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Reservoir thermal energy storage pre-assessment for the United States

Storing thermal energy underground for later use in electricity production or direct-use heating/cooling is a promising, viable, and economical green energy option. Reservoir thermal energy storage (RTES) is one such option, which stores energy in underutilized permeable strata with low ambient groundwater flow rates and more geochemically evolved (e.g. brackish/saline) waters relative to overlying principal aquifer systems. The U.S. Geological Survey has begun assessing RTES potential nationally by focusing on five generalized geologic regions (Basin and Range, Coastal Plain, Illinois Basin, Michigan Basin, Pacific Northwest) across the United States. Hydrogeologic reservoir models are developed for the following eight metropolitan area cities within those regions to evaluate RTES performance across different climates and subsurface conditions: Albuquerque, New Mexico; Charleston, South Carolina; Chicago and Decatur, Illinois; Lansing, Michigan; Memphis, Tennessee; Phoenix, Arizona; and Portland, Oregon. Evaluated metrics include estimated required well spacing, thermal storage capacity, and thermal recovery efficiency through time. Also considered for each reservoir are potential complicating factors, including reservoir depth, thermally driven free convection, and groundwater salinity. This work focuses on direct-use cooling because the need for cooling modern office buildings greatly exceeds that for heating in most parts of the country (Falta and others, 2016); however, the evaluated metrics are also relevant to heating and electricity applications. Results indicate that favorable RTES conditions exist in each region, with the Coastal Plain and Basin and Range being especially favorable for thermal storage capacity, while the Pacific Northwest and Michigan Basin excel at energy recovery for the evaluated cooling application. The results underscore the utility of developing maps of thermal storage capacity, subsurface temperature models, and volumetric estimates of thermal storage capacity to serve as key RTES resource classification standards. Overall, this pre-assessment provides a basic understanding of RTES potential in several cities and geologic regions throughout the country and will aid ongoing thermal energy storage assessment efforts.

Arizona, Illinois, Michigan, New Mexico, Oregon, S

Estimating agricultural irrigation water consumption for the High Plains aquifer region with integrated energy- and water-balance evapotranspiration modeling approaches

Estimation of irrigation water use provides essential information for the management and conservation of agricultural water resources. Conventionally, water use data are created based on reports and surveys from water users, whereas manual records may not be complete due to lacking flow meters, measurement gaps, inconsistent methods across regions, and time- and cost-consuming data processing. Alternatively, spatially explicit estimation of irrigation water use can be conducted efficiently using remote sensing evapotranspiration (ET) modeling approaches. In this study, we created a gridded blue water evapotranspiration (BWET) dataset to estimate historical irrigation water consumption (1986 – 2020) in the croplands across the United States High Plains aquifer region. The BWET data were generated by integrating an energy-balance ET model [Operational Simplified Surface Energy Balance model (SSEBop)] and a water-balance ET model [Vegetation ET model (VegET)]. BWET in croplands indicates crop consumptive use of irrigation water extracted from surface water and groundwater resources. The BWET estimates were compared with reported irrigation water use data for all counties within the aquifer region. The results revealed high agreement between growing season (May – September) BWET and annual water withdrawal at county level. Specifically, correlation coefficients of volumetric BWET and water withdrawal were 0.90 and 0.96, respectively, for the entire aquifer region and western Kansas. The timeseries of BWET and water withdrawal showed similar temporal trends and high covariations. The BWET estimates were systematically lower than the water withdrawal measurements, which was primarily attributed to blue water losses in the irrigation system. The irrigation efficiency, calculated as the ratio of BWET to water withdrawal depth, was 0.57 and 0.74 for the entire aquifer region and western Kansas, respectively. This study demonstrates the capability of using satellite-based ET models (e.g., SSEBop and VegET) to efficiently estimate crop water consumption and evaluate irrigation efficiency at landscape, county, and regional scales.

