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At least 343 records · Page 19Linked to original sources

Response of fish assemblages to declining acidic deposition in Adirondack Mountain lakes, 1984–2012

Adverse effects of acidic deposition on the chemistry and fish communities were evident in Adirondack Mountain lakes during the 1980s and 1990s. Fish assemblages and water chemistry in 43 Adirondack Long-Term Monitoring (ALTM) lakes were sampled by the Adirondack Lakes Survey Corporation and the New York State Department of Environmental Conservation during three periods (1984–87, 1994–2005, and 2008–12) to document regional impacts and potential biological recovery associated with the 1990 amendments to the 1963 Clean Air Act (CAA). We assessed standardized data from 43 lakes sampled during the three periods to quantify the response of fish-community richness, total fish abundance, and brook trout ( Salvelinus fontinalis) abundance to declining acidity that resulted from changes in U.S. air-quality management between 1984 and 2012. During the 28-year period, mean acid neutralizing capacity (ANC) increased significantly from 3 to 30 μeq/L and mean inorganic monomeric Al concentrations decreased significantly from 2.22 to 0.66 μmol/L, yet mean species richness, all species or total catch per net night (CPNN), and brook trout CPNN did not change significantly in the 43 lakes. Regression analyses indicate that fishery metrics were not directly related to the degree of chemical recovery and that brook trout CPNN may actually have declined with increasing ANC. While the richness of fish communities increased with increasing ANC as anticipated in several Adirondack lakes, observed improvements in water quality associated with the CAA have generally failed to produce detectable shifts in fish assemblages within a large number of ALTM lakes. Additional time may simply be needed for biological recovery to progress, or else more proactive efforts may be necessary to restore natural fish assemblages in Adirondack lakes in which water chemistry is steadily recovering from acidification.

New York

Surficial sediment character of the New York-New Jersey offshore continental shelf region: A GIS compilation

Broad continental shelf regions such as the New York Bight are the product of a complex geologic history and dynamic oceanographic processes, dominated by the Holocene marine transgression (>100 m sea-level rise) following the end of the last Pleistocene ice advance ~ 20,000 years ago. The area of the U.S. Exclusive Economic Zone (U.S. EEZ) territory, extending 200 nautical miles seaward from the coast, is larger than the continental U.S. and contains submerged landforms that provide a variety of natural functions and societal benefits, such as: critical habitats for fisheries, ship navigation and homeland security, and engineering activities (i.e. oil and gas platforms, pipeline and cable routes, potential wind-energy-generation sites). Some parts of the continental margins, particularly inner-continental shelf regions, also contain unconsolidated hard-mineral deposits such as sand and gravel that are regarded as potential aggregate resources to meet or augment needs not met by onshore deposits (Williams, 1992). The present distribution of surficial sediment off the northeastern United States is shaped from the deposits left by the last glaciation and reflects the cumulative effects of sediment erosion, transport, sorting, and deposition by storm and tidal processes during the Holocene rise in sea level. As a result, the sediments on the sea floor represent both an historical record of former conditions and a guide to possible future sedimentary environments. The U.S. Geological Survey (USGS) through the Coastal and Marine Geology Program, in cooperation with the University of Colorado and other partners, has compiled extant sediment character and textural data as well as other geologic information on the sea floor from all regions around the U.S. into the usSEABED data system (Reid and others, 2005; Buczkowski and others, 2006; Reid and others, 2006). The usSEABED system, which contains information on sediment grain size and lithology for more than 340,500 stations within the U.S. EEZ. has been developed and populated with data as part of the USGS Marine Aggregate Resources and Processes and the National Benthic Habitats projects in order to provide the base-line data needed to update the current maps of offshore surficial geologic character and sediment distribution. The maps are also used to characterize benthic sea floor environments important for marine ecosystems. U.S. Geological Survey, Data Series 118 (Reid and others, 2005), of the usSEABED data release series, represents the combined efforts of the USGS and several other government agencies to provide a unified resource for accessing and preserving records of U.S. east coast sea floor geologic information and sediment texture data. For this present report, we have chosen to focus on the New York-New Jersey region, an area that has been intensely studied by the USGS for many years to address many complex issues. This report illustrates the uses of the usSEABED database for GIS applications, while offering additional insight into the resources and data available from the USGS and its collaborative institutions. This report is based on data contained in U.S. Geological Survey Data Series 118 (Reid and others, 2005) and shows an assortment of example GIS products that are possible using usSEABED. All data are intended to be GIS-ready and should not require any additional cleanup, formatting, or renaming of fields in order to use the data in a Geographic Information System. This project employs the Environmental Systems Research Institute's (ESRI) ArcView™ software. Many of these maps were made as part of the ongoing USGS study to assess marine aggregate resources offshore New York and New Jersey, but these maps can serve many other purposes. The marine science community, educators, students and others are encouraged to use these data to generate GIS products for their own purposes. The objectives of the Marine Aggregate Resources and Processes project are to produce a series of new geologic maps and reports of the sea floor that will provide scientific insights into the character and geologic development of U.S. continental margins and to use these maps and information to assess the potential availability of offshore sand and gravel resources. The mapping and aggregate resource assessments are being conducted on a national scale using the usSEABED data base as described in Williams and others (2003). Potential uses for these data include: (1) defining the geological variability of the sea floor in relation to benthic habitat diversity; (2) improving our understanding of the processes that control the distribution and transport of bottom sediments and benthic habitats; (3) locating aggregate resources for beach nourishment and industrial applications; and (4) providing a detailed geospatial framework for future marine science research, monitoring, and management activities. The initial assessments are in progress for the New York Bight and Louisiana offshore areas.

