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Geohydrology of the Cross-Florida Barge Canal area, with special reference to the Ocala vicinity

The Cross-Florida Barge Canal route commences at Palatka on the St. Johns River, about 75 miles upstream from the Atlantic Ocean, and extends 110 miles southwestward across Peninsular Florida into deep water in the Gulf of Mexico near Yankeetown. The canal will be equipped with five locks, each 600 feet long and 84 feet wide, and the channel will be a minimum of 12 feet deep and 150 feet wide. From near Ocala northeastward, the canal channel will replace much of the natural channel of the Oklawaha River, and will be excavated into beds of the so-called shallow sand aquifer of Miocene age and younger, which overlies limestone of the Floridan aquifer. Westward from Ocala, most of the canal will be excavated below the potentiometric surface into limestone and dolomite of the Floridan aquifer. Water levels of Rodman, Eureka, and Inglis Pools will be controlled by dams and spillways with the limited exchange of water between the pools and the aquifers. The water levels in the Summit Pools will fluctuate with the natural changes in the ground-water level of the Floridan aquifer, although the stage of the pool will be controlled partly by the stage held in the Eureka Pool. A dynamic inflow-outflow relationship will exist between the Summit Pool and the Floridan aquifer. The Floridan aquifer in the canal area is 1,000 to 1,200 feet thick and consists of limestone and dolomite of middle Eocene Miocene age, including from older to younger, the Lake City, Avon Park, and Ocala limestones plus permeable sandy, dolomitic limestone in the lower part of the Hawthorn Formation. It is possible that most of the flow to the two major springs in the area occurs in the upper 100 feet or so of the aquifer in the Ocala Limestone. The aquifer is underlain by the Oldsmar limestone of early Eocene age and is overlain by sand, clayey sand, clay and shell beds of Miocene through Holocene age, in thickness from a few feet to 300 feet. The permeable beds overlying the Floridan aquifer constitute the shallow aquifer, while the poorly permeable ones act as confining beds where the Floridan aquifer is under artesian conditions. A north-south line drawn separating the head of Silver Springs on the west from the Oklawaha River on the east marks the approximate western limit of a continuous blanket of materials of Miocene-Pliocene(?) age covering the rocks of the Floridan aquifer. East of the line, much of the aquifer is under artesian conditions, particularly in the Oklawaha River valley, although in some areas east of the valley, direct recharge through thick permeable Miocene-Pliocene(?) sands occurs. West of the line, only scattered remnants of a once continuous Miocene-Pliocene(?) cover remain. Lack of the cover is a result of erosion on the crest and flank of the Ocala Uplift, a broad northwest-southeast trending anticlinal upwarp, the axis of which is crossed by the canal route in the Dunnellon area. Over most of this area the Floridan aquifer is unconfined and receives direct recharge through a cover of a few tens of feet of sand and clayey sand of Quaternary age. Tensional stresses during the structural evolution of the Ocala Uplift produced an intersecting system of fractures and normal faults in rocks of the Floridan aquifer. The fractures and faults are important controls for orientation of solution channels and, therefore, for development of ground-water circulation patterns. When the system surface streams, which once drained the Barge Canal area, eroded the poorly permeable Miocene-Pliocene(?) cover from the flanks of the Ocala Uplift, surface runoff was reduced and precipitation began to directly infiltrate the underlying limestones. Now only principal streams remain, such as the Oklawaha and Withlacoochee Rivers and a few short tributaries, while one of the most highly developed subsurface drainage systems in the world has evolved in cavernous limestone of the Floridan aquifer. Two of the larger freshwater springs in the world now discharge from the Floridan aquifer in the canal area. Silver Springs near Ocala discharges an average 531 mgd (million gallons per day) down the 4-mile long Silver River, which flows on poorly permeable beds to the Oklawaha River. Rainbow Springs near Dunnellon discharges on average 468 mgd from numerous orifices in the bed of the 5-mile-long Rainbow River, which flows into the Withlacoochee River. The heads of the springs have migrated to their present positions partly because of a tendency of ground-water levels to decline as permeability in the aquifer is increased due to removal of limestone by solution, and because of mechanical erosion of the limestone in the vicinity of the spring heads. Also, points of principal spring discharges have shifted in the past due to changes in ground-water levels in response to changes in sea level. The subsurface drainage system is continuing to evolve today, as evidenced in part by frequent occurrence of new sinkholes and by the presence of significant amounts of calcium bicarbonate in the spring waters. Rodman Pool, at the east end of the canal, is separated from the Floridan aquifer by poorly permeable materials. The pool's operating water level will be only a few feet above the potentiometric surface at the downstream end, and at or slightly below the potentiometric surface at the upstream end. Little exchange of water between the Rodman Pool and the Floridan aquifer is expected. Eureka Pool, just upstream from Rodman Pool, will also be separated from the Floridan aquifer by poorly permeable beds. However, the stage of the pool will be about 15 feet higher than the natural potentiometric surface at the pool's downstream end, and some seepage into the Floridan aquifer is anticipated through faults and leaky parts of the poorly permeable beds, with a consequent rise in ground-water levels in areas adjacent to the lower end of the pool. Possibilities for particulate contamination of the aquifer will tend to be minimized because of the filtering capacity of the materials through which water must pass to reach the aquifer, although the natural filter will not preclude movement into the aquifer of contaminants which might become dissolved in the pool waters. No significant interchange of water between the pool and the aquifer is expected at the upstream end of the Eureka Pool. Present construction plans indicate an operating stage for Eureka Pool which will range between 38 and 40 feet above mean sea level, although it is possible to dredge the pool deep enough to permit a range in stage of 36 to 40 feet. A backwater effect extending up Silver River from the Eureka Pool is expected to regulate the stage at the head of Silver Springs between 39 and 44 feet above mean sea level if the pool ranges between 36 and 40 feet. If Eureka Pool ranges only between 38 and 40 feet, the range of stage at the head of the springs should be about 41 to 44 feet above mean sea level. From Inglis Lock west, the canal will have direct connection with the Gulf, and canal stage will fluctuate with the Gulf tide. Since the canal stage will be slightly lower than the adjacent ground-water levels along much of the reach, there will be some ground-water inflow to the canal. No significant changes in the existing ground-water regime are expected in the vicinity of Inglis Pool, the first step up in the canal east of the Gulf. Existing ground-water and surface-water levels in the area will not change appreciable, and the natural stage and flow of Rainbow Springs, which will flow by way of Rainbow River into Inglis Pool, should not be affected by canal operations. A possible adverse effect of the canal on the Inglis Pool area could result if sea water is locked up from the Gulf through Inglis Lock. However, the high step of 25 feet at the lock, flushing action of continuous flow from Inglis Pool to the lower reaches of the Withlacoochee River, and use of possible preventive locking procedures should minimize the problem. The potential for adverse effects on the ground-water regime is greatest in the area of the Summit Pool. Through most of the length of the pool, the canal channel will be excavated into limestone of the Floridan aquifer to depths of 12 to 27 feet below the potentiometric surface. Changes that will take place in the ground-water flow system in the Silver Springs drainage area, once the canal is completed, were estimated by flow-net analysis. Variation in aquifer transmissivity was determined by calculating transmissivity in 25 different flow cells surrounding Silver Springs. Transmissivity in the 25 cells averages about 15,600,000 gpd/ft [2,090,000 ft2/day (feet squared)], but transmissivity in the six cells through which the Summit Pool passes ranges from 9,000,000 to 44,000,000 gpd/ft (1,210,000 to 5,900,000 ft2/day). Transmissivity was used to compute static stage of the Summit Pool under given ground-water level conditions. Had the canal existed in May 1968 and had the stage of Eureka Pool been held at 36 feet at the time, the static stage in Summit Pool would have been about 42.1 feet above mean sea level. Thus, a conceptual model of the changes in the potentiometric surface wrought by the finished canal was drawn, and zones of ground-water inflow and outflow were delineated. Most outflow from the Summit Pool to the aquifer should be limited to one 4-mile-long zone along the north side of the pool, about 5 miles south of Silver Springs. It is estimated that a water volume equivalent to about 8 percent of the daily flow of Silver Springs will enter the Summit Pool each day from the southern one-third of the Silver Springs drainage area. A like amount will reenter the aquifer at the main zone of outflow and move toward Silver Springs at an estimated average velocity of about 200 feet per day, if something close to the natural static stage of the pool is maintained by return pumpage of the lockage losses. At a velocity of 200 feet per day, water from the Summit Pool would discharge at Silver Springs about 140 days later. However, any estimate of velocity in the highly cavernous limestone aquifer in the area should be used with caution, because difficult to measure changes in porosity and thickness of major zones of flow may cause large variations in velocity. If all lockage losses are returned to the Summit Pool by pumping from Eureka Pool, no net loss from the Silver Springs drainage area, except for some evaporation from the water surface in the canal and possible leakage around locks, will result from canal operations. The zone of outflow from the Summit Pool to the aquifer will be in a natural potentiometric trough, and the zone of inflow will be in a potentiometric ridge area. The equilibrium water level in the pool will tend to be about 1 foot higher than the altitude of the lowest level in the pre-canal potentiometric trough, and about 2 feet lower than the highest level on the pre-canal potentiometric ridge. West of the Silver Springs drainage area just east of Dunnellon Lock, in the area of a local potentiometric high, the water level in the Summit Pool is expected to be about 15 feet below the natural potentiometric surface. In most areas 2 to 3 miles away from the Summit Pool, effects of the canal on the natural potentiometric surface should be slight. The stage of the Summit Pool, judging from the 36-year record for ground-water level changes and the anticipated indirect effect of the controlled stage in Eureka Pool, should have a maximum of about 10.5 feet with a maximum water level of about 51.5 feet above mean sea level and a minimum of about 41.0 feet above mean sea level. Of particular importance in the Summit Pool is an implementation of well planned construction and operational procedures designed to minimize risks of ground-water contamination.

