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At least 325 records · Page 18Linked to original sources

Pesticides in the Hudson River Basin, 1994-96

The occurrence, distribution, and temporal patterns of pesticide concentrations were studied in the Hudson River Basin during 1994 - 96. This article presents the results of three separate pesticide studies conducted as part of the U.S. Geological Survey (USGS) National Water Quality Assessment (NAWQA) program. Pesticides were found in all three studies, but rarely at concentrations exceeding any U.S. Environmental Protection Agency drinking-water standards. The highest concentrations were detected during and immediately after the first runoff following pesticide applications in the late spring and early summer. The herbicides atrazine and metolachlor were the most commonly detected pesticides and were present in nearly every sample collected from streams draining agricultural areas; they also were detected in many streams draining areas with other land uses. Herbicides were most often detected, and had the highest concentrations, in samples from streams draining agricultural areas, whereas insecticides such as diazinon were most commonly detected, and had the highest concentrations, in samples from streams draining urban areas.

Northeastern Geology and Environmental Sciences↗

Direct photolysis rates and transformation pathways of the lampricides TFM and niclosamide in simulated sunlight

The lampricides 3-trifluoromethyl-4-nitrophenol (TFM) and 2′,5-dichloro-4′-nitrosalicylanilide (niclosamide) are directly added to many tributaries of the Great Lakes that harbor the invasive parasitic sea lamprey. Despite their long history of use, the fate of lampricides is not well understood. This study evaluates the rate and pathway of direct photodegradation of both lampricides under simulated sunlight. The estimated half-lives of TFM range from 16.6 ± 0.2 h (pH 9) to 32.9 ± 1.0 h (pH 6), while the half-lives of niclosamide range from 8.88 ± 0.52 days (pH 6) to 382 ± 83 days (pH 9) assuming continuous irradiation over a water depth of 55 cm. Both compounds degrade to form a series of aromatic intermediates, simple organic acids, ring cleavage products, and inorganic ions. Experimental data were used to construct a kinetic model which demonstrates that the aromatic products of TFM undergo rapid photolysis and emphasizes that niclosamide degradation is the rate-limiting step to dehalogenation and mineralization of the lampricide. This study demonstrates that TFM photodegradation is likely to occur on the time scale of lampricide applications (2–5 days), while niclosamide, the less selective lampricide, will undergo minimal direct photodegradation during its passage to the Great Lakes.

Environmental Science & Technology↗

Simulation of water availability in the Southeastern United States for historical and potential future climate and land-cover conditions

A study was conducted by the U.S. Geological Survey (USGS), in cooperation with the Gulf Coastal Plains and Ozarks Landscape Conservation Cooperative (GCPO LCC) and the Department of the Interior Southeast Climate Adaptation Science Center, to evaluate the hydrologic response of a daily time step hydrologic model to historical observations and projections of potential climate and land-cover change for the period 1952–2099. The model simulations were used to compute the potential changes in hydrologic response and streamflow statistics across the Southeastern United States, using historical observations of climate and streamflow. Thirteen downscaled general circulation models with four representative concentration pathways were used to represent a range of potential future changes in climate (a total of 45 future simulations) from the Coupled Model Intercomparison Project Phase 5. The streamflow statistics were selected to describe streamflow conditions that may be most useful in defining the suitability for each river or stream to support sustaining populations of priority aquatic species across the GCPO LCC. An application of the Precipitation-Runoff Modeling System (included as part of the USGS National Hydrologic Model) was used to develop the hydrologic simulations. The results showed increases in air temperature across the study area, with the highest increases occurring in the northern part of the study area during July to September. The results showed a mix of increases and decreases in precipitation accumulation across the study area and across seasons, with decreases in precipitation accumulation across all seasons for the southwestern part of the study area. Actual evapotranspiration decreased for the southeastern part of the study area and increased for the northwestern part of the study area. The results showed general decreases in runoff across the study area, with increases in runoff in areas surrounding large metropolitan regions where potential future increases in impervious area occur. Results from a statistical analysis (Kolmogorov-Smirnov test) showed that the downscaled general circulation models generally have more skill in producing historical streamflow statistics in the duration and magnitude categories and less skill in producing historical streamflow statistics in the frequency, rate of change, and timing categories for this study area. The potential changes in the streamflow statistics and the results of the Kolmogorov-Smirnov test are available through the GCPO LCC Conservation Planning Atlas, an online science-based mapping platform built specifically for land managers and planners.

