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Bedrock geologic map of the Bellows Falls 7.5- x 15-minute quadrangle, Windham and Windsor Counties, Vermont, and Sullivan and Cheshire Counties, New Hampshire

Introduction The bedrock geology of the Bellows Falls 7.5- x 15-minute quadrangle, Vermont and New Hampshire, consists of polydeformed Ordovician to Devonian metasedimentary, metavolcanic, and metaplutonic rocks of the Connecticut Valley trough, Bronson Hill anticlinorium (or Bronson Hill terrane), and the Central Maine terrane. Previous work in this area includes a 1:62,500-scale published map and text (1946), State geologic maps of New Hampshire (1997) and Vermont (2011), and various maps and reports presented largely as parts of field trip guidebooks. A provisional open-file map of the geology of the Vermont part of the Bellows Falls 7.5- x 15-minute quadrangle, completed in 1997, is incorporated and revised on this map based on additional fieldwork. This study recognizes three major structural levels from west to east and from lowest to highest: (1) autochthonous rocks of the Connecticut Valley trough; (2) allochthonous rocks of the New Hampshire sequence and Bronson Hill arc in the Monroe thrust sheet (or nappe), including the Skitchewaug nappe; and (3) allochthonous rocks of the Fall Mountain thrust sheet or nappe.

New Hampshire, Vermont

Geology and geochemistry of Ni-Co laterite occurrences of northern California and southern Oregon

Ni-Co laterite occurrences in the Klamath Mountains of southern Oregon and northern California contain Ni, Co, and Sc values comparable to global deposits. However, they are thin and limited in extent, often occurring as landslides and slumps. Olivine in the parent material contains Ni and Co and enstatite contains Sc. Through pervasive weathering, these elements where concentrated in Fe- and Mn-oxides. Unlike the mined Nickel Mountian deposit near Riddle, Oregon, these occurrences have no hydrous-Mg silicate minerals. Although the region experienced pervasive weathering in the Eocene, preservation of the laterite profiles was limited in the Klamath Mountains due to accelerated uplift and erosion compared to the Coast Range Provence.

Conference Paper

Water-quality assessment of the New England coastal basins in Maine, Massachusetts, New Hampshire, and Rhode Island: Environmental settings and implications for water quality and aquatic biota

The New England Coastal Basins in Maine, Massachusetts, New Hampshire, and Rhode Island constitute one of 59 study units selected for water-quality assessment as part of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) program. England Coastal Basins study unit encompasses the fresh surface waters and ground waters in a 23,000 square-mile area that drains to the Atlantic Ocean. Major basins include those of the Kennebec, Androscoggin, Saco, Merrimack, Charles, Blackstone, Taunton, and Pawcatuck Rivers. Defining the environmental setting of the study unit is the first step in designing and conducting a multi-disciplinary regional water-quality assessment. The report describes the natural and human factors that affect water quality in the basins and includes descriptions of the physiography, climate, geology, soils, surface- and ground-water hydrology, land use, and the aquatic ecosystem. Although surface-water quality has greatly improved over the past 30 years as a result of improved wastewater treatment at municipal and industrial wastewater facilities, a number of water-quality problems remain. Industrial and municipal wastewater discharges, combined sewer overflows, hydrologic modifications from dams and water diversions, and runoff from urban land use are the major causes of water-quality degradation in 1998. The most frequently detected contaminants in ground water in the study area are volatile organic compounds, petroleum-related products, nitrates, and chloride and sodium. Sources of these contaminants include leaking storage tanks, accidental spills, landfills, road salting, and septic systems and lagoons. Elevated concentrations of mercury are found in fish tissue from streams and lakes throughout the study area.

Maine, Massachusetts, New Hampshire, Rhode Island

Relationship of basin structure and bedrock lithology to faulting in the 2019 Ridgecrest earthquake region, California, from gravity and aeromagnetic data

We investigate patterns of cumulative offsets on the faults that ruptured in 2019 and along the Garlock Fault in the Ridgecrest region, California using recently published gravity and aeromagnetic data. We also examine the relationship of basin structure and bedrock structure to the 2019 M7.1 Ridgecrest earthquake ruptures (Fig. 1A), which were primarily along a dextral northwest-striking fault system, and along a sinistral northeast-striking fault, which ruptured hours earlier with a M6.4 event.

