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Chemical data for rock, sediment, biological, precipitate, and water samples from abandoned copper mines in Prince William Sound, Alaska

Introduction In the early 20th century, approximately 6 million metric tons of copper ore were mined from numerous deposits located along the shorelines of fjords and islands in Prince William Sound, Alaska. At the Beatson, Ellamar, and Threeman mine sites (fig. 1), rocks containing Fe, Cu, Zn, and Pb sulfide minerals are exposed to chemical weathering in abandoned mine workings and remnant waste piles that extend into the littoral zone. Field investigations in 2003 and 2005 as well as analytical data for rock, sediment, precipitate, water, and biological samples reveal that the oxidation of sulfides at these sites is resulting in the generation of acid mine drainage and the transport of metals into the marine environment (Koski and others, 2008; Stillings and others, 2008). At the Ellamar and Threeman sites, plumes of acidic and metal-enriched water are flowing through beach gravels into the shallow offshore environment. Interstitial water samples collected from beach sediment at Ellamar have low pH levels (to ~3) and high concentrations of metals including iron, copper, zinc, cobalt, lead, and mercury. The abundant precipitation of the iron sulfate mineral jarosite in the Ellamar gravels also signifies a low-pH environment. At the Beatson mine site (the largest copper mine in the region) seeps containing iron-rich microbial precipitates drain into the intertidal zone below mine dumps (Foster and others, 2008). A stream flowing down to the shoreline from underground mine workings at Beatson has near-neutral pH, but elevated levels of zinc, copper, and lead (Stillings and others, 2008). Offshore sediment samples at Beatson are enriched in these metals. Preliminary chemical data for tissue from marine mussels collected near the Ellamar, Threeman, and Beatson sites reveal elevated levels of copper, zinc, and lead compared to tissue in mussels from other locations in Prince William Sound (Koski and others, 2008). Three papers presenting results of this ongoing investigation of sulfide oxidation in Prince William Sound are in press. Koski and others (2008) provide an overview of rock alteration, surface water chemistry, and the distribution of metals at the Ellamar, Threeman, and Beatson mine sites. Based on a 60-day, stream-discharge experiment at Beatson in 2005, Stillings and others (2008) analyze changes in water chemistry during storm events and the flux of metals to the shoreline. Foster and others (2008) investigate the biomass and diversity of microbial communities present in surface waters (streams, seeps, pore waters) using fatty acid methyl ester (FAMES) data and principal component analysis. The publications cited above contain a subset of the total chemical data for rock, sediment, biological, precipitate, and water samples collected from the three mine sites in 2003 and 2005. The purpose of this report is the presentation of complete chemical data sets for all samples collected during the two field periods of fieldwork. Data for a small number of samples collected at two other mines (Schlosser and Fidalgo, fig. 1), visited in 2003, are also included in the tables.

Alaska↗

Chemical data for rock, sediment, biological, precipitate, and water samples from abandoned copper mines in Prince William Sound, Alaska

