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Council monitoring and assessment program (CMAP): A framework for using the monitoring program inventory to conduct gap assessments for the Gulf of Mexico Region

Executive Summary Under the Resources and Ecosystem Sustainability, Tourist Opportunities, and Revived Economies of the Gulf Coast States Act of 2012 (RESTORE Act), the Gulf Coast Ecosystem Restoration Council (RESTORE Council or Council) is required to report on the progress of funded projects and programs. Systematic monitoring of restoration at the project-specific and programmatic-levels (watershed and Gulf of Mexico) enables consistent reporting and gives the public confidence that the restoration investments selected by the RESTORE Council will be evaluated and adaptively managed accordingly. Monitoring information that has been collected at different spatial and temporal scales can be used as the foundation to illustrate progress towards comprehensive ecosystem restoration goals and objectives that promote holistic Gulf of Mexico recovery (see ‘RESTORE Council Background’ at the beginning of this report for additional Council information). Currently, federal, state and local agencies, universities, private industry, and non-governmental organizations (NGOs) are conducting monitoring activities at various scales around the Gulf of Mexico. In addition, each RESTORE Council-funded project will, at a minimum, perform project-specific monitoring. This collection of monitoring activities was inventoried and coordinated into a network of existing programs by the Council-funded RESTORE Council Monitoring and Assessment Program (CMAP), which will suggest opportunities for efficiencies and collaborative cross-program review of performance with other Gulf ecosystem recovery efforts. CMAP was designed and funded to inventory and integrate existing monitoring efforts, improve discovery and accessibility of existing monitoring data, and ensure the collected information supports management decisions. The fundamental approach to building the CMAP Gulf of Mexico water quality monitoring, habitat monitoring, and mapping network was to: 1. Adopt, or construct as needed, a comprehensive inventory of existing habitat and water quality observation, monitoring, and mapping programs in the Gulf of Mexico (hereafter referred to as the “Inventory”; NOAA and USGS, 2019a); 2. Evaluate the suitability/applicability of each program and its existing and prospective data for use in restoration activities; 3. Develop a process to use the Inventory to conduct gap assessments; 4. Develop a catalog of baseline assessments conducted in the Gulf of Mexico (NOAA and USGS, 2019b); and 5. Develop a searchable monitoring information portal/database to enable access to collected information and products.

Alabama, Florida, Georgia, Louisiana, Mississippi,

Sampling and monitoring for closure

An important aspect of planning a new mine or mine expansion within the modern regulatory framework is to design for ultimate closure. Sampling and monitoring for closure is a form of environmental risk management. By implementing a sampling and monitoring program early in the life of the mining operation, major costs can be avoided or minimized. The costs for treating mine drainage in perpetuity are staggering, especially if they are unanticipated. The Metal Mining Sector of the Acid Drainage Technology Initiative (ADTI-MMS), a cooperative government-industry-academia organization, was established to address drainage-quality technologies of metal mining and metallurgical operations. ADTI-MMS recommends that sampling and monitoring programs consider the entire mine-life cycle and that data needed for closure of an operation be collected from exploration through postclosure.

Reviews in Engineering Geology

Ethoxyresorufin-O-deethylase (EROD) activity in fish as a biomarker of chemical exposure

This review compiles and evaluates existing scientific information on the use, limitations, and procedural considerations for EROD activity (a catalytic measurement of cytochrome P4501A induction) as a biomarker in fish. A multitude of chemicals induce EROD activity in a variety of fish species, the most potent inducers being structural analogs of 2,3,7,8-tetracholordibenzo- p -dioxin. Although certain chemicals may inhibit EROD induction/activity, this interference is generally not a drawback to the use of EROD induction as a biomarker. The various methods of EROD analysis currently in use yield comparable results, particularly when data are expressed as relative rates of EROD activity. EROD induction in fish is well characterized, the most important modifying factors being fish species, reproductive status and age, all of which can be controlled through proper study design. Good candidate species for biomonitoring should have a wide range between basal and induced EROD activity (e.g., common carp, channel catfish, and mummichog). EROD activity has proven value as a biomarker in a number of field investigations of bleached kraft mill and industrial effluents, contaminated sediments, and chemical spills. Research on mechanisms of CYP1A-induced toxicity suggests that EROD activity may not only indicate chemical exposure, but also may also precede effects at various levels of biological organization. A current research need is the development of chemical exposure-response relationships for EROD activity in fish. In addition, routine reporting in the literature of EROD activity in standard positive and negative control material will enhance confidence in comparing results from different studies using this biomarker.