California

Active volcanism on the Arabian Shield—Geology, volcanology, and geophysics of northern Harrat Rahat and vicinity, Kingdom of Saudi Arabia

Active volcanic systems pose serious hazards to people and property including inundation and incineration by lava, blanketing by tephra (volcanic ash), exposure to noxious volcanic gases, and damage from shallow earthquakes triggered by ascending molten material (magma). To improve understanding of volcanism and associated seismicity on the western Arabia Plate, the Saudi Geological Survey and the U.S. Geological Survey conducted a multi-year investigation of the northern Harrat Rahat volcanic field adjacent to the city of Al Madīnah al Munawwarah, Kingdom of Saudi Arabia. Project components included creation of a high-resolution digital topographic base; interpretation of eruptive history supported by detailed geologic mapping, paleomagnetism, and abundant high-precision geochronology of volcanic deposits; assessments of eruptive styles and volcanic hazards by physical volcanology; investigation of the origins of magmas in the mantle and of their differentiation in the crust revealed by chemical and isotopic petrology; gravity and magnetotelluric surveys to reveal crustal structures and to search for magma reservoirs; and regional and local seismic tomography and analyses of seismic hazards. Project results are presented in this Professional Paper as chapters written for technical scientific audiences.

Professional Paper

Geologic framework, hydrostratigraphy, and ichnology of the Blanco, Payton, and Rough Hollow 7.5-minute quadrangles, Blanco, Comal, Hays, and Kendall Counties, Texas

During 2023, the U.S. Geological Survey, in cooperation with the Edwards Aquifer Authority, revised an initial characterization completed during 2015–16 of the geologic framework, hydrostratigraphy, and ichnology of the Edwards and Trinity aquifers in the Blanco, Payton, and Rough Hollow 7.5-minute quadrangles in Blanco, Comal, Hays, and Kendall Counties, Texas. The purpose of this report is to present the updated geologic framework, hydrostratigraphy, and ichnology of the Trinity and Edwards Groups in those quadrangles. Rocks exposed in the study area are of the Lower Cretaceous Trinity Group and lower part of the Fort Terrett Formation of the Lower Cretaceous Edwards Group. The faulting and fracturing in the study area are part of the Balcones Fault Zone, an extensional system of faults active during the Paleocene to middle Eocene that generally trends southwest to northeast in south-central Texas. Hydrostratigraphically, the rocks exposed in the study area contain a section of the Edwards (Balcones Fault Zone) aquifer, upper zone of the Trinity aquifer, and middle zone of the Trinity aquifer. In the study area, the only hydrostratigraphic units of the Edwards (Balcones Fault Zone) aquifer remaining are (from top to bottom) VII and VIII, which cap several hills. The mapped hydrostratigraphic units of the upper zone of the Trinity aquifer are (from top to bottom) the cavernous, Camp Bullis, upper evaporite, fossiliferous, and lower evaporite. The mapped hydrostratigraphic units of the middle zone of the Trinity aquifer are (from top to bottom) the Bulverde, Little Blanco, Twin Sisters, Doeppenschmidt, Herff Falls (where present), Rust, Honey Creek, Hensell, and Cow Creek hydrostratigraphic units.

Texas

Sensitivity of benthic biota and toxicity of cadmium, cobalt, copper, nickel, lead, and zinc mixtures in Washington, United States, and British Columbia, Canada