Florida↗

Base flow and ground water in upper Sweetwater Valley, Tennessee

The upper Sweetwater Valley area has a flow system with complex interaction between surface and ground water. A water budget study indicated that during dry years approximately three-fourths of the annual flow to Sweetwater Creek may be derived from ground-water sources. Hydrograph analysis showed seasonal variation of recharge to the ground-water flow system. Streamflow records were analyzed to estimate the frequency of low flow of Sweetwater Creek at river mile 16.7, and indicated the lowest average flow for 1 day in 20 years to be about 5.1 cubic feet per second. Two periods of base-flow measurements of Sweetwater Creek identified channel reaches with significant gains and losses of streamflow. Base flow measurements also showed interbasin transfer of water among sub-basins of the valley. Major flow surpluses were associated with areas in which the majority of flow originated at a spring. Topographically low areas adjacent to the main stem of Sweetwater Creek generally have surplus flow. Topographically higher areas generally have deficient surface outflow unless significant spring flow occurs in the basin. Ground-water recharge occurs by water draining into sinkholes, faults, and fractures. Ground-water flow is regionally diffused across formation strikes from the topographically low areas unless the water is exposed to highly permeable formations or impervious formations. Ground water infiltrates the highly permeable formations and flows along strike. Ground water encountering impervious formations may discharge at small springs at the contact, or may reroute along the contact if the upgradient rock is sufficiently permeable or has well developed secondary porosity. Groundwater discharges to streams at innumerable seeps and at a few large springs. Areas of ground-water flow up-gradient of large springs are hypothesized as likely areas of significant ground-water reservoirs.