Critical Reviews in Toxicology

Geologic characteristics of sediment- and volcanic-hosted disseminated gold deposits - Search for an occurrence model

The current expansion of resource information, particularly on "disseminated" gold, and the improved technologies now available for resource investigations should place us in an enhanced position for developing a better predictive methodology for meeting one of the important responsibilities of the U.S. Geological Survey-to examine and assess the mineral resources of the geologic terranes composing the public (and privately owned) lands of the United States. The first step is systematic organization of these data. Geologic-occurrence models are an effective systematic method by which to organize large amounts of resource information into a logical sequence facilitating its use more effectively in meeting several industry and Survey objectives, which include the exploration for resources and the assessment of resource potential for land-use decisions. Such models also provide a scientific basis for metallogenesis research, which considers the observable features or attributes of ore occurrence and their "fit" into the Earth's resource puzzle. The use of models in making resource assessments/appraisals was addressed by Shawe (1981), who reported the results of a workshop on methods for resource appraisal of Wilderness and Conterminous United States Mineral Appraisal Program (CUSMAP; 1:250,000-scale quadrangles) areas. The Survey's main objective in the 1982 workshop was to evaluate the status of knowledge about disseminated or very fine grained gold deposits and, if possible, to develop an occurrence model(s). This report on the workshop proceedings has three main objectives: (1) Education through the publication of a summary review and presentation of new thinking and observations about the scientific bases for those geologic processes and environments that foster disseminated gold-ore formation; (2) systematic organization of available geologic, geochemical, and geophysical information for a range of typical disseminated gold deposits (including recognition of gaps in those data); and (3) assessment of current understanding (as presented in objective 2) toward formulating an empirical ore-occurrence model for this type of deposit. As such, this volume represents a preliminary first step at classification and provides a source of pertinent background information. Readers of this volume will soon discover, however, that full agreement has not yet been achieved in the interpretation of some of the geologic evidence. The resulting variations in tentative occurrence models for these controversial deposits ultimately will be resolved by filling the gaps in information that have already been identified. Thus, this volume does not report a U.S. Geological Survey consensus; the conclusions expressed in each chapter represent the particular interpretations of the various workshop participants.

Arizona, California, Idaho, Nevada, Utah

The hydrogeologic framework and a reconnaissance of ground-water quality in the Piedmont Province of North Carolina, with a design for future study

The U.S. Geological Survey is investigating the relation of ground- water quality and land use in the regolith and fractured rock ground-water system of the North Carolina Piedmont. The initial phase of this study provides a description of the ground-water flow system and a review of available ground-water data and formulates hypotheses that guide the design of a water-quality monitoring network for study of selected areas. In the Piedmont, the solid igneous and metamorphic bedrock grades upward into unweathered fractured rock that is covered by a transition zone of highly-fractured, partially weathered rock, clay-rich saprolite, and the soil. The fractured bedrock, transition zone, saprolite, and soil make up a complex flow system. A review of available ground-water quality data shows a lack of information about organic compounds and trace metals and changes in ground- water quality with depth. Land use, soils, and geology significantly influence ground-water quality. The hypotheses that need to be tested in the next study phase are: (1) that ground-water contamination can be related to land use, and (2) that the transition zone between bedrock and regolith serves as a primary transmitter of contaminants. Monitoring of basins containing industrial, urban, residential, and agricultural land uses in future studies will help define the relation of ground-water quality to land use. Water quality at different depths in the flow system and in streams during base flow needs to be identified.