Relative sensitivities and responses of juvenile white sturgeon ( Acipenser transmontanus ), Hyalella azteca , two families of mayfly (Ephemerellidae, Heptageniidae), one family of caddisfly (Brachycentridae), and a natural community of benthic macroinvertebrates (BMI) to multiple metals are predicted using previously collected laboratory and field samples and a metal mixture model. Biological responses in single metal exposures are used to parameterize toxicity functions, which include accumulations of hydrogen and selected metals on biological receptors, intrinsic potencies of hydrogen and metals, sensitivities of organisms, and times of exposure. The model then is used to predict responses in multiple metal laboratory exposures and field-collected porewater. The following sensitivity sequence in porewater was determined based on endpoints of survival or total abundance: juvenile white sturgeon greater than (>) Ephemerellidae family > Hyalella azteca > Heptageniidae family about equal to (~) benthic macroinvertebrate community > Brachycentridae family. The fraction of porewater samples that are predicted to have adverse impacts on benthic biota (20-percent or greater negative response) depends on organism sensitivities and metal toxicities, and ranges from 44 to 48 percent for juvenile white sturgeon, 23 to 26 percent for the Ephemerellidae family, 16 to 22 percent for Hyalella azteca , 5 to 8 percent for the Heptageniidae family and BMI community, and 0 percent for the caddisfly family. The most toxic porewater in the upper Columbia River Basin (UCR) is at the backwater bar site at Deadmans Eddy and China Bend. The model also indicates that the element responsible for the most toxic conditions in UCR porewater is copper for all organisms, except Hyalella azteca and the metal-insensitive Brachycentridae family. Copper and lead result in the most toxic conditions for Hyalella azteca . This approach and results can aid in assessing metal toxicity and its potential risk to aquatic biota in ecosystems impacted by historical mining activities.

British Columbia, Washington

Perchlorate, metals, organic compounds, and lead isotopes in groundwater, surface water, shallow groundwater, and soil within and near the Middleton Municipal Airport–Morey Field (C29), Middleton, Wisconsin, 2022

The Middleton Municipal Airport–Morey Field (C29) is in the City of Middleton and adjacent to the towns of Middleton and Springfield, Wisconsin. Nearby homes in the towns rely on private drinking water wells, and residents are concerned about the potential contamination of groundwater and surface water by airport activities, including flights by small aircraft that use leaded aviation fuel and a fireworks display in July 2021. The U.S. Geological Survey, in cooperation with the Town of Middleton, completed a study in 2022 to characterize the occurrence and sources of perchlorate, metals (including lead), and organic compounds in samples of groundwater, surface water, shallow groundwater, and soils within and near the airport. Lead isotopes were also measured to determine sources of lead by comparing samples to environmental references. Magnitudes of concentrations from samples of water and soil collected in 2022, and their spatial patterns across site locations, indicate the fireworks display in July 2021 was a likely source of perchlorate and metals in the airport study area. The highest perchlorate concentration was measured in surface water at the southeastern corner of the airport near the fireworks launch site; the highest concentrations of fireworks-associated metals were measured in shallow groundwater near the same location. Fireworks were not the only possible source of perchlorate and metals in the airport study area because both were also detected upgradient and away from the fireworks launch site. Ratios of lead isotopes indicate that lead measured in water and soil within the airport study area was primarily sourced from background atmospheric lead deposition or Wisconsin galena lead ore. However, two groundwater samples (one upgradient and one downgradient from the airport; both with concentrations less than 1 microgram per liter) had isotopic signatures matching leaded aviation fuel sold at the airport.

Wisconsin

Geochemical and hydrological investigations of historical data collected at the Lee Acres Landfill and Giant Bloomfield Refinery, New Mexico, 1985–2020

The Lee Acres Landfill and Giant Bloomfield Refinery are adjacent properties near the City of Farmington, New Mexico, each having undergone monitoring and remediation related to historical site activities. At the landfill, site cleanup has included the installation of a capillary barrier over former liquid waste lagoons and periodic monitoring of groundwater elevations and groundwater quality. At the refinery, remediation has focused on several petrochemical and crude oil release areas and included soil excavation, groundwater treatment, and regular monitoring of groundwater elevations and quality. Groundwater at both sites has higher concentrations of volatile organic compounds and trace metals than background aquifer concentrations. In 2022, the U.S. Geological Survey compiled the Lee Acres-Giant Bloomfield Refinery Database (LAGBRD), which contains publicly available groundwater-elevation data and organic and inorganic groundwater-quality data from both sites, spanning from 1985 to 2020. Data from the LAGBRD and precipitation data from other sources were used to better understand the cause of relatively high manganese concentrations observed in some groundwater wells at the site through comparison of groundwater chemistry to chemical end members, interpretation of spatial and temporal patterns in the groundwater chemistry, and interpretation of groundwater flow properties. In this study, elevated chloride concentrations in groundwater downgradient from the landfill have been attributed to landfill leachate based on the temporal and spatial variability of chloride concentrations and chloride-to-bromide ratios. Installation of a capillary barrier and surface-water runoff controls at the landfill in 2005 appears to have altered infiltration patterns at that site, resulting in a decrease in chloride at some wells but an increase in chloride and dissolved manganese at others. The timing and relation among groundwater elevation, chloride concentration, and manganese concentration suggest that leachate stored in the vadose zone provides a continued source of contamination to groundwater.