Tennessee↗

Geology of an area near Brentwood, Williamson County, Tennessee

The lithology and geologic structure of an area near Brentwood, Williamson County, Tennessee, were studied to define the potential aquifers and confining units of the ground-water flow system. Four formations were identified. They are, in descending order, the Bigby-Cannon Limestone, the Hermitage Formation, the Carters Limestone, and the Lebanon Limestone. The Bigby-Cannon Limestone and the Carters Limestone are potential aquifers. The Hermitage Formation and the Lebanon Limestone are confining units. The Bigby-Cannon Limestone and the Hermitage Formation have been affected by recent erosion. Any variation of the Carters Limestone is controlled by pre-Carters erosion of the top of the Lebanon Limestone. The thickness of the Carters Limestone ranges from 65 to 79 feet. Structurally, the area reflects the regional northwest dip. A small scale anti-cline-syncline pair also is evident. This feature is not a result of erosion and also occurs in the T-3 bentonite bed in the Carters Limestone.

Tennessee↗

An investigation of shallow ground-water quality near East Fork Poplar Creek, Oak Ridge, Tennessee

Alluvial soils and fill materials in and near the floodplain of East Fork Poplar Creek in Oak Ridge, Tennessee, are contaminated with various trace metals (primarily mercury), organic compounds, and radionuclides that were lost to the stream as a result of past operations at the Y-12 Plant, a nuclear-processing facility located within the U.S. Department of Energy’s Oak Ridge Reservation. Observation wells were installed in the shallow (above bedrock) aquifer in and near the floodplain of East Fork Poplar Creek and water-quality samples were collected to determine if contaminants found in the soils and fill are also present in the shallow ground water. The shallow aquifer in the East Fork Poplar Creek flood plain consists primarily of alluvial silt and clay with lesser amounts of sand and gravel. Thickness of the shallow aquifer ranges from essentially zero to as much as 20 feet. A silty-clay glei horizon is present between the base of the alluvium and the top of bedrock at most flood-plain locations and, where present, likely impedes downward ground-water movement. Water in the shallow aquifer near East Fork Poplar Creek occurs under water-table conditions. Recharge to the shallow aquifer is principally from precipitation, and discharge is through springs and seeps to East Fork Poplar Creek and its tributaries. During spring, summer; and fall, evapotranspiration also accounts for the removal of water in storage in the shallow aquifer. Water levels in the shallow aquifer fluctuate seasonally in response to variations in recharge and evapotranspiration. Generally, the depth to water in the observation wells ranged from about 1 to 4 feet below land surface in late winter, and from about 2 to 7 feet below land surface in late fall. During extremely dry periods, the water table recedes below the top of bedrock in some flood-plain areas, possibly causing East Fork Poplar Creek to lose water to the shallow aquifer along some reaches. Contaminants found in water samples collected from several of the observation wells in concentrations (total and (or) total-recoverable) which equaled or exceeded drinking-water standards established by the U.S. Environmental Protection Agency are antimony, chromium, lead, mercury, selenium, total phenols, and strontium-90. Total and dissolved uranium concentrations exceeded 1.0 microgram per liter in samples from nearly 70 percent of the wells in the East Fork Poplar Creek flood plain. Organic compounds that were identified in low concentrations in samples from a few wells in the flood plain are: Arochlor 1260, benzo(a)anthracene, benzo(b)fluoranthene, chrysene, 3,3-dichlorobenzidine, di-n-butylphthalate, N-nitrosodiphenylamine, and pyrene. Water from one well in the East Fork Poplar Creek flood plain at a contaminated fill site contained 37and 8 micrograms per liter of trichloroethene and trans-1,2-dichloroethene, respectively. Comparison of the results of total and (or) total-recoverable trace-metal determinations with those from dissolved determinations demonstrates that elevated concentrations of these substances in water collected from several of the wells in the East Fork Poplar Creek flood plain resulted from sorption of trace metals (and possibly organic compounds and radionuclides) by fine sediment suspended in the samples. The occurrence of contaminated sediment in these samples is suspected to be the result of borehole contamination during well installation.

Tennessee↗

Effects of storm-water runoff on local ground-water quality, Clarksville, Tennessee

