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A 10-year continuous daily simulation of chloride flux from a suburban watershed in Fairfax County, Virginia, USA

Increasing levels of chloride in surface water are associated with detrimental effects on water quality, aquatic ecosystems, infrastructure, and human health. Numerous mass-balance studies have inferred watershed transport processes by interpreting chloride inputs and outputs, but few represent internal dynamics explicitly. We constructed a coupled water/chloride mass balance model to gain insights into storage, residence time, and transport processes in a 10-km 2 urban watershed. The model, which operates over a 10-year period at a daily time scale, represents storage in a dynamic soil-moisture reservoir, quick-flow runoff from storm events, and slow-flow runoff that sustains streamflow in dry weather. The calibrated model accurately represented (a)the observed transition from a streamflow enrichment regime in cold months to a dilution regime in warmer months, (b) the observed tendency for late-summer concentrations to be higher after winters with heavy snowfall, and (c) a period-of-record downward trend in chloride concentration likely associated with a downward trend in annual snowfall. Estimated chloride inputs averaged 195 metric tons per year, while the average output was 270 metric tons per year. In contrast, estimated storage was only 107 metric tons. The estimated mean residence time in groundwater was 1.27 years. This short residence time indicates that efforts to reduce inputs will manifest as decreased concentrations in streamflow on a management-relevant time scale of several years. The coupled mass balance model yielded insights into internal watershed dynamics that would not be possible from simple input/output analysis; such models can be useful tools for gaining insight into small watershed hydrology and pollutant transport.

Virginia

Pesticides in surface waters of the Upper Colorado River Basin, Colorado, 1996-98

Forty-four river, stream, and drain sites in the Upper Colorado River Basin in Colorado were sampled during 1996-98 to determine the occurrence and distribution of pesticides in the basin. In a fixed-station study, 57 surface-water samples were collected from October 1996 through January 1998 at four sites. Each site was sampled approximately monthly for up to a year, with more frequent sampling during the spring and summer growing season. In a synoptic study, surface-water samples were collected at 43 sites in the agricultural areas of the Grand Valley and the Uncompahgre River Valley in May 1998. Each site was sampled once. Pesticide concentrations generally were low and varied seasonally and across land uses. Thirty-five pesticides were detected at least once in the two studies, and 11 pesticides accounted for almost 82 percent of the detections. Herbicides were more commonly detected than insecticides, and only the herbicides alachlor and atrazine were detected in more than 50 percent of the samples. Carbofuran was the most commonly detected insecticide and was detected in 19 percent of the samples. Pesticide detections increased and were measured at higher concentrations in the summer months and at the agriculture sites. All pesticide concentrations were less than drinking-water standards, and most complied with human-health advisories and criteria for the protection of freshwater aquatic life. Pesticides in the Upper Colorado River Basin in Colorado were detected slightly less frequently and generally at lower concentrations than in 20 National Water-Quality Assessment Program study-unit basins that collected water-quality data from 1992 through 1996. Results from surface-water sampling conducted during 1996?98 in the Upper Colorado River Basin in Colorado indicate that beneficial uses of water were not being impaired by the presence of pesticides in surface waters in the basin.

Colorado

Evolution of arsenic speciation during thermal treatment simulating wildfire heating in arsenic-rich sediments

Understanding arsenic transformations during wildfires can help better constrain the environmental impacts of increased wildfire intensity, frequency, and burned area. Previous studies have monitored the evolution of metal(loid) speciation at specific time/temperature endpoints, hampering the comprehension of the dynamic transformations of metal(loid)s during wildfires. Here, a novel approach, namely in situ time-resolved X-ray absorption near edge structure (TR-XANES) spectroscopy, was used for the first time to monitor the heat-induced redox transformations of arsenic (As) in two As-rich sediments with different characteristics. No arsenic transformations were observed in either sediment at room temperature or when the sediments were heated to a maximum temperature of 400 ºC. When heated to a maximum temperature of 600 or 700 ºC, As underwent complex, dynamic, and partially reversible redox transformations, the extent of which varied with sediment properties, initial As speciation, and heating temperature and duration. In the case of sediments initially containing As(V) and a low sulfide/sulfate ratio, the As(V) was reduced to As(III) over a short period of time, followed by immediate reoxidation of As(III) to As(V). The extent of the transient As reduction increased with increasing maximum temperature. The final As speciation at the end of the heating experiment was not substantially different from that at the beginning of the experiment. In contrast, in sediments that were best described by a more complex combination of reference compounds (As(V) coprecipitated with or adsorbed on iron oxide, arseniosiderite, arsenopyrite) with a high sulfide/sulfate ratio, As(V) phases were reduced to As(III) and As(III) was further reduced to As(-I) (at 700 ºC, only), followed by delayed reoxidation of As(-I) to As(III) (at 700 ºC, only) and reoxidation of As(III) to As(V). Approximately 9% and 26% of all As remained as As(III) ( i.e., was not reoxidized to As(V)) at the end of the experiment when heated to a maximum temperature of 600 and 700 ºC, respectively, which is higher than the relative abundance of As(III) in the native sediment. These fire-induced As transformations can potentially enhance As mobilization to surface water and groundwater, posing risks to environmental and human health.