North Carolina

Geomagnetic Workshop

A workshop on geomagnetism, sponsored by the Geologic Division of the U.S. Geological Survey, was held in the Denver West Office Complex in Golden, Colorado, April 13–15, 1982. There were 90 registered participants from government agencies, academic institutions, and industry. This effort stemmed from the realization that geomagnetism, once a small but coherent discipline, has now expanded into numerous areas of the geosciences, yet those doing research in these specialties seldom make contact outside their area of immediate interest. The impetus for this event came from the members of a committee formed to review the geomagnetic activities within the U.S. Geological Survey. They observed that the level of communication between the various elements of this now diverse discipline was inadequate, not only within their organization but also between federal agencies, academia, and the private sector. While the desire was to cover as much of geomagnetism as possible, it was necessary for a workshop of reasonable size and length to exclude some important areas of the subject: magnetic reversal chronology, studies of the externally produced variations, and most aspects of internal induction. The plan was to give emphasis to some of the newer areas: those which have recently seen a high level of activity and those with increasing activity abroad compared to that in the United States. The purpose was to evaluate the status and problems in selected areas with an eye to those whose emphasis might produce fruitful results in the next decade.

Eos, Transactions, American Geophysical Union

Hydrological, morphometrical, and biological characteristics of the connecting rivers of the International Great Lakes: a review

The connecting channels of the Great Lakes are large rivers (1, 200-9, 900 m3 • s-1) with limited tributary drainage systems and relatively stable hydrology (about 2:1 ration of maximum to minimum flow). The rivers, from headwaters to outlet, are the St. Marys, St. Clair, Detroit, Niagara, and St. Lawrence. They share several characteristics with certain other large rivers: the fish stocks that historically congregated for spawning or feeding have been overfished, extensive channel modification have been made, and they have been used as a repository for domestic and industrial wastes and for hydroelectric energy generation. Levels of phosphorus, chlorophyll a, and particulate organic matter increase 3- to 5-fold from the St. Marys River to the St. Lawrence River. Biological communities dependent on nutrients in the water column, such as phytoplankton, periphyton, and zooplankton similarly increase progressively downstream through the system. The standing crop of emergent macrophytes is similar in all of the rivers, reflecting the relatively large nutrient pools in the sediments and atmosphere. Consequently, emergent macrophytes are an important source of organic matter (67% of total primary production) in the nutrient poor waters of the St. Marys River, whereas phytoplankton production dominates (76%) in the enriched St. Lawrence River. Submersed and emergent macrophytes and the associated periphyton are major producers of organic matter in the connecting channels. Another major source of organic matter (measured as ash free dry weight, AFDW) in the Detroit River is sewage, introduced at a rate of 26, 000 t per year. The production of benthos ranges from a low 5.4 g AFDW•m-2 in the Detroit River to a high of 15.5 g AFDW•m-2 in the St. Marys River. The rivers lack the organic transport from riparian sources upstream but receive large amounts of high quality phytoplankton and zooplankton from the Great Lakes.

Canadian Special Publication of Fisheries and Aqua

U.S. Geological Survey Pollinator Science Strategy, 2025–35—A Review and Look Forward