Storm-related water-quality data were collected at a drainage-well site and at a spring site in Clarksville, Tennessee, to define the effects of storm-water runoff on the quality of ground water in the area. A dye-trace test verified the direct hydraulic connection between the drainage well and Mobley Spring. Samples of storm run off and spring flow were collected at these sites for nine storms during the period February to October 1988. Water samples were collected also from Mobley Spring and two other springs and two observation wells in the area during dry-weather conditions to assess the general quality of ground water in an urban karst terrain. Evaluation of the effect of storm-water runoff on the quality of local ground water is complicated by the presence of other sources of contaminants in the area Concentrations and load for most major constituents were much smaller in storm-water runoff at the drainage well than in the discharge of Mobley Spring, indicating that much of the chemical constituent load discharged from the spring comes from sources other than the drainage well. However, for some of the minor constituents associated with roadway runoff (arsenic, copper, lead, organic carbon, and oil and grease), the drainage well contributed relatively large amounts of these constituents to local ground water during storms. The close correlation between concentrations of total organic carbon and concentrations of most trace metals at the drainage-well and Mobley Spring sites indicates that these constituents are transported together. Many trace metals were flushed early during each runoff event. Mean storm loads for copper, lead, zinc, and four nutrient species (total nitrogen, ammonia nitrogen, total phosphorus, and orthophosphorus) in storm-water runoff at the drainage-well site were lower than mean storm load predicted from an existing regression model. The overprediction by the model may be a result of the small size of the drainage area relative to the range of drainage areas used in the development of the models, or to the below-normal amounts of rainfall during the period of sampling for this investigation. Loads& in storm-water runoff for 22 constituents were extrapolated from sampled storms to total loads for the period February to October 1988. Calculated loads for trace metals for the period ranged from 0.030pound.s for cadmium to 12pound.s for strontium. Loads of the primary nutrients ranged from 0.97pounds for nitrite as nitrogen to 34pounds of organic nitrogen. Storm-water quality at the drainage-well and Mobley Spring sites was compared to background water quality of the local aquifer; as characterized by dry-weather samples from three springs and two observation wells in the Clarksville area. Concentrations of total-recoverable cadmium, chromium, copper, lead, and nickel were higher in many stormwater samples from both the drainage-well and Mobley Spring sites than in samples from any other site. In addition, concentrations of total organic carbon, methylene blue active substances, and total-recoverable oil and grease were generally higher in storm-water samples from the drainage-well site than in any ground-water sample. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total recoverable iron, manganese, and methylene blue active substances in storm samples from the drainage-well site exceeded the maximum contaminant levels listed in Tennessee’s drinking-water standards (1988) by as much as 2,500 and 5,500 colonies per 100 milliliters, and 2.7, 0.29, and 0.05 milligrams per liter, respectively. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total-recoverable iron, manganese, and lead in storm samples from Mobley Spring exceeded the maximum contaminant levels by as much as 500 and 4,500 colonies per 100 milliliters, and 18.7,0.65, and 0.02 milligrams per liter, respectively. For iron, manganese, and bacteria, these undesirable levels are not necessarily attributable to storm-water recharge, because concentrations of these constituents also exceeded drinking-water standards in one or more of the dry-weather samples from selected springs and observation wells in the area.

Tennessee↗

Effects of septic-tank effluent on ground-water quality in northern Williamson County and southern Davidson County, Tennessee

An investigation of the potential contamination of ground water from septic tank systems blasted in bedrock in Williamson and Davidson Counties, Tennessee, was conducted during 1988-89. Water samples were collected from domestic and observation wells, springs, and surface-water sites in a residential subdivision in the northern part of Williamson County near Nashville. The subdivision has a high density of septic-tank field lines installed into blasted bedrock Water samples also were collected from a well located in an area of Davidson County where field lines were installed in 5 feet of soil. Samples were analyzed for major inorganic constituents, nutrients, total organic carbon, optical brighteners, and bacteria. Although results of analyses of water samples from wells indicate no effect of septic-tank effluent on ground-water quality at these sites, water from two springs located downgradient from the subdivision had slightly larger concentrations of nitrite plus nitrate (2.2 and 2.7 milligrams per liter N), and much larger concentrations of fecal coliform and fecal streptococci bacteria (2,000 to 3,200 and 700 to 900 colonies per 100 milliliters of sample, respectively), than other wells and springs sampled during 1988. Water from one of these springs contained optical brighteners, which indicates that septic-tank effluent is affecting ground-water quality.

Tennessee↗

Geochemistry of and radioactivity in ground water of the Highland Rim and Central Basin aquifer systems, Hickman and Maury counties, Tennessee

A reconnaissance of the geochemistry of and radioactivity in ground water from the Highland Rim and Central Basin aquifer systems in Hickman and Maury Counties, Tennessee, was conducted in 1989. Water in both aquifer systems typically is of the calcium or calcium magnesium bicarbonate type, but concentrations of calcium, magnesium, sodium, potassium, chloride, and sulfate are greater in water of the Central Basin system; differences in the concentrations are statistically significant. Dissolution of calcite, magnesium-calcite, dolomite, and gypsum are the primary geochemical processes controlling ground-water chemistry in both aquifer systems. Saturation-state calculations using the computer code WATEQF indicated that ground water from the Central Basin system is more saturated with respect to calcite, dolomite, and gypsum than water from the Highland Rim system. Geochemical environments within each aquifer system are somewhat different with respect to dissolution of magnesium-bearing minerals. Water samples from the Highland Rim system had a fairly constant calcium to magnesium molar ratio, implying congruent dissolution of magnesium-bearing minerals, whereas water samples from the Central Basin system had highly variable ratios, implying either incongruent dissolution or heterogeneity in soluble constituents of the aquifer matrix. Concentrations of radionuclides in water were low and not greatly different between aquifer systems. Median gross alpha activities were 0.54 picocuries per liter in water from each system; median gross beta activities were 1.1 and 2.3 picocuries per liter in water from the Highland Rim and Central Basin systems, respectively. Radon-222 concentrations were 559 and 422 picocuries per liter, respectively. Concentrations of gross alpha and radium in all samples were substantially less than Tennessee’s maximum permissible levels for community water-supply systems. The data indicated no relations between concentrations of dissolved radionuclides (uranium, radium-226, radium-228, radon-222, gross alpha, and gross beta) and any key indicators of water chemistry, except in water from the Highland Rim system, in which radon-222 was moderately related to pH and weakly related to dissolved magnesium. The only relation among radiochemical constituents indicated by the data was between radium-226 and gross alpha activity; this relation was indicated for water from both aquifer systems.

