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At least 343 records · Page 19Linked to original sources

Mining geology of the Pond Creek seam, Pikeville Formation, Middle Pennsylvanian, in part of the Eastern Kentucky Coal Field, USA

The Pond Creek seam is one of the leading producers of coal in the Eastern Kentucky Coal Field. The geologic factors that affect mining were investigated in several underground mines and categorized in terms of coal thickness, coal quality, and roof control. The limits of mining and thick coal are defined by splitting along the margin of the coal body. Within the coal body, local thickness variation occurs because of (1) leader coal benches filling narrow, elongated depressions, (2) rider coal benches coming near to or merging with the main bench, (3) overthrust coal benches being included along paleochannel margins, (4) cutouts occuring beneath paleochannels, and (5) very hard and unusual rock partings occuring along narrow, elongated trends. In the study area, the coal is mostly mined as a compliance product: sulfur contents are less than 1% and ash yields are less than 10%. Local increases in sulfur occur beneath sandstones, and are inferred to represent post-depositional migration of fluids through porous sands into the coal. Run-of-mine quality is also affected by several mine-roof conditions and trends of densely concentrated rock partings, which lead to increased in- and out-of-seam dilution and overall ash content of the mined coal. Roof control is largely a function of a heterolithic facies mosaic of coastal-estuarine origin, regional fracture trends, and unloading stress related to varying mine depth beneath the surface. Lateral variability of roof facies is the rule in most mines. The largest falls occur beneath modern valleys and parallel fractures, along paleochannel margins, within tidally affected 'stackrock,' and beneath rider coals. Shale spalling, kettlebottoms, and falls within other more isolated facies also occur. Many of the lithofacies, and falls related to bedding weaknesses within or between lithofacies, occur along northeast-southwest trends, which can be projected in advance of mining. Fracture-related falls occur independently of lithofacies trends along northwest-southeast trends, especially beneath modern valleys where overburden thickness decreases sharply. Differentiating roof falls related to these trends can aid in predicting roof quality in advance of mining.The Pond Creek-Lower Elkhorn seam has been an important exploration target because it typically has very low sulfur contents and ash yields. Geologic research in several large Pond Creek mines suggested variability in roof quality and coal thickness. Due to mine access, geologic problems encountered during mining are documented and described.

International Journal of Coal Geology

Geologic map of the San Francisco Bay region

The rocks and fossils of the San Francisco Bay region reveal that the geology there is the product of millions of years at the active western margin of North America. The result of this history is a complex mosaic of geologic materials and structures that form the landscape. A geologic map is one of the basic tools to understand the geology, geologic hazards, and geologic history of a region. With heightened public awareness about earthquake hazards leading up to the 100th anniversary of the 1906 San Francisco earthquake, the U.S. Geological Survey (USGS) is releasing new maps of the San Francisco Bay Area designed to give residents and others a new look at the geologic history and hazards of the region. The “Geologic Map of the San Francisco Bay region” shows the distribution of geologic materials and structures, demonstrates how geologists study the age and origin of the rocks and deposits that we live on, and reveals the complicated geologic history that has led to the landscape that shapes the Bay Area.

California

Major, trace element and isotope geochemistry (Sr-Nd-Pb) of interplinian magmas from Mt. Somma-Vesuvius (Southern Italy)

Major, trace element and isotopic (Sr, Nd, Pb) data are reported for representative samples of interplinian (Protohistoric, Ancient Historic and Medieval Formations) activity of Mt. Somma-Vesuvius volcano during the last 3500 years. Tephra and lavas exhibit significant major, trace element and isotopic variations. Integration of these data with those obtained by previous studies on the older Somma suites and on the latest activity, allows to better trace a complete petrological and geochemical evolution of the Mt. Somma-Vesuvius magmatism. Three main groups of rocks are recognized. A first group is older than 12.000 yrs, and includes effusive-explosive activity of Mt. Somma. The second group (8000-2700 yrs B.P.) includes the products emitted by the Ottaviano (8000 yrs. B.P.) and Avellino (3550 yrs B.P.) plinian eruptions and the interplinian activity associated with the Protohistoric Formation. Ancient Historic Formation (79-472 A.D.), Medieval Formation (472-1139 A.D.) and Recent interplinian activity (1631-1944 A.D.) belong to the third group of activity (79-1944 A.D.). The three groups of rocks display distinct positive trends of alkalis vs. silica, which become increasingly steeper with age. In the first group there is an increase in silica and alkalis with time, whereas an opposite tendency is observed in the two younger groups. Systematic variations are also evident among the incompatible (Pb, Zr, Hf, Ta, Th, U, Nb, Rb, Cs, Ba) and compatible elements (Sr, Co, Cr). REE document variable degrees of fractionation, with recent activity displaying higher La/Yb ratios than Medieval and Ancient Historic products with the same degree of evolution. N-MORB normalized multi-element diagrams for interplinian rocks show enrichment in Rb, Th, Nb, Zr and Sm (> *10 N-MORB). Sr isotope ratios are variable, with Protohistoric rocks displaying 87Sr/86Sr= 0.70711-0.70810, Ancient Historic 87Sr/86Sr=0.70665-0.70729, and Medieval 87Sr/86Sr=0.70685-0.70803. Neodymium isotopic compositions in the interplinian rocks show a tendency to become slightly more radiogenic with age, from the Protohistoric (143Nd/144Nd=0.51240-0.51247) to Ancient Historic (143Nd/144Nd=0.51245-0.51251). Medieval interplinian activity (143Nd/144Nd: 0.51250-0.51241) lacks meaningful internal trends. All the interplinian rocks have virtually homogeneous compositions of 207Pb/204Pb and 208Pb/204Pb in acid-leached residues (207Pb/204Pb ???15.633 to 15.687, 208Pb/204Pb ???38.947 to 39.181). Values of 206Pb/204Pb are very distinctive, however, and discriminate among the three interplinian cycles of activity (Protohistoric: 18.929-18.971, Ancient Historic: 19.018-19.088, Medieval: 18.964-19.053). Compositional trends of major, trace element and isotopic compositions clearly demonstrate strong temporal variations of the magma types feeding the Somma-Vesuvius activity. These different trends are unlikely to be related only to low pressure evolutionary processes, and reveal variations of parental melt composition. Geochemical data suggest a three component mixing scheme for the interplinian activity. These involve HIMU-type and DMM-type mantle and Calabrian-type lower crust. Interaction between these components has taken place in the source; however, additional quantitative constraints must be acquired in order to better discriminate between magma characteristics inherited from the sources and those acquired during shallow level evolution.