California

Pathways for potential exposure to onshore oil and gas wastewater: What we need to know to protect human health

Produced water is a chemically complex waste stream generated during oil and gas development. Roughly four trillion liters were generated onshore in the United States in 2021 (ALL Consulting, 2022, https://www.gwpc.org/wp-content/uploads/2021/09/2021_Produced_Water_Volumes.pdf ). Efforts are underway to expand historic uses of produced water to offset freshwater needs in water-stressed regions, avoid induced seismic activity associated with its disposal, and extract commodities. Understanding the potential exposures from current and proposed produced water uses and management practices can help to inform health-protective practices. This review summarizes what is known about potential human exposure to produced water from onshore oil and gas development in the United States. We synthesize 236 publications to create a conceptual model of potential human exposure that illustrates the current state of scientific inquiry and knowledge. Exposure to produced water can occur following its release to the environment through spills or leaks during its handling and management. Exposure can also arise from authorized releases, including permitted discharges to surface water, crop irrigation, and road treatment. Knowledge gaps include understanding the variable composition and toxicity of produced water released to the environment, the performance of treatment methods, migration pathways through the environment that can result in human exposure, and the significance of the exposures for human and ecosystem health. Reducing these uncertainties may help in realizing the benefits of produced water use while simultaneously protecting human health.

Environmental Health Perspectives

Statewide cumulative human health risk assessment of inorganics-contaminated groundwater wells, Montana, USA

Across the United States, rural residents rely on unregulated and generally unmonitored private wells for drinking water, which may pose serious health risks due to unrecognized contaminants. We assessed the nature, degree, and spatial distribution of cumulative health risks from inorganic contaminants in groundwater. Our analysis included nearly 84,000 data points from 6500+ wells, across 51 of Montana's 98 watersheds, using a public groundwater database. We compared a drinking water screening level cumulative risk assessment (CRA) for inorganics based on the U.S. Environmental Protection Agency (EPA) protective health thresholds (Maximum Contaminant Level Goals, Health Advisories [MCLG-HAs]) to a CRA based on EPA public supply enforceable Maximum Contaminant Levels (MCLs). Based on median concentrations of 19 inorganics (antimony, arsenic, barium, beryllium, boron, cadmium, chromium, copper, fluoride, manganese, molybdenum, nickel, nitrate, lead, selenium, strontium, thallium, uranium, zinc), 75% of watersheds had MCLG-HA-based cumulative risk values > 1.0; arsenic and uranium contributed the most risk, followed by strontium, fluoride, manganese and boron. Hence, this screening level (Tier I) CRA indicated widespread potential for unrecognized human health risk to private well users from inorganic contaminants considering both carcinogenic and non-carcinogenic risks. Sensitivity analysis showed that benchmarks applied (MCLG-HAs versus MCLs) exerted the largest control on results. Our findings identify priority regions for Tier 2 risk assessments to elucidate local sources and distributions of geogenic versus anthropomorphic contaminants. Our study is the first statewide assessment of cumulative health risk from groundwater that we are aware of, and results support increased statewide drinking water education and testing to reduce human health risks from contaminated private well water.