This “U.S. Geological Survey Pollinator Science Strategy, 2025–35—A Review and Look Forward” (“Pollinator Science Strategy”) describes the science vision of the U.S. Geological Survey (USGS) to support management, conservation, and policy decisions on animal pollinators and their habitats. As the science arm of the Department of the Interior, the USGS has a primary role in providing scientific information to natural resource managers and policymakers across the United States. This “Pollinator Science Strategy” was drafted by a team of USGS pollinator researchers and was further developed through feedback from Federal, State, Tribal, nongovernmental organizations, and industry partners. This “Pollinator Science Strategy” highlights the USGS’s role in the research to promote healthy pollinator populations and address partner information gaps so they can make more informed management decisions. By outlining the importance of USGS science in addressing the information needs of other agencies, organizations, and the public, the “Pollinator Science Strategy” reaffirms the USGS’s commitment to pollinator research and showcases our research priorities for 2025–35. With more than 300 research centers nationally, the USGS is equipped to address pollinator science across scales of complexity and geographic range. USGS pollinator science is organized according to the following five thematic areas: Assessing species ecology, distributions, and natural history requirements. Tracking species status and trends. Understanding species threats and stressors. Informing restoration and management actions. Developing novel methods for improving pollinator research, monitoring, and population outcomes that can benefit our Nation. Our pollinator information products and associated data are made widely available to the public to ensure scientific transparency and accessibility. This “Pollinator Science Strategy” concludes with several research goals that the USGS will work towards from 2025 to 2035, representing our vision for USGS science. These research goals include synthesizing and modernizing the latest information on pollinator threats, developing research that assists managers with habitat design and restoration, providing training to partners on native bee identification and monitoring design, and developing new technologies for assessing the status and trends of our nation’s pollinators.

Circular

Sea-level rise modeling handbook: Resource guide for coastal land managers, engineers, and scientists

Global sea level is rising and may accelerate with continued fossil fuel consumption from industrial and population growth. In 2012, the U.S. Geological Survey conducted more than 30 training and feedback sessions with Federal, State, and nongovernmental organization (NGO) coastal managers and planners across the northern Gulf of Mexico coast to evaluate user needs, potential benefits, current scientific understanding, and utilization of resource aids and modeling tools focused on sea-level rise. In response to the findings from the sessions, this sea-level rise modeling handbook has been designed as a guide to the science and simulation models for understanding the dynamics and impacts of sea-level rise on coastal ecosystems. The review herein of decision-support tools and predictive models was compiled from the training sessions, from online research, and from publications. The purpose of this guide is to describe and categorize the suite of data, methods, and models and their design, structure, and application for hindcasting and forecasting the potential impacts of sea-level rise in coastal ecosystems. The data and models cover a broad spectrum of disciplines involving different designs and scales of spatial and temporal complexity for predicting environmental change and ecosystem response. These data and models have not heretofore been synthesized, nor have appraisals been made of their utility or limitations. Some models are demonstration tools for non-experts, whereas others require more expert capacity to apply for any given park, refuge, or regional application. A simplified tabular context has been developed to list and contrast a host of decision-support tools and models from the ecological, geological, and hydrological perspectives. Criteria were established to distinguish the source, scale, and quality of information input and geographic datasets; physical and biological constraints and relations; datum characteristics of water and land components; utility options for setting sea-level rise and climate change scenarios; and ease or difficulty of storing, displaying, or interpreting model output. Coastal land managers, engineers, and scientists can benefit from this synthesis of tools and models that have been developed for projecting causes and consequences of sea-level change on the landscape and seascape.

Professional Paper

Hydrogeologic framework, water levels, and selected contaminant concentrations at Valmont TCE Superfund Site, Luzerne County, Pennsylvania, 2020

