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Yuma Ridgway’s rail selenium exposure and occupancy within managed and unmanaged emergent marshes at the Salton Sea

Yuma Ridgway’s rail ( Rallus obsoletus yumanensis , hereafter, rail) is an endangered species for which patches of emergent marsh within the Salton Sea watershed comprise a substantial part of habitat for the species’ disjointed range in the southwestern United States. These areas of emergent marsh include (1) marshes managed by federal (particularly the U.S. Fish and Wildlife Service’s Sonny Bono Salton Sea National Wildlife Refuge), state (California Department of Fish and Wildlife), and local (Imperial Irrigation District) resource agencies that are sustained by direct deliveries of Colorado River water and (2) unmanaged marshes sustained by agricultural drainage water. Management of rail habitat in this arid environment is complicated by increasingly limited availability of unimpaired freshwater owing to water management decisions associated with the Quantification Settlement Agreement and risks posed by potentially harmful concentrations of selenium found in agricultural drainage water that can readily bioaccumulate in aquatic food webs. To provide timely science for managers, herein we report summary statistics for managed and unmanaged emergent marshes sampled at the Salton Sea during the rail breeding season of 2016 pertaining to (1) selenium concentrations in food webs representing dietary pathways of selenium exposure and (2) patterns of rail occupancy and inter-marsh movements, estimated abundance, and regional population size of rail. For selenium-specific objectives, we sampled unfiltered surface water, midge larvae (Chironomidae), water boatmen (Corixidae), mosquitofish ( Gambusia spp.), and crayfish (Astacidae). Selenium samples were collected from 15 fixed sampling points, each in managed and unmanaged marshes, during late February, April, and June 2016, which corresponded to rail pre-nesting, nesting, and fledgling reproductive life-stages, respectively. Two areas within the two treatment types (managed versus unmanaged marsh) were of particular interest to help assess risks associated with changing sea dynamics and different water-management strategies: (1) a large unmanaged marsh (Morton Bay) unintentionally created in approximately 2008 when it became separated from the Salton Sea as water inflows began to drop and a berm formed from accumulated sediment and (2) a restored marsh (HZ9A) managed by the Sonny Bono Salton Sea National Wildlife Refuge, which is currently supplied with Colorado River water but may be sustained in the future by a blend of clean (that is, low selenium) Colorado River and agricultural drainage water with higher selenium from the Alamo River. Hence, baseline data for these marshes are important for future management decisions. We also report selenium concentrations in rail blood, head feathers, and breast feathers from rails captured as part of the movement study. Results indicated relatively higher risks from dietary selenium exposure for rails occupying unmanaged marshes compared to managed marshes and similar risks among unmanaged marshes. However, risks also were potentially elevated for rails occupying some managed marshes (that is, the Hazard Marshes), where relatively high proportions of Chironomidae and mosquitofish exceeded dietary thresholds for selenium effects on avian reproduction. For rail-specific objectives, we quantified occupancy and spatial distribution using call count data analyzed with imperfect detection models. Imperfect detection models allowed us to jointly estimate detection probability and abundance of detected rails in association with habitats. We then used estimates of detection probability and abundance at the habitat level to extrapolate rail population abundance for the Salton Sea region. Inter- and intra-marsh movements were described from over 5,000 locations obtained from 15 radio-marked rails. Resultant space use patterns indicated that, in general, selenium risk to individuals is not equally shared because of high levels of territoriality and very limited movement throughout the landscape. Moreover, the largest contiguous blocks of habitat are associated with unmanaged marshlands located on the former southeastern shoreline and outside traditional management areas and authorities. Thus, a substantial proportion of the rail population that is using unmanaged marsh on the southeastern shoreline may have disproportionate risk of elevated selenium exposure, yet how that risk translates to population-level effects remains unknown.