Alabama, Arkansas, Florida, Georgia, Illinois, Kan↗

The SAFRR Tsunami Scenario

The U.S. Geological Survey and several partners operate a program called Science Application for Risk Reduction (SAFRR) that produces (among other things) emergency planning scenarios for natural disasters. The scenarios show how science can be used to enhance community resiliency. The SAFRR Tsunami Scenario describes potential impacts of a hypothetical, but realistic, tsunami affecting California (as well as the west coast of the United States, Alaska, and Hawaii) for the purpose of informing planning and mitigation decisions by a variety of stakeholders. The scenario begins with an Mw 9.1 earthquake off the Alaska Peninsula. With Pacific basin-wide modeling, we estimate up to 5m waves and 10 m/sec currents would strike California 5 hours later. In marinas and harbors, 13,000 small boats are damaged or sunk (1 in 3) at a cost of $350 million, causing navigation and environmental problems. Damage in the Ports of Los Angeles and Long Beach amount to $110 million, half of it water damage to vehicles and containerized cargo. Flooding of coastal communities affects 1800 city blocks, resulting in $640 million in damage. The tsunami damages 12 bridge abutments and 16 lane-miles of coastal roadway, costing $85 million to repair. Fire and business interruption losses will substantially add to direct losses. Flooding affects 170,000 residents and workers. A wide range of environmental impacts could occur. An extensive public education and outreach program is underway, as well as an evaluation of the overall effort.

Conference Paper↗

Soil nitrogen balance under wastewater management: Field measurements and simulation results

The use of treated wastewater for irrigation of crops could result in high nitrate-nitrogen (NO3-N) concentrations in the vadose zone and ground water. The goal of this 2-yr field-monitoring study in the deep silty clay loam soils south of Dodge City, Kansas, was to assess how and under what circumstances N from the secondary-treated, wastewater-irrigated corn reached the deep (20-45 m) water table of the underlying High Plains aquifer and what could be done to minimize this problem. We collected 15.2-m-deep soil cores for characterization of physical and chemical properties; installed neutron probe access tubes to measure soil-water content and suction lysimeters to sample soil water periodically; sampled monitoring, irrigation, and domestic wells in the area; and obtained climatic, crop, irrigation, and N application rate records for two wastewater-irrigated study sites. These data and additional information were used to run the Root Zone Water Quality Model to identify key parameters and processes that influence N losses in the study area. We demonstrated that NO3-N transport processes result in significant accumulations of N in the vadose zone and that NO3-N in the underlying ground water is increasing with time. Root Zone Water Quality Model simulations for two wastewater-irrigated study sites indicated that reducing levels of corn N fertilization by more than half to 170 kg ha-1 substantially increases N-use efficiency and achieves near-maximum crop yield. Combining such measures with a crop rotation that includes alfalfa should further reduce the accumulation and downward movement of NO3-N in the soil profile. Copyright ?? 2009 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗

Geologic map of Big Bend National Park, Texas

The purpose of this map is to provide the National Park Service and the public with an updated digital geologic map of Big Bend National Park (BBNP). The geologic map report of Maxwell and others (1967) provides a fully comprehensive account of the important volcanic, structural, geomorphological, and paleontological features that define BBNP. However, the map is on a geographically distorted planimetric base and lacks topography, which has caused difficulty in conducting GIS-based data analyses and georeferencing the many geologic features investigated and depicted on the map. In addition, the map is outdated, excluding significant data from numerous studies that have been carried out since its publication more than 40 years ago. This report includes a modern digital geologic map that can be utilized with standard GIS applications to aid BBNP researchers in geologic data analysis, natural resource and ecosystem management, monitoring, assessment, inventory activities, and educational and recreational uses. The digital map incorporates new data, many revisions, and greater detail than the original map. Although some geologic issues remain unresolved for BBNP, the updated map serves as a foundation for addressing those issues. Funding for the Big Bend National Park geologic map was provided by the United States Geological Survey (USGS) National Cooperative Geologic Mapping Program and the National Park Service. The Big Bend mapping project was administered by staff in the USGS Geology and Environmental Change Science Center, Denver, Colo. Members of the USGS Mineral and Environmental Resources Science Center completed investigations in parallel with the geologic mapping project. Results of these investigations addressed some significant current issues in BBNP and the U.S.-Mexico border region, including contaminants and human health, ecosystems, and water resources. Funding for the high-resolution aeromagnetic survey in BBNP, and associated data analyses and interpretation, was from the USGS Crustal Geophysics and Geochemistry Science Center. Mapping contributed from university professors and students was mostly funded by independent sources, including academic institutions, private industry, and other agencies.

Texas↗

Tracking acid mine-drainage in Southeast Arizona using GIS and sediment delivery models

This study investigates the application of models traditionally used to estimate erosion and sediment deposition to assess the potential risk of water quality impairment resulting from metal-bearing materials related to mining and mineralization. An integrated watershed analysis using Geographic Information Systems (GIS) based tools was undertaken to examine erosion and sediment transport characteristics within the watersheds. Estimates of stream deposits of sediment from mine tailings were related to the chemistry of surface water to assess the effectiveness of the methodology to assess the risk of acid mine-drainage being dispersed downstream of abandoned tailings and waste rock piles. A watershed analysis was preformed in the Patagonia Mountains in southeastern Arizona which has seen substantial mining and where recent water quality samples have reported acidic surface waters. This research demonstrates an improvement of the ability to predict streams that are likely to have severely degraded water quality as a result of past mining activities. ?? Springer Science+Business Media B.V. 2007.

Environmental Monitoring and Assessment↗

Remote sensing and GIS technology in the Global Land Ice Measurements from Space (GLIMS) Project

Global Land Ice Measurements from Space (GLIMS) is an international consortium established to acquire satellite images of the world's glaciers, analyze them for glacier extent and changes, and to assess these change data in terms of forcings. The consortium is organized into a system of Regional Centers, each of which is responsible for glaciers in their region of expertise. Specialized needs for mapping glaciers in a distributed analysis environment require considerable work developing software tools: terrain classification emphasizing snow, ice, water, and admixtures of ice with rock debris; change detection and analysis; visualization of images and derived data; interpretation and archival of derived data; and analysis to ensure consistency of results from different Regional Centers. A global glacier database has been designed and implemented at the National Snow and Ice Data Center (Boulder, CO); parameters have been expanded from those of the World Glacier Inventory (WGI), and the database has been structured to be compatible with (and to incorporate) WGI data. The project as a whole was originated, and has been coordinated by, the US Geological Survey (Flagstaff, AZ), which has also led the development of an interactive tool for automated analysis and manual editing of glacier images and derived data (GLIMSView). This article addresses remote sensing and Geographic Information Science techniques developed within the framework of GLIMS in order to fulfill the goals of this distributed project. Sample applications illustrating the developed techniques are also shown. ?? 2006 Elsevier Ltd. All rights reserved.