Tennessee↗

Ground-water quality near an inactive landfill and sludge-spreading area, Tallahassee, Florida

Ground-water quality of a 120-acre area encompassing an inactive landfill southwest of Tallahassee, Florida, was assessed by installing and sampling 21 monitoring wells. Sludge from a municipal sewage-treatment plant was also applied to the land surface near the landfill site. Water samples were collected from the 21 monitoring wells from June 1987 through September 1990 and analyzed for concentrations of major ions, nitrogen species, trace metals, field measurements, and more than 140 organic constituents. Water quality in the Upper Floridan aquifer at the study site was compared to background water quality in other areas of Leon County. Ground-water quality of the study site was evaluated by the location of wells sampled in relation to the landfill and the sludge-spreading areas. Results of nonparametric statistical analysis indicated that potassium and nitrite plus nitrate as nitrogen concentrations in water samples from wells completed in the Upper Floridan aquifer at the study site were significantly different at the 5 percent probability level from those in samples from background wells completed in this aquifer in Leon County. Median potassium concentrations were 0.4 mg/L (milligrams per liter) in water from wells at the study site and 0.7 mg/L in water from background wells in Leon County. Median nitrite plus nitrate concentrations were 6.48 mg/L in water samples from wells at the study site and 0.51 mg/L in water samples from background wells. Graphical comparison of the water quality characteristics in water from six categories of wells; upgradient, landfill, adjacent to the landfill, downgradient onsite, downgradient offsite, and background Leon County, indicated that sodium, bicarbonate, sulfate, iron, manganese, and dissolved solids concentrations and specific conductance values were highest within the landfill. Upgradient and downgradient well categories include wells in areas affected by sludge spreading. Localized reducing conditions were indicated in a downgradient area by median iron concentrations of 930 and 30 ug/L (micrograms per liter) in samples from wells only 5 feet apart. Nitrite plus nitrate concentrations were lowest in water from wells in the landfill compared to water from the other categories. Concentrations of most trace elements and organic compounds were mostly below detection limits, although State maximum contaminant levels of 1 ug/L for benzene and vinyl chloride and 3 ug/L for tetrachloroethene were exceeded in 14 samples. Concentrations of sodium, potassium, chloride, sulfate, nitrite plus nitrate, total organic and ammonia nitrogen, and ammonia nitrogen in ground water were statistically analyzed in areas affected by sludge-spreading and other areas. Only nitrite plus nitrate and chloride concentrations were significantly different between the two areas. Median nitrite plus nitrate and chloride concentrations in sludge-spreading areas were 6.9 mg/L and 2.9 mg/L, respectively, compared to 1.1 mg/L and 1.8 mg/L in other areas.

Florida↗

Water quality of the Boca Raton canal system and effects of the Hillsboro Canal inflow, southeastern Florida, 1990-91

The City of Boca Raton in southeastern Palm Beach County, Florida, is an urban residential area that has sustained a constant population growth with subsequent increase in water use. The Boca Raton network of canals is controlled to provide for drainage of excess water, to maintain proper coastal ground-water levels to prevent saltwater intrusion, and to recharge the surficial aquifer system from which the city withdraws potable water. Most of the water supplied to the Boca Raton canal system and the surficial aquifer system, other than rainfall and runoff, is pumped from the Hillsboro Canal. The Biscayne aquifer, principal hydrogeologic unit of the surficial aquifer system, is highly permeable and there is a close relation between water levels in the canals and the aquifer. The amount of water supplied by seepage from the conservation areas is unknown. Because the Hillsboro Canal flows from Lake Okeechobee and Water Conservation Areas 1 and 2, which are places of more highly mineralized ground water and surface water, the canal is a possible source of contamination. Water samples were collected at 10 canal sites during wet and dry seasons and analyzed for major inorganic ions and related characteristics, nutrients, and trace elements. All concentrations were generally within or less than the drinking-water standards established by the Florida Department of Environmental Protection. The high concentrations of sodium and chloride that were detected in samples from the Boca Raton canal system are probably from the more mineralized water of the Hillsboro Canal. Other water-quality data, gathered from various sources from 1982 through 1991, did not indicate any significant changes nor trends. The data include pesticide and metal analyses of water samples and bottom sediments collected at four canal sites in the Boca Raton study area by the U.S. Geological Survey during 1982-84. The effects of the Hillsboro Canal on the water quality of the Boca Raton canal system are indicated by increased concentrations of sodium, chloride, dissolved solids, and total organic carbon. Concentrations of the constituents in the canal water generally decrease with distance from the Hillsboro Canal pumping station and are the result of dilution by receiving canal waters.

Florida↗

Evaluation of ground-water flow and hydrologic budget for Lake Five-O, a seepage lake in northwestern Florida

Temporal and spatial distributions of ground-water inflow to, and leakage from Lake Five-O, a softwater, seepage lake in northwestern Florida, were evaluated using hydrologic data and simulation models of the shallow ground-water system adjacent to the lake. The simulation models indicate that ground-water inflow to the lake and leakage from the lake to the ground-water system are the dominant components in the total inflow (precipitation plus ground-water inflow) and total outflow (evaporation plus leakage) budgets of Lake Five-O. Simlulated ground-water inflow and leakage were approximately 4 and 5 times larger than precipitation inputs and evaporative losses, respectively, during calendar years 1989-90. Exchanges of water between Lake Five-O and the ground-water system were consistently larger than atmospheric-lake exchanges. A consistent pattern of shallow ground-water inflow and deep leakage was also evident throughout the study period. The mean time of travel from ground-water that discharges at Lake Five-O (time from recharge at the water table to discharge at the lake) was estimated to be within a range of 3 to 6 years. Flow-path evaluations indicated that the intermediate confining unit probably has a negligible influence on the geochemistry of ground-water inflow to Lake Five-O. The hydrologic budgets and flow-path evaluations provide critical information for developing geochemical budgets for Lake Five-O and for improving the understanding of the relative importance of various processes that regulate the acid-neutralizing capacity of softwater seepage lakes in Florida.

