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Annual review 2016: Exploration review

This summary of international mineral exploration activities for the year 2016 draws upon information from industry sources, published literature, SNL Metals & Mining (SNL), an offering of S&P Global Market Intelligence (New York, NY), and specialists in the U.S. Geological Survey (USGS) National Minerals Information Center. Three types of information are reported and analyzed in this annual review of international exploration: 1) budgetary statistics expressed in U.S. dollars provided by SNL; 2) regional and site-specific exploration activities that took place in 2016 as compiled by the USGS and 3) regional events and legislation that affected exploration activities including economic, social and political conditions, which were derived from published sources and discussions with USGS and industry specialists. Commodity and regional compilations are presented in this summary. Because multiple sources were used to develop commodity and regional compilations, statistics may vary depending on the source and type of data that are being reported.

Mining Engineering

Apparent Consumption vs. Total Consumption--A Lead-Acid Battery Case Study

Introduction: This report compares estimates of U.S. apparent consumption of lead with estimates of total U.S. consumption of this mineral commodity from a materials flow perspective. The difference, attributed to the amount of lead contained in imported and exported products, was found to be significant for this sector. The study also assesses the effects of including mineral commodities incorporated in manufactured products on the interpretation of observed trends in minerals consumption and trade. Materials flow is a systems approach to understanding what happens to the materials we use from the time a material is extracted, through its processing and manufacturing, to its ultimate disposition. The U.S. Geological Survey (USGS) provides accurate and detailed mineral production and mineral commodity consumption statistics that are essential for government, nongovernment organizations, and the public to gain a better understanding of how and where materials are used and their effect on the environment and society. Published statistics on mineral apparent consumption are limited to estimates of consumption of raw material forms (ore, concentrate, and [or] refined metal). For this study, apparent consumption is defined as mine production + secondary refined production + imports (concentrates and refined metal) ? exports (concentrates and refined metal) + adjustments for government and industry stock changes. These estimates do not account for the amount of mineral commodities contained in manufactured products that are imported to the United States, nor do they deduct the amount of these mineral commodities contained in manufactured products that are exported from the United States. When imports or exports of manufactured products contribute significantly to the total use of a particular raw material, an estimate of consumption that does not consider the incorporated forms of these mineral commodities within imported or exported manufactured products can be either under- or overreported (depending on the net trade flow). Factors that influence consumption and trade patterns include variations in industry structure, labor or financial markets, legislation, and technology. As U.S. trade patterns of manufactured products change, omitting mineral commodities incorporated into these goods as part of U.S. mineral commodity consumption estimates may affect the interpretation of observed trends in minerals consumption and trade. Although it may be desirable to include minerals contained in manufactured products as part of consumption estimates, collection and estimation of these data are sometimes difficult. Consumption and trade data for every traded product may not be readily available. Compiling comprehensive consumption statistics for mineral commodities, which have many end uses, each including multiple products, may be time consuming. For these reasons, studies of all mineral commodities are not feasible. Mineral commodity selection for this study is based on data accessibility considerations and the relative importance of lead contained in imported and exported products when considered part of total U.S. lead consumption. Lead was selected for this initial evaluation of total mineral consumption because of the need to understand the consumption pattern of this potentially toxic metal and its compounds, the relative simplicity of this sector?s end-use structure, and the availability of trade data. This study draws upon the findings of an earlier lead consumption study (Biviano and others, 1999) conducted by the USGS for the period 1984 to 1993, but uses a different study methodology for an industry whose structure has changed from that considered in the earlier study. Figure 1 shows the quantity of material contributing to U.S. total consumption of lead metal from domestic and foreign industrial sectors in 2004, based upon trade data reported by the USGS and the U.S. International Trade Commission (USITC). For

Scientific Investigations Report

Water resources inventory of Connecticut Part 3: lower Thames and southeastern coastal river basins

