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Spectrographic and chemical analyses of geochemical samples from the McCarthy Quadrangle, Alaska

As an integral part of the Alaskan Mineral Resource Assessment Program, a geochemical reconnaissance survey was conducted in the McCarthy quadrangle during the summer of 1974. The investigation consisted of geochemical sampling, multielement chemical and spectrographic analyses, compilation of new and existing geochemical data, statistical evaluation of the total data set, and the generation of element distribution and abundance maps. The purpose of the survey was to define areas in the quadrangle that contain anomalous concentrations of metallic and nonmetallic elements. These studies are fundamental to a comprehensive evaluation of the mineral resource potential of the area and to assist in the discovery of additional economic mineral deposits. The first-large scale geochemical sampling and analytical surveys were initiated in the McCarthy quadrangle in the early 1960's with the inception of the Wrangell Mountain project by the U.S. Geological Survey. Since that time, levels of activity in geochemical sampling in the quadrangle have fluctuated. Each year, many geochemical samples have been collected concomitantly with geologic mapping, and was culminated under the Alaskan Minerals Resource Assessment Program 1974.

Alaska↗

Slides showing aeromagnetic and gravity data for regional mineral exploration in Colorado, New Mexico, and Arizona

Examples of aeromagnetic and gravity data over 1? x 2? areas are presented for regions near the Cripple Creek mining area, Colorado, and the Lordsburg-Tyrone-Silver City mining areas, southern New Mexico and Arizona. These data indicate broad crustal structures and compositional variations that are marked by magnetization and density contrasts. The focus is on anomalies that may signal large-dimension controlling structures for the emplacement of economic mineral deposits. An example is a continuous, quasi-linear, north-trending gradient in both gravity and magnetic data located west of Cripple Creek area along long. 105? 30? W. This trend correlates with two mineral deposits of the Southern Rocky Mountains Front Range. It also correlates in part with an area of volcanic rock and with a mapped fault complex (Elkhorn-Currant Creek-Else-Westcliffe). The trend is interpreted to indicate a continuous crustal fault system, although exposures of this system are discontinuous between areas of alluvium and volcanic-rock cover. Similar geophysical trends exist in the Silver City to Tyrone area, where northeast-and northwest-trending anomalies appear to be marked by intrusion and mineralization. In this area, northwest-trending alluvial basins favor the use of geophysics to infer economically accessible but hidden bedrock whose association with exposed mineralization seems possible. An example of an inferred broad and relatively shallow, but hidden bedrock complex in association with more areally-limited mineralization is the Victorio Mountains area about 34 mi (55 km) south-southeast of Tyrone, New Mexico. The mineralization is within faulted sediments whose outcrop covers a small portion of the geophysical anomaly-complex.

Open-File Report↗

Description of slides showing aeromagnetic and gravity data for regional mineral exploration in Colorado, New Mexico, and Arizona

Examples of aeromagnetic and gravity data over 1? x 2? areas are presented for regions near the Cripple Creek mining area, Colorado, and the Lordsburg-Tyrone-Silver City mining areas, southern New Mexico and Arizona. These data indicate broad crustal structures and compositional variations that are marked by magnetization and density contrasts. The focus is on anomalies that may signal large-dimension controlling structures for the emplacement of economic mineral deposits. An example is a continuous, quasi-linear, north-trending gradient in both gravity and magnetic data located west of Cripple Creek area along long. 105? 30? W. This trend correlates with two mineral deposits of the Southern Rocky Mountains Front Range. It also correlates in part with an area of volcanic rock and with a mapped fault complex (Elkhorn-Currant Creek-Else-Westcliffe). The trend is interpreted to indicate a continuous crustal fault-system, although exposures of this system are discontinuous between areas of alluvium and volcanic-rock cover. Similar geophysical trends exist in the Silver City to Tyrone area, where northeast-and northwest-trending anomalies appear to be marked by intrusion and mineralization. In this area, northwest-trending alluvial basins favor the use of geophysics to infer economically accessible but hidden bedrock whose association with exposed mineralization seems possible. An example of an inferred broad and relatively shallow, but hidden bedrock complex in association with more areally-limited mineralization is the Victorio Mountains area about 34 mi (55 km) south-southeast of Tyrone, New Mexico. The mineralization is within faulted sediments whose outcrop covers a small portion of the geophysical anomaly-complex.

