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Oligocene–Miocene development and evolution of the south Dome Rock Mountains basin, lower Colorado River corridor, Arizona, USA

Sedimentary basins in the Colorado River extensional corridor record large-magnitude Basin and Range extension and younger dextral shear deformation in the evolving Pacific−North America plate boundary. The south Dome Rock Mountains basin is located in west-central Arizona (USA), where the history of basin evolution, style of deformation, and timing of the transition between extension and dextral shear are not well constrained. We integrate new geologic mapping of the south Dome Rock Mountains basin with zircon U-Pb geochronology of six marker beds to characterize the timing of basin evolution and the slip history of the south Dome Rock Mountains normal fault. Structural analysis defines structures consistent with regional extension and younger dextral shear deformation. We use sedimentological and petrological analysis to interpret the depositional environments of three basin sequences. A lower basin sequence consists of fluvial strata deposited in an internally drained intermontane basin from ca. 35 Ma to 24.4 Ma. A sequence of volcanic rocks was emplaced in the basin between 24.4 Ma and 23.3 Ma, before the onset of local extensional faulting. An upper basin sequence of coarse conglomerate and sedimentary breccia was deposited on the hanging wall of a half graben structure after 23.3 Ma and through ca. 12.8 Ma, synchronous with 3−7 km of dip slip on the west-dipping, listric south Dome Rock Mountains fault. The basin was subsequently deformed by dextral shear after 12.8 Ma and before 4.8 Ma. These results document how distributed deformation related to the evolving Pacific−North America plate boundary occurred >100 km from the primary plate boundary.

Arizona, California

Satellite time series analysis to quantify changing climax ciénegas using a state and transition model approach

Ciénegas are rare wetlands in arid landscapes of the North American Southwest, historically providing critical ecological and hydrological functions but increasingly threatened by changing climate and land use pressures. This study quantifies changes in ciénega condition and floodplain dynamics using a state-and-transition model (STM) informed by expert knowledge and remote sensing. Key factors include woody plant encroachment, water availability, and soil aggradation. We mapped 31 ciénegas with high-resolution imagery and analyzed Landsat data (1985–2023) to assess vegetation health and moisture using the Normalized Difference Vegetation Index (NDVI) and Normalized Difference Infrared Index (NDII). Results show substantial interannual variability in phenology, water stress, and soil moisture, with regional drying and elevation strongly influencing ciénega resilience. We classified ciénegas into three functional states—healthy, desiccated, and dormant—and mapped their 2023 condition. Trend analyses indicate most ciénegas exhibit greening despite drought, though localized variability underscores the need for site-specific management. None are in a stable climax (reference) state; rather, they transition among states in response to external drivers. Increasing woody plant cover and surface drying, likely linked to declining regional water tables, favor deep-rooted species over wetland grasses—a pattern mirrored in adjacent control plots. Spatially explicit analysis revealed intra-ciénega variability often masked by aggregated data, highlighting the importance of high-resolution monitoring. Seasonal and long-term trends provide context for understanding ciénega dynamics, including degradation and restoration pathways. This study emphasizes the importance of groundwater conservation and demonstrates how remote sensing supports long-term monitoring. The STM framework offers a practical tool for adaptive management to sustain freshwater resources in arid environments.

