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Characterization of groundwater resources near the southeastern part of Puget Sound, Washington

More than 1 million people live within the active model area (AMA) in the southeastern part of the lowlands surrounding Puget Sound, or Puget Lowland, Washington, and groundwater is the source for approximately one-half of their public, domestic, and irrigation water demands. The 887-square-mile AMA, located in King and Pierce Counties, represents the area of analysis for the conceptual hydrogeologic framework and numerical groundwater-flow models within the study area and includes the Puyallup River and Chambers-Clover Creek watersheds. To assess the potential hydrologic and anthropogenic impacts to groundwater and the connected surface-water resources, conceptual and numerical groundwater-flow models of groundwater flow were developed by the U.S. Geological Survey Washington Water Science Center in close cooperation with 18 water-resource agencies and stakeholders. This multichapter volume documents the development of the conceptual and numerical groundwater-flow models of groundwater flow. Chapters A, B, and C provide an overall introduction to the multichapter volume (Chapter A), the conceptual hydrogeologic framework (Chapter B), and the groundwater budget (Chapter C). Chapters D and E describe numerical groundwater-flow model construction and calibration (Chapter D) and the numerical groundwater-flow model results (Chapter E). Collectively, these reports present a characterization and simulation tool for groundwater resources near the southeastern part of Puget Sound, Washington.

Scientific Investigations Report

Water, ice, meteorological, and speed measurements at South Cascade Glacier, Washington, 1999 balance year

Winter snow accumulation and summer snow, firn, and ice melt were measured at South Cascade Glacier, Washington, to determine the winter and net balances for the 1999 balance year. The 1999 winter snow balance, averaged over the glacier, was 3.59 meters, and the net balance was 1.02 meters. Since the winter balance record began in 1959, only three winters have had a higher winter balance. Since the net balance record began in 1953, only 2 years have had a greater positive net balance than 1999. Runoff was measured from the glacier and an adjacent non-glacierized basin. Air temperature, precipitation, and humidity were measured nearby, and ice speed was measured. This report makes these data available to the glaciological and climatological community.

Washington

Reconfigured-Channel Monitoring and Assessment Program

A U.S. Geological Survey program to monitor and assess channel reconfiguration activity is described. A data base available on the world wide web will enable land-management agencies and other interested parties to evaluate the long-term success of various channel reconfiguration projects. A demonstration project on the Lake Fork of the Gunnison River, Colorado, illustrates the program objectives and approach.

Colorado

High-resolution landscape-scale maps of nutrients, phytoplankton, and related water-quality constituents in Suisun Bay and the Sacramento–San Joaquin Delta, California, during 2018—Results from high-resolution underway surveys

We examined the abundance and distribution of nutrients and phytoplankton in the tidal aquatic environments of the Sacramento–San Joaquin Delta (Delta) and Suisun, Grizzly, and Honker Bays in California by completing three spatial surveys that used continuous underway high frequency (1 hertz) measurements and sampling onboard a high-speed boat. Surveys were conducted in May, July, and October 2018. Water was sampled continuously during surveys to simultaneously collect information about the concentration and spatial distribution of all major nutrient forms together with information about the major classes of phytoplankton and associated standard field measurements of water quality, such as dissolved oxygen, dissolved organic matter, pH, salinity, specific conductance, turbidity, and water temperature. The results show a greater than 50-fold variation in nutrient and phytoplankton concentrations across space and time, providing evidence of the dynamic environmental processes that shape the ways nutrients interact with and affect Delta aquatic habitats.