Computers & Geosciences↗

Using environmental DNA (eDNA) to assess the presence of cavefish and cave crayfish populations in caves of the Ozark Highlands

Many cavefishes and cave crayfishes are considered of conservation concern; however, sampling these species is inherently difficult given their occupied environments. The goal of our project was to verify the presence of select karst organisms while developing the foundation for sampling approaches that might be useful to conservation and management agencies. Our project objectives were to develop assays to amplify deoxyribonucleic acid (DNA) from several species of Ozark cavefishes and cave crayfishes and complete an initial surveillance of locations across the Ozark Highlands using environmental DNA (eDNA). Using DNA either provided by agency cooperators or that we extracted from tissue samples, we PCR amplified and then sequenced the Cytochrome Oxidase 1 (CO1) gene for cave crayfishes and the NADH Dehydrogenase Subunit 2 (ND2) gene for cavefishes. We developed species-specific primers and probes for five cave crayfishes and two cavefishes. From February 2017 to May 2017, we sampled 1–5 sampling units from 42 caves, wells, and springs (i.e., sites) using eDNA and traditional visual surveys. We measured physicochemical parameters at each sampling unit to estimate detection probability associated with both techniques. We also calculated two occupancy covariates for each site using geospatial data. We successfully amplified Troglichthys rosae DNA from the environment and detected DNA representing this species at 24 of 40 sites. At 16 of the sites where we detected T. rosae DNA, we did not visually observe the species. Although our assay for Typlichthys eigenmanni successfully amplified the target DNA from the environment, it also resulted in false absences where the species was visually confirmed. Using eDNA to detect cave crayfishes was much more difficult. The assay for Cambarus subterraneus did not work for eDNA samples and we were unable to pick up DNA from the environment, even at locations where it was visually confirmed. Alternatively, the eDNA surveys worked well for C. tartarus and we were able to amplify DNA at every site where it was visually observed. Our assay for C. aculabrum was based on a single sample obtained from GenBank, and did not amplify eDNA from field samples. Lastly, our eDNA results from samples in the known range of Orconectes stygocaneyi suggested the species may be found at an additional cave. Detection using eDNA based on our O. stygocaneyi assay was likely low because it was designed from a pseudogene; however, positive eDNA samples were sequenced to confirm species-specific DNA. Detection probability of both cavefishes and cave crayfishes varied by survey technique and was influenced by water volume, water clarity, water velocity, and substrate. Detection of cavefishes and cave crayfishes via visual surveys decreased when water volume increased, whereas detection using eDNA increased with greater water volume. Detection between taxa using either sample method was highest in habitats classified by fine substrates, except for eDNA detection of crayfishes which was greatest in coarse substrates. Detection of cavefishes increased with water clarity, but detection of cave crayfishes increased with turbidity. Detection probability of both cavefishes and crayfishes using eDNA increased slightly with water velocity, but decreased with visual surveys as water velocity increased. Occupancy by both taxa was positively related to particular geologic series. Crayfish occupancy was negatively related to fine-scale anthropogenic disturbance (i.e., 500-m buffer around the site), whereas crayfish showed no relationship with disturbance. Our results suggest possible range extensions, provide insights to factors driving detection using both sample techniques, and suggest areas where recharge zones may be shared among caves. Future efforts focused on a comprehensive evaluation of genetic diversity among cave crayfishes to improve assay design could improve detection and the applicability of eDNA as a supplemental and non-invasive sampling approach.

Cooperator Science Series↗

Applied citizen science in freshwater research

Worldwide, scientists are increasingly collaborating with the general public. Citizen science methods are readily applicable to freshwater research, monitoring, and education. In addition to providing cost-effective data on spatial and temporal scales that are otherwise unattainable, citizen science provides unique opportunities for engagement with local communities and stakeholders in resource management and decision-making. However, these methods are not infallible. Citizen science projects require deliberate planning in order to collect high data quality and sustain meaningful community partnerships. Citizen science practitioners also have an ethical responsibility to ensure that projects are not putting the safety of participants at stake. We discuss here how citizen science is being applied in freshwater research, emerging challenges in project planning and implementation, as well as how citizen science is shaping public understanding, policy, and management of freshwaters.

