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At least 343 records · Page 19Linked to original sources
USGS1992

The stable isotope geochemistry of acid sulfate alteration

Acid sulfate wall-rock alteration, characterized by the assemblage alunite + kaolinite + quartz + or - pyrite, results from base leaching by fluids concentrated in H 2 SO 4 . Requisite amounts of H 2 SO 4 can be generated by different mechanisms in three principal geologic environments: (1) by atmospheric oxidation of sulfides in the supergene environment, (2) by atmospheric oxidation at the water table in the steam-heated environment of H 2 S released by deeper, boiling fluids, and (3) by the disproportionation of magmatic SO 2 to H 2 S and H 2 SO 4 during condensation of a magmatic vapor plume at intermediate depths in magmatic hydrothermal environments in silicic and andesitic volcanic terranes. In addition, coarse vein alunite may form in a magmatic steam environment from rapid release of an SO 2 -rich magmatic vapor phase at high temperature and low pressure or from the oxidation of a more reduced magmatic vapor by entrained atmospheric oxygen in the carapace of a volcanic edifice.Alunite [KAl 3 (SO 4 ) 2 (OH) 6 ] contains four stable isotope sites and complete analyses (delta D, delta 18 O (sub SO 4 ) , delta 18 O OH , and delta 34 S) are now possible. Except for delta 18 O OH in magmatic hydrothermal alunites, primary values are usually retained. In cooperation with many colleagues, over 500 measurements have been made on nearly 200 samples of alunite and associated minerals from 23 localities, and 55 additional analyses have been taken from the literature. This survey confirms that kinetic factors play an important role in the stable isotope systematics of alunite and acid sulfate alteration. To a very large extent they form the isotopic basis for distinguishing between environments of acid sulfate alteration, and they provide important insights into attendant processes. Stable isotope analyses of alunite, often in combination with those on associated sulfides and kaolinite, permit recognition of environments of formation and provide information on origins of components, processes (including rates), physical-chemical environments, and temperatures of formation.Supergene acid sulfate alteration may form over any sulfide zone when it is raised above the water table by tectonics or exposed by erosion. It may overprint earlier acid sulfate assemblages, particularly the magmatic hydrothermal assemblages which are pyrite rich such as at El Salvador, Chile; Rodalquilar, Spain; and Goldfield, Nevada. Supergene alunite normally has delta 34 S values virtually identical to precursor sulfides unless bacteriogenic reduction of aqueous sulfate takes place in standing pools of water. delta D values are close to that of local meteoric water unless extensive evaporation occurs. delta D and delta 18 O OH values of supergene alunites from a range of latitudes fall in a broad zone parallel to the meteoric water line much the way delta D and delta 18 O values of associated halloysite-kaolinite fall near the kaolinite line of Savin and Epstein (1970). delta 18 O (sub SO 4 ) values are kinetically controlled and will reflect the hydro-geochemistry of the environment. delta 18 O (sub SO 4 -OH) alues are grossly out of equilibrium and large negative values are definitive of a supergene origin.In steam-heated environments, such as those at the Tolfa district, Italy, and Marysvale, Utah, and numerous modern geothermal systems, acid sulfate alteration zones are characterized by pronounced vertical zoning. Such acid sulfate alteration may occur over adularia-sericite-type base and precious metal ore deposits such as the one at Buckskin, Nevada. Initial delta 18 O (sub SO 4 ) and delta 34 S values are kinetically controlled, but delta 18 O (sub SO 4 ) values usually reach equilibrium with fluids, and even delta 34 S values may reflect partial exchange with H 2 S where the residence time of aqueous sulfate is sufficient. Most alunites of steam-heated origin have delta 34 S values the same as those of precursor H 2 S (and as related sulfides, if present) and delta D values similar to that of local meteoric water. In the samples analyzed, most delta 18 O (sub SO 4 -OH) values give reasonable temperatures of 90 degrees to 160 degrees C, indicating that delta 18 O (sub SO 4 ) and delta 18 O OH values reflect a close approach to equilibrium with the fluid. The delta 18 O (sub SO 4 ) and delta 18 O OH values also reflect the degree of exchange of the meteoric fluids with wall rock. Coeval kaolinites typically have delta 18 O and delta D values to the left of the kaolinitc line.Magmatic hydrothermal, acid sulfate alteration zones in near-surface epithermal deposits such as Summitville, Colorado. Julcani, Peru, and Red Mountain and Lake City, Colorado, are characterized by vertical orientation and horizontal zoning, the presence of coeval pyrite, PO 4 analogues of alunite, zunyite, and later gold, pyrite and enargite, and often other Cu-As-Sb-S minerals. Acid sulfate alteration assemblages also occur as late stages in the porphyry-copper deposit at E1 Salvador, Chile. In the examples studied, magmatic hydrothermal alunites have delta D values close to those for magmatic water. delta 34 S values are 16 to 28 per mil larger than those for associated pyrite, reflecting equilibrium between aqueous H 2 S and SO 4 formed by the disproportionation of magmatically derived SO 2 . delta 18 O (sub SO 4 ) values are usually 8 to 18 per mil and vary systematically with delta 34 S values, reflecting variations in temperature and/or H 2 S/SO 4 fluid ratios. Further variation in delta 18 O (sub SO 4 ) values may result if SO 2 condenses in mixed magmatic meteoric water fluids. delta 18 O (sub SO (sub 4-) OH) values of magmatic hydrothermal alunites are generally unsuitable for temperature determinations because of retrograde exchange in the OH site, but delta 34 S (sub alunite-pyrite) values provide reliable temperature estimates.Magmatic steam environments appear to occur over a range of depths and are characterized by monomineralic veins of coarse alunite in variably alunitized and kaolinized wall rocks containing minor pyrite. Alunite formed in the magmatic steam environment can usually be recognized by delta 34 S near delta 34 S (sub Sigma S) values and delta D and delta 18 O (sub SO 4 ) values near magmatic values. Magmatic steam alunite differs from magmatic hydrothermal alunite by having delta 34 S close to delta 34 S (sub Sigma S) values of the system. delta 18 O (sub SO (sub 4-) OH) values of most magmatic steam alunite give temperatures ranging from 90 degrees to 210 degrees C but, for reasons which are not understood, some temperatures as well as calculated delta 18 O (sub H 2 O) values are too low for presumed precipitation from a magmatic vapor phase. Magmatic steam environments may occur over porphyry-type mineralization as at Red Mountain, Colorado, and Alunite Ridge, Utah, and over or adjacent to adularia-sericite-type deposits in volcanic domes as at Cactus, California.