Arizona, Colorado, New Mexico↗

Peralkaline and peraluminous granites and related mineral deposits of the Arabian Shield, Kingdom of Saudi Arabia

In the Precambrian Arabian Shield, granitoid plutonic rocks are widespread and range in age from 800 to 550 Ma old; but the mineral-resource potential associated with these plutonic rocks is restricted mainly to the younger, postorogenic granites. Two granite types of current economic interest are zirconium- niobium-enriched per alkaline granites and tin-tungsten-enriched peraluminous granites. Both types are highly evolved, are enriched in lithium, rubidium, and fluorine, and have distinctive mineralogy, textures, and chemistry. The zirconium-niobium-enriched granites are related to medium- to large-sized plutons and complexes of peralkaline granite, and the tin-tungsten-enriched granites are related to medium-sized plutons of biotite or biotite-muscovite granite. Existing geochemical and geologic data for many parts of the Arabian Shield were compiled as a basis for evaluating the resource potential of the granites of the Shield. Commodities associated with granites that have potential for economic mineral deposits include tin, tungsten, molybdenum, beryllium, niobium, tantalum, zirconium, uranium, thorium, rare-earth elements, and fluorite. Prospecting methods useful in discriminating those granites having significant economic potential include reconnaissance geologic mapping, petrographic and mineralogic studies, geochemical sampling of rock and wadi sediment, and radiometric surveying.

Open-File Report↗

Integrated geophysical imaging of a concealed mineral deposit: a case study of the world-class Pebble porphyry deposit in southwestern Alaska

We combined aeromagnetic, induced polarization, magnetotelluric, and gravity surveys as well as drillhole geologic, alteration, magnetic susceptibility, and density data for exploration and characterization of the Cu-Au-Mo Pebble porphyry deposit. This undeveloped deposit is almost completely concealed by postmineralization sedimentary and volcanic rocks, presenting an exploration challenge. Individual geophysical methods primarily assist regional characterization. Positive chargeability and conductivity anomalies are observed over a broad region surrounding the deposit, likely representing sulfide minerals that accumulated during multiple stages of hydrothermal alteration. The mineralized area occupies only a small part of the chargeability anomaly because sulfide precipitation was not unique to the deposit, and mafic rocks also exhibit strong chargeability. Conductivity anomalies similarly reflect widespread sulfides as well as water-saturated glacial sediments. Mineralogical and magnetic susceptibility data indicate magnetite destruction primarily within the Cu-Au-Mo mineralized area. The magnetic field does not show a corresponding anomaly low but the analytic signal does in areas where the deposit is not covered by postmineralization igneous rocks. The analytic signal shows similar lows over sedimentary rocks outside of the mineralized area, however, and cannot uniquely distinguish the deposit. We find that the intersection of positive chargeability anomalies with analytic signal lows, indicating elevated sulfide concentrations but low magnetite at shallow depths, roughly delineates the deposit where it is covered only by glacial sediments. Neither chargeability highs nor analytic signal lows are present where the deposit is covered by several hundred meters of sedimentary and volcanic rocks, but a 3D resistivity model derived from magnetotelluric data shows a corresponding zone of higher conductivity. Gravity data highlight geologic features within the deposit, including shallow diorite sills that locally contain higher-grade mineralization. The results thus show ways in which an integrated survey approach might be used to distinguish zones of potentially economic mineralization.

Alaska↗

Miocene magmatism in the Bodie Hills volcanic field, California and Nevada: A long-lived eruptive center in the southern segment of the ancestral Cascades arc

