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USGS2005

The 2003 phreatomagmatic eruptions of Anatahan volcano - Textural and petrologic features of deposits at an emergent island volcano

Stratigraphic and field data are used in conjunction with textural and chemical evidence (including data from scanning electron microscope, electron microprobe, X-ray fluorescence, X-ray diffraction, and instrumental neutron activation analysis) to establish that the 2003 eruption of Anatahan volcano was mainly phreatomagmatic, dominated by explosive interaction of homogeneous composition low-viscosity crystal-poor andesite magma with water. The hydromagmatic mode of eruption contributed to the significant height of initial eruptive columns and to the excavation and eruption of altered rock debris from the sub-volcanic hydrothermal system. Volatile contents of glass inclusions in equilibrium phenocrysts less abundances of these constituents in matrix glass times the estimated mass of juvenile magma indicate minimum emissions of 19 kt SO2 and 13 kt Cl. This petrologic estimate of SO2 emission is an order-of-magnitude less than an estimate from TOMS. Similarly, inferred magma volumes from the petrologic data are an order of magnitude greater than those modeled from deformation data. Both discrepancies indicate additional sources of volatiles, likely derived from a separate fluid phase in the magma. The paucity of near-source volcanic-tectonic earthquakes preceding the eruption, and the dominance of sustained long-period tremor are attributed to the ease of ascent of the hot low-viscosity andesite, followed by a shallow phreatomagmatic mode of eruption. Phreatomagmatic eruptions are probably more common at emergent tropical island volcanoes, where shallow fresh-water lenses occur at near-sea-level vents. These relations suggest that phreatomagmatic explosions contributed to the formation of many of the near-sea-level craters and possibly even to the small calderas at the other Mariana islands.

Northern Mariana Islands↗

USGS2012

Global petrologic variations on the moon: A ternary-diagram approach.

A ternary-diagram approach for determination of global petrologic variations on the lunar surface is presented that incorporates valuable improvements in our previous method of using geochemical variation diagrams. This new approach uses a ternary diagram that is subdivided into equally spaced segments along each of its three sides and has a triangular area in its center. The segments are assigned distinct colors that cover the range of the visible spectrum. The apexes are assigned the three primary colors, and the center triangle, which represents equal proportions of the three apexes, is assigned the color gray. The apexes are assigned the average Fe and (Th/Ti) c (ratio normalized to chondrites) compositions of KREEP/Mg-suite rocks, mare basalts, and ferroan anorthosites. The composition of each picture element (pixel) within these Apollo orbital gamma ray databases is used to determine its position within the ternary diagram. The color corresponding to this ternary position is then placed on a classification map at that pixel's position within the orbital databases. Error databases produced for the Fe and (Th/Ti) c data were used to exclude pixels having high errors. The resultant classification map shows spatial transitions among petrologic units, allows direct determination of the relative proportions of each end-member composition in a pixel, and increases the geologic interpretability of these data over that of the individual elemental databases. The classification units correspond remarkably well to observed geologic units, when we consider the spatial resolution (100 km) of the gamma ray spectrometer. Our results are as follows: (1) The highlands contain large areas of relatively pure ferroan anorthosite. (2) The average composition of the upper lunar crust is represented by an “anorthositic gabbro” composition, which supports the “magma-ocean” hypothesis for lunar crustal genesis. (3) KREEP/Mg-suite rocks are a minor fraction of the upper lunar crust. (4) Within the farside highlands, areas of KREEP/Mg-suite rocks coincide mostly with areas of crustal thinning, which are probably areas of KREEP basalt extrusions or localized excavations of Mg-suite rocks or KREEP-rich rocks. (5) Portions of the east limb and farside highlands have considerable amounts of a mafic, chondritic Th/Ti component (like mare basalt) whose occurrences coincide with mapped concentrations of light plains that display dark-halo craters; the presence of this component supports the hypothesis that mare volcanism had occurred within this highland region before the end of final heavy bombardment.

Journal of Geophysical Research Solid Earth↗

USGS1970

A linear programming and least squares computer method for solving petrologic mixing problems

Problems of petrologic mixing have been solved using a two-stage computer-based calculation. First, linear programming is used to obtain an approximate solution and to identify non-negative solution values. Then a conventional least squares calculation is performed using the analyses represented by non-negative solution values as input to yield an optimum set of solution values. The error attached to each solution value is estimated by an empirical procedure. Petrologic application of the program has been demonstrated with three types of calculations: chemical mode, magma mixing, and liquid line of descent.