Data Report

Stream sediment sources in Medicine Creek, northern Missouri and southern Iowa

This report presents the results of a cooperative study by the U.S. Geological Survey and Missouri Department of Natural Resources to quantify sediment transport source contributions in the Medicine Creek drainage basin. Understanding relative source contributions provides valuable information for selecting the conservation practices that may be most effective in reducing sediment and sediment-associated nutrient transport in the Medicine Creek drainage basin and similar areas of the Lower Grand River drainage basin. Sediment samples were collected from potential contributing areas (source samples) and from fluvial-transported samples (target samples). Source sample types included streambanks, row crop fields, and a combined pastures and forests category. Samples were analyzed for particle size and quantity of carbon, nitrogen, stable isotopes of carbon and nitrogen, and 49 mineral elements as potential tracers. Results for the carbon stable isotope ratio of carbon-13/carbon-12 (δ 13 C) and concentrations of total carbon, total nitrogen, calcium, potassium, and copper were selected by discriminant function analysis as the best combination of multiple tracers to differentiate each source type. The discriminant function analysis poorly differentiated pastures and forests, so these source types were combined. The sources defined by the discriminant function analysis were then used in an unmixing model to apportion sources for each target sample. In the study area, transported sediment was predominantly bank sediment, with an overall average of 86.9 percent of suspended-sediment samples and depositional streambed samples attributed to bank material. Suspended-sediment samples from the mainstem of Medicine Creek were dominated by bank sediments (average of 95.8 percent), and depositional streambed samples from throughout the drainage basin had more variable source contributions with an average of 71.1 percent attributed to bank material. The relative importance of upland sources (row crop fields and the combined pastures and forests category) varied seasonally and with streamflow but was not related to land use or drainage basin size. Relative contributions from upland sources were greater in the summer through winter rather than spring and during lower streamflow, though this may be driven by the seasonality of streamflow. These results indicate management practices that reduce bank erosion could be effective strategies for managing the dominant source of sediment and sediment-associated phosphorus.

Iowa, Missouri

3D semantic mapping of surface geological features

Semantic mapping in 3D is fundamental to a wide range of geoscientific studies and applications, including geomorphology, hazard assessment, and environmental monitoring. However, automatically segmenting geological features from large-scale photogrammetric datasets remains a significant challenge. We present a methodology to address this gap. Using overlapping images collected over environments of interest, Structure-from-Motion (SfM) produces georeferenced point clouds and estimates camera poses. Existing large vision models, such as Segment Anything Model, segment objects in the images, generating pixel-segmentation associations. To produce pixel-point associations, we project the points back onto the camera image planes. As objects are independently segmented across multiple images with different perspectives, we develop a segmentation mosaicking algorithm to build probabilistic point-segmentation associations that combines the pixel-segmentation associations and pixel-point associations. Our methodology is validated using both synthetic data generated by Kubric and real-world UAV-SfM data. The implementation is designed to be compatible with existing SfM software, including Agisoft and OpenDroneMap, for photogrammetry mapping in geoscience studies. As a case study, we apply our method to the semantic mapping of precariously balanced rocks (PBRs), which provide upper-bound constraints on historical ground motion shaking intensity. To support object-level identification of PBRs, we additionally integrated Grounding DINO, enabling text-prompted segmentation of features of interest within UAV imagery. This case study demonstrates the effectiveness of our method in generating a 3D semantic map of PBRs, enabling spatial distribution of PBR fragility for earthquake hazard analysis.

Computers & Geosciences

Design, revisions, and considerations for continued use of a ground-water-flow model of the coastal plain aquifer system in Virginia

A digital numerical model of the ground-water-flow system in the Virginia Coastal Plain was constructed as part of the Regional Aquifer System Analysis program of the U.S. Geological Survey and subsequently revised based on reinterpretations of the hydrogeologic framework. The revised model has been incorporated by the Virginia Department of Environmental Quality as a means to evaluate the effects of existing and proposed ground-water withdrawals. The revised model, which is documented here, includes many design features of the original model. Principal modifications are (1) reassignment of some model layers to represent different aquifers, (2) replacement of applied recharge and the uppermost surface-water layer by constant-head cells to represent the unconfined aquifer, and (3) revision of the lateral extents and transmissivity and vertical leakance values assigned to model layers. Ground-water levels simulated by the revised model under steady-state conditions, using withdrawal rates representing the period 1978-80, generally are similar to the water levels simulated by the original model under transient conditions using the same withdrawal rates. Differences probably result largely from changes in transmissivity and vertical leakance values. T he revised model enables the continued evaluation of development of the large and complex aquifer system. Improved information on parts of some aquifers has been incorporated. Only large, regional-scale trends in ground-water water levels, flow directions, and flow rates are simulated, however, and not local trends and (or) short-term changes in water level and flow. Changing hydraulic stresses, knowledge of hydrogeologic conditions, and resource-management needs require periodic revision of the model to maintain its usefulness for the management of ground-water resources in the Virginia Coastal Plain.

