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Detection of crystalline hematite mineralization on Mars by the Thermal Emission Spectrometer: evidence for near-surface water

The Thermal Emission Spectrometer (TES) instrument on the Mars Global Surveyor (MGS) mission has discovered a remarkable accumulation of crystalline hematite (α-Fe 2 O 3 ) that covers an area with very sharp boundaries approximately 350 by 350–750 km in size centered near 2°S latitude between 0° and 5°W longitude (Sinus Meridiani). Crystalline hematite is uniquely identified by the presence of fundamental vibrational absorption features centered near 300, 450, and >525 cm −1 and by the absence of silicate fundamentals in the 1000 cm −1 region. Spectral features resulting from atmospheric CO 2 , dust, and water ice were removed using a radiative transfer model. The spectral properties unique to Sinus Meridiani were emphasized by removing the average spectrum of the surrounding region. The depth and shape of the hematite fundamental bands show that the hematite is crystalline and relatively coarse grained (>5–10 μm). Diameters up to and greater than hundreds of micrometers are permitted within the instrumental noise and natural variability of hematite spectra. Hematite particles <5–10 μm in diameter (as either unpacked or hard-packed powders) fail to match the TES spectra. The spectrally derived areal abundance of hematite varies with particle size from ∼10% (>30 μm diameter) to 40–60% (10 μm diameter). The hematite in Sinus Meridiani is thus distinct from the fine-grained (diameter <5–10 μm), red, crystalline hematite considered, on the basis of visible, near-IR data, to be a minor spectral component in Martian bright regions like Olympus-Amazonis. Sinus Meridiani hematite is closely associated with a smooth, layered, friable surface that is interpreted to be sedimentary in origin. This material may be the uppermost surface in the region, indicating that it might be a late stage sedimentary unit or a layered portion of the heavily cratered plains units. We consider five possible mechanisms for the formation of coarse-grained, crystalline hematite. These processes fall into two classes depending on whether they require a significant amount of near-surface water: the first is chemical precipitation that includes origin by (1) precipitation from standing, oxygenated, Fe-rich water (oxide iron formations), (2) precipitation from Fe-rich hydrothermal fluids, (3) low-temperature dissolution and precipitation through mobile ground water leaching, and (4) formation of surface coatings, and the second is thermal oxidation of magnetite-rich lavas. Weathering and alteration processes, which produce nanophase and red hematite, are not consistent with the coarse, crystalline hematite observed in Sinus Meridiani. We prefer chemical precipitation models and favor precipitation from Fe-rich water on the basis of the probable association with sedimentary materials, large geographic size, distance from a regional heat source, and lack of evidence for extensive groundwater processes elsewhere on Mars. The TES results thus provide mineralogic evidence for probable large-scale water interactions. The Sinus Meridiani region may be an ideal candidate for future landed missions searching for biotic and prebiotic environments, and the physical characteristics of this site satisfy all of the engineering requirements for the missions currently planned.

Journal of Geophysical Research E: Planets

Errors in acoustic doppler profiler velocity measurements caused by flow disturbance

Acoustic Doppler current profilers (ADCPs) are commonly used to measure streamflow and water velocities in rivers and streams. This paper presents laboratory, field, and numerical model evidence of errors in ADCP measurements caused by flow disturbance. A state-of-the-art three-dimensional computational fluid dynamic model is validated with and used to complement field and laboratory observations of flow disturbance and its effect on measured velocities. Results show that near the instrument, flow velocities measured by the ADCP are neither the undisturbed stream velocity nor the velocity of the flow field around the ADCP. The velocities measured by the ADCP are biased low due to the downward flow near the upstream face of the ADCP and upward recovering flow in the path of downstream transducer, which violate the flow homogeneity assumption used to transform beam velocities into Cartesian velocity components. The magnitude of the bias is dependent on the deployment configuration, the diameter of the instrument, and the approach velocity, and was observed to range from more than 25% at 5cm from the transducers to less than 1% at about 50cm from the transducers for the scenarios simulated. ?? 2007 ASCE.