The lower Thames and southeastern coastal river basins have a relatively abundant supply of water of generally good quality which is derived from streams entering the area and precipitation that has fallen on the area. Annual precipitation has ranged from about 32 inches to 65 inches and has averaged about 48 inches over a 30-year period. Approximately 22 inches of water are returned to the atmosphere each year by evaporation and transpiration; the remainder of the annual precipitation either flows overland to streams or percolates downward to the water table and ultimately flows out of the report area through estuaries and coastal streams or as underflow through the deposits beneath. During the autumn and winter months precipitation normally is sufficient to cause a substantial increase in the amount of water stored underground and in surface reservoirs within the report area, whereas in the summer most of the precipitation is lost through evaporation and transpiration, resulting in sharply reduced stream-flow and lowered ground-water levels. The mean monthly storage of water on an average is about 3.8 inches higher in November than it is in June. The amount of water that flows through and out of the report area represents the total amount of water potentially available for use by man. For the 30-year period 1931 through 1960, the annual runoff from the report area has averaged nearly 26 inches (200 billion gallons), from the entire Thames River basin above Norwich about 24 inches (530 billion gallons), and from the Pawcatuck River basin about 26 inches (130 billion gallons). A total average annual runoff of 860 billion gallons is therefore available. Although runoff indicates the total amount of water potentially available, it is usually not economically feasible for man to use all of it. On the other hand, with increased development, it is possible that some water will be reused several times. The water available may be tapped as it flows through the area or is temporarily stored in streams, lakes, and aquifers. The amounts that can be developed vary from place to place and time to time, depending on the amount of precipitation, on the size of drainage area, on the thickness, permeability, and areal extent of aquifers, and on the variations in chemical and physical quality of the water. Differences in streamflow from point to point are due primarily to differences in the proportion of stratified drift in the drainage basin above each point, which affect the timing of streamflow, and to differences in precipitation, which affect the amount of streamflow. Ground water can be obtained from wells almost anywhere in the area, but the amount obtainable at any particular point depends upon the type and water-bearing properties of the aquifers. For practical purposes, the earth materials in the report area comprise three aquifers--stratified drift, bedrock, and till. Stratified drift is the only aquifer generally capable of yielding more than 100 gpm (gallons per minute) to individual wells. It covers about 20 percent of the area and occurs chiefly in lowlands where it overlies till and bedrock. The coefficient of permeability of the coarse-grained unit of stratified drift averages about 1,500 gbd (gallons per day) per sq ft. Drilled, screened wells tapping this unit are known to yield from 4 to 88o gpm and average 146 gpm. Dug wells in coarse-grained stratified drift supply about 2 gpm per foot of drawdown over a period of a few hours. Fine-grained stratified drift has an average coefficient of permeability of about 300 gpd per sq ft and can usually yield supplies sufficient for household use to dug wells. Bedrock and till are widespread in extent but generally provide only small water supplies. Bedrock is tapped chiefly by drilled wells, about 90 percent of which will supply at least 3 gpm. Very few, however, will supply more than 50 gpm. Till is tapped in a few places by dug wells which can yield small supplies of only a few hundred gpd throughout all or most of the year. The coefficient of permeability of till ranges from about 0.2 gpd per sq ft to 120 gpd per sq ft. The amount of ground water potentially available in the report area depends upon the amount of ground-water outflow, the amount of ground water in storage, and the quantity of water available by induced infiltration from streams and lakes. From data on permeability, saturated thickness, recharge, yield from aquifer storage, well performance, and streamflow, preliminary estimates of ground-water availability can be made for any point in the report area. Long-term yields estimated for 18 areas of stratified drift especially favorable for development of large ground-water supplies ranged from 1.3 to 66 mgd. Detailed site studies to determine optimum yields, drawdowns, and spacing of individual wells are needed before major ground-water development is undertaken in these or other areas. The chemical quality of water in the report area is generally good to excellent. Samples of naturally occurring surface water collected at 24 sites contained less than 151 ppm (parts per million) of dissolved solids and less than 63 ppm of hardness. Water from wells is more highly mineralized than naturally occurring water from streams. Even so only 12 percent of the wells sampled yielded water with more than 200 ppm of dissolved solids and only 8 percent yielded water with more than 120 ppm of hardness. Even in major streams, which are used to transport industrial waste, hardness rarely exceeds 60 ppm and the dissolved mineral content is generally less than 200 ppm. At a few places in the town of Montville however, waters may contain dissolved mineral concentrations of 2,000 to 4,000 ppm. Iron and manganese in both ground water and surface water are the only constituents whose concentrations commonly exceed recommended limits for domestic and industrial use. Most wells in the report area yield clear water with little or no iron or manganese, but distributed among them are wells yielding ground water that contains enough of these dissolved constituents to be troublesome for most uses. Iron concentrations in naturally occurring stream water exceed 0.3 ppm under low-flow conditions at 33 percent of the sites sampled. Large concentrations of iron in stream water result from discharge of iron-bearing water from aquifers or from swamps where it is released largely from decaying vegetation. Ground water more than 30 feet below the land surface has a relatively constant temperature, usually between 48°F and 52°F. Water temperature in very shallow wells may fluctuate from about 38°F in February or March to about 55°F in late summer. Water temperature in the larger streams fluctuates much more widely, ranging from 32°F at least for brief periods in winter, to about 85°F occasionally during summer. The quality of suspended sediment transported by streams in the area is negligible. Turbidity in streams is generally not a problem although amounts large enough to be troublesome may occur locally at times. The total amount of water used in the report area for all purposes during 1964 was about 118,260 million gallons, of which 105,600 million gallons was estuarine water used for cooling by industry. The average per capita water use, excluding estuarine, temporary summer residence, and institutional water was equivalent to 186 gpd. Public water systems supplied the domestic needs of nearly tw0-thirds the population of the report area. All of the 19 systems, which were sampled, provided water of better quality than the U.S. Public Health Service suggests for drinking water standards.