WIREs Water↗

U.S. Geological Survey Subsidence Interest Group Conference; proceedings of the Technical Meeting, Las Vegas, Nevada, February 14-16, 1995

Introduction to Papers: This report is a compilation of short papers that are based on oral presentations summarizing the results of recent research that were given at the third meeting of the Subsidence Interest Group held in Las Vegas, Nevada, February 14-16, 1995. The report includes case studies of land subsidence and aquifer-system deformation resulting from fluid withdrawal, geothermal development, and mine collapse. Methods for monitoring land subsidence using Global Positioning System technology for the rapid and accurate measurement of changes in land-surface altitude also are described. The current status of numerical simulation of land subsidence in the USGS is summarized, and several of the short papers deal with the development and application of new numerical techniques for simulation and quantification of aquifer system deformation. Not all oral presentations made at the meeting are documented in this report. Several of the presentations were of ongoing research and as such, the findings were provisional in nature and were offered at the meeting to stimulate scientific discussion and debate among colleagues. The information presented in this report, although only a subset of the proceedings of the meeting in Las Vegas, should help expand the scientific basis for management decisions to mitigate or control the effects of land subsidence. The short papers describing the results of these studies provide a cross section of ongoing research in aquifer mechanics and land subsidence and also form an assessment of the current technology and 'state of the science.' The analytical and interpretive methods described in this report will be useful to scientists involved in studies of ground-water hydraulics and aquifer-system deformation.

Open-File Report↗

A multi-decade record of high-quality fCO2 data in version 3 of the Surface Ocean CO2 Atlas (SOCAT)

The Surface Ocean CO 2 Atlas (SOCAT) is a synthesis of quality-controlled f CO 2 (fugacity of carbon dioxide) values for the global surface oceans and coastal seas with regular updates. Version 3 of SOCAT has 14.7 million f CO 2 values from 3646 data sets covering the years 1957 to 2014. This latest version has an additional 4.6 million f CO 2 values relative to version 2 and extends the record from 2011 to 2014. Version 3 also significantly increases the data availability for 2005 to 2013. SOCAT has an average of approximately 1.2 million surface water f CO 2 values per year for the years 2006 to 2012. Quality and documentation of the data has improved. A new feature is the data set quality control (QC) flag of E for data from alternative sensors and platforms. The accuracy of surface water f CO 2 has been defined for all data set QC flags. Automated range checking has been carried out for all data sets during their upload into SOCAT. The upgrade of the interactive Data Set Viewer (previously known as the Cruise Data Viewer) allows better interrogation of the SOCAT data collection and rapid creation of high-quality figures for scientific presentations. Automated data upload has been launched for version 4 and will enable more frequent SOCAT releases in the future. High-profile scientific applications of SOCAT include quantification of the ocean sink for atmospheric carbon dioxide and its long-term variation, detection of ocean acidification, as well as evaluation of coupled-climate and ocean-only biogeochemical models. Users of SOCAT data products are urged to acknowledge the contribution of data providers, as stated in the SOCAT Fair Data Use Statement. This ESSD (Earth System Science Data) “living data” publication documents the methods and data sets used for the assembly of this new version of the SOCAT data collection and compares these with those used for earlier versions of the data collection (Pfeil et al., 2013; Sabine et al., 2013; Bakker et al., 2014).

Earth System Science Data↗

Attenuation of acid rock drainage by stimulating sulfur-reducing bacteria

Iron-sulfide minerals found in shale formations are stable under anaerobic conditions. However, in the presence of oxygen and water, acid-loving chemolithotrophic bacteria can transform the iron-sulfide minerals into a toxic solution of sulfuric acid and dissolved iron and minerals known as acid rock drainage (ARD). The objective of this study was to disrupt chemolithotrophic bacteria responsible for ARD using chemical treatments and to foster an environment favorable for competing microorganisms to attenuate the biologically induced ARD. Chemical treatments were injected into flow-through microcosms consisting of 501 g of pyrite-rich shale pieces inoculated with ARD bacteria. Three treatments were tested in the microcosms: (1) a sodium hydroxide-bleach mix, (2) a sodium lactate solution, and (3) a sodium lactate-soy infant formula mix. The effectiveness of the treatments was assessed by monitoring pH, dissolved iron, and other geochemical constituents in the discharge waters. The optimal treatment was a sequential injection of 1.5 g sodium hydroxide, followed by 0.75 g lactate and 1.5 g soy formula dissolved in 20 mL water. The pH of the discharge water rose to 6.0 within 10 days, dissolved iron concentrations dropped below 1 mg/L, the median alkalinity increased to 98 mg/L CaCO 3 , and sulfur-reducing and slime-producing bacteria populations were stimulated. The ARD attenuating benefits of this treatment were still evident after 231 days. Other treatments provided a number of ARD attenuating effects but were tempered by problems such as high phosphate concentrations, short longevity, or other shortcomings. The results of these laboratory microcosm experiments were promising for the attenuation of ARD. Additional investigations and careful selection of treatment methods will be needed for field application.