GSA Bulletin↗

USGS2009

Petrology and geochronology of crustal xenoliths from the Bering Strait region: Linking deep and shallow processes in extending continental crust

Petrologic, geochemical, and metamorphic data on gneissic xenoliths derived from the middle and lower crust in the Neogene Bering Sea basalt province, coupled with U-Pb geochronology of their zircons using sensitive high-resolution ion microprobe-reverse geometry (SHRIMP-RG), yield a detailed comparison between the P-T-t and magmatic history of the lower crust and magmatic, metamorphic, and deformational history of the upper crust. Our results provide unique insights into the nature of lithospheric processes that accompany the extension of continental crust. The gneissic, mostly maficxenoliths (constituting less than two percent of the total xenolith population) from lavas in the Enmelen, RU, St. Lawrence, Nunivak, and Seward Peninsula fields most likely originated through magmatic fractionation processes with continued residence at granulite-facies conditions. Zircon single-grain ages (n ??? 125) are interpreted as both magmatic and metamorphic and are entirely Cretaceous to Paleocene in age (ca. 138-60 Ma). Their age distributions correspond to the main ages of magmatism in two belts of supracrustal volcanic and plutonic rocks in the Bering Sea region. Oscillatory-zoned igneous zircons, Late Cretaceous to Paleocene metamorphic zircons and overgrowths, and lack of any older inheritance in zircons from the xenoliths provide strong evidence for juvenile addition of material to the crust at this time. Surface exposures of Precambrian and Paleozoic rocks locally reached upper amphibolite-facies (sillimanite grade) to granulite-facies conditions within a series of extension-related metamorphic culminations or gneiss domes, which developed within the Cretaceous magmatic belt. Metamorphic gradients and inferred geotherms (??30-50 ??C/km) from both the gneiss domes and xenoliths aretoo high to be explained by crustal thickening alone. Magmatic heat input from the mantle is necessary to explain both the petrology of the magmas and elevated metamorphic temperatures. Deep-crustal seismic-reflection and refraction data reveal a 30-35-km-thick crust, a sharp Moho and refl ective lower and middle crust. Velocities do not support a largely mafic (underplated) lower crust, but together with xenolith data suggest that Late Cretaceous to early Paleocene maficintrusions are likely increasingly important with depth in the crust and that the elevated temperatures during granulite-facies metamorphism led to large-scale flow of crustal rocks to produce gneiss domes and the observed subhorizontal refl ectivity of the crust. This unique combined data set for the Bering Shelf region provides compelling evidence for the complete reconstitution/re-equilibration of continental crust from the bottom up during mantle-driven magmatic events associated with crustal extension. Thus, despite Precambrian and Paleozoic rocks at the surface and Alaska's accretionary tectonic history, it is likely that a significant portion of the Bering Sea region lower crust is much younger and related to post-accretionary tectonic and magmatic events. ?? 2009 The Geological Society of America.

Special Paper of the Geological Society of America↗

USGS1980

Late Cenozoic volcanic rocks of the southern Sierra Nevada, California: I. Geology and petrology: Summary

The geology and petrology of the Cenozoic volcanic rocks of the region of California between 38° and 35°45'N latitude and 117°30' and 120°W longitude, including the rocks of a major potassic magmatic province on the west slope of the Sierra Nevada, have been described in Part I (Moore and Dodge, 1980) of this study. The geochemical features of these rocks may provide clues to their origin and aid in comparing and contrasting the Sierra Nevada potassic province with other localized potassic provinces elsewhere in the world. Basaltic rocks occur in numerous small lava-flow remnants, dikes, and plugs that intrude the predominantly granitic terrain of the western slope of the southern Sierra Nevada. Leucite-bearing rocks are present at several localities in this western region. More voluminous basalt, commonly associated with rhyolite, is present east of the range in the Basin and Range province. However, leucite-bearing rocks have been found-at only one locality in this region. Most of the late Cenozoic volcanic rocks in the southern Sierra Nevada eastward through Owens Valley and in the extreme western Basin-Range occur in five rather distinctive areas—the San Joaquin-Kings, Kern, Big Pine, and Coso volcanic fields, and the Mono-Long Valley volcanic center (Fig. 1).

Geological Society of America Bulletin, Part I↗

USGS2016

Sedimentary petrology and reservoir quality of the Middle Jurassic Red Glacier Formation, Cook Inlet forearc basin: Initial impressions

The Division of Geological & Geophysical Surveys and Division of Oil & Gas are currently conducting a study of the hydrocarbon potential of Cook Inlet forearc basin (Gillis, 2013, 2014; LePain and others, 2013; Wartes, 2015; Herriott, 2016 [this volume]). The Middle Jurassic Tuxedni Group is recognized as a major source of oil in Tertiary reservoirs (Magoon, 1994), although the potential for Tuxedni reservoirs remains largely unknown. As part of this program, five days of the 2015 field season were spent examining outcrops, largely sandstones, of the Middle Jurassic Red Glacier Formation (Tuxedni Group) approximately 6.4 km northeast of Johnson Glacier on the western side of Cook Inlet (fig. 4-1). Three stratigraphic sections (fig. 4-2) totaling approximately 307 m in thickness were measured and described in detail (LePain and others, 2016 [this volume]). Samples were collected for a variety of analyses including palynology, Rock-Eval pyrolysis, vitrinite reflectance, detrital zircon geochronology, and petrology. This report summarizes our initial impressions of the petrology and reservoir quality of sandstones encountered in these measured sections. Interpretations are based largely on hand-lens observations of hand specimens and are augmented by stereomicroscope observations. Detailed petrographic (point-count) analyses and measurement of petrophysical properties (porosity, permeability, and grain density) are currently in progress.