New Jersey, New York

Relating management practices and nutrient export in agricultural watersheds of the United States

Relations between riverine export (load) of total nitrogen (N) and total phosphorus (P) from 133 large agricultural watersheds in the United States and factors affecting nutrient transport were evaluated using empirical regression models. After controlling for anthropogenic inputs and other landscape factors affecting nutrient transport-such as runoff, precipitation, slope, number of reservoirs, irrigated area, and area with subsurface tile drains-the relations between export and the area in the Conservation Reserve Program (CRP) (N) and conservation tillage (P) were positive. Additional interaction terms indicated that the relations between export and the area in conservation tillage (N) and the CRP (P) progressed from being clearly positive when soil erodibility was low or moderate, to being close to zero when soil erodibility was higher, to possibly being slightly negative only at the 90th to 95th percentile of soil erodibility values. Possible explanations for the increase in nutrient export with increased area in management practices include greater transport of soluble nutrients from areas in conservation tillage; lagged response of stream quality to implementation of management practices because of nitrogen transport in groundwater, time for vegetative cover to mature, and/or prior accumulation of P in soils; or limitations in the management practice and stream monitoring data sets. If lags are occurring, current nutrient export from agricultural watersheds may still be reflecting the influence of agricultural land-use practices that were in place before the implementation of these management practices.

Journal of Environmental Quality

Watershed Continuum Monitoring Approach: Combining multiple water quality patterns along stream and river flowpaths to track sources, pathways, and processing of pollutants

There is a growing need to improve and expand water quality monitoring approaches to more accurately track the sources, fate, and transport of multiple chemicals and pollutants holistically and quantify the effects of best management practices (BMPs) at the watershed scale. An overarching question raised by scientists, environmental managers, and the general public is: how far can water quality impacts from disturbances or benefits from watershed management and restoration propagate along stream and river flowpaths? Many studies using the classic watershed approach focus on analyzing changes in water quality over time at one or a few sampling stations, whereas theories such as the River Continuum Concept focus on predicting shifts in energy sources and biological communities along rivers but have not been directly applied to water quality. We propose to merge these concepts to create a Watershed Continuum Monitoring Approach (WCMA) that combines both spatial and temporal monitoring in order to better detect and quantify trends and transitions in multiple water quality indicators along flowpaths. Specifically, an array of multiple water quality indicators are analyzed at multiple downstream points along a watershed flowpath over time. These multiple water quality indicators are analyzed together for making comparisons to infer hydrological, biological, and geochemical processes controlling sources, transport, and attenuation of pollutants ( e.g. , analagous to stream tracer studies at the watershed scale). The WCMA leverages the natural expansion of watershed areas along a flowpath, which reflect transitions in land use, land cover, and environmental management across spatial and temporal dimensions for making direct comparisons across different stream reaches and spatial trend analysis. WCMA facilitates monitoring of multiple water quality indicators together, and identifcation of hot spots in sources and attenuation of pollutants or mixtures of pollutants. We illustrate practical applications of the WCMA to analyze water quality trends, transitions, and tradeoffs ( i.e. , a tradeoff occurs when one pollutant is reduced but another is directly or indirectly increased downstream). We explore case studies that quantify: (1) downstream reductions in concentrations of multiple pollutants along a stream flowing to a major drinking water source due to engineered and nature-based solutions, (2) downstream reductions in multiple pollutants and water quality tradeoffs along streams experiencing stormwater BMPs and stream restoration, (3) comparisons in downstream reductions of multiple pollutants and nutrient uptake along streams draining into major drinking water sources based on types of stream restoration, (4) comparisons of downstream pollutant reductions along streams experiencing riparian forest conservation vs. stream restoration, and (5) mapping and visualizing hot spots of increasing water quality problems such as hypoxia, contaminant mobilization, and freshwater salinization that extend downstream to tidal rivers of the Chesapeake Bay. We explore future applications of WCMA for tracking decreasing trends in salinity, E. coli , and other pollutants of emerging concern. WCMA can holistically inform progress towards achieving multiple water quality goals and also be used as a screening tool for selecting monitoring sites and targeting management in strategic locations. Overall, WCMA enables the simultaneous quantification and comparison of sources and transport and attenuation rates for different chemicals and pollutants across a broader range of watershed sizes and flowpath lengths, which is critical for understanding ecological, hydrological, geochemical, and biogeochemical processes along human-impacted streams and rivers.

Ecological Engineering

Identifying and filling critical knowledge gaps can optimize financial viability of blue carbon projects in tidal wetlands