Florida↗

The distribution of bromide in water in the Floridan aquifer system, Duval County, northeastern Florida

Although Duval County, Florida, has ample ground-water resources for public supply, the potential exists for a problem with excessive disinfectant by-products. These disinfectant by-products result from the treatment of raw water containing low concentrations of bromide and naturally occurring organic compounds. Because of this potential problem, the relation of bromide concentrations to aquifer tapped, well location and depth, and chemical characteristics of water in the Floridan aquifer system underlying Duval County were studied to determine if these relations could be applied to delineate water with low-bromide concentrations for future supplies. In 1992, water samples from 106 wells that tap the Floridan aquifer system were analyzed for bromide and major dissolved constituents. A comparison of bromide concentrations from the 1992 sampling with data from earlier studies (1979-80) indicates that higher bromide concentrations were detected during the earlier studies. The difference between the old and new data is probably because of a change in analytical methodology in the analysis of samples. Bromide concentrations exceeded the detection limit (0.10 milligrams per liter) in water from 28 of the 106 wells (26 percent) sampled in 1992. The maximum concentration was 0.56 milligrams per liter. There were no relations between bromide and major dissolved constituents, well depth, or aquifer tapped that would be useful for determining bromide concentrations. Areal patterns of bromide occurrence are not clearly defined, but areas with relatively high bromide concentrations tend to be located in a triangular area near the community of Sunbeam, Florida, and along the St. Johns River throughout Duval County.

Florida↗

Water-quality assessment of the Ozark Plateaus study unit, Arkansas, Kansas, Missouri, and Oklahoma: Analysis of information on nutrients, suspended sediment, and suspended solids, 1970-92

Water-quality data collected during water years 1970-90 (October 1 to September 30) for 83 surface-water sites and during 1970-92 for 395 ground-water sites in the 48,000 square mile Ozark Plateaus study unit of the National Water Quality Assessment Program were analyzed using selected descriptive and statistical methods. The water- quality data include nutrient (nitrogen and phosphorus), suspended sediment, and suspended- solids data, and ancillary information such as fertilizer use, animal waste, sewage treatment plant, and land use. Statistically significant differences exist in surface-water quality that can be attributed to physiography, land use, and other effects. The sites that were considered to be substantially affected by sewage treatment plants had the largest concentrations of nutrients. Nutrient concentrations generally were larger at sites associated with agricultural basins than at sites associated with forested basins. Statistically significant differences existed in the quality of ground water that can be attributed to hydrogeologic and land-use effects. Nutrient concentrations generally were largest where the water source is indicated to be shallow in origin and where parts of the hydrogeologic units are in agricultural land-use areas. Water quality has changed at several surface-water sites since 1970. Nutrient concentrations appear to have increased at some sites and decreased at other sites. Causes of these apparent trends are not known, but many of the sites with apparent trends are in agricultural areas. Surface-water loads of nutrients and suspended sediment were affected by several factors including streamflow, climate, drainage area, reservoir operation, and inputs from point and nonpoint sources. Annual loads were largest in large basins, with large inputs of nutrients or sediment during periods of high streamflows at locations where reservoir operation effects are not substantial.

Arkansas, Kansas, Missouri, Oklahoma↗

Effects of waste-disposal practices on ground-water quality at five poultry (broiler) farms in north-central Florida, 1992-93

Waste-disposal areas such as chicken-house floors, litter stockpiles, fields that receive applications of litter, and dead-chicken pits are potential sources of nitrates and other chemical constituents in downward-percolating recharge water. Broiler- farms in north-central Florida are concentrated in a region where the Upper Floridan aquifer is unconfined and susceptible to contamination. Eighteen monitoring wells installed at five sites were sampled quarterly from March 1992 through January 1993. Increases in median concentrations of constituents relative to an upgradient well were used to determine the source of the nitrate at two sites. At these sites, increases in the median concentrations of nitrate as nitrogen in ground water in the vicinity of waste-disposal areas at these sites were: 5.4 mg/L for one chicken house; 9.0 mg/L for a second chicken house; 2.0 mg/L for a fallow field that received an application of litter; and, 2.0 mg/L for a dead-chicken pit. At the three remaining sites where the direction of local ground-water flow could not be ascertained, the sources of concentrations of nitrate and other constituents could not be determined. However, median nitrate concentrations in the vicinity of waste-disposal areas at these sites were: 45.5 mg/L for a set of two chicken houses; 3.0 mg/L for a stockpile area; and 2.1 mg/L for a hayfield that received an application of litter. The nitrate concentration in ground water in the vicinity of a field that had previously received heavy applications of litter increased from 3.0 mg/L to 105 mg/L approximately 4 months after receiving an application of commercial fertilizer. Increases in concentrations of organic nitrogen in ground water in the vicinity of waste-disposal areas may be related to the decomposition of litter and subsequent movement with downward percolating recharge water.