Alaska↗

USGS2019

Petrologic and mineral physics database for use with the U.S. Geological Survey National Crustal Model

We present a petrologic and mineral physics database as part of the U.S. Geological Survey National Crustal Model (NCM). Each of 209 geologic units, 134 of which are currently part of the geologic framework within the NCM, was assigned a mineralogical composition according to generalized classifications with some refinement for specific geologic formations. This report is concerned with the petrology and mineral physics of each geologic unit within the NCM, which control the physical behavior of the solid mineral matrix within the rock. This mineral physics database builds on the work of Abers and Hacker to include 13 minerals specific to continental rock types. We explored the effect of this database on zero-porosity anharmonic P- and S-wave rock velocities and density relative to a well-used empirical study of relations between wavespeeds and density by Brocher. We found that empirical relations between P-wave velocity and S-wave velocity or density do well on average but can differ from mineral physics calculations by up to 15 percent in S-wave velocity and almost 40 percent in density. This is consistent with Brocher’s study where he obtained similar results for in situ measurements and laboratory rock specimens. Additionally, the substantial presence of quartz in many rocks plays a major role in crustal seismic velocities and density due to quartz’s α – β phase transition, which can interfere with these empirical relationships. With increasing depth, quartz P-wave velocity can suddenly jump by 15 percent accompanied by little change in S-wave velocity and a modest decrease in density. Empirical relations based on observed P-wave velocity where P-wave velocity is positively correlated with S-wave velocity and density would then significantly overestimate both S-wave velocity and density.

Open-File Report↗

USGS1982

The depositional environment and petrology of the White Rim Sandstone Member of the Permian Cutler Formation, Canyonlands National Park, Utah

The White Rim Sandstone Member of the Cutler Formation of Permian age in Canyonlands National Park, Utah, was deposited in coastal eolian and associated interdune environments. This conclusion is based on stratigraphic relationships primary sedimentary structures, and petrologic features. The White Rim consists of two major genetic units. The first represents a coastal dune field and the second represents related interdune ponds. Distinctive sedimentary structures of the coastal dune unit include large- to medium-scale, unidirectional, tabular-planar cross-bedding; high-index ripples oriented parallel to dip direction of the foresets; coarse-grained lag layers; avalanche or slump marks; and raindrop impressions. Cross-bedding measurements suggest the dunes were deposited as transverse ridges by a dominantly northwest to southeast wind. Distinctive sedimentary structures of the interdune pond unit include wavy, horizontally laminated bedding, adhesion ripples, and desiccation polygons. These features may have been produced by alternate wetting and drying of sediment during water-table fluctuations. Evidence of bioturbation is also present in this unit. Petrologic characteristics of the White Rim helped to define the depositional environment as coastal. A crinoid fragment was identified at one location; both units are enriched in heavy minerals, and small amounts of well rounded, reworked glauconite were found in the White Rim throughout the study area. Earlier work indicates that the White Rim sandstone is late Wolfcampian to early Leonardian in age. During this time, the Canyonlands area was located in a depositional area alternately dominated by marine and nonmarine environments. Results of this study suggest the White Rim represents a coastal dune field that was deposited by predominantly on-shore winds during a period of marine transgression.

