Geology ReportsSearch

SEARCH · Geology Reports

Results for “Journal of Geophysical Research: Earth Surface”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

1,666 records · Page 19Linked to original sources

Three-dimensional geologic framework model of the Rio San Jose groundwater basin and adjacent areas, New Mexico

As part of a U.S. Geological Survey study in cooperation with the Bureau of Reclamation and the Pueblo of Acoma, New Mexico, and the Pueblo of Laguna, New Mexico, a digital three-dimensional geologic framework model was constructed for the Rio San Jose and its surface-water drainage basin in west-central New Mexico. This three-dimensional model defines the altitude, thickness, and extent of 18 geologic units for use in a regional numerical hydrologic model. The model included an undifferentiated Proterozoic basement layer, 13 consolidated Paleozoic and Mesozoic rock units, and 4 Cenozoic units. Model input data were compiled from published cross sections, well data, structure contour maps, selected geophysical data, and data derived from geologic maps and structural features in the study area. These data were used to construct faulted surfaces that represent the upper and lower subsurface geologic unit boundaries. The digital three-dimensional geologic framework model combines faults, the altitude of the tops of each geologic unit, and boundary lines depicting the subsurface extent of each geologic unit. The digital three-dimensional geologic model described in this report and the corresponding data release represents the generalized geometry of the subsurface geologic units; it reproduces with reasonable accuracy the input geologic data and is consistent with previously published subsurface conceptualizations of the region. The geologic framework model is at a scale and resolution appropriate for use as the foundation for a numerical hydrologic model of the study area.

New Mexico

Shallow differentiation of primitive arc magmas at the Jurassic Emigrant Gap mafic complex, Sierra Nevada, California

The Emigrant Gap composite pluton exposes ultramafic to silicic intrusive rocks that preserve the chemical evolution of primitive mafic arc magmas and their open-system interactions in the upper crust during mid-Jurassic growth of the Sierra Nevada batholith (California). We present field and petrographic observations and mineral and whole-rock chemistry of the ~35-km 2 ultramafic to dioritic Emigrant Gap mafic complex and an adjacent penecontemporaneous ~90-km 2 granodiorite that together make up the composite pluton. In the Emigrant Gap mafic complex, four roughly central masses of dunite, wehrlite, and olivine clinopyroxenite are surrounded by weakly layered gabbronorite and non-layered diorite. The ultramafic rocks are cumulates formed from near-liquidus minerals of primitive arc magmas that accumulated in steep feeder zones with substantial modification by melt–mush reaction as primitive liquids repeatedly transited the mush-filled conduits. The dominant gabbronoritic rocks are the variably accumulative products of more advanced crystallization–differentiation of arc tholeiitic basalts and basaltic andesites. The adjacent granodiorite intrusion originated separately and preserves field and geochemical evidence for assimilation of metasedimentary rocks. Open-system hybridization between the gabbronoritic mushes and the granodioritic magma produced an intervening body of two-pyroxene diorite. We infer that the ultramafic rocks and gabbronorite of the Emigrant Gap mafic complex crystallized from near-primitive arc basaltic to basaltic andesitic magmas at ~0.15–0.3 GPa, with estimated f O 2 of ≥FMQ +1 and dissolved H 2 O concentrations of only ~0.5–2 wt %. Notably, the Emigrant Gap composite pluton is distinct from other Mesozoic plutons in the Sierra Nevada batholith because of (1) its abundance of mafic and ultramafic rocks that crystallized from relatively primitive mafic melts and (2) the low inferred H 2 O concentrations of its parental magmas, indicated by a near absence of igneous amphibole and by the intermediate rather than calcic compositions of plagioclase. A Jurassic regional extension event probably accounts for the formation of relatively dry primitive arc magmas, as well as for their ascending to the upper crust.