Virginia

Preconditioned Conjugate-Gradient 2 (PCG2), a computer program for solving ground-water flow equations

This report documents PCG2: a numerical code to be used with the U.S. Geological Survey modular three-dimensional, finite-difference, ground-water flow model. PCG2 uses the preconditioned conjugate-gradient method to solve the equations produced by the model for hydraulic head. Linear or nonlinear flow conditions may be simulated. PCG2 includes two reconditioning options: modified incomplete Cholesky preconditioning, which is efficient on scalar computers; and polynomial preconditioning, which requires less computer storage and, with modifications that depend on the computer used, is most efficient on vector computers. Convergence of the solver is determined using both head-change and residual criteria. Nonlinear problems are solved using Picard iterations. This documentation provides a description of the preconditioned conjugate gradient method and the two preconditioners, detailed instructions for linking PCG2 to the modular model, sample data inputs, a brief description of PCG2, and a FORTRAN listing.

Water-Resources Investigations Report

ECCOE Landsat quarterly Calibration and Validation report—Quarter 1, 2024

Executive Summary The U.S. Geological Survey Earth Resources Observation and Science Calibration and Validation (Cal/Val) Center of Excellence (ECCOE) focuses on improving the accuracy, precision, calibration, and product quality of remote-sensing data, leveraging years of multiscale optical system geometric and radiometric calibration and characterization experience. The ECCOE Landsat Cal/Val Team continually monitors the geometric and radiometric performance of active Landsat missions and makes calibration adjustments, as needed, to maintain data quality at the highest level. This report provides observed geometric and radiometric analysis results for Landsats 8 and 9 for quarter 1 (January–March), 2024. All data used to compile the Cal/Val analysis results presented in this report are freely available from the U.S. Geological Survey EarthExplorer website: https://earthexplorer.usgs.gov . This quarterly report is the third to include analysis results for Landsat 9, which was launched in September 2021. The inclusion of Landsat 9 analysis results was dependent on two factors: a complete reprocessing of the Landsat 9 data archive and enough time elapsing to begin formulating lifetime trends. In April 2023, all Landsat 9 image data acquired since the satellite’s launch were reprocessed to take advantage of calibration updates identified by the ECCOE Landsat Cal/Val Team. Additional information about the Landsat 9 reprocessing effort is available at https://www.usgs.gov/landsat-missions/news/upcoming-reprocessing-all-landsat-9-data . Additional information about Landsat 9 prelaunch, commissioning, and early on-orbit imaging performance is available at https://www.mdpi.com/journal/remotesensing/special_issues/15B4V2K92K . This quarterly report is the first to not include analysis results for Landsat 7 because Enhanced Thematic Mapper Plus imaging was suspended on January 19, 2024, after the satellite transitioned into full sunlight. The satellite has been drifting since early 2022 after being lowered from the nominal orbit altitude, and the transition into full sunlight is a result of the satellite operating in its extended science mission. Additional information about the imaging suspension is available at https://www.usgs.gov/landsat-missions/news/landsat-7-imaging-suspended . Additional information about the Landsat 7 extended science mission is available at https://www.usgs.gov/landsat-missions/landsat-7-extended-science-mission .