Connecticut

Surface waters of Illinois River basin in Arkansas and Oklahoma

The estimated runoff from the Illinois River basin of 1,660 square miles has averaged 1,160,000 acre-feet per year during the water years 1938-56, equivalent to an average annual runoff depth of 13.1 inches. About 47 percent of the streamflow is contributed from drainage in Arkansas, where an average of 550,000 acre-ft per year runs off from 755 square miles, 45.5 percent of the total drainage area. The streamflow is highly variable. Twenty-two years of record for Illinois River near Tahlequah, Okla., shows a variation in runoff for the water year 1945 in comparison with 1954 in a ratio of almost 10 to 1. Runoff in 1927 may have exceeded that of 1945, according to records for White River at Beaver, Ark., the drainage basin just east of the Illinois River basin. Variation in daily discharge is suggested by a frequency analysis of low flows at the gaging station near Tahlequah, Okla. The mean flow at that site is 901 cfs (cubic feet per second), the median daily flow is 350 cfs, and the lowest 30-day mean flow in a year probably will be less than 130 cfs half of the time and less than 20 cfs every 10 years on the average. The higher runoff tends to occur in the spring months, March to May, a 3-month period that, on the average, accounts for almost half of the annual flow. High runoff may occur during any month in the year, but in general, the streamflow is the lowest in the summer. The mean monthly flow of Illinois River near Tahlequah, Okla., for September is about 11 percent of that for May. Records show that there is flow throughout the year in Illinois River and its principal tributaries Osage Creek, Flint Creek and Barren Fork. The high variability in streamflow in this region requires the development of storage by impoundment if maximum utilization of the available water supplies is to be attained. For example, a 120-day average low flow of 22 cfs occurred in 1954 at Illinois River near Tahlequah, Okla. To have maintained the flow at 350 cfs, the median daily flow during the 19-year base period, an impoundment at that site would have required a usable storage of 185,000 acre-ft to satisfy this demand during the drought years 1954-1956. The surface waters of the Illinois River basin are excellent quality being suitable for municipal, agriculture and most industrial uses. The average concentration of the dissolved mineral content is about 105 ppm (parts per million) and the hardness about 85 ppm. The water is slightly alkaline, having a range of pH values from 7.2 to 8.0. This report gives the estimated average discharge at gaging stations and approximations of average discharge at the State line for 3 sub-basins during the 19-year period October 1937 to September 1956, used as a base period in this report. Duration-of-flow data for various percentages of the time are shown for the period of observed record at the gaging stations; similar data are estimated for the selected base period. Storage requirements to sustain flow during the recent drought years are given for 3 stations. The streamflow records in the basin are presented on a monthly and annual basis through September 1957; provisional records for 3 stations are included through July 1958 for correlation purposes. Results of discharge measurements are given for miscellaneous sites where low-flow observations have been made. (available as photostat copy only)