California↗

A seasonal agricultural drought forecast system for food-insecure regions of East Africa

The increasing food and water demands of East Africa's growing population are stressing the region's inconsistent water resources and rain-fed agriculture. More accurate seasonal agricultural drought forecasts for this region can inform better water and agricultural management decisions, support optimal allocation of the region's water resources, and mitigate socio-economic losses incurred by droughts and floods. Here we describe the development and implementation of a seasonal agricultural drought forecast system for East Africa (EA) that provides decision support for the Famine Early Warning Systems Network's science team. We evaluate this forecast system for a region of equatorial EA (2° S to 8° N, and 36° to 46° E) for the March-April-May growing season. This domain encompasses one of the most food insecure, climatically variable and socio-economically vulnerable regions in EA, and potentially the world: this region has experienced famine as recently as 2011. To assess the agricultural outlook for the upcoming season our forecast system simulates soil moisture (SM) scenarios using the Variable Infiltration Capacity (VIC) hydrologic model forced with climate scenarios for the upcoming season. First, to show that the VIC model is appropriate for this application we forced the model with high quality atmospheric observations and found that the resulting SM values were consistent with the Food and Agriculture Organization's (FAO's) Water Requirement Satisfaction Index (WRSI), an index used by FEWS NET to estimate crop yields. Next we tested our forecasting system with hindcast runs (1993–2012). We found that initializing SM forecasts with start-of-season (5 March) SM conditions resulted in useful SM forecast skill (> 0.5 correlation) at 1-month, and in some cases at 3 month lead times. Similarly, when the forecast was initialized with mid-season (i.e. 5 April) SM conditions the skill until the end-of-season improved. This shows that early-season rainfall is critical for end-of-season outcomes. Finally we show that, in terms of forecasting spatial patterns of SM anomalies, the skill of this agricultural drought forecast system is generally greater (> 0.8 correlation) during drought years. This means that this system might be particularity useful for identifying the events that present the greatest risk to the region.

Hydrology and Earth System Sciences↗

Waterfowl density on agricultural fields managed to retain water in winter

Managed water on private and public land provides habitat for wintering waterfowl in the Mississippi Valley, where flood control projects have reduced the area of natural flooding. We compared waterfowl densities on rice, soybean, and moist-soil fields under cooperative agreements to retain water from 1 November through 28 February in Arkansas and Mississippi and assessed temporal changes in waterfowl density during winter in 1991-1992 and 1992-1993. Fields flooded earlier in Arkansas, but retained water later in Mississippi. Over winter, waterfowl densities decreased in Arkansas and increased in Mississippi. Densities of waterfowl, including mallard (Anas platyrhynchos), the most abundant species observed, were greatest on moist-soil fields. However, soybean fields had the greatest densities of northern shoveler (Spatula clypeata).

Wildlife Society Bulletin↗

Characterization of water use and water balance for the croplands of Kansas using satellite, climate, and irrigation data

Kansas is one of the most productive agricultural states in the United States, where agricultural irrigation is a primary user of underground and surface water. Because of low precipitation and declining groundwater levels in western and central Kansas, sustainable management of irrigation water resources is a critical issue in the agricultural productivity of the state. The objective of this study is to analyze and characterize the water use and water balance in the croplands of Kansas using satellite observations, meteorological data, and in situ irrigation water use records. We used actual evapotranspiration ( ETa ), precipitation, soil moisture, and irrigation water use to calculate water balance for Kansas in 2015 at scales of counties, climatic divisions, and groundwater management districts (GMD). The Operational Simplified Surface Energy Balance model was implemented to estimate 30-m resolution ETa . Results showed that the seasonal (May – September) precipitation, soil water storage change, and ETa are 528 mm, 80 mm, and 555 mm, respectively, on average of all croplands in the state. The annual net irrigation water consumption was 293 mm for irrigated croplands, indicating that irrigation water constitutes an substantial portion of the water supply in the state. The total volumetric irrigation water use was 3.24 km 3 for all croplands within five GMDs in western and south-central Kansas, while only 0.38 km 3 was outside of GMDs. The multiple regression models of ETa against precipitation and irrigation water use were statistically significant with R 2 values of 0.71 and 0.87, respectively, at county and climate division scales. Regression models also indicated a higher rate of ETa response to irrigation water use than that to precipitation. Our study demonstrated the spatial patterns of crop water use and water balance in Kansas, which could provide useful information for management of irrigation agriculture and water resources for the state.

