches that are in the 79 incorporated communities and 17 counties that have land in the scenario tsunami-inundation zone. Although all coastal communities face some level of threat from this scenario, the highest concentrations of people in the scenario tsunami-inundation zone are in Long Beach, San Diego, Newport Beach, Huntington Beach, and San Francisco. Communities also vary in the prevalent categories of populations that are in scenario tsunami-inundation zones, such as residents in Long Beach, employees in San Francisco, tourists at public venues in Santa Cruz, and beach or park visitors in unincorporated Los Angeles County. Certain communities have higher percentages of groups that may need targeted outreach and preparedness training, such as renters, the very young and very old, and individuals with limited English-language skills or no English-language skills at all. Sustained education and targeted evacuation messaging is also important at several high-occupancy public venues in the scenario tsunami-inundation zone (for example, city and county beaches, State or national parks, and amusement parks). Evacuations will be challenging, particularly for certain dependent-care populations, such as patients at hospitals and children at schools and daycare centers. We estimate that approximately 8,678 of the 91,956 residents in the scenario inundation zone are likely to need publicly provided shelters in the short term. Information presented in this report could be used to support emergency managers in their efforts to identify where additional preparedness and outreach activities may be needed to manage risks associated with California tsunamis.

California

Using GIS to assess priorities of infrastructure and health needs of colonias along the United States-Mexico border

Colonias, which are unincorporated border setdements in the United. States, have emerged in rural areas without the governance and services normally provided by local government. Colonia residents live in poverty and lack adequate health care, potable water, and sanitation systems. These conditions create substantial health risks for themselves and surrounding communities. By 2001, more than 1,400 colonias were identified in Texas. Cooperation with several Federal and Texas state agencies has allowed the U.S. Geological Survey (USGS) to improve colonia Geographic Information System (GIS) boundaries and develop the Colonia Health, Infrastructure, and Platting Status tool (CHIPS). Together, the GIS boundaries and CHIPS aid the Texas government in prioritizing the limited funds that are available for infrastructure improvement. CHIPS's report: generator can be tailored, to the needs of the user, providing either broad or specific output. CHIPS is publicly available on the U.S. Geological Survey Border Environmental Health Initiative website at http://borderhealth.cr. usgs.gov.

Journal of Latin American Geography

Availability of ground water in the lower Connecticut River basin, southwestern New Hampshire

This map scale 1:125,000 presents a preliminary assessment of the availability of ground water in the lower Connecticut River basin in southwestern New Hampshire. It is a generalization of several hydrogeologic factors and provides a guideline for ground-water exploration useful in water- and land-use planning. It does not describe the absolute quantity or quality of ground water available. The best aquifers in the basin are deposits of stratified sand or sand and gravel of Pleistocene age. Large aquifers of this type occur in places in the Connecticut River valley and in valleys of tributaries to the Connecticut River. Ground water is generally of good chemical quality. Iron and manganese in concentrations greater than the recommended limits for drinking water suggested by the U.S. Public Health Service are not uncommon. (USGS).

New Hampshire

Highly efficient, rapid, and concurrent removal of toxic heavy metals by the novel 2D hybrid LDH–[Sn2S6]

According to a United Nations report, by 2050 nearly six billion people worldwide will suffer from clean water scarcity. This is mostly because of the exponential proliferation of world population, urbanization, industrialization, and water pollution. Heavy metals are common water pollutants that can pose grave public health consequences. Existing water purification systems are lack of materials that have the potential for quick, simultaneous, efficient, and cost-efficient removal of numerous toxic metals from wastewater. Here, we report the design and synthesis of an economically viable Layered Double Hydroxides - Stannic Sulfide, LDH–[Sn 2 S 6 ] that exhibits a rapid, efficient, selective, and concurrent removal of Cu 2+ , Ag + , Cd 2+ , Pb 2+ , and Hg 2+ from parts per million (ppm) level to below 5 parts per billion (ppb) satisfying World Health Organization’s (WHO) safe drinking water limit. Moreover, LDH–[Sn 2 S 6 ] shows exceptionally high removal efficiencies of the above metals in acidic, neutral, and basic conditions. LDH–[Sn 2 S 6 ] also demonstrates enormous sorption capacities of 378, 978, 332, 579, and 666 mg/g for Cu 2+ , Ag + , Cd 2+ , Pb 2+ , and Hg 2+ , respectively. Remarkably, LDH–[Sn 2 S 6 ] displays extraordinary tolerance to the concentrations of Na + , Ca 2+ , Mg 2+ , Cl - , CO 3 2– , NO 3 – ,and SO 4 2- , and other constituents in tap and river water, it efficiently sequestrates Cu 2+ , Ag + , Cd 2+ , Pb 2+ , and Hg 2+ from ppm to safe drinking water levels in minutes. LDH–[Sn 2 S 6 ] shows pseudo-second-order sorption kinetics suggesting chemisorption adsorption mechanism involving M−S bonding. Altogether, the regeneratable LDH–[Sn 2 S 6 ] becomes an exceptional material that shows ultrahigh removal, unprecedented selectivity, rapid adsorption kinetics , wide pH stability, and a massive adsorption capacity. The integration of these features places LDH–[Sn 2 S 6 ] at the top of all adsorbents known to date and thus could be used for wastewater purifications.