Arizona, New Mexico

Riverscape heterogeneity shapes population diversity for a migratory fish

Habitat patch dynamics can scale up to influence population demography and diversity with implications for resilience to environmental stochasticity. But how the spatial arrangement and size of habitat patches interact with other components of habitat heterogeneity to shape population diversity at larger spatial scales is not well understood. For riverine fishes, there is increasing evidence that tributary streams provide critical demographic support to main stem rivers. However, the extent to which main stem rivers rely on demographic contributions from tributaries, and the factors underlying this dependence, have not been assessed. Here, we used genetic stock identification to evaluate the effect of tributaries on population diversity of Yellowstone cutthroat trout ( Oncorhynchus virginalis bouvieri ) occupying the main stem Snake River, Wyoming, USA. We found that the main stem relied almost entirely on tributaries for demographic support, but main stem composition varied spatially among river sections. Distance between habitat patches, catchment area, and groundwater availability acted in concert to determine the contribution of specific tributaries to the main stem, but contributions were ultimately modulated by habitat connectivity. We also found evidence for multi-scale spatial structure in tributary contributions, providing insight into untested drivers of main stem river population diversity. Our results demonstrate how spatially discrete and distributed riverscape attributes influence population diversity at broader spatial scales, illustrating how ecosystem resilience emerges from the dynamic, two-way exchange of individuals and energy across habitat networks. Management plans for large rivers that address the ecological contributions of tributaries may be needed to achieve optimal outcomes. Similarly, conservation strategies that exclusively focus on headwater streams may fail to capture the broader habitat requirements necessary to maintain robust cold-water fish populations and associated recreational fisheries, particularly under global environmental change.

Wyoming

Timescales of surface faulting preservation in low-strain intraplate regions from landscape evolution modeling and the geomorphic and historical record

Large surface-rupturing intraplate earthquakes in stable continental regions (SCRs) are uncommon globally and have recurrence intervals of thousands to hundreds of thousands of years based on the paleoseismic and geomorphic record, challenging accurate active fault identification in these regions. To constrain the timescales of preservation for scarps created by surface ruptures from dip-slip earthquakes, we use a two-dimensional scarp diffusion model for typical intraplate settings and explore which parameters influence fault scarp preservation. These parameters include the coseismic vertical surface offset, the recurrence interval of similar magnitude earthquakes, diffusivity (as a proxy for mean annual precipitation rate), and the erodibility of the surficial material. We constrain parameter ranges from a compilation of historical surface ruptures in intraplate settings in a variety of climates, including the Central and Eastern United States, Australia, Europe, Central Asia (Mongolia, China), India, and West Africa. The timescales of scarp preservation from landscape evolution modeling agree well with observations of scarp preservation in low-strain SCR and intraplate tectonic settings, with some notable exceptions for Australian scarps. We find that the erodibility of the surficial material and earthquake recurrence interval have a stronger effect on the timescales of scarp preservation than diffusivity or coseismic vertical surface offset. Our model results may aid in identifying and characterizing subtle, slow-moving active faults in low-strain SCR and intraplate tectonic settings for different tectonic, geomorphic, and climatic characteristics. Accurate fault locations and characterization from the landscape record has implications for both probabilistic seismic and fault displacement hazard analyses.

Journal of Geophysical Research Solid Earth

Development of vegetation based soil quality indices for mineralized terrane in arid and semi-arid regions

Soil quality indices (SQIs) are often management driven and attempt to describe key relationships between above- and below-ground parameters. In terrestrial systems, indices that were initially developed and modified for agroecosystems have been applied to non-agricultural systems in increasing number. We develop an SQI in arid and semi-arid ecosystems of the Western US impacted by different types of geologic mineralization using the relationship between vegetation community parameters and soil abiotic and biotic properties. We analyze these relations in soils associated with three different mineralization types: podiform chromite, Cu/Mo porphyry, and acid-sulfate gold vein systems at four different sites in California and Nevada. Soil samples were collected from undisturbed soils in both mineralized and nearby unmineralized substrates as well as from waste rock and tailings. Aboveground net primary productivity (ANPP), canopy cover and shrub density were measured for the vegetative communities. Minimum data sets were developed based on correlations between the soil and vegetation parameters, refined using principal components analysis, scored using non-linear functions, and combined into an overall SQI. The indices are comprised of one or two microbial parameters and three to six abiotic parameters, the latter consisting of nutrients and metals. Given the preliminary development of this approach, the parameters and combinations to arrive at an SQI for a given site cannot at this time be correlated or compared with that of another site. This SQI approach provides a means of quantifying disturbed ecosystem recovery resulting from mining, and could be applied to other disturbances in a way that readily distills the information for potential use by land managers. However, severely disturbed areas with little to no aboveground biomass, such as unreclaimed tailings, have likely crossed an ecological threshold that precludes the use of this type of monitoring tool.

