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Geology and ground-water resources of Goshen County Wyoming with a section on chemical quality of the ground water

Goshen County, which has an area of 2,186 square miles, lies in southeastern Wyoming. The purpose of this study was to evaluate the ground-water resources of the county by determining the character, thickness, and extent of the waterbearing materials; the source, occurrence, movement, quantity, and quality of the ground water; and the possibility of developing additional ground water. The rocks exposed in the area are sedimentary and range in age from Precambrian to Recent. A map that shows the areas of outcrop and a generalized section that summarizes the age, thickness, physical character, and water supply of these formations are included in the report. Owing to the great depths at which they lie beneath most of the county, the formations older than the Lance formation of Late Cretaceous age are not discussed in detail. The Lance formation, of Late Cretaceous age, which consists mainly of beds of fine-grained sandstone and shale, has a maximum thickness of about 1,400 feet. It yields water, which usually is under artesian pressure, to a large number of domestic and stock wells in the south-central part of the county. Tertiary rocks in the area include the Chadron and Brule formations of Oligocene age, the Arikaree formation of Miocene age, and channel deposits of Pliocene age. The Chadron formation is made up of two distinct units: a lower unit of highly variegated fluviatile deposits that has been found only in the report area; and an upper unit that is typical of the formation as it occurs in adjacent areas. The lower unit, which ranges in thickness from a knife edge to about 95 feet, is not known to yield water to wells, but its coarse-grained channel deposits probably would yield small quantities of water to wells. The upper unit, which ranges in thickness from a knife edge to about 150 feet, yields sufficient quantities of water for domestic and stock uses from channel deposits of sandstone under artesian pressure. The Brule formation, which is mainly a siltstone, ranges in thickness from a knife edge to about 450 feet and yields water to domestic and stock wells from fractures and from lenses of sandstone. The Arikaree formation ranges in thickness from a knife edge to about 1,000 feet, and yields water to several domestic and stock wells in the northwestern part of the area. The Pliocene channel deposits, which probably do not exceed 25 feet in thickness, are not a source of water for wells in Goshen County. The upland deposits, which are mainly of Pleistocene age, generally are dry and do not serve as aquifers; however, test drilling revealed several deep, buried channels occupied by deposits which probably would yield moderate quantities of water to wells if a sufficient saturated thickness were penetrate The deposits of the third terrace, which are of Pleistocene age, range in thickness from a knife edge to about 210 feet and yield water to a large number of irrigation wells in the area. The flood-plain deposits, which are of Pleistocene and Recent age, range in thickness from a knife edge to about 200 feet. Those in the valley of the North Platte River yield abundant water to many large supply wells. The flood-plain deposits along the valley of Rawhide Creek consist mainly of fine-grained materials and yield large supplies of water to well only in the lower stretches of the creek valley near its confluence with the valley of the North Platte River. The deposits along the valleys of Horse and Bear Creeks generally are relatively thin and fine grained. In the vicinity of Ls grange, however, the deposits, which are about 45 feet thick, yield moderate, supplies of water to several irrigation wells. Other Recent deposits in the area--dune sand, loesslike deposits, and slope wash--generally are fine grained and relatively thin and, hence, are not important sources of ground water. The unconsolidated sand and gravel of the flood-plain and terrace deposits are the principal aquifers in the area.

Wyoming↗

Water-level maps of the Mississippi River Valley alluvial aquifer in eastern Arkansas, spring 1992

Water-level maps of the Mississippi River Valley alluvial aquifer are presented for spring 1992 in this map report. The alluvial aquifer consists of sand and gravel in flood-plain and terrace deposits of Quaternary age and supplies much of the water used for irrigation and aquaculture in eastern Arkansas. The map of the potentiometric surface, 5-year water-level change, and depth to water illustrates the effects of large with- drawals for irrigation on water levels in the aquifer. One large area of depression in the potentiometric surface, caused by large with- drawals of ground water for irrigation, occurs in Arkansas, Lonoke, and Prairie Counties, and another extends from Monroe County to western Craighead County.

Open-File Report↗

Digital data sets that describe aquifer characteristics of the alluvial and terrace deposits along the Beaver-North Canadian River from the panhandle to Canton Lake in northwestern Oklahoma

ARC/INFO export and nonproprietary format files This diskette contains digitized aquifer boundaries and maps of of hydraulic conductivity, recharge, and ground-water level elevation contours for the alluvial and terrace deposits along the alluvial and terrace deposits along the Beaver-North Canadian River from the panhandle to Canton Lake in northwestern Oklahoma. Ground water in 830 square miles of the Quaternary-age alluvial and terrace aquifer is an important source of water for irrigation, industrial, municipal, stock, and domestic supplies. The aquifer consists of poorly sorted, fine to coarse, unconsolidated quartz sand with minor amounts of clay, silt, and basal gravel. The hydraulically connected alluvial and terrace deposits unconformably overlie the Tertiary-age Ogallala Formation and Permian-age formations. Most of the lines in the aquifer boundary and recharge data sets and some of the lines in the hydraulic conductivity data set were extracted from a published digital surficial geology data set based on a scale of 1:250,000. The ground-water elevation contours and some of the lines for the aquifer boundary, hydraulic conductivity, and recharge data sets were digitized from a ground-water modeling report about the aquifer published at a scale of 1:250,000. The hydraulic conductivity values and recharge rates also are from the ground-water modeling report. The data sets are provided in both nonproprietary and ARC/INFO export file formats. Ground-water flow models are numerical representations that simplify and aggregate natural systems. Models are not unique; different combinations of aquifer characteristics may produce similar results. Therefore, values of hydraulic conductivity and recharge used in the model and presented in this data set are not precise, but are within a reasonable range when compared to independently collected data.