Open-File Report↗

USGS2010

Petrology and geochemistry of the 2006 eruption of Augustine Volcano

Deposits from the 2006 eruption of Augustine Volcano, Alaska, record a complex history of magma mixing before and during the eruption. The eruption produced five major lithologies: low-silica andesite scoria (LSAS; 56.5 to 58.7 weight percent SiO 2 ), mostly during the initial explosive phase; high-silica andesite pumice (HSA; 62.2 to 63.3 weight percent SiO 2 ), prevalent during the continuous phase; dense low-silica andesite (DLSA; 56.4 to 59.3 weight percent SiO 2 ), predominantly during the late effusive phase; and dense intermediate andesite (DIA) and banded clasts, present throughout the eruption but most abundant in the continuous phase. The DIA and banded clasts have compositions that fall between and partially overlap the ranges noted above. All rock types are phenocryst-rich (36 to 44 volume percent), containing plagioclase, orthopyroxene, augite, Fe-Ti oxides, olivine, and rare amphibole, apatite, and anhydrite. Glasses from tephra and flow-deposit clasts range from 66 to nearly 80 weight percent SiO 2 and represent highly evolved melt relative to the bulk rock compositions. Fe-Ti oxides recorded f O2 ~2 log units above the Ni-NiO buffer and temperatures of 904±47°C and 838±14°C from LSAS and HSA samples, respectively, with the intermediate lithologies falling in the middle of these ranges. The dense low-silica andesite and scoria (collectively LSA) are compositionally nearly identical, and trace-element patterns show that the HSA is not the result of shallow crustal fractionation of the LSA. The petrological and geochemical data indicate that two-component magma mixing between the LSA and HSA caused the compositional spread in eruptive products. The phenocryst population in the LSA suggests that it represents a hybrid formed from the HSA and an unerupted, basaltic “replenishing” magma. On the basis of petrological and geophysical observations reported here and elsewhere in this volume, the HSA was stored as a crystal-rich mush with its top at ~5-km depth. An influx of basalt remobilized and partially mixed with a portion of the mush, forming the hybrid LSA. The lower viscosity LSA ascended towards the surface as a dike, erupting during the explosive phase in mid-January 2006. In late January, a large explosion produced the first significant volumes of HSA, followed by several days of rapid HSA effusion during the eruption’s continuous phase. After a three-week hiatus marked by elevated gas output, signifying an open system, degassed LSA erupted during the final, effusive phase. Consistency in eruptive styles and compositions suggests that the HSA magma body may have been similarly rejuvenated during the past several eruptions.

Alaska↗

USGS2017

Field-trip guide to Mount St. Helens, Washington - An overview of the eruptive history and petrology, tephra deposits, 1980 pyroclastic density current deposits, and the crater

This field trip will provide an introduction to several fascinating features of Mount St. Helens. The trip begins with a rigorous hike of about 15 km from the Johnston Ridge Observatory (9 km north-northeast of the crater vent), across the 1980 Pumice Plain, to Windy Ridge (3.6 km northeast of the crater vent) to examine features that document the dynamics and progressive emplacement of pyroclastic flows. The next day, we examine classic tephra outcrops of the past 3,900 years and observe changes in thickness and character of these deposits as we traverse their respective lobes. We examine clasts in the deposits and discuss how the petrology and geochemistry of Mount St. Helens deposits reveal the evolution of the magmatic system through time. We also investigate the stratigraphy of the 1980 blast deposit and review the chronology of this iconic eruption as we travel through the remains of the blown-down forest. The third day is another rigorous hike, about 13 km round trip, climbing from the base of Windy Ridge (elevation 1,240 m) to the front of the Crater Glacier (elevation 1,700 m). En route we examine basaltic andesite and basalt lava flows emplaced between 1,800 and 1,700 years before present, a heterolithologic flow deposit produced as the 1980 blast and debris avalanche interacted, debris-avalanche hummocks that are stranded on the north flank and in the crater mouth, and shattered dacite lava domes that were emplaced between 3,900 and 2,600 years before present. These domes underlie the northern part of the volcano. In addition, within the crater we traverse well-preserved pyroclastic-flow deposits that were emplaced on the crater floor during the summer of 1980, and a beautiful natural section through the 1980 deposits in the upper canyon of the Loowit River. Before plunging into the field-trip log, we provide an overview of Mount St. Helens geology, geochemistry, petrology, and volcanology as background. The volcano has been referred to as a “master teacher.” The 1980 eruption and studies both before and after 1980 played a major role in the establishment of the modern U.S. Geological Survey Volcano Hazards Program and our understanding of flank collapses, debris avalanches, cryptodomes, blasts, pyroclastic density currents, and lahars, as well as the dynamics of magma ascent and eruption.

Washington↗

USGS1990

Petrology of the Rainy Lake area, Minnesota, USA-implications for petrotectonic setting of the archean southern Wabigoon subprovince of the Canadian Shield