In the early 20th century, approximately 6 million metric tons of copper ore were mined from numerous deposits located along the shorelines of fjords and islands in Prince William Sound, Alaska. At the Beatson, Ellamar, and Threeman mine sites (fig. 1), rocks containing Fe, Cu, Zn, and Pb sulfide minerals are exposed to chemical weathering in abandoned mine workings and remnant waste piles that extend into the littoral zone. Field investigations in 2003 and 2005 as well as analytical data for rock, sediment, precipitate, water, and biological samples reveal that the oxidation of sulfides at these sites is resulting in the generation of acid mine drainage and the transport of metals into the marine environment (Koski and others, 2008; Stillings and others, 2008). At the Ellamar and Threeman sites, plumes of acidic and metal-enriched water are flowing through beach gravels into the shallow offshore environment. Interstitial water samples collected from beach sediment at Ellamar have low pH levels (to ~3) and high concentrations of metals including iron, copper, zinc, cobalt, lead, and mercury. The abundant precipitation of the iron sulfate mineral jarosite in the Ellamar gravels also signifies a low-pH environment. At the Beatson mine site (the largest copper mine in the region) seeps containing iron-rich microbial precipitates drain into the intertidal zone below mine dumps (Foster and others, 2008). A stream flowing down to the shoreline from underground mine workings at Beatson has near-neutral pH, but elevated levels of zinc, copper, and lead (Stillings and others, 2008). Offshore sediment samples at Beatson are enriched in these metals. Preliminary chemical data for tissue from marine mussels collected near the Ellamar, Threeman, and Beatson sites reveal elevated levels of copper, zinc, and lead compared to tissue in mussels from other locations in Prince William Sound (Koski and others, 2008). Three papers presenting results of this ongoing investigation of sulfide oxidation in Prince William Sound are in press. Koski and others (2008) provide an overview of rock alteration, surface water chemistry, and the distribution of metals at the Ellamar, Threeman, and Beatson mine sites. Based on a 60-day, stream-discharge experiment at Beatson in 2005, Stillings and others (2008) analyze changes in water chemistry during storm events and the flux of metals to the shoreline. Foster and others (2008) investigate the biomass and diversity of microbial communities present in surface waters (streams, seeps, pore waters) using fatty acid methyl ester (FAMES) data and principal component analysis. The publications cited above contain a subset of the total chemical data for rock, sediment, biological, precipitate, and water samples collected from the three mine sites in 2003 and 2005. The purpose of this report is the presentation of complete chemical data sets for all samples collected during the two field periods of fieldwork. Data for a small number of samples collected at two other mines (Schlosser and Fidalgo, fig. 1), visited in 2003, are also included in the tables.

Alaska↗

Formation and distribution of coal balls in the Herrin Coal (Pennsylvanian), Franklin County, Illinois Basin, USA

Large areas of concentrated coal balls (permineralized peat) up to 4 m thick obstructed longwall mining in the Herrin Coal at the Old Ben No. 24 mine. The largest coal‐ball area mapped contained >1500 m 3 ; several areas contained >400 m 3 of coal balls. In‐mine mapping established that there were two types of roof (freshwater and marine), and that the coal balls were spatially correlated with the marine roof units. Regional studies and local data revealed that the younger, freshwater Energy Shale (mud) originally covered all of the peat deposited at the mine, but the mud was locally removed during a period of erosion. The great majority of coal balls are found within the coal seam, where they were permineralized in situ by carbonates. Some coal balls are found exposed on the eroded coal surface and others are within the channel fill associated with the erosion, which predates any marine sedimentation. Thus, the mineralization of the coal balls was synchronous with the erosion of the Energy Shale mud. Data from C‐and O‐isotope, geochemical, and mineralogical analyses of coal balls and associated materials were used to refine a depositional model of coal‐ball formation. The concentrated coal‐ball areas were created by the triggered degassing of CO 2 from partially decomposed peat in the presence of cations from fresh waters; 13 C/ 12 C ratios in these coal balls average −23.9‰. 13 C/ 12 C ratios as low as −34‰ occurring in the most concentrated coal balls are consistent with CO 2 produced by anaerobic oxidation of methane. Top‐of‐seam coal balls were formed later and show slight to strong marine influence; their 13 C/ 12 C ratios average −10.8‰.

Illinois↗

Seamount mineral deposits: A source of rare metals for high technology industries

The near exponential growth in Earth’s population and the global economy puts increasing constraints on our planet’s finite supply of natural metal resources, and, consequently, there is an increasing need for new sources to supply high-tech industries. To date, effectively all of our raw-metal resources are produced at land-based sites. Except for nearshore placer deposits, the marine environment has been largely excluded from metal mining due to technological difficulties, even though it covers more than 70% of the planet. The case can be made that deep-water seabed mining is inevitable in the future, owing to the critical and strategic metal needs for human society. In this paper, we evaluate the case that seamounts offer significant potential for mining.

