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USGS2023

Annotated bibliography of scientific research on greater sage-grouse published from October 2019 to July 2022

Integrating recent scientific knowledge into management decisions supports effective natural resource management and can lead to better resource outcomes. However, finding and accessing scientific knowledge can be time consuming and costly. To assist in this process, the U.S. Geological Survey (USGS) created a series of annotated bibliographies on topics of management concern for western lands. Previously published reports introduced a methodology for preparing annotated bibliographies to facilitate integration of recent, peer-reviewed science into resource management decisions. Therefore, relevant text from those efforts is reproduced here and built on to incorporate new information. The greater sage-grouse (Centrocercus urophasianus; hereafter “GRSG”) has been a focus of scientific investigation and management action for the past two decades. The 2015 U.S. Fish and Wildlife Service listing determination of “not warranted” under the Endangered Species Act was in part a result of a large-scale collaborative effort to develop strategies to conserve GRSG populations and their habitat and to reduce threats to both. New scientific information augments existing knowledge and can help inform updates or modifications to existing plans for managing GRSG and sagebrush ecosystems. However, the sheer number of scientific publications can be a challenge for managers tasked with evaluating and determining the need for potential updates to existing planning documents. To assist in this process, the USGS has reviewed and summarized the scientific literature published since January 1, 2015. Our most recent GRSG literature summary was published in 2020 (Carter and others, 2020) and included products published through October 2, 2019. Here, we consider products published between October 2, 2019, and July 21, 2022. We compiled and summarized peer-reviewed journal articles, data products, and formal technical reports (such as U.S. Department of Agriculture Forest Service General Technical Reports and USGS Open-File Reports) on greater sage-grouse. We first systematically searched three reference databases and three government databases using the search phrase “greater sage-grouse.” We refined the initial list of products by removing (1) duplicates, (2) publications not published as research, data products, or scientific review articles in peer-reviewed journals or as formal technical reports, and (3) products for which greater sage-grouse was not a research focus or the study did not present new data or findings about greater sage-grouse. We summarized each product using a consistent structure (background, objectives, methods, location, findings, and implications) and identified management topics addressed by each product; for example, species and population characteristics. We also identified projects that provided new geospatial data. The review process for this annotated bibliography included two initial internal colleague reviews of each summary, requesting input on each summary from an author of the original publication, and formal peer review. Our initial searches resulted in 221 total products, of which 147 met our criteria for inclusion. Across products summarized in the annotated bibliography, broad-scale habitat characteristics, behavior or demographics, site-scale habitat characteristics, habitat selection, and population estimates or targets were the most commonly addressed management topics. The online version of this bibliography, which will be available on the Science for Resource Managers tool ( https://apps.usgs.gov/science-for-resource-managers ), will be searchable by topic, location, and year, and will include links to each original publication. The studies compiled and summarized here may inform planning and management actions that seek to maintain and restore sagebrush landscapes and GRSG populations across the GRSG range.

Open-File Report↗

USGS2009

Sources and transformations of nitrate from streams draining varying land uses: Evidence from dual isotope analysis

Knowledge of key sources and biogeochemical processes that affect the transport of nitrate (NO 3 - ) in streams can inform watershed management strategies for controlling downstream eutrophication. We applied dual isotope analysis of NO 3 - to determine the dominant sources and processes that affect NO 3 - concentrations in six stream/river watersheds of different land uses. Samples were collected monthly at a range of flow conditions for 15 mo during 2004-05 and analyzed for NO 3 - concentrations, ?? 15 N NO3 , and ?? 18 O NO3 . Samples from two forested watersheds indicated that NO 3 - derived from nitrification was dominant at baseflow. A watershed dominated by suburban land use had three ?? 18 O NO3 values greater than +25???, indicating a large direct contribution of atmospheric NO 3 - transported to the stream during some high flows. Two watersheds with large proportions of agricultural land use had many ?? 15 N NO3 values greater than +9???, suggesting an animal waste source consistent with regional dairy farming practices. These data showed a linear seasonal pattern with a ?? 18 O NO3 :?? 15 N NO3 of 1:2, consistent with seasonally varying denitrification that peaked in late summer to early fall with the warmest temperatures and lowest annual streamflow. The large range of ?? 15 N NO3 values (10???) indicates that NO 3 - supply was likely not limiting the rate of denitrification, consistent with ground water and/or in-stream denitrification. Mixing of two or more distinct sources may have affected the seasonal isotope patterns observed in these two agricultural streams. In a mixed land use watershed of large drainage area, none of the source and process patterns observed in the small streams were evident. These results emphasize that observations at watersheds of a few to a few hundred km 2 may be necessary to adequately quantify the relative roles of various NO 3 - transport and process patterns that contribute to streamflow in large basins. Copyright ?? 2009 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗

USGS2004

Estimation of runoff and sediment yield in the Redrock Creek watershed using AnnAGNPS and GIS

Sediment has been identified as a significant threat to water quality and channel clogging that in turn may lead to river flooding. With the increasing awareness of the impairment from sediment to water bodies in a watershed, identifying the locations of the major sediment sources and reducing the sediment through management practices will be important for an effective watershed management. The annualized agricultural non-point source pollution (AnnAGNPS) model and newly developed GIS interface for it were applied in a small agricultural watershed, Redrock Creek watershed, Kansas, in this pilot study for exploring the effectiveness of using this model as a management tool. The calibrated model appropriately simulated monthly runoff and sediment yield through the practices in this study and potentially suggested the ways of sediment reduction through evaluating the changes of land use and field operation in the model for the purpose of watershed management.

Journal of Environmental Sciences↗

USGS2017

Human drivers, biophysical changes, and climatic variation affecting contemporary cropping proportions in the northern prairie of the U.S

Grassland to cropland conversion in the northern prairie of the United States has been a topic of recent land use change studies. Within this region more corn and soybeans are grown now (2017) than in the past, but most studies to date have not examined multi-decadal trends and the synergistic web of socio-ecological driving forces involved, opting instead for short-term analyses and easily targeted agents of change. This paper examines the coalescing of biophysical and socioeconomic driving forces that have brought change to the agricultural landscape of this region between 1980 and 2013. While land conversion has occurred, most of the region’s cropland in 2013 had been previously cropped by the early 1980s. Furthermore, the agricultural conditions in which crops were grown during those three decades have changed considerably because of non-biophysical alterations to production practices and changing agricultural markets. Findings revealed that human drivers played more of a role in crop change than biophysical changes, that blending quantitative and qualitative methods to tell a more complete story of crop change in this region was difficult because of the synergistic characteristics of the drivers involved, and that more research is needed to understand how farmers make crop choice decisions.

Minnesota, North Dakota, South Dakota↗

USGS2015

Modelling regional land change scenarios to assess land abandonment and reforestation dynamics in the Pyrenees (France)

Over the last decades and centuries, European mountain landscapes have experienced substantial transformations. Natural and anthropogenic LULC changes (land use and land cover changes), especially agro-pastoral activities, have directly influenced the spatial organization and composition of European mountain landscapes. For the past sixty years, natural reforestation has been occurring due to a decline in both agricultural production activities and rural population. Stakeholders, to better anticipate future changes, need spatially and temporally explicit models to identify areas at risk of land change and possible abandonment. This paper presents an integrated approach combining forecasting scenarios and a LULC changes simulation model to assess where LULC changes may occur in the Pyrenees Mountains, based on historical LULC trends and a range of future socio-economic drivers. The proposed methodology considers local specificities of the Pyrenean valleys, sub-regional climate and topographical properties, and regional economic policies. Results indicate that some regions are projected to face strong abandonment, regardless of the scenario conditions. Overall, high rates of change are associated with administrative regions where land productivity is highly dependent on socio-economic drivers and climatic and environmental conditions limit intensive (agricultural and/or pastoral) production and profitability. The combination of the results for the four scenarios allows assessments of where encroachment (e.g. colonization by shrublands) and reforestation are the most probable. This assessment intends to provide insight into the potential future development of the Pyrenees to help identify areas that are the most sensitive to change and to guide decision makers to help their management decisions.