One of the world’s largest “blue carbon” ecosystems, Louisiana’s tidal wetlands on the US Gulf of Mexico coast, is rapidly being lost. Louisiana’s strong legal, regulatory, and monitoring framework, developed for one of the world’s largest tidal wetland systems, provides an opportunity for a programmatic approach to blue carbon accreditation to support restoration of these ecologically and economically important tidal wetlands. Louisiana’s coastal wetlands span ∼1.4 million ha and accumulate 5.5–7.3 Tg yr −1 of blue carbon (organic carbon), ∼6%–8% of tidal marsh blue carbon accumulation globally. Louisiana has a favorable governance framework to advance blue carbon accreditation, due to centralized restoration planning, long term coastal monitoring, and strong legal and regulatory frameworks around carbon. Additional restoration efforts, planned through Louisiana’s Coastal Master Plan, over 50 years are projected to create, or avoid loss of, up to 81,000 ha of wetland. Current restoration funding, primarily from Deepwater Horizon oil spill settlements, will be fully committed by the early 2030s and additional funding sources are required. Existing accreditation methodologies have not been successfully applied to coastal Louisiana’s ecosystem restoration approaches or herbaceous tidal wetland types. Achieving financial viability for accreditation of these restoration and wetland types will require expanded application of existing blue carbon crediting methodologies. It will also require expanded approaches for predicting the future landscape without restoration, such as numerical modeling, to be validated. Additional methodologies (and/or standards) would have many common elements with those currently available but may be beneficial, depending on the goals and needs of both the state of Louisiana and potential purchasers of Louisiana tidal wetland carbon credits. This study identified twenty targeted needs that will address data and knowledge gaps to maximize financial viability of blue carbon accreditation for Louisiana’s tidal wetlands. Knowledge needs were identified in five categories: legislative and policy, accreditation methodologies and standards, soil carbon flux, methane flux, and lateral carbon flux. Due to the large spatial scale and diversity of tidal wetlands, it is expected that progress in coastal Louisiana has high potential to be generalized to similar wetland ecosystems across the northern Gulf of Mexico and globally.

Louisiana

Wind, sun, and wildlife: Do wind and solar energy development “short-circuit” conservation in the western United States?

Despite the trade-offs between renewable energy development, land use, humans, and wildlife, wind and solar development continues to transform the southwestern US into a green energy landscape. While renewable energy reduces carbon emissions and reliance on fossil fuels, many studies have emerged on the associated ecological and social impacts of this technology. Here, we review the current state of knowledge on the nexus between wildlife conservation and energy development in the western US since 2010. We revisit pertinent ecological concepts and questions presented in earlier reviews to assess how far the field has progressed in mitigating negative effects. Specifically, we ask, what density or design of development maximizes energy benefits while minimizing negative effects on wildlife, whether the results of previously-deficient before-after control-impact studies are now more readily-available, and ultimately, can the impacts of renewable energy development on wildlife be mitigated? We also provide a case study on the federally-protected Desert Tortoise, a conservation-reliant species in the Desert Southwest US, to highlight efforts to mitigate the negative effects of renewable energy development. Our review concludes that successful mitigation is possible via use of spatial decision support tools, applying novel wildlife deterrence and detection systems developed for existing installed facilities, and incorporating impact studies that provide managers with conservation metrics for evaluating different future development land-use scenarios.

Environmental Research Letters

Integrated rangeland fire management strategy actionable science plan completion assessment: Restoration topic, 2015–20

Loss and degradation of sagebrush rangelands due to an accelerated invasive annual grass-wildfire cycle and other stressors are substantial management, conservation, and economic issues in the western United States. These sagebrush rangelands comprise a unique biome spanning 11 states, support over 350 wildlife species, and provide important ecosystem services that include stabilizing the economies of western communities. Impacts to sagebrush ecosystem processes over large areas due to the annual grass-wildfire cycle necessitated the development of a coordinated, science-based strategy for improving efforts to achieve long-term protection, conservation, and restoration of sagebrush rangelands, which was framed in 2015 under the Integrated Rangeland Fire Management Strategy (IRFMS). Central to this effort was the development of an Actionable Science Plan (Plan) that identified 37 priority science needs (Needs) for informing the actions proposed under the 5 topics (Fire, Invasives, Restoration, Sagebrush and Sage-Grouse, Climate and Weather) that were part of the collective focus of the IRFMS. Notable keys to this effort were identification of the Needs co-produced by managers and researchers, and a focus on resulting science being “actionable.” Substantial investments aimed at fulfilling the Needs identified in the Plan have been made since its release in 2016. While the state of the science has advanced considerably, the extent to which knowledge gaps remain relative to identified Needs is relatively unknown. Moreover, new Needs have likely emerged since the original strategy as results from actionable science reveal new questions, and possible (yet untested) solutions. A quantifiable assessment of the progress made on the original science Needs can identify unresolved gaps and new information that can help inform prioritization of future research efforts. This report details a systematic literature review that evaluated how well peer-reviewed journal articles and formal technical reports published between January 1, 2015, and December 31, 2020, addressed 10 needs (hereinafter “Needs”) identified under the Restoration topic in the Plan. The topic outlined research Needs for improving restoration success in degraded sagebrush rangelands. We established the level of progress towards addressing each Need following a standardized set of criteria, and developed summaries detailing how research objectives nested within Needs identified in the Plan (“Next Steps”) were either addressed well, partially addressed or remain outstanding (that is, addressed poorly) in the literature through 2020. Our searches resulted in the inclusion of 371 science products that at least partially addressed a Need identified in the Restoration topic. The Needs that were well and partially addressed included: the development of methods to improve seeding success of native plants after fire; evaluation of short- and long-term plant responses relative to biotic and abiotic factors following restoration treatments; assessments of long-term effects on ecosystem processes following conifer removal treatments and development of decision support tools to aid in conifer management; determination of the costs of restoration treatments relative to the benefits to sage-grouse occupancy, survival, and populations; and assessments of the factors which contribute to soil degradation and development of soil enhancement methods that enhance seed germination and seedling survival while resisting nonnative plants. Needs that were not addressed well included: the development of methods for the rapid recovery of sagebrush and native herbaceous plants following wildfire and determination of whether treatments benefit sage-grouse and mitigate impacts from fires; determination of thresholds for successful restoration across a range of environmental conditions and development of decision support tools to assist with restoration effectiveness monitoring; and development and evaluation of the utility of seed transfer zones. The information provided in this assessment will assist updating the Plan along with other science strategies.