The Middle to Late Miocene Bodie Hills volcanic field is a >700 km 2 , long-lived (∼9 Ma) but episodic eruptive center in the southern segment of the ancestral Cascades arc north of Mono Lake (California, U.S.). It consists of ∼20 major eruptive units, including 4 trachyandesite stratovolcanoes emplaced along the margins of the field, and numerous, more centrally located silicic trachyandesite to rhyolite flow dome complexes. Bodie Hills volcanism was episodic with two peak periods of eruptive activity: an early period ca. 14.7–12.9 Ma that mostly formed trachyandesite stratovolcanoes and a later period between ca. 9.2 and 8.0 Ma dominated by large trachyandesite-dacite dome fields. A final period of small silicic dome emplacement occurred ca. 6 Ma. Aeromagnetic and gravity data suggest that many of the Miocene volcanoes have shallow plutonic roots that extend to depths ≥1–2 km below the surface, and much of the Bodie Hills may be underlain by low-density plutons presumably related to Miocene volcanism. Compositions of Bodie Hills volcanic rocks vary from ∼50 to 78 wt% SiO 2 , although rocks with <55 wt% SiO 2 are rare. They form a high-K calc-alkaline series with pronounced negative Ti-P-Nb-Ta anomalies and high Ba/Nb, Ba/Ta, and La/Nb typical of subduction-related continental margin arcs. Most Bodie Hills rocks are porphyritic, commonly containing 15–35 vol% phenocrysts of plagioclase, pyroxene, and hornblende ± biotite. The oldest eruptive units have the most mafic compositions, but volcanic rocks oscillated between mafic and intermediate to felsic compositions through time. Following a 2 Ma hiatus in volcanism, postsubduction rocks of the ca. 3.6–0.1 Ma, bimodal, high-K Aurora volcanic field erupted unconformably onto rocks of the Miocene Bodie Hills volcanic field. At the latitude of the Bodie Hills, subduction of the Farallon plate is inferred to have ended ca. 10 Ma, evolving to a transform plate margin. However, volcanism in the region continued until 8 Ma without an apparent change in rock composition or style of eruption. Equidimensional, polygenetic volcanoes and the absence of dike swarms suggest a low differential horizontal stress regime throughout the lifespan of the Bodie Hills volcanic field. However, kinematic data for veins and faults in mining districts suggest a change in the stress field from transtensional to extensional approximately coincident with the inferred cessation of subduction. Numerous hydrothermal systems were operative in the Bodie Hills during the Miocene. Several large systems caused alteration of volcaniclastic rocks in areas as large as 30 km 2 , but these altered rocks are mostly devoid of economic mineral concentrations. More structurally focused hydrothermal systems formed large epithermal Au-Ag vein deposits in the Bodie and Aurora mining districts. Economically important hydrothermal systems are temporally related to intermediate to silicic composition domes. Rock types, major and trace element compositions, petrographic characteristics, and volcanic features of the Bodie Hills volcanic field are similar to those of other large Miocene volcanic fields in the southern segment of the ancestral Cascade arc. Relative to other parts of the ancestral arc, especially north of Lake Tahoe in northeastern California, the scarcity of mafic rocks, relatively K-rich calc-alkaline compositions, and abundance of composite dome fields in the Bodie Hills may reflect thicker crust beneath the southern ancestral arc segment. Thicker crust may have inhibited direct ascent and eruption of mafic, mantle-derived magma, instead stalling its ascent in the lower or middle crust, thereby promoting differentiation to silicic compositions and development of porphyritic textures characteristic of the southern ancestral arc segment.

California, Nevada↗

Geology and lithogeochemistry of the Ren gold prospect, Elko County, Nevada - the role of rock sampling in exploration for deep Carlin-type deposits

The Ren gold prospect, Elko County, Nevada, is in the northern part of the Carlin trend, two kilometers northwest of the recently-discovered, high-grade Purple Vein deposit. The Ren area is underlain mainly by Paleozoic sedimentary rocks, consisting of limestone, calcareous siltstone, and mudstone of the eastern (carbonate) assemblage, overlain in thrust contact by chert, quartzite, and mudstone of the western (siliceous) assemblage. Cretaceous(?) granodiorite porphyry and hornblende porphyry dikes have intruded the sedimentary rocks along north-striking faults. Three stages of mineralization include a pre- or syntectonic base metal-barite assemblage, a middle stage of Ag- and Sb-rich jasperoid, and a late Au-rich stage responsible for the potentially economic mineralization at the prospect. The latter two stages of alteration and mineralization were focused along steep east-dipping faults and dikes, and the nearly flat-lying contact between lower massive limestone and laminated calcareous siltstone. Mineralization is present between 380 and 500 m below the surface. Alteration includes decalcification and weak silicification in siltstone, and formation of massive jasperoid in the upper part of the limestone unit. Alteration of dikes is mainly sericite-quartz-pyrite, with late pyrite-quartz-kaolinite.

Journal of Geochemical Exploration↗

Preliminary lead isotope investigations of brine from the Red Sea, Galena from the Kingdom of Saudi Arabia, and galena from United Arab Republic (Egypt)

The isotopic composition of lead in Red Sea chloride brine containing 0.5 ppm Pb is found to be similar to that of some Cenozoic ore leads such as galena at Rabigh in Saudi Arabia that may have formed during mineralization accompanying Tertiary rifting. Bir Ranga galena in Miocene sediments from United Arab Republic (Egypt) is also isotopically similar to lead in Red Sea brine. The chlorine brine must be considered a possible mineralizing fluid. Lead isotopes show promise for use in mineral prospect evaluation in that galena from Samrah is isotopically similar to that from Mahd adh Dhahab, which has been the only ore producer in Saudi Arabia since 1945. Drilling at Samrah does indicate a possible economic mineralization. The lead isotope data coupled with available geologic knowledge and geochronometry are used to tentatively divide the ore prospects of the Kingdom of Saudi Arabia into relative categories of mineralization age. Two Mesozoic and Cenozoic mineralizations are distinguished on the basis of a 207 Pb/ 204 Pb difference; an early Paleozoic mineralization grouping is outlined; and a late Precambrian mineralization period is suggested.