Chemical Engineering Journal

Groundwater quality and the relation between pH values and occurrence of trace elements and radionuclides in water samples collected from private wells in part of the Kickapoo Tribe of Oklahoma Jurisdictional Area, central Oklahoma, 2011

From 1999 to 2007, the Indian Health Service reported that gross alpha-particle activities and concentrations of uranium exceeded the Maximum Contaminant Levels for public drinking-water supplies in water samples from six private wells and two test wells in a rural residential neighborhood in the Kickapoo Tribe of Oklahoma Jurisdictional Area, in central Oklahoma. Residents in this rural area use groundwater from Quaternary-aged terrace deposits and the Permian-aged Garber-Wellington aquifer for domestic purposes. Uranium and other trace elements, specifically arsenic, chromium, and selenium, occur naturally in rocks composing the Garber-Wellington aquifer and in low concentrations in groundwater throughout its extent. Previous studies have shown that pH values above 8.0 from cation-exchange processes in the aquifer cause selected metals such as arsenic, chromium, selenium, and uranium to desorb (if present) from mineral surfaces and become mobile in water. On the basis of this information, the U.S. Geological Survey, in cooperation with the Kickapoo Tribe of Oklahoma, conducted a study in 2011 to describe the occurrence of selected trace elements and radionuclides in groundwater and to determine if pH could be used as a surrogate for laboratory analysis to quickly and inexpensively identify wells that might contain high concentrations of uranium and other trace elements. The pH and specific conductance of groundwater from 59 private wells were measured in the field in an area of about 18 square miles in Lincoln and Pottawatomie Counties. Twenty of the 59 wells also were sampled for dissolved concentrations of major ions, trace elements, gross alpha-particle and gross beta-particle activities, uranium, radium-226, radium-228, and radon-222 gas. Arsenic concentrations exceeded the Maximum Contaminant Level of 10 micrograms per liter in one sample having a concentration of 24.7 micrograms per liter. Selenium concentrations exceeded the Maximum Contaminant Level of 50 micrograms per liter in one sample having a concentration of 147 micrograms per liter. Both samples had alkaline pH values, 8.0 and 8.4, respectively. Uranium concentrations ranged from 0.02 to 383 micrograms per liter with 5 of 20 samples exceeding the Maximum Contaminant Level of 30 micrograms per liter; the five wells with uranium concentrations exceeding 30 micrograms per liter had pH values ranging from 8.0 to 8.5. Concentrations of uranium and radon-222 and gross alpha-particle activity showed a positive relation to pH, with the highest concentrations and activity in samples having pH values of 8.0 or above. The groundwater samples contained dissolved oxygen and high concentrations of bicarbonate; these characteristics are also factors in increasing uranium solubility. Concentrations of radium-226 and radium-228 (combined) ranged from 0.03 to 1.7 picocuries per liter, with a median concentration of 0.45 picocuries per liter for all samples. Radon-222 concentrations ranged from 95 to 3,600 picocuries per liter with a median concentration of 261 picocuries per liter. Eight samples having pH values ranging from 8.0 to 8.7 exceeded the proposed Maximum Contaminant Level of 300 picocuries per liter for radon-222. Eight samples exceeded the 15 picocuries per liter Maximum Contaminant Level for gross alpha-particle activity at 72 hours (after sample collection) and at 30 days (after the initial count); those samples had pH values ranging from 8.0 to 8.5. Gross beta-particle activity increased in 15 of 21 samples during the interval from 72 hours to 30 days. The increase in gross beta-particle activity over time probably was caused by the ingrowth and decay of uranium daughter products that emit beta particles. Water-quality data collected for this study indicate that pH values above 8.0 are associated with potentially high concentrations of uranium and radon-222 and high gross alpha-particle activity in the study area. High pH values also are associated with potentially high concentrations of arsenic, chromium, and selenium in groundwater when these elements occur in the aquifer matrix along groundwater-flow paths.

Oklahoma

Water-quality data for the Southern Ute Indian Reservation, southwestern Colorado

Water-quality data from a study by the U.S. Geological Survey on the Southern Ute Indian Reservation in southwestern Colorado are presented in two tables. The data were collected during 1973-76 from 338 ground-water and surface-water samples. All samples were analyzed for major catons and anions, and selenium and arsenic. Data in the tables are keyed by numbers to maps showing the locations of sampling sites. Many of the samples contained arsenic, chloride, dissolved solids, fluoride, iron, magnesium, manganese, nitrate, nitrite-plus-nitrate as nitrogen, selenium, and sulfate in concentrations exceeding recommended or mandatory standards for drinking water established by the Colorado Department of Health and U.S. Public Health Service. (Woodard-USGS)

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