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USGS2014

Mineral resource of the month: Iron and steel

Iron is one of the most abundant elements on Earth, but it does not occur in nature in a useful metallic form. Although ancient people may have recovered some iron from meteorites, it wasn’t until smelting was invented that iron metal could be derived from iron oxides. After the beginning of the Iron Age in about 1200 B.C., knowledge of iron- and steelmaking spread from the ancient Middle East through Greece to the Roman Empire, then to Europe and, in the early 17th century, to North America. The first successful furnace in North America began operating in 1646 in what is now Saugus, Mass. Introduction of the Bessemer converter in the mid-19th century made the modern steel age possible. Pig iron is a high-carbon alloy made by smelting iron ore in a blast furnace with carbonaceous material, typically coke, as a reducing agent. Limestone is added to the iron ore-coke charge as a fluxing agent to remove impurities. Steel is produced from pig iron by removing some of the carbon in a basic oxygen converter and adding several alloying elements, such as manganese, chromium, copper, nickel, titanium, molybdenum, tungsten and vanadium. Steel is also made by recycling ferrous scrap in an electric arc furnace. There are many grades of steel, but the three major types of steel are carbon, alloy and stainless. About 93 percent of the steel made in the United States is carbon steel, which contains a maximum 2 percent carbon. Applications are found in appliances, construction, shipbuilding, containers and packaging, as well as in the automotive, machinery and equipment industries. Alloy steel, about 5 percent of annual production, contains as much as 4 percent alloying elements. Special applications for alloy steel include use in machined parts and tool fabrication. Stainless steel, which accounts for about 2 percent of annual steel production, is formed by adding chromium and usually nickel to steel to make it highly corrosion-resistant. Since 2008, steelmaking capacity has greatly exceeded apparent steel consumption, primarily as a result of China’s rapid economic expansion and rapidly increasing capacity. This has resulted in an influx of steel products into the United States and other steelmaking countries that already have excess capacity. Demand by China’s steelmakers has also driven unprecedented increases in the prices of iron ore and metallurgical coal. In the short term, steelmaking capacity, globally and especially in China, is expected to continue to exceed steel consumption, with steel prices and production costs remaining stable.

Earth↗

USGS2000

Stratigraphic and structural evolution of the Selenga Delta Accommodation Zone, Lake Baikal Rift, Siberia

Seismic reflection profiles from the Lake Baikal Rift reveal extensive details about the sediment thickness, structural geometry and history of extensional deformation and syn-rift sedimentation in this classic continental rift. The Selenga River is the largest single source of terrigenous input into Lake Baikal, and its large delta sits astride the major accommodation zone between the Central and South basins of the lake. Incorporating one of the world's largest lacustrine deltas, this depositional system is a classic example of the influence of rift basin structural segmentation on a major continental drainage. More than 3700 km of deep basin-scale multi-channel seismic reflection (MCS) data were acquired during the 1989 Russian and the 1992 Russian–American field programs. The seismic data image most of the sedimentary section, including pre-rift basement in several localities. The MCS data reveal that the broad bathymetric saddle between these two major half-graben basins is underlain by a complex of severely deformed basement blocks, and is not simply a consequence of long-term deltaic deposition. Maximum sediment thickness is estimated to be more than 9 km in some areas around the Selenga Delta. Detailed stratigraphic analyses of the Selenga area MCS data suggest that modes of deposition have shifted markedly during the history of the delta. The present mode of gravity- and mass-flow sedimentation that dominates the northern and southern parts of the modern delta, as well as the pronounced bathymetric relief in the area, are relatively recent developments in the history of the Lake Baikal Rift. Several episodes of major delta progradation, each extending far across the modern rift, can be documented in the MCS data. The stratigraphic framework defined by these prograding deltaic sequences can be used to constrain the structural as well as depositional evolution of this part of the Baikal Rift. An age model has been established for this stratigraphy, by tying the delta sequences to the site of the Baikal Drilling Project 1993 Drill Hole. Although the drill hole is only 100 m deep, and the base of the cores is only ∼670 ka in age, ages were extrapolated to deeper stratigraphic intervals using the Reflection-Seismic-Radiocarbon method of Cohen et al. (1993). The deep prograding delta sequences now observed in the MCS data probably formed in response to major fluctuations in sediment supply, rather than in response to shifts in lake level. This stratigraphic framework and age model suggest that the deep delta packages developed at intervals of approximately 400 ka and may have formed as a consequence of climate changes affiliated with the northern hemisphere glaciations. The stratigraphic analysis also suggests that the Selenga Basin and Syncline developed as a distinct depocentre only during the past ∼2–3 Ma.