Open-File Report

ECCOE Landsat quarterly Calibration and Validation report—Quarter 2, 2024

Executive Summary The U.S. Geological Survey Earth Resources Observation and Science Calibration and Validation (Cal/Val) Center of Excellence (ECCOE) focuses on improving the accuracy, precision, calibration, and product quality of remote-sensing data, leveraging years of multiscale optical system geometric and radiometric calibration and characterization experience. The ECCOE Landsat Cal/Val Team continually monitors the geometric and radiometric performance of active Landsat missions and makes calibration adjustments, as needed, to maintain data quality at the highest level. This report provides observed geometric and radiometric analysis results for Landsats 8 and 9 for quarter 2 (April–June) of 2024. All data used to compile the Cal/Val analysis results presented in this report are freely available from the U.S. Geological Survey EarthExplorer website: https://earthexplorer.usgs.gov . This is the fourth quarterly report to include analysis results for Landsat 9, which was launched in September 2021. The inclusion of Landsat 9 analysis results was dependent on two factors: a complete reprocessing of the Landsat 9 data archive and enough time elapsing to begin formulating lifetime trends. In April 2023, all Landsat 9 image data acquired since the satellite’s launch were reprocessed to take advantage of calibration updates identified by the ECCOE Landsat Cal/Val Team. Additional information about the Landsat 9 reprocessing effort is available at https://www.usgs.gov/landsat-missions/news/upcoming-reprocessing-all-landsat-9-data . Additional information about Landsat 9 prelaunch, commissioning, and early on-orbit imaging performance is available at https://www.mdpi.com/journal/remotesensing/special_issues/15B4V2K92K . This is the second quarterly report that does not include analysis results for Landsat 7 because Enhanced Thematic Mapper Plus imaging was suspended on January 19, 2024, after the satellite transitioned into full sunlight. The satellite has been drifting since early 2022 when it was lowered from the nominal orbit altitude, and the transition into full sunlight is a result of the satellite operating in its extended science mission. Additional information about the imaging suspension is available at https://www.usgs.gov/landsat-missions/news/landsat-7-imaging-suspended . Additional information about the Landsat 7 extended science mission is available at https://www.usgs.gov/landsat-missions/landsat-7-extended-science-mission .

Open-File Report

Magnitude and frequency of floods in the Suwannee River Water Management District, Florida

Flood-frequency statistics for 2-, 5-, 10-, 25-, 50-. 100-, 200-, and 500-year recurrence intervals, based on three methods of analysis, are presented for 25 continuous-record and seven peak flow partial-record gaging stations in the Suwannee River Water Management District. The first method, for gaged stations, utilizes station records; the second method, for ungaged sites, utilizes regional regression analysis; and the third method uses a weighted combination of the station and regional values. Because the weighted values utilize two more or less independent estimates of the peak flow statistic, they are considered more accurate than the station estimates or the regression estimates alone. Also, the use of another weighting scheme to improve estimates of flood frequency statistics at ungaged sites is demonstrated. The karstic nature of much of the Suwannee River Water Management District significantly attenuates flood peaks in some streams by providing substantial subsurface storage when river stages are high. At such times, springs discharging into rivers may reverse flow temporarily and become sinks.

Florida

Preserving and increasing water resources—Natural infrastructure in dryland streams in Baja California Sur, Mexico

The Los Planes watershed of Baja California Sur, Mexico, and its underlying aquifer are experiencing groundwater decline owing to low average annual rainfall (28.1 centimeters per year) and rising water demand from population growth and agricultural activities. This decline in water availability can lead to desertification—a process that changes arable land to desert by degrading soil and vegetation—and can pose serious challenges to livelihoods that depend on the land. To address these issues, a ranch in the Los Planes watershed has installed many natural infrastructures in dryland streams (NIDS) in channels for soil and water conservation. In 2022, the U.S. Geological Survey (USGS) began working with regional researchers and land managers to investigate the effects of NIDS on natural biological, geochemical, and physical processes and determine the efficacy of NIDS for water augmentation in the Los Planes watershed. The USGS also worked with local academic institutions and nonprofit organizations to create public educational opportunities focused on the area’s hydrogeology. These and other collaborative efforts with the U.S. Water Partnership and Innovaciones Alumbra aim at enhancing water resources in the Baja California Sur region and promoting water security and safeguarding community well-being. Resume La cuenca de Los Planes, ubicada en Baja California Sur, México, y su acuífero subyacente, están sufriendo una disminución de las aguas subterráneas debido a la baja precipitación media anual (28.1 centímetros por año) y la alta demanda de agua por parte de una población creciente y la actividad agrícola. Esta disminución de la disponibilidad de agua puede conducir a la desertificación—un proceso que por medio de la degradación del suelo y la vegetación convierte a la tierra cultivable en desierto—representando un serio desafío para los medios de vida de las personas. Para abordar estos problemas, un rancho en la cuenca de Los Planes ha instalado numerosas obras de Infraestructura Natural en Arroyos de Tierras Áridas (INATS) para conservación del suelo y del agua. En 2022, el Servicio Geológico de los Estados Unidos (USGS, por sus siglas en inglés) comenzó a trabajar con investigadores regionales y gestores de tierras para estudiar los efectos de INATS en los procesos biológicos, geoquímicos y físicos, y determinar su eficacia en el aumento de los recursos hídricos en la cuenca de Los Planes. El USGS se ha asociado con instituciones académicas y organizaciones locales sin fines de lucro para crear oportunidades educativas públicas centradas en la hidrogeología de la zona. Estos y otros esfuerzos colaborativos con la Asociación del Agua de Estados Unidos (U.S. Water Partnership) e Innovaciones Alumbra, tienen como objetivo mejorar el uso de los recursos hídricos en la región de Baja California Sur, promover la seguridad hídrica y proteger el bienestar de la comunidad.