Open-File Report

United States Geological Survey Yearbook, fiscal year 1980

It is not very often that a single event is so overwhelming that it changes public perceptions of natural hazards for generations. Perhaps for the U.S. Geological Survey, the explosive volcanic activity of Mount St. Helens began such a change. After 101 years of careful science of the Earth's past and meticulous observations and assessments of the present, predictive earth science was in full public view. However vague and faint the glimpse of the future made possible by earth science, it was enough. Warnings were issued, thousands of lives were saved, and the age of real-time geology began. The Survey's basic mission has not changed, but the power of our analytical tools has increased by several orders of magnitude. The Survey's efforts to understand Earth processes and hydrologic principles continued with the collection, during fiscal year 1980, of valuable new data on the geologic origin and framework, seismicity, and mineral and energy resources of the United States. The Survey is also responsible for classification of the leasable minerals on Federal lands and the regulation of mineral exploration and development activities on Federal and Indian lands. As the principal earth science fact-gathering agency, the Survey provides information for sound decisionmaking by government and private industry. Industry uses the Survey's information in exploring for energy and minerals and improving their efforts to make development of energy and minerals compatible with environmental protection standards. Government uses the Survey's information in conducting leasing operations on public lands, in regulating the safe design and siting of nuclear plants, and in establishing guidelines for determining and locating areas that are subject to geologic hazards such as landslides, earthquakes, and volcanic eruptions. The Yearbook reports a broad range of the Survey's accomplishments during the past fiscal year and provides an overview of future directions. Many of the topics covered will continue to be important natural resource and earth science issues of the 1980's.

Yearbook

Mineral of the month: chromium

Chromium is one of the most indispensable industrial metals and it plays an essential but hidden role in daily life. Chromium is used in many consumer and building products, and it contributes to a clean, efficient and healthy environment.

Geotimes

Mineral resource of the month: antimony

The article describes the characteristics and industrial uses of antimony. Antimony, which is produced as a byproduct of mining other metals such as gold, lead or silver, is used in everything from flame retardants, batteries, ceramics and glass. It is also used in glass for television picture tubes, computer monitors, pigments and catalysts.

Earth

Magnetic susceptibilities of minerals

Magnetic separation of minerals is a topic that is seldom reported in the literature for two reasons. First, separation data generally are byproducts of other projects; and second, this study requires a large amount of patience and is unusually tedious. Indeed, we suspect that most minerals probably are never investigated for this property. These data are timesaving for mineralogists who concentrate mono-mineralic fractions for chemical analysis, age dating, and for other purposes. The data can certainly be used in the ore-beneficiation industries. In some instances, magnetic-susceptibility data may help in mineral identification, where other information is insufficient. In past studies of magnetic separation of minerals, (Gaudin and Spedden, 1943; Tille and Kirkpatrick, 1956; Rosenblum, 1958; Rubinstein and others, 1958; Flinter, 1959; Hess, 1959; Baker, 1962; Meric and Peyre, 1963; Rojas and others, 1965; and Duchesne, 1966), the emphasis has been on the ferromagnetic and paramagnetic ranges of extraction. For readers interested in the history of magnetic separation of minerals, Krumbein and Pettijohn (1938, p. 344-346) indicated nine references back to 1848. The primary purpose of this paper is to report the magnetic-susceptibility data on as many minerals as possible, similar to tables of hardness, specific gravity, refractive indices, and other basic physical properties of minerals. A secondary purpose is to demonstrate that the total and best extraction ranges are influenced by the chemistry of the minerals. The following notes are offered to help avoid problems in separating a desired mineral concentrate from mixtures of mineral grains.

Open-File Report

Mineral resources of the U.S. Atlantic continental margin

Most geologic materials may be usable resources in some form and at some time, whether it be for general land fill and aggregate, beach replenishment, construction material, or as a source of metals and fuels. Thus, most natural materials occurring within the Atlantic continental margin are resources, defined as “materials, including those only surmised to exist, that have present or anticipated future value” (U.S.G.S., 1980). Whether a resource becomes a reserve or not (an economically recoverable commodity) depends upon the properties and economic values of that material, which are determined by the following factors: (a) availability, concentration, and occurrence of the material; (b) methods of recovering and processing the commodity; (c) transportation costs of ore and beneficiated products; and (d) environmental setting and costs of permitting and mitigation. Also, the economics of a given mineral resource change dramatically in response to new technological advances, discoveries of new deposits, or as industrial and social demands change through time. An increasingly critical component associated with the economics for development of any mineral commodity, is a good geologic knowledge of the resource base.