Economic Geology↗
USGS2025

Widespread occurrence of former anhydrite phenocrysts in Laramide-age magmas related to porphyry-skarn Cu mineralization at Santa Rita and Hanover-Fierro, New Mexico, USA

Reports of magmatic anhydrite are relatively rare, with only ~30 occurrences documented worldwide so far. However, magmatic anhydrite saturation is difficult to recognize because anhydrite decomposes rapidly in near-surface environments. In most cases, only anhydrite inclusions shielded within other phenocryst phases were able to survive. Alternatively, since anhydrite phenocrysts preserved in fresh volcanic rocks are characteristically intergrown with apatite phenocrysts, the former presence of anhydrite phenocrysts can be recognized based on the occurrence of lath-shaped cavities that show a strong spatial association with apatite phenocrysts. These cavities can be either empty or filled with low-temperature, secondary minerals such as zeolites, carbonates, or microcrystalline silica. A systematic search for the occurrence of such cavities, combined with optical and Raman-spectroscopic identification of anhydrite inclusions preserved within apatite, hornblende and quartz phenocrysts, demonstrates that most of the Laramide-age magmas associated with the Santa Rita and Hanover-Fierro porphyry-skarn Cu (Zn, Mo, Au, Pb) deposits were saturated in magmatic anhydrite. The anhydrite typically coexisted with monosulfide solid solution (MSS), suggesting oxygen fugacities of ~2.0±0.5 log units above the fayalite-magnetite-quartz buffer. The magmas range from andesitic to rhyodacitic in composition, and from shortly pre-mineralization (~61 Ma) to shortly post-mineralization (~57 Ma) in age. In three samples with particularly well-recognizable former anhydrite phenocrysts, their modal abundance could be quantified based on high-resolution scans of polished hand specimens. The observed modal anhydrite abundances of 0.63–1.8 vol% translate into minimum magma sulfur contents of 0.20–0.56 wt% S. The highest sulfur content of 0.56 wt% S is difficult to reconcile with available anhydrite solubility models, but it could be reproduced in an anhydrite solubility experiment performed at 950 °C and 1.15 GPa on a natural latite containing 13.1 wt% dissolved H2O. The sample with the second-highest sulfur content of 0.26 wt% S requires ~10 wt% H2O in the silicate melt, and, consequently, a minimum pressure of ~0.5 GPa. Taken together, the results suggest that the magmas of the Central Mining District were extremely hydrous and thus originated from great depth. Indeed, their major element compositions and reconstructed H2O and S contents agree well with experimentally observed and numerically predicted compositions of residual silicate melts after 50–70 wt% crystallization of ordinary arc basalts at high pressure and high oxygen fugacities.

New Mexico↗
USGS2017

Planting richness affects the recovery of vegetation and soil processes in constructed wetlands following disturbance

The resilience of constructed wetland ecosystems to severe disturbance, such as a mass herbivory eat-out or soil disturbance, remains poorly understood. In this study, we use a controlled mesocosm experiment to examine how original planting diversity affects the ability of constructed freshwater wetlands to recover structurally and functionally after a disturbance (i.e., aboveground harvesting and soil coring). We assessed if the planting richness of macrophyte species influences recovery of constructed wetlands one year after a disturbance. Mesocosms were planted in richness groups with various combinations of either 1, 2, 3, or 4 species (RG 1–4) to create a gradient of richness. Structural wetland traits measured include morphological regrowth of macrophytes, soil bulk density, soil moisture, soil %C, and soil %N. Functional wetland traits measured include above ground biomass production, soil potential denitrification, and soil potential microbial respiration. Total mesocosm cover increased along the gradient of plant richness (43.5% in RG 1 to 84.5% in RG 4) in the growing season after the disturbance, although not all planted individuals recovered. This was largely attributed to the dominance of the obligate annual species. The morphology of each species was affected negatively by the disturbance, producing shorter, and fewer stems than in the years prior to the disturbance, suggesting that the communities had not fully recovered one year after the disturbance. Soil characteristics were almost uniform across the planting richness gradient, but for a few exceptions (%C, C:N, and non-growing season soil moisture were higher slightly in RG 2). Denitrification potential (DEA) increased with increasing planting richness and was influenced by the abundance and quality of soil C. Increased open space in unplanted mesocosms and mesocosms with lower species richness increased labile C, leading to higher C mineralization rates.