Earth and Planetary Science Letters↗

Mineral resource potential map of the Shining Rock Wilderness, Haywood County, North Carolina

The Shining Rock Wilderness is in the Blue Ridge Mountains of Haywood County, N. C., and is underlain by complexly folded, high-grade metamorphic rocks. These rocks contain a few small, subeconomic deposits of sheet muscovite mica that have a small potential for scrap mica. Quartz as a source of silica (SiO2) and gneiss and schist suitable for common building stone and crushed rock are the only identified economic mineral resources. Other minerals and rocks, including kaolin, soapstone, copper, corundum, and dunite, have been prospected or mined nearby, but either they do not occur or have no current economic potential in the wilderness. A possibility exists for the presence of natural gas at depths greater than 5,000 ft (1,500 m).

North Carolina↗

Modeling byproduct and coproduct mine production and mineral substitution using multidimensional supply curves: Application to the Cu-Co-Ni system and beyond

Rapid demand growth is expected for many metals used in the energy transition. Many of these metals are byproducts of other commodities. Byproduct production’s price response is tied to host mineral economics, complicating its supply dynamics. Moreover, many of these metals are used in applications where the material properties desired are difficult to substitute; effectively, limiting how quickly demand can adapt to changes in commodity price. Previous work has demonstrated the interconnectivity of jointly produced mineral commodities from the supply side, where the copper–cobalt–nickel system was used and demand was assumed independent across commodities. Studies to understand byproduct-coproduct market interconnectivity on the demand side are limited, while studies on the interconnectivity of supply and demand simultaneously are even more so. We propose a modification to the multicommodity supply curve method to enable inter-commodity effects on demand simultaneous with supply. In batteries, high cobaltprices may push consumers to transition to high-nickel chemistries, causing the nickel demand surface to decrease with nickel price but increase with cobaltprice, creating a two-dimensional demand surface. Below cross-price elasticities of 0.05, inter-commodity effects were found to be negligible, potentially permitting exclusion of these effects for many commodities. This additional demand curve complexity introduces potential computation challenges alongside the capacity to model many interrelated commodity systems such as rare earth elements, ferroalloys, country-oriented subsidies or restrictions, and bifurcated sustainable metals markets. By presenting the work done on multicommodity supply surfaces to date and potential new directions, this work aims to catalyze the next round of innovative approaches to modeling jointly produced commodities.

Conference Paper↗

Geochemical orientation for mineral exploration in the Hashemite Kingdom of Jordan

This report is a supplement to previous accounts of geochemical exploration conducted in the Hashemite Kingdom of Jordan by the Natural Resources Authority of the Royal Government of Jordan and the U.S. Geological Survey. The field work on which this report is based was sponsored by the U.S. Agency for International Development, U.S. Department of State. Procedures used in collecting various kinds of rocks, ores, slags, eluvial and alluvial sediments, heavy-mineral concentrates, and organic materials for use as geochemical sample media are summarized, as are the laboratory procedures followed for the analysis of these sample materials by semiquantitative spectrographic, atomic absorption, fluorometric, and X-ray diffraction methods. Geochemical evaluations of the possibilities for economic mineral deposits in certain areas are presented. The results of these preliminary investigations open concepts for further use in geochemical exploration in the search for metallic mineral deposits in Jordan. Perhaps the most desirable new activity would be hydrogeochemical exploration for uranium and base metals, accompanied by interpretation of such remote-sensing data as results of airborne radiometric surveys and computer-enhanced LANDSAT imagery. For more conventional approaches to geochemical exploration, however, several fundamental problems regarding proper choice of geochemical sample media for different geologic and geographic parts of the Country must be solved before effective surveys can be made. The present results also show that such common geochemical exploration techniques as the determination of the trace-element contents of soils, plant ash, and slags have direct application also toward the resolution of several archaeological problems in Jordan. These include the relation of trace-elements chemistry of local soils to the composition of botanic remains, the trace-elements composition of slags to the technological development of the extractive metallurgy of copper and iron in the region, and the use of charcoal from slags for the C-14 dating of periods of archaeometallurgical activity. Less directly, interpretations based on the distribution in time and space of the archaeometallurgical activities of the region might add to the knowledge of early climatic conditions and vegetative cover of the area.

Open-File Report↗

Thermochronology of the Cornubian batholith in southwest England: Implications for pluton emplacement and protracted hydrothermal mineralization