Journal of Mountain Science↗

USGS2017

Parcels versus pixels: modeling agricultural land use across broad geographic regions using parcel-based field boundaries

Land use and land cover (LULC) change occurs at a local level within contiguous ownership and management units (parcels), yet LULC models primarily use pixel-based spatial frameworks. The few parcel-based models being used overwhelmingly focus on small geographic areas, limiting the ability to assess LULC change impacts at regional to national scales. We developed a modified version of the Forecasting Scenarios of land use change model to project parcel-based agricultural change across a large region in the United States Great Plains. A scenario representing an agricultural biofuel scenario was modeled from 2012 to 2030, using real parcel boundaries based on contiguous ownership and land management units. The resulting LULC projection provides a vastly improved representation of landscape pattern over existing pixel-based models, while simultaneously providing an unprecedented combination of thematic detail and broad geographic extent. The conceptual approach is practical and scalable, with potential use for national-scale projections.

Journal of Land Use Science↗

USGS2004

Landsat yesterday and today: An American vision and an old challenge

Since the late 1960s, the United States government has invested more than $1 billion in designing, launching, and operating the Landsat (land satellite) series of Earth-observing satellites. Global change researchers, geologists, and environmental scientists have used images gathered by the satellites for purposes ranging from human health research, energy exploration, and pollution detection to agricultural assessments, urban growth monitoring, and earthquake lineament studies. The earliest data were captured on a digital medium called wide-band video tape (WBVT). However, two decades of unsound media storage conditions and a poorly maintained processing system have left the physically deteriorating WBVTs with no mechanism for interpretation. A national treasure was in jeopardy. With seed money from the National Aeronautics and Space Administration (NASA), the U.S. Geological Survey (USGS) began a project to rescue the data. More than 21,000 tapes from the 1970s have been transcribed to stable, archival media, preserving the data for future studies in Earth System Science.

Journal of Map & Geography Libraries↗

USGS2013

Recent land-use/land-cover change in the Central California Valley

Open access to Landsat satellite data has enabled annual analyses of modern land-use and land-cover change (LULCC) for the Central California Valley ecoregion between 2005 and 2010. Our annual LULCC estimates capture landscape-level responses to water policy changes, climate, and economic instability. From 2005 to 2010, agriculture in the region fluctuated along with regulatory-driven changes in water allocation as well as persistent drought conditions. Grasslands and shrublands declined, while developed lands increased in former agricultural and grassland/shrublands. Development rates stagnated in 2007, coinciding with the onset of the historic foreclosure crisis in California and the global economic downturn. We utilized annual LULCC estimates to generate interval-based LULCC estimates (2000–2005 and 2005–2010) and extend existing 27 year interval-based land change monitoring through 2010. Resulting change data provides insights into the drivers of landscape change in the Central California Valley ecoregion and represents the first, continuous, 37 year mapping effort of its kind.

California↗

USGS2019

A bibliometric profile of the Remote Sensing Open Access Journal published by MDPI between 2009 and 2018

Remote Sensing Open Access Journal (RS OAJ) is an international leading journal in the field of remote sensing science and technology. It was first published in the year 2009 and is currently celebrating tenth year of publications. In this research, a bibliometric analysis of RS OAJ was conducted based on 5588 articles published during the 10-year (2009–2018) time-period. The bibliometric analysis includes a comprehensive set of indicators such as dynamics and trends of publications, journal impact factor, total cites, eigenfactor score, normalized eigenfactor, CiteScore, h-index, h-classic publications, most productive countries (or territories) and institutions, co-authorship collaboration about countries (territories), research themes, citation impact of co-occurrences keywords, intellectual structure, and knowledge commutation. We found that publications of RS OAJ presented an exponential growth in the past ten years. From 2010 to 2017 (for which complete years data were available), the h-index of RS OAJ is 67. From 2009–2018, RS OAJ includes publications from 129 countries (or territories) and 3826 institutions. The leading nations contributing articles, based on 2009–2018 data, and listed based on ranking were: China, United States, Germany, Italy, France, Spain, Canada, England, Australia, Netherlands, Japan, Switzerland and Austria. The leading institutions, also for the same period and listed based on ranking were: Chinese Academy of Sciences, Wuhan University, University of Chinese Academy of Sciences, Beijing Normal University, The university of Maryland, National Aeronautics and Space Administration, National Oceanic and Atmospheric Administration, China University of Geosciences, United States Geological Survey, German Aerospace Centre, University of Twente, and California Institute of Technology. For the year 2017, RS OAJ had an impressive journal impact factor of 3.4060, a CiteScore of 4.03, eigenfactor score of 0.0342, and normalized eigenfactor score of 3.99. In addition, based on 2009–2018, data co-word analysis determined that “remote sensing”, “MODIS”, “Landsat”, “LiDAR” and “NDVI” are the high-frequency of author keywords co-occurrence in RS OAJ. The main themes of RS OAJ are multi-spectral and hyperspectral remote sensing, LiDAR scanning and forestry remote sensing monitoring, MODIS and LAI data applications, Remote sensing applications and Synthetic Aperture Radar (SAR). Through author keywords citation impact analysis, we find the most influential keyword is Unmanned Aerial Vehicle (UAV), followed, forestry, Normalized Difference Vegetation Index (NDVI), terrestrial laser scanning, airborne laser scanning, forestry inventory, urban heat island, monitoring, agriculture, and laser scanning. By analyzing the intellectual structure of RS OAJ, we identify the main reference publications and find that the themes are about Random Forests, MODIS vegetation indices and image analysis, etc. RS OAJ ranks first in cited journals and third in citing, this indicates that RS OAJ has the internal knowledge flow. Our results will bring more benefits to scholars, researchers and graduate students, who hopes to get a quick overview of the RS OAJ. And this article will also be the starting point for communication between scholars and practitioners. Finally, this paper proposed a nuanced h-index (nh-index) to measure productivity and intellectual contribution of authors by considering h-index based on whether the one is first, second, third, or nth author. This nuanced approach to determining h-index of authors is powerful indicator of an academician’s productivity and intellectual contribution.