Florida↗

Streamflow, ground-water recharge and discharge, and characteristics of surficial deposits in Buzzards Bay Basin, southeastern Massachusetts

Streamflow measurements at 14 low-flow partial-record stations and two discontinued streamflow-gaging stations were related to concurrent streamflows at six long-term streamflow-gaging stations to estimate streamflows at selected flow durations from 50 to 99 percent for water years 1967-91. At low flows, stream discharge per square mile generally increased with increasing percentage of subbasin underlain by stratified-drift deposits. At the 70-, 90-, and 99-percent flow durations, subbasins underlain primarily by stratified-drift deposits had stream discharges per square mile at least 2, 4, and 8 times greater, respectively, than subbasins underlain primarily by till and bedrock deposits. Streamflow measured three times at the Paskamanset River showed that streamflows downstream of municipal pumped wells increased at a lower rate per unit drainage area than streamflows upstream of the pumped wells. When pumpage from wells near the river was added to measured streamflow at the most downstream station, the sum was similar to the potential streamflow at the station if its streamflow per unit area was the same as that upstream from the pumped wells. Mean ground-water recharge and discharge rates were computed from continuous records of daily mean discharge during water years 1967-91 for six streamflow-gaging stations in southeastern Massachusetts and Rhode Island. Estimates of mean ground-water recharge were 19.7 to 22.6 inches per year for stations with drainage areas primarily underlain by till and bedrock deposits, and 23.8 to 25.2 inches per year for stations with drainage areas primarily underlain by stratified-drift deposits. During drought years, annual ground-water recharge can be less than 50 percent of the mean ground-water recharge rate for water years 1967-91. Estimates of ground-water discharge rates generally were 1 to 4 inches per year less than estimates of ground-water recharge rates. Ground-water discharge-duration curves were calculated from hydrograph separation of streamflow records at the six continuous streamflow-gaging stations for water years 1967-91. When streamflows were less than the median streamflow (50-percent duration), ground-water discharges averaged 85.7 percent of the total streamflow at the six streamflow-gaging stations. Ground-water discharges were estimated at the 14 low-flow partial-record stations and two discontinued streamflow-gaging stations by multiplying streamflows at the selected flow durations from 50 to 99 percent for water years 1967-91 by 85.7 percent. Data on surficial deposits in the basin were obtained by drilling 10 wells, by conducting 12 seismic-refraction surveys, and by collecting well log data for 313 wells from consulting firms and the Massachusetts Department of Environmental Management. These data indicated that a few minor corrections could be made to existing saturated thickness maps for stratified-drift deposits in Buzzards Bay Basin. Few well logs were detailed enough to estimate transmissivities; thus existing transmissivity maps were not updated for stratified-drift deposits in the basin.

Massachusetts↗

Hydrogeologic investigation and simulation of ground-water flow in the Upper Floridan Aquifer of north-central Florida and southwestern Georgia and delineation of contributing areas for selected city of Tallahassee, Florida, water-supply wells

A 4-year investigation of the Upper Floridan aquifer and ground-water flow system in Leon County, Florida, and surrounding counties of north-central Florida and southwestern Georgia began in 1990. The purpose of the investigation was to describe the ground-water flow system and to delineate the contributing areas to selected City of Tallahassee, Florida, water-supply wells. The investigation was prompted by the detection of low levels of tetrachloroethylene in ground-water samples collected from several of the city's water-supply wells. Hydrologic data and previous studies indicate that; ground-water flow within the Upper Floridan aquifer can be considered steady-state; the Upper Floridan aquifer is a single water-bearing unit; recharge is from precipitation; and that discharge occurs as spring flow, leakage to rivers, leakage to the Gulf of Mexico, and pumpage. Measured transmissivities of the aquifer ranged from 1,300 ft 2 /d (feet squared per day) to 1,300,000 ft2/d. Steady-state ground-water flow in the Upper Floridan aquifer was simulated using a three-dimensional ground- water flow model. Transmissivities ranging from less than 5,000 ft2/d to greater than 11,000,000 ft 2 /d were required to calibrate to observed conditions. Recharge rates used in the model ranged from 18.0 inches per year in areas where the aquifer was unconfined to less than 2 inches per year in broad areas where the aquifer was confined. Contributing areas to five Tallahassee water-supply wells were simulated by particle- tracking techniques. Particles were seeded in model cells containing pumping wells then tracked backwards in time toward recharge areas. The contributing area for each well was simulated twice, once assuming a porosity of 25 percent and once assuming a porosity of 5 percent. A porosity of 25 percent is considered a reasonable average value for the Upper Floridan aquifer; the 5 percent porosity simulated the movement of ground-water through only solution-enhanced bedding plains and fractures. The contributing areas were generally elliptical in shape, reflecting the influence of the sloping potentiometric surface. The contributing areas delineated for a 5 percent porosity were always much larger than those determined using a 25 percent porosity. The lowest average ground-water velocity computed within a contributing area, using a 25 percent porosity, was 1.0 ft/d (foot per day) and the highest velocity was 1.6 ft/d. The lowest average ground-water velocity, determined using a 5 percent porosity, was 2.4 ft/d and the highest was 7.4 ft/d. The contributing areas for each of the five wells was also determined analytically and compared to the model-derived areas. The upgradient width of the simulated contributing areas were larger than the upgradient width of the analytically determined contributing areas for four of the five wells. The model could more accurately delineate contributing areas because of the ability to simulate wells as partially penetrating and by incorporating complex, three-dimensional aquifer characteristics, which the analytical method could not.