Atlantic Continental Margin

Variability in results from mineralogical and organic geochemical interlaboratory testing of U. S. Geological Survey shale reference materials

The expansion of unconventional petroleum resource exploration and production in the United States has led to an increase in source rock characterization efforts, particularly related to bulk organic and mineralogical properties. To support the analytical and research needs of industry and academia, as well as internal work, the U.S. Geological Survey (USGS) has collected and prepared shale geochemical reference materials (GRMs) from several major shale petroleum systems in the U.S. The sources of these materials are the Late Cretaceous Boquillas (lower Eagle Ford-equivalent) Formation (roadcut near Del Rio, TX), Late Cretaceous Mancos Shale (outcrop near Delta, CO), Devonian–Mississippian Woodford Shale (outcrop near Ardmore, OK), Late Cretaceous Niobrara Formation (quarry near Lyons, CO), Middle Devonian Marcellus Shale (creek bed in LeRoy, NY), and Eocene Mahogany zone oil shale of the Green River Formation (oil shale mine near Rifle, CO). Of particular interest in the development of these GRMs has been the examination of variability between laboratories and specific methods or instruments in commonly made measurements, including major- and trace-element concentrations, X-ray diffraction (XRD) mineralogy, total organic carbon (TOC) content, and programmed pyrolysis (PP) parameters. For the component concentrations and parameters we measured, the techniques and instrument types included: (1) elemental analysis by X-ray fluorescence, inductively coupled plasma mass spectrometry, and instrumental neutron activation analysis; (2) XRD mineralogy with various preparatory methods (spray drying or micronizing with or without internal standard); (3) TOC by combustion with infrared detection after carbonate removal or the PP approach; (4) PP by Rock-Eval 2 or more recently developed instruments (Rock-Eval 6, Source Rock Analyzer or SRA, and Hydrocarbon Analyzer With Kinetics or HAWK). Overall, the results showed that the selected shales cover a wide range of source rock organic and mineralogical properties. Major- and trace-element chemistry results showed low heterogeneity consistent with other USGS GRMs. Comparison of TOC results showed coefficients of variation (COV) of around 5% and the most consistent organic geochemical results between different laboratories and methods. Arguably the most relevant PP measurement, S2 or kerogen hydrocarbon-generating potential (mg-HC/g-rock), showed a somewhat wider range of variability than TOC (COV ~10%), but was consistent between the three modern instruments and the industry-standard Rock-Eval 2. Major phase mineralogy (mineral concentrations ≥10 wt. %, organic-free basis) were comparable between laboratories, but variability in minor phase identification and quantification was observed. Utilization of these shale GRMs as quality control samples and testing materials is expected to help support analytical and experimental efforts in the continued development of unconventional petroleum resources.

Colorado, Texas, Oklahoma

U.S. Geological Survey Appalachian region integrated science workshop proceedings, Gatlinburg, Tennessee, October 22-26, 2001

Some of nature's most magnificent creations on Earth are the picturesque landscape and the terrestrial and aquatic inhabitants of the Appalachian Mountains of the Eastern United States. Mother Nature has been kind to the region but man, often, has not. The Appalachian mountains and valleys have been home to a variety of human cultures, dating back approximately 12,000 years. A series of Native American peoples, including most recently the Cherokee Nation, inhabited the region prior to European settlement which began in the 1600's. All of these peoples have had the desire to reap the benefits of the land. Current and historic use of the land ranges from mineral extraction to agricultural development to timber production to industrial and residential development, all of which have now threatened the landscape. Many individuals and organizations desire to save the awe and beauty of the Appalachians for the generations to come, in a way that is environmentally and economically sustainable. They have tried for years to raise alarms that this area is threatened and worth the attention of all who are interested in an effort of restitution and preservation. Residents, environmental groups, land managers, scientists, business groups, and the multitude of visitors who pass through the national parks and other public lands located within the Appalachians have raised these same alarms. There is a need to not only identify the issues resulting from anthropogenic pressures on the landscape, but also to collect the information and conduct the science that will allow land managers and policy makers to become better informed and better able to execute their responsibilities.