The Valmont TCE Superfund Site, Luzerne County, Pennsylvania is underlain by fractured and folded sandstones and shales of the Pottsville and Mauch Chunk Formations, which form a fractured-rock aquifer recharged locally by precipitation. Industrial activities at the former Chromatex Plant resulted in trichloroethene (TCE) contamination of groundwater at and near the facility, which was identified in 1987 and led to listing as a Superfund site by the U.S. Environmental Protection Agency (EPA) in 1989. To address the problem of TCE concentrations in nearby residential wells that exceed the maximum contaminant level (MCL) of 5 micrograms per liter (μg/L), alternate water supplies were provided. A 2015 review of initial characterization and subsequent remediation by the EPA identified the need for an updated understanding of the complex hydrogeology and the conceptual site model. Additional contaminants present in groundwater at the site include some other volatile organic compounds (VOCs) and per- and polyfluoroalkyl substances (PFAS), predominantly consisting of perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) present in concentrations that exceeded the EPA Health Advisory (HA) level of 5 nanograms per liter (ng/L) for combined PFOA and PFOS. In response to a request from the EPA in 2019, the U.S. Geological Survey (USGS) prepared cross sections and maps to provide more information about the hydrogeologic framework at and near the site and assist in improving the conceptual site model using water level and contaminant data collected by the EPA in 2020. The cross sections present lithologic correlations from available geophysical logs collected in wells from 2002 to 2014; they show alternating intervals of relatively elevated and reduced natural gamma activity that correspond to changes in lithology, with water-bearing zones and well screens commonly located at lithologic contacts, sometimes near thin coal seams. Water-bearing zones commonly are associated with fractures at or near lithologic contacts but also may be associated with fractures at or near apparent faulting. Recent (March 2020) water-level data shown on cross sections and maps indicate large downward vertical gradients and apparent radial gradients laterally to the northeast, northwest, and southwest that generally following topography. Recent (February to March 2020) data for TCE groundwater concentration shown on cross sections and maps indicate the highest TCE concentrations (greater than 3,000 μg/L and as much as 75,000 μg/L) and combined PFOA and PFOS concentrations (greater than 1,000 ng/L and up to at least 2,350 ng/L) are from shallow (less than 60 feet [ft] below land surface [bls]) and intermediate depth (60 to 100 ft bls) wells near the center of the former Chromatex Plant. TCE and PFAS (as combined PFOA and PFOS) contamination is present at greater depths, as much as 304 ft bls, as evidenced by samples collected from one well (a reconstructed former production well) near the plant, that contained concentrations of about 240 μg/L and 508 ng/L, respectively. The 2020 data also indicate that TCE and PFAS concentrations which exceed drinking-water MCL or HA levels are present in groundwater depths of less than 200 ft in an area that extends predominantly in a northeast direction from the former Chromatex Plant, and is apparently influenced by hydraulic gradients, lithology, and geologic structure.

Pennsylvania

Can ozone be used to control the spread of freshwater Aquatic Invasive Species?

The introduction of aquatic invasive species to non-native habitats can cause negative ecological effects and also billions of dollars in economic damage to governments and private industries. Once aquatic invasive species are introduced, eradication may be difficult without adversely affecting native species and habitats, urging resource managers to find preventative methods to protect non-invaded areas. The use of ozone (O 3 ) as a non-physical barrier has shown promise as it is lethal to a wide range of aquatic taxa, requires a short contact time, and is relatively environmentally safe in aquatic systems when compared to other chemicals. However, before O 3 can be considered as an approach to prevent the spread of aquatic invasive species, its effects on non-target organisms and already established aquatic invasive species must be fully evaluated. A review of the current literature was conducted to summarize data regarding the effects of O 3 on aquatic taxa including fish, macroinvertebrates, zooplankton, phytoplankton, microbes, and pathogens. In addition, we assessed the practicality of ozone applications to control the movement of aquatic invasive species, and identified data gaps concerning the use of O 3 as a non-physical barrier in field applications.

Management of Biological Invasions

Fracture patterns and their origin in the upper Devonian Antrim Shale gas reservoir of the Michigan basin: A review

