Geology ReportsSearch

SEARCH · Geology Reports

Results for “EPA Report”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 37 records · Page 2Linked to original sources

Surface geophysics and porewater evaluation at the Lower Darby Creek Area Superfund Site, Philadelphia, Pennsylvania, 2013

In cooperation with the U.S. Environmental Protection Agency (EPA), Region 3, the U.S. Geological Survey (USGS) is participating in an ongoing study to aid in the identification of subsurface heterogeneities that may act as preferential pathways for contaminant transport in and around the Lower Darby Creek Area (LDCA) Superfund Site, Philadelphia Pa. Lower Darby Creek, which flows into the Delaware River, borders the western part of the former landfill site. In 2013, the USGS conducted surface geophysics measurements and stream porewater sampling to provide additional data for EPA’s site characterization. This report contains data collected from field measurements of direct current (DC) resistivity, frequency-domain electromagnetic (FDEM) surveys, and stream porewater specific conductance (SC).

Pennsylvania

Results of a workshop concerning ecological zonation in bottomland hardwoods

Under Section 404 of the Clean Water Act, the U.S. Environmental Protection Agency (EPA) has regulatory responsibilities concerning the discharge of dredged or fill material into the Nation's waters. In addition to its advisory role in the U.S. Army Corps of Engineers' permit program, EPA has a number of specific authorities, including formulation of the Section 404(b)(1) Guidelines, use of Section 404(c) to prohibit disposal at particular sites, and enforcement actions for unauthorized discharges. A number of recent court cases focus on the geographic scope of Section 404 jurisdiction in potential bottomland hardwood (BLH) wetlands and the nature of landclearing activities in these areas that require a permit under Section 404. Accordingly, EPA needs to establish the scientific basis for implementing its responsibilities under Section 404 in bottomland hardwoods. EPA is approaching this task through a series of workshops designed to provide current scientific information on bottomland hardwoods and to organize that information in a manner pertinent to key questions, including the following. What are the characteristics of bottomland hardwoods (in terms of hydrology, soils, vegetation, fish, wildlife, agricultural potential, and the like) and how can the functions (e.g., flood storage, water quality maintenance, detrital export) that they perform best be quantified? How do perturbations like landclearing, levee construction, and drainage impact the functions that bottomland hardwoods perform and how can these effects best be quantified? And finally, how significant are the impacts and how is their significance likely to change under various management scenarios? The first workshop in this series was held December 3-7, 1984, in St. Francisville, Louisiana. The workshop was attended by over 40 scientists and regulators (see ACKNOWLEDGMENTS section) and facilitated by the editors of this report under an Interagency Agreement between EPA and the U.S. Fish and Wildlife Service. The general objective of the workshop was to examine ways in which the structure and function of BLH ecosystems can be characterized and, in particular, to investigate the utility of a conceptual framework developed at a workshop held in Lake Lanier, Georgia, in 1980. In this framework, the transition from aquatic habitats to upland habitats through a BLH ecosystem is divided into six zones based on concomitant variation in the soil moisture regime and associated vegetation (Table 1). The zonation concept is of particular interest to EPA from at least two perspectives. The first is simply as a framework for organizing information. If the zones are discernible in the field, have recognizable characteristics, and perform identifiable functions, they might form a useful basis for tasks such as assessing the impacts of a particular site-specific activity. The second is the potential utility of the zonation concept in identifying the wetland portions of BLH communities. If the zones can be recognized in the field, and if one or more of them can be shown consistently to have wetland characteristics (i.e., perform functions, such as detrital export, often attributed to wetlands), while others do not, then the zones might have utility in identifying areas that fall under the jurisdiction of Section 404. The workshop itself was divided into two parts. The first was a series of papers in which authors described current research and data-synthesis activities in the context of the zonation concept. The second was a series of six workgroups in which participants discussed the zonation concept from the perspective of hydrology, soils, vegetation, fish, wildlife, and ecosystem processes. This report is a compilation of the written material from those workgroups, much of which was produced at the workshop. The formal papers presented in the first part of the workshop have been distributed to participants under separate cover, but are referenced in this report by citations such as: (Jones, workshop presentation).

Report

Arsenic, nitrate, and chloride in groundwater, Oakland County, Michigan

In 1996, the U.S. Geological Survey (USGS), in cooperation with the Michigan Department of Environmental Quality (MDEQ) and nine southeast Michigan counties, began a study of the factors controlling arsenic concentrations in drinking water. The early results of this study raised broader concerns in Oakland County about the quality of groundwater in general and drinking water in particular. In response to these concerns, Oakland County worked with the USGS and the Center for Applied Environmental Research at the University of Michigan - Flint (CAER) to study distributions of arsenic, nitrate and chloride in groundwater, with emphasis on sites where concentrations of these constituents exceeded the Maximum Contaminant Levels (MCLs) and Secondary Maximum Contaminant Levels (SMCLs) set by the U.S. Environmental Protection Agency (EPA). The maps produced for this report are based on historical data compiled from MDEQ records.