California

Relating systematic molecular and textural properties of graptolite pyrolyzed via gold tube hydrous pyrolysis: Implications for thermal proxies in lower Paleozoic marine shales

A series of gold tube pyrolysis experiments (72 h, 300–550 °C, 50 MPa) conducted on a graptolite-rich lower Paleozoic marine shale generated pyrolysis residues for a comprehensive evaluation of the molecular and structural variability of three types of graptolite periderm. Organic petrology, Raman spectroscopy, and field emission scanning electron microscopy (FE-SEM) with energy dispersive spectroscopy (EDS) were combined to evaluate the thermal evolution process. The three types of graptolite periderm, namely granular, non-granular, and nodular graptolite, were analyzed by Raman spectroscopy wherein point measurements were obtained after the maceral was identified and the location verified by organic petrology. Distinct thermal evolution pathways among non-granular, granular, and nodular graptolite periderms were recorded. The evolution patterns of the Raman parameters, particularly D1 and G bands, highlight the differences in geochemical composition of the graptolite periderm types and the alteration of molecular structure with increasing thermal maturity. Raman parameters D1 (position of the D1 peak), G-FWHM (full width at half maximum of the G peak), and ratios D1-FWHM/G-FWHM (full width at half maximum of the D1 peak ratioed to G-FWHM) and A D1 /A G (ratio of D1 and G peak intensities) showed effectiveness in assessing thermal maturity. Bireflectance with increasing gold tube pyrolysis temperature followed a hierarchy: non-granular > granular > nodular, reflecting different molecular alignment intensities. Qualitative FE-SEM evaluation showed that fine-grained mineral inclusions (primarily Fe-sulfide as determined via EDS) were associated with the graptolite populations, with granular graptolite containing greater amounts of coarser-grained (e.g., ∼300–1400 nm) mineral inclusions relative to non-granular and nodular graptolite, which contain finer-grained (e.g., ∼100–200 nm) inclusions difficult to resolve with optical microscopy. These findings are investigated to highlight the mechanisms that drive organic matter evolution within graptolite during thermal maturation, as well as to explore some of the limitations of using spectroscopic parameters as thermal maturity proxies.

International Journal of Coal Geology

Apatite and monazite geochemistry record magmatic and metasomatic processes in rare earth element mineralization at Mountain Pass, California

The largest rare earth element (REE) deposit in the United States is a carbonatite intrusion at Mountain Pass in the Mojave Desert, California. Despite a clear spatiotemporal association of alkaline silicate and carbonatite intrusions at Mountain Pass, a genetic model of their mutual formation has not been resolved. The Mountain Pass carbonatite has long been upheld as an example of a primary magmatic body, but recent work has suggested it could be fluid-derived. This study investigates the geochemistry of apatite and monazite grains from the alkaline silicate and carbonatite stocks and dikes of the Mountain Pass district, to elucidate the magmatic history of the intrusive suite and identify the role of fluids in rare earth element mineralization. Three apatite populations are identified in the alkaline silicate rocks. A primary magmatic apatite group supports intrusion of the stocks as separate pulses of magma derived from a spatially extensive metasomatized mantle source region. The second group implicates the role of a regional fluid that mobilized light rare earth elements from apatite grains. A minor group of inherited apatite cores, identified by low Sr and negative Eu anomalies, supports assimilation of crustal material in the formation of the intrusive suite. Analyses of monazite and apatite grains from the carbonatite orebody also reveal a mix of primary magmatic and metasomatic (fluid-related) minerals. Compositional similarities between primary phosphates in the carbonatite and alkaline silicate rocks support a genetic link between the intrusive suites. The presence of fluids regionally and within the carbonatite orebody indicates the Mountain Pass carbonatite should not be classified as a purely magmatic REE deposit.

Arizona, California, Nevada

A framework for integrating spatiotemporal deep learning methods with landsat for annual land cover and impervious surface mapping