New Mexico

Capitalization of positional (Lower/Middle/Upper) and temporal (Early/Middle/Late) adjectives in the names of formal chronostratigraphic and geochronologic units of the Phanerozoic

Many authors are understandably confused about the capitalization of the words “lower,” “middle,” “upper,” “early,” and “late.” Where these words are used simply as descriptive adjectives, they should be in lowercase; where they form the first word of a formal chronostratigraphic or geochronologic unit name, they should be in uppercase.

Professional Paper

Assessing potential effects of oil and gas development activities on groundwater quality near and overlying the Elk Hills and North Coles Levee Oil Fields, San Joaquin Valley, California

Groundwater resources are utilized near areas of intensive oil and gas development in California’s San Joaquin Valley. In this study, we examined chemical and isotopic data to assess if thermogenic gas or saline water from oil producing formations have mixed with groundwater near the Elk Hills and North Coles Levee Oil Fields in the southwestern San Joaquin Valley. Major ion concentrations and stable isotope compositions were largely consistent with natural processes, including mixing of different recharge sources and water-rock interactions. Trace methane concentrations likely resulted from microbial rather than thermogenic sources. Trace concentrations of benzene and other dissolved hydrocarbons in three wells had uncertain sources that could occur naturally or be derived from oil and gas development activities or other anthropogenic sources. In the mid-1990s, two industrial supply wells had increasing Cl and B concentrations likely explained by mixing with up to 15 percent saline oil-field water injected for disposal in nearby injection disposal wells. Shallow groundwater along the western margin of Buena Vista Lake Bed had elevated Cl, B, and SO 4 concentrations that could be explained by accumulation of salts during natural wetting and drying cycles or, alternatively, legacy surface disposal of saline oil-field water in upgradient ephemeral drainages. This study showed that groundwater had relatively little evidence of thermogenic gas or saline water from oil and gas sources in most parts of the study area. However, the evidence for groundwater mixing with injected disposal water, and possibly legacy surface disposal water, demonstrates produced water management practices as a potential risk factor for groundwater-quality degradation near oil and gas fields. Additional studies in the San Joaquin Valley and elsewhere could improve understanding of such risks by assessing the locations, volumes, and types of produced water disposal practices used during the life of oil fields.

California

Profiles of gamma-ray and magnetic data for aerial surveys over parts of the Western United States from longitude 108 to 126 degrees W. and from latitude 34 to 49 degrees N.

This CD-ROM contains images generated from geophysical data, software for displaying and analyzing the images and software for displaying and examining profile data from aerial surveys flown as part of the National Uranium Resource Evaluation (NURE) Program of the U.S. Department of Energy. The images included are of gamma-ray data (uranium, thorium, and potassium channels), Bouguer gravity data, isostatic residual gravity data, aeromagnetic anomalies, topography, and topography with bathymetry. This publication contains image data for the conterminous United States and profile data for the conterminous United States within the area longitude 108 to 126 degrees W. and latitude 34 to 49 degrees N. The profile data include apparent surface concentrations of potassium, uranium, and thorium, the residual magnetic field, and the height above the ground. The images on this CD-ROM include graytone and color images of each data set, color shaded-relief images of the potential-field and topographic data, and color composite images of the gamma-ray data. The image display and analysis software can register images with geographic and geologic overlays. The profile display software permits the user to view the profiles as well as obtain data listings and export ASCII versions of data for selected flight lines.