Colorado, Kansas, Nebraska, New Mexico, Oklahoma,

Relating systematic molecular and textural properties of graptolite pyrolyzed via gold tube hydrous pyrolysis: Implications for thermal proxies in lower Paleozoic marine shales

A series of gold tube pyrolysis experiments (72 h, 300–550 °C, 50 MPa) conducted on a graptolite-rich lower Paleozoic marine shale generated pyrolysis residues for a comprehensive evaluation of the molecular and structural variability of three types of graptolite periderm. Organic petrology, Raman spectroscopy, and field emission scanning electron microscopy (FE-SEM) with energy dispersive spectroscopy (EDS) were combined to evaluate the thermal evolution process. The three types of graptolite periderm, namely granular, non-granular, and nodular graptolite, were analyzed by Raman spectroscopy wherein point measurements were obtained after the maceral was identified and the location verified by organic petrology. Distinct thermal evolution pathways among non-granular, granular, and nodular graptolite periderms were recorded. The evolution patterns of the Raman parameters, particularly D1 and G bands, highlight the differences in geochemical composition of the graptolite periderm types and the alteration of molecular structure with increasing thermal maturity. Raman parameters D1 (position of the D1 peak), G-FWHM (full width at half maximum of the G peak), and ratios D1-FWHM/G-FWHM (full width at half maximum of the D1 peak ratioed to G-FWHM) and A D1 /A G (ratio of D1 and G peak intensities) showed effectiveness in assessing thermal maturity. Bireflectance with increasing gold tube pyrolysis temperature followed a hierarchy: non-granular > granular > nodular, reflecting different molecular alignment intensities. Qualitative FE-SEM evaluation showed that fine-grained mineral inclusions (primarily Fe-sulfide as determined via EDS) were associated with the graptolite populations, with granular graptolite containing greater amounts of coarser-grained (e.g., ∼300–1400 nm) mineral inclusions relative to non-granular and nodular graptolite, which contain finer-grained (e.g., ∼100–200 nm) inclusions difficult to resolve with optical microscopy. These findings are investigated to highlight the mechanisms that drive organic matter evolution within graptolite during thermal maturation, as well as to explore some of the limitations of using spectroscopic parameters as thermal maturity proxies.

International Journal of Coal Geology

A probabilistic assessment methodology for the evaluation of geologic energy storage capacity—Natural gas storage in depleted hydrocarbon reservoirs

The need for energy storage, particularly underground, where capacity and duration may far exceed battery storage technologies, is especially relevant given the increasing demands for reliable power alongside the development of intermittent renewable electricity sources. Geologic energy storage facilities already exist, and expanded use would enable storing gases such as methane and hydrogen. In 2018, a National Academies of Sciences, Engineering, and Medicine report, “Future Directions for the U.S. Geological Survey's Energy Resources Program,” recommended that the U.S. Geological Survey (USGS) prioritize assessing underground energy storage in geologic formations in the United States. The U.S. Geological Survey has since developed a methodology for assessing natural gas storage capacities in depleted hydrocarbon reservoirs on a national scale. The methodology introduced in this report prescribes three approaches for calculating gas storage capacity. This methodology relies on the availability of input data, including cumulative hydrocarbon production records, reservoir petrophysical properties, and reservoir pressure data. Assessment inputs can be obtained from public, State-level databases and propriety national-scale databases, although the use of analogs could be warranted for estimating input parameters. Probabilistic assessment results are aggregated to play, petroleum province, regional, and national scales. The steps defined in this report are demonstrated on the Michigan Basin Province, which includes the Mississippian Sandstone Gas Play and the Clinton Structural Play. This methodology could be used to systematically and consistently assess hydrocarbon plays and provinces for natural gas storage capacity across the United States.