Montana

Perspectives and insights gained from applying landscape ecological approaches to the Upper Mississippi riverscape

Advances in remote sensing, spatial data collection, hydraulic and geospatial models, and the maturation of landscape ecology during the early 2000s spurred the concept of rivers as landscapes or ‘riverscapes’. Since that time, the Upper Mississippi River Restoration (UMRR) Program - one of the world’s longest running large-river ecosystem restoration and monitoring programs - has applied landscape ecological principles to the Upper Mississippi River System (UMRS). I examine spatial patterns of aquatic nutrient concentrations, submersed aquatic vegetation, and fish and mussel communities, finding that within-river patterns are often patchy in nature, likely resulting from how nutrient processes and community traits interact with spatial variability in hydraulic exchange patterns. Local-scale patchy spatial patterns in the UMRS are embedded in system-scale longitudinal gradients and a hierarchical view of the river has provided a foundation for strategic river restoration planning. Key Words: Aquatic Habitat, hydraulic connectivity, patch, restoration, riverscape

BioScience

A novel drive-point multilevel system to investigate PFAS and other contaminants of global concern in the hyporheic zone of a wastewater effluent dominated stream

Contaminants found in treated wastewater discharged to streams, including pharmaceuticals and per- and polyfluoroalkyl substances (PFAS), are of global concern due to their deleterious effects on aquatic ecosystems and potential impacts to human health. Hyporheic zones have strong potential for contaminant attenuation. Assessing this potential requires collection of physical and biogeochemical data within the hyporheic zone. This study tested the applicability of a novel drive-point multilevel system (DP-MLS) for quantifying head profiles and characterizing contaminant concentrations in the hyporheic zone of a temperate region effluent dominated stream (EDS). DP-MLS, each with 4 ports, were installed in the stream bed at two sites, DS-1 and DS-2, 0.2 and 4.7 km downstream of the effluent outfall, respectively. Head profiles were measured and groundwater collected for analysis of pharmaceuticals and PFAS temporally over two years. The DP-MLS withstood rapid changes in stage, ice formation, and floating debris. Vertical hydraulic gradients (VHG) were generally upward but varied in magnitude indicating heterogeneity in hydraulic conductivity and variability in flow conditions. Upward VHG were also about 2X larger at DS-1 than at DS-2. Contaminant concentration profiles consistently showed penetration of pharmaceuticals and PFAS to 1 m below the bed at DS-2 while there was less penetration, lower groundwater concentrations, and more temporal variability in concentrations at DS-1. Integration of the physical and chemical data suggests weaker upwelling conditions at DS-2 are more easily reversed during periods of high stream stage, which could facilitate migration of wastewater contaminants into the bed. However, further studies incorporating other transport processes and reach scale dynamics are required to fully characterize these exchanges. Overall, this study demonstrates the efficacy of these novel DP-MLSs for characterization of the hyporheic zone and provides new insights into the occurrence, composition, and persistence of wastewater derived contaminants in the hyporheic zone of a well-studied EDS.

Iowa

U.S. Geological Survey science strategy to address white-nose syndrome and bat health in 2025–2029

Since its discovery in 2006, the fungal disease known as white-nose syndrome (WNS) has killed millions of bats. Of the 47 bat species native to the conterminous United States, Alaska, Hawaii, and Canada, 12 have been affected by WNS, including 3 endangered species and 1 proposed endangered species. WNS has also been detected in 40 States and 9 Canadian Provinces. U.S. Geological Survey (USGS) scientists have been critical in identifying the causal fungus for WNS ( Pseudogymnoascus destructans [Pd]), characterizing the effects of WNS, and tracking the spread of Pd in many bat populations in North America. The mission of the USGS WNS and Bat Health Science Team is to deliver integrated science in order to build resiliency into free-ranging bat populations through more effective WNS management, build capacity for bat health science, and enhance bat health information sharing across USGS science centers and cooperative research units as well as with stakeholders. The USGS can play an important role in supporting regional and national capacity building by providing resources and guidance to local, State, and Tribal management entities and by providing tools to enhance disease management. The USGS Ecosystems Mission Area’s Biological Threats and Invasive Species Research Program is the lead Federal program for free-ranging wildlife disease research and surveillance. As of 2024, guided by the science priorities set by the WNS Steering Committee, USGS scientists are engaged in a nationwide response to WNS. This work is done in close coordination with our partners at the U.S. Fish and Wildlife Service, National Park Service, Bureau of Land Management, U.S. Forest Service of the U.S. Department of Agriculture, U.S. Department of Defense, as well as State and Tribal agencies. In addition to conducting WNS research, the USGS is mapping the spread of WNS and coordinating the North American Bat Monitoring Program (NABat) to understand how WNS and other stressors affect the status and trends of native bats across their range. The USGS is supporting the national WNS response through four science goals: (1) provide situational awareness on the health of bat populations; (2) conduct ecological studies of bats along the gradient of disease vulnerability; (3) contribute actionable science to enhance the resiliency of bat populations; and (4) implement an adaptive, holistic approach to bat health.