Oklahoma↗

Digital data sets that describe aquifer characteristics of the alluvial and terrace deposits along the North Canadian River from Canton Lake to Lake Overholser in central Oklahoma

ARC/INFO export and nonproprietary format files This diskette contains digitized aquifer boundaries and maps of of hydraulic conductivity, recharge, and ground-water level elevation contours for the alluvial and terrace deposits along the alluvial and terrace deposits along the North Canadian River from Canton Lake to Lake Overholser in central Oklahoma. Ground water in approximately 400 square miles of Quaternary-age alluvial and terrace aquifer is an important source of water for irrigation, industrial, municipal, stock, and domestic supplies. The aquifer consists of clay, silt, sand, and gravel. Sand-sized sediments dominate the poorly sorted, fine to coarse, unconsolidated quartz grains in the aquifer. The hydraulically connected alluvial and terrace deposits unconformably overlie Permian-age formations. The aquifer is overlain by a layer of wind-blown sand in parts of the area. Most of the lines in the aquifer boundary, hydraulic conductivity, and recharge data sets were extracted from published digital surficial geology data sets based on a scale of 1:250,000. The ground-water elevation contours and some of the lines for the aquifer boundary, hydraulic conductivity, and recharge data sets were digitized from a ground-water modeling report about the aquifer published at a scale of 1:250,000. The hydraulic conductivity values and recharge rates also are from the ground-water modeling report. Ground-water flow models are numerical representations that simplify and aggregate natural systems. Models are not unique; different combinations of aquifer characteristics may produce similar results. Therefore, values of hydraulic conductivity and recharge used in the model and presented in this data set are not precise, but are within a reasonable range when compared to independently collected data.

Oklahoma↗

Geohydrology of principal aquifers in the Republican River basin, Kansas

Principal aquifers in the Republican River basin in Kansas are unconsolidated alluvial deposits. One such aquifer is formed by the Ogallala Formation of Miocene age which covers most of the western part of the area. Because saturated thickness of the aquifer decrease northeastward, maximum yields to irrigation wells decrease in that direction from 2,000 to 500 gallons per minute. The Grand Island Formation of Pleistocene age occurs in an ancestral channel of the Republican River in northeast Jewell and northwest Republic counties. The maximum yield to wells from this aquifer was estimated to be 2,000 gallons per minute. Quaternary alluvium of Pleistocene and Holocene age occurs in most major stream valleys. The aquifer in the Republican River valley yields as much as 2,000 gallons per minute to irrigation wells. Water levels in the Ogallala Formation commonly declined from 5 to 40 feet during 1950-77 as a result of irrigation withdrawals. Recharge from irrigation by stream diversions have raised water levels as much as 25 feet in the Grand Island Formation and as much as 15 feet in the Quaternary alluvium of the Prairie Dog Creek valley. (USGS)

Open-File Report↗

Determination of vadose zone and saturated zone nitrate lag times using long-term groundwater monitoring data and statistical machine learning

In this study, we explored the use of statistical machine learning and long-term groundwater nitrate monitoring data to estimate vadose zone and saturated zone lag times in an irrigated alluvial agricultural setting. Unlike most previous statistical machine learning studies that sought to predict groundwater nitrate concentrations within aquifers, the focus of this study was to leverage available groundwater nitrate concentrations and other environmental variables to determine mean regional vertical velocities (transport rates) of water and solutes in the vadose zone and saturated zone (3.50 and 3.75 m yr −1 , respectively). The statistical machine learning results are consistent with two primary recharge processes in this western Nebraska aquifer, namely ( 1 ) diffuse recharge from irrigation and precipitation across the landscape and ( 2 ) focused recharge from leaking irrigation conveyance canals. The vadose zone mean velocity yielded a mean recharge rate (0.46 m yr −1 ) consistent with previous estimates from groundwater age dating in shallow wells (0.38 m yr −1 ). The saturated zone mean velocity yielded a recharge rate (1.31 m yr −1 ) that was more consistent with focused recharge from leaky irrigation canals, as indicated by previous results of groundwater age dating in intermediate-depth wells (1.22 m yr −1 ). Collectively, the statistical machine learning model results are consistent with previous observations of relatively high water fluxes and short transit times for water and nitrate in the primarily oxic aquifer. Partial dependence plots from the model indicate a sharp threshold in which high groundwater nitrate concentrations are mostly associated with total travel times of 7 years or less, possibly reflecting some combination of recent management practices and a tendency for nitrate concentrations to be higher in diffuse infiltration recharge than in canal leakage water. Limitations to the machine learning approach include the non-uniqueness of different transport rate combinations when comparing model performance and highlight the need to corroborate statistical model results with a robust conceptual model and complementary information such as groundwater age.

