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Assessing the state of hydrologic science in the Upper Klamath Basin—A comprehensive review of data, tools, and models

Water demand in the Upper Klamath Basin (UKB) from various stakeholders and ecological needs often outstrips available supply, leading to persistent management challenges. This study reviews the state of hydrologic science within the UKB as of 2025—specifically, the tools, data, and models available for assessing five key components of the water system: (1) surface water; (2) precipitation; (3) evapotranspiration; (4) groundwater; and (5) water use. The UKB water supply is critical for Native American communities, regional agriculture, and federally listed fishes and faces challenges from competing needs, climate variability, and operational/regulatory requirements. We assess existing datasets, regional and national models, and historical studies to understand the available resources and identify gaps that may hinder integrated water assessments and management. Our findings indicate areas where improvements in data collection and model precision could improve the accuracy of water-availability forecasts and support water-management practices. This review can inform near-term forecasting, assist in optimizing water-resource data collection and management strategies, and support regional water-availability assessments of the basin.

Oregon

Vulnerability assessment of groundwater influenced ecosystems in the Northeastern United States

Groundwater-influenced ecosystems (GIEs) are increasingly vulnerable due to groundwater extraction, land-use practices, and climate change. These ecosystems receive groundwater inflow as a portion of their baseflow or water budget, which can maintain water levels, water temperature, and chemistry necessary to sustain the biodiversity that they support. In some systems (e.g., springs, seeps, fens), this connection with groundwater is central to the system’s integrity and persistence. Groundwater management decisions for human use often do not consider the ecological effects of those actions on GIEs. This disparity can be attributed, in part, to a lack of information regarding the physical relationships these systems have with the surrounding landscape and climate, which may influence the environmental conditions and associated biodiversity. We estimate the vulnerability of areas predicted to be highly suitable for the presence of GIEs based on watershed (U.S. Geological Survey Hydrologic Unit Code 12 watersheds: 24–100 km 2 ) and pixel (30 m × 30 m pixels) resolution in the Atlantic Highlands and Mixed Wood Plains EPA Level II Ecoregions in the northeastern United States. We represent vulnerability with variables describing adaptive capacity (topographic wetness index, hydric soil, physiographic diversity), exposure (climatic niche), and sensitivity (aquatic barriers, proportion urbanized or agriculture). Vulnerability scores indicate that ~26% of GIEs were within 30 m of areas with moderate vulnerability. Within these GIEs, climate exposure is an important contributor to vulnerability of 40% of the areas, followed by land use (19%, agriculture or urbanized). There are few areas predicted to be suitable for GIEs that are also predicted to be highly vulnerable, and of those, climate exposure is the most important contributor to their vulnerability. Persistence of GIEs in the northeastern United States may be challenged as changes in the amount and timing of precipitation and increasing air temperatures attributed to climate change affect the groundwater that sustains these systems.

Connecticut, Delaware, District of Columbia, Maine

Water-quality assessment of south-central Texas — Descriptions and comparisons of nutrients, pesticides, and volatile organic compounds at three intensive fixed sites, 1996-98

Water-quality samples were collected during April 1996-April 1998 at three intensive fixed sites in the San Antonio region of the South-Central Texas study unit as part of the U.S. Geological Survey National Water-Quality Assessment Program. The sampling strategy for the intensive fixed-site assessment is centered on obtaining information about the occurrence and seasonal patterns of selected constituents including nutrients, pesticides, and volatile organic compounds. The three sites selected to determine the effects of agriculture and urbanization on surface-water quality in the study unit are Medina River at LaCoste (agriculture indicator site), Salado Creek (lower station) at San Antonio (urban indicator site), and San Antonio River near Elmendorf (integrator site). Concentrations of two nutrients, dissolved nitrite plus nitrate nitrogen and total phosphorus, were largest at the integrator site, which is downstream of municipal wastewater treatment plants. Nitrite plus nitrate nitrogen concentrations at this site often exceeded the U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL) for drinking water. All total phosphorus concentrations at the site exceeded the EPA recommended maximum concentration for streams not discharging directly into reservoirs. Nitrite plus nitrate nitrogen concentrations at the integrator site tended to be smaller, and total phosphorus concentrations at the urban site tended to be larger in samples collected during stormflow than during base flow. The most detections and largest concentrations of three pesticides (atrazine, diazinon, and prometon) were in samples collected at the urban site. Some pesticide concentrations at the agriculture site showed a seasonal pattern of increasing concentrations during spring, the peak application season. Four pesticides (atrazine, deethylatrazine, diazinon, and prometon) were detected in at least 38 percent of samples collected at all three sites. The concentrations of all detected pesticides that have an MCL were less than the MCL at the three sites. More volatile organic compounds (VOC) were detected at the urban indicator site than at the agriculture indicator site, mostly likely because more sources are located in urbanized areas. The most VOCs detected and the largest concentrations of two VOCs (chloroform and tetrahydrofuran) were in samples from the integrator site. More VOCs were detected in samples collected at the integrator site during stormflow than during base flow. The concentrations of all detected VOCs that have an MCL were less than the MCL at the three sites.