Appalachia

Water availability, Jefferson County, Alabama

The average annual precipitation in Jefferson County is about 53 inches (1,346.2 millimeters) or about 2,820 mgd (million gallons per day), which is equivalent to 124 m 3 /s (cubic meters per second). Part of the rainfall (about 1,130 mgd or 50 m 3 /s) runs off directly into streams, and the remaining 1,690 mgd (74 m 3 /s) replenishes soil moisture to underground reservoirs. Potential sources of ground water in the county are limestone, dolomite, sandstone, and chert aquifers. Wells developed in these aquifers may produce as much as 0.5 mgd (0.022 m 3 /s) per well. In some areas, wells developed in the limestone, dolomite, and chert aquifers may produce more than 0.5 mgd (0.022 m 3 / s) per well. Potential sources of surface water in Jefferson County are the Black Warrior and Cahaba Rivers, Locust Fork, and Valley, Village, Fivemile, Shades, and Turkey Creeks. Average flows at the mouth of these streams or at the point where the stream leaves the county are 4, 070, 250, 1, 230, 360, 100, 120, 100, and 90 mg (178, 11, 54, 16, 4.4, 5. 3, 4. 4, and 3.9 m 3 /s), respectively. Low flows (7-day Q 2 ) are generally in the range of 10 to 100 mgd (0. 44 to 4.4 m 3 /s). Most streams, however, are affected in some way by urbanization. These effects must be considered and better defined before extensive use of streamflow is made. Water from the limestone and dolomite aquifers generally is moderately hard to very hard, contains less than 0.3 mg/1 (milligrams per liter) iron, and has 3 median value of 150 mg/1 dissolved solids. Water from the sandstone aquifer generally is soft to moderately hard, contains iron in excess of 0.3 mg/1, and has a median value of 210 mg/1 dissolved solids. The concentrations of mineral constituents of surface water generally become progressively greater in the downstream direction. The increase in concentration of mineral constituents is attributed to inflow of municipal and industrial waste in the downstream reaches of the stream. This waste disposal has degraded the quality of water in Shades, Valley, Village, and Fivemile Creeks, and Locust Fork. The average water use in Jefferson County was estimated to be about 200 mgd (8.8 m 3 /s) in 1970. The major sources of this supply are Lewis Smith Lake, Inland Lake, and Lake Purdy. These three sources supply water for about 75 percent of Jefferson County's population or 66 percent of the water used.

Alabama

Borates

Four minerals represent 90 percent of the borates used by industry worldwide — the sodium borates, tincal and kernite; the calcium borate, colemanite; and the sodium-calcium borate, ulexite.

Mining Engineering

The US Geological Survey’s Earth Mapping Resources Initiative (Earth MRI)—Providing framework geologic, geophysical, and elevation data to the nation’s critical mineral-bearing regions

New detailed mapping of the geologic resources of the Nation has the potential to significantly close the gap in the essential data needed to fuel a modern era of economic development and technological innovation, while at the same time dramatically enhancing our understanding of the fundamental way geology impacts everyday life, from the domestic critical mineral resources that are necessary for modern technology and the economy, to domestic energy and water resources, geologic hazards, agriculture, and other pressing needs. The U.S. Geological Survey established the Earth Resources Mapping Initiative (Earth MRI) to address the shortfall in geologic, geophysical, and elevation data with sufficient detail to support evaluation of regions in the United States that have potential to host critical mineral resources. The new effort is a collaboration with the Association of American State Geologists, who are providing new detailed geologic maps and making available online archived data and information related to critical mineral resources. The geophysical and lidar surveys are being contracted through industry specialists to assure that high-quality data are available to the public. This article provides an overview of the Earth MRI effort with discussions on the initial geophysical surveys funded for areas that have known potential for rare earth element resources. Subsequent projects are being designed to address areas that may host other critical mineral resources.