Michigan

Water-quality assessment of the Rio Grande Valley, Colorado, New Mexico and Texas: Ground-water quality in the Rio Grande flood plain, Cochiti Lake, New Mexico, to El Paso, Texas, 1995

From March to May of 1995, water samples were collected from 30 wells located in the flood plain of the Rio Grande between Cochiti Lake, New Mexico, and El Paso, Texas. These samples were analyzed for a broad host of constituents, including field parameters, major constituents, nutrients, dissolved organic carbon, trace elements, radiochemicals, pesticides, and volatile organic compounds. The main purpose of this study was to observe the quality of ground water in this part of the Rio Grande Valley study unit of the U.S. Geological Survey National Water-Quality Assessment program. The sampling effort was limited to the basin- fill aquifer beneath the above-defined reach of the Rio Grande flood plain because of the relative homogeneity of the hydrogeology, the large amount of ground-water use for public supply, and the potential for land-use activities to affect the quality of ground water. Most of the wells sampled for the study are used for domestic purposes, including drinking water. Depths to the tops of the sampling intervals in the 30 wells ranged from 10 to 345 feet below land surface, and the median was 161.5 feet; the sampling intervals in most of the wells spanned about 10 feet or less. Quality-control data were collected at three of the wells. A significant amount of variation was found in the chemical composition of ground water sampled throughout the study area, but the water generally was found to be of suitable chemical quality for use as drinking water, according to current enforceable standards established by the U.S. Environmental Protection Agency (EPA). Nutrients generally were measured at concentrations near or below their method reporting limits. The most dominant nutrient species was nitrite plus nitrate, at a maximum concentration of 1.9 milligrams per liter (as N). Only eight of the trace elements analyzed for had median concentrations greater than their respective minimum reporting levels. Water from one well exceeded the lifetime health advisory established by the EPA for molybdenum; water from a different well exceeded the proposed EPA maximum contaminant level for uranium. Gross alpha and gross beta particle activities generally appeared to strongly correlate with quantities of uranium and potassium, respectively, detected in ground water. However, water from one well exceeded the EPA maximum contaminant level for gross alpha particle activity and may exceed the EPA maximum contaminant level for beta particle and photon activity, although current data on gross beta particle activities are not conclusive on this point. Radon concentrations did not appear to directly correlate with uranium concentrations. The herbicide prometon was the only synthetic organic compound detected in ground water in the study area, and was detected in only one well, at a concentration of 0.038 microgram per liter. This well is shallow and is not used for drinking water. With the exception of the one detection of prometon, no strong evidence was found of effects on ground-water quality from human activities. Therefore, most of the water sampled probably recharged at the margins of the alluvial basins or recharged through the flood plain before human development began. With respect to major constituents, the concentrations of dissolved solids ranged from 209 to 3,380 milligrams per liter, and the median concentration was 409.5 milligrams per liter. There is evidence that the overall chemical composition of ground water in the study area may be affected by several processes, including cation exchange, feldspar weathering, calcite dissolution and precipitation, dissolution of volcanic glass, and microbial activity. Several chemical constituents in ground water showed relatively distinct spatial patterns that appear to be related to one or more of these processes.

Texas

Endocrine disrupting chemicals research program of the U.S. Environmental Protection Agency: summary of a peer-review report

At the request of the U.S. Environmental Protection Agency (EPA) Office of Research and Development, a subcommittee of the Board of Scientific Counselors Executive Committee conducted an independent and open peer review of the Endocrine Disrupting Chemicals Research Program (EDC Research Program) of the U.S. EPA. The subcommittee was charged with reviewing the design, relevance, progress, scientific leadership, and resources of the program. The subcommittee found that the long-term goals and science questions in the EDC Program are appropriate and represent an understandable and solid framework for setting research priorities, representing a combination of problem-driven and core research. Long-term goal (LTG) 1, dealing with the underlying science surrounding endocrine disruptors, provides a solid scientific foundation for conducting risk assessments and making risk management decisions. LTG 2, dealing with defining the extent of the impact of endocrine-disrupting chemicals (EDCs), has shown greater progress on ecologic effects of EDCs compared with that on human health effects. LTG 3, which involves support of the Endocrine Disruptor Screening and Testing Program of the U.S. EPA, has two mammalian tests already through a validation program and soon available for use. Despite good progress, we recommend that the U.S. EPA a ) strengthen their expertise in wildlife toxicology, b ) expedite validation of the Endocrine Disruptors Screening and Testing Advisory Committee tests, c ) continue dependable funding for the EDC Research Program, d ) take a leadership role in the application of “omics” technologies to address many of the science questions critical for evaluating environmental and human health effects of EDCs, and e ) continue to sponsor multidisciplinary intramural research and interagency collaborations.