Data Series

High-resolution landscape-scale maps of nutrients, phytoplankton, and related water-quality constituents in Suisun Bay and the Sacramento–San Joaquin Delta, California, during 2018—Results from high-resolution underway surveys

We examined the abundance and distribution of nutrients and phytoplankton in the tidal aquatic environments of the Sacramento–San Joaquin Delta (Delta) and Suisun, Grizzly, and Honker Bays in California by completing three spatial surveys that used continuous underway high frequency (1 hertz) measurements and sampling onboard a high-speed boat. Surveys were conducted in May, July, and October 2018. Water was sampled continuously during surveys to simultaneously collect information about the concentration and spatial distribution of all major nutrient forms together with information about the major classes of phytoplankton and associated standard field measurements of water quality, such as dissolved oxygen, dissolved organic matter, pH, salinity, specific conductance, turbidity, and water temperature. The results show a greater than 50-fold variation in nutrient and phytoplankton concentrations across space and time, providing evidence of the dynamic environmental processes that shape the ways nutrients interact with and affect Delta aquatic habitats.

Data Report

Effects of drought and cloud-water interception on groundwater recharge and wildfire hazard for recent and future climate conditions, Kauaʻi, Oʻahu, Molokaʻi, Maui, and the Island of Hawaiʻi

The Water-budget Accounting for Tropical Regions Model (WATRMod) code was used for Kauaʻi, Oʻahu, Molokaʻi, Maui, and the Island of Hawaiʻi to estimate the spatial distribution of groundwater recharge, soil moisture, evapotranspiration, and climatic water deficit for a set of water-budget scenarios. The scenarios included historical and future drought conditions, and a land-cover condition where shrubland and forest within the cloud zone were converted to grassland. For the historical drought condition, island-wide mean annual recharge estimates range from a decrease of 30 percent (239 million gallons per day [Mgal/d]) for Kauaʻi to a decrease of 39 percent (2,706 Mgal/d) for the Island of Hawaiʻi, relative to the reference condition consisting of 1978–2007 rainfall and 2020 land cover. For the future drought condition, estimates of island-wide mean annual recharge range from a decrease of 40 percent (477 Mgal/d) on Maui to a decrease of 51 percent (116 Mgal/day) on Molokaʻi. Complete conversion of all shrubland and forest within the cloud zone to grassland for each drought condition produces estimated land-cover-related decreases in island-wide mean annual recharge (in addition to the drought-related decreases) of 11–12 Mgal/d on Oʻahu, 119–135 Mgal/day on Maui, and 689–849 Mgal/d on the Island of Hawaiʻi. The spatial distributions of increases in conditions indicative of moisture stress and potential wildfire hazard were quantified using the relative frequency of soil moisture less than a selected threshold value (monthly mean soil moisture less than 0.074, expressed as a fraction of available water capacity), evapotranspiration less than a selected threshold value (monthly evapotranspiration less than 0.96 inches), and climatic water deficit greater than a selected threshold value (monthly climatic water deficit greater than 0.77, expressed as fraction of potential evapotranspiration). For the historical drought condition, the greatest increases in the relative frequency for the moisture-stress indicators occur across parts of east and southwest Kauaʻi; central, east, and west Oʻahu; central Molokaʻi; central Maui and low- to mid-altitude parts of West Maui volcano; and the northwestern and southern parts of the Island of Hawaiʻi. For the future drought condition, the greatest increases in the relative frequency of the moisture-stress indicators occur across parts of west Kauaʻi; central and west Oʻahu and Molokaʻi; a band of mid-altitude area on the southern slope of West Maui volcano and across the southwestern slope of Haleakalā; and mid-altitude areas of the northwestern and southern parts of the Island of Hawaiʻi. Complete conversion of all shrubland and forest within the cloud zone to grassland for each drought condition results in land-cover-related increases in the relative frequency of moisture-stress indicators around Kaʻala in the Waiʻanae Range and the southeastern part of the Koʻolau Range on Oʻahu, the southern part of West Maui volcano and the southwestern slope of Haleakalā on Maui, and the upland regions of the western and southern parts of the Island of Hawaiʻi.