California

Status of water-quality conditions in the United States, 2010–20

Degradation of water quality can make water harmful or unusable for humans and ecosystems. Although many studies have assessed the effect of individual constituents or narrow suites of constituents on freshwater systems, no consistent, comprehensive assessment exists over the wide range of water-quality effects on water availability. Using published studies, data, and models completed at regional or national scales in the United States during 2010–20, this chapter moves towards a comprehensive assessment by summarizing how selected anthropogenic and geogenic water-quality constituents affect national-scale water availability for human and ecosystem needs. Several types of human health, agricultural, ecological, and beneficial-use standards or thresholds were used to provide context for categorizing surface-water and groundwater quality. Water availability for human and ecological use is limited by elevated concentrations of geogenic and anthropogenic constituents in surface and groundwater. Elevated concentrations of five geogenic constituents (arsenic, manganese, strontium, radium, and adjusted gross alpha) are common in groundwater and collectively affect the drinking water supply to over 30 million people. Surface water sourced drinking water supplies are impaired in about a third of assessed stream miles, most commonly because of non-mercury metals and salinity. Health-based violations at community water systems may disproportionately affect socially vulnerable communities. Ecological water uses are predominantly limited by nutrients, sediment, temperature, pathogens, salinity, and pesticides. Water availability for human and ecological use is adversely affected by human activities including human contaminant sources (for example, wastewater, agriculture), processes (for example, dredging, groundwater pumping), or permanent landscape modifications (for example, dams, urbanization). Primary contaminant sources vary spatially and include fertilizer and manure, atmospheric deposition, wastewater treatment plants, urban land, and a range of natural sources. Contaminants of emerging concern, contaminants without regulatory thresholds, and mixtures of geogenic and anthropogenic water contaminants also contribute to ecological degradation and human exposure.

conterminous United States

Diverging mineral chemistry of iron and nickel throughout Earth’s changing redox conditions reveals foundation for their evolution as protein cofactors

Iron (Fe) and nickel (Ni) were both foundational to early metabolism, yet their biological trajectories diverged as Earth’s surface redox state changed. Here, we integrate mineral chemistry network analysis, protein metal-site coordination-sphere analysis, and curated redox comparisons to test how geochemistry and metalloprotein architecture co-evolved. Mineral network analyses show broader electronegativity variation and network diversity for Fe-bearing minerals through time relative to Ni-bearing minerals. In structural analyses of protein metal centers in a combined Fe/Ni protein structure set, it is shown that Fe- and Ni-associated environments differ in amino-acid composition, hydropathy structure, and cysteine representation. The greater chemical diversity and electronegativity variation in Fe minerals mirror the higher redox and structural versatility of Fe-binding proteins. The presence of Fe in a broader range of mineral and protein environments demonstrates the chemical adaptability of the metal, from the anoxic Archean to oxidative Earth surface conditions following the Great Oxidation Event. Iron, with its broad redox potential range in Fe-oxidoreductases, has a central role in both anaerobic and aerobic metabolisms. Nickel, by contrast, is less widespread in biology. Today, Ni is predominantly employed in deeply branching anaerobic pathways and by proteins with narrower redox potential ranges. Our results show that evolutionary processes, constrained by metal chemistry, habitually utilize Fe as a redox generalist while retaining Ni in specialized roles. The divergent paths of Ni and Fe, from rocks to proteins, demonstrate the intimate relationship between planetary geochemistry and metabolic origins on Earth and suggest that Fe/Ni geochemistry may inform habitability assessments in extraterrestrial environments when interpreted within specific planetary environmental contexts.