INTRODUCTION: Black shale members of the Upper Devonian Antrim Shale are both the source and reservoir for a regional gas accumulation that presently extends across parts of six counties in the northern part of the Michigan basin (fig. 1). Natural fractures are considered by most petroleum geologists and oil and gas operators who work the Michigan basin to be a necessary condition for commercial gas production in the Antrim Shale. Fractures provide the conduits for free gas and associated water to flow to the borehole through the black shale which, otherwise, has a low matrix permeability. Moreover, the fractures assist in the release of gas adsorbed on mineral and(or) organic matter in the shale (Curtis, 1992). Depths to the gas-producing intervals (Norwood and Lachine Members) generally range from 1,200 to 1,800 ft (Oil and Gas Journal, 1994). Locally, wells that produce gas from the accumulation are as deep as 2,200 (Oil and Gas Journal, 1994). Even though natural fractures are an important control on Antrim Shale gas production, most wells require stimulation by hydraulic fracturing to attain commercial production rates (Kelly, 1992). In the U.S. Geological Survey's National Assessment of United States oil and gas, Dolton (1995) estimates that, at a mean value, 4.45 trillion cubic feet (TCF) of gas are recoverable as additions to already discovered quantities from the Antrim Shale in the productive area of the northern Michigan trend. Dolton (1995) also suggests that undiscovered Antrim Shale gas accumulations exist in other parts of the Michigan basin. The character, distribution, and origin of natural fractures in the Antrim Shale gas accumulation have been studied recently by academia and industry. The intent of these investigations is to: 1) predict 'sweet spots', prior to drilling, in the existing gas-producing trend, 2) improve production practices in the existing trend, 3) predict analogous fracture-controlled gas accumulations in other parts of the Michigan basin, and 4) improve estimates of the recoverable gas in the Antrim Shale gas plays (Dolton, 1995). This review of published literature on the characteristics of Antrim Shale fractures, their origin, and their controls on gas production will help to define objectives and goals in future U.S. Geological Survey studies of Antrim Shale gas resources.

Michigan

Seismology of the continental crust and upper mantle

More seismological studies of the continental crust and sub‐crustal lithosphere of the United States have been completed in the past four years than at any other similar period, and a continued growth in activity is likely to continue for years to come. Several trends account for this phenomenon. First, the interest in seismic reflection studies generated initially by COCORP results in this country [ Brown and others , 1986], and later by the British BIRPS results [ Matthews and Gheadie , 1986], has led to the development of several other seismic reflection programs. Among the most active of these research programs are those of the University of Wyoming [ Smithson and others , 1986], Virginia Polytechnic Institute, CALCRUST [ Henyey , 1986], and the U.S. Geological Survey (USGS) [ Hamilton , 1986]. In Canada, the Lithoprobe program has achieved remarkable results in a variety of geographic locations [ Green et al. , 1986]. A second trend is the resurgence of interest in seismic‐refraction/wide‐angle reflection profiling. The year 1978 marked the beginning of this increased activity when several large projects were conducted in the western U.S., such as the Yellowstone‐Snake River Plain experiment organized by the University of Utah. Since 1979, a large amount of refraction/wide‐angle reflection data has been collected by the USGS and by university groups utilizing large numbers of state‐of‐the‐art industry seismographs in cooperative experiments. A third trend is the increased sophistication of other seismic methods such as teleseismic delay‐time methods, tomography, and receiver‐transfer functions. In these studies, permanent or temporary recording arrays have been used to determine local and regional crustal and upper‐mantle structure with impressive resolution.

Reviews of Geophysics

Simulation of groundwater flow in a volatile organic compound-contaminated area near Bethpage, Nassau County, New York: A discussion of modeling considerations

The 2010 Bethpage groundwater-flow model (ARCADIS, 2010) was based on a steady state assumption. Although it is widely acknowledged that significant water-level changes have occurred in the past, the reviewed model does not represent changing water levels. The steady state approach limits the effectiveness of the following: 1. identification of sources of contamination, 2. analysis of model accuracy, 3. model calibration, and 4. simulations of future scenarios. Future plume movement was simulated in an incomplete manner through an unchanging groundwater-flow field. Available time-series information on temporal variation of factors affecting groundwater-flow dynamics includes: 1. public-supply pumping, 2. groundwater discharges from systems remediating volatile organic compound (VOC) plumes, 3. recharge and precipitation rates, and 4. water levels and streamflows. Transient phenomena that might be useful in future hypothetical simulations include pumping variations, redirection of containment-system waters for industrial use, and climate-change scenarios. Public-domain computer programs, U.S. Geological Survey guidance reports on transient-state calibration and uncertainty methods (Doherty and Hunt, 2010), and additional local and regional datasets are available to provide additional confidence in model evaluations and allow better evaluation of their limitations.