Oceanography↗

Potash—A vital agricultural nutrient sourced from geologic deposits

This report summarizes the primary sources of potash in the United States. Potash is an essential nutrient that, along with phosphorus and nitrogen, is used as fertilizer for growing crops. Plants require sufficient potash to activate enzymes, which in turn catalyze chemical reactions important for water uptake and photosynthesis. When potassium is available in quantities necessary for healthy plant growth, disease resistance and physical quality are improved and crop yield and shelf life are increased. Potash is a water-soluble compound of potassium formed by geologic and hydrologic processes. The principal potash sources discussed are the large, stratiform deposits that formed during retreat and evaporation of intracontinental seas. The Paradox, Delaware, Holbrook, Michigan, and Williston sedimentary basins in the United States are examples where extensive potash beds were deposited. Ancient marine-type potash deposits that are close to the surface can be mined using conventional underground mining methods. In situ solution mining can be used where beds are too deep, making underground mining cost-prohibitive, or where underground mines are converted to in situ solution mines. Quaternary brine is another source of potash that is recovered by solar evaporation in manmade ponds. Groundwater from Pleistocene Lake Bonneville (Wendover, Utah) and the present-day Great Salt Lake in Utah are sources of potashbearing brine. Brine from these sources pumped to solar ponds is evaporated and potash concentrated for harvesting, processing, and refinement. Although there is sufficient potash to meet near-term demand, the large marine-type deposits are either geographically restricted to a few areas or are too deep to easily mine. Other regions lack sources of potash brine from groundwater or surface water. Thus, some areas of the world rely heavily on potash imports. Political, economic, and global population pressures may limit the ability of some countries from securing potash resources in the future. In this context, a historical perspective on U.S. potash production in a global framework is discussed.

Open-File Report↗

Seabed ripple morphology and surficial sediment size at the SAX04 experiments near Fort Walton Beach, Florida, fall 2004

Data presented in this report originates from measurements obtained off the Florida coast (fig. 1) as part of the Sediment Acoustics Experiment (SAX04) and Ripples Department Research Initiative (DRI) (Office of Naval Research (ONR), Critical Benthic Environmental Processes and Modeling, Long Range BAA 04-001, Sept. 10, 2003). The aim of this document is to present methods employed to extract data and the resulting measured ripple characteristics (ripple height, wavelength, and orientation) and seabed grain sizes. Application and analysis of the data with respect to hydro- and morphodynamics will be addressed in subsequent reports. Sediment transport in the coastal region is a complex process involving interactions between flow dynamics, sediments, and bedforms. Sediment type and bed geometry directly influence entrainment of sediments into suspension, and at sites where ripples occur (sand formations on the order of several cm high and less than two meter long wavelengths), the understanding of ripple dynamics is an essential component in improving sediment transport models. To gain a better understanding and ability to predict sediment transport, a field study was undertaken to investigate morphology, orientation, and dynamics of ripples on the seafloor. The data obtained from the field campaign also supports an on-going effort to study the effects of ripples on low grazing acoustic penetration into sandy marine sediments for the detection of objects, such as mines (Jackson and others, 2002).

Florida↗

Map showing free-air gravity anomalies in the southern Beaufort Sea

Free-air gravity anomaly data used in this compilation were obtained from the U.S. Geological Survey; the University of Connecticut Institute of Marine Sciences; and the Earth Physics Branch, Department of Energy, Mines, and Resources, Canada. Bathymetric contours are based primarily upon water-depth data (uncorrected) collected together with the gravity data. Water depths were reported every half hour (approximately every 5.5 km) along USGS tracklines and interpolated to 10 minute intervals. Where no new bathymetric data were available, depth contours were taken from U.S. Hydrographic Office charts 6782 and 6785. Geographic features were taken from the same charts.