The metalliferous ore deposits of southwest England are associated with biotite-muscovite granites that intruded upper Paleozoic sediments and volcanic rocks at the end of the Hercynian Orogeny. The hydrothermal mineralization can be subdivided into four stages: 1. exoskarns 2. high-temperature tin and tungsten oxide-bearing sheeted greisen bordered veins and Sn-bearing tourmaline veins and breccias 3. polymetallic quartz-tourmaline-chlorite-sulfide-fluorite-bearing fissure veins, which represent the main episode of economic mineralization 4. late-stage, low-temperature polymetallic fluorite veins. U-Pb dating of monazite and xenotime and 40 Ar 39 Ar "> 40 Ar 39 Ar dating of muscovite were used to determine emplacement ages and cooling times for individual plutons within the Cornubian batholith, as well as separate intrusive phases within the plutons. In addition, 40 Ar 39 Ar "> 40 Ar 39 Ar ages from hornblende and secondary muscovite and Sm-Nd isochron ages from fluorite were employed to determine the relationship between pluton emplacement and different stages of mineralization. The U-Pb ages indicate that granite magmatism was protracted from ~300 Ma down to ~275 Ma with no evidence of a major hiatus. There is no systematic relation between the age of a pluton and its location within the batholith. The U-Pb ages for separate granite phases within a single pluton are resolvable and indicate that magma emplacement within individual plutons occurred over periods of as much as 4.5 myrs. Felsic porphyry dike emplacement was coeval with plutonism, but continued to ~270 Ma. The geochronologic data suggest that the Cornubian batholith originated from repeated melting events over 30 myrs and was formed by a series of small coalescing granitic bodies. Cooling rates of the main plutons are unrelated to emplacement age, but decrease from the southwest to the northeast from ~210°C myr −1 to ~60°C myr −1 with a mean of 100°C myr −1 . These slow cooling rates appear to reflect the addition of heat from multiple intrusive episodes. The mineralization history is distinct for each pluton and ranges from coeval with, to up to 40 myrs younger than the cooling age for the host pluton. Stage 2 mineralization is broadly synchronous with the emplacement of granite magmas, is dominated by fluids expelled during crystallization, and may be repeated by the emplacement of younger magmas within the same pluton. Sm-Nd isochrons for fluorite from stage 3 polymetallic mineralization give ages of 259 ± 7, 266 ± 3 and 267 ± 12 Ma, postdating stage 2 mineralization by up to 25 myrs within the same deposit. The similarity in age of the main polymetallic mineralization hosted by the oldest and youngest plutons, suggests that this stage of mineralization is unlikely to be related to hydrothermal circulation driven by the emplacement and cooling of the host granite. The mineralization is more likely the product of regional hydrothermal circulation driven by heat from the emplacement and crystallization of younger buried pulses of magma.

Cornubian Batholith↗

Structural fabrics, mineralization and Lamaride kinematics of the Idaho Springs-Ralston shear zone, Colorado mineral belt and central Front Range uplift

The Idaho Springs and Central City mining districts form the central portion of a structurally controlled hydrothermal precious- and base-metal vein system in the Front Range of the northeast-trending Colorado Mineral Belt. Three new 40Ar/39Ar plateau ages on hydrothermal sericite indicate the veins formed during the Laramide orogeny between 65.4??1.5 - 61.9??1.3 Ma. We compile structural geologic data from surface geological maps, subsurface mine maps, and theses for analysis using modern graphical methods and integration into models of formation of economic mineral deposits. Structural data sets, produced in the 1950s and 1960s by the U.S. Geological Survey, are compiled for fabric elements, including metamorphic foliations, fold axial trends, major brittle fault zones, quartz and precious- and base-metal veins and fault veins, Tertiary dikes, and joints. These fabric elements are plotted on equal-area projections and analyzed for mean fabric orientations. Strike-slip fault-vein sets are mostly parallel or sub-parallel, and not conjugate as interpreted by previous work; late-stage, normal-slip fault veins possibly show a pattern indicative of triaxial strain. Fault-slip kinematic analysis was used to model the trend of the Laramide maximum horizontal stress axis, or compression direction, and to determine compatibility of opening and shear motions within a single stress field. The combined-model maximum compression direction for all strike slip fault veins is ???068??, which is consistent with published Laramide compression directions of ???064?? (mean of 23 regional models) and ???072?? for the Front Range uplift. The orientations of fabric elements were analyzed for mechanical and kinematic compatibility with opening, and thus permeability enhancement, in the modeled regional east-northeast, Laramide compression direction. The fabric orientation analysis and paleostress modeling show that structural permeability during mineralization was enhanced along pre-existing metamorphic foliations and fold axial planes. Large orientation dispersion in most fabric elements likely caused myriad potential pathways for permeability. The dominant orientations of opening and shear mode structures are consistent with a sub-parallel network of structures that formed in the Laramide east-northeast compression direction. The results presented demonstrate the importance of using mechanical and kinematic theory integrated with contemporary ideas of permeability structure to better understand the coupled nature of fluid flow, mineral deposition, stress, and strain. Further, the results demonstrate that there is significant internal strain within this basement-cored uplift that was localized by optimally oriented pre-existing structures in a regional stress field.