New York

Council monitoring and assessment program (CMAP): Common monitoring program attributes and methodologies for the Gulf of Mexico Region

Executive Summary Under the Resources and Ecosystem Sustainability, Tourist Opportunities, and Revived Economies of the Gulf Coast States Act of 2012 (RESTORE Act), the Gulf Coast Ecosystem Restoration Council (RESTORE Council or Council) is required to report on the progress of funded projects and programs. Systematic monitoring of restoration at the project-specific and programmatic-levels (i.e., watershed and Gulf of Mexico) enables consistent reporting and gives the public confidence that the restoration investments selected by the RESTORE Council will be evaluated and adaptively managed accordingly. Monitoring information that has been collected at different spatial and temporal scales can be used as the foundation to illustrate progress towards comprehensive ecosystem restoration goals and objectives that promote holistic Gulf of Mexico recovery (see ‘RESTORE Council Background’ at the beginning of this report for additional Council information). Federal, state and local agencies, universities, private industry, and non-governmental organizations (NGOs) have conducted and are conducting extensive monitoring activities around the Gulf of Mexico. In addition, each RESTORE Council-funded project will, at a minimum, perform project-specific monitoring. This collection of monitoring activities was inventoried and compiled into a framework of tools and resources by the Council-funded RESTORE Council Monitoring and Assessment Program (CMAP). CMAP was designed and funded to inventory and integrate existing water quality and habitat monitoring and mapping efforts to support discovery and accessibility of existing monitoring data and ensure the collected information is made available to support management decisions. Results of CMAP Inventory queries can be used to identify opportunities for efficiencies and support crossprogram review of performance across Gulf of Mexico ecosystem recovery efforts. The fundamental approach being used to inform the build out of the CMAP Gulf of Mexico water quality monitoring, habitat monitoring, and mapping framework includes: 1. Adopt, or construct as needed, a comprehensive inventory of existing habitat and water quality observation, monitoring, and mapping programs in the Gulf of Mexico (hereafter referred to as the “Inventory”; NOAA and USGS, 2019a); 2. Evaluate the suitability/applicability of each program and its existing and prospective data for use in restoration activities; 3. Develop a process to use the Inventory to conduct gap assessments; 4. Develop a catalog of baseline assessments conducted in the Gulf of Mexico (NOAA and USGS, 2019b); and 5. Develop a searchable monitoring information portal/database to enable access to collected information and products.

Alabama, Florida, Georgia, Louisiana, Mississippi,

Workshops report for mesophotic and deep benthic community fish, mobile invertebrates, sessile invertebrates and infauna

Two workshops with subject matter experts in the appropriate fields, were held in November and December 2021 to elicit guidance and feedback from the broader mesophotic and deep benthic scientific community. These workshops focused on best practices/approaches and identifying data gaps relative to habitat assessment and evaluation goals of the Mesophotic and Deep Benthic Community (MDBC) restoration portfolio. The first workshop was a combined effort of the Habitat Assessment and Evaluation (HAE) Project Team and the Deepwater Horizon (DWH) Program. Industrial Economics, Inc. (IEc) provided extensive workshop planning, organizing, execution, and facilitation support during all stages of the workshop. Based on a questionnaire sent to scientists in August, 2021, the workshop focused on fish and mobile invertebrate habitat associations, abundance trends, community metrics, and food web functionality. Topical presentations and discussions focused not only on demersal fish and mobile invertebrates that are directly associated with mesophotic and deep benthic habitats, but also considered water column species and communities that benefit from these habitats more broadly. The second workshop, intended to complement the first workshop, focused on identifying best practices and critical information gaps for key community metrics, larval dispersal modeling, connectivity, effects and variability of environmental parameters, and recovery trajectories of corals, infauna, and other sessile invertebrates. Through literature review, internal HAE scientists considered these topics to be critical for restoration success. Products from the literature review included topical summaries (see Appendix B) that summarized the current state-of-the-science and provided the framework for the workshop. Information generated from the workshops will assist the MDBC HAE Project, and more broadly the DWH Program, identify data gaps and develop a suite of best practices for restoration activities.