Tennessee↗

Nitrate in groundwater of the United States, 1991-2003

An assessment of nitrate concentrations in groundwater in the United States indicates that concentrations are highest in shallow, oxic groundwater beneath areas with high N inputs. During 1991-2003, 5101 wells were sampled in 51 study areas throughout the U.S. as part of the U.S. Geological Survey National Water-Quality Assessment (NAWQA) program. The well networks reflect the existing used resource represented by domestic wells in major aquifers (major aquifer studies), and recently recharged groundwater beneath dominant land-surface activities (land-use studies). Nitrate concentrations were highest in shallow groundwater beneath agricultural land use in areas with well-drained soils and oxic geochemical conditions. Nitrate concentrations were lowest in deep groundwater where groundwater is reduced, or where groundwater is older and hence concentrations reflect historically low N application rates. Classification and regression tree analysis was used to identify the relative importance of N inputs, biogeochemical processes, and physical aquifer properties in explaining nitrate concentrations in groundwater. Factors ranked by reduction in sum of squares indicate that dissolved iron concentrations explained most of the variation in groundwater nitrate concentration, followed by manganese, calcium, farm N fertilizer inputs, percent well-drained soils, and dissolved oxygen. Overall, nitrate concentrations in groundwater are most significantly affected by redox conditions, followed by nonpoint-source N inputs. Other water-quality indicators and physical variables had a secondary influence on nitrate concentrations.

Environmental Science & Technology↗

A science-based, watershed strategy to support effective remediation of abandoned mine lands

A U.S. Geological Survey Abandoned Mine Lands Initiative will develop a strategy for gathering and communicating the scientific information needed to formulate effective and cost-efficient remediation of abandoned mine lands. A watershed approach will identify, characterize, and remediate contaminated sites that have the most profound effect on water and ecosystem quality within a watershed. The Initiative will be conducted during 1997 through 2001 in two pilot watersheds, the Upper Animas River watershed in Colorado and the Boulder River watershed in Montana. Initiative efforts are being coordinated with the U.S. Forest Service, Bureau of Land Management, National Park Service, and other stakeholders which are using the resulting scientific information to design and implement remediation activities. The Initiative has the following eight objective-oriented components: estimate background (pre-mining) conditions; define baseline (current) conditions; identify target sites (major contaminant sources); characterize target sites and processes affecting contaminant dispersal; characterize ecosystem health and controlling processes at target sites; develop remediation goals and monitoring network; provide an integrated, quality-assured and accessible data network; and document lessons learned for future applications of the watershed approach.

