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USGS1999

A plan for assessing the occurrence and distribution of methyl tert-butyl ether and other volatile organic compounds in drinking water and ambient ground water in the Northeast and Mid-Atlantic regions of the United States

A plan to assess the occurrence and distribution of methyl tert-butyl ether (MTBE) and other volatile organic compounds (VOCs) in drinking water and ambient ground water in the Northeast and Mid-Atlantic regions of the United States was designed to meet two primary objectives. This study will provide the U.S. Environmental Protection Agency with information on potential human exposure to MTBE and other VOCs from drinking water. In addition, the study will further the goals of the U.S. Geological Survey's (USGS) National Water Quality Assessment Program (NAWQA) by providing additional information on the occurrence and distribution of VOCs in ambient ground water beneath a large, highly urbanized part of the Nation. The study will proceed in two phases-a drinking-water assessment (phase 1) and an ambient ground-water assessment (phase 2). The drinking-water assessment will involve compilation, review, and analysis of available water- quality and ancillary data for approximately 20 percent of the community water systems in 12 States in the Northeast and Mid-Atlantic regions. This effort will summarize the occurrence and distribution of MTBE and other VOCs in drinking water supplied by 2,110 community water systems. The ambient ground-water assessment will involve compilation, review, and analysis of data on MTBE and other VOCs from previous USGS studies in the 12-State area, including regional water-quality assessments conducted for the USGS's NAWQA, plus other available State or local datasets. These data will be related, to the extent allowed by the completeness and quality of the data, to land-use patterns, population density, and other anthropogenic and natural factors using statistical tests. The occurrence and distribution of MTBE and other VOCs in ambient ground water and, to the extent possible, drinking water in relation to such factors, will be evaluated.

Open-File Report↗

USGS2006

Occurrence of trihalomethanes in the nation's ground water and drinking-water supply wells, 1985-2002

This report describes the occurrence of trihalomethanes (THMs) in the Nation's ground water and drinking-water supply wells based on analysis of 5,642 samples of untreated ground water and source water collected or compiled during 1985-2002 by the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program. THMs are a group of volatile organic compounds (VOCs) with natural and anthropogenic sources that are of interest because they are associated with acute and chronic health problems in humans. THMs occur in water primarily from chlorination and are classified as disinfection by-products. In this report, the four THMs are discussed in the order of chloroform, bromodichloromethane, dibromochloromethane, and then bromoform; this sequence corresponds to largest to smallest chlorine content and smallest to largest bromine content. Four trihalomethanes were detected in less than 20 percent of samples from studies of (1) aquifers, (2) shallow ground water in agricultural areas, (3) shallow ground water in urban areas, (4) domestic wells, and (5) public wells. Detection frequencies for individual THMs in the five studies ranged from zero for shallow ground water in agricultural areas to 19.5 percent for shallow ground water in urban areas. None of the samples from aquifer studies, domestic wells, or public wells had total THM concentrations (the sum of the concentrations of chloroform, bromodichloromethane, dibromochloromethane, and bromoform) greater than or equal to the U.S. Environmental Protection Agency Maximum Contaminant Level of 80 micrograms per liter (?g/L). Comparisons of results among studies of aquifers, shallow ground water in agricultural areas, and shallow ground water in urban areas were used to describe the occurrence of the four THMs in ground water for three different land-use settings-mixed, agricultural, and urban, respectively. At the 0.2-?g/L assessment level, one or more of the four THMs were detected in 7.9 percent of the samples from aquifer studies, 2.2 percent of the samples from shallow ground water in agricultural areas, and 19.5 percent of the samples from shallow ground water in urban areas. In general, detection frequencies and concentrations of the four THMs were greater in shallow ground water in urban areas compared to aquifer studies and to shallow ground water in agricultural areas. For all three of these studies, the most common two-THM mixture at the 0.2-?g/L assessment level was chloroform-bromodichloromethane, and this was the only two-THM mixture found in samples of shallow ground water in agricultural areas. Comparisons of results between studies of domestic wells and public wells were used to describe the occurrence of the four THMs in two different supplies of ground water used for drinking water. At the 0.2-?g/L assessment level, one or more of the four THMs were detected in 5.2 percent of the domestic well samples and in 14.7 percent of the public well samples. In general, detection frequencies and THM concentrations were greater in samples from public wells than from domestic wells. At the 0.2-?g/L assessment level, the six possible two-THM mixtures occurred about six times more frequently in samples from public wells than from domestic wells. One of the most common two-THM mixtures in samples from domestic and public wells was bromodichloromethane-dibromochloromethane. Detection frequency is associated with the chlorine content of the THM compound. In general, for each of the five studies, as the chlorine content of the THM compound decreased, the detection frequency at the 0.2-?g/L assessment level also decreased. The exception was the study of public wells in which the detection frequency of the THMs decreased in the following order: chloroform, bromoform, dibromochloromethane, and bromodichloromethane. At the 0.2-?g/L assessment level, the median concentration for one or more of the four THMs ranged from 0.3 ?g/L (shallow ground water in agricultural a