Circular

Multidecadal change in pesticide concentrations relative to human health benchmarks in the Nation’s groundwater

Groundwater-quality trend assessments identify aquifers that are responding to changes in pesticide use and the compounds that may pose a threat to water availability. The U.S. Geological Survey has been monitoring pesticide concentrations in groundwater for 25 principal aquifers across the conterminous United States since 1993. The groundwater well locations represent a range of soils, climate, and landforms. The wells are used to monitor groundwater underlying selected agricultural and urban settings and groundwater used for domestic supply. This study examined changes in relative concentrations, defined here as the percentage of wells with pesticide concentrations exceeding a human health benchmark (HHB). HHBs used in this report are legally enforceable drinking-water standards and nonenforceable drinking water levels. Relative pesticide concentration increases may lead to decreased water availability, as restrictions may be put in place for groundwater used as a drinking-water source. This study focused on concentration changes in 22 pesticides that were included in laboratory analysis from 1993 to 2023. The analysis and interpretation of these pesticide concentrations in groundwater have been separated into approximate decadal intervals (decade 1 (1993–2001), decade 2 (2002–12), and decade 3 (2013–22). For one pesticide, 1,2-dibromo-3-chloropropane (DBCP), concentration data were also collected in decade 4 (2023–onward). Atrazine, deethylatrazine, alachlor, prometon, and simazine were 5 pesticides detected at moderate concentrations (greater than 10 percent of the HHB but less than or equal to the HHB). The percentage of wells that had groundwater pesticide concentrations in the moderate concentration category decreased from 7 percent in decade 1 to 2 percent in decade 3. The agricultural networks had the highest percentages of wells with moderate concentrations, and these percentages decreased from 13 percent in decade 1 to 4 percent in decade 3. Moderate concentrations in the urban networks decreased between decades 1 and 2 from 4 percent to 0 percent. No moderate concentrations occurred in the urban networks in decade 3. The percentage of wells with moderate concentrations in the domestic supply networks (1 percent) was the lowest of all the network types and did not change across the three decades. Moderate atrazine or deethylatrazine concentrations occurred across all three decades in aggregated ecoregions representing similar soils, climate, and landforms in the Semiarid West, Midcontinent, and Northeastern United States. Moderate concentrations of prometon, alachlor, and simazine also occurred in the Midcontinent, Arid West, Northeast, South Atlantic Gulf, and Semiarid West regions, but the moderate concentrations did not persist across all three decades. DBCP was the only pesticide that exceeded its respective HHB, and the exceedances occurred across all four decades. In this report, the DBCP analysis was limited to one well network in the Central Valley, California. Agricultural use of DBCP was suspended in 1977. Forty-five years after being banned, DBCP concentrations were greater than the maximum contaminant level of 2 micrograms per liter (μg/L), but the number of exceedances decreased from 50 percent to 15 percent of the samples between 1993 and 2023. This assessment of decadal groundwater pesticide concentrations provides a characterization of changes in water availability because of pesticide contamination in areas where groundwater is used as a drinking-water source. The results highlight the importance of continued long-term monitoring and assessment of groundwater pesticides to identify locations and specific compounds that may pose a potential risk to human health.

continental United States

Water table rise sustains carbon release from soils in wetland-dominated landscapes: An intact soil core study

Wetland-dominated landscapes influence carbon cycling through their potential to act as both carbon sinks and sources. Wetlands in low-relief landscapes have dynamic terrestrial-aquatic interfaces that change seasonally with variable surface water and groundwater levels. However, few studies have directly quantified dissolved organic matter (DOM) release and greenhouse gas (CO 2 , CH 4 ) fluxes from wetland soils along terrestrial-aquatic interfaces as they are seasonally re-saturated by groundwater. To estimate groundwater-mediated soil DOM and gas fluxes, we performed laboratory simulations of vertical groundwater rise on intact soil cores collected from four Delmarva bay wetlands located in the Mid-Atlantic United States. At each wetland, one core was collected from within the wetland basin and the other from the transitional zone at the basin edge. Cores were re-saturated with groundwater over 15 days and then kept fully saturated for an additional 25 days. Source groundwater, soil porewater, and exfiltrated surface water samples were collected and analyzed for pH, ORP, DOM concentration, and DOM optical indices. In both the wetland and transition zone cores, porewater DOM concentrations increased over the wet up and were sustained during prolonged saturation. Optical indices shifted from recently produced, microbial-like signatures towards aromatic, terrestrial-like signatures. Fluxes of CO 2 decreased as the duration of soil saturation increased and soil cores switched from CH 4 sinks to sources upon full soil core saturation. Results indicate that groundwater rise sustains carbon mobilization from soils in wetland-dominated landscapes, emphasizing the need to understand how climate-driven changes to groundwater dynamics may affect carbon fluxes along terrestrial-aquatic interfaces.