Alaska↗

Extensional faulting in the southern Klamath Mountains, California

Large northeast striking normal faults in the southern Klamath Mountains may indicate that substantial crustal extension occurred during Tertiary time. Some of these faults form grabens in the Jurassic and older bedrock of the province. The grabens contain continental Oligocene or Miocene deposits (Weaverville Formation), and in two of them the Oligocene or Miocene is underlain by Lower Cretaceous marine formations (Great Valley sequence). At the La Grange gold placer mine the Oligocene or Miocene strata dip northwest into the gently southeast dipping mylonitic footwall surface of the La Grange fault. The large normal displacement required by the relations at the La Grange mine is also suggested by omission of several kilometers of structural thickness of bedrock units across the northeast continuation of the La Grange fault, as well as by significant changes in bedrock across some northeast striking faults elsewhere in the Central Metamorphic and Eastern Klamath belts. The Trinity ultramafic sheet crops out in the Eastern Klamath terrane as part of a broad northeast trending arch that may be structurally analogous to the domed lower plate of metamorphic core complexes found in eastern parts of the Cordillera. The northeast continuation of the La Grange fault bounds the southeastern side of the Trinity arch in the Eastern Klamath terrane and locally cuts out substantial lower parts of adjacent Paleozoic strata of the Redding section. Faults bounding the northwestem side of the Trinity arch generally trend northeast and juxtapose stacked thrust sheets of lower Paleozoic strata of the Yreka terrane against the Trinity ultramafic sheet. Geometric relations suggest that the Tertiary extension of the southern Klamath Mountains was in NW-SE directions and that the Redding section and the southern part of the Central Metamorphic terrane may be a large Tertiary allochthon detached from the Trinity ultramafic sheet. Paleomagnetic data indicate a lack of rotation about a vertical axis during the extension. We propose that the Trinity ultramafic sheet is structurally analogous to a metamorphic core complex; if so, it is the first core complex to be described that involves ultramafic rocks. We infer that Mesozoic terrane accretion produced a large gravitational instability in the crust that spread laterally during Tertiary extension

California↗

Introduction to the special section on seismoacoustics and seismoacoustic data fusion

A variety of geophysical hazards (e.g., volcanic activity, earthquakes, mass movements, marine storms, bolides) and anthropogenic sources (e.g., chemical and nuclear explosions, mining blasts, rocket launches) can release energy as mechanical waves in the ground, ocean, and atmosphere (Arrowsmith et al., 2010; Campus and Christie, 2009). Due to the mechanical coupling between a planetary body, its ocean, and its atmosphere, waves can propagate across these interfaces (Ben-Menahem and Singh, 1981) and carry information about the source and the media they propagated through. The field of seismoacoustics, driven by geophysical observations of both seismic and low-frequency acoustic (infrasound) waves, has several interdisciplinary applications. Observations of both seismic and infrasonic waves can be used to discriminate between atmospheric and subsurface events, such as sonic booms and earthquakes. Moreover, seismoacoustic analyses can provide useful information for the source characterization of shallow anthropogenic events, such as underground or surface explosions, volcanic, and tectonic events (e.g., Arrowsmith et al., 2020; Assink et al., 2016; de Groot-Hedlin and Hedlin, 2019; Matoza et al., 2009). Similarly, remote observations (e.g., on regional seismic and infrasonic arrays) can help monitor natural events such as volcanic eruptions and provide additional details about eruption dynamics. Recent works additionally suggest that infrasound can be used to discriminate between different volcanic processes (Watson et al., 2022). Finally, looking outwards, the study of seismo-acoustics has been a particularly valuable tool for planetary science (e.g., Krishnamoorthy et al., 2018; Martire et al., 2018; Krishnamoorthy et al., 2019; Martire et al., 2020; Garcia et al., 2020; Brissaud et al., 2021).

Bulletin of the Seismological Society of America↗

Review of rare earth element concentrations in oil shales of the Eocene Green River Formation

Concentrations of the lanthanide series or rare earth elements and yttrium were determined for lacustrine oil shale samples from the Eocene Green River Formation in the Piceance Basin of Colorado and the Uinta Basin of Utah. Unprocessed oil shale, post-pyrolysis (spent) shale, and leached shale samples were examined to determine if oil-shale processing to generate oil or the remediation of retorted shale affects rare earth element concentrations. Results for unprocessed Green River oil shale samples were compared to data published in the literature on reference materials, such as chondritic meteorites, the North American shale composite, marine oil shale samples from two sites in northern Tibet, and mined rare earth element ores from the United States and China. The Green River oil shales had lower rare earth element concentrations (66.3 to 141.3 micrograms per gram, μg g -1 ) than are typical of material in the upper crust (approximately 170 μg g -1 ) and were also lower in rare earth elements relative to the North American shale composite (approximately 165 μg g -1 ). Adjusting for dilution of rare earth elements by organic matter does not account for the total difference between the oil shales and other crustal rocks. Europium anomalies for Green River oil shales from the Piceance Basin were slightly lower than those reported for the North American shale composite and upper crust. When compared to ores currently mined for rare earth elements, the concentrations in Green River oil shales are several orders of magnitude lower. Retorting Green River oil shales led to a slight enrichment of rare earth elements due to removal of organic matter. When concentrations in spent and leached samples were normalized to an original rock basis, concentrations were comparable to those of the raw shale, indicating that rare earth elements are conserved in processed oil shales.