Environmental Health Perspectives

Introduction to emergent wetlands: Chapter A in Emergent wetlands status and trends in the northern Gulf of Mexico: 1950-2010

Throughout the past century, emergent wetlands have been declining across the Gulf of Mexico. Emergent wetland ecosystems provide a plethora of resources including plant and wildlife habitat, commercial and recreational economic activity, water quality improvement, and natural barriers against storms. As emergent wetland losses increase, so does the need for information on the causes and effects of these losses, for emergent wetland mapping, for monitoring and restoration efforts, and for increased education. The U.S. Geological Survey (USGS) and the U.S. Environmental Protection Agency’s Gulf of Mexico Program Office (EPA GMPO) are committed to providing the best science to restore, enhance, and protect these important ecosystems. The Emergent Wetlands Status and Trends Report is a continuation of the completed Seagrass Status and Trends in the Northern Gulf of Mexico Report (Handley and others, 2007), both of which serve to update the EPA GMPO Status and Trends of Emergent and Submerged Vegetated Habitats of Gulf of Mexico Coastal Waters, USA Report (Duke and Kruczynski, 1992). The Emergent Wetlands Status and Trends Report is also part of the Gulf of Mexico Alliance Ecosystems Integration and Assessment Priority Issue Team’s work plan to provide resources that will aid in the ecological and economic enhancement of the Gulf of Mexico region. The purpose of this report is to provide scientists, managers, and citizens with valuable baseline information on the status and trends of emergent wetlands along the coast of the Gulf of Mexico. The study upon which this report is based examines the emergent wetlands of eight individual estuarine areas within the northern Gulf of Mexico region and presents statewide summaries for Texas, Louisiana, Mississippi, Alabama, and Florida. Each estuarine area is detailed in vignettes that address current status and historical trends of estuarine and palustrine emergent wetlands, emergent wetlands mapping and monitoring, causes of status change, restoration and enhancement activities, background information for the study area, and the methodology employed to analyze and document the historical trends and current status of emergent wetlands. The eight individual estuarine areas examined in this report are:  Corpus Christi/ Nueces/Aransas Bays, Tex.  Galveston Bay, Tex.  Barataria/Terrebonne Bay, La.  Mississippi Delta, La.  Mississippi Sound, Miss.  Mobile Bay, Ala.  Florida Panhandle, Fla.  Tampa Bay, Fla.

Report

Mercury concentrations in water, and mercury and selenium concentrations in fish from Brownlee Reservoir and selected sites in Boise and Snake Rivers, Idaho and Oregon, 2013

Mercury (Hg) analyses were conducted on samples of sport fish and water collected from six sampling sites in the Boise and Snake Rivers, and Brownlee Reservoir to meet National Pollution Discharge and Elimination System (NPDES) permit requirements for the City of Boise, Idaho. A water sample was collected from each site during October and November 2013 by the City of Boise personnel and was analyzed by the Boise City Public Works Water Quality Laboratory. Total Hg concentrations in unfiltered water samples ranged from 0.73 to 1.21 nanograms per liter (ng/L) at five river sites; total Hg concentration was highest (8.78 ng/L) in a water sample from Brownlee Reservoir. All Hg concentrations in water samples were less than the EPA Hg chronic aquatic life criterion in Idaho (12 ng/L). The EPA recommended a water-quality criterion of 0.30 milligrams per kilogram (mg/kg) methylmercury (MeHg) expressed as a fish-tissue residue value (wet-weight MeHg in fish tissue). MeHg residue in fish tissue is considered to be equivalent to total Hg in fish muscle tissue and is referred to as Hg in this report. The Idaho Department of Environmental Quality adopted the EPA’s fish-tissue criterion and a reasonable potential to exceed (RPTE) threshold 20 percent lower than the criterion or greater than 0.24 mg/kg based on an average concentration of 10 fish from a receiving waterbody. NPDES permitted discharge to waters with fish having Hg concentrations exceeding 0.24 mg/kg are said to have a reasonable potential to exceed the water-quality criterion and thus are subject to additional permit obligations, such as requirements for increased monitoring and the development of a Hg minimization plan. The Idaho Fish Consumption Advisory Program (IFCAP) issues fish advisories to protect general and sensitive populations of fish consumers and has developed an action level of 0.22 mg/kg wet weight Hg in fish tissue. Fish consumption advisories are water body- and species-specific and are used to advise of allowable fish consumption from specific water bodies. The geometric mean Hg concentration of 10 fish of a single species collected from a single water body (lake or stream) in Idaho is compared to the action level to determine if a fish consumption advisory should be issued. The U.S. Geological Survey collected and analyzed individual fillets of mountain whitefish ( Prosopium williamsoni ), smallmouth bass ( Micropterus dolomieu ), and channel catfish ( Ictalurus punctatus ) for Hg. The median Hg concentration of 0.32 mg/kg exceeded the Idaho water-quality criterion at the site in Brownlee Reservoir. Average Hg concentrations from Brownlee Reservoir (0.32 mg/kg) and the Boise River at mouth (0.33 mg/kg) exceeded the Hg RPTE threshold (>0.24 mg/kg). IFCAP action levels also were exceeded at the sites on Brownlee Reservoir and at the mouth of the Boise River. Median Hg concentrations in fish at the remaining four river sites were less than 0.20 mg/kg with average concentrations ranging from 0.14 to 0.21 mg/kg Hg. Selenium (Se) analysis also was conducted on one composite fish tissue sample per site to screen for general concentrations and to provide information for future risk assessments. Concentrations of Se ranged from 0.07 to 0.49 mg/kg wet weight; average concentrations were highest in smallmouth bass (0.40 mg/kg) and lowest in mountain whitefish (0.12 mg/kg).