The Rainy Lake area in northern Minnesota and southwestern, Ontario is a Late Archean (2.7 Ga) granite-greenstone belt within the Wabigoon subprovince of the Canadian Shield. In Minnesota the rocks include mafic and felsic volcanic rocks, volcaniclastic, chemical sedimentary rocks, and graywacke that are intrucded by coeval gabbro, tonalite, and granodiorite. New data presented here focus on the geochemistry and petrology of the Minnesota part of the Rainy Lake area. Igneous rocks in the area are bimodal. The mafic rocks are made up of three distinct suites: (1) low-TiO2 tholeiite and gabbro that have slightly evolved Mg-numbers (63-49) and relatively flat rare-earth element (REE) patterns that range from 20-8 x chondrites (Ce/YbN=0.8-1.5); (2) high-TiO2 tholeiite with evolved Mg-numbers (46-29) and high total REE abundances that range from 70-40 x chondrites (Ce/YbN=1.8-3.3), and (3) calc-alkaline basaltic andesite and geochemically similar monzodiorite and lamprophyre with primitive Mg-numbers (79-63), enriched light rare-earth elements (LREE) and depleted heavy rare-earth elements (HREE). These three suites are not related by partial melting of a similar source or by fractional crystallization of a common parental magma; they resulted from melting of heterogeneous Archean mantle. The felsic rocks are made up of two distinct suites: (1)low-Al2O3 tholeiitic rhyolite, and (2) high-Al2O3 calc-alkaline dacite and rhyolite and consanguineous tonalite. The tholeiitic felsic rocks are high in Y, Zr, Nb, and total REE that are unfractionated and have pronounced negative Eu anomalies. The calcalkaline felsic rocks are depleted in Y, Zr, and Nb, and the REE that are highly fractionated with high LREE and depleted HREE, and display moderate negative Eu anomalies. Both suites of felsic rocks were generated by partial melting of crustal material. The most reasonable modern analog for the paleotectonic setting is an immature island arc. The bimodal volcanic rocks are intercalated with sedimentary rocks and have been intruded by pre- and syntectonic granitoid rocks. However, the geochemistry of the mafic rocks does not correlate fully with that of mafic rocks in modern are evvironments. The low-TiO2 tholeiite is similar to both N-type mid-ocean-ridge basalt (MORB) and low-K tholeiite from immature marginal basins. The calc-alkaline basaltic andesite is like that of low-K calc-alkaline mafic volcanic rocks from oceanic volcanic arcs; however, the high-TiO2 tholeiite is most similar to modern E-type MORB, which occurs in oceanic rifts. The conundrum may be explained by: (1) rifting of a pre-existing immature arc system to produce the bimodal volcanic rocks and high-TiO2 tholeiite; (2) variable enrichment of a previously depleted Archean mantle, to produce both the low- and high-TiO2 tholeiite and the calc-alkaline basaltic andesite, and/or (3) enrichment of the parental rocks of the high-TiO2 tholeiite by crustal contamination. ?? 1990 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

USGS2020

Generation of calc-alkaline magmas during crystallization at high oxygen fugacity: An experimental and petrologic study of tephras from Buldir Volcano, western Aleutian Arc, Alaska, USA

Despite agreement that calc-alkaline volcanism occurs at subduction zones and is responsible for the genesis of continental landmasses, there is no consensus on the source of the Fe-depleted signature hallmark to calc-alkaline volcanism. In this study, we utilize mafic tephras collected from Buldir Volcano to address the genesis of strongly calc-alkaline volcanic rocks (those with a low Tholeiitic Index; ≤0·7) in a segment of the western Aleutian Arc to determine if the eruptions are plausibly part of a liquid line of descent, if they are mixtures of crustal melts and parental magmas, or if they are mixtures of melts of the mantle and the subducting slab. We conducted a series of H 2 O-saturated phase equilibrium experiments (1175–1000°C; 100 MPa) in a rapid-quench cold-seal (MHC) apparatus on the most primitive natural lava from Buldir (9·34 wt % MgO) at oxidizing conditions near the Re–ReO 2 buffer. We confirmed that all experiments equilibrated 0·3 ± 0·23 log units above the Re–ReO 2 buffer (ΔQFM ∼ +2·8) using X-ray Absorption Near Edge Structure (XANES) spectroscopy. Chromite is the liquidus phase, followed by olivine, then plagioclase, then clinopyroxene, and finally hornblende. Once clinopyroxene saturates, spinel composition shifts to magnetite. We compared our experimental results to the major element geochemistry and petrology of six tephras (51·9–54·8 wt % SiO 2 ) from Buldir collected during the 2015 field season of the GeoPRISMS shared platform. Tephras contain olivine + plagioclase + clinopyroxene + spinel ± hornblende; plagioclase comprises most of the crystalline volume, followed by either olivine or hornblende. Spinel is ubiquitous; with Cr-rich spinel inclusions in olivine and hornblende, and magnetite in the groundmass. Variations in phenocryst assemblages and compositions between samples can be attributed to differences in pre-eruptive temperatures, where hotter samples are devoid of hornblende, and contain Fo-rich olivine and plagioclase with lower An-contents, owing to the position of the mineral-in curves at fluid-saturated conditions. Experimental glasses match the depletion in FeO T observed in the tephra whole rock compositions. The continuous depletion in FeO T is attributable to saturation of spinel as a liquidus phase (initially as chromite) and continuous crystallization through the experimental series (changing to magnetite at colder temperatures). In contrast to the natural samples, the experiments show enrichment in TiO 2 with decreasing MgO, suggesting that differentiation did not occur at 100 MPa on Buldir. The TiO 2 depletion in volcanic rocks from Buldir can be accounted for if hornblende crystallization occurs close to the liquidus of a parental magma; a condition that is met at higher pressures and hydrous conditions. The emerging picture for Buldir Island is that (1) oxidizing conditions are required to drive the observed depletions in FeO T via crystallization of spinel, and (2) elevated H 2 O contents and high pressures are required to saturate hornblende close to the liquidus to reproduce the entire suite of major elements. Our study provides a mechanism to generate the calc-alkaline trends observed at Buldir without requiring mixing of slab and mantle melts. We conclude that calc-alkaline volcanic rocks with extremely low Tholeiitic Indices (0·7), like those from Buldir, cannot be generated in absence of high oxygen fugacity, even at high pressure and/or elevated water pressures.