Mineralogy and Petrology

Experimental studies of pegmatite genesis: I. A model for the derivation and crystallization of granitic pegmatites

The genesis of granitic igneous pegmatites is here considered in terms of a model conceived from results of field and laboratory studies and subsequently tested by means of experimental investigations. This model emphasizes the roles of water (and/or other relatively volatile substances), both as a dissolved constituent in granitic magmas and as the dominant constituent of a separate fluid phase that is in the supercritical state under most conditions of pegmatite formation. Pegmatite magma, as distinguished by a content of dissolved water that is high relative to the limit of solubility under existing confining pressure, can be formed either through partial melting of crustal materials or as rest-liquid in a cooling igneous body yielding dominantly anhydrous crystalline phases. Such granitic magma can be expected to consolidate according to the following three-fold sequence: 1. Crystallization from hydrous silicate melt, yielding anhydrous solid phases with or without OH-bearing phases. The product is characterized by normal phaneritic textures that generafly are coarse grained. It has been termed pegmatite in some occurrences, and granite in others. 2. Crystallization concomitantly from silicate melt and from a coexisting exsolved aqueous fluid of considerably lower viscosity, yielding giant-textured pegmatite along with much finer-grained, even aplitic, mineral aggregates. Segregation of these products can vary enormously in scale and degree. Partitioning of constituents between melt and aqueous fluid, rapid diffusion of constituents through the aqueous phase, and gravitational rising of this fluid through the system contribute to formation of pods, zones, and other rock units of unusual composition and texture. 3. Crystallization in the absence of silicate melt, yielding a wide variety of late-stage products. These include so-called "pocket minerals" and numerous mineral aggregates formed through exchanges of material among aqueous fluid and earlier-formed crystal-line phases. Development of pegmatite bodies can begin with either Step 1 or Step 2, but it is suggested that the processes involved in Step 2 are essential to the formation of all true pegmatites of igneous origin. The appearance of a second fluid phase, in general a supercritical aqueous fluid derived from the crystallizing melt, is regarded as the decisive event; it is promptly followed by fundamental changes in distribution and texture of the solid phases being formed. The processes can operate effectively in a fully closed system, and they also can modify the surrounding rocks if the system is open at any stage. Step 1 can include reactions between magma and earlier-formed crystals, but far more rapid and extensive exchanges of materials are subsequently effected by processes included in Steps 2 and 3; indeed, such exchanges also can account satisfactorily for pegmatites of metamorphic origin. Crystallization of most granitic magmas in the absence of a separate aqueous phase probably would begin within the temperature range 1,300°-650 ° C, the specific liquidus temperature depending mainly upon the amounts of volatile constituents held in solution at the time. This compositional factor also would be important in controlling the stage of crystallization-late, intermediate, or early-at which a separate aqueous fluid would make its appearance. Depending upon confining pressure as dictated by geologic conditions for a given system, the stage in crystallization represented by the presence of both silicate melt and aqueous fluid could begin within about the same temperature range of 1.300°-650 ° C. Exhaustion of the melt could occur within range extending downward to temperatures of 600C or even somewhat lower. Textural and structural features appear to be the most reliable indicators of the stages and fundamental processes involved in crystallization of both natural and synthetic pegmatites. The contrasting processes of crystallization from one fluid and from more than one fluid can operate over such broad P-T-X ranges that simple genetic pegmatite classifications based largely upon "key minerals," presumed temperature or pressure intervals, or the presence or absence of supercritical conditions appear to be somewhat unrealistic. © 1969 Society of Economic Geologists, Inc.

Economic Geology

Organic geochemistry and petrology of Devonian shale in eastern Ohio: Implications for petroleum systems assessment

Recent production of light sweet oil has prompted reevaluation of Devonian petroleum systems in the central Appalachian Basin. Upper Devonian Ohio Shale (lower Huron Member) and Middle Devonian Marcellus Shale organic-rich source rocks from eastern Ohio and nearby areas were examined using organic petrography and geochemical analysis of solvent extracts to test ideas related to organic matter sources, oil–source rock correlation, thermal maturity, and distances of petroleum migration. The data from these analyses indicate organic matter in the Ohio and Marcellus Shales primarily was derived from marine algae and its degradation products, including bacterial biomass. Absence of odd-over-even n - alkane distributions (n - C 13 to n - C 21 range) in gas chromatograms and low gammacerane index values in Devonian source rocks are similar to those of Devonian-reservoired oils in eastern Ohio, suggesting an oil–source rock correlation. Lower Paleozoic oils from eastern Ohio, in contrast, are characterized by the presence of odd-over-even n - alkane distributions (n - C 13 to n - C 21 range) and higher gammacerane values, which discriminate them from Devonian shale-derived oils. Thermal maturity estimates from equilibrium(?) biomarker isomerization ratios suggest that some of the Devonian source rock samples are at middle to peak oil window conditions (i.e., approximate vitrinite reflectance values of 0.8%–0.9%). This observation requires local to short-distance (<50 mi) lateral migration for emplacement of Devonian-sourced oils into Devonian reservoirs of eastern Ohio and may impact exploration and assessment of petroleum resources in the Upper Devonian Berea Sandstone.