Journal of Hydraulic Engineering

Assessing factors affecting the thermal properties of a passive thermal refuge using three-dimensional hydrodynamic flow and transport modeling

Everglades restoration activities may cause changes to temperature and salinity stratification at the Port of the Islands (POI) marina, which could affect its suitability as a cold weather refuge for manatees. To better understand how the Picayune Strand Restoration Project (PSRP) may alter this important resource in Collier County in southwestern Florida, the USGS has developed a three-dimensional hydrodynamic model for the marina and canal system at POI. Empirical data suggest that manatees aggregate at the site during winter because of thermal inversions that provide warmer water near the bottom that appears to only occur in the presence of salinity stratification. To study these phenomena, the environmental fluid dynamics code simulator was used to represent temperature and salinity transport within POI. Boundary inputs were generated using a larger two-dimensional model constructed with the flow and transport in a linked overland-aquifer density-dependent system simulator. Model results for a representative winter period match observed trends in salinity and temperature fluctuations and produce temperature inversions similar to observed values. Modified boundary conditions, representing proposed PSRP alterations, were also tested to examine the possible effect on the salinity stratification and temperature inversion within POI. Results show that during some periods, salinity stratification is reduced resulting in a subsequent reduction in temperature inversion compared with the existing conditions simulation. This may have an effect on POI’s suitability as a passive thermal refuge for manatees and other temperature-sensitive species. Additional testing was completed to determine the important physical relationships affecting POI’s suitability as a refuge.

Florida

Interrelations among the soil-water retention, hydraulic conductivity, and suction-stress characteristic curves

The three fundamental constitutive relations that describe fluid flow, strength, and deformation behavior of variably saturated soils are the soil-water retention curve (SWRC), hydraulic conductivity function (HCF), and suction-stress characteristic curve (SSCC). Until recently, the interrelations among the SWRC, HCF, and SSCC have not been well established. This work sought experimental confirmation of interrelations among these three constitutive functions. Results taken from the literature for six soils and those obtained for 11 different soils were used. Using newly established analytical relations among the SWRC, HCF, and SSCC and these test results, the authors showed that these three constitutive relations can be defined by a common set of hydromechanical parameters. The coefficient of determination for air-entry pressures determined independently using hydraulic and mechanical methods is >0.99, >0.98 for the pore size parameter, and 0.94 for the residual degree of saturation. One practical implication is that one of any of the four experiments (axis-translation, hydraulic, shear-strength, or deformation) is sufficient to quantify all three constitutive relations.

Journal of Geotechnical and Geoenvironmental Engin

Spring mudflows at Wrightwood, Southern California

The Wrightwood area in the San Gabriel Mountains of southern California is known as a site of recurring mudflow activity. The community of Wrightwood is built on the coalesced fans of Sheep, Acorn and Heath Creeks, and the fan deposits are probably chiefly of mudflow origin. Historically, mudflows there have been observed in association with three climatic conditions: (1) short period of high-intensity rainfall during the summer dry season (thunderstorms); (2) periods of heavy rainfall during the October-March winter season, when most of the year's rain and snow fall; and (3) thaw of the winter snow pack. The mudflow activity associated with heavy rainfall has generally been of only a few hours or at most a few days duration. Mudflow activity associated with spring thaw has been of longer duration, as much as several weeks. At various times in the past, mudflows generated by all three conditions have inundated homes and highways in the Wrightwood area, which is now defended by a flood control levee system. During May and June, 1969 the rapid melting of a heavy snow pack resulted in a 40-day period of mudflow activity in Heath Creek. All flows originated in the steep upper reaches of Heath Creek, where steep ravines are incised in the toe of a large active landslide. Direct observation by the authors showed that flows formed when small masses of debris fell or slid from the surface of the landslide mass into the steep channel. Some of the masses were fluid enough to continue downstream without interruption; others stopped in the channel until remobilized by added melt water or the passage of a mudflow from a higher altitude. Both processes resulted in discrete ‘slugs’ which continued down the steep ravine, through an allu-viated canyon, to a fan where most of the debris was deposited. The activity may be described as a spring mudflow cycle, within which three stages were observed in a gradational sequence. A waxing stage began with sporadic short-duration mudflows, during which the lower alluviated canyon floor of Heath Creek was aggraded. A climactic stage of larger mudflows at more frequent intervals and of longer duration was characterized by the incision of a single, narrow, U-shaped channel in the alluviated canyon floor, and transportation of debris as much as 2 miles (3.2 km) from the source. A waning stage followed as meltwater supply decreased; short-duration flows backfilled the U-shaped channel and spilled over the banks, again aggrading the alluviated canyon floor.