Alaska↗

USGS2026

Petrological, textural, and volatile constraints on the architecture of Mauna Loa’s magmatic system over 170 years (1852–2022)

Mauna Loa’s reawakening in 2022 highlighted the limited availability of petrological constraints characterizing the geometry and dynamics of pre-eruptive storage at this volcano. In particular, there has been relatively little prior work constraining pre-eruptive volatile budgets, mineral zoning and textures. To address this, we examine olivine- and orthopyroxene-hosted melt inclusions (MIs), their mineral hosts, and matrix glasses from seven Mauna Loa eruptions spanning 170 years (1852–2022). We present the first extensive MI dataset from Mauna Loa with direct Raman measurements of vapor bubble CO 2 . Olivine- and orthopyroxene-hosted MIs contain 0.3–0.5 wt % H 2 O and 100–600 μg/g CO 2 . MI saturation pressures reveal that the dominant reservoir is located at ~2–5 km depth, consistent with fluid inclusion barometry and geophysical constraints. This depth has remained consistent over the past 170 years, although some eruptions appear to have tapped a narrower range of depths than others. Even the high-Mg# orthopyroxene phenocryst-hosted MIs record saturation pressures of <150 MPa (<6 km depth), which is inconsistent with a deep sub-Moho origin proposed by previous studies that rely on thermodynamic modeling. Our Raman measurements also provide an opportunity to assess the accuracy of different methods to reconstruct the amount of CO 2 in vapor bubbles, with applications to MI datasets published without direct Raman measurements. In general, models that partition CO 2 between the melt and bubble using the bubble volume prior to pre-eruptive quenching (e.g. Melt Inclusion Modification Corrections, MIMiC) systematically underestimate CO 2 contents by a median of ~100–200 μg/g (depending on the model and K D choice) and thus underestimate storage depths by ~0.5–1.5 km. While these methods are useful for first-order estimates of bubble CO 2 in published datasets, new studies should measure bubble CO 2 by Raman spectroscopy or perform MI rehomogenization. The zoning and textures of the crystals that host the MIs provide additional constraints on the plumbing system to supplement MI barometry. Orthopyroxene crystals exhibit varied zoning patterns, including oscillatory zoning that records repeated fluctuations in magmatic conditions, and sector zoning indicating rapid, kinetically controlled crystal growth. While faster Fe-Mg diffusion in olivine results in a simpler zoning record, complexly zoned olivines with higher-Fo ‘shoulders’ from 1852, 1868, and 1950 also record the injection of more primitive melts at shallow levels. Electron backscatter diffraction reveals that touching crystals in orthopyroxene glomerocrysts exhibit only very weakly systematic crystallographic orientation relationships, perhaps due to rapid aggregation in a dynamic system. Overall, our data are consistent with a large, shallow (~2–5 km) pre-eruptive reservoir repeatedly recharged by primitive magma injections that homogenized prior to eruption due to their small volume relative to the overall size of this reservoir. This chemical complexity is effectively recorded in mineral and MI compositions (orthopyroxene zoning in particular) but is obscured in glass and whole-rock analyses.