Michigan

Paleomagnetic correlation of surface and subsurface basalt flows in the central and southwestern part of the Idaho National Laboratory, Idaho

The U.S. Geological Survey, in cooperation with the U.S. Department of Energy, used paleomagnetic data from 22 coreholes to construct 3 fence diagrams of subsurface basalt flows in the southern part of the Idaho National Laboratory. These diagrams provide comprehensive descriptions of the horizontal and vertical distribution of basalt flows and sediment layers beneath the surface, aiding geological studies and contributing valuable data to numerical models of groundwater flow and contaminant transport. The correlations established though these diagrams include spatial correlations between basalt flows found in multiple coreholes. Correlations were identified by matching average paleomagnetic inclinations and confirming or denying these correlations using petrology, geochemistry and radiometric ages. The fence diagrams aid in identifying potential locations of subsurface vents, volcanic vents that have been buried by more recent volcanic activity, associated to subsurface basalt flows. By tracing the subsurface flows and analyzing where the greatest thickness occurs, the locations of buried vents can be inferred. Some subsurface flows exhibit correlations across several coreholes and may indicate yet unidentified surface or buried vents, thereby enhancing our understanding of the volcanic history and subsurface geology of the region.

Idaho

Critical minerals in zinc ore—An update on Earth Mapping Resources Initiative Research in the Boulder Batholith region, Montana

Plain Language Summary U.S. Geological Survey research, in collaboration with Montana Technical University and Montana Bureau of Geology and Mines, is providing key critical mineral information that may have potential for critical mineral production of several mining districts in the Boulder Batholith region, to better understand the abundance and distribution of natural resources within this region. Continued research can be used to show the potential for previously undiscovered critical mineral resources in southwestern Montana and in other parts of the United States.

Montana

A synthesis engine for constructing geologic maps of the United States

The geologic history of the United States is cataloged in thousands of geologic maps produced during many decades. However, the disparate nature of these individual maps makes it challenging to assess resources, research geologic histories, or characterize natural hazards holistically across the Nation. The U.S. House of Representatives 2020 appropriations bill for the U.S. Department of the Interior (H.R. 116-100) requires the U.S. Geological Survey to “bring together detailed national and continental-resolution [two-dimensional] and [three-dimensional] information produced throughout the Survey and by [F]ederal and [S]tate partners.” In response to this directive, this report presents a compilation and synthesis of geologic maps across the United States in the form of a relational database. The synthesis database includes thematic maps that synthesize the Nation’s geology, and retains the original input maps as well as linkages to standardized vocabularies to aid the discoverability of geologic information. Specifically, the synthesis database is targeted toward producing four National-resolution maps for the conterminous United States: Quaternary geology, the geology at the Earth’s surface, pre-Quaternary geology, and Precambrian geology. In addition, the synthesis database includes the infrastructure necessary to expand to additional resolutions in the future.

conterminous United States

Geology, mineralogy, and cassiterite geochronology of the Ayawilca Zn-Pb-Ag-In-Sn-Cu deposit, Pasco, Peru