Life

Miocene evolution of the Humboldt Current

Diatom records from the East Pisco Basin (EPB) of southern Peru and offshore Ocean Drilling Program (ODP) Hole 682 A reveal stepwise increases in the primary productivity of the Humboldt Current during the middle and late Miocene. Although diatoms are present back through the late middle Eocene, successively enhanced diatom production occurs during the Miocene in four steps. The first step between 14.2 and 13.8 Ma marks the onset of diatom deposition in the Pisco-0 sequence. A second step at ∼12.9 Ma coincides with a major drop in global sea level during which diatom deposition ceased in the EPB but continued in ODP 682 A as well as in Chile, Ecuador, and Colombia. Beginning at 10.4 to 10.0 Ma, a major increase in diatom sedimentation rates in both the EPB and in ODP 682 A signals an abrupt intensification of the Humboldt Current productivity, which may be related to the closure of the Central American Seaway to deeper water circulation. A fourth step coincides with the transgressive deposition of the diatom-rich Pisco-2 sequence at 8.4 Ma and is enhanced by the onset of the global Late Miocene Biogenic Bloom (8.0–4.5 Ma). Between 7 and 6 Ma, common subtropical diatoms in ODP 682 A contrast with high diatom deposition rates in the EPB, suggesting variable El Niño-La Niña conditions. During this time, fossil vegetation evidence from southern Peru supports the presence of seasonal periods of enhanced rainfall typical of El Niño conditions. The Miocene trend of increasing sea mammal diversity in the EPB parallels these steps, further supporting stepwise enhancement of primary productivity in the Humboldt Current during the Miocene.

Humboldt Current

Alternative approaches to dryland reclamation enhance vegetation cover and soil stability at a former uranium mine

Introduction Conventional reclamation methods to recover dryland ecosystems after mineral extraction often have low success. Alternative reclamation techniques may help overcome the many challenges to establishing persistent native vegetation and stable soils. Objectives Compare conventional reclamation approaches that focus primarily on soil stabilization to alternative approaches that may improve native ecosystem restoration at the Kanab North Mine in northern Arizona. Methods In a fully crossed experiment, conventional seed mix (native and non-native species) and seeding methods (drill-seeding) were compared to alternative practices, including a native-only seed mix, connectivity modifiers (ConMods) with hand seeding, and a biocrust inoculation. Restoration metrics like plant establishment, species composition, soil surface cover and stability, biocrust establishment, and near-surface wind-driven sediment were monitored over the first 5 years post-reclamation. Results While all restoration metrics improved with time, compared to traditional methods, ConMods increased total, graminoid, and native plant species cover, and the native-only seed mix increased woody, native, and perennial species cover. Biocrust inoculation increased late-successional biocrust development, but biocrusts only persisted over 5 years in combination with ConMods. Soil stability increased in all treatments, but both ConMods and biocrust inoculation increased stability compared to traditional practices. Conclusion Overall, alternative approaches to reclamation tested here (ConMods, native seed, and biocrust inoculation) were more effective than traditional practices at increasing total plant cover, facilitating biocrust establishment, and promoting soil stability after uranium mine reclamation.

Arizona

Structural evolution and slip rate variations through time of the Puente-Hills blind-thrust fault beneath Los Angeles: Implications for seismic hazard and folding kinematics

Using seismic reflection profiles, historical well logging data, and luminescence and radiocarbon ages, we determine a Pleistocene-Holocene slip history for the central, Santa Fe Springs segment of the Puente Hills blind-thrust fault (PHT), a major seismogenic fault situated beneath the urbanized Los Angeles metropolitan region. We analyze the geometry of correlative stratigraphic units in the forelimb and backlimb of the overlying growth-fold, the Santa Fe Springs anticline, and determine the uplift of seven age-correlative markers. Uplift measurements are converted to thrust displacements on the underlying PHT using a structural method laid out by Don et al. (2022, https://doi.org/10.1785/0120220048 ) that accounts for the geometry of the fault. These data indicate that deep thrust displacement on the PHT is partially consumed updip in the creation of a hanging-wall fault-bend fold, with forelimb growth strata recording <80% of the slip documented within the backlimb. Chronological data from growth strata yield age constraints for folding and faulting on the underlying PHT, providing a detailed incremental slip history derived from both the forelimb and backlimb folding for seven discrete growth horizons, spanning the past 1.4 million years. The resulting six incremental slip rates demonstrate that fault slip has varied through time from the middle Pleistocene to the Holocene. Moreover, these results reveal synchronous acceleration of both the central, Santa Fe Springs and western, Los Angeles segments of the fault system since late Pleistocene time (after 200 ka) and slip rates of greater than 2 mm/yr on the downdip, backlimb, fault-ramp below the anticline.