Fast Times

A compilation of rate parameters of water-mineral interaction kinetics for application to geochemical modeling

Geochemical reaction path modeling is useful for rapidly assessing the extent of water-aqueous-gas interactions both in natural systems and in industrial processes. Modeling of some systems, such as those at low temperature with relatively high hydrologic flow rates, or those perturbed by the subsurface injection of industrial waste such as CO2 or H2S, must account for the relatively slow kinetics of mineral-gas-water interactions. We have therefore compiled parameters conforming to a general Arrhenius-type rate equation, for over 70 minerals, including phases from all the major classes of silicates, most carbonates, and many other non-silicates. The compiled dissolution rate constants range from -0.21 log moles m-2 s-1 for halite, to -17.44 log moles m-2 s-1 for kyanite, for conditions far from equilibrium, at 25 ?C, and pH near neutral. These data have been added to a computer code that simulates an infinitely well-stirred batch reactor, allowing computation of mass transfer as a function of time. Actual equilibration rates are expected to be much slower than those predicted by the selected computer code, primarily because actual geochemical processes commonly involve flow through porous or fractured media, wherein the development of concentration gradients in the aqueous phase near mineral surfaces, which results in decreased absolute chemical affinity and slower reaction rates. Further differences between observed and computed reaction rates may occur because of variables beyond the scope of most geochemical simulators, such as variation in grain size, aquifer heterogeneity, preferred fluid flow paths, primary and secondary mineral coatings, and secondary minerals that may lead to decreased porosity and clogged pore throats.

Open-File Report

Carolina slate belt gold deposits in Virginia, North Carolina, South Carolina, and Georgia

The Southeastern United States, in particular, the Carolina slate belt of Virginia, North Carolina, South Carolina, and Georgia, has been an important region of mineral production (fig. 1). This region is thought to have major potential for containing large undiscovered deposits of gold and silver, as well as copper, lead, zinc, molybdenum, and tin. Gold production from the major mines (Haile, Brewer, Ridgeway, and Barite Hill) in South Carolina ranked sixth in the Nation in 1992. Despite the closing of all but one mine in 1997, the region continues to attract intense scrutiny by the mining industry. Current U.S. Geological Survey (USGS) efforts in the slate belt are led by a multidisciplinary team focused on an integrated, multistate, and multiyear project that has the potential to result in a fundamental reinterpretation of the economic geology of the region. The slate belt is considered a scientific frontier because of the rapid pace of data acquisition by the USGS, academia, and private sector geologists and because emerging concepts of its geologic evolution are controversial. Establishing the origin of the gold deposits is important, not only in guiding exploration, but for more accurate assessment of the potential for the occurrence of new deposits throughout the southern Appalachians. These efforts may result in further industry exploration that may lead to discovery of new economically viable mineral deposits, which would have a broad economic impact on the region. Another goal is to find ways to prevent human activities related to gold extraction from remobilizing toxic metals found in these deposits, which could have potential harmful effects on the environment.

Georgia, North Carolina, South Carolina, Virginia

Historical files from Federal Government mineral exploration-assistance programs, 1950 to 1974

The Defense Minerals Administration (DMA), Defense Minerals Exploration Administration (DMEA), and Office of Minerals Exploration (OME) mineral exploration programs were active over the period 1950–1974. Under these programs, the Federal Government contributed financial assistance in the exploration for certain strategic and critical minerals. The information about a mining property that was collected under these programs was placed in files called dockets. A docket is a collection of material (application, contract, correspondence, maps, reports, results) about a property for which an individual applied for exploration assistance from the Federal Government. Information found in dockets describe where mineral deposits were examined, what was found, and whether it was mined. As such, they provide very useful information to private industry regarding potential and non-potential prospect areas, provide the U.S. Geological Survey with useful information on mineral occurrences that are used in national assessments for particular mineral deposits, and provide other U.S. Federal agencies (Bureau of Indian Affairs, Bureau of Land Management, and Environmental Protection Agency) information relevant to land management, permitting, and leasing.

Data Series

Mineral resource of the month: cobalt

Cobalt is a metal used in numerous commercial, industrial and military applications. On a global basis, the leading use of cobalt is in rechargeable lithium-ion, nickel-cadmium and nickel-metal hydride battery electrodes. Cobalt use has grown rapidly since the early 1990s, with the development of new battery technologies and an increase in demand for portable electronics such as cell phones, laptop computers and cordless power tools.

Earth