Science of the Total Environment↗
USGS1977

Review and analysis of hydrogeologic conditions near the site of a potential nuclear-waste repository, Eddy and Lea counties, New Mexico

This interim report reviews and summarizes the hydrogeology of rocks associated with the Permian salt beds (Castile and Salado Formations) of Los Medanos area in southeastern New Mexico. The information will be considered, together with other factors, in the preparation of an analysis of the impact of a potential nuclear-waste repository on the environment. Most of the geologic units in and adjacent to the Permian salt deposits are characterized by low permeabilities and highly mineralized water. Sandstone of the Delaware Mountain Group, which underlies the salt, has an average hydraulic conductivity of 0.16 ft/d and an average porosity of 15.65 percent. Flow is north-northeastward toward the margin of the Capitan Limestone, at velocities ranging from 0.0005 to 0.0008 ft/d. The Capitan Limestone, a relatively high yielding limestone-reef aquifer adjacent to the study area, has transmissivity values ranging from 500 sq ft/d to 10,000 sq ft/d and an average hydraulic conductivity of about 5 ft/d. Water movement west of the Pecos River is northeastward in the reef, with discharge at Carlsbad Springs. East of the Pecos River, water moves at very low rates and the direction of movement is uncertain. The Castile and Salado Formations, which might be used to contain the nuclear waste, have a few isolated pockets of brine and gas, but generally transmit little or no ground water. (Woodard-USGS)

Open-File Report↗
USGS1982

Drilling results at the Farah Garan ancient mine, southwestern Saudi Arabia

The Farah Garan ancient mine is located at fat 17?41'00'' N., long 43?38'15'' E. in the southwestern part of the Kingdom of Saudi Arabia. Three diamond drill holes intersected base-metal sulfides, which are present both as conformable layers in Precambrian tuffaceous volcanic rocks and as fracture fillings, irregularly shaped masses, disseminations, and clots in intensely hydrothermally altered and brecciated fault zones. The sulfides probably formed through volcanic processes in a shallow-marine environment and subsequently were greatly modified by tectonism and hydrothermal activity. Drill hole F.G.-1 intersected sparse base and precious metal minerals along a length of 30 m; several narrow, isolated zones contain as much as 22 grams per metric ton (g/t) silver, 1.25 percent copper, and 3.10 percent zinc. Drill hole F.G.-2 intersected low-grade base and precious metal minerals along a length of 50 m. Within this zone, a 10-m interval contains an average of 0.15 g/t gold, 10.7 g/t silver, and 0.86 percent zinc. Drill hole F.G.-3 cut commercial-grade base and precious metal minerals in a 3.55-m interval that contains an average of 20.06 g/t gold, 32.75 g/t silver, and 6.28 percent zinc. Additional exploration, including drilling and laboratory studies, is recommended to further define potential tonnages of base and precious metals intersected in drill hole F.G.-3 and to learn more about their genesis and mineral form. Arsenic and antimony are locally abundant in both drillcore and surface samples. Because of its weathering characteristics, mobility, and association with precious metals, arsenic commonly is a pathfinder for gold. Approximately 1,100 splits of surface samples collected in the Farah Garan area are stored at the Directorate General of Mineral Resources-U. S. Geological Survey chemical laboratory in Jiddah, and any further exploration should include assaying these samples for arsenic and antimony by wet-chemical analysis ?

Open-File Report↗
USGS2018

Sulfur cycle in the Valles Caldera volcanic complex, New Mexico – Letter 1: Sulfate sources in aqueous system, and implications for S isotope record in Gale Crater on Mars

Initial in situ sulfur (S) isotope measurements of the Martian bedrock in Gale Crater have revealed an unexpectedly wide range of δ 34 S values (−47 to +28%). Generally, it is unclear what processes could have contributed to these large isotope fractionations. Therefore, we studied S sources and aqueous SO 2− 4 cycling in the Valles Caldera volcanic complex, New Mexico to better understand S isotope fractionations related to S degassing, hydrothermal activity, and low-temperature processes in aqueous environment. Overall, our study demonstrates that volcanic systems show large spatial heterogeneity in δ 34 S. Magmatic S sources are obvious in steam-dominated H 2 S degassing and precipitation of secondary minerals from hydrothermal fluids with low δ 34 S values of +0.9 ±3%. Locally, however, hydrothermal processes have resulted in more negative δ 34 S values in sulfide minerals (−18 to −4%) and more positive δ 34 S values in sulfate minerals (−1 to +3%). Major aqueous SO 2− 4 sources are oxidation of H 2 S from modern hydrothermal gas emission, and oxidation and dissolution of sulfide and sulfate minerals present in the hydrothermally altered bedrock and crater-lake sediments. The δ 34 S of aqueous SO 2− 4 in surface water and groundwater varies widely (−8 to +5%) and is similar to major S endmembers that undergo oxidation and/or dissolution by active hydrological system. Minor SO 2− 4 contributions with more positive δ 34 S values (+9 to +14%) come from deeply circulating geothermal fluids and negligible amounts from atmospheric deposition (+5 to +7% in snow). Elevated SO 2− 4 contents are mainly associated with modern and past H 2 S emissions and oxidations near the surface. On regional scale, however, most of the intracaldera bedrock is S-depleted, thus the SO 2− 4 contents are usually low in the surface aquatic system and younger sedimentary lake deposits formed at times of negligible near surface hydrothermal activity. In general, magmatic-hydrothermal processes apparently cause the largest δ 34 S variation in S-bearing minerals on volcanic terrains. Therefore, we infer that the measured wide range of δ 34 S values in the Gale sediments by the Curiosity rover on Mars can be explained by S isotope composition of magmatic-hydrothermal sulfide and sulfate minerals that were present in the initial igneous/volcanic rocks prior to crater formation. Later aqueous processes involved oxidation and dissolution of S minerals initially present in these rocks and led to subsequent formation of diagenetic fluids and alteration products enriched in SO 2− 4 with relatively large δ 34 S variation. Additionally, physical erosion, transport and deposition of detrital hydrothermal S minerals from igneous/volcanic rocks might be in part responsible for the measured wide range of δ 34 S in Gale Crater. These unique S isotope results, measured in situ on another planet for the first time, imply the importance of magmatic-hydrothermal fluids in S transport on early Mars and their subsequent alteration in low-temperature aqueous environments.