Texas

Modeling future groundwater depletion to evaluate sustainability goals set under the Sustainable Groundwater Management Act in the critically overdrafted basins of the Central Valley, California, USA (2020–2070)

In 2014, California's Sustainable Groundwater Management Act (SGMA) mandated local agencies to devise and implement groundwater sustainability plans to address critically overdrafted conditions throughout the state's aquifers. However, the feasibility of these agencies' sustainability goals has not previously been assessed through a regional-scale, integrative lens. Here, we develop and analyze a novel, basin-wide database of 936 sustainability indicator wells located within Central Valley subbasins designated as critically overdrafted, most of which lie in the San Joaquin Valley. Our database shows 2040 groundwater elevation goals vary widely from 60 m above to 80 m below 2020 levels, with variability within and between adjacent subbasins. To evaluate the feasibility of achieving these goals, we coupled the database with a regional hydrologic model (Central Valley Hydrologic Model version 2) and simulated multiple future pumping scenarios. Results show that under increased groundwater demand, 60%–70% of indicator wells may fail to meet their 2040 goals. Even a 50% reduction from 2020 demand levels leaves nearly 40% of wells failing to meet their sustainability thresholds by 2040. Baseline models show that by 2070, up to 70% of wells could fail to meet their goals due to large-scale, spatially connected regions of groundwater depletion. This integrated framework, linking the first region-wide compilation of SGMA indicator wells with a regional groundwater model, demonstrates that many local sustainability goals may be unattainable with substantial (up to 50%) reductions in pumping. Additional management interventions, such as expanded recharge or coordinated demand reductions, may help achieve sustainability goals.

California

Simulation of the impacts of projected climate change on groundwater resources in the urban, semiarid Yucaipa Valley watershed, southern California using an integrated hydrologic model

Managing water resources in semiarid watersheds is challenging due to limited supply and uncertain future climate conditions. This paper examines the impact of future climate changes on an urban watershed in southern California using an integrated hydrologic model. GSFLOW modeling software is used to simulate the nonlinear relationships between climate trends and precipitation partitioning into ET, runoff, and subsurface storage. Four global circulation models (GCMs), each with two greenhouse-gas scenarios, RCP45 and RCP85 are used to project future climate conditions. GCMs include the CanESM2, CNRM-CM5, HadGEM2-ES, and MIROC5 models. The model's simulated hydrologic conditions are compared with historical data to assess changes in water budgets and groundwater supply. Results indicate decreased groundwater storage in most scenarios due to increased natural evapotranspiration, vegetation consumptive use, and streamflow out of the watershed. Only scenarios with substantially increased future precipitation show increased groundwater storage. The study also highlights increased future aridity despite the rise in precipitation and large precipitation events forecast by GCMs, which increase the risk of urban floods and decrease stream leakage and water available to vegetation.

California

Ambient field seismology in critical zone hydrological sciences

Passive ambient noise monitoring is an emerging tool in environmental seismology, leveraging the ambient seismic field to assess temporal variations in shallow subsurface properties. This review focuses on the potential and challenges of using scattered coda waves from noise correlation functions to monitor critical zone dynamics. The sensitivity of seismic velocities to various environmental factors, including precipitation, snowmelt, atmospheric pressure, and groundwater fluctuations, underscores the method’s versatility. While coda waves excel in detecting subtle changes due to their scattered nature, ballistic waves provide higher spatial resolution, albeit with challenges in source stability. Advances in seismic sensing, including distributed acoustic sensing and low-cost geophone networks, have enabled high-resolution monitoring of hydrological processes, subsurface deformation, and seismic hazards. Integrating seismic data with hydrological models provides insights into water storage, pore pressure changes, and soil moisture dynamics. However, limitations in spatial resolution, calibration with ground truth data, and coupled effects between environmental factors remain key challenges. This review emphasizes the importance of interdisciplinary approaches in refining methodologies, enhancing sensor deployments, and addressing data gaps. Passive seismic monitoring offers opportunities to understand critical zone processes and their broader impacts on seismic hazards and environmental sustainability.