Ohio

Suppression of vitrinite reflectance by bitumen generated from liptinite during hydrous pyrolysis of artificial source rock

Mean random vitrinite reflectance (R o ) is the most widely accepted method to determine thermal maturity of coal and other sedimentary rocks. However, oil-immersion R o of polished rock or kerogen samples is commonly lower than R o values measured in samples from adjacent vitrinite-rich coals that have undergone the same level of thermal stress. So-called suppressed R o values have also been observed in hydrous pyrolysis experiments designed to simulate petroleum formation. Various hypotheses to explain R o suppression, such as sorption of products generated from liptinite during maturation, diagenetic formation of perhydrous vitrinite or overpressure, remain controversial. To experimentally test for suppression of vitrinite reflectance, artificial rock was prepared using silica and a calcined blend of limestone and clay with various proportions of thermally immature vitrinite-rich Wyodak-Anderson coal and liptinite-rich kerogen isolated from the oil-prone Parachute Creek Member of the Green River Formation. The samples were subjected to hydrous pyrolysis for 72 h. at isothermal temperatures of 300 °C, 330 °C, and 350 °C to simulate burial maturation. Compared to artificial rock that contains only coal, samples with different proportions of oil-prone kerogen show distinct suppression of calibrated R o at 300 °C and 330 °C. The reflectance of solid bitumen generated during heating of the samples is lower than that of the associated vitrinite and does not interfere with the R o measurements. These results provide the first experimental evidence that R o suppression occurs in vitrinite mixed with liptinite-rich kerogen in a rock matrix. Although the precise chemical mechanism for R o suppression by liptinite remains unclear, free radicals generated from solid bitumen and associated volatile products during maturation of liptinite may contribute to termination reactions that slow the aromatization and rearrangement of polyaromatic sheets in vitrinite, thus suppressing R o . This mechanism does not preclude R o suppression that might result from overpressure or differences in redox conditions during diagenesis.

Organic Geochemistry

Geology, sequence stratigraphy, and oil and gas assessment of the Lewis Shale Total Petroleum System, San Juan Basin, New Mexico and Colorado: Chapter 5 in Total petroleum systems and geologic assessment of undiscovered oil and gas resources in the San Juan Basin Province, exclusive of Paleozoic rocks, New Mexico and Colorado

The Lewis Shale Total Petroleum System (TPS) in the San Juan Basin Province contains a continuous gas accumulation in three distinct stratigraphic units deposited in genetically related depositional environments: offshore-marine shales, mudstones, siltstones, and sandstones of the Lewis Shale, and marginal-marine shoreface sandstones and siltstones of both the La Ventana Tongue and the Chacra Tongue of the Cliff House Sandstone. The Lewis Shale was not a completion target in the San Juan Basin (SJB) in early drilling from about the 1950s through 1990. During that time, only 16 wells were completed in the Lewis from natural fracture systems encountered while drilling for deeper reservoir objectives. In 1991, existing wells that penetrated the Lewis Shale were re-entered by petroleum industry operators in order to fracture-stimulate the Lewis and to add Lewis gas production onto preexisting, and presumably often declining, Mesaverde Group production stratigraphically lower in the section. By 1997, approximately 101 Lewis completions had been made, both as re-entries into existing wells and as add-ons to Mesaverde production in new wells. Based on recent industry drilling and completion practices leading to successful gas production from the Lewis and because new geologic models indicate that the Lewis Shale contains both source rocks and reservoir rocks, the Lewis Shale TPS was defined and evaluated as part of this U.S. Geological Survey oil and gas assessment of the San Juan Basin. Gas in the Lewis Shale Total Petroleum System is produced from shoreface sandstones and siltstones in the La Ventana and Chacra Tongues and from distal facies of these prograding clastic units that extend into marine rocks of the Lewis Shale in the central part of the San Juan Basin. Reservoirs are in shoreface sandstone parasequences of the La Ventana and Chacra and their correlative distal parasequences in the Lewis Shale where both natural and artificially enhanced fractures produce gas. The Lewis Continuous Gas Assessment Unit (AU 50220261) is thought to be self-sourced from and self-sealed by marine shales and mudstones deposited within the Lewis Shale that enclose clastic parasequences in the La Ventana and Chacra Tongues. The gas resource is thought to be a continuous accumulation sourced from the Lewis Shale throughout the depositional basin. In the Lewis Continuous Gas Assessment Unit (AU 50220261), for continuous gas resources, there is an F95 of 8,315.22 billion cubic feet of gas (BCFG) and an F5 of 12,282.31 BCFG, with a mean value of 10,177.24 BCFG. There is an F95 of 18.08 million barrels of natural gas liquids (MMBNGL) and an F5 of 47.32 MMBNGL, with a mean of 30.53 MMBNGL.