Idaho;Oregon

Source-water susceptibility assessment in Texas—Approach and methodology

Public water systems provide potable water for the public's use. The Safe Drinking Water Act amendments of 1996 required States to prepare a source-water susceptibility assessment (SWSA) for each public water system (PWS). States were required to determine the source of water for each PWS, the origin of any contaminant of concern (COC) monitored or to be monitored, and the susceptibility of the public water system to COC exposure, to protect public water supplies from contamination. In Texas, the Texas Commission on Environmental Quality (TCEQ) was responsible for preparing SWSAs for the more than 6,000 public water systems, representing more than 18,000 surface-water intakes or groundwater wells. The U.S. Geological Survey (USGS) worked in cooperation with TCEQ to develop the Source Water Assessment Program (SWAP) approach and methodology. Texas' SWAP meets all requirements of the Safe Drinking Water Act and ultimately provides the TCEQ with a comprehensive tool for protection of public water systems from contamination by up to 247 individual COCs. TCEQ staff identified both the list of contaminants to be assessed and contaminant threshold values (THR) to be applied. COCs were chosen because they were regulated contaminants, were expected to become regulated contaminants in the near future, or were unregulated but thought to represent long-term health concerns. THRs were based on maximum contaminant levels from U.S. Environmental Protection Agency (EPA)'s National Primary Drinking Water Regulations. For reporting purposes, COCs were grouped into seven contaminant groups: inorganic compounds, volatile organic compounds, synthetic organic compounds, radiochemicals, disinfection byproducts, microbial organisms, and physical properties. Expanding on the TCEQ's definition of susceptibility, subject-matter expert working groups formulated the SWSA approach based on assumptions that natural processes and human activities contribute COCs in quantities that vary in space and time; that increased levels of COC-producing activities within a source area may increase susceptibility to COC exposure; and that natural and manmade conditions within the source area may increase, decrease, or have no observable effect on susceptibility to COC exposure. Incorporating these assumptions, eight SWSA components were defined: identification, delineation, intrinsic susceptibility, point- and nonpoint-source susceptibility, contaminant occurrence, area-of-primary influence, and summary components. Spatial datasets were prepared to represent approximately 170 attributes or indicators used in the assessment process. These primarily were static datasets (approximately 46 gigabytes (GB) in size). Selected datasets such as PWS surface-water-intake or groundwater-well locations and potential source of contamination (PSOC) locations were updated weekly. Completed assessments were archived, and that database is approximately 10 GB in size. SWSA components currently (2011) are implemented in the Source Water Assessment Program-Decision Support System (SWAP-DSS) computer software, specifically developed to produce SWSAs. On execution of the software, the components work to identify the source of water for the well or intake, assess intrinsic susceptibility of the water- supply source, assess susceptibility to contamination with COCs from point and nonpoint sources, identify any previous detections of COCs from existing water-quality databases, and summarize the results. Each water-supply source's susceptibility is assessed, source results are weighted by source capacity (when a PWS has multiple sources), and results are combined into a single SWSA for the PWS.'SWSA reports are generated using the software; during 2003, more than 6,000 reports were provided to PWS operators and the public. The ability to produce detailed or summary reports for individual sources, and detailed or summary reports for a PWS, by COC or COC group was a unique capability of SWAP-DSS. In 2004, the TCEQ began a rotating schedule for SWSA wherein one-third of PWSs statewide would be assessed annually, or sooner if protection-program activities deemed it necessary, and that schedule has continued to the present. Cooperative efforts by the TCEQ and the USGS for SWAP software maintenance and enhancements ended in 2011 with the TCEQ assuming responsibility for all tasks.

Texas

Nitrate-nitrogen and total phosphorus river loads

Nitrate-nitrogen and total phosphorus loads from the major rivers draining Illinois were updated through the 2021 water year (Figure 3.1). Beginning with the 2023 biennial update to the Illinois NLRS, nutrient loads were estimated using data from the U.S. Geological Survey continuous monitoring stations rather than the original Illinois EPA monitoring stations. To maintain consistency with previous biennial report updates, the loads from the new sites were rescaled to match the original drainage areas (Table 3.1). As before, the statewide nutrient load was estimated by summing the loads of the eight major rivers adjusting for out-of-state contributions and unmonitored areas.