Nebraska↗

Ground-water resources of the lower Niobrara River and Ponca Creek basins, Nebraska and South Dakota

This report describes the area in north-central Nebraska and south-central South Dakota drained by Ponca Creek and by the Niobrara River below Valentine, Nebr. The Niobrara River and Ponca Creek are neighboring eastward flowing tributaries of the Missouri River. The Dakota sandstone of Cretaceous age is the oldest formation tapped by wells; the water it yields to wells in small to moderate quantities is rather highly mineralized and very hard; it is unsuitable for irrigation and most domestic uses. Overlying the Dakota, in ascending order, are the following formations of Cretaceous age: the Graneros shale, Greenhorn limestone, Carlile shale, Niobrara formation, and Pierre shale. None of these is a source of water supply. The Niobrara is the oldest formation exposed, cropping out in only the deeper valleys at the eastern end of the area. The Pierre shale, which is exposed much more extensively, crops out in the deeper valleys throughout nearly all the area. Except where the Niobrara River, its major tributaries, and Ponca Creek have cut their valleys into them, the Cretaceous rocks are overlain by semiconsolidated rocks of Tertiary age. Two Tertiary formations, the Brule and the Ogallala, are present in the area. The Brule formation underlies all the western part of the area and is exposed in the valleys of both the Niobrara and Keya Paha Rivers. The Ogallala formation, which overlaps the Brule, forms the upland on both sides of the river and is exposed in many places. The Brule is not a source of water supply, whereas the Ogallala yields small to moderately large quantities of water to many wells on the upland. The water in the Ogallala is of the calcium bicarbonate type and is moderately mineralized and hard. Unconsolidated deposits of Quaternary age mantle the Tertiary rocks throughout nearly all the upland area south of the Niobrara River and in parts of the upland area north of the river. They also floor the Niobrara River valley. Where saturated, these sediments, which consist of stream-deposited sand and gravel and wind-deposited sand, yield small to large amounts of water to wells. The water in the Quaternary deposits is of the calcium bicarbonate type but is less mineralized and softer than that in the Ogallala. The only significant source of recharge to the Dakota sandstone in the report area is underflow from the west. Except for waiter yielded to wells tapping the Dakota, water in the formation is discharged from the area by underflow to the east. In the upland part of the area, the Ogallala formation and the overlying deposits of Quaternary age constitute a single aquifer, water moving from one Into the other without apparent hindrance. This aquifer is recharged principally by the direct infiltration of precipitation but in part also by underflow from the west and south and by seepage from intermittent streams and ponds. Water is discharged from the upland aquifer by outflow through springs or seepage into streams, through the process of evapotranspiration, and by wells when they are pumped. Ground water leaves the report area by underflow where the Quaternary deposits in the valleys of the Niobrara River and Ponca Creek merge with the Quaternary deposits in the Missouri River valley. In places where the Niobrara formation, the Pierre shale, or the Brule formation is at the surface or is mantled by thin deposits of the Ogallala or thin deposits of Quaternary age, only meager amounts of ground water can be obtained unless wells are deep enough to tap the Dakota sandstone. Elsewhere the Ogallala formation and the deposits of Quaternary age generally yield ample water for domestic and stock supplies, and in some places, notably in the vicinity of Ainsworth, they yield enough water for irrigation. Additional large supplies of ground water could be obtained on the upland in the southwestern and west-central parts of the area. The report contains an annotated bibliography of previous publications on the geology and ground-water resources of the area, brief descriptions of the Cretaceous, Tertiary, and Quaternary rocks, a map showing the contour of the water table, logs of test holes and wells not published elsewhere, results of analyses of ground- and surface-water samples, and records of all wells of large discharge and representative wells of small discharge.