Colorado;New Mexico

Controls on sediment production in two U.S. deserts

Much of the world’s airborne sediment originates from dryland regions. Soil surface disturbances in these regions are ever-increasing due to human activities such as energy and mineral exploration and development, recreation, suburbanization, livestock grazing and cropping. Sediment production can have significant impacts to human health with particles potentially carrying viruses such as Valley Fever or causing asthma or other respiratory diseases. Dust storms can cause decreased visibility at the ground level, resulting in highway accidents, and reduced visual quality in park and wildland airsheds. Sediment production and deposition is also detrimental to ecosystem health, as production reduces soil fertility at its source and can bury plants and other organisms where it is deposited. Therefore, it is important to understand how we can predict what areas are prone to producing sediment emissions both before and after soil surface disturbance. We visited 87 sites in two deserts of the western U.S. that represented a range of soil texture and surface cover types. We used a portable wind tunnel to estimate the threshold friction velocity (TFV) required to initiate sediment transport and the amount of sediment produced by the tunnel at a set wind speed. Wind tunnel runs were done before and after soil surface disturbance with a four-wheel drive vehicle. Results show that most undisturbed desert soils are very stable, especially if covered by rocks or well-developed biological soil crusts, which make them virtually wind-erosion proof. Particles at disturbed sites, in contrast, moved at relatively low wind speeds and produced high amounts of sediment. Silt was an important predictor of TFV and sediment production across all sites, whereas the influence of rock cover and biological soil crusts was site-dependent. Understanding the vulnerability of a site after disturbance is important information for land managers as they plan land use activities and attempt to mitigate the harmful effects that sediment production can have on both human and ecosystem health.

Aeolian Research

The delicate balance between soil production and erosion, and its role on landscape evolution

The diversity in landscapes at the Earth’s surface is the result, amongst other things, of the balance (or imbalance) between soil production and erosion. While erosion rates are well constrained, it is only recently that we have been able to quantify rates of soil production. Uranium-series isotopes have been useful to provide such estimates independently of erosion rates. In this study, new U-series isotope are presented data from weathering profiles developed over andesitic parent rock in Puerto Rico, and granitic bedrock in southeastern Australia. The site in Australia is located on a highland plateau, neighbouring a retreating escarpment where soil production rates between 10 and 50 mm/kyr have been determined. The results show that production rates are invariant in these two regions of Australia with values between 15 and 25 mm/kyr for the new site. Andesitic soils show much faster rates, about 200 mm/kyr. Overall, soil production rates determined with U-series isotopes range between 10 and 200 mm/kyr. This is comparable to erosion rates in soil-mantled landscapes, but faster than erosion in cratonic areas and slower than in alpine regions and cultivated areas. This suggests that soil-mantled landscapes maintain soil because they can: there is a balance between production and erosion. Similarly, thick weathering profiles develop in cratonic areas because, despite slow erosion rates, soil production is still significant. Bare landscapes in Alpine regions are probably the result of the inability of soil production to catch up with fast erosion rates, although this needs testing by U-series isotope studies of these regions. Finally, the range of production rates is up to several orders of magnitude lower than erosion rates in cultivated areas, demonstrating quantitatively the fast depletion of soil resources with common agricultural practices.

Applied Geochemistry

Hydrous carbonates on Mars?: Evidence from Mariner 6/7 infrared spectrometer and ground‐based telescopic spectra

Absorption features at 2.28 and 5.4 μm identified in Mariner 6/7 infrared spectrometer and terrestrial telescopic spectra are consistent with the spectra of hydrous magnesium carbonates such as hydromagnesite and artinite. Spectral characteristics of these hydrous carbonates are different from those of the anhydrous carbonates, as the former do not have the strong spectral features typically associated with anhydrous carbonates such as calcite and siderite. Theoretical mixing indicates that, depending on the type of hydrous carbonate, 10–20 wt % can be incorporated into the regolith without contradicting the spectral observations or the Viking x ray fluorescence chemical analysis. Hydrous carbonates form as weathering products of mafic minerals in the presence of H 2 O and CO 2 , even in the Antarctic. Their formation as evaporite minerals from either original magmas or hydrothermally altered rocks is consistent with the Martian environment, provided liquid water is or has been at least transiently present. On Earth, formation of hydrous Mg carbonates is associated with the production of amorphous iron oxides, which is consistent with both the environment and the inferred surface mineralogy of Mars. These minerals are about 60 wt % H 2 O, CO 3 , and OH; if they are abundant everywhere at the 10% level, then about 6% of the surface weight could be volatiles bound in this type of mineral. Although the stability of hydrous carbonates in a Martian environment is uncertain, there may be kinetic factors inhibiting the dehydration of these minerals, which may persist metastably in the current environment. Although the spectroscopic evidence for anhydrous carbonates is scant, the possible presence of hydrous carbonates provides an appealing mechanism for the existence of carbonates on Mars.

Journal of Geophysical Research

Ore genesis constraints on the Idaho Cobalt Belt from fluid inclusion gas, noble gas isotope, and ion ratio analyses