Kansas↗

Estimating irrigation water demand using an improved method and optimizing reservoir operation for water supply and hydropower generation: a case study of the Xinfengjiang reservoir in southern China

The ever-increasing demand for water due to growth of population and socioeconomic development in the past several decades has posed a worldwide threat to water supply security and to the environmental health of rivers. This study aims to derive reservoir operating rules through establishing a multi-objective optimization model for the Xinfengjiang (XFJ) reservoir in the East River Basin in southern China to minimize water supply deficit and maximize hydropower generation. Additionally, to enhance the estimation of irrigation water demand from the downstream agricultural area of the XFJ reservoir, a conventional method for calculating crop water demand is improved using hydrological model simulation results. Although the optimal reservoir operating rules are derived for the XFJ reservoir with three priority scenarios (water supply only, hydropower generation only, and equal priority), the river environmental health is set as the basic demand no matter which scenario is adopted. The results show that the new rules derived under the three scenarios can improve the reservoir operation for both water supply and hydropower generation when comparing to the historical performance. Moreover, these alternative reservoir operating policies provide the flexibility for the reservoir authority to choose the most appropriate one. Although changing the current operating rules may influence its hydropower-oriented functions, the new rules can be significant to cope with the increasingly prominent water shortage and degradation in the aquatic environment. Overall, our results and methods (improved estimation of irrigation water demand and formulation of the reservoir optimization model) can be useful for local watershed managers and valuable for other researchers worldwide.

Xinfengjiang Reservoir↗

Role of solute-transport models in the analysis of groundwater salinity problems in agricultural areas

Undesirable salinity increases occur in both groundwater and surface water and are commonly related to agricultural practices. Groundwater recharge from precipitation or irrigation will transport and disperse residual salts concentrated by evapotranspiration, salts leached from soil and aquifer materials, as well as some dissolved fertilizers and pesticides. Where stream salinity is affected by agricultural practices, the increases in salt load usually are attributable mostly to a groundwater component of flow. Thus, efforts to predict, manage, or control stream salinity increases should consider the role of groundwater in salt transport. Two examples of groundwater salinity problems in Colorado, U.S.A., illustrate that a model which simulates accurately the transport and dispersion of solutes in flowing groundwater can be (1) a valuable investigative tool to help understand the processes and parameters controlling the movement and fate of the salt, and (2) a valuable management tool for predicting responses and optimizing the development and use of the total water resource.

Colorado↗

Deep subsurface drip irrigation using coal-bed sodic water: part I. water and solute movement

Water co-produced with coal-bed methane (CBM) in the semi-arid Powder River Basin of Wyoming and Montana commonly has relatively low salinity and high sodium adsorption ratios that can degrade soil permeability where used for irrigation. Nevertheless, a desire to derive beneficial use from the water and a need to dispose of large volumes of it have motivated the design of a deep subsurface drip irrigation (SDI) system capable of utilizing that water. Drip tubing is buried 92 cm deep and irrigates at a relatively constant rate year-round, while evapotranspiration by the alfalfa and grass crops grown is seasonal. We use field data from two sites and computer simulations of unsaturated flow to understand water and solute movements in the SDI fields. Combined irrigation and precipitation exceed potential evapotranspiration by 300-480 mm annually. Initially, excess water contributes to increased storage in the unsaturated zone, and then drainage causes cyclical rises in the water table beneath the fields. Native chloride and nitrate below 200 cm depth are leached by the drainage. Some CBM water moves upward from the drip tubing, drawn by drier conditions above. Chloride from CBM water accumulates there as root uptake removes the water. Year over year accumulations indicated by computer simulations illustrate that infiltration of precipitation water from the surface only partially leaches such accumulations away. Field data show that 7% and 27% of added chloride has accumulated above the drip tubing in an alfalfa and grass field, respectively, following 6 years of irrigation. Maximum chloride concentrations in the alfalfa field are around 45 cm depth but reach the surface in parts of the grass field, illustrating differences driven by crop physiology. Deep SDI offers a means of utilizing marginal quality irrigation waters and managing the accumulation of their associated solutes in the crop rooting zone.