Mountain Geologist↗

Timing of hydrothermal alteration and Au-Sb-W mineralization, Stibnite-Yellow Pine district, Idaho

The Stibnite-Yellow Pine district of central Idaho was mined from the early 1900s until the 1990s, extracting gold, antimony, tungsten, and mercury from veins and disseminated and replacement ores in mountainous terrain along the headwaters of the Salmon River. Mining during the two World Wars supplied critical antimony and tungsten to the war efforts. Recent exploration has delineated mineral resources of over 187 metric tons Au, 274 metric tons Ag, and 93,000 metric tons Sb. Mineralization is hosted in Cretaceous Idaho batholith granitic rocks and a sequence of Neoproterozoic to Paleozoic metasedimentary strata of carbonate and siliciclastic compositions. Historical studies outlined some of the complex paragenesis but debated the absolute age of mineralization. New petrographic and geochronologic work documents a sequence of five hydrothermal events in the Stibnite-Yellow Pine district. Event 1 is related to Cretaceous magmatic and hydrothermal activity and includes events ranging in age from 86 to 75 Ma, including sparse quartz-molybdenite veins dated at 86 Ma. Disseminated gold mineralization of event 2 is associated with sericitic alteration and sulfidation of igneous biotite and replacement of plagioclase by potassium feldspar, largely in granodiorite. Gold is present in zoned arsenian pyrite in both disseminated ores and in crosscutting carbonate-quartz veins containing pyrite and arsenopyrite. The large Yellow Pine deposit, localized at a dilatant bend in the Meadow Creek fault, hosts such disseminated and vein gold. Event 2 is interpreted as the major gold-forming event; 40 Ar/ 39 Ar ages of sericite and potassium feldspar alteration range, respectively, from 70 to 59 and 66 to 56 Ma. The long span is interpreted to reflect the age of gold mineralization and local overprinting by event 3. A narrower range from 66 to 61 Ma is interpreted to date the peak of gold mineralization and alteration. Event 3, tungsten mineralization with scheelite, is texturally later than event 2 gold and localized along the Meadow Creek structure. Event 3 scheelite has been dated by isotope dilution-thermal ionization mass spectrometry (ID-TIMS) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb methods at 57 Ma. Event 4, best developed in the West End area, includes gold-silver–bearing quartz-carbonate-pyrite veins and breccias with epithermal textures and potassium feldspar alteration envelopes. Adularia from event 4 yields 40 Ar/ 39 Ar plateau ages of 52 to 51 Ma. Event 5 antimony and mercury mineralization consists of stibnite veins and breccia cements at the Yellow Pine and Hangar Flat deposits as well as cinnabar veins and replacements at the peripheral Fern and Hermes deposits; it is constrained by an LA-ICP-MS U-Pb date on scheelite (ca. 47 Ma) intergrown with stibnite. Minor propylitic and argillic alteration is evident in 47 Ma igneous dikes, which do not contain economic mineralization. The Au-Sb-W ores in the Stibnite-Yellow Pine mining district formed over an extended time period from about 70 to 45 Ma in multiple pulses that were localized along the Meadow Creek fault zone. Each event corresponds to episodes of magmatism and/or hydrothermal activity in the region. Insignificant event 1 skarn and molybdenum mineralization is similar in age to the Thompson Creek porphyry molybdenum deposit in central Idaho. Event 2 gold mineralization occurred during a magmatic gap in central Idaho but was synchronous with magmatism in the Bitterroot lobe further north; event 2 is similar in age to orogenic gold-arsenic mineralization at the Beartrack mine in eastern Idaho. Event 3 scheelite mineralization coincides with tungsten mineralization at the Quartz Creek deposit, late magmatism in the Bitterroot lobe, and rapid exhumation of the Atlanta lobe of the Idaho batholith. Event 4 gold mineralization is coincident with the onset of regional Challis magmatism and extension. Event 5 antimony and mercury mineralization is time-equivalent to epithermal gold mineralization in the nearby Thunder Mountain volcanic field and the peak of Challis magmatism.

Idaho↗

Characteristics, extent and origin of hydrothermal alteration at Mount Rainier Volcano, Cascades Arc, USA: Implications for debris-flow hazards and mineral deposits