California

Groundwater contamination downstream of a contaminant penetration site. I. Extension-expansion of the contaminant plume

This study concerns the possible use of boundary layer (BL) approach for the analysis and evaluation of contaminant transport in groundwater due to contaminant penetration into the groundwater aquifer through a site of limited size. The contaminant penetration may occur through either the upper (surface) or lower (bedrock) boundary of the aquifer. Two general cases of contaminant penetration mechanisms are considered: (1) the contaminant is transferred through an interface between a contaminating and freshwater fluid phases, and (2) the contaminant arrives at groundwater by leakage and percolation. For the purpose of BL evaluation the contaminant plume is divided into three different sections: (1) the penetration section, (2) the extension-expansion section, and (3) the spearhead section. In each section a different BL method approach yields simple analytical expressions for the description of the contaminant plume migration and contaminant transport. Previous studies of the BL method can be directly applied to the evaluation of contaminant transport at the contaminant penetration section. The present study extends those studies and concerns the contaminant transport in the two other sections, which are located downstream of the penetration section. This study shows that the contaminant concentration profiles in sections 2 and 3 incorporate two BLs: (1) an inner BL adjacent to the aquifer bottom or surface boundary, and (2) an outer BL, which develops above or below the inner one. The method developed in the present study has been applied to practical issues concerning salinity penetration into groundwater in south central Kansas.

Journal of Environmental Science and Health - Part

A fuzzy logic approach for estimating recovery factors of miscible CO2-EOR projects in the United States

"Recovery factor (RF) is one of the most fundamental parameters that define engineering and economical success of any operational phase in oil and gas production. The effectiveness of the operation, e.g. CO2-EOR (enhanced oil recovery with carbon dioxide injection), is usually defined by multiplying the resultant recovery factor by the original oil in place. Moreover, investment decisions for such engineering projects are also performed based on predicted recovery factors. Despite its importance, though, it is not easy to predict recovery factors as they are affected by many factors including the type of the recovery process, reservoir type, fluid properties, reservoir heterogeneity, depth, thickness, to name a few. The usual method of estimating recovery factors is laboratory experiments or numerical modeling, each of which has their own limitations due to data requirements, boundary conditions and scale effects. In this work, a fuzzy inference system approach has been adopted to predict miscible CO2-EOR recovery factors of the major field applications in the United States with the premise that it can be used as a guidance tool for making decisions based on different inputs. The fuzzy system was build using a Mamdani-type fuzzy logic inference engine, and by using reservoir data compiled from different sources as inputs and recovery factors gathered from a literature survey. Due to the limited number of field cases that could be used for this purpose, 24 sets of applications were included in the study. Selected input variables were water saturation after waterflood (Sorw), well spacing, porosity, permeability, depth, net pay thickness, initial pressure, API gravity of oil, hydrocarbon pore volume CO2 injected, and reservoir lithology. The type of membership functions were decided based on the system’s predictive performance. The model showed reasonable predictive capability for the field observations of recovery factor despite the complexity of this parameter. In addition, since the fuzzy solution was multi-dimensional due to multiple inputs, system behavior was used to demonstrate response of miscible CO2-EOR recovery factor to different inputs. "

Journal of Petroleum Science and Engineering

A distribution-based parameterization for improved tomographic imaging of solute plumes

Difference geophysical tomography (e.g. radar, resistivity and seismic) is used increasingly for imaging fluid flow and mass transport associated with natural and engineered hydrologic phenomena, including tracer experiments, in situ remediation and aquifer storage and recovery. Tomographic data are collected over time, inverted and differenced against a background image to produce ‘snapshots’ revealing changes to the system; these snapshots readily provide qualitative information on the location and morphology of plumes of injected tracer, remedial amendment or stored water. In principle, geometric moments (i.e. total mass, centres of mass, spread, etc.) calculated from difference tomograms can provide further quantitative insight into the rates of advection, dispersion and mass transfer; however, recent work has shown that moments calculated from tomograms are commonly biased, as they are strongly affected by the subjective choice of regularization criteria. Conventional approaches to regularization (Tikhonov) and parametrization (image pixels) result in tomograms which are subject to artefacts such as smearing or pixel estimates taking on the sign opposite to that expected for the plume under study. Here, we demonstrate a novel parametrization for imaging plumes associated with hydrologic phenomena. Capitalizing on the mathematical analogy between moment-based descriptors of plumes and the moment-based parameters of probability distributions, we design an inverse problem that (1) is overdetermined and computationally efficient because the image is described by only a few parameters, (2) produces tomograms consistent with expected plume behaviour (e.g. changes of one sign relative to the background image), (3) yields parameter estimates that are readily interpreted for plume morphology and offer direct insight into hydrologic processes and (4) requires comparatively few data to achieve reasonable model estimates. We demonstrate the approach in a series of numerical examples based on straight-ray difference-attenuation radar monitoring of the transport of an ionic tracer, and show that the methodology outlined here is particularly effective when limited data are available.

Geophysical Journal International