Lake Baikal Rift↗

USGS2006

Distributary channels, sand lobes, and mesotopography of Navy Submarine Fan, California Borderland, with applications to ancient fan sediments

The deep-tow instrument package of Scripps Institution of Oceanography provides a unique opportunity to delineate small-scale features of a size comparable to those features usually described from ancient deep-sea fan deposits. On Navy Fan, the deep-tow side-scanning sonar readily detected steep channel walls and steps and terraces within channels. The most striking features observed in side-scan are large crescentic depressions commonly occurring in groups. These appear to be large scours or flutes carved by turbidity currents. Four distinct acoustic facies were mapped on the basis of qualitative assessment of reflectivity of 4 kHz reflection profiles. There is a distinct increase in depth of acoustic penetration, number of sub-bottom reflectors, and reflector continuity from the upper fan-valley to the lower fan. These changes are accompanied by a decrease in surface relief. Navy Fan is made up of three active sectors. The active upper fan is dominated by a single channel with prominent levees that decrease in height downstream. The active mid-fan region or suprafan is where sand is deposited. Well defined distributary channels with steps, terraces, and other mesotopography terminate in depositional lobes. Interchannel areas are rough, containing giant scours as well as other relief. The active lower fan accumulates mud and silt and is without resolvable surface morphology. The morphological features seen on Navy Fan other than levees, interchannel areas, and lobes are principally erosional. The distributary channels are up to 0.5 km wide and 5–15 m deep. Such features, because of their large size and low relief, are rarely completely exposed or easily detectable in ancient rock sequences. Some flute-shaped scours are larger than channels in cross section but many are 5-30 m across and 1-2 m deep. If observed in ancient rocks transverse to palaeo-current direction, they would perhaps be indistinguishable from channels. Surface sediment distribution combined with fan morphology can be used to relate modern sediments to facies models for ancient fan sediments. Gravel and sand occur in the upper valley, massive sand beds in the mid-fan distributary channels, classical complete Bouma sequences on depositional lobes, incomplete Bouma sequences (lacking division a) on the lower mid-fan, and Bouma sequence with lenticular shape or other limited extent on mid-fan interchannel areas and on levees.

California↗

USGS2022

Tungsten skarn potential of the Yukon-Tanana Upland, eastern Alaska, USA—A mineral resource assessment

Tungsten (W) is used in a variety of industrial and technological applications and has been identified as a critical mineral for the United States, India, the European Union, and other countries. These countries rely on W imports mostly from China, which leaves them vulnerable to supply disruption. Consequently, the U.S. government has a current initiative to understand domestic resource potential. The eastern Alaska portion of the Yukon-Tanana Upland (YTU), is prospective for W skarn deposits, the major source of global W supply. The regional geology consists of juxtaposed Paleozoic lithotectonic packages that were reaccreted to North America in the Mesozoic . Multiple subsequent episodes of arc-related magmatism intruded the lithotectonic packages, accompanied by W skarn formation mostly associated with 100–90 Ma intrusions; major W skarn deposits in Canada are part of the same metallogenic event (e.g., Mactung, Cantung). In this paper, we present an assessment for undiscovered W skarn resources for parts of the lesser-explored western (Alaskan) portion of the YTU. We used GIS proximity analysis to map the intersection of pluton and carbonate-bearing rocks to define three permissive tracts for W skarn deposits. The permissive tracts were qualitatively assessed by mineral potential mapping using region-wide sediment geochemistry and mineral concentrate datasets. This analysis showed that much of the western YTU has high potential for undiscovered W skarn deposits, whereas the eastern and southern YTU had only isolated areas of medium to high potential. Historical production and the quality of the geochemistry data of the western YTU tract (ca. 9200 km 2 ) permitted a quantitative assessment of undiscovered W resources. Probabilistic estimates by a panel of 20 experts predicted a 70% chance of one to three undiscovered W skarn deposits in the western YTU tract. The rationale for favorability employed by the expert panel included favorable lithology, previous production, clustering of previously mined deposits, W placers in the area, lack of recent exploration, pan concentrates containing W minerals, and W geochemical anomalies. Estimates were combined with a global grade and tonnage model for W skarns in a Monte Carlo simulation and provided a median estimate of undiscovered resources of 94 kt WO 3 . If the undiscovered W skarn deposits are located close to infrastructure (e.g., near Fairbanks, or close to roads and/or power grid), application of an economic filter indicates that the median total economically recoverable WO 3 is 63 kt with a net present value (NPV) of $330 million USD (2008 dollars). Whereas if deposits are far from infrastructure, median recoverable WO 3 is only 30 kt and the NPV is $44 million. Our models for contained WO 3 resources and NPV estimates for the western YTU tract are considerably lower than the known resources in skarns in adjacent areas in Canada. Estimates for the western YTU are also lower than preliminary estimates for undiscovered W skarn deposits in areas of the western conterminous United States. We speculate that lower permeability and continuity of favorable carbonate rock horizons in the relatively higher-grade metamorphic country rocks in the Alaska portion of the YTU may explain some of the differences in prospectivity. More detailed geologic mapping, modern geochemistry, and geophysical surveys are needed to refine the resource potential of the whole YTU. Regardless, quantitative mineral resource assessment provides a useful tool for making first-order regional estimates of undiscovered resources, identifying target areas for new data acquisition, and guiding research on the fundamental controls of district-scale metallogenic endowments.