Hawaii↗

USGS2005

Volcán Popocatépetl, Mexico. Petrology, magma mixing, and immediate sources of volatiles for the 1994- Present eruption

Volcán Popocatépetl has been the site of voluminous degassing accompanied by minor eruptive activity from late 1994 until the time of writing (August 2002). This contribution presents petrological investigations of magma erupted in 1997 and 1998, including major-element and volatile (S, Cl, F, and H 2 O) data from glass inclusions and matrix glasses. Magma erupted from Popocatépetl is a mixture of dacite (65 wt % SiO 2 , two-pyroxenes + plagioclase + Fe–Ti oxides + apatite, ∼3 wt % H 2 O, P = 1·5 kbar, f O 2 = ΔNNO + 0·5 log units) and basaltic andesite (53 wt % SiO 2 , olivine + two-pyroxenes, ∼3 wt % H 2 O, P = 1–4 kbar). Magma mixed at 4–6 km depth in proportions between 45:55 and 85:15 wt % silicic:mafic magma. The pre-eruptive volatile content of the basaltic andesite is 1980 ppm S, 1060 ppm Cl, 950 ppm F, and 3·3 wt % H 2 O. The pre-eruptive volatile content of the dacite is 130 ± 50 ppm S, 880 ± 70 ppm Cl, 570 ± 100 ppm F, and 2·9 ± 0·2 wt % H 2 O. Degassing from 0·031 km 3 of erupted magma accounts for only 0·7 wt % of the observed SO 2 emission. Circulation of magma in the volcanic conduit in the presence of a modest bubble phase is a possible mechanism to explain the high rates of degassing and limited magma production at Popocatépetl.

Journal of Petrology↗

USGS2020

Petrologic insights into rift zone magmatic interactions from the 2011 eruption of Kīlauea Volcano, Hawaiʻi

The high frequency of historical eruptions at Kīlauea Volcano presents an exceptional opportunity to address fundamental questions related to the transport, storage, and interaction of magmas within rift zones. The Nāpau Crater area on Kīlauea’s East Rift Zone (ERZ) experienced nine fissure eruptions within 50 years (1961–2011). Most of the magma intruded during these frequent eruptions remained stored within the rift zone, creating a potential magma mixing depot within the ERZ. The superbly monitored and sampled 2011 eruption (Puʻu ʻŌʻō episode 59) presents an extraordinary opportunity to evaluate magma mixing processes within the ERZ. Whole-rock, glass, and olivine compositions were determined, not only for lava from the 2011 eruption, but also for a new suite of Nāpau Crater area samples from the 1963, 1965, 1968, 1983, and 1997 eruptions, as well as the previously undocumented 1922 eruption. Whole-rock XRF data revealed two geochemically distinct magma batches for episode 59: one less evolved (∼6·6 wt % MgO, 0·46 wt % K2O) than the other (∼6·2 wt % MgO, 0·58 wt % K2O). Episode 59 lava is remarkably aphyric (∼0·1 vol. % phenocrysts), making use of mineralogy to identify parent magma affinities problematic. Linear compositional trends of whole-rock major and trace elements, and reversely zoned olivine crystals indicate episode 59 lavas underwent magma mixing. Least squares regression calculations and plots of major and trace element data, were used to evaluate whether the episode 59 samples are products of mixing summit-derived magma with residual magma from previous Nāpau Crater area eruptions. The regression results and trace element ratios are inconsistent with previously proposed mixing scenarios, but they do support mixing between summit-derived magma and residual magma from the 1983 and 1997 Nāpau Crater area eruptions. These magmas were stored in physically and chemically distinct pods at depths of 1·6–3·0 km prior to mixing with new magma intruded from the summit to produce the episode 59 lava. One pod contained a fractionated equivalent of 1983 lava, and the other a hybrid of compositions similar to 1983 and 1997 lavas. The petrology of episode 59 lava demonstrates that magmas from two previous eruptions (1983 and 1997) were available to mix with magma intruded from the summit region. This study clarifies the pre-eruptive history of the mixed episode 59 lava, and elucidates the evolution of the volcano's magmatic system in a region of frequent eruptions.

Hawaii↗

USGS1987

Mineralogy and petrology of the Cretaceous- Tertiary boundary clay bed and adjacent clay-rich rocks, Raton Basin, New Mexico and Colorado.