The Ayawilca deposit in Pasco, Peru, represents the most significant recent base-metal discovery in the central Andes and one of the largest undeveloped In resources globally. As of 2018, it hosts an 11.7 Mt indicated resource grading 6.9% Zn, 0.16% Pb, 15 g/t Ag, and 84 g/t In, an additional 45.0 Mt inferred resource grading 5.6% Zn, 0.23% Pb, 17 g/t Ag, and 67 g/t In, and a separate Sn-Cu-Ag inferred resource of 14.5 Mt grading 0.63% Sn, 0.21% Cu, and 18 g/t Ag. Newly obtained U–Pb dates for cassiterite by LA-ICP-MS (22.77 ± 0.41 and 23.05 ± 2.06 Ma) assign the Ayawilca deposit to the Miocene polymetallic belt of central Peru. The polymetallic mineralization occurs as up to 70-m-thick mantos hosted by carbonate rocks of the Late Triassic to Early Jurassic Pucará Group, and subordinately, as steeply dipping veins hosted by rocks of the Pucará Group and overlying Cretaceous sandstones-siltstones of the Goyllarisquizga Group. Relicts of a distal retrograde magnesian skarn and cassiterite (stage pre-A) were identified in the deepest mantos. The volumetrically most important mineralization at Ayawilca comprises a low-sulfidation assemblage (stage A) with quartz, pyrrhotite, arsenopyrite, chalcopyrite, Fe-rich sphalerite, and traces of stannite and herzenbergite. Stage A sphalerite records progressive Fe depletion, from 33 to 10 mol% FeS, which is compatible with the observed transition from low- to a subsequent intermediate-sulfidation stage (B) marked by the crystallization of abundant pyrite and marcasite. Finally, during a later intermediate-sulfidation stage (C) sphalerite (up to 11 mol% FeS), galena, native bismuth, Cu-Pb-Ag sulfosalts, siderite, Mn-Fe carbonates, kaolinite, dickite, and sericite were deposited. This paragenetic evolution shows striking similarities with that at the Cerro de Pasco Cordilleran-type polymetallic deposit, even if at Ayawilca stage C did not reach high-sulfidation conditions. The occurrence of an early retrograde skarn assemblage suggests that the manto bodies at Ayawilca formed at the transition between distal skarn and skarn-free (Cordilleran-type) carbonate-replacement mineralization. Mineral assemblages define a T- f S 2 evolutionary path close to the pyrrhotite-pyrite boundary. Buffering of hydrothermal fluids by underlying Devonian carbonaceous phyllites of the Excelsior Group imposed highly reduced conditions during stage A mineralization (log f O 2 < − 30 atm). The low f O 2 favored efficient Sn mobility during stages pre-A and A, in contrast to other known ore deposits in the polymetallic belt of central Peru, in which the occurrence of Sn minerals is minor. Subsequent cooling, progressive sealing of vein walls, and decreasing buffering potential of the host rocks promoted the shift from low- (stage A) to intermediate-sulfidation (stages B and C) states. LA-ICP-MS analyses reveal significant In contents in Fe-rich sphalerite (up to 1.7 wt%), stannite (up to 1908 ppm), and chalcopyrite (up to 1185 ppm). The highest In content was found in stage A sphalerite that precipitated along with chalcopyrite and stannite, thus pointing to the early, low-sulfidation assemblage as prospective for this high-tech metal in similar mineral systems. Indium was likely incorporated into the sphalerite crystal lattice via Cu + + In 3+ ↔ 2 Zn 2+ and (Sn, Ge) 4+ + (Ga, In) 3+ + (Cu + Ag) + ↔ 4 Zn 2+ coupled substitutions. Indium incorporation mechanisms into the stannite and chalcopyrite crystal lattices remain unclear.

Pasco

The Sedimentary Geochemistry and Paleoenvironments Project Phase 2 data release: An open data resource for the study of Earth's environmental history

Geochemical data from sedimentary rocks are the primary source of information regarding Earth's surface evolution through time, including its air and water envelopes and interactions with life and deep Earth processes. The Sedimentary Geochemistry and Paleoenvironments Project (SGP) is a scientific consortium centered around open data and community-driven development of cyberinfrastructure tools and resources for sedimentary geochemistry and Earth history. Here we describe the SGP Phase 2 data release, which focused on incorporating Paleoproterozoic and Mesoproterozoic (2500–1000 million years ago) data and better accommodating carbonate data. This data release was built through the involvement of >200 researchers worldwide in academia, government, and industry, and provides the largest available public data resource for our user community in the academic fields of geochemistry, sedimentology, tectonics, paleontology, Earth history, and paleoclimate, as well as the petroleum and minerals industries. The dataset now encompasses 126,006 samples and 4,132,371 geochemical analyses. In addition to direct entry by SGP Team Members, we have ingested and incorporated datasets from the Geoscience Australia OZCHEM database, the Alberta Geological Survey, and the Deep-Time Marine Sedimentary Element Database (DM-SED) compilation. This paper details sampling in the Phase 2 dataset with respect to age, geography, lithology, and other geological characteristics, documents access via our search website and API, discusses possible issues and/or biases in the dataset that could impact analyses, describes plans for governance and stewardship of data from Indigenous lands, and serves as the citable reference paper for the data release.