Illinois

Palos Verdes Shelf oceanographic study; data report for observations December 2007–April 2008

Beginning in 1997, the Environmental Protection Agency (EPA) defined a contaminated section of the Palos Verdes Shelf region in southern California as a Superfund Site, initiating a continuing investigation of this area. The investigation involved the EPA, the U.S. Geological Survey (USGS), Science Applications International Corporation (SAIC), Los Angeles County Sanitation Districts (LACSD) data, and other allied agencies. In mid-2007, the Palos Verdes Shelf project team identified the need for additional data on the sediment properties and oceanographic conditions at the Palos Verdes Superfund Site and deployed seven bottom platforms, three subsurface moorings, and three surface moorings on the shelf. This additional data was needed to support ongoing modeling and feasibility studies and to improve our ability to model the fate of the effluent-affected deposit over time. It provided more detail on the spatial variability and magnitude of resuspension of the deposit during multiple storms that are expected to transit the region during a winter season. The operation began in early December 2007 and ended in early April 2008. The goal was to measure the sediment response (threshold of resuspension, suspended-sediment concentrations, and suspended-sediment transport rates) to bed stresses associated with waves and currents. Other objectives included determining the structure of the bottom boundary layer (BBL) relating nearbed currents with those measured at 10 m above bottom (mab) and comparing those with the long-term data from the LACSD Acoustic Doppler Current Profiler (ADCP) deployments for nearbed current speed and direction. Low-profile tripods with high-frequency ADCPs co-located with two of the large tripods were selected for this goal. This report describes the data obtained during the field program, the instruments and data-processing procedures used, and the archive that contains the data sets that have passed our quality-assurance procedures.

California

Occurrence and trends in the concentrations of fecal-indicator bacteria and the relation to field water-quality parameters in the Allegheny, Monongahela, and Ohio Rivers and selected tributaries, Allegheny County, Pennsylvania, 2001–09

The U.S. Geological Survey (USGS), in cooperation with the Allegheny County Health Department and Allegheny County Sanitary Authority, collected surface-water samples from the Allegheny, Monongahela, and Ohio Rivers and selected tributaries during the period 2001–09 to assess the occurrence and trends in the concentrations of fecal-indicator bacteria during both wet- and dry-weather conditions. A total of 1,742 water samples were collected at 52 main-stem and tributary sites. Quantifiable concentrations of Escherichia coli ( E. coli ) were reported in 1,667 samples, or 97.0 percent of 1,719 samples; concentrations in 853 samples (49.6 percent) exceeded the U.S. Environmental Protection Agency (EPA) recreational water-quality criterion of 235 colonies per 100 milliliters (col/100 mL). Quantifiable concentrations of fecal coliform (FC) bacteria were reported in 1,693 samples, or 98.8 percent of 1,713 samples; concentrations in 780 samples (45.5 percent) exceeded the Commonwealth of Pennsylvania water contact criterion of 400 col/100 mL. Quantifiable concentrations of enterococci bacteria were reported in 912 samples, or 87.5 percent of 1,042 samples; concentrations in 483 samples (46.4 percent) exceeded the EPA recreational water-quality criterion of 61 col/100 mL. The median percentage of samples in which bacteria concentrations exceeded recreational water-quality standards across all sites with five or more samples was 48 for E. coli , 43 for FC, and 75 for enterococci. E. coli , FC, and enterococci concentrations at main-stem sites had significant positive correlations with streamflow under all weather conditions, with rho values ranging from 0.203 to 0.598. Seasonal Kendall and logistic regression were evaluated to determine whether statistically significant trends were present during the period 2001–09. In general, Seasonal Kendall tests for trends in E. coli and FC bacteria were inconclusive. Results of logistic regression showed no significant trends in dry-weather exceedance of the standards; however, significant decreases in the likelihood that wet-weather E. coli and FC bacteria concentrations will exceed EPA recreational standards were found at the USGS streamgaging station Allegheny River at 9th Street Bridge. Nonparametric correlation analysis, including Spearman’s rho and the paired Prentice-Wilcoxon test, was used to screen for associations among fecal indicator bacteria concentrations and the field characteristics streamflow, water temperature, pH, specific conductance, dissolved-oxygen concentration, and turbidity.

Pennsylvania

Environmental monitoring of groundwater, surface water, and soil at the Ammonium Perchlorate Rocket Motor Destruction Facility at the Letterkenny Army Depot, Chambersburg, Pennsylvania, 2021