Scientific Investigations Report↗

USGS2021

Is there an urban pesticide signature? Urban streams in five U.S. regions share common dissolved-phase pesticides but differ in predicted aquatic toxicity

Pesticides occur in urban streams globally, but the relation of occurrence to urbanization can be obscured by regional differences. In studies of five regions of the United States, we investigated the effect of region and urbanization on the occurrence and potential toxicity of dissolved pesticide mixtures. We analyzed 225 pesticide compounds in weekly discrete water samples collected during 6–12 weeks from 271 wadable streams; development in these basins ranged from undeveloped to highly urbanized. Sixteen pesticides were consistently detected in 16 urban centers across the five regions—we propose that these pesticides comprise a suite of urban signature pesticides (USP) that are all common in small U.S. urban streams. These USPs accounted for the majority of summed maximum pesticide concentrations at urban sites within each urban center. USP concentrations, mixture complexity, and potential toxicity increased with the degree of urbanization in the basin. Basin urbanization explained the most variability in multivariate distance-based models of pesticide profiles, with region always secondary in importance. The USPs accounted for 83% of pesticides in the 20 most frequently occurring 2-compound unique mixtures at urban sites, with carbendazim+prometon the most common. Although USPs were consistently detected in all regions, detection frequencies and concentrations varied by region, conferring differences in potential aquatic toxicity. Potential toxicity was highest for invertebrates (benchmarks exceeded in 51% of urban streams), due most often to the neonicotinoid insecticide imidacloprid and secondarily to organophosphate insecticides and fipronil. Benchmarks were rarely exceeded in urban streams for plants (at 3% of sites) or fish (<1%). We propose that the USPs identified here would make logical core (nonexclusive) constituents for monitoring dissolved pesticides in U.S. urban streams, and that unique mixtures containing imidacloprid, fipronil, and carbendazim are priority candidates for mixtures toxicity testing.

Science of the Total Environment↗

USGS2002

Spatial and temporal variability of trace element concentrations in an urban subtropical watershed, Honolulu, Hawaii

Trace metal concentrations in soils and in stream and estuarine sediments from a subtropical urban watershed in Hawaii are presented. The results are placed in the context of historical studies of environmental quality (water, soils, and sediment) in Hawaii to elucidate sources of trace elements and the processes responsible for their distribution. This work builds on earlier studies on sediments of Ala Wai Canal of urban Honolulu by examining spatial and temporal variations in the trace elements throughout the watershed. Natural processes and anthropogenic activity in urban Honolulu contribute to spatial and temporal variations of trace element concentrations throughout the watershed. Enrichment of trace elements in watershed soils result, in some cases, from contributions attributed to the weathering of volcanic rocks, as well as to a more variable anthropogenic input that reflects changes in land use in Honolulu. Varying concentrations of As, Cd, Cu, Pb and Zn in sediments reflect about 60 a of anthropogenic activity in Honolulu. Land use has a strong impact on the spatial distribution and abundance of selected trace elements in soils and stream sediments. As noted in continental US settings, the phasing out of Pb-alkyl fuel additives has decreased Pb inputs to recently deposited estuarine sediments. Yet, a substantial historical anthropogenic Pb inventory remains in soils of the watershed and erosion of surface soils continues to contribute to its enrichment in estuarine sediments. Concentrations of other elements (e.g., Cu, Zn, Cd), however, have not decreased with time, suggesting continued active inputs. Concentrations of Ba, Co, Cr, Ni, V and U, although elevated in some cases, typically reflect greater proportions attributed to natural sources rather than anthropogenic input. ?? 2002 Elsevier Science Ltd. All rights reserved.

Applied Geochemistry↗

USGS1996

Level II scour analysis for Bridge 145 (HANCVT01000145) on Vermont Highway 100, crossing the Hancock Branch of the White River, Hancock, Vermont