Utah;Colorado;Wyoming↗

Marine origin of pyritic sulfur in the Lower Bakerstown coal bed, Castleman coal field, Maryland (U.S.A.)

The amount, kind, distribution, and genesis of pyrite in the Lower Bakerstown coal bed in a 150 × 15 m area of the Bettinger mine, Castleman coal field, Maryland, were studied by various analytical techniques. The mined coal, which had a nonmarine roof rock, contained 1.4–2.8 wt.% total sulfur, generally much lower than the high-sulfur coal (> 3.0 wt.% total S) to the north, which is associated with marine roof rocks. Small-scale systematic and nonsystematic variations in total sulfur and pyrite distribution were found in the mined area. In the column sample, most of the pyrite was found in the upper 9 cm of the 69-cm-thick mined coal and occurred mainly as a pyrite lens containing cell fillings in seed-fern tissue (coal ball). As-bearing pyrite was detected by laser microprobe techniques in the cell walls of this tissue but not elsewhere in the column sample. This may indicate that the As was derived from decomposition of organic matter in the cell walls. The sulfur isotopic composition and distribution of pyrite in the coal are consistent with introduction of marine sulfate shortly after peat deposition, followed by bacterial reduction and pyrite precipitation. Epigenetic cleat pyrite in the coal is isotopically heavy, implying that later aqueous sulfate was 34 S-enriched.

International Journal of Coal Geology↗

A ground electromagnetic survey used to map sulfides and acid sulfate ground waters at the abandoned Cabin Branch Mine, Prince William Forest Park, northern Virginia gold-pyrite belt

INTRODUCTION AND BACKGROUND: Prince William Forest Park is situated at the northeastern end of the Virginia Gold-Pyrite belt northwest of the town of Dumfries, VA. The U. S. Marine Corps Reservation at Quantico borders the park on the west and south, and occupies part of the same watershed. Two abandoned mines are found within the park: the Cabin Branch pyrite mine, a historic source of acid mine drainage, and the Greenwood gold mine, a source of mercury contamination. Both are within the watershed of Quantico Creek (Fig.1). The Cabin Branch mine (also known as the Dumfries mine) lies about 2.4 km northwest of the town of Dumfries. It exploited a 300 meter-long, lens-shaped body of massive sulfide ore hosted by metamorphosed volcanic rocks; during its history over 200,000 tons of ore were extracted and processed locally. The site became part of the National Capitol Region of the National Park Service in 1940 and is currently managed by the National Park Service. In 1995 the National Park Service, in cooperation with the Virginia Department of Mines, Minerals, and Energy reclaimed the Cabin Branch site. The Virginia Gold-Pyrite belt, also known as the central Virginia volcanic-plutonic belt, is host to numerous abandoned metal mines (Pavlides and others, 1982), including the Cabin Branch deposit. The belt itself extends from its northern terminus near Cabin Branch, about 50 km south of Washington, D.C., approximately 175 km to the southwest into central Virginia. It is underlain by metamorphosed volcanic and clastic (non-carbonate) sedimentary rocks, originally deposited approximately 460 million years ago during the Ordovician Period (Horton and others, 1998). Three kinds of deposits are found in the belt: volcanic-associated massive sulfide deposits, low-sulfide quartz-gold vein deposits, and gold placer deposits. The massive sulfide deposits such as Cabin Branch were historically mined for their sulfur, copper, zinc, and lead contents, but also yielded byproduct gold and silver. The environmental impact of massive sulfide deposits can be substantial. These deposits are characterized by high concentrations of heavy-metal sulfide minerals, hosted by silicate rocks. Thus, weathering of these deposits and their mine wastes has the potential to generate heavy-metal laden sulfuric acid that can have negative impacts on aquatic ecosystems. In addition, lead associated with solid mine wastes has the potential for human health impacts through ingestion. The heavy metals that are encountered in these deposits and are most likely to cause environmental impacts include copper, zinc, lead, cadmium, and arsenic. In addition, the weathering of pyrite releases large amounts of iron, and the acid generated attacks the country rocks and causes the release of large amounts of aluminum, which also can severely impact aquatic ecosystems. A reclamation attempt was made at the site in 1995, including construction of storm-water diversion trenches around the abandoned mine area, grading tailings away from the stream bank, addition of pulverized limestone and topsoil, and revegetation. The post-reclamation chemistry of shallow groundwaters (<3 meters deep) shows a neutral pH on the southwestern bank of the stream but pH of 4.1 to 4.5 on the northeastern bank. The dominant ions are Fe2+ and SO42- (Seal, Haffner, Meier, and Pollio, 1999) A ground electromagnetic survey was conducted over the site in 1999 as part of a wider study ( Seal, Haffner, and Meier, 1998a,b, 1999). It was hoped that a 3-D map of the soil conductivity derived from the survey could provide insight into the distribution of the mobilized sulfides present under the ground.