Remote Sensing↗

USGS2013

Projected surface radiative forcing due to 2000--2050 land-cover land-use albedo change over the eastern United States

Satellite-derived contemporary land-cover land-use (LCLU) and albedo data and modeled future LCLU are used to study the impact of LCLU change from 2000 to 2050 on surface albedo and radiative forcing for 19 ecoregions in the eastern United States. The modeled 2000–2050 LCLU changes indicate a future decrease in both agriculture and forested land and an increase in developed land that induces ecoregion radiative forcings ranging from −0.175 to 0.432 W m −2 driven predominately by differences in the area and type of LCLU change. At the regional scale, these projected LCLU changes induce a net negative albedo decrease (−0.001) and a regional positive radiative forcing of 0.112 W m −2 . This overall positive forcing (i.e., warming) is almost 4 times greater than that estimated for documented 1973–2000 LCLU albedo change published in a previous study using the same methods.

Journal of Land Change Science↗

USGS2021

Techniques to improve ecological interpretability of black box machine learning models

Statistical modeling of ecological data is often faced with a large number of variables as well as possible nonlinear relationships and higher-order interaction effects. Gradient boosted trees (GBT) have been successful in addressing these issues and have shown a good predictive performance in modeling nonlinear relationships, in particular in classification settings with a categorical response variable. They also tend to be robust against outliers. However, their black-box nature makes it difficult to interpret these models. We introduce several recently developed statistical tools to the environmental research community in order to advance interpretation of these black-box models. To analyze the properties of the tools, we applied gradient boosted trees to investigate biological health of streams within the contiguous USA, as measured by a benthic macroinvertebrate biotic index. Based on these data and a simulation study, we demonstrate the advantages and limitations of partial dependence plots (PDP), individual conditional expectation (ICE) curves and accumulated local effects (ALE) in their ability to identify covariate–response relationships. Additionally, interaction effects were quantified according to interaction strength (IAS) and Friedman’s H 2 "> H 2 statistic. Interpretable machine learning techniques are useful tools to open the black-box of gradient boosted trees in the environmental sciences. This finding is supported by our case study on the effect of impervious surface on the benthic condition, which agrees with previous results in the literature. Overall, the most important variables were ecoregion, bed stability, watershed area, riparian vegetation and catchment slope. These variables were also present in most identified interaction effects. In conclusion, graphical tools (PDP, ICE, ALE) enable visualization and easier interpretation of GBT but should be supported by analytical statistical measures. Future methodological research is needed to investigate the properties of interaction tests. Supplementary materials accompanying this paper appear on-line.