Delaware, Maryland

High-resolution landscape-scale maps of nutrients, phytoplankton, and related water-quality constituents in Suisun Bay and the Sacramento–San Joaquin Delta, California, during 2018—Results from high-resolution underway surveys

We examined the abundance and distribution of nutrients and phytoplankton in the tidal aquatic environments of the Sacramento–San Joaquin Delta (Delta) and Suisun, Grizzly, and Honker Bays in California by completing three spatial surveys that used continuous underway high frequency (1 hertz) measurements and sampling onboard a high-speed boat. Surveys were conducted in May, July, and October 2018. Water was sampled continuously during surveys to simultaneously collect information about the concentration and spatial distribution of all major nutrient forms together with information about the major classes of phytoplankton and associated standard field measurements of water quality, such as dissolved oxygen, dissolved organic matter, pH, salinity, specific conductance, turbidity, and water temperature. The results show a greater than 50-fold variation in nutrient and phytoplankton concentrations across space and time, providing evidence of the dynamic environmental processes that shape the ways nutrients interact with and affect Delta aquatic habitats.

Data Report

New York and Landsat

From the iconic skyline of New York City to the forested landscapes of the Adirondack Mountains and the countryside of the Allegheny Plateau, the State of New York is overflowing with diversity and life. Bordered by the Atlantic Ocean on the east and two of the Great Lakes to the north and west, New York has more than 7,600 lakes, ponds, and reservoirs and more than 70,000 miles of rivers and streams. New York’s stewardship of its freshwater resources is fundamental to the health and well-being of all who work at, reside in, and visit the State’s landmarks and places. Harmful algal blooms in the State’s waterbodies are a growing concern and threaten the health of the region and its inhabitants. Images and data from Landsat satellites continue to provide critical information to scientists, public health officials, and resource managers who are studying the effects and risks of the problem.

New York

Investigation of drivers and sources of potential harmful algal blooms in Lake Anna, Virginia, 2023-24

Algal blooms in freshwater reservoirs are an increasing concern because of the risk to aquatic ecosystem health, recreational use, and water quality. Among the taxa that comprise an algal bloom, cyanobacteria are of particular concern due to the potential to produce toxic compounds which can cause acute and chronic illness in humans if ingested through contaminated water or shellfish. When toxins are above a toxin-specific threshold in the water column, the Commonwealth of Virginia categorizes the bloom as a harmful algal bloom (HAB), distinguishing it from an algal bloom without toxins present. Toxins are of particular concern in bodies of water which serve as major recreational areas, such as Lake Anna in central Virginia. Lake Anna is a 27 km-long and 47 km2 reservoir in central Virginia. Since the Commonwealth of Virginia revised the HAB monitoring framework in 2018, algal bloom advisories for potentially toxigenic blooms have been issued in the western, riverine zone of the reservoir. There were detections of microcystin and anatoxin production but no detections of cylindrospermopsin and saxitoxin production in Lake Anna; however, toxin concentrations were low, at values less than 0.65 µg/L. In 2023, the U.S. Geological Survey, in cooperation with Virginia Department of Environmental Quality, initiated a 19-month intensive and extensive study of western Lake Anna and its tributaries (North Anna River and Pamunkey Creek) to (1) characterize the algal community, biomass, and toxin production; (2) identify potential drivers leading to algal bloom initiation, persistence, and decline; and (3) assess the primary sources of the drivers contributing to algal blooms. Continuous and discrete monitoring of water quality within the lake, watershed inputs, meteorological conditions, and algal communities were monitored. Multiple modeling scenarios identified that the formation and persistence of algal blooms in Lake Anna are driven by interactions among chemical, macro- and micronutrient, and physical factors. Key drivers include total nitrogen, total phosphorus, water temperature, suspended sediment concentration, wind speed, copper, iron, molybdenum, nickel, sodium, and alkalinity. During this study, winter stormflow events delivered the highest loading of macro- and micronutrients from the tributaries to the lake. The lake is a sink for these nutrients in the water column or in the lake-bed sediments. During high-occupancy and recreation periods on the lake in the summer months, boating activity can promote internal loading by the resuspension of the lake-bed sediments, thereby increasing the nutrient availability for algal uptake. Thermal stratification and hypoxic conditions were observed, which can contribute to the passive release of nutrients into the water column, further facilitating algal bloom proliferation. These processes may create a positive feedback loop that supports the formation, persistence, and annual recurrence of algal blooms in the western region of Lake Anna. Continued water-quality monitoring of early warning indicators may improve the detection and forecasting of algal growth in the lake and help managers proactively manage water quality and algal growth.