Virginia↗

Metal dispersion resulting from mining activities in coastal environments: A pathways approach

Acid rock drainage (ARD) and disposal of tailings that result from mining activities impact coastal areas in many countries. The dispersion of metals from mine sites that are both proximal and distal to the shoreline can be examined using a pathways approach in which physical and chemical processes guide metal transport in the continuum from sources (sulfide minerals) to bioreceptors (marine biota). Large amounts of metals can be physically transported to the coastal environment by intentional or accidental release of sulfide-bearing mine tailings. Oxidation of sulfide minerals results in elevated dissolved metal concentrations in surface waters on land (producing ARD) and in pore waters of submarine tailings. Changes in pH, adsorption by insoluble secondary minerals (e.g., Fe oxyhydroxides), and precipitation of soluble salts (e.g., sulfates) affect dissolved metal fluxes. Evidence for bioaccumulation includes anomalous metal concentrations in bivalves and reef corals, and overlapping Pb isotope ratios for sulfides, shellfish, and seaweed in contaminated environments. Although bioavailability and potential toxicity are, to a large extent, functions of metal speciation, specific uptake pathways, such as adsorption from solution and ingestion of particles, also play important roles. Recent emphasis on broader ecological impacts has led to complementary methodologies involving laboratory toxicity tests and field studies of species richness and diversity.

Oceanography↗

Mercury and methylmercury contents in mine-waste calcine, water, and sediment collected from the Palawan Quicksilver mine, Philippines

The Palawan Quicksilver mine, Philippines, produced about 2,900 t of mercury during mining of cinnabar ore from 1953 to 1976. More than 2,000,000 t of mine-waste calcines (retorted ore) were produced during mining, much of which were used to construct a jetty in nearby Honda Bay. Since 1995, high Hg contents have been found in several people living near the mine, and 21 of these people were treated for mercury poisoning. Samples of mine-waste calcine contain high total Hg concentrations ranging from 43-660 ??g/g, whereas total Hg concentrations in sediment samples collected from a mine pit lake and local stream vary from 3.7-400 ??g/g. Mine water flowing through the calcines is acidic, pH 3.1-4.3, and total Hg concentrations ranging from 18-31 ??g/l in this water significantly exceed the 1.0-??g/l drinking water standard for Hg recommended by the World Health Organization (WHO). Total Hg contents are generally lower in water samples collected from surrounding domestic wells, the mine pit lake, Honda Bay, and the nearby stream, varying from 0.008-1.4 ??g/l. Methylmercury concentrations in water draining mine calcines range from <0.02-1.4 ng/l, but methylmercury is highest in the pit lake water, ranging from 1.7-3.1 ng/l. Mercury methylation at the Palawan mine is similar to or higher than that found in other mercury mines worldwide. Much of the methylmercury generated in Palawan mine-waste calcines and those in Honda Bay is transferred to water, and then to marine fish and seafood. A food source pathway of Hg to humans is most likely in this coastal, high fish-consuming population.