Nebraska, North Dakota↗

Ground-water resources of Sheridan County, Wyoming

Sheridan County is in the north-central part of Wyoming and is an area of about 2,500 square miles. The western part of the county is in the Bighorn Mountains, and the eastern part is in the Powder River structural basin. Principal streams are the Powder and Tongue Rivers, which are part of the Yellowstone River system. The climate is semiarid, and the mean annual precipitation at Sheridan is about 16 inches. Rocks of Precambrian age are exposed in the central part of the Bighorn Mountains, and successively younger rocks are exposed eastward. Rocks of Tertiary age, which are the most widespread, are exposed throughout a large part of the Powder River structural basin. Deposits of Quaternary age underlie the flood plains and terraces along the larger streams, particularly in the western part of the basin. Aquifers of pre-Tertiary age are exposed in the western part of the county, but they dip steeply and are deeply buried just a few miles east of their outcrop. Aquifers that might yield large supplies of water include the Bighorn Dolomite, Madison Limestone, Amsden Formation, and Tensleep Sandstone. The Flathead Sandstone, Sundance Formation, Morrison Formation, Cloverly Formation,. Newcastle Sandstone, Frontier Formation, Parkman Sandstone, Bearpaw Shale, .and Lance Formation may yield small or, under favorable conditions, moderate supplies of water. Few wells tap aquifers of pre-Tertiary age, and these are restricted to the outcrop area. The meager data available indicate that the water from the Lance Formation, Bearpaw Shale, Parkman Sandstone, Tensleep Sandstone and Amsden Formation, and Flathead Standstone is of suitable quality for domestic or stock purposes, and that water from the Tensleep Sandstone and Amsden Formation and the Flathead Sandstone is of good quality for irrigation. Samples could not be obtained from other aquifers of pre-Tertiary age; so the quality of water in these aquifers could not be determined. Adequate supplies of ground water for stock or domestic use can be developed throughout much of the report area from the Fort Union and Wasatch Formations of Tertiary age; larger supplies might be obtained from the coarse-grained sandstone facies of the Wasatch Formation near Moncreiffe Ridge. Four aquifer tests were made at wells tapping formations of Tertiary age, and the coefficients of permeability determined ranged from 2.5 to 7.9 gallons per day per square foot. The depths to which wells must be drilled to penetrate an aquifer differ within relatively short distances because of the lenticularity of the aquifers. Water in aquifers of Tertiary age may occur under water-table, artesian, or a combination of artesian and gas-lift conditions. Water from the Fort Union is usable for domestic purposes, but the iron and dissolved-solids content impair the quality at some localities. Water from the Fort Union Formation is not recommended for irrigation because of sodium and bicarbonate content. The water is regarded as good to fair for stock use. Water from the Wasatch Formation generally contains dissolved solids in excess of the suggested domestic standards, but this water is usable in the absence of other supplies. The development of irrigation supplies from the Wasatch Formation may be possible in some areas, but the water quality should be carefully checked. Water of good to very poor quality for stock supplies is obtained, depending upon the location. Hydrogen sulfide, commonly present in water of the Fort Union and Wasatch Formations, becomes an objectionable characteristic when the water is used for human consumption. Deposits of Quaternary age generally yield small to moderate supplies of water to wells. Two pumping tests were conducted, and the coefficients of permeability of the aquifers tested were 380 and 1,100 gallons per day per square foot. Usable supplies of ground water can be developed from the deposits of Quaternary age, principally along the valleys of perennial strea

Water Supply Paper↗

Assessing the Vulnerability of Public-Supply Wells to Contamination: Central Valley Aquifer System near Modesto, California

This fact sheet highlights findings from the vulnerability study of a public-supply well in Modesto, California. The well selected for study pumps on average about 1,600 gallons per minute from the Central Valley aquifer system during peak summer demand. Water samples were collected at the public-supply well and at monitoring wells installed in the Modesto vicinity. Samples from the public-supply wellhead contained the undesirable constituents uranium, nitrate, arsenic, volatile organic compounds (VOCs), and pesticides, although none were present at concentrations exceeding drinking-water standards. Of these contaminants, uranium and nitrate pose the most significant water-quality risk to the public-supply well because human activities have caused concentrations in groundwater to increase over time. Overall, study findings point to four primary factors that affect the movement and (or) fate of contaminants and the vulnerability of the public-supply well in Modesto: (1) groundwater age (how long ago water entered, or recharged, the aquifer); (2) irrigation and agricultural and municipal pumping that drives contaminants downward into the primary production zone of the aquifer; (3) short-circuiting of contaminated water down the public-supply well during the low-pumping season; and (4) natural geochemical conditions of the aquifer. A local-scale computer model of groundwater flow and transport to the public-supply well was constructed to simulate long-term nitrate and uranium concentrations reaching the well. With regard to nitrate, two conflicting processes influence concentrations in the area contributing recharge to the well: (1) Beneath land that is being farmed or has recently been farmed (within the last 10 to 20 years), downward-moving irrigation waters contain elevated nitrate concentrations; yet (2) the proportion of agricultural land has decreased and the proportion of urban land has increased since 1960. Urban land use is associated with low nitrate concentrations in recharge (3.1 milligrams per liter). Results of the simulation indicate that nitrate concentrations in the public-supply well peaked in the late 1990s and will decrease slightly from the current level of 5.5 milligrams per liter during the next 100 years. A lag time of 20 to 30 years between peak nitrate concentrations in recharge and peak concentrations in the well is the result of the wide range of ages of water reaching the public-supply well combined with changing nitrogen input concentrations over time. As for uranium, simulation results show that concentrations in the public-supply well will likely approach the Maximum Contaminant Level of 30 micrograms per liter over time; however, it will take more than 100 years because of the contribution of old water at depth in the public-supply well that dilutes uranium concentrations in shallower water entering the well. This allows time to evaluate management strategies and to alter well-construction or pumping strategies to prevent uranium concentrations from exceeding the drinking-water standard.

Fact Sheet↗

Ground water in the Verdigris River basin, Kansas and Oklahoma

Ground water in the Verdigris River basin occurs in consolidated rocks and unconsolidated deposits ranging in age from Mississippian to Quaternary. Water for municipal, industrial, and irrigation supplies generally can be obtained in limited quantities from the alluvial deposits in the stream valleys. Except for water in the alluvial deposits in the stream valleys and in the outcrop areas of the bedrock aquifers, the groundwater is generally of poor chemical quality. Owing to the generally poor chemical quality of water and low yields to wells, an increase in the use of ground water from the consolidated rocks is improbable. The unconsolidated rocks in the Verdigris River basin receive about 166,000 acre-feet of recharge annually, and about 1 million acre-fee of water is in temporary storage in the deposits. In 1968 about 4,200 acre-feet of ground was withdrawn for all uses. About 800 acre-feet of ground and 5,000 acre-feet of surface water were pumped for irrigation of 5,300 acres of cropland. The total annual withdrawal of ground water for irrigation may be 2,000 acre-feet by the year 2000.