western United States

Hydrogeology of sand and gravel aquifers in the Owasco Inlet watershed, Cayuga and Tompkins Counties, New York

This study is a continuation of a series of hydrogeologic appraisals that have been conducted since 1980, as part of a cooperative, long-term, detailed aquifer mapping program by the U.S. Geological Survey and the New York State Department of Environmental Conservation. These appraisals provide a foundation for wellhead protection programs, water-resource management and planning decisions, and groundwater remediation in upstate New York. The Owasco Inlet watershed drains north directly to Owasco Lake, one of New York’s Finger Lakes. The watershed is similar in form to other watersheds of the Finger Lakes region of New York State and is characterized by broad, smooth uplands punctuated by the 18-mile-long Owasco Inlet valley and the secondary valleys of Decker, Dresserville, and Hemlock Creeks. All these streams occupy “through valleys”—the valleys are continuous into adjacent watersheds such that watershed divides are high points within the valley bottoms, rather than in uplands. Most glacial deposits in the watershed were deposited during the Valley Heads Readvance and subsequent retreat (with at least one minor readvance). Estimates are that the Valley Heads Readvance likely peaked in the Cayuga basin about 17,000 (calendar) years ago based on dates from western New York and the Mohawk Valley in east-central New York. It was the last major ice advance of the Pleistocene Epoch in this region. This readvance covered the entire Owasco watershed. Valley Heads ice in the Owasco watershed was part of the Cayuga ice lobe, which flowed parallel to the Owasco Inlet valley as far south as Moravia, but which became progressively more eastward south of Locke, effectively raking across the valley from the west. The Owasco Inlet watershed drains north, like other Finger Lakes watersheds, and during deglaciation, northward meltwater drainage was largely blocked by the ice, which resulted in development of a series of regional proglacial lakes in which fine lacustrine sediments predominated. Lacustrine sediments constitute much of the Owasco Inlet valley fill, but it has been pointed out that there are no obvious outlet channels exiting the Owasco Inlet watershed, and it has been proposed that there was northward drainage of meltwater into the ice within the larger, neighboring Cayuga Trough. The lacustrine deposits in the Owasco Inlet valley are commonly underlain by thinner coarse-grained stratified deposits (subaqueous fans and eskers) of variable sorting and permeability. An exception occurs at Groton, N.Y., where retreating ice paused long enough for coarse-grained sediments to fill much of the valley. Smaller, higher elevation valleys have a wider variety of glacial valley-fill deposits, ranging from fine lacustrine sediments to sand and gravel to till. Groundwater is the sole source of water supply in the area; glacial sand and gravel aquifers are the primary water source in the Owasco Inlet and Decker Creek valleys, and fractured bedrock aquifers typically supply domestic wells in the remaining valleys and upland areas. Municipal supplies tap a variety of aquifer types in the Owasco Inlet valley and nearby uplands. The hamlet of Locke taps the extensive confined aquifer beneath fine-grained lacustrine deposits in the valley. The Village of Moravia taps a semiconfined aquifer that overlies proglacial lake deposits and is partly confined by overlying recent lake deposits and alluvium. Withdrawals from this aquifer may also induce water from the Owasco Inlet into the aquifer. The Village of Groton draws from two aquifers: (1) a thin upland unconfined sand and gravel aquifer tapped by an infiltration gallery and (2) the local unconfined or semiconfined aquifer in the Owasco Inlet valley. Another aquifer with potential for municipal supply is the unconfined aquifer in the Decker Creek valley near Wilson Corners. The confined aquifer in the lower Dresserville Creek valley may have some water-resource potential, but it is largely untested. Unconfined aquifers are the most susceptible to contamination from activities at land surface directly above the aquifer because precipitation and subsequent recharge can transport contaminants directly to the water table. Adjacent upland areas can also contribute contaminants. Confined aquifers are less susceptible to contamination from overlying land surface areas because confining units largely prevent downward movement of water. Recharge occurs elsewhere at unconfined upvalley locations and along valley walls where alluvial fans, ice-contact deposits, or stream incision into the valley wall may provide pathways for downward movement of groundwater.

New York

Emerging coral diseases in Kāne'ohe Bay, O'ahu, Hawai'i (USA): two major disease outbreaks of acute Montipora white syndrome

In March 2010 and January 2012, we documented 2 widespread and severe coral disease outbreaks on reefs throughout Kāne‘ohe Bay, Hawai‘i (USA). The disease, acute Montipora white syndrome (aMWS), manifested as acute and progressive tissue loss on the common reef coral M. capitata . Rapid visual surveys in 2010 revealed 338 aMWS-affected M. capitata colonies with a disease abundance of (mean ± SE) 0.02 ± 0.01 affected colonies per m of reef surveyed. In 2012, disease abundance was significantly higher (1232 aMWS-affected colonies) with 0.06 ± 0.02 affected colonies m -1 . Prior surveys found few acute tissue loss lesions in M. capitata in Kāne‘ohe Bay; thus, the high number of infected colonies found during these outbreaks would classify this as an emerging disease. Disease abundance was highest in the semi-enclosed region of south Kāne‘ohe Bay, which has a history of nutrient and sediment impacts from terrestrial runoff and stream discharge. In 2010, tagged colonies showed an average tissue loss of 24% after 1 mo, and 92% of the colonies continued to lose tissue in the subsequent month but at a slower rate (chronic tissue loss). The host-specific nature of this disease (affecting only M. capitata ) and the apparent spread of lesions between M. capitata colonies in the field suggest a potential transmissible agent. The synchronous appearance of affected colonies on multiple reefs across Kāne‘ohe Bay suggests a common underlying factor. Both outbreaks occurred during the colder, rainy winter months, and thus it is likely that some parameter(s) associated with winter environmental conditions are linked to the emergence of disease outbreaks on these reefs.