California

Evolution of permeability and strength recovery of shear fracture under hydrothermal conditions

Geothermal energy is a clean and renewable resource that depends on the ability to move water through hot rock. In many locations, the ability to move water through rock requires the presence of extensive natural or human-made systems of fractures. However, these fracture systems are influenced by a variety of complex processes that occur at the temperature and pressure conditions found in geothermal reservoirs. To make geothermal systems more efficient, it is important to understand how these fractures evolve over time in response to these processes. This study explored how fractures in rock change under high-temperature and pressure conditions, like those found in geothermal reservoirs, through laboratory experiments and numerical simulations. In general fractures, tend to close due to pressure from the surrounding rock preventing the flow of water. One set of laboratory experiments revealed that fractures in granitic rock can weaken over time at elevated temperatures. These weak fractures can then slip slowly potentially keeping the fracture open for a longer period. This study also showed that at the highest temperature examined (250 °C) large differences between the chemical composition of the rock and the fluid moving through it could improve water flow temporarily likely due to the water dissolving parts of the rock. Flow rate predicted by models shows overall good agreement with the flow rate measured in our experiments but with some long time-scale variations that may be due to mechanical wear of the fracture surface. A second set of experiments found that, over the temperature range examined, the closure of fractures was caused by brittle failure driven by high stresses at points where fracture surfaces were in contact. This result suggests that fracture closure in geothermal reservoirs could be counteracted by maintaining high pore pressures. Additionally, we also tested a new method using electrical resistance to measure fracture closure in controlled systems with high precision.

Final Technical Report

Evolution of arsenic speciation during thermal treatment simulating wildfire heating in arsenic-rich sediments

Understanding arsenic transformations during wildfires can help better constrain the environmental impacts of increased wildfire intensity, frequency, and burned area. Previous studies have monitored the evolution of metal(loid) speciation at specific time/temperature endpoints, hampering the comprehension of the dynamic transformations of metal(loid)s during wildfires. Here, a novel approach, namely in situ time-resolved X-ray absorption near edge structure (TR-XANES) spectroscopy, was used for the first time to monitor the heat-induced redox transformations of arsenic (As) in two As-rich sediments with different characteristics. No arsenic transformations were observed in either sediment at room temperature or when the sediments were heated to a maximum temperature of 400 ºC. When heated to a maximum temperature of 600 or 700 ºC, As underwent complex, dynamic, and partially reversible redox transformations, the extent of which varied with sediment properties, initial As speciation, and heating temperature and duration. In the case of sediments initially containing As(V) and a low sulfide/sulfate ratio, the As(V) was reduced to As(III) over a short period of time, followed by immediate reoxidation of As(III) to As(V). The extent of the transient As reduction increased with increasing maximum temperature. The final As speciation at the end of the heating experiment was not substantially different from that at the beginning of the experiment. In contrast, in sediments that were best described by a more complex combination of reference compounds (As(V) coprecipitated with or adsorbed on iron oxide, arseniosiderite, arsenopyrite) with a high sulfide/sulfate ratio, As(V) phases were reduced to As(III) and As(III) was further reduced to As(-I) (at 700 ºC, only), followed by delayed reoxidation of As(-I) to As(III) (at 700 ºC, only) and reoxidation of As(III) to As(V). Approximately 9% and 26% of all As remained as As(III) ( i.e., was not reoxidized to As(V)) at the end of the experiment when heated to a maximum temperature of 600 and 700 ºC, respectively, which is higher than the relative abundance of As(III) in the native sediment. These fire-induced As transformations can potentially enhance As mobilization to surface water and groundwater, posing risks to environmental and human health.