New Mexico↗
USGS2009

Process recognition in multi-element soil and stream-sediment geochemical data

Stream-sediment and soil geochemical data from the Upper and Lower Coastal Plains of South Carolina (USA) were studied to determine relationships between soils and stream sediments. From multi-element associations, characteristic compositions were determined for both media. Primary associations of elements reflect mineralogy, including heavy minerals, carbonates and clays, and the effects of groundwater. The effects of groundwater on element concentrations are more evident in soils than stream sediments. A "winnowing index" was created using ratios of Th to Al that revealed differing erosional and depositional environments. Both soils and stream sediments from the Upper and Lower Coastal Plains show derivation from similar materials and subsequent similar multi-element relationships, but have some distinct differences. In the Lower Coastal Plain, soils have high values of elements concentrated in heavy minerals (Ce, Y, Th) that grade into high values of elements concentrated into finer-grain-size, lower-density materials, primarily comprised of carbonates and feldspar minerals (Mg, Ca, Na, K, Al). These gradational trends in mineralogy and geochemistry are inferred to reflect reworking of materials during marine transgressions and regressions. Upper Coastal Plain stream-sediment geochemistry shows a higher winnowing index relative to soil geochemistry. A comparison of the 4 media (Upper Coastal Plain soils and stream sediments and Lower Coastal Plain soils and stream sediments) shows that Upper Coastal Plain stream sediments have a higher winnowing index and a higher concentration of elements contained within heavy minerals, whereas Lower Coastal Plain stream sediments show a strong correlation between elements typically contained within clays. It is not possible to calculate a functional relationship between stream sediment-soil compositions for all elements due to the complex history of weathering, deposition, reworking and re-deposition. However, depending on the spatial separation of the stream-sediment and soil samples, some elements are more highly correlated than others. Crown Copyright ?? 2009.

Applied Geochemistry↗
USGS2010

Geology, geochemistry, and genesis of the Greens Creek massive sulfide deposit, Admiralty Island, southeastern Alaska

In 1996, a memorandum of understanding was signed by representatives of the U.S. Geological Survey and Kennecott Greens Creek Mining Company to initiate a cooperative applied research project focused on the Greens Creek massive sulfide deposit in southeastern Alaska. The goals of the project were consistent with the mandate of the U.S. Geological Survey Mineral Resources Program to maintain a leading role in national mineral deposits research and with the need of Kennecott Greens Creek Mining Company to further development of the Greens Creek deposit and similar deposits in Alaska and elsewhere. The memorandum enumerated four main research priorities: (1) characterization of protoliths for the wall rocks, and elucidation of their alteration histories, (2) determination of the ore mineralogy and paragenesis, including metal residences and metal zonation within the deposit, (3) determination of the ages of events important to ore formation using both geochronology and paleontology, and (4) development of computer models that would allow the deposit and its host rocks to be examined in detail in three dimensions. The work was carried out by numerous scientists of diverse expertise over a period of several years. The written results, which are contained in this Professional Paper, are presented by 21 authors: 13 from the U.S. Geological Survey, 4 from Kennecott Greens Creek Mining Company, 2 from academia, and 2 from consultants. The Greens Creek deposit (global resource of 24.2 million tons at an average grade of 13.9 percent zinc, 5.1 percent lead, 0.15 troy ounce per ton gold, and 19.2 troy ounces per ton silver at zero cutoff) formed in latest Triassic time during a brief period of rifting of the Alexander terrane. The deposit exhibits a range of syngenetic, diagenetic, and epigenetic features that are typical of volcanogenic (VMS), sedimentary exhalative (SEDEX), and Mississippi Valley-type (MVT) genetic models. In the earliest stages of rifting, formation of precious-metal-rich silica-barite-carbonate white ores began at low temperature in a shallow, subaqueous setting, probably a thin carbonate shelf on the flanks of the Alexander landmass. Epigenetic carbonate replacement textures in the footwall dolostones are overlain by stratiform silica-carbonate-barite-rich ores and indicate that early mineralization formed at and just beneath the paleo sea floor by mixing of a reduced, precious-metal-rich, base-metal-poor hydrothermal fluid with oxygenated seawater. As rifting intensified, the shelf was downfaulted and isolated as a graben. Isolation of the basin and onset of starved-basin shale sedimentation was concurrent with emplacement of mafic-ultramafic intrusives at shallow levels in the rift, resulting in an increasingly higher temperature and progressively more anoxic ore-forming environment. The formation of the main stage of massive sulfide ores began as the supply of bacterially reduced sulfur increased in the accumulating shales. As the main-stage mineralization intensified, shale sedimentation inundated the hydrothermal system, eventually forming a cap. Biogenic sulfate reduction supplied reduced sulfur to the base of the shales where mixing occurred with hot, base-metal-rich hydrothermal fluids. Ore deposition continued by destruction and epigenetic replacement of the early white ores in proximal areas and by inflation and diagenetic replacement of unlithified shale at the interface between the white ores and the base of the shale cap. Ore deposition waned as the shales became lithified and as the supply of bacterially reduced sulfur to the site of ore deposition ceased. The final stages of rifting resulted in the emplacement of mafic-ultramafic intrusive rocks into the Greens Creek system and extrusion of voluminous basaltic flows at the top of the Triassic section. Greenschist facies metamorphism during the Jurassic-Cretaceous accretion of the Alexander terrane to the continental margin resulted in recrystalli