The Cretaceous-Tertiary (K-T) boundary is preserved in a sequence of coal-bearing, fluvial rocks in the lower part of the Raton Formation (Late Cretaceous and Paleocene) at several sites in the east-central part of the Raton Basin. The K-T boundary occurs at the top of a kaolinitic claystone layer, commonly referred to as the "boundary clay layer," in an interval of coal and carbonaceous shale. The boundary is defined by the disappearance of certain fossil-pollen taxa. The boundary clay layer also contains shocked quartz grains and abundance anomalies of iridium, chromium, and other elements. Each of these characteristics support the hypothesis of an asteroid impact at the end of the Cretaceous. Small goyazite spheres were also found in the boundary clay bed; however, their origin is uncertain. X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and thin-section petrography have shown that the boundary clay bed exhibits unique mineralogic and petrologic characteristics not possessed by other clay-rich beds in coal-bearing rocks of the Raton Basin. The boundary clay bed is composed primarily of well-crystallized kaolinite but also contains subordinate, randomly interstratified, mixed-layer illite/smectite, both of which appear to have been formed by the alteration of vitreous material in a coal-swamp environment. The bulk mineralogy of the boundary clay bed is similar to that of other kaolinite-rich clay beds (tonsteins) that altered in coal swamps from airfall volcanic ash. The alteration process and diagenetic products of the host material in the boundary clay bed, however, differed from those of the tonsteins, resulting in a unique petrographic fabric. The boundary clay bed is characterized by an overall imbricate fabric that may reflect an original vitreous material that included shards, bubbles, and spheres. The original fallout material of the boundary clay bed first altered to "cabbage-like" microspherules, indicating a halloysite or allophane precursor, and then to well-crystallized kaolinite; the well-crystallized kaolinite is the diagenetic stable phase for these rocks at their maximum burial conditions. In comparison, the vitreous components of the tonsteins were altered directly to coarse vermicular and platey kaolinite. Alteration of the original fallout material in the boundary bed was probably rapid, leading to hydrated, disordered, fine-grained clay minerals that formed into curled spherical or tubular shapes. The factors that produced these unique fabrics in the boundary clay bed existed at all K-T sites in the Raton Basin and were much different from those that formed the coarse platey and vermicular fabrics of ordinary tonsteins. The distinctive character of the boundary clay may be due to the unique nature and chemistry of the fallout material and (or) physical or chemical conditions existing shortly after its deposition.

Journal of Sedimentary Petrology↗

USGS1989

Petrologic constraints on rift-zone processes - Results from episode 1 of the Puu Oo eruption of Kilauea volcano, Hawaii

The Puu Oo eruption in the middle of Kilauea volcano's east rift zone provides an excellent opportunity to utilize petrologic constraints to interpret rift-zone processes. Emplacement of a dike began 24 hours before the start of the eruption on 3 January 1983. Seismic and geodetic evidence indicates that the dike collided with a magma body in the rift zone. Most of the lava produced during the initial episode of the Puu Oo eruption is of hybrid composition, with petrographic and geochemical evidence of mixing magmas of highly evllved and more mafic compositions. Some olivine and plagioclase grains in the hybrid lavas show reverse zoning. Whole-rock compositional variations are linear even for normally compatible elements like Ni and Cr. Leastsquares mixing calculations yield good residuals for major and trace element analyses for magma mixing. Crystal fractionation calculations yield unsatisfactory residuals. The highly evolved magma is similar in composition to the lava from the 1977 eruption and, at one point, vents for these two eruptions are only 200 m apart. Possibly both the 1977 lava and the highly evolved component of the episode 1 Puu Oo lava were derived from a common body of rift-zone-stored magma. The more mafic mixing component may be represented by the most mafic lava from the January 1983 eruption; it shows no evidence of magma mixing. The dike that was intruded just prior to the start of the Puu Oo eruption may have acted as a hydraulic plunger causing mixing of the two rift-zone-stored magmas. ?? 1989 Springer-Verlag.

Bulletin of Volcanology↗

USGS2020

Petrology and geochemistry of three early Holocene eruptions from Makushin volcano, Alaska

Makushin stratovolcano, Alaska, produced three, highly explosive, andesitic eruptions between ~ 9292 and 6215 yBP. Those eruptions are informally named the CFE (“crater-forming eruption”), Nateekin, and Driftwood Pumice, and they deposited significant tephra fallout in the present-day port of Dutch Harbor and City of Unalaska area. The focus of this study is to examine the geochemistry and petrology of those eruptions to better understand Makushin volcano hazards, andesite petrogenesis and eruption triggering by mafic recharge processes. The CFE, Nateekin, and Driftwood Pumice samples range from basaltic andesite to dacite but are predominantly andesitic (SiO 2 = 55.6 to 63.5 wt%). The CFE deposits are slightly compositionally stratified, with the top CFE samples slightly more mafic (55 to 60 wt% SiO 2 ) than the basal deposits (58 to 60 wt% SiO 2 ). Disequilibrium mineral compositions and textures in the CFE, Nateekin, and Driftwood Pumice samples, combined with two pyroxene thermometry and An-rich plagioclase microlites (An 80 ) found only in the top of the CFE deposits, provide evidence for repetitive mafic recharge triggering those eruptions, consistent with prior studies. We compare the Makushin geochemical data with data from select satellite vents and cones in the Makushin Volcanic Field (MVF) from prior studies, to examine possible genetic relationships. The geochemical data and Rhyolite-MELTS models run at crustal storage conditions (2 kbar, fO 2 = Ni-NiO, and 1.5 and 3.5 wt% H 2 O) indicate that no single parental magma supplies the MVF satellite cones and Makushin volcano. Instead, two component mixing models better fit the MVF geochemical array. Our Makushin results compare well with models of predominantly andesitic volcanoes that require mafic recharge to mobilize the andesites and trigger eruptions.

Alaska↗