California

Archean to Mesozoic–Cenozoic seismic crustal structure: Implications for geological and biological evolution

We use >4500 measurements of crustal structure to investigate the seismic structure of continental crust, Archean to Mesozoic–Cenozoic. The mean crustal thickness of continents, including their margins, is 36.5 km. We find that Archean, Paleoproterozoic, and Mesoproterozoic crust have similar mean crustal thickness (41 km), seismic velocities, Vp/Vs ratio, and density. Crusts of these ages span 3 Ga, from 4.0 to 1.0 Ga, and their similarity of physical properties (thickness, density, and seismic velocities) suggests that the process of crustal formation may have been similar during this time period, which covers 66% of Earth's history. Neoproterozoic crustal properties differ significantly from Mesoproterozoic and older crusts. The mean thickness of Neoproterozoic crust is 32 km, some 9 km thinner than the mean thickness of Archean, Paleoproterozoic, and Mesoproterozoic crust. A lithospheric root with a thickness of 150–200 km underlies Archean, Paleoproterozoic, and Mesoproterozoic crusts, and this root resists lithospheric rifting and crustal extension and thinning. Based on these observations, particularly the lithospheric thickness, we conclude that Archean, Paleoproterozoic, and Mesoproterozoic lithosphere are unique and together form the stable cratonic nuclei, defined as the thick (150–250 km), long-lived cores of continents. Higher mantle temperatures during the Archean, Paleoproterozoic, and Mesoproterozoic may have played a key role in the formation of the thick lithospheric roots. The second key finding is that the similarities of mean seismic properties indicate that the process of crustal formation operating in the Archean continued during the Paleoproterozoic and Mesoproterozoic. The thin (mean value < 135 km) lithospheric root beneath Neoproterozoic and younger crust may be related to the steady decrease in mantle temperature through time. Neoproterozoic and Paleozoic crust have similar physical properties, and these eras are characterized by pronounced biodiversification, including the renowned Garden of Ediacara, the Cambrian Explosion, and the Great Ordovician Biodiversification. Mesozoic–Cenozoic crust is the most diverse and reflects the current tectonic and magmatic processes of crustal formation.

Book chapter

Spatial variation in effectiveness and costs of sagebrush restoration treatments across the western United States

Natural resource managers strive to improve restoration efficiency across the vast network of public lands of the United States, seeking the best return on investment through innovation, geographic prioritization, and adaptive management. This challenge is exemplified by ecosystems dominated by sagebrush ( Artemisia spp.), which occur across the western United States and have been degraded by increasing wildfire frequency driven by invasive plant spread, among other factors. However, both costs and effectiveness of sagebrush restoration can vary spatially due to management practices in addition to biotic and abiotic factors, and characterizing this variation could inform broad-scale planning. We leveraged published models of sagebrush recovery and treatment costs to predict and evaluate cost-effectiveness of aerial and drill seeding Artemisia spp. across 429 718 km 2 that overlapped 12 US states. Compared to natural recovery, effectiveness for both methods was generally low, yet effectiveness was often greater, and costs were always greater, for drill than aerial seeding, resulting in slightly higher cost-effectiveness on average for drill seeding. Cost-effectiveness for both treatments increased near major roads and in areas with more repeated burns. Cost-effectiveness also increased with predisturbance cover of sagebrush but decreased with herbaceous cover. However, we also identified areas where aerial seeding was more cost-effective than drill seeding, particularly with greater slope. Our results provide spatially explicit estimates and potential mechanisms of cost-effectiveness for two common seeding methods for sagebrush, which can help prioritize limited resources, guide land use, and improve restoration efficiency and effectiveness across public rangelands of the western United States.

western United States

Assessing environmental drivers of denitrification in restored riverine floodplains