Wyoming↗

Indicators of streamflow alteration, habitat fragmentation, impervious cover, and water quality for Massachusetts stream basins

Massachusetts streams and stream basins have been subjected to a wide variety of human alterations since colonial times. These alterations include water withdrawals, treated wastewater discharges, construction of onsite septic systems and dams, forest clearing, and urbanization—all of which have the potential to affect streamflow regimes, water quality, and habitat integrity for fish and other aquatic biota. Indicators were developed to characterize these types of potential alteration for subbasins and groundwater contributing areas in Massachusetts. The potential alteration of streamflow by the combined effects of withdrawals and discharges was assessed under two water-use scenarios. Water-use scenario 1 incorporated publicly reported groundwater withdrawals and discharges, direct withdrawals from and discharges to streams, and estimated domestic-well withdrawals and septic-system discharges. Surface-water-reservoir withdrawals were excluded from this scenario. Water-use scenario 2 incorporated all the types of withdrawal and discharge included in scenario 1 as well as withdrawals from surface-water reservoirs—all on a long-term, mean annual basis. All withdrawal and discharge data were previously reported to the State for the 2000–2004 period, except domestic-well withdrawals and septic-system discharges, which were estimated for this study. The majority of the state’s subbasins and groundwater contributing areas were estimated to have relatively minor (less than 10 percent) alteration of streamflow under water-use scenario 1 (seasonally varying water use; no surface-water-reservoir withdrawals). However, about 12 percent of subbasins and groundwater contributing areas were estimated to have extensive alteration of streamflows (greater than 40 percent) in August; most of these basins were concentrated in the outer metropolitan Boston region. Potential surcharging of streamflow in August was most commonly indicated for main-stem river subbasins, although surcharging was also indicated for some smaller tributary subbasins. In the high-flow month of April, only 4.8 percent of subbasins and groundwater contributing areas had more than 10 percent potential flow alteration. A majority of the state’s subbasins and groundwater contributing areas were also indicated to have relatively minor alteration of streamflow under water-use scenario 2 (long-term average water use, including surface-water-reservoir withdrawals). Extensive alteration of mean annual flows was estimated for about 6 percent of the state’s subbasins and groundwater contributing areas. The majority of subbasins estimated to have extensive long-term flow alteration contained reservoirs that were specifically designed, constructed, and managed to supply drinking water to cities. Only a small number of subbasins and groundwater contributing areas (1 percent) were extensively surcharged on a long-term, mean annual basis. Because site-specific data concerning surface-water-reservoir storage dynamics and management practices are not available statewide, the seasonal effects of surface-water-reservoir withdrawals on downstream flows could not be assessed in this study. The impounded storage ratio (volume of impounded subbasin or groundwater-contributing-area storage divided by mean annual predevelopment outflow from the subbasin or contributing area, in units of days) indicates the potential for alteration of streamflow, sediment-transport, and temperature regimes by dams, independent of water use. Storage ratios were less than 1 day for 33 percent of the subbasins and groundwater contributing areas, greater than 1 month for about 40 percent of the cases, and greater than 1 year for 3.2 percent of the cases statewide. Dam density, an indicator of stream-habitat fragmentation by dams, averaged 1 dam for every 6.7 stream miles statewide. Many of these dams are not presently (2009) being managed. The highest dam densities were in portions of Worcester County and in the Plymouth-Carver region, respectively, reflecting the historical reliance of Massachusetts industry upon water power and agricultural water-management practices in southeastern Massachusetts. Impervious cover is a frequently used indicator of urban land use. About 33 percent of the state’s 1,429 subbasins and groundwater contributing areas are relatively undeveloped at the local scale, with a local impervious cover of less than 4 percent. About 18 percent of Massachusetts subbasins and contributing areas are highly developed, with a local impervious cover greater than 16 percent. The remaining 49 percent of subbasins and contributing areas have levels of urban development between these extremes (4 to 16 percent local impervious cover). Cumulative impervious cover, defined for the entire upstream area encompassed by each subbasin, shows a smaller range (0 to 55 percent) than local impervious cover. Both local and cumulative impervious cover were highest in metropolitan Boston and other urban centers. High elevated impervious-cover values were also found along major transportation corridors. The water-quality status of Massachusetts streams is assessed periodically by the Massachusetts Department of Environmental Protection pursuant to the requirements of the Federal Clean Water Act. Streams selected for assessment are commonly located in larger subbasins where some degree of impairment is expected. In the 72 percent of the state’s subbasins and groundwater contributing areas with assessed streams in 2002, more than 50 percent of the assessed stream miles were considered impaired. All of the assessed stream miles were considered impaired in 66 percent of the subbasins and groundwater contributing areas with assessed streams. Large streams, such as the main stems of rivers that make up most of the assessed stream miles, also are in many cases the receiving waters for treated wastewater discharges and for this reason may be more susceptible to water-quality impairments than smaller streams. Subbasins and contributing areas with large fractions of assessed stream miles that are listed as impaired are distributed across the state, but are more prevalent in eastern Massachusetts.