Diseases of Aquatic Organisms

An integrated monitoring approach using multiple reference sites to assess sustainable restoration in coastal Louisiana

Achieving sustainable resource management in coastal Louisiana requires establishing reference conditions that incorporate the goals and objectives of restoration efforts. Since the reference condition is usually considered sustainable, it can be a gauge to assess the present condition of a (degraded) system or to evaluate progress of management actions toward some target system state (the reference or desired conditions). In 2003, the Coastal Wetlands Planning, Protection, and Restoration Act (CWPPRA) Task Force and the Louisiana State Wetlands Authority adopted the “Coastwide Reference Monitoring System -- Wetlands” (CRMS--Wetlands) for Louisiana. This system will provide data from multiple reference sites to explore the properties of a sustained reference condition. CRMS--Wetlands provides links between project-specific and system-wide objectives, criteria for selecting reference sites or conditions, a more robust statistical design, and critical monitoring variables. In addition, a system-wide assessment and monitoring plan (SWAMP) is being developed that incorporates and evaluates existing monitoring efforts (to the extent possible) within a system-wide experimental design. The SWAMP will integrate monitoring of biological, chemical, physical, and climatological variables in four modules: wetlands (CRMS--Wetlands), barrier islands, inshore waters and rivers, and nearshore coastal waters. Data and information collected under SWAMP will contribute to developing a systems-synthesis model for coastal Louisiana. Regional restoration project leaders in coastal Louisiana acknowledge the mutual dependence of monitoring and modeling the coastal landscape. For example, experiments or measurements should not be conducted independently of modeling and vice versa. Assessment should be directed at reducing scientific uncertainty to improve confidence in modeling and monitoring tools and ultimately to assist management actions. An adaptive environmental assessment and management process prescribes modeling, monitoring, and research activities to be conducted from initial stages of restoration planning to optimize the ability to assess and achieve sustainable restoration.

Louisiana

Unexpected diversity of Endozoicomonas in deep-sea corals

ABSTRACT: The deep ocean hosts a large diversity of azooxanthellate cold-water corals whose associated microbiomes remain to be described. While the bacterial genus Endozoicomonas has been widely identified as a dominant associate of tropical and temperate corals, it has rarely been detected in deep-sea corals. Determining microbial baselines for these cold-water corals is a critical first step to understanding the ecosystem services their microbiomes contribute, while providing a benchmark against which to measure responses to environmental change or anthropogenic effects. Samples of Acanthogorgia aspera , A. spissa , Desmophyllum dianthus , and D. pertusum ( Lophelia pertusa ) were collected from western Atlantic sites off the US east coast and from the northeastern Gulf of Mexico. Microbiomes were characterized by 16S rRNA gene amplicon surveys. Although D. dianthus and D. pertusum have recently been combined into a single genus due to their genetic similarity, their microbiomes were significantly different. The Acanthogorgia spp. were collected from submarine canyons in different regions, but their microbiomes were extremely similar and dominated by Endozoicomonas . This is the first report of coral microbiomes dominated by Endozoicomonas occurring below 1000 m, at temperatures near 4°C. D. pertusum from 2 Atlantic sites were also dominated by distinct Endozoicomonas , unlike D. pertusum from other sites described in previous studies, including the Gulf of Mexico, the Mediterranean Sea and a Norwegian fjord.

Marine Ecology Progress Series

Nitrate in the Mississippi River and its tributaries, 1980 to 2008: Are we making progress?

Changes in nitrate concentration and flux between 1980 and 2008 at eight sites in the Mississippi River basin were determined using a new statistical method that accommodates evolving nitrate behavior over time and produces flow-normalized estimates of nitrate concentration and flux that are independent of random variations in streamflow. The results show that little consistent progress has been made in reducing riverine nitrate since 1980, and that flow-normalized concentration and flux are increasing in some areas. Flow-normalized nitrate concentration and flux increased between 9 and 76% at four sites on the Mississippi River and a tributary site on the Missouri River, but changed very little at tributary sites on the Ohio, Iowa, and Illinois Rivers. Increases in flow-normalized concentration and flux at the Mississippi River at Clinton and Missouri River at Hermann were more than three times larger than at any other site. The increases at these two sites contributed much of the 9% increase in flow-normalized nitrate flux leaving the Mississippi River basin. At most sites, concentrations increased more at low and moderate streamflows than at high streamflows, suggesting that increasing groundwater concentrations are having an effect on river concentrations.

Illinois, Iowa, Louisiana, Missouri

Hydrogeology and water quality of the Floridan aquifer system and effects of Lower Floridan aquifer pumping on the Upper Floridan aquifer at Fort Stewart, Georgia