Chemical Geology

SUTRA— A code for simulation of saturated-unsaturated, variable-density groundwater flow with solute or energy transport—Documentation of the version 4.0 enhancements—Freeze-thaw capability, saturation and relative-permeability relations, spatially varying properties, and enhanced budget and velocity outputs

Version 4.0 of the Saturated-Unsaturated Transport (SUTRA) software code provides the capability to simulate the freezing and thawing of groundwater during energy transport simulations under saturated and unsaturated conditions. In addition to the types of hydrogeologic processes that SUTRA has been able to simulate in the past, this version can be used to study the effects of the freeze-thaw process on the flow and energy dynamics of hydrogeologic systems. The freeze-thaw simulation capability accounts for the latent heat of fusion and allows thermal property values to vary with changing total-water saturation, liquid-water saturation, and ice saturation. It allows the effective permeability of the porous medium to change as a result of freezing and thawing. This version also provides several user-selectable relations for the dependence of total-water saturation on fluid pressure, the dependence of liquid-water saturation on temperature during freezing and thawing, and the dependence of relative permeability on liquid saturation, as well as three user-selectable formulae for defining the bulk thermal conductivity of a mixture of solid grains, liquid water, ice, and air. For unsaturated simulations without freezing, the selectable total-water saturation relations eliminate the need for the user to program these and their associated relative-permeability functions, as had been required in previous SUTRA versions. Optional nonlinear dependence of fluid density on temperature, which covers the range from supercooled (about −50 degrees Celsius) to superheated (about 400 degrees Celsius), is also provided. Additionally, this version makes it possible to spatially vary parameters that, in previous versions of SUTRA, were required to be spatially uniform: solid-matrix properties, adsorption parameters, and parameters for production of solute mass or energy. Spatial variation is also allowed for the newly included freeze-thaw process parameters. Additional enhancements provide (1) output of water-mass and energy budgets that include values of all component terms in the governing balance equations, and (2) output of Darcy velocities (fluid fluxes), in addition to the velocity output provided by previous SUTRA versions. These enhanced outputs allow fuller interpretation of simulation results, especially for freeze-thaw phenomena. The set of processes simulated by this version of SUTRA are useful for studying a wide range of hydrogeologic system types, conditions, and questions. For cryohydrogeologic simulations, however, this version of the code is limited in that (1) it does not simulate thermomechanical effects of freeze-thaw, (2) pressure changes due to water density change during freezing are neglected, (3) ice saturation cannot exceed the initial porosity of the simulated medium, and (4) cryosuction, the migration of liquid water toward freezing fronts, is neglected. Furthermore, this version does not account for air flow or for water vaporization and sublimation under unsaturated conditions.

Techniques and Methods

The geology of Canadian potash: A critical mineral for feeding the world

Potash, potassium-bearing water-soluble salt, is the primary global economic source of potassium. Potash is recognized as a critical mineral in Canada as it is the largest source of potassium used in fertilizers. It is essential for global agricultural productivity and food security. Canada is the world’s largest potash exporter with vast deposits in the widely mined Prairie Evaporite of Saskatchewan, which formed in the epicontinental Elk Point Basin during the Middle Devonian. Potash is also found in the Windsor Group of Atlantic Canada where it formed in a series of tectonically active basins during the Mississippian that have undergone substantial post-depositional subsurface alteration and deformation. Potash deposits were mined in New Brunswick up until 2016. Both deposits are salt giants, recording times in the geologic record of extensive and long-lasting evaporite genesis under arid conditions in restricted seas. This paper reviews the geological and economic significance of Canadian potash, including (1) the genesis of each deposit, (2) diagenetic, erosional, and tectonic modification, and (3) exploration and mining in each basin. Underdeveloped regions, possible undiscovered resources, environmental considerations, and the importance of sustainable practices in light of climate change and socioeconomic risks are also addressed.