This report provides the results of a detailed Level II analysis of scour potential at structure HANCVT01000145 on State Route 100 crossing the Hancock Branch of the White River, Hancock, Vermont (figures 1–8). A Level II study is a basic engineering analysis of the site, including a quantitative analysis of stream stability and scour (U.S. Department of Transportation, 1993). Results of a Level I scour investigation also are included in Appendix E of this report. A Level I investigation provides a qualitative geomorphic characterization of the study site. Information on the bridge, gleaned from Vermont Agency of Transportation (VTAOT) files, was compiled prior to conducting Level I and Level II analyses and is found in Appendix D. The site is in the Green Mountain section of the New England physiographic province in central Vermont. The 22.0-mi 2 drainage area is in a predominantly rural and forested basin. In the vicinity of the study site, the surface cover is urban on left bank and forested on the right bank upstream of the bridge while the immediate banks have woody vegetation. Downstream of the bridge surface cover on both banks is pasture while the immediate banks have woody vegetation. In the study area, the Hancock Branch of the White River has an incised, sinuous channel with a slope of approximately 0.006 ft/ft, an average channel top width of 48 ft and an average channel depth of 3 ft. The predominant channel bed materials are cobble and gravel with a median grain size (D 50 ) of 71.9 mm (0.236 ft). The geomorphic assessment at the time of the Level I and Level II site visit on November 16, 1994, indicated that the reach was stable. State Route 100 crossing the Hancock Branch of the White River is a 55-ft-long, two-lane bridge consisting of one 53-foot steel-beam span (Vermont Agency of Transportation, written communication, August 26, 1994). The bridge is supported by vertical, concrete abutments with wingwalls. The channel is not skewed to the opening and the opening-skewto-roadway is 0 degrees. The only scour protection measures at the site were type-3 stone fill (less than 48 inches diameter) at the upstream right wingwall, both downstream wingwalls and the downstream ends of both abutments. Also there was type-2 stone fill (less than 36 inches diameter) at the upstream left wingwall. Additional details describing conditions at the site are included in the Level II Summary and Appendices D and E. Scour depths and rock rip-rap sizes were computed using the general guidelines described in Hydraulic Engineering Circular 18 (Richardson and others, 1995). Total scour at a highway crossing is comprised of three components: 1) long-term streambed degradation; 2) contraction scour (due to accelerated flow caused by a reduction in flow area at a bridge) and; 3) local scour (caused by accelerated flow around piers and abutments). Total scour is the sum of the three components. Equations are available to compute depths for contraction and local scour and a summary of the results of these computations follows. Contraction scour for all modelled flows ranged from 3.4 to 4.3 ft. The worst-case contraction scour occurred at the 500-year discharge. Abutment scour ranged from 8.2 to 11.1 ft. The worst-case abutment scour occurred at the 100-year discharge. Additional information on scour depths and depths to armoring are included in the section titled “Scour Results”. Scoured-streambed elevations, based on the calculated scour depths, are presented in tables 1 and 2. A cross-section of the scour computed at the bridge is presented in figure 8. Scour depths were calculated assuming an infinite depth of erosive material and a homogeneous particle-size distribution. It is generally accepted that the Froehlich equation (abutment scour) gives “excessively conservative estimates of scour depths” (Richardson and others, 1995, p. 47). Usually, computed scour depths are evaluated in combination with other information including (but not limited to) historical performance during flood events, the geomorphic stability assessment, existing scour protection measures, and the results of the hydraulic analyses. Therefore, scour depths adopted by VTAOT may differ from the computed values documented herein.

Vermont↗

USGS2009

Nitrate removal in stream ecosystems measured by 15 N addition experiments: Denitrification

We measured denitrification rates using a field 15 N-NO- 3 tracer-addition approach in a large, cross-site study of nitrate uptake in reference, agricultural, and suburban-urban streams. We measured denitrification rates in 49 of 72 streams studied. Uptake length due to denitrification (S Wden ) ranged from 89 m to 184 km (median of 9050 m) and there were no significant differences among regions or land-use categories, likely because of the wide range of conditions within each region and land use. N 2 production rates far exceeded N 2 O production rates in all streams. The fraction of total NO- 3 removal from water due to denitrification ranged from 0.5% to 100% among streams (median of 16%), and was related to NHz 4 concentration and ecosystem respiration rate (ER). Multivariate approaches showed that the most important factors controlling S Wden were specific discharge (discharge / width) and NO- 3 concentration (positive effects), and ER and transient storage zones (negative effects). The relationship between areal denitrification rate (U den ) and NO- 3 concentration indicated a partial saturation effect. A power function with an exponent of 0.5 described this relationship better than a Michaelis-Menten equation. Although Uden increased with increasing NO- 3 concentration, the efficiency of NO- 3 removal from water via denitrification declined, resulting in a smaller proportion of streamwater NO- 3 load removed over a given length of stream. Regional differences in stream denitrification rates were small relative to the proximate factors of NO- 3 concentration and ecosystem respiration rate, and land use was an important but indirect control on denitrification in streams, primarily via its effect on NO- 3 concentration. ?? 2009.