The Idaho cobalt belt is a 60-km-long alignment of deposits composed of cobaltite, Co pyrite, chalcopyrite, and gold with anomalous Nb, Y, Be, and rare-earth elements (REEs) in a quartz-biotite-tourmaline gangue hosted in Mesoproterozoic metasedimentary rocks of the Lemhi Group. It is the largest cobalt resource in the United States with historic production from the Blackbird Mine. All of the deposits were deformed and metamorphosed to upper greenschist-lower amphibolite grade in the Cretaceous. They occur near a 1377 Ma anorogenic bimodal plutonic complex. The enhanced solubility of Fe, Co, Cu, and Au as chloride complexes together with gangue biotite rich in Fe and Cl and gangue quartz containing hypersaline inclusions allows that hot saline fluids were involved. The isotopes of B in gangue tourmaline are suggestive of a marine source, whereas those of Pb in ore suggest a U ± Th-enriched source. The ore and gangue minerals in this belt may have trapped components in fluid inclusions that are distinct from those in post-ore minerals and metamorphic minerals. Such components can potentially be identified and distinguished by their relative abundances in contrasting samples. Therefore, we obtained samples of Co and Cu sulfides, gangue quartz, biotite, and tourmaline and post-ore quartz veins as well as Cretaceous metamorphic garnet and determined the gas, noble gas isotope, and ion ratios of fluid inclusion extracts by mass spectrometry and ion chromatography. The most abundant gases present in extracts from each sample type are biased toward the gas-rich population of inclusions trapped during maximum burial and metamorphism. All have CO 2 /CH 4 and N 2 /Ar ratios of evolved crustal fluids, and many yield a range of H 2 -CH 4 -CO 2 -H 2 S equilibration temperatures consistent with the metamorphic grade. Cretaceous garnet and post-ore minerals have high R H and R S values suggestive of reduced sulfidic conditions. Most extracts have anomalous 4 He produced by decay of U and Th and 38 Ar produced by nucleogenic production from 41 K. In contrast, some ore and gangue minerals yield significant SO 2 and have low R H and R S values of a more oxidized fluid. Three extracts from gangue quartz have high helium R/R A values indicative of a mantle source and neon isotope compositions that require nucleogenic production of 22 Ne in fluorite from U ± Th decay. Two extracts from gangue quartz have estimated 40 K/ 40 Ar that permit a Precambrian age. Extracts from gangue quartz in three different ore zones are biased toward the hypersaline population of inclusions and have a tight range of ion ratios (Na, K, NH 4 , Cl, Br, F) suggestive of a single fluid. Their Na, Cl, Br ratios suggest this fluid was a mixture of magmatic and basinal brine. Na-K-Ca temperatures (279°–347°C) are similar to homogenization temperatures of hypersaline inclusions. The high K/Na of the brine may be due to albitization of K silicate minerals in country rocks. Influx of K-rich brines is consistent with the K metasomatism necessary to form gangue biotite with high Cl. An extract from a post-ore quartz vein is distinct and has Na, Cl, Br ratios that resemble metamorphic fluids in Cretaceous silver veins of the Coeur d’Alene district in the Belt Basin. The results show that in some samples, for certain components, it is possible to “see through” the Cretaceous metamorphic overprint. Of great import for genetic models, the volatiles trapped in gangue quartz have 3 He derived from a mantle source and 22 Ne derived from fluorite, both of which may be attributed to nearby ~1377 Ma basalt-rhyolite magmatism. The brine trapped in gangue quartz is a mixture of magmatic fluid and evaporated seawater. The former requires a granitic intrusion that is present in the bimodal intrusive complex, and the latter equatorial paleolatitudes that existed in the Mesoproterozoic. The results permit genetic models involving heat and fluids from the neighboring bimodal plutonic complex and convection of basinal brine in the Lemhi Group. While the inferred fluid sources in the Idaho cobalt belt are similar in many respects to those in iron oxide copper-gold deposits, the fluids were more reduced such that iron was fixed in biotite and tourmaline instead of iron oxides.

Idaho

Regional patterns of Mesozoic-Cenozoic magmatism in western Alaska revealed by new U-Pb and 40Ar/39Ar ages

In support of regional geologic framework studies, we obtained 50 new argon-40/argon-39 ( 40 Ar/ 39 Ar) ages and 33 new uranium-lead (U-Pb) ages from igneous rocks of southwestern Alaska. Most of the samples are from the Sleetmute and Taylor Mountains quadrangles; smaller collections or individual samples are from the Bethel, Candle, Dillingham, Goodnews Bay, Holy Cross, Iditarod, Kantishna River, Lake Clark, Lime Hills, McGrath, Medfra, Talkeetna, and Tanana quadrangles. A U-Pb zircon age of 317.7±0.6 million years (Ma) reveals the presence of Pennsylvanian intermediate igneous (probably volcanic) rocks in the Tikchik terrane, Bethel quadrangle. A U-Pb zircon age of 229.5±0.2 Ma from gabbro intruding the Rampart Group of the Angayucham-Tozitna terrane, Tanana quadrangle, confirms and tightens a previously cited Triassic age for this intrusive suite. A fresh mafic dike in Goodnews Bay quadrangle yielded a 40 Ar/ 39 Ar whole rock age of 155.0±1.9 Ma; this establishes a Jurassic or older age for the previously unconstrained (Paleozoic? to Mesozoic?) sandstone unit that it intrudes. A thick felsic tuff in the Gemuk Group in Taylor Mountains quadrangle yielded a U-Pb zircon age of 153.0±2.0 Ma, extending the age of magmatism in this part of the Togiak terrane back into the Late Jurassic. We report three new U-Pb zircon ages between 120 and 110 Ma—112.0±0.9 Ma from syenite in the Candle quadrangle, 114.9±0.3 Ma from orthogneiss assigned to the Ruby terrane in Iditarod quadrangle, and 116.6±0.1 Ma from a gabbro of the Dishna River mafic-ultramafic complex in Iditarod quadrangle. The latter result requires a substantial age revision, from Triassic to Cretaceous, for at least some rocks that have been mapped as the Dishna River mafic-ultramafic complex. A tuff in the Upper Cretaceous Kuskokwim Group yielded a U-Pb zircon (sensitive high-resolution ion microprobe, SHRIMP) age of 88.3±1.0 Ma; we speculate that the eruptive source was an arc along the trend of the Pebble porphyry copper deposit along the Gulf of Alaska continental margin. More than half of the new ages fall between 75 and 65 Ma, confirming the existence, based on conventional potassium-argon (K-Ar) ages, of a 70-Ma igneous flare-up across southwestern Alaska. Our new ages hint that during this pulse, the locus of magmatism shifted toward the Gulf of Alaska, that is, toward a more outboard position. This shift is consistent with the hypothesis that magmatism was the product of rollback of a subducted slab, which at that time would have been the Resurrection Plate. Intrusive rocks in the Taylor Mountains and Sleetmute quadrangles in the age range of 63 to 59 Ma were emplaced shortly before the onset of ridge subduction as dated by near-trench plutons in the adjacent part of the Chugach accretionary complex. Southwestern Alaska at this time would have been positioned above a very young subducted slab belonging to the Resurrection Plate; magmas, in this scenario, were generated near the edge of the slab window related to ridge subduction. A 56.3±0.2 Ma granite in Taylor Mountains quadrangle and a 54.7±0.7 Ma ashfall tuff in McGrath quadrangle were likely emplaced above the Resurrection-Kula slab window, which by this time is inferred to have entered the region. Another ashfall tuff in McGrath quadrangle, at 42.8±0.5 Ma, likely belongs to the Meshik Arc, the product of renewed subduction after inferred passage of the slab window. A 49.0±0.3-Ma rhyolite in Taylor Mountains quadrangle is about the age of the transition from slab window to renewed subduction. Two plutons in the western Alaska Range, at 31.8±0.4 and 30.9±0.6 Ma, belong to a suite of gabbro to peralkaline granite of unknown origin. Finally, a 4.6±0.1-Ma basalt from a flow in Taylor Mountains quadrangle belongs to the Neogene basaltic province of western Alaska. These rocks were erupted in a distal retroarc setting; the cause of magmatism is unknown.