Professional Paper↗
USGS1979

Progress in remote sensing as it applies to missions of Committee for Coordination of Joint Prospecting for Mineral Resources in Asian Offshore Areas

The major thrusts of investigations of the use of space data for understanding our Earth continue to focus on the land and near-shore environments. This is expectable; people live on the land, draw most of their resources from the land or near-shore areas, and in these areas environmental degradation or improvement are most clearly observable. An exception to this focus of investigation was the launch of Seasat, a satellite dedicated to marine investigations. Seasat was short lived but the data produced strongly supported the use of imaging radar for land investigation, and, although studies are incomplete, suggest eventual benefits for the navigator, searchers for marine resources, and mariners--provided that the data and/or interpretations can be available to the marine users shortly after collection. In this regard, the positive steps now being taken in Southeast Asia to establish reception, processing, and interpretation centers are a major development.

Open-File Report↗
USGS1980

Intrusions and intrusive complexes in an ophiolite near San Luis Obispo; a chemical and petrologic study

The San Luis Obispo ophiolite is a sequence of mafic and ultramafic rocks that lie as a thrust-like slice on top of Franciscan melange in the southern California Coast Range. The ophiolite comprises the classic Steinmann Trinity of basal serpentinized ultramafic rocks overlain sequentially by spilitized pillow lavas and cherts. The ophiolite is intruded by numerous diabasic dikes and several large intrusive complexes that contain peridotite, gabbro, diabase and felsic rocks. Field relations indicate that this ophiolite originated as a sequence of submarine volcanic flows and breccia units extruded onto an ultramafic basement. Later the volcanic and ultramafic rocks were intruded along their contact by mafic magma that crystallized as a stratiform complex of cumulate peridotite and gabbro. Next, this stratiform complex was intruded by diorite and albite-granite (trondhjemite) sills, which may have been produced by partial melting of gabbros in the upper levels of the stratiform complex. Finally all earlier units were intruded by diabasic sills and dikes that probably were late feeders for the pre-existing volcanic unit. All the ophiolite rocks underwent subsequent highly localized brecciation, under greenschist-facies conditions, in which felsic rocks were incipiently melted by frictional heating. The host rocks and intrusions were metamorphosed at low temperature and the mafic rocks were altered by Na- and Si-metasomatism. Despite this pervasive alteration, evidences of the formational stages of the ophiolite are preserved in disequilibrium mineral assemblages, primarily within mafic and ultramafic rocks of the intrusive complexes. Whole-rock analyses of the ophiolite suite indicate that alteration has obscured but not obliterated the original chemical character of the mafic rocks. The ophiolite diabases and basalts contain up to 6 weight percent Na 2 0 and 58 percent Si0 2 , in contrast to normal Si0 2 contents of 50 percent or less and Na 2 0 contents of less than 3 percent for unaltered oceanic and continental tholeiite basalts. However, the low K 2 0 contents (less than 0.8 percent) of all units in the ophiolite suite indicate that these rocks are not part of an alkalic kindred, but rather are altered tholeiites. Compositions of relict amphibole and plagioclase in the mafic rocks indicate that the ophiolite formed in a high-temperature environment and the deep seated rocks were metamorphosed under amphibolite-facies conditions. A later change in the environmental conditions allowed subsequent low-temperature (greenschist facies) metamorphism and metasomatism. The structure and chemistry of the San Luis Obispo ophiolite support the hypothesis that this body may represent a fragment of oceanic crust and mantle. The volcanic rocks and the intrusive complexes probably formed at a mid-ocean ridge, where conditions of high heat-flow provided the requisite high-temperature environment and promoted the production of mafic magmas. The change to low-temperature conditions probably was due to inception or acceleration of crustal spreading at that portion of the ridge where this ophiolite formed. The nature of brecciation in the ophiolite indicates that the low-temperature environment also was one of greater tectonic disturbance, relative to conditions at the ridge. This tectonically active environment probably corresponds to an island arc where the ophiolite-bearing plate was subducted in an adjacent trench. The absence of a high-pressure mineral assemblage in the San Luis Obispo ophiolite suggests that this segment of ocean-crust and upper mantle was not buried in a subduction zone, but rather was rafted on top of subduction melange (Franciscan Formation) into its present position.