Limnology and Oceanography↗

USGS2024

Temporal variability and sources of PFAS in the Rio Grande, New Mexico through an arid urban area using multiple tracers and high-frequency sampling

Per- and polyfluoroalkyl substances (PFAS) are ubiquitous in the environment but sources are not well defined for temporal and spatial aspects within an urban environment, and especially for an arid urban environment subject to seasonal short term high-intensity precipitation events. A focused diel sampling was conducted in the summer of 2021 to assess the temporal and spatial variability of PFAS in the Rio Grande near Albuquerque, New Mexico and showed an order of magnitude increase of PFAS as it flows through the Albuquerque urban area. Discrete samples were collected at two different locations on the Rio Grande in addition to wastewater treatment plant (WWTP) effluent that discharges directly to the Rio Grande between the sampling locations. Short-term high-intensity precipitation events occurred during the study period and mobilized PFAS from urban runoff. Dissolved organic matter composed of tryptophan-like organic substances and refined fuel and fuel byproducts, characteristic of an urban signature, were also related to the precipitation events. The PFAS in discharge from the WWTP was consistent over a 24-h period with slight differences in some compounds. Wastewater presence on the Rio Grande downstream of the WWTP was evidenced by a gadolinium anomaly as well as increases in several other trace elements, total dissolved nitrogen, and fluorescence indicators, in addition to PFAS. PFAS varied depending on source contribution, where urban runoff was associated with PFOA, PFOS, and PFBA, whereas PFHxA and PFPeA were associated with wastewater effluent. In addition, passive polar organic chemical integrative samplers (POCIS) using hydrophilic-lipid balance (HLB) sorption media were deployed for a month at two locations on the Rio Grande to assess longer term PFAS concentrations. The POCIS results show some compounds (PFPeA and PFHpA) were greater than the average concentration from discrete samples, whereas other compounds (PFHxA, PFOA, PFDA, and PFNA) were lower in the POCIS, and PFOS was very similar between the two. The POCIS did not detect PFBA, which may be related to the HLB media not performing well for short chain PFAS compounds. The results show promise for integrative samplers utilizing sorbent media. More detailed investigation of the spatial and temporal variability of water chemistry on the Rio Grande as it flows through Albuquerque could provide information applicable to urban areas worldwide.

New Mexico↗

USGS1981

Water-resources investigations of the U.S. Geological Survey in Kansas; fiscal years 1979 and 1980

Activities of the U.S. Geological Survey in Kansas include the systematic collection and analysis of data to describe the framework of hydrologic systems, assess the water resources, define existing or potential problems in the quantity or quality of water, and provide information for optimum development and management of resources. Streamflow studies are made to determine availability of supplies and relations to rainfall runoff, urbanization, flood frequencies, and sediment-transport. Ground-water studies are made to determine the quantity of supplies available in aquifer systems, the effects of natural or artificial contamination, and the effects of withdrawals by irrigation, industrial, and municipal supplies. Water-quality studies are made to define physical, chemical, and biological characteristics in streams and principal aquifers, and to evaluate the chemical changes due to urbanization and surface mining.

Kansas↗

USGS2006

Effects of urbanization on stream ecosystems in the South Platte River basin, Colorado and Wyoming

This report describes the effects of urbanization on physical, chemical, and biological characteristics of stream ecosystems in 28 basins along an urban land-use gradient in the South Platte River Basin, Colorado and Wyoming, from 2002 through 2003. Study basins were chosen to minimize natural variability among basins due to factors such as geology, elevation, and climate and to maximize coverage of different stages of urban development among basins. Because land use or population density alone often are not a complete measure of urbanization, land use, land cover, infrastructure, and socioeconomic variables were integrated in a multimetric urban intensity index to represent the degree of urban development in each study basin. Physical characteristics studied included stream hydrology, stream temperature, and habitat; chemical characteristics studied included nutrients, pesticides, suspended sediment, sulfate, chloride, and fecal bacteria concentrations; and biological characteristics studied included algae, fish, and invertebrate communities. Semipermeable membrane devices (SPMDs), passive samplers that concentrate trace levels of hydrophobic organic contaminants like polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs), also were used. The objectives of the study were to (1) examine physical, chemical, and biological responses along the gradient of urbanization; (2) determine the major physical, chemical, and landscape variables affecting the structure of aquatic communities; and (3) evaluate the relevance of the results to the management of water resources in the South Platte River Basin. Commonly observed effects of urbanization on instream physical, chemical, and biological characteristics, such as increased flashiness, higher magnitude and more frequent peak flows, increased concentrations of chemicals, and changes in aquatic community structure, generally were not observed in this study. None of the hydrologic, temperature, habitat, or chemical variables were correlated strongly (Spearman's rho greater than or equal to 0.7) with urban intensity, with the exception of some of the SPMD-based toxicity and chemical variables. SPMD-based measures of potential toxicity and PAH concentrations were positively correlated with urban intensity. The PAH concentrations also were positively correlated with measures of road density and negatively correlated with distance to the nearest road, indicating that automobile exhaust is a major source of these compounds in the study area. This source may be localized enough that the transport of PAHs would be minimally affected by water-management practices such as diversion or storage upstream. In contrast, the predominant sources of nutrients, bacteria, suspended sediment, sulfate, chloride, and pesticides may be more dispersed throughout the drainage area and, therefore, their transport to downstream sites may be subject to greater disruption by water regulation. Although no direct link was found between most water-chemistry characteristics and urbanization, invertebrate, algae, and fish-community characteristics were strongly associated with nutrients, pesticides, sulfate, chloride, and suspended sediment. None of the biological community variables were strongly correlated with the urban intensity index. Algal biomass predominantly was associated with total nitrogen concentrations, nitrite-plus-nitrate concentrations, and the duration of high flows. Fish communities predominantly were associated with housing age, the percentage of suspended sediment finer than 0.063 millimeters and chloride concentrations. Invertebrate communities predominantly were associated with the frequency of rising and falling flow events, the duration of high flows, total nitrogen concentrations, nitrite-plus-nitrate concentrations, and total herbicide concentrations. Historical records indicate that aquatic communities in the region may have been altered prior to any substantial urban development by early agricultural and water-management practices. Present-day aquatic communities are composed primarily of tolerant species even in areas of minimal urban development; when development does occur, the communities already may be resistant to disturbance. In addition to the effects of historical stressors on aquatic community structure, it is possible that current water-management practices in the study basins are having an effect. In the absence of natural, unaltered hydrologic conditions, more sensitive taxa may be unable to recolonize urban streams. The movement and storage of water also may lead to a disconnect between the land surface and streams, resulting in instream physical, chemical, and biological characteristics that, to some degree, are independent of land-cover characteristics.