Alaska

Summary appraisals of the nation's ground-water resources – Tennessee region

Ground water is an abundant and little-used resource in the Tennessee Region, a 41,000 square mile area dominated by the Tennessee River system and including parts of Alabama, Georgia, Kentucky, Mississippi, North Carolina, Tennessee, and Virginia. One-fifth to one-fourth of the precipitation that falls on the region enters the ground-water reservoirs. During the year approximately the same amount of water leaves the ground-water system, sustaining the dry-weather flow of streams. Recharge for the region is about 22,000 million gallons per day or 0.5 million gallons per day per square mile. The major types of aquifers in the region are unconsolidated material (including sand and regolith), carbonate rocks, and fractured noncarbonate rocks. One or more of these aquifer types occurs in each of the six physiographic subdivisions of the region. The productivity of these aquifers depends on their hydraulic properties and on the distribution of these properties. The unconsolidated sand aquifers are the most homogeneous in composition and most predictable in occurrence. These aquifers commonly yield 200 to 600 gallons per minute per well depending on the thickness of sand penetrated. The most difficult aquifers to predict in regard to depth and yield are the carbonate rocks. In these aquifers it is possible to drill dry holes within a few hundred feet of wells capable of producing several thousand gallons per minute. However, with an adequate reconnaissance study to determine the occurrence of ground water and a planned test drilling program, yields of up to 300 gallons per minute per well can be expected in the carbonate aquifers. Potential yields from the fractured noncarbonate aquifers are lower than in the carbonate rocks. The chemical and physical properties of ground water in the Tennessee Region are usually within the limits recommended by the Environmental Protection Agency for drinking water, and the ground water in all but some very shallow aquifers tends to be free of pathogenic microorganisms. Saline water is not known to occur in significant quantities in the region. In 1970, 173 million gallons per day of ground water were used in the Tennessee Region. This was less than 8 percent of the total quantity of water used in the region and only 0.8 percent of the estimated ground-water recharge. Ground water is used chiefly as a source of water supply for rural areas and small towns. A lesser amount is used by industries and commercial establishments located beyond the limits of municipal water-supply systems. However, there is potential for significantly increased use in order to augment surface-water supplies and to utilize the total water resource more efficiently. Hydrologic studies and adequate test drilling would greatly increase the chances of locating large amounts of ground water, especially in the nine-tenths of the Tennessee Region that is underlain by either carbonate rocks or fractured noncarbonate rocks which have highly variable water-bearing properties. Collectively, such studies are useful in developing a concept of the hydrologic system which would permit the development of criteria for selecting well sites in other areas with a similar geological and hydrological setting. Hydrologic studies that include test drilling have been conducted in all parts of the region except the Cumberland Plateau. Some of the basic data necessary for hydrologic studies, such as geologic maps, well records, and streamflow records are available throughout the region. However, detailed information on groundwater levels, ground-water quality, and aquifer characteristics are not equally available throughout the region. This type of information cannot be obtained quickly when it is needed; it must be the product of a continuing program of studies designed to evaluate the Tennessee Region's ground-water resource. Because of the interdependence of ground water and surface water, water management efforts can be fully effective only if they involve the whole water resource. In the Tennessee Region, surface water is highly controlled, but there is at present no regionwide water-resources management plan that includes ground water.