Test drilling, field investigations, and digital modeling were completed at Fort Stewart, GA, during 2009?2010, to assess the geologic, hydraulic, and water-quality characteristics of the Floridan aquifer system and evaluate the effect of Lower Floridan aquifer (LFA) pumping on the Upper Floridan aquifer (UFA). This work was performed pursuant to the Georgia Environmental Protection Division interim permitting strategy for new wells completed in the LFA that requires simulation to (1) quantify pumping-induced aquifer leakage from the UFA to LFA, and (2) identify the equivalent rate of UFA pumping that would produce the same maximum drawdown in the UFA that anticipated pumping from LFA well would induce. Field investigation activities included (1) constructing a 1,300-foot (ft) test boring and well completed in the LFA (well 33P028), (2) constructing an observation well in the UFA (well 33P029), (3) collecting drill cuttings and borehole geophysical logs, (4) collecting core samples for analysis of vertical hydraulic conductivity and porosity, (5) conducting flowmeter and packer tests in the open borehole within the UFA and LFA, (6) collecting depth-integrated water samples to assess basic ionic chemistry of various water-bearing zones, and (7) conducting aquifer tests in new LFA and UFA wells to determine hydraulic properties and assess interaquifer leakage. Using data collected at the site and in nearby areas, model simulation was used to assess the effects of LFA pumping on the UFA. Borehole-geophysical and flowmeter data indicate the LFA at Fort Stewart consists of limestone and dolomitic limestone between depths of 912 and 1,250 ft. Flowmeter data indicate the presence of three permeable zones at depth intervals of 912-947, 1,090-1,139, and 1,211?1,250 ft. LFA well 33P028 received 50 percent of the pumped volume from the uppermost permeable zone, and about 18 and 32 percent of the pumped volume from the middle and lowest permeable zones, respectively. Chemical constituent concentrations increased with depth, and water from all permeable zones contained sulfate at concentrations that exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level of 250 milligrams per liter. A 72-hour aquifer test pumped LFA well 33P028 at 740 gallons per minute (gal/min), producing about 39 ft of drawdown in the pumped well and about 0.4 foot in nearby UFA well 33P029. Simulation using the U.S. Geological Survey finite-difference code MODFLOW was used to determine long-term, steady-state flow in the Floridan aquifer system, assuming the LFA well was pumped continuously at a rate of 740 gal/min. Simulated steady-state drawdown in the LFA was identical to that observed in pumped LFA well 33P028 at the end of the 72-hour test, with values larger than 1 ft extending 4.4 square miles symmetrically around the pumped well. Simulated steady-state drawdown in the UFA resulting from pumping in LFA well 33P028 exceeded 1 ft within a 1.4-square-mile circular area, and maximum drawdown in the UFA was 1.1 ft. Leakage from the UFA through the Lower Floridan confining unit contributed about 98 percent of the water to the well; lateral flow from specified-head model boundaries contributed about 2 percent. About 80 percent of the water supplied to LFA well 33P028 originated from within 1 mile of the well, and 49 percent was derived from within 0.5 mile of the well. Vertical hydraulic gradients and vertical leakage are progressively higher near the LFA pumped well which results in a correspondingly higher contribution of water from the UFA to the pumped well at distances closer to the pumped well. Simulated pumping-induced interaquifer leakage from the UFA to the LFA totaled 725 gal/min (1.04 million gallons per day), whereas simulated pumping at 205 gal/min (0.3 million gallons per day) from UFA well 33P029 produced the equivalent maximum drawdown as pumping LFA well 33P028 at 740 gal/min during the aquifer test. This equivalent pumpin

Georgia

Late Holocene environmental change in Celestun Lagoon, Yucatan, Mexico

Epikarst estuary response to hydroclimate change remains poorly understood, despite the well-studied link between climate and karst groundwater aquifers. The influence of sea-level rise and coastal geomorphic change on these estuaries obscures climate signals, thus requiring careful development of paleoenvironmental histories to interpret the paleoclimate archives. We used foraminifera assemblages, carbon stable isotope ratios (δ 13 C) and carbon:nitrogen (C:N) mass ratios of organic matter in sediment cores to infer environmental changes over the past 5300 years in Celestun Lagoon, Yucatan, Mexico. Specimens (> 125 µm) from modern core top sediments revealed three assemblages: (1) a brackish mangrove assemblage of agglutinated Miliammina and Ammotium taxa and hyaline Haynesina (2) an inner-shelf marine assemblage of Bolivina , Hanzawaia , and Rosalina, and (3) a brackish assemblage dominated by Ammonia and Elphidium . Assemblages changed along the lagoon channel in response to changes in salinity and vegetation, i.e. seagrass and mangrove. In addition to these three foraminifera assemblages, lagoon sediments deposited since 5300 cal yr BP are comprised of two more assemblages, defined by Archaias and Laevipeneroplis, which indicate marine Thalassia seagrasses, and Trichohyalus, which indicates restricted inland mangrove ponds. Our data suggest that Celestun Lagoon displayed four phases of development: (1) an inland mangrove pond (5300 BP) (2) a shallow unprotected coastline with marine seagrass and barrier island initiation (4900 BP) (3) a protected brackish lagoon (3000 BP), and (4) a protected lagoon surrounded by mangroves (1700 BP). Stratigraphic (temporal) changes in core assemblages resemble spatial differences in communities across the modern lagoon, from the southern marine sector to the northern brackish region. Similar temporal patterns have been reported from other Yucatan Peninsula lagoons and from cenotes (Nichupte, Aktun Ha), suggesting a regional coastal response to sea level rise and climate change, including geomorphic controls (longshore drift) on lagoon salinity, as observed today. Holocene barrier island development progressively protected the northwest Yucatan Peninsula coastline, reducing mixing between seawater and rain-fed submarine groundwater discharge. Superimposed on this geomorphic signal, assemblage changes that are observed reflect the most severe regional wet and dry climate episodes, which coincide with paleoclimate records from lowland lake archives (Chichancanab, Salpeten). Our results emphasize the need to consider coastal geomorphic evolution when using epikarst estuary and lagoon sediment archives for paleoclimate reconstruction and provide evidence of hydroclimate changes on the Yucatan Peninsula.