Colorado, Wyoming↗

USGS2019

Replicated landscape genomics identifies evidence of local adaptation to urbanization in wood frogs

Native species that persist in urban environments may benefit from local adaptation to novel selection factors. We used double-digest restriction-side associated DNA (RAD) sequencing to evaluate shifts in genome-wide genetic diversity and investigate the presence of parallel evolution associated with urban-specific selection factors in wood frogs ( Lithobates sylvaticus ). Our replicated paired study design involved 12 individuals from each of 4 rural and urban populations to improve our confidence that detected signals of selection are indeed associated with urbanization. Genetic diversity measures were less for urban populations; however, the effect size was small, suggesting little biological consequence. Using an F ST outlier approach, we identified 37 of 8344 genotyped single nucleotide polymorphisms with consistent evidence of directional selection across replicates. A genome-wide association study analysis detected modest support for an association between environment type and 12 of the 37 F ST outlier loci. Discriminant analysis of principal components using the 37 F ST outlier loci produced correct reassignment for 87.5% of rural samples and 93.8% of urban samples. Eighteen of the 37 F ST outlier loci mapped to the American bullfrog ( Rana [Lithobates] catesbeiana ) genome, although none were in coding regions. This evidence of parallel evolution to urban environments provides a powerful example of the ability of urban landscapes to direct evolutionary processes.

Maine↗

USGS2009

Assigning land use to supply wells for the statistical characterization of regional groundwater quality: Correlating urban land use and VOC occurrence

Many national and regional groundwater studies have correlated land use "near" a well, often using a 500 m radius circle, with water quality. However, the use of a 500 m circle may seem counterintuitive given that contributing areas are expected to extend up-gradient from wells, and not be circular in shape. The objective of this study was to evaluate if a 500 m circle is adequate for assigning land use to a well for the statistical correlation between urban land use and the occurrence of volatile organic compounds (VOCs). Land use and VOC data came from 277 supply wells in four study areas in California. Land use was computed using ten different-sized circles and wedges (250 m to 10 km in radius), and three different-sized "searchlights" (1-2 km in length). We define these shapes as contributing area surrogates (CASs), recognizing that a simple shape is at best a surrogate for the actual contributing area. The presence or absence of correlation between land use and the occurrence of VOCs was evaluated using Kendall's tau (??). Values of ?? were within 10% of one another for wedges and circles ranging in size from 500 m to 2 km, with correlations remaining statistically significant (p < 0.05) for all CAS sizes and shapes, suggesting that a 500 m circular CAS is adequate for assigning land use to a well. Additional evaluation indicated that urban land use is autocorrelated at distances ranging from 8 to 36 km. Thus, urban land use in a 500 m CAS is likely to be predictive of urban land use in the actual contributing area.

Journal of Hydrology↗

USGS2016

Regional differences in upland forest to developed (urban) land cover conversions in the conterminous U.S., 1973–2011

In this U.S. Geological Survey study of forest land cover across the conterminous U.S. (CONUS), specific proportions and rates of forest conversion to developed (urban) land were assessed on an ecoregional basis. The study period was divided into six time intervals between 1973 and 2011. Forest land cover was the source of 40% or more of the new urban land in 35 of the 84 ecoregions located within the CONUS. In 11 of these ecoregions this threshold exceeded in every time interval. When the percent of change, forest to urban, was compared to the percent of forest in each ecoregion, 58 ecoregions had a greater percent of change and, in six of those, change occurred in every time interval. Annual rates of forest to urban land cover change of 0.2% or higher occurred in 12 ecoregions at least once and in one ecoregion in all intervals. There were three ecoregions where the above conditions were met for nearly every time interval. Even though only a small number of the ecoregions were heavily impacted by forest loss to urban development within the CONUS, the ecosystem services provided by undeveloped forest land cover need to be quantified more completely to better inform future regional land management.