California↗
USGS2000

Applications of imaging spectroscopy data: A case study at Summitville, Colorado

From 1985 through 1992, the Summitville open-pit mine produced gold from lowgrade ore using cyanide heap-leach techniques, a method to extract gold whereby the ore pile is sprayed with water containing cyanide, which dissolves the minute gold grains. Environmental problems due to mining activity at Summitville include significant increases in acidic and metal-rich drainage from the site, leakage of cyanide-bearing solutions from the heap-leach pad into an underdrain system, and several surface leaks of cyanide-bearing solutions into the Wightman Fork of the Alamosa River. In general, drainage from the Summitville mine moves downslope into the Wightman Fork, a small tributary of the Alamosa River, which in turn flows east into the Terrace Reservoir before entering the agricultural lands of the San Luis Valley. The increase in the trace-metal burden of the Alamosa River watershed due to the mining activities at Summitville is of concern to farmers and fisherman, as well as Federal and State of Colorado agencies having responsibility for land stewardship. The environment of the Summitville area is a result of 1) its geologic evolution, that culminated in the formation of precious-metal mineral deposits; and 2) previous metal mining activity. Mining accentuates, accelerates, and pertubates natural geochemical processes. The development of underground workings, open pits, mill tailings, and spoil heaps and the extractive processing of ore enhances the likelihood of releasing chemicals and elements to the surrounding areas and at increased rates relative to unmined areas. Both mined and unmined mineralized areas can produce acid drainage from the formation and movement of highly acidic water rich in heavy metals. This acidic water forms principally through the chemical reaction of oxygenated surface water and shallow subsurface water with rocks that contain sulfide minerals, producing sulphuric acid. Heavy metals can be leached by the acid solution that comes in contact with mineralized rocks, a process that may be enhanced by bacterial action. The resulting fluids may be highly toxic and, when mixed with groundwater, surface water, and soil, may have harmful effects on humans, animals, and plants. Thus, understanding the geologic and hydrologic history of this area is a critical piece of the environmental puzzle in the Summitville area. The Summitville mine operators had ceased active mining and begun environmental remediation, including treatment of the heap-leach pile and installation of a water-treatment facility, when it declared bankruptcy in December 1992 and abandoned the mine site. The U.S. Environmental Protection Agency (EPA) immediately took over the Summitville site under EPA Superfund Emergency Response authority. Summitville has focused public attention on the environmental effects of modern mineral-resource development. Soon after the mine was abandoned, Federal, State, and local agencies, along with Alamosa River water users and private companies, began extensive studies at the mine site and surrounding areas. These studies included analysis of water, soil, livestock and vegetation. The role of the U.S. Geological Survey (USGS) was to provide geologic, hydrologic and agricultural information about the mine and surrounding area and to describe and evaluate the environmental condition of the Summitville mine and the downstream effects of the mine on the San Luis Valley (King 1995).

Colorado↗
USGS2010

Mineralogical and chemical characteristics of some natural jarosites

This paper presents a detailed study of the mineralogical, microscopic, thermal, and spectral characteristics of jarosite and natrojarosite minerals. Systematic mineralogic and chemical examination of a suite of 32 natural stoichiometric jarosite and natrojarosite samples from diverse supergene and hydrothermal environments indicates that there is only limited solid solution between Na and K at low temperatures, which suggests the presence of a solvus in the jarosite-natrojarosite system at temperatures below about 140 C. The samples examined in this study consist of either end members or coexisting end-member pairs of jarosite and natrojarosite. Quantitative electron-probe microanalysis data for several natural hydrothermal samples show only end-member compositions for individual grains or zones, and no detectable alkali-site deficiencies, which indicates that there is no hydronium substitution within the analytical uncertainty of the method. In addition, there is no evidence of Fe deficiencies in the natural hydrothermal samples. Hydronium-bearing jarosite was detected in only one relatively young supergene sample suggesting that terrestrial hydronium-bearing jarosites generally are unstable over geologic timescales. Unit-cell parameters of the 20 natural stoichiometric jarosites and 12 natural stoichiometric natrojarosites examined in this study have distinct and narrow ranges in the a- and c-cell dimensions. There is no overlap of these parameters at the 1r level for the two end-member compositions. Several hydrothermal samples consist of fine-scale (2–10 lm) intimate intergrowths of jarosite and natrojarosite, which could have resulted from solid-state diffusion segregation or growth zoning due to variations in the Na/K activity ratio of hydrothermal solutions.

Geochimica et Cosmochimica Acta↗
USGS2023

Triple oxygen isotope compositions of globally distributed soil carbonates record widespread evaporation of soil waters

The stable isotopic composition of pedogenic carbonates is central to many studies of past climate and topography, providing a basis for our understanding of Earth's terrestrial history. A core assumption of many applications of oxygen isotope values (δ18O) of pedogenic carbonate is that they reflect the δ18O value of precipitation (rain/snow). This assumption is violated if soil carbonates form in evaporated soil waters. In this work, we develop a means to identify evaporation in ancient soils using the triple oxygen isotope composition (16O-17O-18O) of pedogenic carbonates. Both theoretical predictions of isotope kinetics during evaporation and studies of triple oxygen isotopes in other geological materials show that the deviation in the relationship between δ17O and δ18O from a reference line, evaluated using the parameter Δ'17O, is sensitive to evaporation. As a first step in developing the use of Δ'17O in ancient pedogenic carbonates, we report Δ'17O values from 47 near-modern pedogenic carbonate samples from globally distributed environments that vary in aridity (hyper-arid to humid). The Δ'17O values of pedogenic carbonate range from -154 to -60 per meg (as CaCO3, measured via O2, VSMOW-SLAP), corresponding to calculated soil water values of -66 to +27 per meg (VSMOW-SLAP) (using a carbonate-water triple oxygen isotope fractionation exponent of 0.5250 and clumped isotope-derived carbonate growth temperatures). The Δ'17O values indicate that evaporative modification of soil water from which pedogenic carbonate forms is common, especially in arid environments. Arid environments host pedogenic carbonates formed from soil waters ranging from highly to minimally evaporated, while humid environments host pedogenic carbonates formed from waters that are only minimally evaporated. The variability in Δ'17O within environments classified by the same aridity may relate to the fact that pedogenic carbonates record soil conditions only during times of carbonate mineralization, which may deviate from annual conditions. Thus, Δ'17O may be useful in understanding the specific circumstances of pedogenic carbonate formation but may not provide incontrovertible evidence of the magnitude of environmental aridity. Evaporative modification of δ18O values of pedogenic carbonates can be detected with Δ'17O, thereby improving estimates of δ18O of unevaporated waters. Our data show that evaporation must be (re)considered for all paleoclimate inferences based on the δ18O of pedogenic carbonate. The addition of Δ'17O will re-energize paleoclimate studies that use (or have avoided using) δ18O of pedogenic carbonate.