Kansas, Oklahoma↗

Potentiometric surfaces of the Mississippi River Valley alluvial aquifer in eastern Arkansas, spring 1972 and 1980

Maps that show contours of the altitude of water levels for wells completed in the Mississippi River Valley alluvial aquifer in eastern Arkansas were prepared using water-level measurements made in the spring of 1972-1980. Hydrographs for selected wells are included to show trends and lack of trends in water-level changes. The aquifer consists of gravel and sand in flood-plain and terrace deposits of Quaternary age. The aquifer supplies much of the water used for irrigation and aquaculture in eastern Arkansas. A large depression in the potentiometric surface caused by pumping for irrigation and aquaculture occurs in Arkansas, Lonoke, and Prairie Counties. A smaller depression in the potentiometric surface occurs north of Brinkley. Significant water-level declines occurred during the period 1972-80 in several counties west of Crowleys Ridge. (USGS)

Water-Resources Investigations Report↗

Isotope geochemistry and fluxes of carbon and organic matter in tropical small mountainous river systems and adjacent coastal waters of the Caribbean

Recent studies have shown that small mountainous rivers (SMRs) may act as sources of aged and/or refractory carbon (C) to the coastal ocean, which may increase organic C burial at sea and subsidize coastal food webs and heterotrophy. However, the characteristics and spatial and temporal variability of C and organic matter (OM) exported from tropical SMR systems remain poorly constrained. To address this, the abundance and isotopic character (δ13C and Δ14C) of the three major C pools were measured in two Puerto Rico SMRs with catchments dominated by different land uses (agricultural vs. non-agricultural recovering forest). The abundance and character of C pools in associated estuaries and adjacent coastal waters were also examined. Riverine dissolved and particulate organic C (DOC and POC, respectively) concentrations were highly variable with respect to land use and sampling month, while dissolved inorganic C (DIC) was significantly higher at all times in the agricultural catchment. In both systems, riverine DOC and POC ranged from modern to highly aged (2,340 years before present), while DIC was always modern. The agricultural river and irrigation canals contained very old DOC (1,184 and 2,340 years before present, respectively), which is consistent with findings in temperate SMRs and indicates that these tropical SMRs provide a source of aged DOC to the ocean. During months of high river discharge, OM in estuarine and coastal waters had C isotope signatures reflective of direct terrestrial input, indicating that relatively unaltered OM is transported to the coastal ocean at these times. This is also consistent with findings in temperate SMRs and indicates that C transported to the coastal ocean by SMRs may differ from that of larger rivers because it is exported from smaller catchments that have steeper terrains and fewer land-use types.

Puerto Rico↗

Reef and nonreef aquifers - A comparison of hydrogeology and geochemistry, northwestern Indiana

The principal bedrock aquifer system across much of Indiana consists of carbonate rocks of Silurian and Devonian age. The Silurian-Devonian aquifer system is used extensively for irrigation in northwestern Indiana and is approximately 170 m thick. Reef and nonreef carbonate aquifers in northwestern Indiana were assessed using hydrogeology (lithology, geophysical logs, aquifer tests) and geochemistry (major ions and stable isotopes). The study showed differences in water quantity and quality between the reef and nonreef aquifers. The reef aquifer had few shales, abundant fossiliferous material (up to 100 m thick), and high porosities (10 to 15%). The nonreef aquifer had abundant shales, less fossiliferous material (a few meters thick), and low porosities. Total transmissivities at the reef sites were 697 m 2 /d, (meters squared per day) and 4831 m 2 /d, compared to 46 m 2 /d at the nonreef site. Flowpaths in the nonreef aquifer were associated with fractures and poorly connected moldic porosity with larger fractures and better connected vuggy porosity in the reef aquifer. Water chemistry data for the nonreef aquifer showed mean concentrations of sodium (235 mg/L [milligrams per liter]), sulfate (160 mg/L), sul-fide (13 mg/L), fluoride (2.7 mg/L), and dissolved solids (635 mg/L) approximately two to five times larger when compared to mean concentrations in the reef aquifer. Ground water at the nonreef site was classified as a sodium-bicarbonate type while that at the reef sites was calcium-magnesium bicarbonate. The oxygen/deuterium isotope data indicates recharge from modern precipitation and not Pleistocene-age recharge.