Letterkenny Army Depot in Chambersburg, Pennsylvania, built an Ammonium Perchlorate Rocket Motor Destruction (ARMD) Facility in 2016 to centralize rocket motor destruction and contain all waste during the destruction process. The U.S. Geological Survey has collected environmental samples from groundwater, surface water, and soils at ARMD since 2016. During 2021, samples were collected from four groundwater wells in September, one surface-water site in October, and five soil sites in November near the facility. Samples were analyzed for nutrients, trace metals, major ions, total volatile organic compounds, and perchlorate. Perchlorate was not detected in any 2021 samples. Groundwater results showed no constituents exceeded any U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL). Dissolved arsenic (As) was detected in one well above the reporting detection level (RDL) of 3 micrograms per liter (μg/L) at 5.4 μg/L but below its MCL of 10 μg/L. Dissolved iron (Fe) was the only inorganic constituent measured above an EPA secondary maximum contaminant level (SMCL). All groundwater samples collected in 2021 exceeded the Fe SMCL of 300 μg/L, with concentrations ranging from 390 μg/L to 3,500 μg/L. Surface-water data collected during 2021 showed no measured constituents in the surface-water sample that exceeded any EPA MCL or SMCL. Soil samples collected from 2016 through 2021 showed all concentrations of As exceeded the EPA soil screening levels of 3 milligrams per kilogram (mg/kg) but did not exceed the Pennsylvania medium-specific concentrations for As of 61 mg/kg. Arsenic concentrations in 2021 ranged from 9.1 mg/kg to 12.9 mg/kg. The 2021 results for the ARMD Facility indicate no increases in concentrations of reported compounds compared to data from 2016 to 2020. The contained burn treatment facility for demilitarization of rocket motors during 2021 appears to have operated without elevating concentrations of target compounds compared to previous years.

Pennsylvania

Concentrations of lead and other inorganic constituents in samples of raw intake and treated drinking water from the municipal water filtration plant and residential tapwater in Chicago, Illinois, and East Chicago, Indiana, July–December 2017

The U.S. Geological Survey (USGS) Environmental Health Mission Area (EHMA) is providing comprehensive science on sources, movement, and transformation of contaminants and pathogens in watershed and aquifer drinking-water supplies and in built water and wastewater infrastructure (referred to as the USGS Water and Wastewater Infrastructure project) in the Greater Chicago Area and elsewhere in the United States, to fill data gaps identified by stakeholders and collaborators in drinking water and public health. EHMA Water and Wastewater Infrastructure research specifically provides insight into natural factors in the environment as well as those water-infrastructure components and processes (such as source-water corrosivity, treatment, plumbing, and so forth) that might influence human exposure to chemical and microbial contaminants at the residential tap. This infrastructure-exposure research role is fulfilled uniquely by the USGS and not by the U.S. Environmental Protection Agency (EPA), other agencies, or municipalities that focus on regulatory and policy activities and related compliance. The USGS approach to assessing the possible links between human health and chemical contaminant and pathogen exposure in drinking water is conducted in collaboration with public health experts and includes comprehensive characterization of the presence/absence and concentrations of more than 500 organic and 27 inorganic chemical constituents at the point of use (tap). Laboratory results for lead and other inorganic contaminants in Chicago, Illinois, and East Chicago, Indiana, residential tapwater are being released to ensure the timely release of quality-assured data to participants in the study. Concentrations of lead and other inorganic constituents were assessed in drinking water at the point of use (kitchen tap or filter) in 45 residential locations and in two locations within each of the two Chicago water purification plants and the two East Chicago water filtration plants during July–December 2017. Three methods were used for analyzing lead. The most sensitive method had a reporting limit of 0.020 micrograms per liter (µg/L). When using the most sensitive analytical method, lead was detected in 39 of 45 residential tapwater samples, with concentrations ranging from less than 0.020 µg/L to 5.31 µg/L (median of the detected values = 0.481 µg/L). Concentrations of lead also were detected in Lake Michigan intake water at all water purification/filtration plant facilities at concentrations ranging from 0.083 to 0.330 µg/L, but were not detected above the reporting limit in any samples of treated, pre-distribution drinking water at any of the water purification/filtration plant facilities. Because the USGS Water and Wastewater Infrastructure project in the Greater Chicago Area is focused on the potential human exposure to a broad suite of organic and inorganic contaminants in drinking water and is not focused specifically on lead, the sampling protocol did not include “first-draw,” stagnant sampling and samples were collected with point-of-use treatment in place, if present. Thus, the lead results reported herein are not appropriate for assessment of compliance with the EPA 1991 Lead and Copper Rule. Information resources for lead mitigation and water filtration are provided.

Illinois, Indiana

Measurements of slope current and environmental geochemistry near the western boundary of the Gulf of the Farallones National Marine Sanctuary

For nearly a decade, dredged material from San Francisco Bay has been deposited at the U.S. Environmental Protection Agency (EPA) Region IX designated disposal site on the continental slope west of the Farallon Islands. Over the past several years, annual disposal volumes have ranged from 136,170 m3 (61 barge loads) to 2,407,600 m3 (1,173 barge loads) (Ota, personal communication, 2000). The EPA has conducted extensive studies to evaluate the fate and effects of the disposed material (Abdelrhman, 1992; Tetra-Tech, 1992; SAIC, 1992). The EPA has also maintained a long-term monitoring program to collect hydrodynamic, sedimentary, chemical, and biological data that are used to determine whether the dredged material adversely affects the ecology of adjacent water bodies and whether it moves from the disposal site, especially into the Gulf of the Farallones National Marine Sanctuary. As part of this monitoring program, the U.S. Geological Survey (USGS) Coastal and Marine Geology Program (CMGP) deployed arrays of instruments on three moorings near the EPA disposal site from November 1997 to November 1998. This report describes the results and findings of this field monitoring experiment.