Baja California Sur

USGS addresses needs for lithium calibration and quality control materials for pLIBS analysis

Lithium (Li) is a globally important commodity used for energy storage, national defense, human health, and advanced technologies. Lithium resource development requires identifying deposits with elevated concentrations and optimal mineralogy, typically associated with select clays and pegmatites. Lithium is a light, highly reactive alkali metal with low atomic mass that is difficult to detect and quantify using conventional portable geochemical techniques such as X-ray fluorescence (XRF). However, portable laser-induced breakdown spectroscopy (pLIBS) is a powerful analytical technique for lithium exploration due to its ability to analyze solids quickly with minimal preparation. The expanded utility of pLIBS is hampered by the lack of matrix-matched calibration and quality control (QC) materials. The United States Geological Survey (USGS) has developed in-house lithium calibration and QC materials for lithium in clay and pegmatite matrices to address this limitation. We present the workflow and implementation of a custom-built matrix specific calibration on a SciAps Z-300 pLIBS, using proprietary Profile Builder software. The implementation of the custom calibration and quality control standards enables us to collect semiquantitative results directly from the pLIBS while in the field. Ultimately, this calibration has improved confidence in sample selection and collection in the field, providing more efficient site characterization.

Conference Paper

Origin and evolution of mafic volcanism associated with 3 m.y. of andesite production at the Goat Rocks volcanic cluster, southern Washington Cascade Range

More than 3 m.y. of mafic volcanism near the Goat Rocks volcanic cluster in the southern Washington Cascade Range, USA, lends insight into the evolution of basalts and the subarc mantle at a long-lived, major arc volcanic locus. We contribute field observations, 40 Ar/ 39 Ar dates, paleomagnetic directions, and bulk rock and mineral compositions to characterize nine mafic units that erupted in association with the Goat Rocks volcanic cluster. The time frame of mafic volcanism, ca. 3.6 Ma to 60 ka, encompasses the lifespan of the central volcanic cluster (3.1 Ma to 115 ka), with a lull from ca. 2.7 Ma to 1.4 Ma. A climactic period of voluminous mafic activity and far-traveled lava flows, including construction of the Hogback Mountain shield volcano, coincided with voluminous andesite eruptions from the central volcanic cluster. The basaltic rocks in the Goat Rocks area are calc-alkaline to barely tholeiitic and have high field strength element depletion relative to large-ion lithophile elements characteristic of calc-alkaline basalts (CAB) of the Cascade volcanic arc. Unlike at neighboring andesitic volcanic centers (Mounts Adams, St. Helens, and Rainier), no other mafic end members such as high-aluminum olivine tholeiite (HAOT) or intraplate-type basalt (IPB) are present at or near the Goat Rocks volcanic cluster, although some of the calc-alkaline basalts in this study have IPB-like affinities. The Goat Rocks mafic units exhibit two main temporal trends in composition: (1) the most primitive basalts erupted earlier, compared to less primitive and more evolved compositions later, and (2) high field strength element concentrations are higher in the younger basalt units relative to the oldest two. In contrast to these temporal trends, the mafic units define two compositional groups that recur through time, a low-Sr and a high-Sr group, each with distinct trace element and Sr and Nd isotope ratios. Although radiogenic isotope ratios are generally aligned with High Cascades CAB and HAOT, some extend toward IPB of Mount Adams and Simcoe Mountains volcanic field. Olivine-dominated crystal fractionation at shallow pressure from a small range of parent magma compositions accounts for much of the variation among the basalts and basaltic andesites. A high-pressure fractionation model is plausible for only one of the youngest basalt units (basalt of Walupt Lake volcano). Mafic recharge and crustal assimilation accounts for the incompatible-element enriched composition of basaltic andesites erupted during construction of the largest andesitic centers, further supporting sustained basalt mass flux and thermal energy driving andesite genesis. We model the most primitive members of the Goat Rocks mafic units as partial melts of successively less depleted mantle in time. Variable degrees of fluxing with fluids and melts from subduction explain the distinction between high-Sr and low-Sr groups. We propose that mantle metasomatism by ancestral subduction and fluid-flux melting is heterogeneously distributed through the local subarc mantle and played a greater role in the genesis of the high-Sr basalt group. The limited range of primitive basalt types around the Goat Rocks volcanic cluster contrasts with the much greater diversity of basalts throughout the southern Washington to northern Oregon Cascade arc. On the other hand, the central volcanic cluster encompasses nearly the entire diversity observed at neighboring composite volcanoes. In the case of the Goat Rocks area at least, and perhaps attributable to the entire region, this means that the genesis of diverse intermediate magmas is independent from and does not require vastly different parental basalt compositions.