Conterminous United States↗

USGS1991

Automated urban change detection using scanned cartographic and satellite image data

The objective of this study was to develop a digital procedure to measure the amount of urban change that has occurred in an area since the publication of its corresponding 1:24,000-scale topographic map. Traditional change detection techniques are dependent upon the visual comparison of high-altitude aerial photographs or, more recently, satellite image data to a corresponding map. Analytical change detection techniques typically involve the digital comparison of satellite images to one another. As a result of this investigation, a new technique has been developed that analytically compares the most recently published map to a corresponding digital satellite image. Scanned cartographic and satellite image data are combined in a single file with a structural component derived from the satellite image. This investigation determined that with this combination of data the spectral characteristics of urban change are predictable. A supervised classification was used to detect and delimit urban change. Although it was not intended to identify the specific nature of any change, this procedure does provide a means of differentiating between areas that have or have not experienced urbanization to determine appropriate map revision strategies.

Conference Paper↗

USGS2014

Hydrologic conditions in urban Miami-Dade County, Florida, and the effect of groundwater pumpage and increased sea level on canal leakage and regional groundwater flow

The extensive and highly managed surface-water system in southeastern Florida constructed during the 20th Century has allowed for the westward expansion of urban and agricultural activities in Miami-Dade County. In urban areas of the county, the surface-water system is used to (1) control urban flooding, (2) supply recharge to production well fields, and (3) control seawater intrusion. Previous studies in Miami-Dade County have determined that on a local scale, leakage from canals adjacent to well fields can supply a large percentage (46 to 78 percent) of the total groundwater pumpage from production well fields. Canals in the urban areas also receive seepage from the Biscayne aquifer that is derived from a combination of local rainfall and groundwater flow from Water Conservation Area 3 and Everglades National Park, which are west of urban areas of Miami-Dade County. To evaluate the effects of groundwater pumpage on canal leakage and regional groundwater flow, the U.S. Geological Survey (USGS) developed and calibrated a coupled surface-water/groundwater model of the urban areas of Miami-Dade County, Florida. The model was calibrated by using observation data collected from January 1997 through December 2004. The model calibration was verified using observation data collected from January 2005 through December 2010. A 1-year warmup period (January 1996 through December 1996) was added prior to the start of the calibration period to reduce the effects of inaccurate initial conditions on model calibration. The model is designed to simulate surface-water stage and discharge in the managed canal system and dynamic canal leakage to the Biscayne aquifer as well as seepage to the canal from the aquifer. The model was developed using USGS MODFLOW–NWT with the Surface-Water Routing (SWR1) Process to simulate surface-water stage, surface-water discharge, and surface-water/groundwater interaction and the Seawater Intrusion (SWI2) Package to simulate seawater intrusion, respectively. Automated parameter estimation software (PEST) and highly parameterized inversion techniques were used to calibrate the model to observed surface-water stage, surface-water discharge, net surface-water subbasin discharge, and groundwater level data from 1997 through 2004 by modifying hydraulic conductivity, specific storage coefficients, specific yield, evapotranspiration parameters, canal roughness coefficients (Manning’s n values), and canal leakance coefficients. Tikhonov regularization was used to produce parameter distributions that provide an acceptable fit between model outputs and observation data, while simultaneously minimizing deviations from preferred values based on field measurements and expert knowledge. Analytical and simulated water budgets for the period from 1996 through 2010 indicate that most of the water discharging through the salinity control structures is derived from within the urban parts of the study area and that, on average, the canals are draining the Biscayne aquifer. Simulated groundwater discharge from the urban areas to the coast is approximately 7 percent of the total surface-water inflow to Biscayne Bay and is consistent with previous estimates of fresh groundwater discharge to Biscayne Bay. Simulated groundwater budgets indicate that groundwater pumpage in some surface-water basins ranges from 13 to 27 percent of the sum of local sources of groundwater inflow. The largest percentage of groundwater pumpage to local sources of groundwater inflow occurs in the basins that have the highest pumping rates (C–2 and C–100 Basins). The ratio of groundwater pumpage to simulated local sources of groundwater inflow is less than values calculated in previous local-scale studies. The position of the freshwater-seawater interface at the base of the Biscayne aquifer did not change notably during the simulation period (1996–2010), consistent with the similar positions of the interface in 1984, 1995, and 2011 under similar hydrologic and groundwater pumping conditions. Landward movement of the freshwater-seawater interface above the base of the aquifer is more prone to occur during relatively dry years. The model was used to evaluate the effect of increased groundwater pumpage and (or) increased sea level on canal leakage, regional groundwater flow, and the position of the freshwater-seawater interface. Permitted groundwater pumping rates, which generally exceed historical groundwater pumping rates, were used for Miami-Dade County Water and Sewer Department groundwater pumping wells in the base-case future scenario. Base-case future and increased pumping scenario results suggest seawater intrusion may occur at the Miami-Springs well field if the Miami Springs, Hialeah, and Preston well fields are operated using current permitted groundwater pumping rates. Scenario simulations also show that, in general, the canal system limits the adverse effects of proposed groundwater pumpage increases on water-level changes and saltwater intrusion. Proposed increases (up to a 7 percent increase) in groundwater pumpage do not have a notable effect on movement of the freshwater-seawater interface. Increased groundwater pumpage increased lateral groundwater inflow into basins subject to additional groundwater pumpage; however, most (55 percent) of the additional groundwater extracted from pumping wells was supplied by changes in canal seepage and leakage in urban areas of the model. Increased sea level caused increased water-table elevations in urban areas and decreased hydraulic gradients across the system; the largest increases in water-table elevations occurred seaward of the salinity control structures. The extent of flood-prone areas and the percentage of time water-table elevations in flood-prone areas were less than 0.5 foot below land surface increased with increased sea level. Increased sea level also resulted in landward migration of the freshwater-seawater interface; the largest changes in the position of the interface occurred seaward of the salinity control structures except in parts of the model area that were inundated by increased sea level. Decreased water-table gradients reduced groundwater inflow, groundwater outflow, canal exchanges, surface-water inflow, and surface-water outflow through salinity control structures. Results for the scenario that evaluated the combination of increased groundwater pumpage and increased sea level did not differ substantially from the scenario that evaluated increased sea level alone. Groundwater inflow, groundwater outflow, and canal exchanges were reduced in urban areas of the study area as a result of decreased water-table gradients across the system, although reductions were less than those in the increased sea-level scenario. The decline in groundwater levels caused by increased groundwater pumpage was less under the increased sea-level scenario than under the increased groundwater-pumpage scenario. The largest reductions in surface-water outflow from the salinity control structures occurred with increased sea level and increased groundwater pumpage. The model was designed specifically to evaluate the effect of groundwater pumpage on canal leakage at the surface-water-basin scale and thus may not be appropriate for (1) predictions that are dependent on data not included in the calibration process (for example, subdaily simulation of high-intensity events and travel times) and (or) (2) hydrologic conditions that are substantially different from those during the calibration and verification periods. The reliability of the model is limited by the conceptual model of the surface-water and groundwater system, the spatial distribution of physical properties, the scale and discretization of the system, and specified boundary conditions. Some of the model limitations are manifested in model errors. Despite these limitations, however, the model represents the complexities of the interconnected surface-water and groundwater systems that affect how the systems respond to groundwater pumpage, sea-level rise, and other hydrologic stresses. The model also quantifies the relative effects of groundwater pumpage and sea-level rise on the surface-water and groundwater systems.