Land cover information is essential for understanding Earth’s surface dynamics and how vegetation, water, soil, climate, and terrain interact. The National Land Cover Database (NLCD) has been the authoritative source for consistent U.S. land cover mapping. To extend NLCD’s temporal resolution and reduce production latency, we developed the Land Cover Artificial Mapping System (LCAMS)—a prototype spatiotemporal deep learning framework piloted as the foundation for the new Annual NLCD. LCAMS builds on concepts from legacy NLCD and the U.S. Geological Survey Land Change Monitoring, Assessment, and Projection (LCMAP) initiatives. It employs a loosely coupled two-stage architecture consisting of independent but functionally interdependent spatial and temporal models. Spatial models extract per-year information from Landsat data, while the temporal models refine the spatial outputs to enforce inter-annual consistency—critical for reliable land change monitoring. LCAMS produces annual 30 m resolution land cover and impervious surface outputs, with region-specific fine-tuning to generalize across diverse landscapes and temporal dynamics. Validation was conducted using an independent dataset of 1925 randomly sampled plots from five U.S. Landsat Analysis Ready Data (ARD) tiles spanning 1985-2021, selected for spatial and temporal variability. This dataset was used consistently to evaluate LCAMS, Legacy NLCD, and LCMAP. Using the NLCD legend, LCAMS achieved 72.1 ± 1.60% overall agreement, compared to 71.1 ± 1.7% agreement for Legacy NLCD. Using the LCMAP legend, LCAMS achieved 83.4 ± 1.22% agreement, compared to 84.6 ± 1.11% agreement for LCMAP. Overall, LCAMS delivers comparable accuracy while offering higher thematic resolution, longer temporal coverage, and automated production of annual 30 m CONUS land cover.

Remote Sensing of Environment

Indications of preferential groundwater seepage feeding northern peatland pools

Groundwater seepage from underlying permeable glacial sedimentary structures, such as eskers, has been hypothesized to directly feed pools in northern peat bogs. These hypotheses directly contradict classical peat bog models for ombrogenous systems, wherein meteoric water is the sole water input to these systems. Variations in the underlying mineral sediment in contact with the peat imply that unrecognized hydrogeologic connectivity may exist with pools in northern peat bogs, particularly where high permeability materials are in contact with the peat. Seepage dynamics originating from these structural variations were investigated using a suite of thermal and hydrogeophysical methods deployed around pools in a peat bog of northeastern Maine, USA. Thermal characterization methods mapped anomalies that were confirmed as matrix seepage or preferential flow pathways (PFPs). Geochemical methods were employed at identified thermal anomalies to confirm upwelling of solute-rich groundwater. Conduits around pools were associated with surficial terminations of suspected peat pipes, based on the inference of pathways extending down into the peat, that focus flow through PFPs in the peat matrix. Discharge also occurred through the peat matrix adjacent to suspected pipe structures and matrix seepage rates were quantified using analysis of diurnal temperature signals recorded at multiple depths. Seepage rates, with a maximum of nearly 0.4 m/d, were measured at localized points around pools. Periods of synchronized temperatures paired with highly muted diurnal temperature signals, recorded in diurnal temperature with depth data, were interpreted qualitatively as activation of strong upward discharge rates through suspected peat pipes. These time periods correlated strongly with local precipitation events around the peatland. Ground-penetrating radar surveys revealed discontinuities in the low permeability glacio-marine clay at the mineral sediment-peat interface, interpreted to be regional glacial esker deposits, which were located beneath and around pools. Heat tracing, specific conductance contrasts, seepage rates, and trace metal concentrations all imply groundwater seepage originating from underlying permeable glacial esker deposits and directly sourcing pools. Preferential groundwater inputs into northern peat bogs may play a key role in developing and maintaining pool systems, with enhanced solute transport impacting peatland ecology, water resources, and carbon cycling.

Maine

Magmatic source of the opening phase of Kīlauea’s 2018 Lower East Rift Zone eruption