Yucatan, Celestun Lagoon

De facto water reuse: Bioassay suite approach delivers depth and breadth in endocrine active compound detection

Although endocrine disrupting compounds (EDCs) have been detected in wastewater and surface waters worldwide using a variety of in vitro effects-based screening tools, e.g. bioassays, few have examined potential attenuation of environmental contaminants by both natural (sorption, degradation, etc) and anthropogenic (water treatment practices) processes. This study used several bioassays and quantitative chemical analyses to assess residence-time weighted samples at six sites along a river in the northeastern United States beginning upstream of a waste water treatment plant (WWTP) outfall and proceeding downstream along the stream reach to a drinking water treatment plant (DWTP). Known steroidal estrogens were quantified and changes in signaling pathway molecular initiating events (activation of estrogen, androgen, glucocorticoid, peroxisome proliferator-activated, pregnane X receptor, and aryl hydrocarbon receptor signaling networks) were identified in water extracts. In initial multi-endpoint assays geographic and receptor-specific endocrine activity patterns in transcription factor signatures and nuclear receptor activation were discovered. In subsequent single endpoint receptor-specific bioassays, estrogen (16 of 18 samples; 0.01 to 28 ng estradiol equivalents [E2Eqs]/L) glucocorticoid (3 of 18 samples; 1.8 to 21 ng dexamethasone equivalents [DexEqs]/L), and androgen (2 of 18 samples; 0.95 to 2.1 ng dihydrotestosterone equivalents [DHTEqs]/L) receptor transcriptional activation occurred above respective assay method detection limits (0.04 ng E2Eqs/L, 1.2 ng DexEqs/L, and 0.77 ng DHTEqs/L) in multiple sampling events. Estrogen activity, the most often detected, correlated well with measured concentrations of known steroidal estrogens (R2 = 0.890). Overall, activity indicative of multiple types of endocrine active compounds was highest in wastewater effluent samples, while activity downstream was progressively lower, and negligible in (unfinished) treated water. This multiple bioassay approach, in conjunction with targeted analytical chemistry methods, has gained acceptance among water quality screening programs. Not only was estrogenic and glucocorticoid activity confirmed in the effluent by utilizing multiple methods concurrently, but other activated signaling networks that historically received less attention (i.e. peroxisome proliferator-activated receptor) were also detected.

Science of the Total Environment

Leveraging machine learning to automate regression model evaluations for large multi-site water-quality trend studies

Large multi-site trend studies provide an opportunity to evaluate progress of waterbodies towards water-quality goals across broad geographic areas. Such studies often aggregate the results of site-specific models and thus contend with evaluating each model for appropriate fit and statistical assumptions. We explored the use of four traditional machine learning models (logistic regression, linear and quadratic discriminant analysis, and k-nearest neighbors) to perform these checks and estimate probabilities that an analyst would publish or reject a site-specific trend model from a multi-site study. We trained these “model-checking models” (MCMs) using a national study of over 6000 trend models and tested the MCMs using a smaller set of novel trend models. Although the MCMs did not perform well enough to bypass analyst review entirely, we found incorporating an MCM into a larger evaluation workflow can reduce the number of trend models needing an analyst review by more than half.

Environmental Modeling and Software

Hydrogeology, water chemistry, and transport processes in the zone of contribution of a public-supply well in Albuquerque, New Mexico, 2007-9