California, Oregon, Washington

Detection of viral, bacterial, and protozoan pathogens and microbial source tracking markers in paired large- and small-volume water samples

When sampling for waterborne microbes, researchers may need to diverge from recommended sample volumes due to logistical constraints, novel targets, or challenging matrices, with little guidance about the potential impact on results. In field studies, we measured bacteria, viruses, and protozoa (15 quantitative polymerase chain reaction assays) in paired large- and small-volume samples to evaluate method performance and relevant factors. Concordance between methods was low. Large-volume ultrafiltration yielded more detections than small-volume sampling, especially for pathogens in groundwater. Greater microbial concentrations were associated with more frequent detections in small-volume samples and greater concordance between paired samples. Large-volume samples appeared to be more susceptible to diminished sensitivity from complex sample matrices. In laboratory studies, recovery of microbes was poorer for large- than small-volume methods, although large-volume methods more reliably detected low-concentration targets. Large-volume samples were less stable than small-volume samples during storage. Overall, large-volume sampling was superior for detecting pathogens but may underestimate concentrations; small-volume sampling was more prone to false negatives but was adequate when concentrations were relatively high, like we observed for microbial source tracking in surface waters.

Wisconsin

Water resources of Mellette and Todd counties, South Dakota

Mellette and Todd Counties are located in south-central South Dakota and have a combined area of 2,694 square miles. The White River and its tributaries, which include the Little White River, drain Mellette County and about one-half of Todd County. Tributaries to the Niobrara River, which include the Keya Paha River, drain the other one-half of Todd County. The average discharge of the Little White River is about 56 cubic feet per second as the river enters Todd County and is about 131 cubic feet per second as it discharges to the White River in northern Mellette County. The average discharge of the Keya Paha River just outside Todd County is about 39 cubic feet per second. The average annual runoff for Mellette and Todd Counties ranges from 0.94 to 2.36 inches based on records from nine streamflow-gaging stations in and near the counties. The average annual runoff is 1.62 inches, which compares with the average annual precipitation of about 19 inches. In Todd County, shallow wells completed in the alluvial, Ogallala, Arikaree, and White River aquifers generally can supply water that has low concentrations of dissolved solids, is fresh, and is soft to moderately hard. Ground water from shallow aquifers is limited in Mellette County; therefore, deep wells, often greater than 1,000 feet, are sometimes installed. The Pierre Shale often is used to supply rural domestic and stock wells in Mellette County even though well yields are low and the water has high dissolved solids, is moderately saline, and is very hard. Alluvial aquifers are present in both counties and store an estimated 1.6 million acre-feet of water. The water quality of the alluvial aquifers is dependent on the underlying deposits, and generally the water has low concentrations of dissolved solids, is fresh, and is soft to moderately hard where underlain by the Ogallala and Arikaree Formations; has moderate concentrations of dissolved solids, is slightly saline, and is hard where underlain by the White River Group; and has high concentrations of dissolved solids, is saline, and is very hard where underlain by the Pierre Shale. Also, yields often are lower where the alluvial aquifers are underlain by the Pierre Shale. The Ogallala aquifer is present in only Todd County, and the Arikaree aquifer is present throughout most of Todd County and southwestern and south-central Mellette County. The Ogallala aquifer contains an estimated 17 million acre-feet of water in storage, and the Arikaree aquifer contains an estimated 50 million acre-feet of water in storage. Both aquifers generally are suitable for irrigation, and yields from these aquifers are sometimes greater than 1,000 gallons per minute. Nitrate concentrations in 13 out of 92 water samples collected from the Ogallala aquifer exceeded the Primary Drinking Water Maximum Contaminant Level (MCL) of 10 milligrams per