Comptes Rendus. Géoscience

Restoring dryland water cycles for precipitation feedback and climate stability; a review

Drylands across the globe are experiencing intensifying water scarcity, land degradation, and hydroclimatic extremes. This review integrates evidence from multidecadal field studies, hydrologic monitoring, geomorphic and ecological assessments, remote sensing, and land–atmosphere science to evaluate how restoration influences key components of the terrestrial water cycle. Low-tech natural infrastructure in dryland streams (NIDS)—including check dams, leaky weirs, one-rock dams, and gabions—has emerged as a promising but under-synthesized nature-based solution for restoring hydrologic function in these environments. We describe the mechanisms through which these interventions modify runoff detention, infiltration, sediment and alluvial storage, shallow-groundwater recharge, vegetation recovery, and surface-energy partitioning, and we summarize outcomes across diverse dryland settings. Findings consistently show increased water residence time, enhanced soil-moisture storage, expanded riparian vegetation, extended flow duration, and shifts toward greater latent-heat flux—producing localized cooling and strengthened ecohydrological feedbacks. Building on these localized effects, we articulate a hypothesis that links the spatial extent of restoration, the density of NIDS per unit drainage area, and the magnitude of the latent-to-sensible-heat contrast generated by wetter post-rainfall conditions. Specifically, we hypothesize that when NIDS are implemented at densities permitted by topography and across areas large enough to maintain elevated soil moisture after storm events, the resulting increases in latent heat flux, surface cooling, and boundary-layer moistening may enhance moisture convergence and boundary-layer development, potentially increasing the likelihood or stability of convective precipitation, analogous to how reductions in these processes have contributed to regional drought intensification. These land–atmosphere feedbacks remain untested at scale but represent an important research Frontier. By integrating hydrologic, geomorphic, ecological, and atmospheric perspectives, this review provides a comprehensive framework for considering how low-tech, landscape-scale interventions can strengthen watershed resilience and contribute to climate-relevant nature-based solutions.

Arizona

Guidelines for producing integrated 210Pb and 14C age-models

Accurate reconstructions of past environmental changes are crucial in paleoecological research and require reliable chronologies of sedimentary archives. Establishing robust age-models and obtaining the most appropriate proxies for analysis is a complex scientific endeavor, requiring extensive resources and collaboration among specialists, including radiochronologists. Radiometric dating methods, such as 210 Pb and radiocarbon ( 14 C), are frequently employed to establish chronologies in aquatic sedimentary deposits and peat bogs. In this study, we review key aspects of sampling, analysis, and the principles underlying 210 Pb and 14 C age-models, focusing on methods for developing robust joint chronologies for paleoenvironmental research. Drawing largely from the authors' experiences and group discussions during and after a scientific workshop in 2022, we discuss important considerations for site selection, sampling strategies, and radiometric dating to construct integrated 210 Pb and 14 C age-models. Using expert consensus, this group – called Paleostats – aims to provide a set of best practices for other geochronologists with this methods paper. Among our conclusions, we emphasize the importance of accounting for site-specific factors such as prior information on sedimentation rates to establish appropriate sampling and analytical strategies. The use of appropriate coring devices can minimize disturbance to sediments and ensure the core surface remains intact and preserved until sectioning. Where excess 210 Pb is expected, sectioning at intervals of ≤1 cm provides an adequate sampling resolution for 210 Pb dating. Exceptions are possible, allowing for ~2–3 cm sections in areas with confirmed high sedimentation rates (e.g., > 1 cm yr −1 ). Recovering deeper core sections for 14 C dating with sufficient overlap allows for accounting errors in depth estimates made in the field. Special attention is advised during time intervals where validation proxies, such as the human-made radionuclides 137 Cs or post-bomb 14 C, are expected, and to determine the depth of secular equilibrium between 210 Pb and 226 Ra. Radiocarbon analyses are commonly performed by accelerator mass spectrometry, and age models are constructed mainly using Bayesian statistics with Markov Chain Monte Carlo techniques (e.g., Bacon ). A Bayesian approach ( Plum ) is now available for producing 210 Pb age-models, which infers the 210 Pb ex flux, eliminates the need for selecting an equilibrium depth, and allows dating cores with incomplete 210 Pb ex inventory. Plum offers improved chronologies by integrating raw 210 Pb and 14 C data, and these age-models can be enriched with other dating methodologies, such as identifying tephras and other well-recorded historical events. Harmonized reporting would contribute to making radiometric age-models reproducible, which would benefit from an international effort. Using 210 Pb and 14 C to produce integrated age-models may yield better insights into the interplay between natural and recent anthropogenic forcings on ecosystems. This can enhance our understanding of environmental processes and their impacts on climate change, ultimately supporting science-based assessments and decisions.