Geochimica et Cosmochimica Acta↗
USGS2022

Primary deposition and early diagenetic effects on the high saturation accumulation of gas hydrate in a silt dominated reservoir in the Gulf of Mexico

On continental margins, high saturation gas hydrate systems (>60% pore volume) are common in canyon and channel environments within the gas hydrate stability zone, where reservoirs are dominated by coarse-grained, high porosity sand deposits. Recent studies, including the results presented here, suggest that rapidly deposited, silt-dominated channel-levee environments can also host high saturation gas hydrate accumulations. Here we present several sedimentological data sets, including sediment composition, biostratigraphic age from calcareous nannofossils, grain size, total organic carbon (TOC), C/N elemental ratio, δ 13 C-TOC , CaCO 3 , total sulfur (TS), and δ 34 S-TS from sediments collected with pressure cores from a gas hydrate rich, turbidite channel-levee system in the Gulf of Mexico during the 2017 UT-GOM2-1 Hydrate Pressure Coring Expedition. Our results indicate the reservoir is composed of three main lithofacies, which have distinct sediment grain size distributions (type A-silty clay to clayey silt, type B-clayey silt, and type C-sandy silt to silty sand) that are characteristic of variable turbidity current energy regimes within a Pleistocene (< 0.91 Ma) channel-levee environment. We document that the TOC in the sediments of the reservoir is terrestrial in origin and contained within the fine fraction of each lithofacies, while the CaCO 3 fraction is composed of primarily reworked grains, including Cretaceous calcareous nannofossils, and part of the detrital load. The lack of biogenic grains within the finest grained sediment intervals throughout the reservoir suggests interevent hemipelagic sediments are not preserved, resulting in a reservoir sequence of silt dominated, stacked turbidites. We observe two zones of enhanced TS at the top and bottom of the reservoir that correspond with enriched bulk sediment δ 34 S, indicating stalled or slowly advancing paleo-sulfate-methane transition zone (SMTZ) positions likely driven by relative decreases in sedimentation rate. Despite these two diagenetic zones, the low abundance of diagenetic precipitates throughout the reservoir allowed the primary porosity to remain largely intact, thus better preserving primary porosity for subsequent pore-filling gas hydrate. In canyon, channel, and levee environments, early diagenesis may be regulated via sedimentation rates, where high rates result in rapid progression through the SMTZ and minimal diagenetic mineralization and low rates result in the stalling of the SMTZ, enhancing diagenetic mineralization. Here, we observed some enhanced pyritization to implicate potential sedimentation rate changes, but not enough to consume primary porosity, resulting in a high saturation gas hydrate reservoir. These results emphasize the important implications of sedimentary processes, sedimentation rates, and early diagenesis on the distribution of gas hydrate in marine sediments along continental margins.

Alabama, Louisiana, Mississippi↗
USGS1961

Copper, vanadium, and uranium deposits in sandstone-their distribution and geochemical cycles

Deposits of copper , vanadium , and uranium in nonmarine sandstones are numerous and widespread. Copper deposits , with or without uranium , are mainly resident in first-generation arkosic sandstones derived from granitic rock terrains; deposits rich in vanadium , with or without much uranium , are dominantly in second-generation sandstones derived from sedimentary rocks; and the uranium deposits with little or no vanadium or copper are in either first- or second-generation sandstones, many of which are associated with beds containing volcanic debris. All three metals are dispersed in igneous rocks but not in close association. Copper and uranium enter the hydrothermal environment, but the record of vanadium in hydrothermal solutions and veins is scant. Some of the uranium and most of the copper minerals in igneous rocks and veins oxidize readily and the metals go into surface- and ground-water solutions, but the vanadium in igneous rocks is not so easily mobilized-under normal geologic conditions, conceivably it may require diagenetic reactions and a second period of weathering to solubilize much vanadium . All three metals precipitate from solutions in the presence of a reducing agent, such as carbonaceous material or associated sulfide ions, either in sediments as they accumulate or in existing rocks. These geochemical habits permit the concept that copper and uranium are made available by weathering of igneous rock terrains and hence might accumulate in first-generation sediments, whereas vanadium would be commonly available only after a second period of weathering. Perhaps the oxidation or devitrification of volcanic debris may contribute uranium to ground waters as does the weathering, of igneous rocks.

Economic Geology↗
USGS1996

Trace elements and organic contaminants in stream sediments from the Red River of the North Basin

To assess the presence and distribution of a variety of hydro-phobic chemicals in streams in the Red River of the North Basin, bottom sediments were analyzed for trace elements, organochlorines, and polycyclic aromatic hydrocarbons (PAHs). Glaciolacustrine clays and carbonate minerals are common in fine sediments of the region, and can help explain the distribution of many elements. Aluminum (Al), an indicator of glaciolacustrine clay minerals, correlates strongly (r>0.75, p<0.05) with Cr, Co, Fe, La, Li, K, Sc, and Ti; and moderately (0.55<r<0.75) with Ce, Cu, Ga, Nd, Ni, Th, V, and Y. Excluding the tributary Pembina River Basin, Eu, Nb, Ce, La, Nd, and Ni also have strong correlations with Al. Al correlates negatively with major elements associated with carbonate minerals (Ca, Mg, and inorganic carbon). No significant correlations with Al, Ca, or Mg were observed for As, Pb, Mn, Hg, Se, or Ag, which implies that these elements have different environmental sources or behaviors than glaciolacustrine clays or carbonate minerals. Reduction-oxidation processes may influence Mn distribution. Lead (Pb) and mercury (Hg) are known to be anthropogenically enriched in the environment--their distribution may indicate environmental enrichment in Red River of the North Basin streams. Organochlorines detected are limited to traces of DDT and its metabolites (mostlyp,p'-DDE). Fourteen PAHs, which are constituents of fossil fuels and of combustion byproducts, were detected in at least halfthe sediment samples; pyrene and fluoranthene were detected in about 90 percent of samples. The contaminants detected in this study were present at low levels, likely indicative of diffuse or remote sources; they occur widely in the environment.