liter. In 11 out of 46 samples collected from the Arikaree aquifer, arsenic concentrations exceeded the MCL of 50 micrograms per liter. The White River aquifer, where present, is usually the shallowest source of ground water in Mellette County. The White River aquifer also is used in northern Todd County where the Ogallala and Arikaree aquifers are not present. The White River aquifer contains an estimated 50 million acre-feet of water in storage. Reported yields from the aquifer range from 1 to 30 gallons per minute, which generally is insufficient to support irrigation in most areas. However, yields are sufficient for livestock-watering and rural-domestic purposes. In both counties, the Pierre Shale is the shallowest bedrock aquifer and is exposed at the land surface throughout most of Mellette County. This aquifer is used primarily in Mellette County. Although the aquifer contains an estimated maximum of 1.5 million acre-feet of water in storage, it is not a viable source of ground water because the aquifer is relatively impermeable, yields are low, and water usually can be obtained from shallower sources, especially in Todd County. Reported yields from the Pierre Shale aquifer range from 1 to 8 gallons per minute. Because few test holes and wells penetrate below the Pierre Shale, little is known about the extent of the deeper bedrock aquifers. All wells completed in the Dakota Sandstone, Inyan Kara, and Minnelusa and Madison aquifers in the counties are used for stock-watering purposes. High concentrations of dissolved solids and hard water are characteristic of the water quality in the bedrock aquifers. Depths to the top of the deeper bedrock aquifers range from 1,270 feet to greater than 2,000 feet below land surface.

South Dakota

Application of Hydrologic Simulation Program—FORTRAN (HSPF) as part of an integrated hydrologic model for the Salinas Valley, California

The U.S. Geological Survey (USGS), in cooperation with the Monterey County Water Resources Agency, conducted studies to help evaluate the surface-water and groundwater resources of the Salinas Valley study area, consisting of the entire Salinas River watershed and several smaller, adjacent coastal watersheds draining into Monterey Bay. The Salinas Valley study area is a highly productive agricultural region that depends on the coordinated use of surface water and groundwater to meet demand for irrigation and public water supply. To continue to meet these demands, a better understanding of the historical water balance and the effects of water-resource development on the long-term sustainability of water resources in the Salinas Valley study area is needed.

California

The distribution of bromide in water in the Floridan aquifer system, Duval County, northeastern Florida

Although Duval County, Florida, has ample ground-water resources for public supply, the potential exists for a problem with excessive disinfectant by-products. These disinfectant by-products result from the treatment of raw water containing low concentrations of bromide and naturally occurring organic compounds. Because of this potential problem, the relation of bromide concentrations to aquifer tapped, well location and depth, and chemical characteristics of water in the Floridan aquifer system underlying Duval County were studied to determine if these relations could be applied to delineate water with low-bromide concentrations for future supplies. In 1992, water samples from 106 wells that tap the Floridan aquifer system were analyzed for bromide and major dissolved constituents. A comparison of bromide concentrations from the 1992 sampling with data from earlier studies (1979-80) indicates that higher bromide concentrations were detected during the earlier studies. The difference between the old and new data is probably because of a change in analytical methodology in the analysis of samples. Bromide concentrations exceeded the detection limit (0.10 milligrams per liter) in water from 28 of the 106 wells (26 percent) sampled in 1992. The maximum concentration was 0.56 milligrams per liter. There were no relations between bromide and major dissolved constituents, well depth, or aquifer tapped that would be useful for determining bromide concentrations. Areal patterns of bromide occurrence are not clearly defined, but areas with relatively high bromide concentrations tend to be located in a triangular area near the community of Sunbeam, Florida, and along the St. Johns River throughout Duval County.

Florida