The 2018 eruption of Kīlauea volcano in its Lower East Rift Zone began with the discharge of evolved high-Ti basalt as weak lava fountains and short, slow-moving lava flows. The lavas were quickly geochemically recognized as being derived from magmas stored within the rift zone and remobilized by a new intrusion, a sequence that is common at Kīlauea. This initial phase of the 2018 eruption, referred to as phase 1a, lasted for 6 days and was followed by extrusion of mixed magma after a 3-day pause. Even though remobilization of older rift zone magmas is common within Kīlauea’s rift zones, it is difficult to determine which past intrusion(s) may have initially emplaced those stored magmas. This difficulty stems from the tendency for Kīlauea magmas to follow very similar differentiation paths without significant variations in major, minor, or even trace element chemistry. We investigate possible magma sources for the lavas erupted during phase 1a of the 2018 eruption using whole-rock, mineral, and glass major and trace element compositions from historical East Rift Zone eruptions with adjacent fissures. We consider two primary hypotheses for the phase 1a source: magmas associated with the 1955 Lower East Rift Zone eruption or the nine eruptions in the Middle and Upper East Rift Zone during the 1960s. Our results suggest that magma associated with the earliest phases of Kīlauea’s 1955 eruption was the most likely source of the 2018 phase 1a remobilized magma. We determine volatile saturation pressures from melt inclusion chemistry and find similar storage depths for the 2018 phase 1a and early 1955 magmas. The phase 1a and early 1955 lavas are nearly indistinguishable in all of the compositional criteria considered, implying that the leftover 1955 magma body barely cooled and differentiated in the 63 years between eruptions (cooling rates of ~0.1 °C/year). This study sheds light on the potential for protracted storage of eruptible magmas in rift zones at Kīlauea, and highlights some of the challenges and solutions to identifying genetic relationships between magmas at Kīlauea.

Hawaii

Validating antler- and movement-based estimates of caribou reproduction using video camera collars

Wildlife agencies invest substantial resources in monitoring ungulate reproductive rates given ongoing concerns about population trends and their implications for management. For barren-ground caribou ( Rangifer tarandus ) in the North American Arctic, data on parturition and neonate survival have traditionally been collected using visual observations of antler retention and calf presence from small, fixed-wing aircraft. However, these surveys are weather-dependent, expensive, and dangerous, motivating the development of movement-based approaches that infer reproductive events from global positioning system (GPS) location data. We had the unique opportunity to use video camera collars to validate both antler- and movement-based methods for estimating reproduction in barren-ground caribou, using data from the Porcupine (2018–2023) and Western Arctic (2021, 2023) herds in Alaska, USA, and Yukon, Canada. For the movement-based approaches, we assessed individual-based and population-based methods, which both inferred parturition following a sharp decline in movement and inferred calf loss following a sharp increase in movement. We investigated these approaches using rarified 1-, 2-, 4-, and 8-hour fix intervals. Based on video collar observations, we found that antler retention at the onset of the calving period was highly accurate for predicting parturition (96% accuracy) but became unreliable as calving progressed, as approximately 80% of parturient females shed their antlers during the calving period. In contrast, both movement methods performed marginally for estimating caribou parturition (~70% accuracy), with estimates from the individual-based method exhibiting greater bias than those from the population-based method. The individual-based method also poorly predicted neonate survival (≤49% accuracy for detecting parturition and calf fate for the Porcupine Herd). Video data revealed that inaccuracies with the movement methods often occurred when caribou bedded during storms, rested after traversing mountainous terrain, lost a calf shortly after birth, or increased movement to evade insects. These results have important implications for management agencies using antler- and movement-based methods to estimate caribou reproduction, particularly when informing assessments of population decline or recovery. Our results demonstrate the utility of video collar data for validating reproductive monitoring approaches and provide insights into how these approaches can be improved.

Alaska, Yukon

Overstorey mortality promotes juvenile piñon pine growth during favourable weather at cooler, wetter sites

Hotter droughts have resulted in widespread tree die-off events globally, frequently leading to regeneration failure. Dry forest recovery often depends on the growth and survival of extant juvenile trees. However, it is unclear how microenvironmental changes following overstorey tree die-off affect juvenile trees, particularly in dryland systems where tree recruitment is typically limited by water availability and heat stress. We simulated an overstorey tree die-off event by girdling trees in piñon-juniper woodlands across the south-western United States. We sampled juvenile piñon pine growth from live and dead overstorey treatments across six study sites spanning a regional latitudinal gradient and local elevational gradients. We examined how juvenile branch and needle growth differed between live and dead overstorey treatments, and whether responses varied with weather conditions and juvenile tree size following overstorey mortality. We found greater juvenile branch and needle growth under dead compared with live overstorey trees for 2 years following overstorey mortality at mid- and high-elevation sites which are typically cooler and wetter than the other sites. These observed growth releases were contingent on favourable post-mortality weather conditions. Higher growth under dead overstorey occurred at sites experiencing near-average climatic water deficits compared with sites experiencing above-average climatic water deficits. Growth at all sites increased from the first to second year after overstorey mortality. Across sites, growth was unrelated to juvenile tree size. Synthesis . Our results underscore differentiation in juvenile responses to overstorey tree die-off driven by local site conditions and weather across the range of Pinus edulis . Overstorey mortality resulted in consistently higher juvenile growth only at climatically favourable sites and during favourable weather, while unmeasured microsite differences could help account for variation observed at the hottest and driest site. Results from less climatically favourable sites suggest that overstorey trees neither directly limit nor facilitate juvenile growth, though further study over longer timeframes is needed to resolve the pace and magnitude of potential recovery or decline. Overall, juvenile vigour may be promoted following overstorey mortality only in a narrow spatial (site) and temporal (weather) environmental context, suggesting additional vulnerabilities for piñon populations under more arid conditions.