Tennessee

Comparative mineral mapping in the Colorado Mineral Belt using AVIRIS and ASTER remote sensing data

This report presents results of interpretation of spectral remote sensing data covering the eastern Colorado Mineral Belt in central Colorado, USA, acquired by the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) and Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) sensors. This study was part of a multidisciplinary mapping and data integration project at the U.S. Geological Survey that focused on long-term resource planning by land-managing entities in Colorado. The map products were designed primarily for the regional mapping and characterization of exposed surface mineralogy, including that related to hydrothermal alteration and supergene weathering of pyritic rocks. Alteration type was modeled from identified minerals based on standard definitions of alteration mineral assemblages. Vegetation was identified using the ASTER data and subdivided based on per-pixel chlorophyll content (depth of 0.68 micrometer absorption band) and dryness (fit and depth of leaf biochemical absorptions in the shortwave infrared spectral region). The vegetation results can be used to estimate the abundance of fire fuels at the time of data acquisition (2002 and 2003). The AVIRIS- and ASTER-derived mineral mapping results can be readily compared using the toggleable layers in the GeoPDF file, and by using the provided GIS-ready raster datasets. The results relating to mineral occurrence and distribution were an important source of data for studies documenting the effects of mining and un-mined, altered rocks on aquatic ecosystems at the watershed level. These studies demonstrated a high correlation between metal concentrations in streams and the presence of hydrothermal alteration and (or) pyritic mine waste as determined by analysis of the map products presented herein. The mineral mapping results were also used to delineate permissive areas for various mineral deposit types.

Colorado

Geology of the Romanzof Mountains, Brooks Range, northeastern Alaska

This remote 700 square mile area in the Brooks Range is topographically rugged and geologically diverse; it contains a granitic pluton, low-grade metamorphic rocks, sedimentary rocks, and mafic igneous rocks, as well as glacial features. Rocks of sedimentary origin include from oldest to youngest: 1.Neruokpuk Formation Middle and Upper Devonian(?), more than 4000 feet thick, a variety of units which represent the greenschist facies, including quartzitic- and schistose-feldspathic graywacke; phyllite, argillite, and slate, as well as dark limestone, sandy limestone, and silicified carbonate rocks. The succession of units in parts of the area is uncertain. Correlations between these units and with others in the eastern Brooks Range are provisional. 2.Kekiktuk Conglomerate and Kayak(?) Shale (Upper Devonian(?) to Upper Mississippian), a single map unit, from absent(?) to 400+ feet thick, containing dark shale Kayak(?) in its uppermost part and quartzite, interbedded dark shale, and some pebble- to boulder-conglomerate in the locally absent lower part (Kekiktuk). The unit overlies the Neruokpuk with angular unconformity, which may reflect either a pre-Kayak(?) or pre-Kekiktuk hiatus or both. 3.Lisburne Group, almost entirely carbonate rocks, and relatively thin in this area, 600 to 800 feet thick. Alapah Limestone (Upper Mississippian), to 560 feet thick, includes gray sandy, crystalline, and cherty limestone; minor dark shale; and dark cherty carbonate rocks in the upper part. The lower contact is gradational with the Kayak(?). Wahoo(?) Limestone (Pennsylvanian(?) to Permian) conformably overlies the Alapah, is absent to 200+ feet thick, and is characterized by light-gray crinoidal limestones in its upper part. 4. Sadlerochit Formation, consisting of three intraconformable units: ferruginous sandstone member (Permian) of ironstained orthoquartzite and dark slate, 175 to 240 feet thick which unconformably overlies the Wahoo(?) and Alapah Limestones; shale member of dark shale, slate, and minor quartzite averaging 400 feet in thickness; and quartzite member (Lower(?) Triassic), 700 feet thick, mostly orthoquartzite with minor shale and conglomerate. The basal clastics were probably shed from the north. 5.Shublik Formation (Middle(?) and Upper Triassic), 600 to 700 feet thick, with the thin phosphatic sandstone member overlain by dark phosphatic limestones and limy shales of the limestone member. 6.Kingak Formation (Jurassic), more than 1000 feet thick. The siltstone member, resistant sandstone and siltstone 75 to 150 feet thick, is overlain by an undetermined thickness of black shale. The basal part contrasts sharply with the underlying Shublik, indicating possible disconformity. 7.Ignek(?) Formation (Cretaceous), represented in the foothills where lithic graywacke, shale, and coaly shale constitute the few exposures examined. 8.Glacial and glaciofluvial materials of five advances recognized on the basis of morphology and position, which are tentatively correlated with five glaciations 15 miles west of the area. 9. Recent alluvial and colluvial deposits including fans which appear to represent at least three stages of encroachment. The Ramanzof granite, exposed in the Okpilak batholith and Jago stock, is mostly light-gray quartz monzonite to granite, and contains essential quartz, perthitic microcline, albite-oligoclase, and partly chloritized biotite. Limited modal and chemical data are presented. Three textural facies are: 1) porphyritic (marginal), with abundant large microcline megacrysts; 2) variable (middle to marginal), which exhibits textural and mineralogical banding; and 3) coarse (inner to marginal), which is gneissoid to equigranular. Facies relationships appear to be mostly gradational but may be locally intrusive. Some schistose metasedimentary(?) rock occurs in the granite. Aplite dikes, inclusions, tourmaline veins and replacements, and chlorite and quartz veins are locally common, as well as quartz monzonite and mafic igneous dikes. Contacts with Neruokpuk Formation rocks are mostly abrupt, concordant to cross-cutting, and locally adjoin tactite and hornfels of the albite-epidote-hornfels and hornblende-hornfels facies. Contacts with Kekiktuk Conglomerate are apparently gradational through a schistoze zone. Both primary and secondary structural elements are present in the Romanzof in granite. Textural and mineralogical banding and, in general, feldspar foliation are considered to be primary in origin; biotite foliation, gneissic and schistose foliation, and schistose zones are considered secondary. Lead-alpha age of zircons appears to be Late Devonian, K-Ar age of biotite is Cretaceous, possibly indicating updating by later reheating. Field age relationships are inconclusive but suggest pre-Kayak(?) (Upper Devonian) granite emplacement. The pluton is interpreted to be essentially the product of melt crystallization, synorogenically emplaced by forceful injection with minor stoping, and may include marginally granitized rock. Mafic igneous rocks of altered basaltic composition (greenstones) include dikes in granitic and Neruokpuk Formation rocks, and volcanics(?). A late Paleozoic age is suggested for them. Structural grain strikes east-northeast; south-dipping elements are common. Structures include the major positive nature of the area (first order), relatively broad folds (second order) which contain small tight folds (third order). Related south-dipping cleavage, schistosity, and biotite foliation in granite in the northern part of the area are cut by prominent sets of transverse joints and faults. Other features are longitudinal normal and reverse faults, at least one large-scale overthrust fault, and sheared zones in granite with possible attendant retrograde metamorphism. Although Mesozoic and Tertiary deformational features are dominant in northern Alaska, the Romanzof area may have been part of a Late Devonian orogenic belt continuous with one in northern Canada. Three alternate trends of such a belt in northern Alaska are discussed, but evidence is inconclusive. The mineral potential of the area is largely unknown. Minor amounts of metallic sulfides and oxides are present in granite and Neruokpuk Formation rocks. Analyses of stream silt samples suggest the possibility of tin and beryllium potential. The Shublik Formation contains rock phosphate.