Massachusetts↗

Eutrophication study at the Panjiakou-Daheiting Reservoir system, northern Hebei Province, People's Republic of China: Chlorophyll-a model and sources of phosphorus and nitrogen

Concentrations, loads, and sources of nitrate and total phosphorus were investigated at the Panjiakou and Daheiting Reservoir system in northern Hebei Province, People's Republic of China. The Luan He River is the primary source of water to these reservoirs, and the upstream watershed has a mix of land uses including agriculture, forest, and one large urban center. The reservoirs have a primary use for storage of drinking water and partially supply Tianjin City with its annual needs. Secondary uses include flood control and aqua culture (fish cages). The response of the reservoir system from phosphorus input, with respect to chlorophyll- a production from algae, was fitted to a model of normalized phosphorus loading that regresses the average summer-time chlorophyll- a concentration to the average annual phosphorus concentration of the reservoir. Comparison of the normalized phosphorus loading and chlorophyll- a response of this system to other reservoirs throughout the world indicate a level of eutrophication that will require up to an approximate 5–10-fold decrease in annual phosphorus load to bring the system to a more acceptable level of algal productivity. Isotopes of nitrogen and oxygen in dissolved nitrate were measured from the headwater streams and at various locations along the major rivers that provide the majority of water to these reservoirs. Those isotopic measurements indicate that the sources of nitrate change from natural background in the rivers to animal manure and septic waste upstream of the reservoir. Although the isotopic measurements suggest that animal and septic wastes are a primary source of nutrients, measurements of the molar ratio of nitrogen to phosphorus are more indicative of row-cropping practices. Options for reduction of nutrient loads include changing the management practices of the aqua culture, installation of new sewage treatment systems in the large urbanized area of the upper watershed, and agricultural management practices that would reduce the loading of nutrients and soil erosion from that land use.

Agricultural Water Management↗

Central Valley Hydrologic Model version 2 (CVHM2): Decision support tool for groundwater and land subsidence management

The San Joaquin Valley (SJV) of California is one of the world’s most productive agricultural regions. Reliance on groundwater has led to some of the greatest rates of human-induced land subsidence in the world in the 20th century, as well as more recently. The United States Geological Survey (USGS) has recently developed an integrated surface–subsurface hydrologic model, the Central Valley Hydrologic Model 2 (CVHM2), that represents the major components of the hydrologic system of California’s Central Valley. In this study, CVHM2 was applied as a decision support tool while simulating various management strategies to mitigate the land subsidence caused by the extraction of groundwater. CVHM2 was extended through to 2073 and applied to simulate management scenarios in terms of three primary drivers and their impact on subsidence along the Delta–Mendota Canal (DMC), a critical piece of infrastructure in the western SJV. The drivers considered were agricultural water demands, managed aquifer recharge (MAR), and changes in future climate. The results show that future subsidence is most sensitive to water demands, second most sensitive to future changes in climate, and relatively insensitive to MAR when it is applied as a surface application in the western SJV. However, we demonstrate via proof-of-concept scenarios that the MAR is capable of arresting subsidence when implemented via injection below the Corcoran Clay Member of the Tulare Formation instead of as a surface application. We also examine the uncertainty that is the result of climate variability and how to use the tool to identify the most appropriate strategies to constrain future subsidence to acceptable levels.