Earth-Science Reviews

The abandoned mine inventory of the United States—A brief summary

The Infrastructure Investment and Jobs Act of 2021 required the Secretary of the Interior to establish a program to inventory abandoned hard-rock mines in the United States. The Department of the Interior’s Office of Environmental Policy and Compliance asked the U.S. Geological Survey’s Mineral Deposit Database project (USMIN) to use existing data sources to build an inventory of all individual abandoned mine features in the United States. In addition to feature locations, this new database documents the surface land management agency, associated physical and environmental hazards, and any completed mitigation efforts. This information will improve risk assessment and support land management efforts, including hazard mitigation, ecosystem restoration planning, and reclamation. This fact sheet provides a brief overview of USMIN’s collaborative efforts with Federal, State, and Tribal agencies to build a comprehensive and authoritative national inventory of abandoned mine features.

Fact Sheet

Assessing nonpoint-source uranium pollution in an irrigated stream-aquifer system

Uranium (U) in rocks and soils of arid and semi-arid environments can be mobilized by irrigation and fertilization, posing environmental and health risks. Elevated U, along with selenium (Se) and nitrate (NO 3 ) co-constituents, necessitates careful monitoring and management. We developed a distributed-parameter numerical model to assess U pollution in an irrigated stream-aquifer system, applying it to a 552 km 2 region in Colorado's Lower Arkansas River Valley (LARV) over 14 years. A MODFLOW model, describing groundwater and stream flow, was coupled with an RT3D-OTIS model to portray reactive U transport. Calibration using the PESTPP-iES iterative ensemble smoother (iES) software indicated good agreement with observed U concentrations. The model revealed substantial and variable U levels across the LARV, highlighting potential hotspots and possible contributing factors, such as geological composition of the bedrock and near-surface shale and aquifer sediments derived from them, irrigation practices, and riparian landscape. U levels exceed the chronic standard (85th percentile = 30 μg/L, set by the US Environmental Protection Agency), which is the permissible regulatory threshold, in groundwater across 44 % of the region and along the river by an average factor of 2.9. Simulated average U concentrations in the non-riparian aquifer and river are 124 μg/L and 60 μg/L, respectively, compared with 112 μg/L and 62 μg/L for measured values. The average 85th percentile U concentration is 222 μg/L in the aquifer and 82 μg/L in the river. Average simulated U mass loading to the river is 0.17 kg/day per km, compared to an estimated 0.23 kg/day per km. Findings provide a baseline for comparing future simulated outcomes of alternative best management practices (BMPs) for U pollution mitigation and offer a methodology applicable to other irrigated regions.

Colorado

Design and function of the Autonomous Benthic Imaging and Surveying System (ABISS) for remote sensing of lake and seabed environments

Lake and seabed environments are home to fisheries and other biota that are important to ecosystems and economies, yet these environments and the species that use them are difficult to accurately assess and monitor. Traditional benthic survey techniques, like bottom trawling used by the U.S. Geological Survey, are limited by substrate constraints, poor spatial resolution and precision, and operational depth limits, hindering accurate assessment of benthic species and habitats. In response to these limitations, the U.S. Geological Survey developed the Autonomous Benthic Imaging and Surveying System, a camera system integrated into underwater vehicles, to capture high-resolution images of the lakebed. The system uses color and stereo cameras to collect imagery, which can be analyzed using computational methods to detect organisms and (or) characterize habitat features, such as geologic substrate types. The system has been integrated into autonomous underwater vehicles and into an underwater housing used by self-contained underwater breathing apparatus (SCUBA) divers. Although the engineering of the system was motivated by the need for data collection in the Great Lakes, it has potential to collect high quality data in any aqueous setting with sufficient water clarity and safe operating conditions. The Autonomous Benthic Imaging and Surveying System can operate across diverse depths and light conditions to map and quantify ecological patterns that were difficult or impossible to assess using traditional methods. The Autonomous Benthic Imaging and Surveying System offers the potential for accurate and precise monitoring and assessment of native benthic biota, invasive species, and habitat, potentially providing natural resource managers with improved information to support decision making about benthic resource management.