Hydrothermal alteration at Mount Rainier waxed and waned over the 500,000-year episodic growth of the edifice. Hydrothermal minerals and their stable-isotope compositions in samples collected from outcrop and as clasts from Holocene debris-flow deposits identify three distinct hypogene argillic/advanced argillic hydrothermal environments: magmatic-hydrothermal, steam-heated, and magmatic steam (fumarolic), with minor superimposed supergene alteration. The 3.8 km 3 Osceola Mudflow (5600 y BP) and coeval phreatomagmatic F tephra contain the highest temperature and most deeply formed hydrothermal minerals. Relatively deeply formed magmatic-hydrothermal alteration minerals and associations in clasts include quartz (residual silica), quartz–alunite, quartz–topaz, quartz–pyrophyllite, quartz–dickite/kaolinite, and quartz–illite (all with pyrite). Clasts of smectite–pyrite and steam-heated opal–alunite–kaolinite are also common in the Osceola Mudflow. In contrast, the Paradise lahar, formed by collapse of the summit or near-summit of the edifice at about the same time, contains only smectite–pyrite and near-surface steam-heated and fumarolic alteration minerals. Younger debris-flow deposits on the west side of the volcano (Round Pass and distal Electron Mudflows) contain only low-temperature smectite–pyrite assemblages, whereas the proximal Electron Mudflow and a < 100 y BP rock avalanche on Tahoma Glacier also contain magmatic-hydrothermal alteration minerals that are exposed in the avalanche headwall of Sunset Amphitheater, reflecting progressive incision into deeper near-conduit alteration products that formed at higher temperatures. The pre-Osceola Mudflow alteration geometry is inferred to have consisted of a narrow feeder zone of intense magmatic-hydrothermal alteration limited to near the conduit of the volcano, which graded outward to more widely distributed, but weak, smectite–pyrite alteration within 1 km of the edifice axis, developed chiefly in porous breccias. The edifice was capped by a steam-heated alteration zone, most of which resulted from condensation of fumarolic vapor and oxidation of H 2 S in the unsaturated zone above the water table. Weakly developed smectite–pyrite alteration extended into the west and east flanks of the edifice, spatially associated with dikes that are localized in those sectors; other edifice flanks lack dikes and associated alteration. The Osceola collapse removed most of the altered core and upper east flank of the volcano, but intensely altered rocks remain on the uppermost west flank. Major conclusions of this study are that: (1) Hydrothermal–mineral assemblages and distributions at Mount Rainier can be understood in the framework of hydrothermal processes and environments developed from studies of ore deposits formed in analogous settings. (2) Frequent eruptions supplied sufficient hot magmatic fluid to alter the upper interior of the volcano hydrothermally, despite the consistently deep (≥ 8 km) magma reservoir which may have precluded formation of economic mineral deposits within or at shallow depths beneath Mount Rainier. The absence of indicator equilibrium alteration-mineral assemblages in the debris flows that effectively expose the volcano to a depth of 1–1.5 km also suggests a low potential for significant high-sulfidation epithermal or porphyry-type mineral deposits at depth. (3) Despite the long and complex history of the volcano, intensely altered collapse-prone rocks were spatially restricted to near the volcano's conduit system and summit, and short distances onto the upper east and west flanks, due to the necessary supply of reactive components carried by ascending magmatic fluids. (4) Intensely altered rocks were removed from the summit, east flank, and edifice interior by the Osceola collapse, but remain on the upper west flank in the Sunset Amphitheater area and present a continuing collapse hazard. (5) Visually conspicuous rocks on the lower east and mid-to-lower west flanks are not intensely altered and probably have not significantly weakened the rock, and thus do not present significant collapse hazards. (6) Alteration developed most intensely within breccia units, because of their high permeability and porosity. Volcanoes with abundant near-conduit upper-edifice breccias are prone to alteration increasing the possibility of collapse, whereas those that are breccia-poor (e.g., massive domes) are less prone to alteration.

Journal of Volcanology and Geothermal Research↗

Post-orogenic peralkaline and calc-alkaline granites and associated mineralization of the Arabian Shield, Kingdom of Saudi Arabia

Following a long period of island arc-like orogenic activity, post-orogenic granites of Pan-African age (670-550 m.y.) were emplaced throughout the Arabian Shield. Most of these rocks are typical subsolvus calc-alkaline biotite monzogranite. The early Pan-African granites are associated with widespread small tholeiitic gabbro intrusions, many of which are layered. The calc-alkaline granites are not evenly distributed and their area of exposure relative to other rock types increases from southwest to north and northeast. In the northeastern part of the shield, they are associated spatially with rhyolites of similar composition and with molasse derived from granitic terrane. The occurrence of 45 late alkali granites, most of which are peralkaline, is described and their chemistry discussed. Most of these rocks are medium- to coarse-grained hypersolvus alkali granites, but phenocrystalline and micrographic varieties are also common. The mafic silicate minerals of the alkali granites are arfvedsonite, aegirine, aegirine-augite, riebeckite, and sparse biotite, aenigmatite, and barkevikite. The alkali granites do not occur in the southwestern third of the Arabian Shield nor in the southeastern portion of the adjacent Nubian Shield of Africa. A syenite-shonkinite province located in the southwestern part of the Arabian Shield is identified. No economic mineral deposits are known to be associated with the Pan-African granites. Numerous mineral occurrences and geochemical anomalies have been found that contain tungsten, molybdenum, tin, beryllium, zirconium, niobium, thorium, uranium, rare earths, and fluorite. The most important of these occurrences are tabulated and their distribution shown.