EarthArXiv

Chronic exposure to waterborne nickel significantly reduced growth of juvenile crayfish (Faxonius virilis)

Crayfish are critical functional components of aquatic ecosystems. Previous research has documented adverse effects of mineral extraction on crayfish. Here, we characterize potential risks of mining-derived waterborne nickel (Ni) to crayfish by documenting the effects of dissolved Ni on growth and food consumption of juvenile virile crayfish ( Faxonius virilis) in a 28-day chronic laboratory exposure. Nominal Ni concentrations ranged from 31.25 to 500 micrograms per liter (µg/L; pH = 7.96 ± 0.20, hardness = 150 ± 1 milligrams per liter as calcium carbonate). Crayfish survival, carapace length, and wet weight were measured. After 28 days of exposure, a 24-h feeding trial was performed to determine differences in food consumption. During the growth trial, 99% of crayfish survived. Change in wet weight and final wet weight were the most sensitive endpoints, with 20% effect concentrations of 24.8 and 22.6 µg/L Ni, respectively. Crayfish exposed to an average of 438 µg/L Ni consumed 41% less, and weighed 65.1% less, than control crayfish. These results suggest chronic, sublethal exposure to waterborne Ni may have negative effects on crayfish growth. Reduced growth and consumption rates in crayfish could have wide-ranging consequences throughout aquatic ecosystems since crayfish are consumers, prey, keystone trophic regulators, and ecosystem engineers. Finally, these results could inform bioenergetics and may be coupled with population models to predict potential changes in population sizes of native and invasive crayfishes.

Ecotoxicology

Microclimate mediates the strength and direction of avian biotic interactions

Theory predicts that that the strength and direction of species interactions can shift from being competitive in benign environments toward being facilitative in stressful environments. However, the environmental context dependency of species interactions has rarely been tested in animal communities. We capitalized on a 15-year, landscape-scale dataset, collected annually in a relatively stable old-growth forest environment to test the long-held hypothesis that the strength and direction of species interactions might be mediated by climatic conditions. It is generally accepted that competitive and facilitative interactions drive the distributions of many species. Using multi-species dynamic occupancy models applied to long-term data, we tested whether annual settlement by bird species could affect either the persistence or settlement by other phylogenetically related species, and whether these interactions are mediated by microclimate. We found that species interactions were influenced by microclimate for some, but not all avian species pairs. Related species pairs more often showed settlement dynamics that were indicative of attraction rather than repulsion. In some cases, competitive interactions at warmer microclimates flipped to become facilitative in colder ones. However, the reverse was also true: facilitative interactions amplified for some species under warm conditions. Furthermore, species pairs that were closely related were more likely to exhibit competitive relationships along at least part of the microclimatic gradient. Our results highlight the importance of using long-term data to incorporate competitive and facilitative interactions into species distribution models and support the notion that the strength and direction of species interactions can be dependent on microclimatic environmental conditions.

Oregon

Using the D-Claw software package to model lahars in the Middle Fork Nooksack River drainage and beyond, Mount Baker, Washington