Great Lakes

Estimating agricultural irrigation water consumption for the High Plains aquifer region with integrated energy- and water-balance evapotranspiration modeling approaches

Estimation of irrigation water use provides essential information for the management and conservation of agricultural water resources. Conventionally, water use data are created based on reports and surveys from water users, whereas manual records may not be complete due to lacking flow meters, measurement gaps, inconsistent methods across regions, and time- and cost-consuming data processing. Alternatively, spatially explicit estimation of irrigation water use can be conducted efficiently using remote sensing evapotranspiration (ET) modeling approaches. In this study, we created a gridded blue water evapotranspiration (BWET) dataset to estimate historical irrigation water consumption (1986 – 2020) in the croplands across the United States High Plains aquifer region. The BWET data were generated by integrating an energy-balance ET model [Operational Simplified Surface Energy Balance model (SSEBop)] and a water-balance ET model [Vegetation ET model (VegET)]. BWET in croplands indicates crop consumptive use of irrigation water extracted from surface water and groundwater resources. The BWET estimates were compared with reported irrigation water use data for all counties within the aquifer region. The results revealed high agreement between growing season (May – September) BWET and annual water withdrawal at county level. Specifically, correlation coefficients of volumetric BWET and water withdrawal were 0.90 and 0.96, respectively, for the entire aquifer region and western Kansas. The timeseries of BWET and water withdrawal showed similar temporal trends and high covariations. The BWET estimates were systematically lower than the water withdrawal measurements, which was primarily attributed to blue water losses in the irrigation system. The irrigation efficiency, calculated as the ratio of BWET to water withdrawal depth, was 0.57 and 0.74 for the entire aquifer region and western Kansas, respectively. This study demonstrates the capability of using satellite-based ET models (e.g., SSEBop and VegET) to efficiently estimate crop water consumption and evaluate irrigation efficiency at landscape, county, and regional scales.

Colorado, Kansas, Nebraska, New Mexico, Oklahoma,

A practical decision tool for marine bird mortality assessments

Given the rise in anthropogenic, environmental, and disease events contributing to marine bird mortality, there is a critical need to improve the rigor of mortality assessments. Deficits in data collection and mortality estimation can hinder a manager’s ability to document the scale of events and assess population level impacts. Therefore, to inform decisions required during activities, such as conservation status assessments or harvest management, organizations may choose to incorporate mortality assessments into response plans. Resources, capacity, and assets to assess mortality vary across jurisdictions (federal, state, Indigenous, local, etc.), and clear guidance to support mortality assessments is often unavailable or not clearly addressed. Here, we present a decision support tool to help managers identify and evaluate survey options to assess bird mortality in a diverse array of scenarios. The objective of the decision tool is to improve data collection and availability, which will increase the ability to estimate mortality robustly, given situation-specific attributes and constraints. This decision tool is designed to guide the response when a mortality event is initially encountered and offers suggestions for assessment and reporting procedures in the absence of other guidance or to complement existing protocols. The decision tool is also meant to inform decision making for response determination and resource allocation. The tool facilitates examination of options for further assessment and monitoring, which users determine by examining questions pertaining to species prioritization, determination of mortality minimum spatial extent, and the potential magnitude of impacts on affected species. Finally, identification of appropriate survey methods that address imperfect detection when a complete census is not possible are determined by exploring location, spatial and temporal extent, and the type of species affected. Ultimately, this decision tool aims to facilitate and improve the standardization of mortality assessments, equipping managers with a practical resource to navigate the decision-making process for marine bird mortality estimation.

Ornithological Applications

Insights and strategic opportunities from the USGS 2024 Per- and Polyfluoroalkyl Substances (PFAS) Interagency Workshop