Groundwater↗

Water resources of the southeast lowlands, Missouri; with a section on water quality

The Southeast Lowlands of Missouri occupies 4,000 square miles of prime agricultural land of the Coastal Plain in the extreme southeastern corner of Missouri. Even though this area receives about 4 feet of rainfall per year, there is a rapidly increasing demand for water for irrigation. The purpose of this study was to evaluate the water resources of this area with particular emphasis on the extent of irrigation and the potential of the groundwater system to support further irrigation development. The area is underlain by consolidated aquifers of Paleozoic age and unconsolidated aquifers of Mesozoic and Cenozoic age. The consolidated aquifers, although possessing the potential to yield large quantities of water, generally are not used throughout much of the area because they lie at considerable death and alternate supplies are readily available. The McNairy aquifer, which underlies about three-fourths of the area, ranges from 0 to 600 feet in thickness with the top lying from 0 to more than 2,200 feet below land surface. This system is attractive as a municipal water supply because of its large artesian head and the small iron and hardness concentrations of the water. Although this system is now used exclusively for municipal water supplies, the McNairy may become more important in the future as a heat source. The Wilcox Group (undivided), which underlies more than one-half of the area and almost always lies less than 300 feet below land surface, is as much as 1,400 feet thick. However, usually only the basal 250 to 500 feet of this group is used as an aquifer. This system, which in some areas is capable of yielding as much as 1,500 gallons per minute to properly constructed wells, is now primarily used for municipal supplies. The alluvial aquifer underlies most of the area and is locally capable of yielding more than 3,000 gallons per minute. This aquifer generally is 100 to 200 feet thick, but in several places more than 250 feet of alluvium has been reported. Irrigation wells withdraw an estimated 95,000 acre-feet per year from this aquifer, whereas municipal, industrial, and domestic wells withdraw an estimated additional 17,000 acre-feet per year. This compares to nearly 6 million acre-feet per year natural discharge and a total storage of 60 million acre feet. The surface-water system in the area consists of a few natural rivers and many manmade ditches. Although a considerable quantity of water is available from the surface-water system, this system is not extensively used because attractive alternative sources are readily available.

Missouri↗

Selenium in waters in and adjacent to the Kendrick Project, Natrona County, Wyoming

Selenium in concentrations exceeding the maximum limit, 0.01 milligrams per liter or 10 micrograms per liter, recommended by the U.S. Public Health Service in 'Drinking-Water Standards, 1962,' Public Health Pub. 956, is present in waters in areas near Casper, Wyo. Some streams containing selenium flow into the North Platte River upstream from several municipalities that obtain water from the river and the alluvium along the river. The area of this investigation includes about 725 square miles in Natrona County in central Wyoming. Study effort was most intensive within the area bounded by the North Platte River, Casper Creek, and Casper Canal, the approximate boundaries of the Kendrick irrigation project. Geologic formations in the area contain selenium that may have been derived from deposits of seleniferous material or from volcanic emanations brought down by rain. Formations older than Cretaceous age were not considered as important sources of selenium in waters of the area, because no irrigation water is applied to areas underlain by these rocks. The selenium concentration in 82 samples of Cretaceous rocks ranged from less than 10 to 4,200 ?g/kg (micrograms per kilogram of sample); no correlation was found between selenium concentration and the depth at which the sample was collected. Of four samples of Tertiary rocks analyzed, three contained no selenium and one had a selenium concentration of 40 ?g/kg. The selenium concentration in 93 samples of Quaternary rocks ranged from less than 10 to 52.0 ?g/kg, and the highest selenium concentration was generally found at depths less than 4 feet. No geologic formation has consistently high concentrations of selenium, but high concentrations were found at points throughout the study area. Probably the rocks in any locality could be the source of selenium in the water in the surrounding vicinity. The selenium concentration in water from some wells fluctuates widely. It is concluded that the selenium concentrations in the ground water in these areas have not reached a state of equilibrium in the aquifer. It is possible that such nonequilibrium conditions exist in aquifers throughout much of the area. If so, statements in this report concerning- trends of selenium concentration in ground water are somewhat speculative.Poison Spring Creek, Poison Spider Creek, Oregon Trail Drain, and Casper Creek are the principal tributaries that contribute selenium to the North Platte River. The selenium load, expressed in pounds per day, in Poison Spring Creek and Poison Spider Creek decreased slightly during the first year of sampling and increased slightly during the second year of sampling. The selenium load in Oregon Trail Drain is greatest in late winter and early spring during the period of low flow; the selenium load in Casper Creek varies, but shows no correlation with season and little correlation with stream discharge. The North Platte River above and below the irrigation project had consistently low selenium concentrations, 10 ?g/l (micrograms per liter) or less, in the period April 1968 through June 1969. The total selenium load contributed to the North Platte River from tributaries in the study area is almost undetectable after mixing with the river water. From the fall of 1968 .to the spring of 1969, results of water sampling in areas influenced by irrigation show that the selenium concentration increased at 29 percent of the locations (average net increase of 64 ?g/l), decreased at 34 percent of the locations (average net decrease of 80 ?g/l), and had little (10 ?g/l or .less) or no change at 37 percent of the locations. As a comparison, results of water sampling in areas not influenced by irrigation showed that the selenium concentration increased at 2 percent of the locations (average net increase of 30 ?g/l), decreased at 26 percent of the locations (average net decrease of 30?g/l), and had little or no change at 72 percent of the locations. It is not possible to

Water Supply Paper↗

Ground-water resources of the Middle Loup division of the lower Platte River basin, Nebraska, with a section on Chemical quality of the ground water