Open-File Report↗

Bedrock geologic map of the Spring Valley, West Plains, and parts of the Piedmont and Poplar Bluff 30'x60' quadrangles, Missouri, including the upper Current River and Eleven Point River drainage basins

This map covers the drainage basins of the upper Current River and the Eleven Point River in the Ozark Plateaus physiographic province of southeastern Missouri. The two surface drainage basins are contiguous in their headwaters regions, but are separated in their lower reaches by the lower Black River basin in the southeast corner of the map area. Numerous dye-trace studies demonstrate that in the contiguous headwaters areas, groundwater flows from the Eleven Point River basin into the Current River basin. Much of the groundwater discharge of the Eleven Point River basin emanates from Big Spring, located on the Current River. This geologic map and cross sections were produced to help fulfill a need to understand the geologic framework of the region in which this subsurface flow occurs. The map includes all of the Ozark National Scenic Riverways, a national park created by an Act of Congress in 1964 to protect 134 miles of the Current and Jacks Fork Rivers in south-central Missouri. Located within the park are numerous large springs, including Big Spring, the largest spring in Missouri and one of the ten largest springs in the world. Also within the map area is Greer Spring, which is the main source of the Eleven Point River. Greer Spring is the largest spring on National Forest land in the United States. During flood, flow from Greer Spring is almost as large, volumetrically, as that from Big Spring. The Wild and Scenic Rivers Act in 1968 established a 44-mile section of the Eleven Point River as the Eleven Point National Scenic River, which is entirely within the boundaries of this map. Potentially economic mineral resources are present in the subsurface in the map area. Exploration drill-hole data indicate that anomalously high concentrations of base-metal sulfides locally occur within the Cambrian Bonneterre Formation. The geologic setting of these anomalous concentrations is similar to that found in the Viburnum Trend, part of the largest lead-mining district in the world. The southernmost part of the Viburnum Trend extends into the northern part of the map area and is exploited by the Sweetwater Mine. Undeveloped and potentially economic occurrences of base metals are known also beneath Blair Creek, a tributary to the Current River in the north-central part of the map area.

Missouri↗

Arc-related porphyry molybdenum deposit model

This report provides a descriptive model for arc-related porphyry molybdenum deposits. Presented within are geological, geochemical, and mineralogical characteristics that differentiate this deposit type from porphyry copper and alkali-feldspar rhyolite-granite porphyry molybdenum deposits. The U.S. Geological Survey's effort to update existing mineral deposit models spurred this research, which is intended to supplement previously published models for this deposit type that help guide mineral-resource and mineral-environmental assessments. Arc-related porphyry molybdenum deposits are a substantial resource for molybdenum metal and may have anomalous concentrations of tungsten. The deposits contain low-grade ore (0.03-0.22 percent molybdenum) as molybdenite, but are large-tonnage, making them amenable to bulk mining open-pit techniques. The mineralizing system usually has fluorine contents of less than 0.1 percent. The cogenetic intrusion is a differentiated calc-alkaline granitoid, typically granodiorite to quartz monzonite in composition, with low rubidium and niobium, and moderate to high strontium concentrations. Metals and hydrothermal fluids are sourced from these intrusions, with an additional meteoric fluid component contributing to peripheral alteration but not adding more metal. The lithology of the surrounding country rocks is not important to the formation of these deposits, but a surrounding carbonate unit may be altered to skarn that contains economic mineralization. The creation of contact-metamorphosed hornfels adjacent to the intrusion is common. Formation of arc-related porphyry molybdenum deposits typically occurs within a continental arc environment related to arc-continent or continent-continent collision and subduction. Few deposits are found in an island arc setting. Most classified arc-related porphyry molybdenum deposits are located in the western cordillera of North America, notably in British Columbia and Alaska. Hydrothermal alteration provides a key component to the identification of a deposit. Alteration usually is zoned from a core of potassic plus/minus silicic alteration outwards through phyllic to propylitic alteration. Argillic alteration may be irregular in shape and will overprint earlier hydrothermal alteration. Exploration should be limited to magmatic arc belts that have been unroofed and eroded to levels of a few kilometers depth. Important geological vectors toward areas of higher grade mineralization include intensity of hydrothermal alteration, veining, and faulting. Anomalous levels of molybdenum, tungsten, copper, lead, or zinc in soils, tills, stream sediments, and drainage waters may indicate the presence of an arc-related porphyry molybdenum deposit. Geophysical exploration techniques have been met with minimal success because of the overall low concentration of associated sulfide and oxide minerals. Geoenvironmental concerns are generally low because of low volumes of sulfide minerals. Most deposits are marginally acid-generating to non-acid-generating with drainage waters being near-neutral pH because of the acid generating potential of pyrite being partially buffered by late-stage calcite-bearing veins. The low ore content results in a waste:ore ratio of nearly 1:1 and large tailings piles from the open-pit method of mining.

Scientific Investigations Report↗