Facets

Aeromagnetic and magnetotelluric imaging of west-central Idaho and the Stibnite-Yellow Pine mining district: A regional to district perspective

Aeromagnetic and magnetotelluric (MT) data are used to better understand the geology and mineral resources near the Stibnite-Yellow Pine mining district in central Idaho. The reduced-to-pole (RTP) transformation of regional-scale aeromagnetic data shows that allochthonous island-arc rocks west of the Salmon River suture are significantly more magnetic than the Laurentian continental rocks east of the suture and that the granitoids of the Idaho batholith have moderate to low magnetization in both early, metaluminous, and late, peraluminous phases. Application of tilt derivative to aeromagnetic data highlights major crustal-scale structures. The 5-km upward continued magnetic data indicate island-arc rocks have deep magnetic sources. The 110-km-long MT profile images resistivity structure to depths around 30 km. At shallow depths, resistivity corresponds to mapped geologic units, with moderate resistivities underlying volcanic and roof-pendant metasedimentary rocks and moderate to high resistivities occurring beneath the Idaho batholith. Crustal-scale moderate resistivities beneath the suture image the results of tectonomagmatic processes that accompanied suturing and translating allochthonous terranes. Low resistivity values beneath and fringing the batholith are derived from metasedimentary rocks that may have served as a melt source and reductant during melt generation and provided metals during later ore formation. In the Stibnite-Yellow Pine mining district, a high-resolution aeromagnetic compilation is shown to correlate with mapped lithologies and mineral deposit-related structures. The RTP transform distinguishes magnetic and nonmagnetic granitoid phases of the Idaho batholith. The tilt derivative highlights metasedimentary rocks, some of which are favorable ore hosts. The Meadow Creek fault hosts the Stibnite and Hangar Flats deposits and is imaged as a magnetic low due to hydrothermal alteration. Reconstructions of magnetic anomaly offsets and orebodies indicate around 3 km of post-95 Ma dextral separation, with some or all of the offset inferred to postdate the main Au mineralization episode (61–66 Ma).

Idaho

Geochemical, mineralogical, and isotopic evidence for multi-stage genesis of the Hicks Dome REE + Y-HFSE-fluorite deposit, Illinois, USA

Hicks Dome hosts breccias enriched in rare earth elements (REE), Y, Th, F, Ba, Ti, Nb, and Be, alongside spatially associated lamprophyre dikes (ca. 271 Ma). Hicks Dome is located within the Illinois–Kentucky Fluorspar District, which hosts fluorite, Pb–Zn, and barite resources. This study investigates the genetic relationships between Hicks Dome mineralization in breccias, alkaline magmatism, and Illinois–Kentucky Fluorspar District mineralization. Lamprophyre dikes are light REE–enriched with chondrite-normalized abundances decreasing from La to Lu. The Host Breccia exhibits middle and heavy REE–enriched patterns that mirror those of the principal REE–Th host minerals, including fluorapatite, xenotime, and thorite. Textural evidence suggests recrystallization of phosphates, sulfates, and Ti–Nb oxides in the Host Breccia. U–Pb geochronology constrains multiple mineralizing events, with ages of 277 ± 18 Ma from low-Th apatite interpreted as main-stage mineralization, and 121.6 ± 9.7 Ma from high-Th apatite indicating later overprinting. O–H–C stable isotope data provide evidence for multiple stages of fluid-rock interaction and fluid mixing: (1) early magmatic fluids dissolved limestone country rock, (2) mixing between magmatic fluids and basinal brines led to main-stage mineralization in the Host Breccia, and (3) late-stage mineralization occurred following mixing of meteoric water and basinal brine. These results indicate that heavy REEs, high field strength elements, and fluorine precipitated proximal to its alkaline magmatic source because of fluid–rock interactions and fluid mixing. Subsequent fluid mixing drove late-stage recrystallization and additional fluorite formation, a process that may be similar to mineralization in the Illinois-Kentucky Fluorspar District.