California

Per- and polyfluoroalkyl substances in groundwater from the Great Miami buried-valley aquifer, southwestern Ohio, 2019–20

Groundwater samples were collected during 2019 and 2020 from 23 wells in the Great Miami buried-valley aquifer (GM-BVA) in southwestern Ohio by the U.S. Geological Survey, in cooperation with the Miami Conservancy District, Dayton, Ohio, to determine concentrations of selected per- and polyfluoroalkyl substances (PFAS). The GM-BVA is a glacial outwash and alluvial fill aquifer that is the sole source of water supply for much of the region. Wells had total depths that ranged from 21 to 101 feet below land surface, and groundwater levels that ranged from 1.39 to 52.15 feet below land surface before sampling in 2019. Groundwater and related quality-control samples were sequentially collected from 22 of the 23 wells and analyzed for 24 different PFAS by 2 methods that used proprietary isotope-dilution based adaptations of U.S. Environmental Protection Agency (EPA) method 537.1, termed methods 1 and 2. Method 2 had smaller reporting limits (RL) for 22 of 24 PFAS analyzed and smaller detection limits (DLs) for all 24 PFAS analyzed compared with method 1, which made method 2 more sensitive to detect PFAS. Concentrations of perfluorooctanesulfonate (PFOS) in a groundwater (GW)-method 2 sample from well CL–275 of 1.9 nanograms per liter (ng/L) and perfluorooctanoate (PFOA) in a GW-method 2 sample from well BU–1106 of 2.1 ng/L were greater than their EPA interim health advisory guidances for drinking water (as of June 2022) by about 9,500 and 52,500 percent, respectively. The EPA interim health advisory guidances for PFOS (0.02 ng/L) and PFOA (0.004 ng/L) were also 65 and 215 times less, respectively, than the smallest method 2 DLs for PFOS (1.3 ng/L) and PFOA (0.86 ng/L). Other PFAS were either not detected in GM-BVA groundwater samples or were detected in concentrations less than Ohio action levels or Federal health-risk-based guidance. The most detected PFAS in groundwater was perfluorobutanesulfonate (PFBS), which had concentrations in samples from eight wells that ranged from 1.0 to 8.0 ng/L or from 0.05 to 0.4 percent of its EPA health advisory of 2,000 ng/L for drinking water. The similarity of PFBS (7.8 ng/L), perfluoropentanesulfonate (PFPeS; 8.1 ng/L), and perfluorohexanesulfonate (PFHxS; 14 ng/L) concentrations yielded from the GW-method 1 sample from well CL–275 on July 9, 2019, to those of PFBS (8.0 ng/L), PFPeS (7.8 ng/L), and PFHxS (16 ng/L) from the paired GW-method 2 sample demonstrated the capability of both methods to reproduce PFAS concentrations that were greater than their respective DLs. Non-detection of these PFAS in follow-up GW-method 1 and sequential replicate (Rep–GW-method 1) samples from CL–275 on April 21, 2020, indicated that the 2019 results represented a transient detection in groundwater. Eleven of twenty-three wells sampled in 2019 had from 1 to 4 PFAS detected in one or more groundwater samples or in a paired replicate sample: PFBS in 8 wells and 9 samples; PFHxS in 4 wells and 5 samples; and PFPeS, PFOS, perfluorobutanoate, perfluoropentanoate, PFOA, and perfluorooctanesulfonamide in 1 well and 1 sample each. More PFAS were detected in GW-method 2 samples than GW-method 1 samples because method 2 had smaller RLs and DLs. Results indicate benefits from the analysis of paired samples, sequential replicate samples, and other quality-control samples using analytical methods with sensitive RLs and DLs to verify PFAS concentrations in groundwater. Groundwater-age estimates indicate that water produced from all sampled wells had infiltrated to the water table within the 1947–present (2022) period of PFAS use or environmental presence. Eight wells with detectable PFBS in groundwater from 2019 samples also had groundwater-recharge dates that ranged from 1991 to 2016. Those ages coincided with the possible environmental presence of PFBS as a PFAS byproduct or use as an alternative to PFOS after about 2002. Two wells that had detections of PFHxS in 2019 groundwater samples also had post-2000 groundwater-recharge dates that coincided with the period of use of PFHxS as an alternative to PFOS. Six of nine wells with more than 66-percent of urban land use that was within 0.3 miles of each well, as of 2012, also had 1 to 4 PFAS detected in one of their groundwater samples. Seven of nine wells that produced groundwater in 2019 with an oxic redox category also had one or more PFAS detected in a sample.