Journal of Agricultural, Biological, and Environme↗

USGS2008

Near-decadal changes in nitrate and pesticide concentrations in the South Platte River alluvial aquifer, 1993-2004

The lower South Platte River basin of Colorado and Nebraska is an area of intense agriculture supported by surface-water diversions from the river and ground-water pumping from a valley-fill alluvial aquifer. Two well networks consisting of 45 wells installed in the South Platte alluvial aquifer were sampled in the early 1990s and again in the early 2000s to examine near-decadal ground-water quality changes in irrigated agricultural areas. Ground-water age generally increases and dissolved-oxygen content decreases with distance along flow paths and with depdi below the water table, and denitrification is an important natural mitigation mechanism for nitrate in downgradient areas. Ground-water travel time from upland areas to the river ranges from 12 to 31 yr on the basis of apparent ground-water ages. Ground-water nitrate concentrations for agricultural land-use wells increased significantly for oxidized samples over the decade, and nitrogen isotope ratios for oxidized samples indicate synthetic fertilizer as the predominant nitrate source. Ground-water concentrations of atrazine, DEA, and prometon decreased significandy. The decrease in pesticide concentrations and a significant increase in the ratio of DEA to atrazine suggest decreases in pesticide concentrations are likely caused by local decreases in application rates and/or degradation processes and that atrazine degradation is promoted by oxidizing conditions. The difference between results for oxidizing and nitrate-reducing conditions indicates redox state is an important variable to consider when evaluating ground-water quality trends for redox-sensitive constituents such as nitrate and pesticides in the South Platte alluvial aquifer. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗

USGS2012

Development and application of methods used to source prehistoric Southwestern maize: a review

Archaeological cobs free of mineral contaminants should be used to source the soils in which they were grown. Mineral contaminants often contain much higher concentrations of metals than vegetal materials and can alter a cob’s apparent metal and heavy-isotope content. Cleaning a cob via immersion in an acid solution for more than a few minutes will result in the incongruent and sometimes complete leaching of metals, including strontium (Sr), from the cob. When using 87 Sr/ Sr to determine the location of potential agriculture fields, it is best to either integrate several depth-integrated soil samples or to integrate several vegetation samples from individual fields. Biologically labile Sr in semi-arid Southwestern soils largely originates from eolian source or sources and usually is not derived from underlying bedrock. Existing Sr-isotope data indicate that archaeological cobs from Aztec Ruins came from either the Mesa Verde-McElmo Dome or Totah areas, that Pueblo Bonito and Chetro Ketl cobs, from Chaco Canyon that predate A.D. 1130, probably came from the Rio Chaco corridor, and that cobs from Chaco Canyon, that postdate A.D. 1130, probably came from either the Totah or Zuni areas.

Journal of Archaeological Science↗

USGS2009

LANDFIRE: A nationally consistent vegetation, wildland fire, and fuel assessment

LANDFIRE is a 5-year, multipartner project producing consistent and comprehensive maps and data describing vegetation, wildland fuel, fire regimes and ecological departure from historical conditions across the United States. It is a shared project between the wildland fire management and research and development programs of the US Department of Agriculture Forest Service and US Department of the Interior. LANDFIRE meets agency and partner needs for comprehensive, integrated data to support landscape-level fire management planning and prioritization, community and firefighter protection, effective resource allocation, and collaboration between agencies and the public. The LANDFIRE data production framework is interdisciplinary, science-based and fully repeatable, and integrates many geospatial technologies including biophysical gradient analyses, remote sensing, vegetation modelling, ecological simulation, and landscape disturbance and successional modelling. LANDFIRE data products are created as 30-m raster grids and are available over the internet at www.landfire.gov , accessed 22 April 2009. The data products are produced at scales that may be useful for prioritizing and planning individual hazardous fuel reduction and ecosystem restoration projects; however, the applicability of data products varies by location and specific use, and products may need to be adjusted by local users.

International Journal of Wildland Fire↗

USGS2018

Beyond the edge: Linking agricultural landscapes, stream networks, and best management practices