Restoration of impaired floodplains is an increasingly prevalent strategy for alleviating water quality concerns and reducing downstream flooding at watershed scales. Floodplains temporarily store water and slow flow velocity to promote sedimentation during overbank flooding and remove inorganic nitrogen from floodwater and groundwater via denitrification. Evaluating the impacts of different restoration strategies on denitrification can inform more strategic investments into floodplain modifications that improve water quality outcomes. Our research investigates how denitrification rates in floodplains respond to environmental factors that are actionable from an engineering perspective through design and water resources management. We seasonally measured soil denitrification enzyme activity and various environmental characteristics in 4 floodplains with different restoration design and management approaches at the confluence of the Wabash and Tippecanoe Rivers in Indiana, United States. Our results showed that denitrification rates in an agricultural floodplain were significantly lower than in restored floodplains with native vegetation. Certain soil conditions characteristic of floodplain wetlands were associated with higher denitrification, particularly elevated total nitrogen, moisture, silt, and organic matter contents. Vegetation species composition was correlated with denitrification rates. This link may reflect the direct effects of vegetation on soil conditions, such as supplying labile organic carbon, or indirect effects, such as vegetation acting as an indicator of hydrologic regime and land use. Denitrification seasonally varied, peaking in winter when nitrate supply from rivers draining agricultural watersheds in the region is also high. Substrate limitation of soil denitrification enzyme activity was most significant during the summer when overbank flooding, which replenishes soil nitrogen stocks, rarely occurs. Our findings indicate that denitrification capacity will likely be maximized in riverine floodplains that are restored as wetlands with diverse native vegetation and enhanced hydrologic connectivity. Such restoration activities promote higher denitrification rates via elevated moisture, fine sediment deposition, and soil organic matter.

Tippecanoe River, Wabash River

Chemical evolution and estimated flow velocity of water in the Trinity Aquifer, south-central Texas

Three permeable zones with varying lithology and water chemistry compose the Trinity aquifer, a principal source of water in the 5,500- square-mile study area in south-central Texas. The upper permeable zone locally yields small quantities of water to wells and was not included in this study. The middle permeable zone primarily is composed of limestone with minor amounts of dolostone. Terrigenous sand and marine limestone, with minor amounts of dolostone, are the principal lithologic units in the lower permeable zone. Dissolved solids concentrations range from 329 to 1,820 milligrams per liter in water samples from the middle permeable zone and from 518 to 3,030 milligrams per liter in water samples from the lower permeable zone. Principal hydrochemical facies in the middle permeable zone are calcium magnesium bicarbonate and calcium magnesium sulfate. Hydrochemical facies in ground-water samples from the lower permeable zone vary. Tritium concentrations as large as 5.3 tritium units in the southeastern part of the study area are indicative of relatively recent recharge. Results of a geochemical mass balance simulation along a flowpath in the middle permeable zone indicate a mass transfer of 4.25 millimoles per liter of dolomite dissolved, 5.74 millimoles per liter of gypsum dissolved, 0.46 millimole per liter of sodium chloride dissolved, 8.07 millimoles per liter of calcite precipitated, and 0.67 millimole per liter of calcium-for-sodium cation exchange between solid and aqueous phases. These results support dedolomitization as a principal chemical process in the middle permeable zone of the Trinity aquifer. Results of a simulation along a flowpath in the lower permeable zone indicate a mass transfer of 0.41 millimole per liter of dolomite dissolved, 0.001 millimole per liter of gypsum dissolved, 9.58 millimoles per liter of sodium chloride dissolved, 1.09 millimoles per liter of calcite precipitated, and 1.11 millimoles per liter of sodium-forcalcium cation exchange between solid and aqueous phases. Lower permeable zone processes indicate sodium chloride dissolution, dedolomitization, and cation exchange. Ground-water-flow velocities determined from adjusted carbon-14 ages, calculated using NETPATH, for selected flowpaths in the middle and lower permeable zones were about 1.7 feet per year and less than about 4.4 feet per year, respectively.