Lahars, or volcanic mudflows, are the most hazardous eruption-related phenomena that will affect communities living along rivers that originate on Mount Baker. In the past 15,000 years, the largest lahars from Mount Baker have affected the Middle Fork Nooksack River drainage and beyond. Here we use the physics-based D-Claw software package to model nine lahar scenarios that are initiated as water-saturated landslides between Sherman Crater and the Roman Wall on the Mount Baker edifice and flow down the Middle Fork Nooksack River. The scenarios range in volume from 1 to 260 million cubic meters and have an initial hydraulic permeability from 10 −12 to 10 −10 meters squared. Model output includes data such as flow depth, velocity, runout distance, area inundated, arrival time, and sediment concentration as well as information that allows scientists to calculate other important hydrologic characteristics such as lahar discharge. These data are important to officials who have the responsibility to plan for, or take mitigation measures against, future Mount Baker lahars. To check the validity of the D-Claw results, we compare the scenarios to known geologic information. We also compare D-Claw results with empirical models that have been used in the past to determine potential inundation areas, runout distances, and arrival times. These comparisons highlight similarities and differences between empirical and physics-based models. We also present D-Claw scenario-based animations to help scientists, officials, and lay people alike to visualize how future lahars could affect communities.

Washington

Monthly variability and possible sources of nitrate in ground water beneath mixed agricultural land use, Suwannee and Lafayette Counties, Florida

In an area of mixed agricultural land use in Suwannee and Lafayette Counties of northern Florida, water samples were collected monthly from 14 wells tapping the Upper Floridan aquifer during July 1998 through June 1999 to assess hydrologic and land-use factors affecting the variability in nitrate concentrations in ground water. Unusually high amounts of rainfall in September and October 1998 (43.5 centimeters total for both months) resulted in an increase in water levels in all wells in October 1998. This was followed by unusually low amounts of rainfall during November 1998 through May 1999, when rainfall was 40.7 centimeters below 30-year mean monthly values. The presence of karst features (sinkholes, springs, solution conduits) and the highly permeable sands that overlie the Upper Floridan aquifer provide for rapid movement of water containing elevated nitrate concentrations to the aquifer. Nitrate was the dominant form of nitrogen in ground water collected at all sites and nitrate concentrations ranged from less than 0.02 to 22 milligrams per liter (mg/L), as nitrogen. Water samples from most wells showed substantial monthly or seasonal fluctuations in nitrate concentrations. Generally, water samples from wells with nitrate concentrations higher than 10 mg/L showed the greatest amount of monthly fluctuation. For example, water samples from six of eight wells had monthly nitrate concentrations that varied by at least 5 mg/L during the study period. Water from most wells with lower nitrate concentrations (less than 6 mg/L) also showed large monthly fluctuations. For instance, nitrate concentrations in water from four sites showed monthly variations of more than 50 percent. Large fluctuations in nitrate concentrations likely result from seasonal agricultural practices (fertilizer application and animal waste spreading) at a particular site. For example, an increase in nitrate concentrations observed in water samples from seven sites in February or March 1999 most likely results from application of synthetic fertilizers during the late winter months. Lower nitrate concentrations were detected in water samples from five of eight wells sampled during high-flow conditions for the Suwannee River in March 1998 compared to low-flow conditions in November 1998. Evidence for reduction of nitrate due to denitrification reactions was observed at one site (AC-1), as indicated by elevated concentrations of nitrogen gas and a corresponding increase in nitrogen isotope (d15N-NO3) values with a decrease in nitrate concentrations. Denitrification is unlikely at other sites based on the presence of dissolved oxygen concentrations greater than 2 mg/L in ground water and no observed trend between nitrate concentrations and values d15N-NO3 values. Nitrate was the dominant nitrogen species in most monthly rainfall samples; however, ammonium concentrations were similar or greater than nitrate during November and December 1998. During February through May 1999, both nitrate and ammonium concentrations were substantially higher in monthly rainfall samples collected at the study area compared to mean monthly concentrations at the Bradford Forest site located east of the study area, which is part of the National Atmospheric Deposition Program/National Trends Network. Also, higher nitrogen deposition rates in the study area compared to those at Bradford Forest could indicate that substantial amounts of ammonia are volatilized from fertilizers and animal wastes, released to the atmosphere, and incorporated as nitrate and ammonium in rainfall deposited in the middle Suwannee River Basin. Ground-water samples from most sites had d15N-NO3 values that indicated a mixture of inorganic and organic sources of nitrogen, which corresponded to multiple land uses where both synthetic fertilizers and manure are used on fields near these sites. Distinct d15N-NO3 signatures, however, were observed at some sites. For example, water samples from areas of row-crop farming as the dominant land use had d15N-NO3 values less than 4 per mil, indicating an inorganic nitrogen source such as synthetic fertilizer. In contrast, d15N-NO3 values greater than 9 per mil were found in water samples from three sites where manure from dairy and or poultry operations is spread on fields throughout the year.

Florida