Introduction In 2021, the U.S. Geological Survey (USGS) published Circular 1490 titled, “Integrated Science for the Study of Perfluoroalkyl and Polyfluoroalkyl Substances (PFAS) in the Environment: A Strategic Science Vision for the U.S. Geological Survey” (Tokranov and others, 2021). Circular 1490 was created to be a resource for USGS scientists prioritizing and planning research related to per- and polyfluoroalkyl substances (PFAS) and to be a guide for developing partnerships with other scientists, State and Federal agencies, and stakeholders engaged in PFAS research and management and mitigation of the environmental and human-health effects of PFAS. This USGS PFAS Strategic Science Vision document was intended to be the foundation for a “living strategic vision,” periodically providing updates on the state of USGS PFAS research, emerging PFAS data gaps and needs, and progress on interagency and stakeholder PFAS partnerships and priorities. To meet this objective, the USGS planned to host an Interagency and Stakeholder PFAS Workshop every 2–3 years. During September 10–12, 2024, the USGS hosted the first Interagency and Stakeholder PFAS Workshop in Reston, Virginia. The Workshop brought together experts from other Federal agencies (U.S. Environmental Protection Agency, National Institute of Environmental Health Sciences, Food and Drug Administration, Department of Defense [Air Force, Army]), State agencies (Washington Fish and Wildlife, Virginia Department of Transportation), and academia (Harvard University, University of Maryland) to address key challenges relating to the measurement and modeling of PFAS and the implications for environmental health. Participants engaged in in-depth discussions centered around six pivotal topics related to PFAS: (1) sampling protocols, methods and interpretation; (2) environmental sources, source apportionment, and occurrence; (3) environmental fate and transport; (4) human and wildlife exposure routes and risk; (5) bioconcentration, bioaccumulation, and biomagnification; and (6) ecotoxicology and effects. Each topic had three breakout sessions. A recurrent theme of workshop discussions was how data on a nationwide scale for PFAS occurrence in various environmental matrices, including air, water, food crops, biota, soil, and streambed sediment could help to advance scientific understanding. Participants noted significant geospatial data gaps, particularly in the midwestern and southern United States and the Pacific Northwest. PFAS data collection tends to be more robust along the eastern seaboard and in California. Participants stressed how enhancing the integration of large and small datasets across various agencies could help to support national scale understanding of PFAS. To address these gaps, attendees suggested leveraging datasets from Federal entities like the USGS and the U.S. Department of Defense, State agencies, and municipal utility services to develop predictive contaminant detection and transport models. Improved coordination between water quality programs and USGS research could help to facilitate access to valuable data, leading to comprehensive databases that inform PFAS point (wastewater treatment plants and landfills) and nonpoint (runoff from land, atmospheric deposition, food packaging) sources, environmental transport mechanisms, environmental detection and concentrations, potential exposure routes, and health effects on different biota, including humans. A specific request was made to develop a map demarking the depth of modern (1953 or later) groundwater, which is susceptible to surface-derived anthropogenic (that is, human-made) contamination, based on tritium-age dating. Emphasis was placed on incorporation of hydrology, groundwater flow paths, groundwater–surface water interactions, and landscape factors in predictive statistical models as a step to improve contaminant source identification and tracking. Molecular fingerprinting approaches garnered attention as techniques to link specific PFAS mixtures detected in a sample to environmental sources and levels in biota (Dávila-Santiago and others, 2022). Integrating data from abiotic (that is, water, soil, and air) and biotic (that is, living organisms) systems identified as a research opportunity. For example, understanding the composition of soils and sediments, which include a mixture of mineral, plant, and animal components, could advance understanding of exposure pathways. The discussions highlighted opportunities to explore and understand the potential redistribution and biotic exposures of PFAS from biosolid and wastewater treatment plant effluent land application practices, in addition to atmospheric releases and discharges from landfill and wastewater treatment plants. Participants identified research gaps surrounding how these sources may contribute to contamination and may affect surrounding ecosystems, including a better definition of anthropogenic background concentrations. Moving forward, the collection of co-occurrence data was noted as a means to improve understanding of complex mixtures and to leverage companion modeling efforts focused on areas with high and low contamination levels to identify areas of concern and unaffected resources. Participants emphasized how centralized USGS databases and the establishment of sample-metadata archives can help to ensure that samples are preserved and accessible for future research. In conclusion, the workshop participants identified opportunities to bridge data gaps and improve measurement techniques, modeling frameworks, databases, and communication, to enhance the understanding of PFAS and their effects on environmental and human health. Upon completion of the workshop, participants indicated an interest in developing strategic data collection, modeling, and analytical approaches to address these challenges.

Open-File Report

The 3D Elevation Program—Supporting New Hampshire’s economy

Introduction The topography of New Hampshire ranges from the Coastal Lowlands to the Eastern New England Upland to the White Mountains region. High-quality statewide elevation data are useful in managing this very diverse landscape. For example, the short coastline, including the Great Bay estuary and the Hampton-Seabrook marshes, is of disproportionately high value to New Hampshire’s tourist economy. The vulnerability of the coast to the effects of sea-level rise underscores the need for accurate, high-quality nearshore topographic elevation data and offshore bathymetric data to effectively manage the coast’s valuable resources, which include important fisheries, habitat, and infrastructure. Another important use for accurate elevation data in New Hampshire is in the evaluation of flood hazards and their potential environmental and infrastructure effects. This evaluation includes mapping of inundation and sediment transport, and assessing the associated costs of flooding. Addressing this challenge requires detailed knowledge of both surface topography and inland bathymetry. Other important activities having a substantial economic element and needing accurate elevation data include geologic resource assessment and hazard mitigation, urban and regional planning, infrastructure and construction management, and cultural resources preservation and management. Critical applications that meet the State’s management needs depend on light detection and ranging (lidar) data that provide a highly detailed three-dimensional model of the Earth’s surface and aboveground features.