Despite much research and investment into understanding and managing nutrients across agricultural landscapes, nutrient runoff to freshwater ecosystems is still a major concern. We argue there is currently a disconnect between the management of watershed surfaces (agricultural landscape) and river networks (riverine landscape). These landscapes are commonly managed separately, but there is limited cohesiveness between agricultural landscape-focused research and river science, despite similar end goals. Interdisciplinary research into stream networks that drain agricultural landscapes is expanding but is fraught with problems. Conceptual frameworks are useful tools to order phenomena, reveal patterns and processes, and in interdisciplinary river science, enable the joining of multiple areas of understanding into a single conceptual–empirical structure. We present a framework for the interdisciplinary study and management of agricultural and riverine landscapes. The framework includes components of an ecosystems approach to the study of catchment–stream networks, resilience thinking, and strategic adaptive management. Application of the framework is illustrated through a study of the Fox Basin in Wisconsin, USA. To fully realize the goal of nutrient reduction in the basin, we suggest that greater emphasis is needed on where best management practices (BMPs) are used within the spatial context of the combined watershed–stream network system, including BMPs within the river channel. Targeted placement of BMPs throughout the riverine landscape would increase the overall buffering capacity of the system to nutrient runoff and thus its resilience to current and future disturbances.

Journal of Environmental Quality↗

USGS2016

Nutrients in the nexus

Synthetic nitrogen (N) fertilizer has enabled modern agriculture to greatly improve human nutrition during the twentieth century, but it has also created unintended human health and environmental pollution challenges for the twenty-first century. Averaged globally, about half of the fertilizer-N applied to farms is removed with the crops, while the other half remains in the soil or is lost from farmers’ fields, resulting in water and air pollution. As human population continues to grow and food security improves in the developing world, the dual development goals of producing more nutritious food with low pollution will require both technological and socio-economic innovations in agriculture. Two case studies presented here, one in sub-Saharan Africa and the other in Midwestern United States, demonstrate how management of nutrients, water, and energy is inextricably linked in both small-scale and large-scale food production, and that science-based solutions to improve the efficiency of nutrient use can optimize food production while minimizing pollution. To achieve the needed large increases in nutrient use efficiency, however, technological developments must be accompanied by policies that recognize the complex economic and social factors affecting farmer decision-making and national policy priorities. Farmers need access to affordable nutrient supplies and support information, and the costs of improving efficiencies and avoiding pollution may need to be shared by society through innovative policies. Success will require interdisciplinary partnerships across public and private sectors, including farmers, private sector crop advisors, commodity supply chains, government agencies, university research and extension, and consumers.

Journal of Environmental Studies and Sciences↗

USGS2010

Trends and transformation of nutrients and pesticides in a Coastal Plain aquifer system, United States

Four local-scale sites in areas with similar corn (Zea mays L.) and soybean [Glycine max (L.) Merr.] agriculture were studied to determine the effects of different hydrogeologic settings of the Northern Atlantic Coastal Plain (NACP) on the transport of nutrients and pesticides in groundwater. Settings ranged from predominantly well-drained soils overlying thick, sandy surficial aquifers to predominantly poorly drained soils with complex aquifer stratigraphy and high organic matter content. Apparent age of groundwater, dissolved gases, N isotopes, major ions, selected pesticides and degradates, and geochemical environments in groundwater were studied. Agricultural chemicals were the source of most dissolved ions in groundwater. Specific conductance was strongly correlated with reconstructed nitrate (the sum of N in nitrate and N gas) (R 2 = 0.81, p < 0.0001), and is indicative of the relative degree of agricultural effects on groundwater. Trends in nitrate were primarily related to changes in manure and fertilizer use at the well-drained sites where aquifer conditions were consistently oxic. Nitrate was present in young groundwater but completely removed over time through denitrification at the poorly drained sites where there were variations in chemical input and in geochemical environment. Median concentrations of atrazine (6-chloro-N-ethyl-N'-(1- methylethyl)-1,3,5-triazine-2,4-diamine), metolachlor (2-chloro-N-(2-ethyl-6- methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide), and some of their common degradates were higher at well-drained sites than at poorly drained sites, with concentrations of degradates generally higher than those of the parent compounds at all sites. An increase in the percentage of deethylatrazine to total atrazine over time at one well-drained site may be related to changes in manure application. Copyright ?? 2010 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗

USGS2008

Environmental presence and persistence of pharmaceuticals: An overview

Emerging contaminants (ECs) in the environment – that is, chemicals with domestic, municipal, industrial, or agricultural sources that are not commonly monitored but may have the potential for adverse environmental effects – is a rapidly growing field of research. The use of “emerging” is not intended to infer that the presence of these compounds in the environment is new. These chemicals have been released into the environment as long as they have been in production or, in the case of hormones and other endogenous compounds, since the rise of animal life. What is emerging is the interest by the scientific and lay communities in the presence of these chemicals in the environment, the analytical capabilities required for detection, and the subtle effects that very small concentrations of these chemicals appear to have on aquatic biota. In December 2006, Environmental Science & Technology devoted an entire special issue (volume 40, number 23) to the topic of ECs, illustrating the increased interest in the subject. Within the EGs, one particular class that has seen a substantial increase in research over the past 10 years is pharmaceuticals and personal-care products (PPCPs). This increased research interest can be demonstrated by several means, including requests for proposals from funding agencies, but the clearest indication of a focused effort to understand the introduction, transformation, and potential health and environmental effects of PPCPs and ECs, in general, is the number of published reports. This increase can be shown by examining six environmental journals that regularly publish PPCP-related papers – Chemosphere , Environmental Science & Technology , Environmental Toxicology and Chemistry , Science of the Total Environment , Water Research , and Water Science and Technology . In 1998 there were 22 papers published on pharmaceuticals, antibiotics, or drugs in these 6 journals; by 2006, this number increased sixfold to 132 papers (Figure 1.1). This growth can be attributed to a number of factors. The presence of pharmaceuticals in surface-water samples from Europe and the United States was documented in several sentinel papers. These ground-breaking works encouraged other scientists to examine the rivers, streams, lakes, and reservoirs in their regions for such chemicals. In addition, the intense public attention paid to news reports on the environmental detections of these chemicals and possible effects of aquatic life has made this issue visible to the wastewater-treatment, drinking-water treatment, and regulatory communities. This has driven the funding bodies associated with these communities to fund studies or request proposals that address the presence, fate, and effects of PPCPs in aquatic systems. The release of the first comprehensive reconnaissance of pharmaceuticals and other wastewater contaminants in the United States provides an example of the intense media interest in this topic. Within 6 days on online publication of this study, 72 newspapers across the United States had published articles describing the results, either locally written or based on international media syndicate reports. There also was substantial concurrent coverage by local and national radio and television outlets, including the Cable News Network, ABC World News Tonight , and National Public Radio. A substantial fraction of these news stories may be attributable to press releases and media briefings prior to publication. However, the interest by television and print journalists in reporting the results of a peer-reviewed journal article to the general public was motivated by the recognition that describing the presence of PPCPs in water supplies would be of interest to the public. To better convey the results of the study published by Koplin et al. to the public, a separate general-interest fact sheet was published to summarize the important points of the study. Because PPCPs are commonly and widely used by individuals, there is likely a preexisting, personal identification with these compounds that does not occur for the wide range of other organic and inorganic contaminants whose presence in the environment has previously been described. This greater public “name recognition” makes itself known through the media to the regulatory and technical community and has prompted interest in sponsoring research that defines the composition and concentrations of PPCPs in potential sources and their fate and effects following relase into the environment. Independent of the drivers that potentially fuel the interest in studies of PPCPs, it is clear that PPCP research has grown beyond surface-water studies to examine issues such as: • Presence in other matrices, such as groundwater, landfill leachates, sediments, and biosolids. • Environmental transport and fate in surface water, groundwater, and soils amended with reclaimed water or biosolids. • PPCP source elucidation, such as wastewater treatment plant (WWTP) effluents, confined animal feeding operations (CAFOs), and aquaculture. • Removal during wastewater and drinking-water treatment. • Effects on aquatic ecosystems, terrestrial ecosystems, and human health. The chapters in this book provide an extensive examination of current environmental pharmaceutical research and are divided into three sections: “Occurrence and Analysis of Pharmaceuticals in the Environment,” “Environment Fate and Transformations of Veterinary Pharmaceuticals,” and “treatment of Pharmaceuticals in Drinking Water and Wastewater.” The purpose of this introductory overview chapter is to outline current (2004-2006) knowledge about the presence and concentration of PPCPs as described in the published literature. Previous reviews should be consulted for discussions on pre-2004 publications. Those reviews will provide the reader with a comprehensive introduction to the topic of PPCPs in the environment. This chapter describes the sources of PPCPs and other organic contaminants often associated with human wastewater into the environment, the range of concentrations present in various environmental compartments, and the potential routes of removal/sequestration. An overview of the sources and fate of veterinary pharmaceuticals will be discussed in Chapter 5, “Fate and Transport of Veterinary Medicines in the Soil Environment.”

Book chapter↗