California↗

Enhancing the Simplified Surface Energy Balance (SSEB) Approach for Estimating Landscape ET: Validation with the METRIC model

Evapotranspiration (ET) can be derived from satellite data using surface energy balance principles. METRIC (Mapping EvapoTranspiration at high Resolution with Internalized Calibration) is one of the most widely used models available in the literature to estimate ET from satellite imagery. The Simplified Surface Energy Balance (SSEB) model is much easier and less expensive to implement. The main purpose of this research was to present an enhanced version of the Simplified Surface Energy Balance (SSEB) model and to evaluate its performance using the established METRIC model. In this study, SSEB and METRIC ET fractions were compared using 7 Landsat images acquired for south central Idaho during the 2003 growing season. The enhanced SSEB model compared well with the METRIC model output exhibiting an r2 improvement from 0.83 to 0.90 in less complex topography (elevation less than 2000 m) and with an improvement of r2 from 0.27 to 0.38 in more complex (mountain) areas with elevation greater than 2000 m. Independent evaluation showed that both models exhibited higher variation in complex topographic regions, although more with SSEB than with METRIC. The higher ET fraction variation in the complex mountainous regions highlighted the difficulty of capturing the radiation and heat transfer physics on steep slopes having variable aspect with the simple index model, and the need to conduct more research. However, the temporal consistency of the results suggests that the SSEB model can be used on a wide range of elevation (more successfully up 2000 m) to detect anomalies in space and time for water resources management and monitoring such as for drought early warning systems in data scarce regions. SSEB has a potential for operational agro-hydrologic applications to estimate ET with inputs of surface temperature, NDVI, DEM and reference ET.

Agricultural Water Management↗

Satellite remote sensing of crop water use across the Missouri River Basin for 1986–2018 period

Understanding historical crop water use (CWU) dynamics is important to improve land and water management. In this study, well-validated (coefficient of determination = 0.91, percent bias = 4%, and percent root mean square error = 11.8%) Landsat-based actual evapotranspiration (ETa) time-series estimations were used to (1) assess summer season CWU (CWU-Su) dynamics, (2) investigate CWU-Su trends over the study period (1986–2018; 33 years) at the regional- and pixel-scales, and (3) attribute CWU-Su driving factors across Missouri River Basin. Spatial variability of the ETa estimations along with the observed bimodal probability density distribution of ETa highlighted a strong relation between land cover and water uses across the basin. The bimodal distribution of ETa also indicated the presence of two major landcovers in the basin. The drier foothill regions in northwestern Missouri River Basin, dominated by grassland/shrubland, showed lower ETa (< 500 mm/year), whereas cropland dominated regions in lower semi-humid basin and forested subbasins exhibited higher ETa (> 600 mm/year). The CWU-Su anomalies revealed the vulnerability of the basin to year-to-year weather conditions. The CWU-Su trend analysis revealed a significant positive trend (p < 0.1) at the regional-scale affecting 30% of basin’s cropland pixels. The cropland pixels under positive CWU-Su trend were found to be clustered in the eastern and central Missouri River Basin as a result of the combined effect of increased crop production area, increased crop yields, crop practice shifts to higher biomass crops, and increased irrigated land. The effect of improved irrigation and water management practices on reducing CWU-Su was observed in western Missouri River Basin, which had a stable major crop throughout the study period. Overall, the study highlights the usefulness of Landsat imagery and remote sensing-based ETa modeling approaches in generating historical time-series ETa maps over a wide range of elevation, vegetation, and climate.