Alaska

Inferring fault rheology from low-frequency earthquakes on the San Andreas

Families of recurring low-frequency earthquakes (LFEs) within nonvolcanic tremor (NVT) on the San Andreas fault in central California show strong sensitivity to shear stress induced by the daily tidal cycle. LFEs occur at all levels of the tidal shear stress and are in phase with the very small, ~400 Pa, stress amplitude. To quantitatively explain the correlation, we use a model from the existing literature that assumes the LFE sources are small, persistent regions that repeatedly fail during shear of a much larger scale, otherwise aseismically creeping fault zone. The LFE source patches see tectonic loading, creep of the surrounding fault which may be modulated by the tidal stress, and direct tidal loading. If the patches are small relative to the surrounding creeping fault then the stressing is dominated by fault creep, and if patch failure occurs at a threshold stress, then the resulting seismicity rate is proportional to the fault creep rate or fault zone strain rate. Using the seismicity rate as a proxy for strain rate and the tidal shear stress, we fit the data with possible fault rheologies that produce creep in laboratory experiments at temperatures of 400 to 600°C appropriate for the LFE source depth. The rheological properties of rock-forming minerals for dislocation creep and dislocation glide are not consistent with the observed fault creep because strong correlation between small stress perturbations and strain rate requires perturbation on the order of the ambient stress. The observed tidal modulation restricts ambient stress to be at most a few kilopascal, much lower than rock strength. A purely rate dependent friction is consistent with the observations only if the product of the friction rate dependence and effective normal stress is ~ 0.5 kPa. Extrapolating the friction rate strengthening dependence of phyllosilicates (talc) to depth would require the effective normal stress to be ~50 kPa, implying pore pressure is lithostatic. If the LFE source is on the order of tens of meters, as required by the model, rate-weakening friction rate dependence (e.g., olivine) at 400 to 600°C requires that the minimum effective pressure at the LFE source is ~ 2.5 MPa.

California

Geohydrologic use of lithofacies maps in glaciated areas

Subsurface conditions may differ considerably from conditions indicated by surficial geologic maps, particularly in glaciated areas. Therefore, it is advantageous to use a series of lithofacies maps as a sequence of overlays plotted on transparent paper. Such maps permit direct visual determination of the lithology and areal extent of aquifers and indicate areas of possible stream losses or gains. They indicate areas and boundaries of confining layers and, in some places, they may be used to delineate areas of water-table and artesian conditions. They are especially useful in determining buried channels in glaciated areas. The porosity of rock units making up an aquifer may be plotted on a lithofacies map, and the product of the volume of each lithologic type and the porosity provides an estimate of the total water in storage. In addition, if the water-bearing properties are known, the quantity of water moving through an aquifer and the amount available to wells may be determined. Lithofacies maps also aid in the explanation of complex changes in water quality.

Water Resources Research

Analysis of vegetation recovery surrounding a restored wetland using the normalized difference infrared index (NDII) and normalized difference vegetation index (NDVI)

Watershed restoration efforts seek to rejuvenate vegetation, biological diversity, and land productivity at Cienega San Bernardino, an important wetland in southeastern Arizona and northern Sonora, Mexico. Rock detention and earthen berm structures were built on the Cienega San Bernardino over the course of four decades, beginning in 1984 and continuing to the present. Previous research findings show that restoration supports and even increases vegetation health despite ongoing drought conditions in this arid watershed. However, the extent of restoration impacts is still unknown despite qualitative observations of improvement in surrounding vegetation amount and vigor. We analyzed spatial and temporal trends in vegetation greenness and soil moisture by applying the normalized difference vegetation index (NDVI) and normalized difference infrared index (NDII) to one dry summer season Landsat path/row from 1984 to 2016. The study area was divided into zones and spectral data for each zone was analyzed and compared with precipitation record using statistical measures including linear regression, Mann– Kendall test, and linear correlation. NDVI and NDII performed differently due to the presence of continued grazing and the effects of grazing on canopy cover; NDVI was better able to track changes in vegetation in areas without grazing while NDII was better at tracking changes in areas with continued grazing. Restoration impacts display higher greenness and vegetation water content levels, greater increases in greenness and water content through time, and a decoupling of vegetation greenness and water content from spring precipitation when compared to control sites in nearby tributary and upland areas. Our results confirm the potential of erosion control structures to affect areas up to 5 km downstream of restoration sites over time and to affect 1 km upstream of the sites.

Cuenca Los Ojos, San Bernardino National Wildlife