The Middle Loup division of the lower Platte River basin is an area of 650 square miles which includes the Middle Loup River valley from the confluence of the Middle and North Loup Rivers in Howard County, Nebr., to the site of the diversion dam that the U. S. Bureau of Reclamation proposes to construct in Blaine County near Milburn, Nebr. It also includes land in Howard and Sherman Counties designated by the Bureau of Reclamation as the Farwell unit. Irrigable land in this division is present on both sides of the Middle Loup River and along its tributaries. Most of the Middle Loup River valley is already irrigated by the Middle Loup Public Power and Irrigation District, which is strictly an irrigation enterprise. The uplands are not irrigated. Loess, dune sand, gravel, silt, and clay of Pleistocene or Recent age are exposed in the report area. These unconsolidated sediments rest on bedrock consisting of alternating layers of shale, mudstone, sandstone, and limestone, which are essentially fiat lying or slightly warped. The Ogallala formation, of Tertiary (Pliocene) age, immediately underlies the Pleistocene sediments and rests on the Pierre shale of Cretaceous age. Belts of alluvium occupy the Middle Loup River valley and the valleys of the principal streams in the area. The soils, dune sand, and terrace deposits are the most recent deposits. The Ogallala formation is water bearing and is the source of supply for some domestic and livestock wells. The saturated part of the sand and gravel formations of Pleistocene age, which yields water freely to wells, is the most important aquifer in the Middle Loup division. The water generally is under water-table conditions. The yields of properly constructed wells range from a few gallons per minute (gpm) to as much as 1,800 gpm. Some wells tap water in both the sand and gravel of Pleistocene age and in the underlying Ogallala formation. No wells are known to penetrate into formations older than the Ogallala. Fluctuations of the water table indicate changes in the amount of ground water stored in the water-bearing formations. The principal factors controlling the rise of the water table are the amount of precipitation within the area, the quantity of water coming into the area as underflow from the west and northwest, seepage from the Middle Loup River at times when the water surface in the river is higher than the adjoining water table, and the infiltration of irrigation water not utilized by vegetation or lost by runoff or evaporation. The principal factors controlling the decline of the water table are the discharge as effluent seepage into the Middle Loup River and its tributaries, the amount of water pumped from wells, evapotranspiration losses, and the amount of water leaving the area as underflow. Periodic water-level measurements were made in a total of 241 observation wells during the period 1948-50. Hydrographs of three observation wells having a longer period of record (1934-50) indicate that the water table rose slightly from 1934 until 1950 and that it remained nearly constant during the 1950 water year. The configuration of the water table in the Middle Loup division shows that, except north and northwest of Sargent, the Middle Loup River is an effluent, or gaining, stream throughout its entire length in this area. Thus any rise or fall in the ground-water level will increase or decrease the discharge of the river. The river recharges the ground- water reservoir only during periods when it is at flood stage. The depth to the water table from the land surface is governed largely by irregularities in topography. The depth to water is less than 10 feet near the river and increases to as much as 60 feet near the valley margins and the bordering intermediate slopes. In the Far- well unit the depth to water is more than 100 feet and in some parts more than 150 feet. Ground water pumped from wells is the source of supply for the principal municipalities in th

Water Supply Paper↗

Ground-water geology of Bexar County, Texas

The investigation in Bexar County was part of a comprehensive study of a large area in south-central Texas underlain by the Edwards and associated limestones (Comanche Peak and Georgetown) of Cretaceous age. The limestones form an aquifer which supplies water to the city of San Antonio, several military installations, many industrial plants, and many irrigated farms. The geologic formations that yield water to wells in Bexar County are sedimentary rocks of Mesozoic and Cenozoic age. The rocks strike northeastward and dip southeastward toward the Gulf of Mexico. In the northern part of the county, in an erosional remnant of the Edwards Plateau, the rocks are nearly flat and free from faulting. In the central and southern parts of the county, however, the rocks dip gulfward at gentle to moderately steep angles and are extensively faulted in the Balcones and Mexia fault zones. Individual faults or shatter zones were traced as much as 25 miles; the maximum displacement is at least 600 feet. In general, the formations are either monoclinal or slightly folded; in the western part of the county the broad Culebra anticline plunges southwestward. Most of the large-capacity wells in Bexar County draw water from the Edwards and associated limestones, but a few draw from the Glen Rose limestone, the Austin chalk, and surficial sand and gravel. The Hosston formation, Glen Rose limestone, Buda limestone, and Austin chalk, all of Cretaceous age, generally yield small to large supplies of water; the Wilcox group and Carrizo sand of Tertiary age yield moderate supplies and alluvium of Pleistocene and Recent age generally yield small supplies. The Edwards and associated limestones are recharged primarily by groundwater underflow into Bexar County from the west, and secondarily by seepage from streams that cross the outcrop of the aquifer in Bexar County. During the period 1934-47 the recharge to the aquifer in Bexar County is estimated to have averaged between 400,000 and 430,000 acre-feet per year. Discharge from the aquifer takes place by means of wells and springs and by underflow into Comal and Guadalupe Counties on the northeast. During the period 1934-47 the estimated average discharge from wells and springs was about 174,000 acre-feet per year. The discharge by underflow out of the county during the same period is estimated to have averaged between 220,000 and 260,000 acre-feet per year. Probably only a small amount of water moves downdip southeast of San Antonio. The presence of highly mineralized water in that area suggests that the circulation of water is poor because of the low permeability of the aquifer. During the period 1934-56 the discharge from the Edwards and associated limestones greatly exceeded the recharge; consequently, water levels in wells declined. The decline was greatest in the northwestern part of the county, where the water levels in wells dropped as much as 100 feet. The decline was progressively less toward the east, averaging 40 feet along the Bexar-Comal County line. The area of the greatest concentration of discharge, which includes San Antonio and extends to the southwest and northeast, coincides with the area of maximum faulting and maximum recorded yields from wells and is not the area of greatest decline. The ability of the Edwards and associated limestones to transmit and store water in the San Antonio area apparently is so great that the discharge from wells results in much smaller declines of water level than do similar or even smaller discharges in other areas. The water from the Edwards is almost uniformly a calcium bicarbonate water of good quality, although hard. In the southern part of the San Antonio area the water is charged with hydrogen sulfide; farther downdip it becomes highly mineralized.