Florida↗

USGS2010

Water-quality data from storm runoff after the 2007 fires, San Diego County, California

The U.S. Geological Survey collected water-quality samples during the first two storms after the Witch and Harris Fires (October 2007) in southern California. The sampling locations represent an urban area (two residential sites in Rancho Bernardo that were affected by the Witch Fire; a drainage ditch and a storm drain) and a rural area (Cotton-wood Creek, which was downstream of a mobile home park destroyed by the Harris Fire). Fires produce ash and solid residues that contain soluble chemicals that can contaminant runoff. The contaminants, whether sorbed to soil and ash or dissolved, can seriously affect the quality of water supplies and sensitive ecosystems. Stormflow water samples were analyzed for field parameters, optical properties, and for a variety of constituents, including nutrients, dissolved organic carbon (DOC), suspended sediment, and metals. pH values for storm runoff from the urban areas (7.6 to 8.5) were less than pH values for ash and burned soil from previous studies (12.5 to 13). pH values for storm runoff from the rural area (about 7.7) also were less than pH values for ash and burned soil collected from the rural area (8.6 to 11.8), but were similar to pH values for wildland burned soil from previous studies. Turbidity values were much lower for the urban area than for the rural area. Nitrate concentrations in stormflow samples from all sites were less than a quarter of the U.S. Environmental Protection Agency's (2006) maximum allowable contaminant level of 10 milligrams per liter (mg/L) (as nitrogen). Phosphorus concentrations were half as much in filtered samples and two orders of magnitude smaller in unfiltered samples at the urban sites than at the rural site. DOC concentrations in stormflow samples were one order of magnitude lower at the urban sites than at the rural site. Ultraviolet (UV) absorbance at 254 nanometers (UV254) in samples ranged from 0.145 to 0.782 per centimeter (cm-1). UV-absorbance data at the urban sites indicate that the composition of DOC remained similar during both storms even though the DOC concentration changed. Total suspended-sediment concentrations ranged from 0.01 to 0.24 mg/L at the urban area, and were 12 and 45 mg/L at the rural area. Trace metals analyzed in unfiltered water samples had lower concentrations in the urban area than in the rural area. No concentrations of arsenic or mercury measured in the samples were above aquatic-life criteria. In the urban area, most concentrations of aluminum, iron, and lead exceeded aquatic-life criteria. In the rural area, aluminum, cadmium, iron, lead, and zinc exceeded aquatic-life criteria. Concentrations of aluminum and iron were two orders of magnitude larger in the rural area than in the urban area.