Texas

Spatio-temporal evolution of distributed volcanic fields, case studies—Sierra Chichinautzin and Michoacán-Guanajuato, México

An analysis of 1,375 volcanoes in the Michoacán-Guanajuato (1,148 volcanoes in a 26,200 square-kilometer area) and Sierra Chichinautzin (227 volcanoes in a 3,500 square-kilometer area) volcanic fields in central Mexico identified patterns in the spatial and temporal distribution of past eruptions. A cluster agglomerative hierarchical method and kernel analysis confirmed that the Michoacán-Guanajuato volcanic field comprises four volcanic fields (Valle de Santiago, Uruapan, Apatzingán, and Pátzcuaro volcanic fields) controlled by different fault systems, indicating that it is not a single volcanic field but rather a group of volcanic fields (a “superfield”), each of which has distinct characteristics. In the Sierra Chichinautzin volcanic field, well-constrained isotopic ages were used to build a model of how the spatial distribution of the eruptions has changed over time. Two new 40Ar/39Ar ages from a locally recognized volcanic feature near the town of El Cantil, herein called El Cantil volcano (1,537±17 kilo-annum [ka]) and the volcanic feature at Cerro el Elefante (herein called El Elefante dome) (1,485±92 ka) belong to the oldest volcanic group identified in the Sierra Chichinautzin volcanic field, confirming the timing of the beginning of monogenetic volcanism in the region. Based on the volcanic groups identified in the Sierra Chichinautzin volcanic field, the youngest volcanism (less than 35 ka) is found only in the central-western sector of the field. Principal component analysis determined the directional trends of feeder dikes only for vents <10 ka in the Sierra Chichinautzin volcanic field. Possible magma migration paths through the crust were identified using seismic data from both volcanic fields using an earthquake catalog from 1973 to 2023, which includes 9,016 earthquakes in the Michoacán-Guanajuato volcanic field and 841 in the Sierra Chichinautzin volcanic field. The spatial distribution of the hypocenters does not highlight any trend that could be associated with superficial movement of magma in the Sierra Chichinautzin volcanic field. In the Michoacán-Guanajuato volcanic field, however, eight seismic swarms since 1997 have been detected. These swarms are interpreted to result from ascending magma. Strengthening monitoring systems and reinforcing mitigation measures to address volcanic hazards and risk are important means of preparing for future eruptions in both regions. Analysis such as those herein provide insights as to where an eruption might occur and may help mitigate volcanic hazards.

Michoacán-Guanajuato, Sierra Chichinautzin

Overstorey mortality promotes juvenile piñon pine growth during favourable weather at cooler, wetter sites

Hotter droughts have resulted in widespread tree die-off events globally, frequently leading to regeneration failure. Dry forest recovery often depends on the growth and survival of extant juvenile trees. However, it is unclear how microenvironmental changes following overstorey tree die-off affect juvenile trees, particularly in dryland systems where tree recruitment is typically limited by water availability and heat stress. We simulated an overstorey tree die-off event by girdling trees in piñon-juniper woodlands across the south-western United States. We sampled juvenile piñon pine growth from live and dead overstorey treatments across six study sites spanning a regional latitudinal gradient and local elevational gradients. We examined how juvenile branch and needle growth differed between live and dead overstorey treatments, and whether responses varied with weather conditions and juvenile tree size following overstorey mortality. We found greater juvenile branch and needle growth under dead compared with live overstorey trees for 2 years following overstorey mortality at mid- and high-elevation sites which are typically cooler and wetter than the other sites. These observed growth releases were contingent on favourable post-mortality weather conditions. Higher growth under dead overstorey occurred at sites experiencing near-average climatic water deficits compared with sites experiencing above-average climatic water deficits. Growth at all sites increased from the first to second year after overstorey mortality. Across sites, growth was unrelated to juvenile tree size. Synthesis . Our results underscore differentiation in juvenile responses to overstorey tree die-off driven by local site conditions and weather across the range of Pinus edulis . Overstorey mortality resulted in consistently higher juvenile growth only at climatically favourable sites and during favourable weather, while unmeasured microsite differences could help account for variation observed at the hottest and driest site. Results from less climatically favourable sites suggest that overstorey trees neither directly limit nor facilitate juvenile growth, though further study over longer timeframes is needed to resolve the pace and magnitude of potential recovery or decline. Overall, juvenile vigour may be promoted following overstorey mortality only in a narrow spatial (site) and temporal (weather) environmental context, suggesting additional vulnerabilities for piñon populations under more arid conditions.

Arizona, Colorado