Arizona, Colorado

Preliminary depth to basement modeling at Salton Sea, California

The San Andreas Fault – Imperial Fault (SAF-IF) transtensional step-over zone along the southern margin of the Salton Sea hosts substantial geothermal production and lithium brine resources. Recent volcanism at the Salton Buttes and active seismicity along the SAFIF fault system highlight active tectonic and magmatic processes that pose natural hazards and may impact energy and mineral production. Characterizing the subsurface architecture and extent of concealed alteration associated with this tectono-magmatic system enhances understanding of these active processes, associated hazards, and resources. We have compiled a gravity database, consisting of new and re-processed existing data, from which we have constructed a new isostatic residual gravity anomaly map of the Salton trough. We have used this new gravity dataset together with a compilation of publicly available borehole data to develop new depth to basement inversion models for the region. These depth to basement models help to constrain basin geometries, inform alteration mapping, and reveal variations in basement rocks. Due to the concealed nature of the complex tectonic framework at the Salton trough, it is necessary to utilize geophysical methods for subsurface characterization. These new depth to basement models are a first step toward constructing 2D and 3D geophysical and geologic models of the Imperial Valley and Salton Sea geothermal area. This analysis complements other geophysical initiatives, including magnetotelluric (MT) modeling (Tokmakoff et al., 2024), magnetic mapping (Glen and Earney, 2023, 2024) and potential field modeling, and seismic studies focused on hazard and resource investigations in the Imperial Valley.

California

Linking distribution and return-on-investment models to optimize woody management for prairie grouse in Nebraska

Grasslands in Nebraska, USA, face threats from agricultural conversion, urban development, and woody encroachment, all of which negatively affect prairie grouse ( Tympanuchus spp.) populations. To optimize conservation planning, Nebraska wildlife agencies developed probabilistic area-based surveys for greater prairie-chicken ( T. cupido ) and sharp-tailed grouse ( T. phasianellus ) to sample landscapes across a range of environmental conditions. This design improves historical surveys and enables the development of distribution models that quantitatively define habitat associations and support scenario-based conservation planning. Using survey data collected during 2020–2022, we modeled prairie grouse occurrence and abundance as functions of land cover, topography, and climate using Bayesian logistic and zero-inflated negative binomial models with regularized horseshoe priors. We then conducted a maximum potential return-on-investment analysis of woody cover treatments, assuming sustained treatment success, relative to projected impacts of woody encroachment on prairie grouse populations by 2050. Among modeled associations were a positive association with grasslands having low woody cover and a negative association with grasslands having high woody cover. Across the 3-year period, median estimated annual populations were 142,380 for greater prairie-chicken (range of 95% CIs across years = 68,821–277,615) and 64,154 for sharp-tailed grouse (range of 95% CIs across years = 27,550–146,559). Under projected woody encroachment, mean predicted population declines were 10% for greater prairie-chicken (range of 95% CIs = 7–14%) and 6% for sharp-tailed grouse (range of 95% CIs = 5–7%). Areas with high prairie grouse density and low treatment costs in 2021, and high projected woody encroachment and population loss by 2050, offered the greatest return on investment for woody management. Return on investment was greatest in the northwestern Shortgrass Prairie ecoregion (northwestern Nebraska) for sharp-tailed grouse and the eastern Sandhills ecoregion (central Nebraska) for both species. These models underscore the value of evidence-based, quantitative approaches for prioritizing conservation actions on working lands. Scenario-based modeling could be extended to guide other treatments, such as optimizing restoration (e.g., Conservation Reserve Program) or incentivizing grassland persistence in areas with predicted climate resilience.