Colorado;Montana↗

Mineral Commodity Profiles -- Rubidium

Overview -- Rubidium is a soft, ductile, silvery-white metal that melts at 39.3 ?C. One of the alkali metals, it is positioned in group 1 (or IA) of the periodic table between potassium and cesium. Naturally occurring rubidium is slightly radioactive. Rubidium is an extremely reactive metal--it ignites spontaneously in the presence of air and decomposes water explosively, igniting the liberated hydrogen. Because of its reactivity, the metal and several of its compounds are hazardous materials, and must be stored and transported in isolation from possible reactants. Although rubidium is more abundant in the earth?s crust than copper, lead, or zinc, it forms no minerals of its own, and is, or has been, produced in small quantities as a byproduct of the processing of cesium and lithium ores taken from a few small deposits in Canada, Namibia, and Zambia. In the United States, the metal and its compounds are produced from imported raw materials by at least one company, the Cabot Corporation (Cabot, 2003). Rubidium is used interchangeably or together with cesium in many uses. Its principal application is in specialty glasses used in fiber optic telecommunication systems. Rubidium?s photoemissive properties have led to its use in night-vision devices, photoelectric cells, and photomultiplier tubes. It has several uses in medical science, such as in positron emission tomographic (PET) imaging, the treatment of epilepsy, and the ultracentrifugal separation of nucleic acids and viruses. A dozen or more other uses are known, which include use as a cocatalyst for several organic reactions and in frequency reference oscillators for telecommunications network synchronization. The market for rubidium is extremely small, amounting to 1 to 2 metric tons per year (t/yr) in the United States. World resources are vast compared with demand.

Open-File Report↗

Techniques for restoration of disturbed coastal wetlands of the Great Lakes

A long history of human-induced degradation of Great Lakes wetlands has made restoration a necessity, but the practice of wetland restoration is relatively new, especially in large lake systems. Therefore, we compiled tested methods and developed additional potential methods based on scientific understanding of Great Lakes wetland ecosytems to providc an overview of approaches for restoration. We addressed this challenge by focusing on four general fields of science: hydrology, sedimentology, chemistry, and biology. Hydrologic remediation methods include restoring hydrologic connections between diked and hydrologically altered wetlands and the lakes, restoring water tables lowered by ditching, and restoring natural variation in lake levels of regulated lakes Superior and Ontario. Sedimentological remediation methods include management of sediment input from uplands, removal or proper management of dams on tributary rivers, and restoration of protective barrier beaches and sand spits. Chemical remediation methods include reducing or eliminating inputs of contaminants from point and non-pont sources, natural sediment remediation by biodegradation and chemical degradation, and active sediment remediation by removal or by in situ treatment Biological remediation methods include control of non-target organisms, enhancing populations of target organisms, and enhancing habitat for target organisms. Some of these method were used in three major restoration projects (Metzger Marsh on Lake Erie and Cootes Paradise and Oshawa Second Marsh on Lake Ontario), which are described as case studies to show practical applications of wetland restoration in the Great Lakes. Successful restoration techniques that do not require continued manipulation must be founded in the basic tenets of ecology and should mimic natural processes. Success is demonstrated by the sustainability, productivity, nutrient-retention ability, invasibility, and biotic interactions within a restored wetland.

Wetlands↗

Vulnerability of shallow groundwater and drinking-water wells to nitrate in the United States

Two nonlinear models were developed at the national scale to (1) predict contamination of shallow ground water (typically < 5 m deep) by nitrate from nonpoint sources and (2) to predict ambient nitrate concentration in deeper supplies used for drinking. The new models have several advantages over previous national-scale approaches. First, they predict nitrate concentration (rather than probability of occurrence), which can be directly compared with water-quality criteria. Second, the models share a mechanistic structure that segregates nitrogen (N) sources and physical factors that enhance or restrict nitrate transport and accumulation in ground water. Finally, data were spatially averaged to minimize small-scale variability so that the large-scale influences of N loading, climate, and aquifer characteristics could more readily be identified. Results indicate that areas with high N application, high water input, well-drained soils, fractured rocks or those with high effective porosity, and lack of attenuation processes have the highest predicted nitrate concentration. The shallow groundwater model (mean square error or MSE = 2.96) yielded a coefficient of determination ( R 2 ) of 0.801, indicating that much of the variation in nitrate concentration is explained by the model. Moderate to severe nitrate contamination is predicted to occur in the High Plains, northern Midwest, and selected other areas. The drinking-water model performed comparably (MSE = 2.00, R 2 = 0.767) and predicts that the number of users on private wells and residing in moderately contaminated areas (>5 to ≤10 mg/L nitrate) decreases by 12% when simulation depth increases from 10 to 50 m.

Environmental Science & Technology↗