Illinois

Uranium—Deposits, production and resources, market dynamics, and supply chain risks

Introduction Interest in nuclear power for the generation of electricity has risen with the increase in the need for more diverse baseload power, enhanced energy security, and the development of new technologies, such as small modular reactors (SMRs), which could provide power for remote areas, industrial applications, and artificial intelligence (AI) data centers. In 2024, the U.S. Department of Energy received $2.7 billion in congressional funding to bolster the domestic uranium production and nuclear fuel supply chain and address reliance on imports from foreign suppliers. In 2025, the U.S. Government issued several Executive and Secretary’s orders aimed at revitalizing the U.S. nuclear sector. If SMRs are to be as widely deployed in the United States and worldwide as envisioned, demand for uranium (nuclear reactor fuel) will likely increase. After the Fukushima nuclear accident in 2011, the market spot price of uranium began a decline, followed by a decrease in U.S. and global uranium exploration and mine development expenditures that led to a uranium supply deficit until 2020, when prices started to recover, prompting a resurgence in uranium exploration and development. In January of 2024, the uranium spot price rose to a 17-year high $106 (U.S. dollars) per pound of U3O8 (triuranium oxide, commonly known as “yellowcake”), which is expected to increase uranium exploration, mine development, and uranium production domestically and worldwide.

Fact Sheet

Reduction of red bed sedimentary rocks in connection with energy metal ore formation: A case study from the Sinbad seep, Mesa County, Colorado

The Paradox Basin’s Sinbad seep is a modern analog for ancient bleaching of red bed sediments by introduced alkaline, reducing brines. This bleaching, involving reductive alteration of former red beds, is essential ground preparation that enables the altered rocks to trap Cu, U, and V from later oxidized fluids, forming ore deposits. Study of Sinbad thus offers insights into these metallic mineralization processes in the Paradox and other sedimentary basins. The Sinbad seep occurs where shallow groundwater interacts with organic-rich petroleum source rocks, flows up a fault, and discharges into Salt Creek. Ratios of Na/Cl, Na/Br, and Cl/Br, plus high sulfate concentrations, indicate that the salinity of the seep water originated from dissolution of halite and gypsum during topographically driven flow of meteoric water across a diapir of the Pennsylvanian Paradox Formation, rather than from deep basinal brines. In contact with the organic-rich shales of the Paradox, these SO 4 -rich waters become reduced through bacterial reduction, producing H 2 S. The waters react with red beds of the Permian Cutler Formation, causing pervasive bleaching. The bleaching at Sinbad is characterized by iron-conservative reduction of ferric iron in diagenetic hematite and detrital ilmenite and magnetite to Fe sulfides. The ferrous iron is retained in these sulfides likely as sorbed Fe. Associated alteration includes precipitation of quartz and feldspar overgrowths, partial dissolution of detrital quartz and feldspar caused by pressure solution, formation of clay and authigenic rutile, and precipitation of carbonate and gypsum. The Fe sulfides rapidly degenerate to a mixture of jarosite and iron oxides on weathering at the surface. Among the major-oxide elements and most trace elements, there is no statistical difference between unbleached and bleached samples. The exceptions are uranium and sulfur, which are somewhat greater in bleached samples. Fission track radiography illuminates that uranium is preferentially concentrated in iron oxide cements, iron sorbed into detrital clasts, and finely disseminated iron oxide in illite cement in bleached samples. A leaching experiment suggests that uranium may be more easily available for mobilization from rocks that have undergone bleaching alteration, making them potential U sources. In addition, bleached rocks form effective traps for U, V, and some Cu mineralization.

Colorado

Geologic map of the Greater Antilles and Virgin Islands

Introduction The geologic map of the Greater Antilles and Virgin Islands is a compilation of information from the literature, integrated to provide a seamless geologic map of the region. This map was prepared to serve as a base map for a mineral resource assessment of the region. Several small-scale regional geologic maps of the region have been prepared in the past. This report supersedes an earlier version of the geologic map of the Greater Antilles and the Virgin Islands that was released as U.S. Geological Survey (USGS) Open-File Report 2019–1036. For this report, the regional geologic overview shown on sheet 1 covers Cuba; the island of Hispaniola, which includes Haiti and Dominican Republic; Jamaica; the Cayman Islands; Puerto Rico; and the U.S. and British Virgin Islands. Sheet 2 shows the geology of Cuba and Cayman Islands, sheet 3 the geology of Jamaica, sheet 4 the geology of Hispaniola, and sheet 5 the geology of Puerto Rico and Virgin Islands. Accompanying the maps are three tables: table 1 lists the map units (in alphabetical order by map-unit label), their ages, and the countries or territories in which they can be found. These are listed in alphabetical order for ease in locating unit names from the symbols on the maps. Table 2 is a list of sources for the geologic map compilation of Puerto Rico. Table 3 shows formations in the Devil’s Race Course Group of Jamaica.