Conference Paper↗

Factors controlling localization of uranium deposits in the Dakota Sandstone, Gallup and Ambrosia Lake mining districts, McKinley County, New Mexico

Geologic studies were made at all of the uranium mines and prospects in the Dakota Sandstone of Early(?) and Late Cretaceous age in the Gallup mining district, McKinley County, New Mexico. Dakota mines in the adjacent Ambrosia Lake mining district were visited briefly for comparative purposes. Mines in the eastern part of the Gallup district, and in the Ambrosia Lake district, are on the Chaco slope of the southern San Juan Basin in strata which dip gently northward toward the central part of the basin. Mines in the western part of the Gallup district are along the Gallup hogback (Nutria monocline) in strata which dip steeply westward into the Gallup sag. Geologic factors which controlled formation of the uranium deposits in the Dakota Sandstone are: (1) a source of uranium, believed to be uranium deposits of the underlying Morrison Formation of Late Jurassic age; (2) the accessibility to the Dakota of uranium-bearing solutions from the Morrison; (3) the presence in the Dakota of permeable sandstone beds overlain by impermeable carbonaceous shale beds; and (4) the occurrence within the permeable Dakota sandstone beds of carbonaceous reducing material as bedding-plane laminae, or as pockets of carbonaceous trash. Most of the Dakota uranium deposits are found in the lower part of the formation in marginal-marine distributary-channel sandstones which were deposited in the backshore environment. However, the Hogback no. 4 (Hyde) Mine (Gallup district) occurs in sandy paludal shale of the backshore environment, and another deposit, the Silver Spur (Ambrosia Lake district), is found in what is interpreted to be a massive beach or barrier-bar sandstone of the foreshore environment in the upper part of the Dakota. The sedimentary depositional environment most favorable for the accumulation of uranium is that of backshore areas lateral to main distributary channels, where levee, splay, and some distributary-channel sandstones intertongue with gray carbonaceous shales and siltstones of the well-drained swamp environment. Deposits of black carbonaceous shale which were formed in the poorly drained swamp deposits of the interfluve area are not favorable host rocks for uranium. The depositional energy levels of the various environments in which the sandstone and shale beds of the Dakota were deposited govern the relative favorability of the strata as uranium host rocks. In the report area, uranium usually occurs in carbonaceous sandstone deposited under low- to medium-energy fluvial conditions within distributary channels. A prerequisite, however, is that such sandstone be overlain by impermeable carbonaceous shale beds. Low- to medium-energy fluvial conditions result in the deposition of sandstone beds having detrital carbonaceous material distributed in laminae or in trash pockets on bedding planes. The carbonaceous laminae and trash pockets provide the necessary reductant to cause precipitation of uranium from solution. High-energy fluvial conditions result in the deposition of sandstones having little or no carbonaceous material included to provide a reductant. Very low energy swampy conditions result in carbonaceous shale deposits, which are generally barren of uranium because of their relative impermeability to migrating uranium-bearing solutions.

Open-File Report↗

Glacial sedimentology of the Precambrian Gowganda Formation, Ontario, Canada

The Gowganda Formation is part of the thick Huronián sequence of Precambrian sedimentary rocks that crop out in central Ontario from Lake Superior to Quebec. Although it has long been considered to be glacial, recent work on submarine slump and turbidite deposits has reopened the question of its origin. This study was made to determine its origin and paleogeography. Till-like conglomerates, varved argillites, and abundant dropstones characterize the Gowganda and provide strong evidence for a glacial origin. Pebble fabric parallel to regional paleocurrents, rare striated and grooved pavements, and abundant unweathered detritus are also in harmony with a glacial origin. Local thin-bedded sandstones contain flame structure, graded bedding, contorted bedding, and rippled tops, suggesting deposition by turbidity flows. Association of these sandstones with varved argillites and rafted stones indicates that Gowganda turbidites are glaciolacustrine. Along the southern margin of the Gowganda, at Whitefish Falls, thick, laterally continuous till-like conglomerates contain internal stratification indicative of subaqueous deposition. Argillites that lack varved structure and associated silty limestones suggest a glacial marine environment. In the Cobalt region the apparent long axes of pebbles in conglomerates show a predominant north-south alignment. In the Bruce Mines-Elliot Lake region, the orientation of the long axes of pebbles is more variable. Differences in orientation are related to stratigraphic position. Ripple cross-lamination in sandstones that are interbedded with argillite indicates south-trending paleocurrents. Distribution of varved argillite, silty limestone, and probable marine argillites suggests a northern fresh-water facies and a southern marine facies. Abundant plutonic pebbles and feldspar indicate that the Gowganda ice sheets eroded a northern plutonic terrane and deposited much of their sediment load on the underlying Huronian sediments to the south.