Minnesota, North Dakota, South Dakota↗
USGS2008

Central Colorado Assessment Project - Application of integrated geologic, geochemical, biologic, and mineral resource studies

Central Colorado is one of the fastest-growing regions in the Western United States. Population along the Front Range increased more than 30 percent between 1990 and 2000 (http://www.demographia.com/db-metro3newworld.htm) with some counties within the study area, such as Park County, experiencing greater than 100-percent growth (http://www.censusscope.org/us/s8/rank_popl_growth.html). This growth has caused tremendous demand for natural resources and has created challenging land-management issues related to the interface between wilderness and urban expansion. Management of this wilderness/urban interface will benefit from current digital geoscience information collected by the U.S. Geological Survey (USGS) Central Colorado Assessment Project that began in 2003. Approximately 20,800 square miles (53,800 km2) of land divided almost equally between the public and private sectors were part of the assessment. The study area includes much of the Colorado Mineral Belt, a northeast-trending zone that contains 30 economically significant metal deposits. Historically, the area provided much of Colorado's metal production. The only active gold and molybdenum mines in Colorado lie within the study area. Recently, metal and uranium exploration activity has increased sharply in response to record prices for metals and uranium. This further underscores the need for up-to-date geoscience information presented in compatible GIS databases to facilitate rapid land-management decisions. Cooperative studies by USDA Forest Service, National Park Service supported by the USGS Mineral Resources Program (MRP), and National Cooperative Geologic Mapping Programs (NCGMP) contributed to the mineral-resource assessment and included regional geologic mapping at the scale 1:100,000, collection and geochemical studies of stream sediments, surface water, and bedrock samples, macroinvertebrate and biofilm studies in the riparian environment, remote-sensing studies, and geochronology. Geoscience information available as GIS layers has improved understanding of the distribution of metallic, industrial, and aggregate resources, location of areas that have potential for their discovery or development, helped to understand the relation of tectonics, magmatism, and paleohydrology to the genesis of the metal deposits in the region, and provided insight on the geochemical and environmental effects that historical mining and natural, mineralized rock exposures have on surface water, ground water, and aquatic life.

Fact Sheet↗
USGS2012

Arc-related porphyry molybdenum deposit model

This report provides a descriptive model for arc-related porphyry molybdenum deposits. Presented within are geological, geochemical, and mineralogical characteristics that differentiate this deposit type from porphyry copper and alkali-feldspar rhyolite-granite porphyry molybdenum deposits. The U.S. Geological Survey's effort to update existing mineral deposit models spurred this research, which is intended to supplement previously published models for this deposit type that help guide mineral-resource and mineral-environmental assessments. Arc-related porphyry molybdenum deposits are a substantial resource for molybdenum metal and may have anomalous concentrations of tungsten. The deposits contain low-grade ore (0.03-0.22 percent molybdenum) as molybdenite, but are large-tonnage, making them amenable to bulk mining open-pit techniques. The mineralizing system usually has fluorine contents of less than 0.1 percent. The cogenetic intrusion is a differentiated calc-alkaline granitoid, typically granodiorite to quartz monzonite in composition, with low rubidium and niobium, and moderate to high strontium concentrations. Metals and hydrothermal fluids are sourced from these intrusions, with an additional meteoric fluid component contributing to peripheral alteration but not adding more metal. The lithology of the surrounding country rocks is not important to the formation of these deposits, but a surrounding carbonate unit may be altered to skarn that contains economic mineralization. The creation of contact-metamorphosed hornfels adjacent to the intrusion is common. Formation of arc-related porphyry molybdenum deposits typically occurs within a continental arc environment related to arc-continent or continent-continent collision and subduction. Few deposits are found in an island arc setting. Most classified arc-related porphyry molybdenum deposits are located in the western cordillera of North America, notably in British Columbia and Alaska. Hydrothermal alteration provides a key component to the identification of a deposit. Alteration usually is zoned from a core of potassic plus/minus silicic alteration outwards through phyllic to propylitic alteration. Argillic alteration may be irregular in shape and will overprint earlier hydrothermal alteration. Exploration should be limited to magmatic arc belts that have been unroofed and eroded to levels of a few kilometers depth. Important geological vectors toward areas of higher grade mineralization include intensity of hydrothermal alteration, veining, and faulting. Anomalous levels of molybdenum, tungsten, copper, lead, or zinc in soils, tills, stream sediments, and drainage waters may indicate the presence of an arc-related porphyry molybdenum deposit. Geophysical exploration techniques have been met with minimal success because of the overall low concentration of associated sulfide and oxide minerals. Geoenvironmental concerns are generally low because of low volumes of sulfide minerals. Most deposits are marginally acid-generating to non-acid-generating with drainage waters being near-neutral pH because of the acid generating potential of pyrite being partially buffered by late-stage calcite-bearing veins. The low ore content results in a waste:ore ratio of nearly 1:1 and large tailings piles from the open-pit method of mining.

Scientific Investigations Report↗