Greater Antilles, Virgin Islands

On-demand global Landsat evapotranspiration product: Development, evaluation, and dissemination

Global actual evapotranspiration (ET) is one of the essential climate variables needed to understand and manage the relationships among food, energy, and water resources. The U.S. Geological Survey Earth Resources Observation and Science (EROS) Center launched a provisional ET product in 2020, offering on-demand, field-scale global coverage derived from Landsat data through the EROS Science Processing Architecture (ESPA) platform. The ESPA interface provides ET data for cloud-free Landsat overpasses starting in 1982 with Landsat 4 through the current Landsat 9. The ET data are delivered as a Provisional Level-3 Science product created using the Operational Simplified Surface Energy Balance (SSEBop) model. Landsat surface temperature and reference ET are the main model drivers along with vegetation index and net radiation for model parameterization. A large volume of Landsat-based ET orders (e.g., over 1,200,000 images from June 2020 through December 2025) around the world indicate increasing awareness and application of the ET data. The ESPA platform enables land and water resource managers and researchers to access a first-order ET product without requiring advanced knowledge of remote sensing technology or evapotranspiration modeling. We present the methodology and workflow of the on-demand Landsat ET product and its performance evaluations over diverse hydro-climatic settings. The product can help estimate field-scale consumptive water use and thus quickly and consistently assess historical water use, allocation, and budget to inform water management under changing environments. Future ET data aggregated to monthly and seasonal time scales are expected to enhance integration with decision-making tools and procedures.

Remote Sensing of Environment

Anatectic origin of Mississippian spodumene-bearing pegmatites in western Maine during orogenic plateau collapse

Spodumene pegmatites are an important lithium source, but the processes and tectonic settings in which they form are poorly understood. The Rumford pegmatite district surrounding Plumbago Mountain, western Maine, is host to numerous spodumene pegmatites, including the Plumbago North pegmatite (a world-class spodumene resource). Competing petrogenetic models for these spodumene pegmatites include (1) highly fractionated melts of the Mooselookmeguntic igneous complex and (2) anatexis. We tested these hypotheses by constraining the geologic, magmatic, metamorphic, and tectonic history of the Plumbago Mountain area with detailed geologic mapping and U-(Th)-Pb geochronology. The Silurian Rangeley Formation records initial isoclinal folding prior to, and contact-related metamorphism synchronous with, the intrusion of the 417 ± 4 Ma Plumbago Mountain pluton. Peak amphibolite facies metamorphism and crustal melting occurred during the ca. 410 to 400 Ma Acadian orogeny. Pulsed emplacement of the Mooselookmeguntic igneous complex occurred between ca. 389 and 356 Ma. Cassiterite U-Pb dates of spodumene pegmatites (333–327 Ma) are ≥23 m.y. younger than nearby granitic plutons, strongly arguing against the fractional crystallization model. Metamorphic monazite and xenotime (346–328 Ma) and 330 to 308 Ma 40 Ar/ 39 Ar hornblende dates indicate metamorphism coeval with spodumene pegmatite emplacement, supporting anatectic models. Reheating, anatexis, and spodumene pegmatite emplacement occurred during collapse of the 380 to 330 Ma Acadian orogenic plateau. Lithium enrichment may be linked to one or more stages of partial melting of metasedimentary and plutonic rocks during the formation, tenure, and collapse of the Acadian altiplano and emphasizes the role of anatexis in producing spodumene pegmatites of economic significance.

Maine