Hawaii

Inference of pattern-based geological CO2 sequestration and oil recovery potential in a commingled main pay and residual oil zone CO2-EOR flood

Several detailed studies have shown that residual oil zones (ROZs) can present significant resources for additional hydrocarbon recovery as well as subsurface carbon dioxide (CO 2 ) sequestration via enhanced oil recovery by injecting CO 2 (CO 2 -EOR). Field development strategies included new wells drilled dedicated to main pay zones (MPZ) and ROZs, or existing wells in MPZs deepened to ROZs for commingled injection-production using different well patterns. The latter presented a challenge when discerning the injection and production from each of the zones, and for subsequent quantification of CO 2 sequestration and EOR potential from different patterns and from the field. In this paper, an innovative method for analyzing commingled injections and productions from MPZs and ROZs, with application to pattern-based data from four staggered line drive patterns in Wasson Field's Denver Unit, Texas, USA, was developed. Decline curve and ratio-trend methods were used as means of history-matching and forecasting. Cumulative production-time and cumulative production-rate data for oil, gas, and water, as well as water-oil ratio (WOR) and gas-oil ratio (GOR), were analyzed along with injection data for time intervals covering major injection events in MPZ, or MPZ and ROZ combined. A combined analysis enabled inference of allocation of fluids into different zones during WAG (water alternating gas) injection and thereby estimation of CO 2 storage, utilization, and retention in different zones as a function of total injection. Results show that ROZs generally present higher CO 2 sequestration potential compared to MPZs, and a comparable incremental oil recovery factor of ∼20%, on average. Results based on ratio analysis further show that while the WOR trend of the pattern production is mostly dominated and controlled by ROZ, GOR is controlled by both intervals. Although the method relying on decline curves and the approach used in zonal fluid allocations are subject to their limitations, this study presents a practical and innovative well-pattern-based method to infer and forecast CO 2 sequestration and oil recovery quantities and fluid ratios from MPZs and ROZs in commingled operations and highlight the added potential offered by ROZs.

Texas

Method for estimating water use and interbasin transfers of freshwater and wastewater in an urbanized basin

Techniques for management of drainage basins that use water budgets to balance available water resources with actual or anticipated water use require accurate and precise estimates of basin withdrawals, interbasin transfers of freshwater, unaccounted-for use, water use, consumptive use, inflow and infiltration, basin return flow, and interbasin transfers of wastewater. Frequently, interbasin transfers of freshwater and wastewater are not included in basin water budgets because they occur within public water-delivery and wastewater-collection systems. A new 10-step method was developed to improve estimates of inflow and infiltration and interbasin transfers using readily available statewide data. The accuracy and precision of water-use estimates determined by this method are improved through careful application of coefficients for small users and the use of metered values for large users. The method was developed and tested with data for the Ten Mile River Basin in southeastern Massachusetts. This report uses examples from the basin to illustrate each step of the method.

Massachusetts

Stable isotope composition and geochemistry of calcite and dolomite in the Mountain Pass carbonatite: A lens into petrogenesis

Carbonatites host most of the global rare earth element (REE) deposits. The petrogenesis of these rocks, including magmatic and post-magmatic processes, are poorly understood but critical in forming and upgrading these deposits. The Mountain Pass carbonatite, which hosts the only active REE mine in North America, is lithologically variable but consistently contains >50% calcite and/or dolomite. Multiple generations of carbonates are evident, suggesting bulk analysis of carbonate minerals would generate a mixed isotopic and geochemical signature. In-situ stable carbon and oxygen isotopes, combined with geochemical analysis and petrography, distinguish carbonate generations, trace the source region of the carbonatite magma, and link carbonate genesis to REE mineralization throughout the intrusion. Primary carbon and oxygen isotope values outside the accepted mantle range may suggest a subduction-related carbon and oxygen source in the mantle. Deformation textures in primary calcite indicate syn- or post-crystallization ductile flow. Carbonates with secondary textures and heavy δ 13 C and δ 18 O values are associated with ore mineralization, suggesting fluid mobilization was important in concentrating REE and upgrading of the Mountain Pass deposit.

California