New Hampshire

From landslide susceptibility to risk assessment in the conterminous U.S.

Understanding the spatial distribution of landslide prone-areas and what consequences they may have is important for risk management and land-use planning. In the United States, although landslides occur in every state, a comprehensive landslide risk assessment is still missing. Existing efforts, such as the Federal Emergency Management Agency (FEMA)’s National Risk Index, rely on aggregated products and coarse cartographic units, limiting their geomorphological and practical accuracy. In this study, we present a methodological advance for landslide risk assessment across large areas with incomplete and sparse data. We apply our procedures to the conterminous United States by integrating geomorphologically meaningful partitions and spatial and temporal probability data-driven models. Landslide susceptibility is estimated using a Generalized Additive Mixed Model incorporating a bias capture/correction scheme to account for inventory inaccuracies (reference Area Under the Curve = 0.75). The exceedance probabilities of landslide occurrence are defined for three temporal scenarios (2, 5, and 10 year). Then, we explore the associated potential economic consequences for human settlements and agricultural areas. The findings indicate that the spatial variability of risk is primarily controlled by exposure rather than by susceptibility/hazard alone. The mean risk increases by ∼170% from the 2-year to the 10-year scenario. Beyond its quantitative outcomes, this study offers a blueprint for continental or sub-continental scale landslide risk assessments, demonstrating both the opportunities and current limitations.

Engineering Geology

Assessing spatial variability of nutrients, phytoplankton, and related water-quality constituents in the California Sacramento–San Joaquin Delta at the landscape scale—2018 high resolution mapping surveys