Water Supply Paper↗

Vertical gradients in water chemistry and age in the Northern High Plains Aquifer, Nebraska, 2003

The northern High Plains aquifer is the primary source of water used for domestic, industrial, and irrigation purposes in parts of Colorado, Kansas, Nebraska, South Dakota, and Wyoming. Despite the aquifer’s importance to the regional economy, fundamental ground-water characteristics, such as vertical gradients in water chemistry and age, remain poorly defined. As part of the U.S. Geological Survey’s National Water-Quality Assessment Program, water samples from nested, short-screen monitoring wells installed in the northern High Plains aquifer were analyzed for major ions, nutrients, trace elements, dissolved organic carbon, pesticides, stable and radioactive isotopes, dissolved gases, and other parameters to evaluate vertical gradients in water chemistry and age in the aquifer. Chemical data and tritium and radiocarbon ages show that water in the aquifer was chemically and temporally stratified in the study area, with a relatively thin zone of recently recharged water (less than 50 years) near the water table overlying a thicker zone of older water (1,800 to 15,600 radiocarbon years). In areas where irrigated agriculture was an important land use, the recently recharged ground water was characterized by elevated concentrations of major ions and nitrate and the detection of pesticide compounds. Below the zone of agricultural influence, major-ion concentrations exhibited small increases with depth and distance along flow paths because of rock/water interactions. The concentration increases were accounted for primarily by dissolved calcium, sodium, bicarbonate, sulfate, and silica. In general, the chemistry of ground water throughout the aquifer was of high quality. None of the approximately 90 chemical constituents analyzed in each sample exceeded primary drinking-water standards. Mass-balance models indicate that changes in groundwater chemistry along flow paths in the aquifer can be accounted for by small amounts of feldspar and calcite dissolution; goethite and clay-mineral precipitation; organic-carbon and pyrite oxidation; oxygen reduction and denitrification; and cation exchange. Mixing with surface water affected the chemistry of ground water in alluvial sediments of the Platte River Valley. Radiocarbon ages in the aquifer, adjusted for carbon mass transfers, ranged from 1,800 to 15,600 14C years before present. These results have important implications with respect to development of ground-water resources in the Sand Hills. Most of the water in the aquifer predates modern anthropogenic activity so excessive removal of water by pumping is not likely to be replenished by natural recharge in a meaningful timeframe. Vertical gradients in ground-water age were used to estimate long-term average recharge rates in the aquifer. In most areas, the recharge rates ranged from 0.02 to 0.05 foot per year. The recharge rate was 0.2 foot per year in one part of the aquifer characterized by large downward hydraulic gradients. Nitrite plus nitrate concentrations at the water table were 0.13 to 3.13 milligrams per liter as nitrogen, and concentrations substantially decreased with depth in the aquifer. Dissolved-gas and nitrogen-isotope data indicate that denitrification in the aquifer removed 0 to 97 percent (average = 50 percent) of the nitrate originally present in recharge. The average amount of nitrate removed by denitrification in the aquifer north of the Platte River (Sand Hills) was substantially greater than the amount removed south of the river (66 as opposed to 0 percent), and the extent of nitrate removal appears to be related to the presence of thick deposits of sediment on top of the Ogallala Group in the Sand Hills that contained electron donors, such as organic carbon and pyrite, to support denitrification. Apparent rates of dissolved-oxygen reduction and denitrification were estimated on the basis of decreases in dissolved-oxygen concentrations and increases in concentrations of excess nitrogen gas and ground-water ages along flow paths from the water table to deeper wells. Median rates of dissolved-oxygen reduction and denitrification south of the Platte River were at least 10 times smaller than the median rates north of the river in the Sand Hills. The relatively large denitrification rates in the Sand Hills indicate that the aquifer in that area may have a greater capacity to attenuate nitrate contamination than the aquifer south of the river, depending on rates of ground-water movement in the two areas. Small denitrification rates south of the river indicate that nitrate contamination in that part of the aquifer would likely persist for a longer period of time.

Nebraska↗