Ontario↗

The Russell gold deposit, Carolina Slate Belt, North Carolina

Gold deposits have been mined in the Carolina slate belt from the early 1800s to recent times, with most of the production from large mines in South Carolina. The Russell mine, one of the larger producers in North Carolina, is located in the central Uwharrie Mountains, and produced over 470 kg of gold. Ore grades averaged about 3.4 grams per tonne (g/ t), with higher-grade zones reported. The Russell deposit is interpreted to be a sediment-hosted, gold-rich, base-metal poor, volcanogenic massive sulfide deposit in which gold was remobilized, in part, during Ordovician metamorphism. The ore was deposited syngenetically with laminated siltstones of the late Proterozoic Tillery Formation that have been metamorphosed to a lower greenschist facies. The Tillery Formation regionally overlies subaerial to shallow marine rhyolitic volcanic and volcaniclastic rocks of the Uwharrie Formation and underlies the marine volcanic and sedimentary rocks of the Cid Formation. Recent mapping has shown that a rhyolitic dome near the Russell mine was extruded during the deposition of the lower part of the Tillery Formation, at about the same time as ore deposition. Relict mafic, rock fragments present in the ore zones suggest contemporaneous bimodal (rhyolite-basalt) volcanism. The maximum formation age of the Russell deposit is younger than 558 Ma, which is similar to that of the larger, well known Brewer, Haile, and Ridgeway deposits of South Carolina. Gold was mined from at least six zones that are parallel to the regional metamorphic foliation. These strongly deformed zones consist of northeast-trending folds, high-angle reverse faults, and asymmetric doubly plunging folds overturned to the southeast. The dominant structure at the mine is an asymmetric doubly plunging anticline with the axis trending N 45?? E, probably related to late Ordovician (456 ?? 2 Ma) regional metamorphism and deformation. Two stages of pyrite growth are recognized. Stage 1, primary, spongy pyrite, is present in thin massive sulfide layers parallel to bedding and intergrown with pyrrhotite, chalcopyrite, sphalerite, and sparse arsenopyrite. Stage 2, secondary pyrite, is present as euhedral, idiomorphic rims on spongy pyrite and as veinlets that parallel the regional foliation. Stage 1 pyrite was deposited syngenetically or diagenetically during or soon after sedimentation. Stage 2 pyrite overgrowths and veins resulted from recrystallization or remobilization of stage 1 pyrite, probably during deformation related to Ordovician regional metamorphism. It is proposed that the spongy texture of the stage 1 pyrite represents nucleation and growth of pyrite on organic matter, possibly of bacterial origin. Other textures, such as geometric voids in spongy pyrite, As-rich zones surrounding central voids, 60-??m ring structures composed of spongy pyrite, and layers of spongy pyrite interlayered with bedding laminations, also appear to indicate replacement of organic matter by pyrite. Stage 1 pyrite contains up to 0.06 wt percent gold. The ??34S values of pyrite in and near pyritic ore (3.5-4.5???), in the rhyolite dome (5.1-5.4???) and in the Tillery Formation (5.9-6.2???) are interpreted to reflect mixing of sulfur derived from igneous and seawater sources. Whole-rock ??18O values of nearby unaltered mudstone are about 11 per mil whereas those from altered mudstone at the deposit are 7.4 to 10.6 per mil. The lower ?? 18O values are interpreted to indicate possible high-temperature exchange between relatively low ??18O hydrothermal fluids and the wall rocks. Gold, As, K, and Mo are enriched relative to the regional background in both the ore zones and in pyrite veins and disseminations in the nearby rhyolite dome, suggesting a possible genetic link between the rhyolitic volcanism and the gold mineralization. ?? 2007 Society of Economic Geologists, Inc.

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