Ohio

Use of DNA markers for investigating sources of bacteria in contaminated ground water: Wooster Township, Wayne County, Ohio

In 2004, a public-health nuisance was declared by the Wayne County Board of Health in the Scenic Heights Drive-Batdorf Road area of Wooster Township, Wayne County, Ohio, because of concerns about the safety of water from local wells. Repeated sampling had detected the presence of fecal-indicator bacteria and elevated nitrate concentrations. In June 2006, the U.S. Geological Survey (USGS), in cooperation with the Ohio Environmental Protection Agency (Ohio EPA), collected and analyzed samples from some of the affected wells to help investigate the possibility of human-origin bacterial contamination. Water samples from 12 wells and 5 home sewage-treatment systems (HSTS) were collected. Bromide concentrations were determined in samples from the 12 wells. Samples from 5 of the 12 wells were analyzed for wastewater compounds. Total coliform, enterococci and Escherichia coli (E. coli) bacteria concentrations were determined for samples from 8 of the 12 wells. In addition, two microbial source-tracking tools that employ DNA markers were used on samples from several wells and a composite sample of water from five septic tanks. The DNA markers from the Enterococcus faecium species and the order Bacteroidales are associated with specific sources, either human or ruminant sources. Bromide concentrations ranged from 0.04 to 0.18 milligrams per liter (mg/L). No wastewater compounds were detected at concentrations above the reporting limits. Samples from the 12 wells also were collected by Ohio EPA and analyzed for chloride and nitrate. Chloride concentrations ranged from 12.6 to 61.6 mg/L and nitrate concentrations ranged from 2.34 to 11.9 mg/L (as N). Total coliforms and enterococci were detected in samples from 8 wells, at concentrations from 2 to 200 colony-forming units per 100 milliliters (CFU/100 mL) and 0.5 to 17 CFU/100 mL, respectively. E. coli were detected in samples from three of the eight wells, at concentrations of 1 or 2 CFU/100 mL. Tests for the human-specific marker of enterococci, the esp gene, were negative in the seven samples tested, including the composite sample of HSTS water. DNA with the general Bacteroidales marker was detected in samples from four wells, but the tests for both the human- and ruminant-associated markers were negative. The presence of the PCR (polymerase chain reaction) -detectable DNA for the general fecal Bacteroidales marker is indicative of fecal contamination and recently recharged water.

Ohio

Meeting report: knowledge and gaps in developing microbial criteria for inland recreational waters

The U.S. Environmental Protection Agency (EPA) has committed to issuing in 2012 new or revised criteria designed to protect the health of those who use surface waters for recreation. For this purpose, the U.S. EPA has been conducting epidemiologic studies to establish relationships between microbial measures of water quality and adverse health outcomes among swimmers. New methods for testing water quality that would provide same-day results will likely be elements of the new criteria. Although the epidemiologic studies upon which the criteria will be based were conducted at Great Lakes and marine beaches, the new water quality criteria may be extended to inland waters (IWs). Similarities and important differences between coastal waters (CWs) and IWs that should be considered when developing criteria for IWs were the focus of an expert workshop. Here, we summarize the state of knowledge and research needed to base IWs microbial criteria on sound science. Two key differences between CWs and IWs are the sources of indicator bacteria, which may modify the relationship between indicator microbes and health risk, and the relationship between indicators and pathogens, which also may vary within IWs. Monitoring using rapid molecular methods will require the standardization and simplification of analytical methods, as well as greater clarity about their interpretation. Research needs for the short term and longer term are described.

Environmental Health Perspectives

Wildlife in a chemical world

Snapping turtles were collected by the Ohio State EPA from six locations in Ohio believed to have different contaminant concentrations. Previously we reported significant correlations among four hepatic microsomal dealkylases and CYP1A in these turtles. Herein we compare ethoxyresorufin-O-dealkylase (EROD) and methoxyROD (MROD) to tissue contaminant concentrations. For Fifty-four of these turtles, muscle, fat body and liver tissues were assessed for PCBs and 20 organochlorine analytes and hepatic microsomal dealkylases. Of the contaminants analyzed, only DDE, dieldrin, oxychlordane, trans-nonachlor and PCB 1260 were detected in >25% of each sample type. When EROD and MROD activities were compared to tissue values for these contaminants, they were found to correlate significantly only to DDE, dieldrin and trans-nonachlor. For an 18 female subset of these turtles, serum PCBs and organochlorine pesticides, egg, fat body and liver dioxins and furans, and hepatic microsomal dealkylases were assessed. EROD and MROD both correlated significantly to serum PCB 105, PCB 138 and DDE, and to egg total PCBs. EROD and MROD did not correlate significantly with liver dioxins and furans, but there were significant correlations between EROD and egg and fat body dioxins and furans, and MROD and fat body dioxins and furans. It is expected that CYP1A-type inducers such as certain PCBs, and halogenated dioxins and furans, but not organochlorine pesticides, would be inducers in turtles. Presumably the correlation of monooxygenase with organochlorine pesticides is fortuitous, and toxic equivalencies are being calculated using a number of systems.

Society of Environmental Toxicology and Chemistry,