Nebraska

Wave propagation in layered soil deposits

Recent advances in the general theory of viscoelastic waves and rays in layered media provide a rigorous mathematical framework for site-specific, soil-response models used for earthquake resistant design. The advances provide general closed-form anelastic solutions for the classic problems of the response of a stack of soil layers to S and P waves, ray theory for reflected and refracted waves, Rayleigh- and Love-Type surface waves, and head waves. These general solutions valid for anelastic media regardless of the amount of material damping yield new insights regarding the characteristics of seismic waves and their ray paths that are not provided by conventional models. They provide corresponding numerical ground-response models and ray-tracing computation algorithms that account for changes in velocity and attenuation of anelastic waves associated with changes in inhomogeneity of the waves induced by anelastic soil and soil-rock boundaries. These anelastic effects manifest themselves as variations in amplitude response, amplitude attenuation, raypath location, and travel time as observed at the Earth’s surface. Implications of these anelastic effects for soil-response models used for earthquake resistant design are provided herein.

Conference Paper

Evaluation of solid bitumen created from marine oil shale bituminite under hydrous and anhydrous pyrolysis conditions

To test the influence of environmental conditions on aromaticity of solid bitumen generated during petroleum generation, four organic-rich (26–36 wt% total organic carbon) oil shale samples collected from the Neoproterozoic–Lower Cambrian restricted marine Salt Range Formation in the upper Indus Basin, Pakistan, were pyrolyzed under hydrous and anhydrous conditions. Experiments used closed system batch reactors at subcritical water temperatures between 300 and 370°C for 72 h. Thermal conversion of bituminite in the Salt Range oil shales created a newly formed solid bitumen, similar to previous observations from experiments on the Eocene lacustrine Green River Formation Mahogany zone oil shale. Newly formed solid bitumen in the Salt Range Formation oil shales generally has higher reflectance (R o ) in hydrous residues compared to anhydrous experiments subjected to the same time-temperature conditions, also similar to prior observations. This finding supports the hypothesis that radical disproportionation is favored in the presence of hydrogen contributed by water, promoting aromatization in the solid bitumen residue with concomitant increased expulsion of saturated hydrocarbons. Indigenous solid bitumen (and vitrinite in a comparison sample) also shows higher reflectance values in hydrous versus anhydrous residues, indicating that additional aromatization in the presence of exogenous hydrogen occurs both in newly formed organic matter and in organic matter that is present throughout the experiment. Despite similarities in their bulk rock geochemical screening parameters, R o evolution shows different trajectories amongst the four Salt Range oil shales, suggesting as-yet undetermined differences in kinetic properties which are probably related to differences in a priori chemical composition. These results have implications for the use of solid bitumen reflectance (BR o ) as a thermal proxy, suggesting BR o values and appearance could vary as a function of the concentration of water. Variation in water concentration may be present at the reservoir or formation scale, but may also be present at a much finer scale in tight oil shales where permeability is several orders of magnitude lower than conventional reservoirs. Therefore, local variations in the presence of water potentially could explain substantial variation in BR o values and appearance in closely spaced source rock samples and even within an individual microscope field.

Journal of Analytical and Applied Pyrolysis

Over, under, and through: Hydrologic connectivity and the future of coastal landscape salinization

Seawater intrusion (SWI) affects coastal landscapes worldwide. Here we describe the hydrologic pathways through which SWI occurs - over land via storm surge or tidal flooding, under land via groundwater transport, and through watersheds via natural and artificial surface water channels—and how human modifications to those pathways alter patterns of SWI. We present an approach to advance understanding of spatiotemporal patterns of salinization that integrates these hydrologic pathways, their interactions, and how humans modify them. We use examples across the East Coast of the United States that exemplify mechanisms of salinization that have been reported around the planet to illustrate how hydrologic connectivity and human modifications alter patterns of SWI. Finally, we suggest a path for advancing SWI science that includes (a) deploying standardized and well-distributed sensor networks at local to global scales that intentionally track SWI fronts, (b) employing remote sensing and geospatial imaging techniques targeted at integrating above and belowground patterns of SWI, and (c) continuing to develop data analysis and model-data fusion techniques to measure the extent, understand the effects, and predict the future of coastal salinization.