Executive Summary This study examined the abundance and distribution of nutrients and phytoplankton in the tidal aquatic environments of the Sacramento–San Joaquin Delta (Delta) and Suisun Bay, comprising three spatial surveys conducted in May, July, and October of 2018 that used continuous underway high frequency sampling and measurements onboard a high-speed boat to characterize spatial variation across the extent of the Delta. The method used involves simultaneously collecting information about the concentration and spatial distribution of all major nutrient forms with analogous information about the major classes of phytoplankton and associated water-quality conditions. The results showed substantial variation across space and time, providing an unprecedented snapshot of the dynamic environmental processes that shape the ways nutrients interact with and affect aquatic habitats in the Delta. The purposes of this study were to improve our understanding of how hydrodynamics, landscape features, and aquatic primary productivity interact to drive nutrient cycling and transport in the Delta and to provide insights into the underlying processes most directly responsible for the conditions at the time of this study, and thus into the range of conditions that may be expected following the wide array of prospective future changes to the Delta. One major anticipated change at the time of this study was the planned upgrade to the Sacramento Regional Wastewater Treatment Plant, but the study also informs our understanding of potential effects from other changes to the Delta, such as those caused by other nutrient-management actions, flow actions, large-scale wetland restoration, drought, flood, levee failure, and changes to water management. Nutrient loading is the primary driver of nutrient concentrations in the Delta, but several other major drivers interact to shape their distribution and effects: geomorphology, hydrodynamics, landscape features, and aquatic productivity. Hydrodynamics affect timescales of transport and dilution of nutrient loads in the Delta. During transit through the system, channel geometry, tidal mixing, and water exports affect hydrodynamics in diverse ways that influence water-residence and transport times, thereby markedly affecting the range of times during which natural internal cycling can alter nutrient concentrations and forms. Channel geometry and location shape tidal energy and river currents into these observed dynamics. Interactions with Delta aquatic landscapes such as herbaceous tidal marsh, submerged aquatic vegetation, and large expanses of intertidal or subtidal sediments (all highly productive landscapes) exert demand on available nutrient supplies but can also simultaneously transform and generate nutrients. Finally, while phytoplankton require nutrients to sustain production and thus are a potential nutrient sink, the amount and form of nutrients also can influence the occurrence of harmful algal blooms (HABs) that adversely affect aquatic organisms as well as affect the occurrence of beneficial algal blooms that result in production of algae that are favorable for imperiled Delta pelagic aquatic food webs. The surveys revealed a complex mosaic of spatial variation, with nutrient concentrations varying from near zero to well above concentrations considered eutrophic; nutrient concentrations were more often related to the extent of hydrologic transport and mixing than to specific geographic locations or to specific landscape features. Similarly, the surveys identified phytoplankton abundance ranging from near detection to the level of large phytoplankton blooms, with large variation in phytoplankton community composition. Although the study occurred during a period of low bloom activity, phytoplankton productivity appeared to be the strongest potential sink for inorganic nutrients in the Delta, indicating that it is a larger control on nutrient concentrations and distribution than previously understood. Cycling and transformation within the water column only appeared to substantially lower total nutrient concentrations at the longest estimated transport timescales. Contrary to expectations, we did not observe substantial nutrient depletion near landscape-scale features such as open-water habitats, submerged aquatic vegetation beds, extensive wetlands, or exposed sediments, indicating that these habitat types did not act as major sinks for nutrients in the Delta during these surveys. These results indicated that nutrient reduction efforts may have the greatest effect on pelagic phytoplankton productivity in the more productive reaches of the Delta and estuary, but these effects are unlikely to be magnified by changes to nutrient loss within the Delta over conceivable changes in flow conditions, Delta water management actions, or large-scale wetland restoration activities. Nevertheless, local processes were shown to cause substantial loss, and thus integrating of nutrient effects with other indicators of aquatic habitat conditions will help inform planning future actions at specific sites. Finally, we note that the primary contribution of this study was intended to be the survey data themselves. Aside from the results highlighted in this report, the surveys are a benchmark against which future environmental change may be evaluated, including changes to nutrient management or water exports, drought, large-scale wetland restoration, and climate change. Further, although we highlight some of the main findings from the surveys in this report, the necessarily limited scope precludes examination of many topics for which these surveys may be highly informative. To facilitate the utility of these data to stakeholders, managers, and researchers, we have released the data online (Bergamaschi and others, 2020) and created an online data exploration portal ( https:​//ca.water​.usgs.gov/​bay-​delta/​2018-​delta-​wide-​mapping-​surveys.html ) where users may query the surveys in a variety of ways to test hypotheses, examine relationships, assess spatial trends, and download data. The data exploration portal is intended to be an immersive experience that allows users to gain greater understanding of the complex interactions that shape Delta aquatic environments. This report is intended as a companion to the portal, allowing the reader to challenge and further explore the highlighted findings. This study was a collaboration between the U.S. Geological Survey and the Delta Regional Monitoring Program, with additional funding provided from U.S. Geological Survey Cooperative Matching Funds Program.

California

Critical review of mercury methylation and methylmercury demethylation rate constants in aquatic sediments for biogeochemical modeling

Mercury is a toxin that causes neurological impairments in adults, is particularly harmful for fetuses and children, and is deadly in severe cases, making it a worldwide health concern. Methylmercury (MeHg) is the environmentally relevant form of mercury (Hg) because it biomagnifies along the food chain. Methylmercury is mainly produced in aquatic sediments via methylation of inorganic Hg (Hg(II)) and transformed back via demethylation. Because transformation rates determine MeHg concentrations, quantification of methylation and demethylation rates is needed to inform management of MeHg. Published rate constants for Hg(II) methylation ( 𝑘 𝑚 ) and MeHg demethylation ( 𝑘 𝑑 ) vary greatly, stemming partly from differences in experimental methods. We conducted a comprehensive review of rate laws, evaluated published rate constants, and performed biogeochemical simulations to assess variability in reported 𝑘 𝑚 and 𝑘 𝑑 . Based on selected studies employing the same pseudo-first-order rate law and similar experimental methods, we found that 𝑘 𝑚 = 0.04 ± 0.03 d −1 is a reasonable range for wetland sediments. Over a number of environments, maximum 𝑘 𝑑 was smaller at sites without Hg source ( 𝑘 𝑑 = 0.5 d −1 ) than at sites with identified Hg source ( 𝑘 𝑑 = 1.8 d −1 ). Larger variability and higher uncertainty in 𝑘 𝑑 compared to 𝑘 𝑚 highlight the need for more research on MeHg demethylation rates. This critical review: (a) aids the design of future experimental studies of 𝑘 𝑚 and 𝑘 𝑑 ; (b) provides guidance for comparing rate constants from different studies; (c) presents a biogeochemical reaction model to assess rate constants; and (d) informs selection of 𝑘 𝑚 and 𝑘 𝑑 values from the literature for use in model simulations.

Critical Reviews in Environmental Science and Tech