Missouri River Basin↗

Assessing the accuracy of OpenET satellite-based evapotranspiration data to support water resource and land management applications

Remotely sensed evapotranspiration (ET) data offer strong potential to support data-driven approaches for sustainable water management. However, practitioners require robust and rigorous accuracy assessments of such data. The OpenET system, which includes an ensemble of six remote sensing models, was developed to increase access to field-scale (30 m) ET data for the contiguous United States. Here we compare OpenET outputs against data from 152 in situ stations, primarily eddy covariance flux towers, deployed across the contiguous United States. Mean absolute error at cropland sites for the OpenET ensemble value is 15.8 mm per month (17% of mean observed ET), mean bias error is −5.3 mm per month (6%) and r 2 is 0.9. Results for shrublands and forested sites show higher inter-model variability and lower accuracy relative to croplands. High accuracy and multi-model convergence across croplands demonstrate the utility of a model ensemble approach, and enhance confidence among ET data practitioners, including the agricultural water resource management community.

Nature Water↗

Residence time, chemical and isotopic analysis of nitrate in the groundwater and surface water of a small agricultural watershed in the Coastal Plain, Bucks Branch, Sussex County, Delaware

Nitrate is a common contaminant in groundwater and surface water throughout the Nation, and water-resource managers need more detailed small-scale watershed research to guide conservation efforts aimed at improving water quality. Concentrations of nitrate in Bucks Branch are among the highest in the state of Delaware and a scientific investigation was performed to provide water-quality information to assist with the management of agriculture and water resources. A combination of major-ion chemistry, nitrogen isotopic composition and age-dating techniques was used to estimate the residence time and provide a chemical and isotopic analysis of nitrate in the groundwater in the surficial aquifer of the Bucks Branch watershed in Sussex County, Delaware. The land use was more than 90 percent agricultural and most nitrogen inputs were from manure and fertilizer. The apparent median age of sampled groundwater is 18 years and the estimated residence time of groundwater contributing to the streamflow for the entire Bucks Branch watershed at the outlet is approximately 19 years. Concentrations of nitrate exceeded the U.S. Environmental Protection Agency drinking-water standard of 10 milligrams per liter (as nitrogen) in 60 percent of groundwater samples and 42 percent of surface-water samples. The overall geochemistry in the Bucks Branch watershed indicates that agriculture is the predominant source of nitrate contamination and the observed patterns in major-ion chemistry are similar to those observed in other studies on the Mid-Atlantic Coastal Plain. The pattern of enrichment in nitrogen and oxygen isotopes (δ15N and δ18O) of nitrate in groundwater and surface water indicates there is some loss of nitrate through denitrification, but this process is not sufficient to remove all of the nitrate from groundwater discharging to streams, and concentrations of nitrate in streams remain elevated.

Delaware↗

Infrared remote sensing for monitoring rainfall

Evaluations of thermal infrared satellite data from TIROS-N and the Heat Capacity Mapping Mission (HCMM) showed that rainfall distribution patterns could be reliably detected on images acquired up to at least three days after the event. The temperature relationship decreased eight days after the event when soil variations influenced the signal. A time-series analysis reduced thermal variability normally observed over diverse landscapes and increased the sensitivity of the procedures. The method of repetitive low-resolution thermal observations could be operationally employed over large geographic regions with currently available satellite systems. The results would augment the existing rain gauge stations by increasing the spatial sensitivity and the reliability of detection and mapping individual rainfall events.

Agricultural Water Management↗

Distillation irrigation: A low-energy process for coupling water purification and drip irrigation

A method is proposed for combining solar distillation and drip irrigation to simultaneously desalinize water and apply this water to row crops. In this paper, the basic method is illustrated by a simple device constructed primarily of sheets of plastic, which uses solar energy to distill impaired water and apply the distillate to a widely spaced row crop. To predict the performance of the proposed device, an empirical equation for distillate production, dp , is developed from reported solar still production rates, and a modified Jensen-Haise equation is used to calculate the potential evapotranspiration, et , for a row crop. Monthly values for et and dp are calculated by using a generalized row crop at five locations in the Western United States. Calculated et values range from 1 to 22 cm month −1 and calculated dp values range from 2 to 11 cm month −1 , depending on the location, the month, and the crop average. When the sum of dp plus precipitation, dp + P , is compared to et for the case of 50% distillation irrigation system coverage, the results indicate that the crop's et is matched by dp + P , at the cooler locations only. However, when the system coverage is increased to 66%, the crop's et is matched by dp + P even at the hottest location. Potential advantages of distillation irrigation include the ability: (a) to convert impaired water resources to water containing no salts or sediments; and (b) to efficiently and automatically irrigate crops at a rate that is controlled primarily by radiation intensities. The anticipated disadvantages of distillation irrigation include: (a) the high costs of a system, due to the large amounts of sheeting required, the short lifetime of the sheeting, and the physically cumbersome nature of a system; (b) the need for a widely spaced crop to reduce shading of the system by the crop; and (c) the production of a concentrated brine or precipitate, requiring proper off-site disposal.