Alaska↗

USGS1998

Experimental investigations regarding the use of sand as an inhibitor of air convection in deep seismic boreholes

Tilt has been the nemesis of horizontal long period seismology since its inception. Modern horizontal long period seismometers with their long natural periods are incredibly sensitive to tilt. They can sense tilts smaller than 10 -11 radians. To most readers, this is just a very very small number, so we will begin with an example, which should help to illustrate just how small 10 -11 radians is. Suppose we have an absolutely rigid rod which is approximately 4170 kilometers long; this just happens to be the Rand McNally map scaled crow flight distance between Los Angeles and Boston. Tilting this rod 10 -11 radians corresponds to raising one end of the rod 0.0000417 meters. Alas, this is just another very very small number! However, this corresponds to slipping a little less than one third a sheet of ordinary copying paper under one end of this perfectly rigid rod. To clarify, we mean, take a sheet of paper just like the paper this report is printed on and split it a little less than one third in the thickness direction, then put it under the end of the 4170 kilometer long rod! This will tilt the rod 10 -11 radians. Real world seismometers are nowhere near the length of this rod. A KS-54000 is about two meters long. Tilting a rod only two meters long 10~n radians corresponds to moving one end of this rod a mere 0.00000000002 meters or 0.02 millimicrons. As one of the authors old math teachers used to say, "That's PDS" (PDS = Pretty Damn Small). Unfortunately, the long period seismologist does not have the luxury of ignoring PDS numbers when it suits him as the mathematician frequently does. He must live in the real world in which tilts this small create severe contamination of long period seismic data. At periods longer than 20 seconds, tilt noise contaminates the long period data from all instruments installed on or near the earth's surface. Many years of experimentation revealed that installing the sensors at depth in deep mines drastically reduced the level of tilt noise in long period data. However, low levels of tilt noise persisted even at great depth; this noise was caused by air convection in the vault in which the sensors were installed. Over the years, methods were developed to control the air motion with mechanical barriers (boxes) around the sensors and by stratifying (creating a situation in which the air temperature increases with height) the air in the vault near the seismometer. These methods decreased tilt noise in deep mines to very low levels. However, deep mines, that are economically and environmentally suitable and accessible to seismology, are not plentiful and are not evenly distributed over the earth's surface. Therefore, the borehole deployable Teledyne Geotech KS-36000 and later the KS-54000 sensor systems were developed to fulfill the need for instruments that could be installed at depth wherever high quality long period data was desired. Early in the development program, it became evident to the Teledyne Geotech personnel that air convection within the borehole was going to be a significant problem in KS deployments. Experimental and theoretical investigations conducted by Teledyne Geotech (see Douze and Sherwin, 1975, and Sherwin and Cook, 1976) produced a list of recommended installation procedures for reducing the effects of air convection. These procedures consisted of wrapping the sensor in a relatively thin layer of foam insulation, filling the free space volume in the vicinity of the centralizer-bail assembly with foam insulation, and the installation of styrofoam hole plugs immediately above the cable strain relief assembly at the top of the sensor package and at the top of the borehole. This technology has performed quite satisfactorily for over 20 years but evidence of tilt noise in the system output has persisted throughout the KS deployment program (the evidence was that the horizontal components were usually noisier than the vertical components) even in deep boreholes. Some deep borehole sites have been plagued by quite high levels of horizontal noise. Therefore, there has been a definite need for a new technique for controlling low level tilt noise in deep boreholes and the use of sand has been under consideration for several years. Figure 1 contains conceptual illustrations of both the conventional holelock installed KS sensor system and the same sensor installed in sand. This figure demonstrates the major differences between the two installation methods. The curved arrows in the borehole on the left in the figure denote possible air convection cells which are believed to be the source of tilt noise in some of the conventional installations. This air motion is eliminated in a sand installation by filling most of the free air volume surrounding the seismometer with sand as shown in the right hand portion of the figure. The sand actually performs two functions; it prevents air motion and provides a remarkably ridgid clamping of the seismometer in the borehole. This report presents the results of quantitative experimental investigations into the effectiveness of controlling low level air convection in seismic borehole installations with sand. The main body of the experimental effort consisted of installing two KS-540001 sensor systems in closely spaced shallow boreholes, allowing the sensors to reach equilibrium operation, and then pouring sand into both boreholes to observe any changes caused by pouring sand into the holes. The hypothesis of the experiment was that the sand would fill up the entire free air volume between the sensor package and the borehole walls thereby preventing movement of the air in the vicinity of the sensor package. The validity of this hypothesis had been qualitatively proven by earlier experiments at ASL and by the sand installations at the IRIS/ASL stations ANMO in 1995 and COLA in 1996. This experiment documents the degree of improved noise levels to be expected if KS instruments are installed in sand instead of in the conventional manner.

Open-File Report↗