DWH MDBC Summary Report

The Global Flows of Metals and Minerals

This paper provides a preliminary review of the trends in worldwide metals and industrial minerals production and consumption based on newly developed global metals and minerals Material Flow Accounts (MFA). The MFA developed encompass data on extraction and consumption for 25 metal and mineral commodities, on a country-by-country and year-by-year basis, for the period 1970 to 2004. The data-base, jointly developed by the authors, resides with the U.S. Geological Survey (USGS) as individual commodity Excel workbooks and within a Filemaker data management system for use in analysis. Numerous national MFA have been developed to provide information on the industrial metabolism of individual countries. These MFA include material flows associated with the four commodity categories of goods that are inputs to a country's economy, agriculture, forestry, metals and minerals, and nonrenewable organic material. In some cases, the material flows associated with the creation and maintenance of the built infrastructure (such as houses, buildings, roads, airports, dams, and so forth) were also examined. The creation of global metals and industrial minerals flows is viewed as a first step in the creation of comprehensive global MFA documenting the historical and current flows of all of the four categories of physical goods that support world economies. Metals and minerals represent a major category of nonrenewable resources that humans extract from and return to the natural ecosystem. As human populations and economies have increased, metals and industrial minerals use has increased concomitantly. This dramatic growth in metals and minerals use has serious implications for both the availability of future resources and the health of the environment, which is affected by the outputs associated with their use. This paper provides an overview of a number of the trends observed by examining the database and suggests areas for future study.

Open-File Report

The assessment and remediation of mercury contaminated sites: A review of current approaches

Remediation of mercury (Hg) contaminated sites has long relied on traditional approaches, such as removal and containment/capping. Here we review contemporary practices in the assessment and remediation of industrial-scale Hg contaminated sites and discuss recent advances. Significant improvements have been made in site assessment, including the use of XRF to rapidly identify the spatial extent of contamination, Hg stable isotope fractionation to identify sources and transformation processes, and solid-phase characterization (XAFS) to evaluate Hg forms. The understanding of Hg bioavailability for methylation has been improved by methods such as sequential chemical extractions and porewater measurements, including the use of diffuse gradient in thin-film (DGT) samplers. These approaches have shown varying success in identifying bioavailable Hg fractions and further study and field applications are needed. The downstream accumulation of methylmercury (MeHg) in biota is a concern at many contaminated sites. Identifying the variables limiting/controlling MeHg production—such as bioavailable inorganic Hg, organic carbon, and/or terminal electron acceptors (e.g. sulfate, iron) is critical. Mercury can be released from contaminated sites to the air and water, both of which are influenced by meteorological and hydrological conditions. Mercury mobilized from contaminated sites is predominantly bound to particles, highly correlated with total sediment solids (TSS), and elevated during stormflow. Remediation techniques to address Hg contamination can include the removal or containment of Hg contaminated materials, the application of amendments to reduce mobility and bioavailability, landscape/waterbody manipulations to reduce MeHg production, and food web manipulations through stocking or extirpation to reduce MeHg accumulated in desired species. These approaches often rely on knowledge of the Hg forms/speciation at the site, and utilize physical, chemical, thermal and biological methods to achieve remediation goals. Overall, the complexity of Hg cycling allows many different opportunities to reduce/mitigate impacts, which creates flexibility in determining suitable and logistically feasible remedies.

Science of the Total Environment