Open-File Report↗

USGS2022

Tracking geomorphic changes after suburban development with a high density of green stormwater infrastructure practices in Montgomery County, Maryland

Stream morphology is affected by changes on the surrounding landscape. Understanding the effects of urbanization on stream morphology is a critical factor for land managers to maintain and improve vulnerable stream corridors in urbanizing landscapes. Stormwater practices are used in urban landscapes to manage runoff volumes and peak flows, potentially mitigating alterations to the flow regime that drive changes in channel morphology. However, there remains a paucity of long-term studies assessing watershed-scale relationships between urbanization and effects on stream morphology where green stormwater infrastructure exists in high densities. This paper evaluates the geomorphic changes across four headwater catchments in the Chesapeake Bay Watershed over the course of >10 yr and relates these changes to urban development. Annual cross-sectional surveys conducted from 2002 to 2019 in one forested catchment, one agricultural catchment, and two treatment catchments were used to understand the relationship between urbanization and changes in stream morphology. Six cross-sectional geomorphic metrics were calculated and compared with development timelines and high flow events. A channel evolution model was then used to understand the status of morphologic stability at sites within the study. Results suggest downstream environments in developing areas are more impacted during early phases of suburban construction. Channel change during construction could be a result of sediment and erosion control efforts' limitations on preventing and controlling overland sediment mobilization or of increased discharge causing widening and thus bank-derived sediment to move to the streambed. Results demonstrate that geomorphic metrics are highly variable within a small area and are not always accurate representations of broader landscape changes but rather of the more localized environment at a specific stream segment. Despite a high density of stormwater management facilities in urban catchments, substantial alterations to cross sections were found at multiple locations in each catchment including the controls.

Maryland↗

USGS2001

Tampa Bay Integrated Science Pilot Study: Baseline mapping, land surface dynamics and predictive modeling, and hazards vulnerability studies

Tampa Bay and its environs have experienced phenomenal urban growth and significant changes in land cover and land-use practices over the past 50 years. This trend is expected to continue, with the impact of human activity broadening geographically and intensifying throughout the region. One of the immediate impacts of urban growth is the creation of additional impervious surfaces, which in turn, generate increased urban runoff that contributes to higher levels of nutrient loading in water bodies throughout the area. To better understand these and other anthropogenic affects on the ecology of the natural environment of the region, this component of the Tampa Bay Pilot Study took a broad basin-wide view. This regional view was intended to provide geographic and temporal context for the smaller intensely studied sample field site locations within the estuarine environment.

Open-File Report↗

USGS2006

Final report (2002-2004): Benthic macroinvertebrate communities of reconstructed freshwater tidal wetlands in the Anacostia River, Washington, D.C

Considerable work has been conducted on the benthic communities of inland aquatic systems, but there remains a paucity of effort on freshwater tidal wetlands. This study characterized the benthic macroinvertebrate communities of recently reconstructed urban freshwater tidal wetlands along the Anacostia River in Washington, D.C. The focus of the study was on the two main areas of Kingman Marsh, which were reconstructed by the U.S. Army Corps of Engineers in 2000 using Anacostia dredge material. Populations from this 'new' marsh were compared to those of similarly reconstructed Kenilworth Marsh (1993) just one half mile upstream, the relic reference Dueling Creek Marsh in the upper Anacostia estuary and the outside reference Patuxent freshwater tidal marsh in an adjacent watershed. Benthic macro invertebrate organisms were collected using selected techniques for evaluation including the Ekman bottom grab sampler, sediment corer, D-net and Hester-Dendy sampler. Samples were collected at least seasonally from tidal channels, tidal mudflats, three vegetation/sediment zones (low, middle and high marsh), and pools over a 3-year period (late 2001-2004). The macroinvertebrate communities present at the marsh sites proved to be good indicators of disturbance and stress (Kingman Marsh), pollution, urban vs. rural location (Kenilworth and Patuxent), and similarities between reconstructed and remnant wetlands (Kenilworth and Dueling Creek). Macroinvertebrate density was significantly greater at Kingman Marsh than Kenilworth Marsh due to more numerous chironomids and oligochaetes. This may reflect an increase in unvegetated sediments at Kingman (even at elevations above natural mudflat) due to grazing pressure from over-abundant resident Canada geese. Unvegetated sediments yielded greater macroinvertebrate abundance but lower richness than vegetated marsh sites. Data collected from this study provides information on the extent that benthic macroinvertebrate communities can serve as indicators of the relative success of freshwater tidal marsh reconstruction.

Report↗