The National Water-Quality Assessment Program (NAWQA) of the U.S. Geological Survey began a series of groundwater studies in 2001 in representative aquifers across the Nation in order to increase understanding of the factors that affect transport of anthropogenic and natural contaminants (TANC) to public-supply wells. One of 10 regional-scale TANC studies was conducted in the Middle Rio Grande Basin (MRGB) in New Mexico, where a more detailed local-scale study subsequently investigated the hydrogeology, water chemistry, and factors affecting the transport of contaminants in the zone of contribution of one 363-meter (m) deep public-supply well in Albuquerque. During 2007 through 2009, samples were collected for the local-scale study from 22 monitoring wells and 3 public-supply (supply) wells for analysis of major and trace elements, arsenic speciation, nutrients, dissolved organic carbon, volatile organic compounds (VOCs), dissolved gases, stable isotopes, and tracers of young and old water. To study groundwater chemistry and ages at various depths within the aquifer, the monitoring wells were divided into three categories: (1) each shallow well was screened across the water table or had a screen midpoint within 18.3 m of the water level in the well; (2) each intermediate well had a screen midpoint between about 27.1 and 79.6 m below the water level in the well; and (3) each deep well had a screen midpoint about 185 m or more below the water level in the well. The 24-square-kilometer study area surrounding the "studied supply well" (SSW), one of the three supply wells, consists of primarily urban land within the MRGB, a deep alluvial basin with an aquifer composed of unconsolidated to moderately consolidated deposits of sand, gravel, silt, and clay. Conditions generally are unconfined, but are semiconfined at depth. Groundwater withdrawals for public supply have substantially changed the primary direction of flow from northeast to southwest under predevelopment conditions, to west to east under modern conditions. Analysis of age tracers indicates that groundwater from most sampled wells is dominated by old (pre-1950) water, ranging in mean age from about 4,000 years to more than 22,000 years, but includes a fraction of young (post-1950) recharge. Patterns in chemical and isotopic data are consistent with the conclusions that shallow groundwater in the area typically includes a fraction that evaporated prior to recharge and (or) flushed accumulated solutes out of the unsaturated zone during recharge, and that shallow groundwater has mixed to deeper parts of the aquifer, which receives recharge mainly by seepage from the Rio Grande. Among shallow and intermediate wells that produced water with a fraction of young recharge, that fraction ranged between 1.5 and 46 percent. Samples from the two deep wells had groundwater ages exceeding 18,000 years, with no fraction of young recharge. Two supply wells (including the SSW) had a fraction of young recharge, which ranged between about 3 and 11 percent, despite mean groundwater ages exceeding 10,000 years. The fraction of young recharge to the SSW varied seasonally, probably because seasonal pumping patterns affected local hydraulic gradients and (or) because of flow through the well bore when the SSW is not pumping. Well-bore flow data collected during winter (low-pumping season) indicated that about 61 percent of the water pumped from the SSW entered the well from the intermediate part of the aquifer, and that the remaining 39 percent entered from the deep part of the aquifer. Volatile organic compounds (VOCs) were detected in samples from most shallow and intermediate monitoring wells and from two of three supply wells, including the SSW. Detected VOCs were primarily chlorinated solvents or their degradation products. Many of the wells in which most of these VOCs were detected are located near known sites of solvent contamination that were targeted for sampling because trichloroethylene (TCE) and cis-1,2-dichloroethylene had been detected in the SSW, and several of these wells may have become contaminated at least partly because of enhanced vertical migration associated with the pumping of and (or) direct migration down deep well bores. Except for TCE in the sample from a shallow monitoring well, all detections of VOCs were at concentrations below Maximum Contaminant Levels (MCLs) set by the U.S. Environmental Protection Agency. Concentrations of all VOCs detected in the supply wells were less than one-tenth of the corresponding MCLs. However, the presence of VOCs in all but deep groundwater, including the detection of chloroform (a chlorination byproduct) in several shallow wells, indicates that groundwater in the study area commonly is affected by human activities, even to substantial depths. The only natural contaminant detected at concentrations near or above its MCL was arsenic, which has been detected at elevated concentrations across broad areas of the MRGB. Concentrations of arsenic, present primarily as arsenate, exceeded the MCL of 10 micrograms per liter (μg/L) in water from the two deep wells (one of which had the highest concentration, 35 μg/L), from one intermediate well, and from two supply wells, including the SSW. Water-quality and solid-phase data from this study are consistent with elevated arsenic concentrations in groundwater being related to pH-dependent desorption of arsenic from ferric oxyhydroxides in sediments in deep parts of the aquifer. Concentrations of nitrate ranged between 1.3 and 5.4 milligrams per liter (mg/L) in water from shallow wells screened across the water table, but were less than 0.9 mg/L in water from all but one deeper well. Nitrogen isotopes and chloride/bromide ratios for shallow wells were consistent with natural soil nitrogen. Nitrate concentrations and nitrogen isotopes indicated that denitrification is occurring at intermediate aquifer depths, and that the progress of the denitrification reaction typically is greatest for wells that include a fraction of groundwater associated with particular recharge sources or with known sites of contamination contributing organic compounds that can provide a carbon source for microbial respiration. Overall, hydrologic and chemical data from the study area indicate that young recharge is reaching the aquifer across broad areas and is migrating from shallow to intermediate depths of the aquifer as a result of mixing that is associated with human development of groundwater. Consequently, groundwater that human activities in the urban study area have affected is present at depths that are within the screened intervals of public-supply wells, resulting in detections of VOCs and implying greater vulnerability to anthropogenic contamination than might be assumed based on the dominantly old age of the regional groundwater. However, the fractions of old groundwater that public-supply wells produce substantially dilute the anthropogenic contaminants, while contributing natural contaminants (primarily arsenic) to the wells. Based on data from the SSW, vulnerability of public-supply wells to natural and anthropogenic contaminants in the area changes through time, including with seasonal changes in pumping stresses that alter the fractions of young and old water being contributed to wells.

New Mexico

Exploring environmental factors that drive diel variations in tree water storage using wavelet analysis

Internal water storage within trees can be a critical reservoir that helps trees overcome both short- and long-duration environmental stresses. We monitored changes in internal tree water storage in a ponderosa pine on daily and seasonal scales using moisture probes, a dendrometer, and time-lapse electrical resistivity imaging (ERI). These data were used to investigate how patterns of in-tree water storage are affected by changes in sapflow rates, soil moisture, and meteorologic factors such as vapor pressure deficit. Measurements of xylem fluid electrical conductivity were constant in the early growing season while inverted sapwood electrical conductivity steadily increased, suggesting that increases in sapwood electrical conductivity did not result from an increase in xylem fluid electrical conductivity. Seasonal increases in stem electrical conductivity corresponded with seasonal increases in trunk diameter, suggesting that increased electrical conductivity may result from new growth. On the daily scale, changes in inverted sapwood electrical conductivity correspond to changes in sapwood moisture. Wavelet analyses indicated that lag times between inverted electrical conductivity and sapflow increased after storm events, suggesting that as soils wetted, reliance on internal water storage decreased, as did the time required to refill daily deficits in internal water storage. We found short time lags between sapflow and inverted electrical conductivity with dry conditions, when ponderosa pine are known to reduce stomatal conductance to avoid xylem cavitation. A decrease in diel amplitudes of inverted sapwood electrical conductivity during dry periods suggest that the ponderosa pine relied on internal water storage to supplement transpiration demands, but as drought conditions progressed, tree water storage contributions to transpiration decreased. Time-lapse ERI- and wavelet-analysis results highlight the important role internal tree water storage plays in supporting transpiration throughout a day and during periods of declining subsurface moisture.

Colorado