Water Resources Research

Forecasting volcanic activity in Germany—A multi-criteria approach

Igneous activity, including shallow intrusions and volcanism, has the potential to disrupt underground critical infrastructure. Notably, future underground infrastructure projects like high-level radioactive waste repositories must be sited in areas of extremely low disruption probability by igneous activity. In Germany, according to the Repository Site Selection Act of 2017 (Standortauswahlgesetz, or StandAG), areas in which Quaternary volcanism is either present or future volcanic activity is expected within the next 1 million years (m.y.) must be excluded from the site selection process. Although the locations of regions with Quaternary volcanism are reasonably well known in Germany, forecasting potential igneous activity at intraplate volcanic fields is challenging, as many processes and their interactions control the spatial distribution of volcanic centers. Here, a semi-quantitative, multi-criteria approach is proposed for a regional evaluation of the relative potential of future igneous activity in Germany. A variety of geoscientific indicators are used, including seismic anomalies in Earth’s mantle, gravity data, tectonic activity, sutures, ground motion, earthquakes, mantle degassing centers, and geochronological data of volcanic rocks. The indicators describe the sequence of processes from potential melt generation in Earth’s mantle, through ascent and accumulation of melt within the lithosphere, to eruption at Earth’s surface. In total, 15 out of 30 proposed geoscientific indicators are selected and quantified using 20 total assigned parameters. Defined threshold values are used to spatially delimit relevant parameter properties to focus on areas with higher potential of future magmatic activity. To consider uncertainties of parameters and their underlying processes, which are usually more spatially extensive below ground, buffer zones are defined in which values of relevance decrease with increasing distance from the initial lateral shape of a parameter. Normalized parameters are combined into an index, whose spatial value distribution is used to differentiate the relative potential of future igneous activity (within the next 1 m.y.). The sensitivity of the results is shown by varying the weighting factors for the relevant parameters in country-wide index maps. Thereby, profiles illustrate the distribution of the resulting index values and respective index fractions of various parameters. Different index maps for the relative potential of future igneous activity are presented and can be used for hazard assessments.

Professional Paper

Confocal laser-scanning microscopy (CLSM)-based thermal maturity of Tasmanites and progress in standardization of fluorescence microspectrometry

Evaluation of thermal maturity in vitrinite-free or vitrinite-deficient sediments via fluorescence microspectrometry can provide relevant information related to petroleum exploration and thermal history assessment. However, variation in spectral fluorescence properties of alginite macerals with increasing thermal maturity is largely underexplored. Here, authors of this study have applied confocal laser-scanning microscopy (CLSM) in conjunction with fluorescence microspectrometry to a maturity series of marine Upper Devonian Tasmanites algae from the Ohio Shale (Huron Member) and a single sample from the Marcellus Formation of the Appalachian Basin. Spectral fluorescence properties of Tasmanites were evaluated in relation to orientation, measurement location, and the number of measurements per sample, and were compared to published literature. Emission spectra of Tasmanites from continuous wave laser excitation (405 nm) were acquired from sections perpendicular and parallel to bedding and at different positions within individual Tasmanites bodies. The results showed a progressive red-shift in emission maxima (λ max ) in a large sample sized maturity series ( N = 19), e.g., 493 to 578 nm for the perpendicular section at middle position. Further, blue-shifted apex and mineral-adjacent positions within sections perpendicular to bedding were observed, with the latter being reported here for the first time. While blue-shift at apex positions can be attributed to mechanical deformation-induced reorientation of photoselected fluorophores, the blue-shifted mineral-adjacent positions could result from strain loading and development of a plastic deformation region at the mineral contact zone with Tasmanites . A decrease in standard deviation with increasing number of measured emission maxima is well-observed, and 15 to 20 individual measurements per sample appears sufficient for low standard deviation and coefficient of variance. CLSM-derived thermal maturity parameters indicated that a moderate positive correlation of red/green quotient (Q 650/500 ; R 2 = 0.67) with solid bitumen reflectance (BR o in %) exists. For reproducible results, the determination of λ max and Q 650/500 should be conducted exclusively in the middle position at perpendicular and parallel sections of the polished whole-rock pellets, where the lowest standard deviation in measurement was observed. These results strengthen the suitability and relevance of the CLSM technique in thermal maturity studies of dispersed organic matter (DOM) and contribute to the standardization of fluorescence microspectrometry methods in organic petrology investigation.