Agricultural Water Management↗

Deep subsurface drip irrigation using coal-bed sodic water: part II. geochemistry

Waters with low salinity and high sodium adsorption ratios (SARs) present a challenge to irrigation because they degrade soil structure and infiltration capacity. In the Powder River Basin of Wyoming, such low salinity (electrical conductivity, EC 2.1 mS cm -1 ) and high-SAR (54) waters are co-produced with coal-bed methane and some are used for subsurface drip irrigation(SDI). The SDI system studied mixes sulfuric acid with irrigation water and applies water year-round via drip tubing buried 92 cm deep. After six years of irrigation, SAR values between 0 and 30 cm depth (0.5-1.2) are only slightly increased over non-irrigated soils (0.1-0.5). Only 8-15% of added Na has accumulated above the drip tubing. Sodicity has increased in soil surrounding the drip tubing, and geochemical simulations show that two pathways can generate sodic conditions. In soil between 45-cm depth and the drip tubing, Na from the irrigation water accumulates as evapotranspiration concentrates solutes. SAR values >12, measured by 1:1 water-soil extracts, are caused by concentration of solutes by factors up to 13. Low-EC (<0.7 mS cm -1 ) is caused by rain and snowmelt flushing the soil and displacing ions in soil solution. Soil below the drip tubing experiences lower solute concentration factors (1-1.65) due to excess irrigation water and also contains relatively abundant native gypsum (2.4 &plusmn; 1.7 wt.%). Geochemical simulations show gypsum dissolution decreases soil-water SAR to <7 and increases the EC to around 4.1 mS cm-1, thus limiting negative impacts from sodicity. With sustained irrigation, however, downward flow of excess irrigation water depletes gypsum, increasing soil-water SAR to >14 and decreasing EC in soil water to 3.2 mS cm-1. Increased sodicity in the subsurface, rather than the surface, indicates that deep SDI can be a viable means of irrigating with sodic waters.

Wyoming↗

Climate, water use, and land surface transformation in an irrigation intensive watershed - streamflow responses from 1950 through 2010

Climatic variability and land surface change have a wide range of effects on streamflow and are often difficult to separate. We analyzed long-term records of climate, land use and land cover, and re-constructed the water budget based on precipitation, groundwater levels, and water use from 1950 through 2010 in the Cimarron&ndash;Skeleton watershed and a portion of the Cimarron&ndash;Eagle Chief watershed in Oklahoma, an irrigation-intensive agricultural watershed in the Southern Great Plains, USA. Our results show that intensive irrigation through alluvial aquifer withdrawal modifies climatic feedback and alters streamflow response to precipitation. Increase in consumptive water use was associated with decreases in annual streamflow, while returning croplands to non-irrigated grasslands was associated with increases in streamflow. Along with groundwater withdrawal, anthropogenic-induced factors and activities contributed nearly half to the observed variability of annual streamflow. Streamflow was more responsive to precipitation during the period of intensive irrigation between 1965 and 1984 than the period of relatively lower water use between 1985 and 2010. The Cimarron River is transitioning from a historically flashy river to one that is more stable with a lower frequency of both high and low flow pulses, a higher baseflow, and an increased median flow due in part to the return of cropland to grassland. These results demonstrated the interrelationship among climate, land use, groundwater withdrawal and streamflow regime and the potential to design agricultural production systems and adjust irrigation to mitigate impact of increasing climate variability on streamflow in irrigation intensive agricultural watershed.

Kansas, Oklahoma↗