Florida, Georgia↗

Nutrients and pesticides in ground water of the Ozark Plateaus in Arkansas, Kansas, Missouri, and Oklahoma

A total of 229 ground-water samples were collected from 215 sites as part of the Ozark Plateaus study unit of the National Water-Quality Assessment Program. These samples were collected from 1993 through 1995 using a network of springs and wells with three scale-dependent components. The first component, the study-unit survey, consisted of 99 randomly selected springs and domestic wells in the Springfield Plateau and Ozark aquifers. The second component, two land-use studies, consisted of 42 springs and domestic wells in a poultry-dominated agricultural area and 40 springs and domestic wells in a cattle-dominated agricultural area overlying the Springfield Plateau aquifer. The third component, the small-watershed study, consisted of 4 springs, 18 domestic wells, and 11 monitoring wells in a small basin within the poultry land-use study area. Samples were analyzed for major ions, nutrients, dissolved organic carbon, methylene blue active substances, tritium, and 88 pesticides and metabolites.The water-quality data from these samples were analyzed with descriptive and statistical methods. Nitrite plus nitrate, which was detected more often and in greater concentrations than any of the other nutrients, ranged from less than 0.05 to 25 milligrams per liter as nitrogen. Nitrite plus nitrate concentrations positively correlated to percent agricultural land use around each site. Median nitrite plus nitrate concentrations generally were greater in samples from springs than in samples from wells. Concentrations of nitrite, ammonia, and ammonia plus organic nitrogen were also affected by land use and also by concentrations of dissolved oxygen in the ground water. Concentrations of phosphorus and orthophosphate probably were affected by land use and also by phosphorus solubility. Pesticides were detected in 80 of 229 samples from 73 of 215 sites. A total of 20 pesticides were detected with a maximum of 5 pesticides detected in any 1 sample. The most commonly detected pesticides were tebuthiuron, atrazine, prometon, desethylatrazine, and simazine. Maximum concentrations ranged from 0.003 to 1.0 microgram per liter. The occurrence and distribution of pesticides were related to land use. Percent agricultural land use was greater for samples with pesticides detected than for samples with no pesticides detected. Pesticides were detected more often in samples from springs than in samples from wells. The occurrence of pesticides also was related to seasonality and chemical characteristics, such as solubility and persistence, of the compounds.

Arkansas, Kansas, Missouri, Oklahoma↗

Water-quality assessment of south-central Texas: Occurrence and distribution of volatile organic compounds in surface water and ground water, 1983-94, and implications for future monitoring

The study area of the South-Central Texas study unit of the National Water-Quality Assessment Program comprises the Edwards aquifer in the San Antonio region and its catchment area. The first phase of the assessment includes evaluation of existing water-quality data for surface water and ground water, including volatile organic compounds, to determine the scope of planned monitoring. Most analyses of volatile organic compounds in surface water are from the National Pollutant Discharge Elimination System sites in San Antonio, Texas. Nine volatile organic compounds were detected at the six sites. The three compounds with the most detections at National Pollutant Discharge Elimination System sites are 1,2,4-trimethylbenzene, toluene, and xylene. Analysis of volatile organic compounds in ground water was limited to Edwards aquifer wells. Twenty-eight volatile organic compounds were detected in samples from 89 wells. The five most commonly detected compounds in samples from wells, in descending order, are tetrachloroethene, trichloroethene, bromoform, chloroform, and dibromochloromethane. Detections of volatile organic compounds in surface water and ground water within the South-Central Texas study area are limited to site-specific sources associated with development; therefore, planned monitoring for possible detections of volatile organic compounds as part of the National Water-Quality Assessment Program will emphasize areas of expanding population and development. Monitoring of volatile organic compounds is planned at National Pollutant Discharge Elimination System sites, at basic fixed surface-water sites, and in the ground-water study-unit surveys.

Texas↗

Hydrologic and water-quality conditions in the Horse Creek basin, west-central Florida, October 1992-February 1995

A baseline study of the 241-square-mile Horse Creek basin was undertaken from October 1992 to February 1995 to assess the hydrologic and water-quality conditions of one of the last remaining undeveloped basins in west-central Florida. During the period of the study, much of the basin remained in a natural state, except for limited areas of cattle and citrus production and phosphate mining. Rainfall in 1993 and 1994 in the Horse Creek basin was 8 and 31 percent, respectively, above the 30-year long-term average. The lowest and highest maximum instantaneous peak discharge of the six daily discharge stations occurred at the Buzzard Roost Branch and the Horse Creek near Arcadia stations with 185 to 4,180 cubic feet per second, respectively. The Horse Creek near Arcadia station had the lowest number of no-flow days with zero days and the Brushy Creek station had the highest number with 113 days. During the study, the West Fork Horse Creek subbasin had the highest daily mean discharge per square mile with 30.6 cubic feet per second per square mile, and the largest runoff coefficient of 43.7 percent. The Buzzard Roost Branch subbasin had the lowest daily mean discharge per square mile with 5.05 cubic feet per second per square mile, and Brushy Creek and Brandy Branch shared the lowest runoff coefficient of 0.6 percent. Brandy Branch had the highest monthly mean runoff in both 1993 and 1994 with 11.48 and 19.28 inches, respectively. During the high-baseflow seepage run, seepage gains were 8.87 cubic feet per second along the 43-mile Horse Creek channel. However, during the low-baseflow seepage run, seepage losses were 0.88 cubic foot per second. Three methods were used to estimate average annual ground-water recharge in the Horse Creek basin: (1) well hydrograph, (2) chloride mass balance, and (3) streamflow hydrograph. Estimated average annual recharge using these three methods ranged from 3.6 to 8.7 inches. The high percentage of carbonate plus bicarbonate analyzed at the Carlton surficial aquifer well could indicate an upward ground-water flow from the underlying intermediate aquifer system. Based on constituent concentrations in water samples from the six daily discharge stations, concentrations generally are lower in the upper three subbasins, West Fork Horse Creek, Upper Horse Creek, and Brushy Creek than in the lower three subbasins. Typically, concentrations were highest for major ions at Buzzard Roost Branch and nutrients at Brushy Creek.

Florida↗