Kentucky, Ohio, Virginia, West Virginia

Will there be water? Climate change, housing needs, and future water demand in California

Climate change in California is expected to alter future water availability, impacting water supplies needed to support future housing growth and agriculture demand. In groundwater-dependent regions like California's Central Coast, new land-use related water demand and decreasing recharge is already stressing depleted groundwater basins. We developed a spatially explicit state-and-transition simulation model that integrates climate, land-use change, water demand, and groundwater gain-loss to examine the impact of future climate and land use change on groundwater balance and water demand in five counties along the Central Coast from 2010 to 2060. The model incorporated downscaled groundwater recharge projections based on a Warm/Wet and a Hot/Dry climate future from a spatially explicit hydrological process-based model. Two urbanization projections from a parcel-based, regional urban growth model representing 1) recent historical and 2) state-mandated housing growth projections were used as alternative spatial targets for future urban growth. Agricultural projections were based on recent historical trends from remote sensing data. Annual projected changes in groundwater balance were calculated as the difference between land-use related water demand, based on historical estimates, and climate-driven recharge plus agriculture return flows. Results indicate that future changes in climate-driven groundwater recharge, coupled with cumulative increases in agricultural water demand, result in overall declines in future groundwater balance, with a Hot/Dry future resulting in cumulative groundwater decline in all but Santa Cruz County. Cumulative declines by 2060 are especially prominent in San Luis Obispo (−2.9 to −5.1 Bm 3 ) and Monterey counties (−6.5 to −8.7 Bm 3 ), despite limited changes in agricultural water demand over the model period. These two counties show declining groundwater reserves in a Warm/Wet future as well, while San Benito and Santa Barbara County barely reach equilibrium. These results suggest future groundwater supplies may not be able to keep pace with regional demand and declining climate-driven recharge, resulting in a potential reduction in water security in the region. However, our county-scale projections showed new housing and associated water demand does not conflict with California's groundwater sustainability goals. Rather, future climate coupled with increasing agricultural groundwater demand may reduce water security in some counties, potentially limiting available groundwater supplies for new housing.

California

A conceptual framework to assess post-wildfire water quality: State of the science and knowledge gaps

Wildfire substantially alters aquatic ecosystems by inducing moderate to catastrophic physical and chemical changes. However, the relations of environmental and watershed variables that drive those effects are complex. We present a Driver-Factor-Stressor-Effect (DFSE) conceptual framework to assess the current state of the science related to post-wildfire water-quality. We reviewed 64 peer-reviewed papers using the DFSE framework to identify drivers, factors, stressors, and effects associated with each study. A total of five drivers were identified and ranked according to their frequency of occurrence in the literature: atmospheric processes > fire characteristics > ecologic processes and characteristics > land surface characteristics > soil characteristics. Commonly reported stressors include increased nutrients, runoff, and sediment transport. Furthermore, although several different factors have been used at least once to explain water-quality effects, relatively few factors outside of precipitation and fire characteristics are frequently studied. We identified several gaps indicating the need for long-term monitoring, multi-factor studies, consideration of organic contaminants, consideration of groundwater, and inclusion of soil characteristics. This assessment expands on other reviews and meta-analyses by exploring causal linkages between influential variables and overall effects in post-wildfire watersheds. Information gathered from our assessment and the framework itself can be used to inform future monitoring plans and as a guide for modeling efforts focused on better understanding specific processes or to mitigate potential risks of post-wildfire water quality.

Water Resources Research